CN114561813A - Dual-channel formaldehyde-removing sunshade composite material - Google Patents
Dual-channel formaldehyde-removing sunshade composite material Download PDFInfo
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- CN114561813A CN114561813A CN202210315488.1A CN202210315488A CN114561813A CN 114561813 A CN114561813 A CN 114561813A CN 202210315488 A CN202210315488 A CN 202210315488A CN 114561813 A CN114561813 A CN 114561813A
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- 239000002131 composite material Substances 0.000 title claims abstract description 27
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 252
- 238000001179 sorption measurement Methods 0.000 claims abstract description 34
- 230000003647 oxidation Effects 0.000 claims abstract description 31
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 31
- 230000001699 photocatalysis Effects 0.000 claims abstract description 29
- 239000004744 fabric Substances 0.000 claims abstract description 25
- 239000011248 coating agent Substances 0.000 claims abstract description 18
- 238000000576 coating method Methods 0.000 claims abstract description 18
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002002 slurry Substances 0.000 claims abstract description 15
- 238000005187 foaming Methods 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 230000002940 repellent Effects 0.000 claims abstract description 4
- 239000005871 repellent Substances 0.000 claims abstract description 4
- 239000006255 coating slurry Substances 0.000 claims description 17
- 238000002156 mixing Methods 0.000 claims description 13
- 229920000058 polyacrylate Polymers 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 11
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims description 8
- 229940088990 ammonium stearate Drugs 0.000 claims description 7
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical compound [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 claims description 7
- 239000006260 foam Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000003381 stabilizer Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- 229920000728 polyester Polymers 0.000 claims description 5
- 239000002759 woven fabric Substances 0.000 claims description 5
- 239000004677 Nylon Substances 0.000 claims description 4
- 229920001778 nylon Polymers 0.000 claims description 4
- 229920013822 aminosilicone Polymers 0.000 claims description 3
- 238000004043 dyeing Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 230000003197 catalytic effect Effects 0.000 abstract description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 3
- 238000000354 decomposition reaction Methods 0.000 abstract description 2
- 238000007146 photocatalysis Methods 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 76
- 239000003463 adsorbent Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 230000029087 digestion Effects 0.000 description 4
- 238000005034 decoration Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011941 photocatalyst Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 208000000059 Dyspnea Diseases 0.000 description 1
- 206010013975 Dyspnoeas Diseases 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- -1 plates Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 208000018316 severe headache Diseases 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/042—Acrylic polymers
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- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0034—Polyamide fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0036—Polyester fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
- D06N3/0047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by incorporating air, i.e. froth
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
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- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
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- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
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- D06N2209/00—Properties of the materials
- D06N2209/08—Properties of the materials having optical properties
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- D06N2209/00—Properties of the materials
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- D06N2209/148—Superabsorbing
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- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/165—Odour absorbing, deodorizing ability
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- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/122—Curtains
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- D06N2213/00—Others characteristics
- D06N2213/02—All layers being of the same kind of material, e.g. all layers being of polyolefins, all layers being of polyesters
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Abstract
The invention discloses a two-channel formaldehyde-removing sun-shading composite material which comprises a fabric base layer, a formaldehyde capturing layer arranged on the fabric base layer, a porous adsorption layer arranged on the formaldehyde capturing layer, a photocatalytic oxidation formaldehyde-removing layer arranged on the porous adsorption layer, and a soft surface slurry layer arranged on the photocatalytic oxidation formaldehyde-removing layer; the fabric base layer is subjected to water repellent finishing and then is processed by a laminated composite coating. The formaldehyde catching layer can react with formaldehyde to form an acylhydrazone structure through polymethacrylhydrazide to digest formaldehyde; the porous adsorption layer is provided with a foaming structure and diatom ooze, so that formaldehyde in the environment where the sun-shading material is located can be effectively adsorbed; the nano manganese dioxide in the photocatalytic oxidation formaldehyde removal layer can perform catalytic oxidation decomposition on formaldehyde enriched in the adsorption layer, so that the adsorption layer is promoted to continuously adsorb free formaldehyde in the air; can be applied to indoor curtains and other sun-shading materials, and has good functions of shading sun, continuously adsorbing formaldehyde, capturing and digesting formaldehyde and decomposing formaldehyde by photocatalysis.
Description
Technical Field
The invention relates to the technical field of building decoration materials, in particular to a two-channel formaldehyde-removing sun-shading composite material.
Background
Formaldehyde is one of the most representative substances in indoor pollutants, and if the interior is over-decorated or building materials (such as paint, plates, glue and the like) are not properly selected, heavy decoration pollution can be caused, including the generation of excessively high concentration of formaldehyde. Such contamination can be extremely harmful to humans, causing the human to experience symptoms such as dyspnea, severe headache, burning throat, etc. Therefore, effectively reducing or controlling the concentration of formaldehyde in the room is an effective means for guaranteeing the health of the human body.
The adsorption method is to perform physical adsorption by utilizing the characteristic that an adsorption medium has a developed pore structure, and common porous adsorbents comprise activated carbon, zeolite molecular sieves, diatom ooze, attapulgite and the like. The raw material sources of the adsorbent are wide, but the adsorbent can not adsorb formaldehyde molecules on a pore structure of the adsorbent because of the maximum adsorption value of each adsorbent in use, and secondary pollution can be caused after the formaldehyde molecules break away, so that the formaldehyde removal efficiency is reduced. Therefore, how to effectively eliminate the adsorbed formaldehyde molecules is a key problem for improving the purification effect of the adsorbents. The photocatalytic oxidation method is characterized in that electrons of a photocatalyst are excited by energy under the irradiation of light with certain wavelength, so that formaldehyde is oxidized to generate water and carbon dioxide, the catalyst can only digest smaller surrounding formaldehyde, and the active digestion effect on formaldehyde at other indoor positions is not achieved; therefore, the design and preparation of new materials with high formaldehyde removal function are very important.
The sunshade composite material is a fiber-based building decoration material which is processed by adopting chemical fiber filaments as a base material and adopting double-layer tissue weaving or coating finishing. Along with the improvement of living standard of people, the quality of the sun-shading composite material is required to be higher, the content of formaldehyde released by the sun-shading composite material is required to be lower, and the sun-shading composite material has a certain formaldehyde removing effect in use. In view of this, a sun-shading composite material with formaldehyde removing function can be designed, which not only can shade the sun, but also has a composite dual-channel formaldehyde removing function, for example, formaldehyde can be removed through adsorption and photocatalyst oxidation (i.e. formaldehyde in the environment is enriched by virtue of the adsorbent, and then the adsorbed formaldehyde is removed through catalytic oxidation under the illumination condition), and formaldehyde can also be removed through adsorption and capture agent digestion (i.e. formaldehyde capture agent can react with the formaldehyde enriched by the adsorbent, so as to achieve the digestion of formaldehyde in the environment); the design and preparation of the sunshade composite material with the dual-channel formaldehyde removal function have positive application value and potential market prospect.
Disclosure of Invention
The invention aims to provide a two-channel formaldehyde-removing sun-shading composite material, which is processed by coating, laminating and attaching, has a sun-shading effect, can remove formaldehyde in an environment through two channels, and specifically comprises the following steps: (1) adsorbing formaldehyde in an indoor environment by using diatom ooze in the sun-shading material, and then removing the adsorbed formaldehyde by using nano manganese dioxide in a surface layer of the sun-shading material through photocatalytic oxidation under the illumination condition; (2) the absorption and the digestion of the catching agent are carried out, namely, formaldehyde in the indoor environment is absorbed by means of diatom ooze in the sunshade material, and then the polymethacrylhydrazide in the sunshade material reacts with the formaldehyde to generate an acylhydrazone structure, so that the formaldehyde is removed, and the sunshade composite material is endowed with two-channel formaldehyde removal and better formaldehyde removal effects.
In order to achieve the purpose, the invention provides the following technical scheme: a two-channel formaldehyde-removing sun-shading composite material comprises a fabric base layer, a formaldehyde capturing layer arranged on the fabric base layer, a porous adsorption layer arranged on the formaldehyde capturing layer, a photocatalytic oxidation formaldehyde-removing layer arranged on the porous adsorption layer, and a soft surface slurry layer arranged on the photocatalytic oxidation formaldehyde-removing layer; the fabric base layer is subjected to water repellent finishing and then is processed by a laminated composite coating, and a formaldehyde capturing layer, a porous adsorption layer, a photocatalytic oxidation formaldehyde removing layer and a soft surface slurry layer are sequentially formed above the fabric base layer.
Preferably, the fabric base layer is a polyester or nylon filament woven fabric which is subjected to jacquard, dyeing or printing processing and is subjected to waterproof finishing, and the gram weight of the polyester or nylon filament woven fabric is 100-150 g/m2。
Preferably, the formaldehyde capturing layer is formed by mixing a formaldehyde capturing agent polymethacrylhydrazide with a polyacrylate emulsion, coating the mixture on the fabric base layer and baking, and the gram weight of the formaldehyde capturing layer is 25-40 g/m2。
Preferably, the porous adsorption layer is prepared by mixing diatom ooze and ammonium stearate serving as a foam stabilizer into polyacrylate emulsion to prepare foaming coating slurry, coating the foaming coating slurry on the formaldehyde capturing layer and baking the formaldehyde capturing layer, wherein the diatom ooze is prepared by mixing diatom ooze and ammonium stearate serving as a foam stabilizerThe grain diameter is 0.5-2.0 microns, and the gram weight of the porous adsorption layer is 50-75 g/m2。
Preferably, the photocatalytic oxidation aldehyde removal layer is prepared by mixing nano manganese dioxide and ammonium stearate serving as a foam stabilizer in a polyacrylate emulsion to prepare foaming coating slurry, coating the foaming coating slurry on the porous adsorption layer and baking, wherein the particle size of the nano manganese dioxide is 200-400 nanometers, and the gram weight of the photocatalytic oxidation aldehyde removal layer is 40-60 g/m2。
Preferably, the soft surface slurry layer is prepared by mixing amino silicone oil into polyacrylate emulsion to prepare coating slurry, coating the coating slurry on a photocatalytic oxidation formaldehyde removal layer and baking, and the gram weight of the soft surface slurry layer is 25-40 g/m2。
Compared with the prior art, the invention has the beneficial effects that:
(1) the fabric base layer endows the sun-shading composite material with appearance effect; (2) the formaldehyde catching layer can react with formaldehyde through polymethacrylhydrazide to form an acylhydrazone structure, and the formaldehyde is digested; (3) the porous adsorption layer is provided with a foaming structure and diatom ooze, so that formaldehyde in the environment where the sun-shading material is located can be effectively adsorbed; (4) the nano manganese dioxide in the photocatalytic oxidation formaldehyde removal layer can perform catalytic oxidation decomposition on formaldehyde enriched in the adsorption layer, so that the adsorption layer is promoted to continuously adsorb free formaldehyde in the air; (5) the soft surface slurry layer not only endows the composite material with better hand feeling, but also has light transmittance, ensures that visible light can penetrate through the soft surface slurry layer to enter the photocatalytic oxidation formaldehyde removal layer, and realizes continuous formaldehyde removal; therefore, the sunshade composite material with the dual-channel formaldehyde removing function can be applied to processing of sunshade materials such as indoor curtains and the like, and has good functions of shading sun, continuously adsorbing formaldehyde, capturing and digesting formaldehyde and decomposing formaldehyde through photocatalysis.
Drawings
FIG. 1 is a schematic cross-sectional view of the present invention.
In the figure: 1. a fabric base layer; 2. a formaldehyde trapping layer; 3. a porous adsorption layer; 4. removing the aldehyde layer by photocatalytic oxidation; 5. and (4) a soft surface sizing layer.
Detailed Description
The technical solution in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1, an embodiment of the present invention: a two-channel formaldehyde-removing sun-shading composite material comprises a fabric base layer 1, a formaldehyde capturing layer 2 arranged on the fabric base layer 1, a porous adsorption layer 3 arranged on the formaldehyde capturing layer 2, a photocatalytic oxidation formaldehyde-removing layer 4 arranged on the porous adsorption layer 3, and a soft slurry layer 5 arranged on the photocatalytic oxidation formaldehyde-removing layer 4; the fabric base layer 1 is subjected to water repellent finishing and then is processed by a laminated composite coating, and a formaldehyde capturing layer 2, a porous adsorption layer 3, a photocatalytic oxidation formaldehyde removing layer 4 and a soft surface slurry layer 5 are sequentially formed above the fabric base layer 1;
in the technical scheme, the fabric base layer 1 is a polyester filament yarn woven fabric which is subjected to jacquard, dyeing or printing processing and waterproof finishing, and the gram weight is 100 g/m2(ii) a The formaldehyde catching layer 2 arranged on the fabric base layer 1 is formed by mixing a formaldehyde catching agent polymethacrylhydrazide into a polyacrylate emulsion, coating the mixture on the fabric base layer 1 and baking, and the gram weight of the formaldehyde catching layer 2 is 25g/m2(ii) a The porous adsorption layer 3 arranged on the formaldehyde capturing layer 2 is prepared by mixing diatom ooze and foam stabilizer ammonium stearate in polyacrylate emulsion to prepare foaming coating slurry, coating the foaming coating slurry on the formaldehyde capturing layer 2 and baking, wherein the particle size of the diatom ooze is 0.5 micron, and the gram weight of the porous adsorption layer 3 is 50 g/m2(ii) a The photocatalytic oxidation aldehyde removal layer 4 arranged on the porous adsorption layer 3 is formed by mixing nano manganese dioxide and ammonium stearate serving as a foam stabilizer into polyacrylate emulsion to prepare foaming coating slurry, coating the foaming coating slurry on the porous adsorption layer 3 and baking, wherein the particle size of the nano manganese dioxide is 200 nanometers, and the gram weight of the photocatalytic oxidation aldehyde removal layer 4 is 40 g/m2(ii) a The soft surface slurry layer 5 arranged on the photocatalytic oxidation layer 4 is formed by mixing amino silicone oil into polyacrylate emulsion to prepare coating slurry, coating the coating slurry on the photocatalytic oxidation formaldehyde-removing layer 4 and baking, and the weight of the soft surface slurry layer 5 is 25g/m2。
Claims (6)
1. The utility model provides a sunshade combined material of aldehyde is removed to binary channels which characterized in that: the fabric comprises a fabric base layer (1), a formaldehyde capturing layer (2) arranged on the fabric base layer (1), a porous adsorption layer (3) arranged on the formaldehyde capturing layer (2), a photocatalytic oxidation formaldehyde removing layer (4) arranged on the porous adsorption layer (3), and a soft surface slurry layer (5) arranged on the photocatalytic oxidation formaldehyde removing layer (4); the fabric base layer (1) is subjected to water repellent finishing and then laminated composite coating processing, and a formaldehyde capturing layer (2), a porous adsorption layer (3), a photocatalytic oxidation formaldehyde removing layer (4) and a soft surface slurry layer (5) are sequentially formed above the fabric base layer (1).
2. The two-channel formaldehyde-removing sun-shading composite material as claimed in claim 1, wherein the fabric base layer (1) is a polyester or nylon filament woven fabric which is subjected to jacquard, dyeing or printing and waterproof finishing, and the gram weight of the polyester or nylon filament woven fabric is 100-150 g/m2。
3. The two-channel formaldehyde-removing sun-shading composite material as claimed in claim 1, wherein the formaldehyde capturing layer (2) is prepared by mixing a formaldehyde capturing agent polymethacrylhydrazide with a polyacrylate emulsion, coating the mixture on the fabric base layer (1) and baking, and the gram weight of the formaldehyde capturing layer (2) is 25-40 g/m2。
4. The two-channel formaldehyde-removing sun-shading composite material as claimed in claim 1, wherein the porous adsorption layer (3) is prepared by mixing diatom ooze and ammonium stearate serving as a foam stabilizer in polyacrylate emulsion to prepare foaming coating slurry, coating the foaming coating slurry on the formaldehyde capturing layer (2) and baking, wherein the particle size of the diatom ooze is 0.5-2.0 microns, and the gram weight of the porous adsorption layer (3) is 50-75 g/m2。
5. The sunshade composite material with two-channel aldehyde removal function as claimed in claim 1, wherein the photocatalytic oxidation aldehyde removal layer (4) is prepared by mixing nano manganese dioxide and ammonium stearate serving as a foam stabilizer in polyacrylate emulsionThe foaming coating slurry is formed by coating the porous adsorption layer (3) with baking, wherein the particle size of the nano manganese dioxide is 200-400 nanometers, and the gram weight of the photocatalytic oxidation formaldehyde removal layer (4) is 40-60 g/m2。
6. The two-channel formaldehyde-removing sun-shading composite material as claimed in claim 1, wherein the soft surface slurry layer (5) is prepared by mixing amino silicone oil into polyacrylate emulsion to prepare coating slurry, coating the coating slurry on the photocatalytic oxidation formaldehyde-removing layer (4) and baking, and the gram weight of the soft surface slurry layer (5) is 25-40 g/m2。
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN115463538A (en) * | 2022-08-16 | 2022-12-13 | 成都柴多多商贸有限公司 | Formaldehyde-removing odor-removing composition and preparation method and application thereof |
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JPH10296919A (en) * | 1997-02-27 | 1998-11-10 | Dainippon Printing Co Ltd | Sheet for capturing formaldehyde and decorative plate |
JP2000062128A (en) * | 1998-08-24 | 2000-02-29 | Dainippon Printing Co Ltd | Decorative sheet and decorative laminated sheet |
CN205189328U (en) * | 2015-11-13 | 2016-04-27 | 沈阳领拓科技有限公司 | Environment -friendly night light wall paper with indoor air purification function |
CN113861786A (en) * | 2021-11-24 | 2021-12-31 | 海宁德易遮阳科技有限公司 | Preparation method of coating slurry capable of adsorbing, removing formaldehyde and purifying air |
CN215481923U (en) * | 2021-06-05 | 2022-01-11 | 海宁德易遮阳科技有限公司 | Sun-shading composite material with formaldehyde removing function |
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JPH10296919A (en) * | 1997-02-27 | 1998-11-10 | Dainippon Printing Co Ltd | Sheet for capturing formaldehyde and decorative plate |
JP2000062128A (en) * | 1998-08-24 | 2000-02-29 | Dainippon Printing Co Ltd | Decorative sheet and decorative laminated sheet |
CN205189328U (en) * | 2015-11-13 | 2016-04-27 | 沈阳领拓科技有限公司 | Environment -friendly night light wall paper with indoor air purification function |
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