CN114551749A - Flexible array substrate, display panel, display screen and electronic equipment - Google Patents

Flexible array substrate, display panel, display screen and electronic equipment Download PDF

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Publication number
CN114551749A
CN114551749A CN202011360868.4A CN202011360868A CN114551749A CN 114551749 A CN114551749 A CN 114551749A CN 202011360868 A CN202011360868 A CN 202011360868A CN 114551749 A CN114551749 A CN 114551749A
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China
Prior art keywords
metal
array substrate
flexible array
anode
cathode
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CN202011360868.4A
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Chinese (zh)
Inventor
毕文涛
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Beijing Xiaomi Mobile Software Co Ltd
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Beijing Xiaomi Mobile Software Co Ltd
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Priority to CN202011360868.4A priority Critical patent/CN114551749A/en
Publication of CN114551749A publication Critical patent/CN114551749A/en
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/805Electrodes
    • H10K50/81Anodes
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F9/00Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements
    • G09F9/30Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements
    • G09F9/301Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements flexible foldable or roll-able electronic displays, e.g. thin LCD, OLED
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F9/00Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements
    • G09F9/30Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements
    • G09F9/33Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements being semiconductor devices, e.g. diodes
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/30Devices specially adapted for multicolour light emission
    • H10K59/38Devices specially adapted for multicolour light emission comprising colour filters or colour changing media [CCM]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/549Organic PV cells

Abstract

The utility model provides a flexible array substrate, display panel, display screen and electronic equipment. The flexible array substrate comprises a substrate, a back plate, an anode, an organic light emitting layer, a cathode, an encapsulating layer and a color film layer, wherein the back plate, the anode, the organic light emitting layer, the cathode and the encapsulating layer are arranged on the substrate in a laminated mode, the anode is made of metal silver, the first metal with smaller light reflectivity is doped into the metal silver, and therefore the light reflectivity of the anode is reduced. Meanwhile, the light transmittance of the color film layer is larger than that of the polarizer, and compared with the polarizer, the light-emitting quantum efficiency of the flexible array substrate is improved and the display power consumption is reduced by using the color film layer.

Description

Flexible array substrate, display panel, display screen and electronic equipment
Technical Field
The present disclosure relates to the field of array substrate technology, and in particular, to a flexible array substrate, a display panel, a display screen, and an electronic device.
Background
Some display panels include a flexible array substrate including an anode and a cathode, and when external ambient light is irradiated to the anode and the cathode, emission occurs, and the existence of reflected light reduces the contrast of the display panel, which seriously affects the viewing experience of a user.
In order to solve the above technical problems, in the related art, a polarizer is additionally disposed in the flexible array substrate to reduce the reflected light. However, the polarizer is thick, and the thickness of the display panel is greatly increased by using the polarizer, which is not favorable for bending the flexible array substrate. Meanwhile, the maximum light transmittance of the polarizer is low, only about 50%, which seriously affects the luminous quantum efficiency of the flexible array substrate and increases the display power consumption.
Disclosure of Invention
The present disclosure provides an improved flexible array substrate, a display panel, a display screen and an electronic device.
The first aspect of the present disclosure provides a flexible array substrate, which includes a substrate, and a back plate, an anode, an organic light emitting layer, a cathode, an encapsulation layer, and a color film layer, which are stacked on the substrate;
the material of the anode comprises metal silver, the metal silver in the anode is doped with a first metal, and the light reflectivity of the first metal is smaller than that of the metal silver.
Optionally, in the anode, the mass ratio of the metallic silver to the first metal ranges from 1:1 to 9: 1.
Optionally, in the anode, the mass ratio of the metallic silver to the first metal is 4: 1.
Optionally, the first metal comprises at least one of: metal magnesium, metal aluminum, metal gold.
Optionally, the material of the cathode includes metallic silver, and the metallic silver in the cathode is doped with a second metal, and the light reflectivity of the second metal is smaller than that of the metallic silver.
Optionally, in the cathode, the mass ratio of the metallic silver to the second metal ranges from 1:1 to 9: 1.
Optionally, in the cathode, the mass ratio of the metallic silver to the second metal is 4: 1.
Optionally, the second metal comprises at least one of: metal magnesium, metal aluminum, metal gold.
A second aspect of the present disclosure provides a display panel including the flexible array substrate of any one of the first aspects.
A third aspect of the present disclosure provides a display screen including the display panel of the second aspect.
A fourth aspect of the present disclosure provides an electronic device including the display screen of the third aspect.
The flexible array substrate provided by the embodiment of the disclosure comprises a substrate, a back plate, an anode, an organic light emitting layer, a cathode, a packaging layer and a color film layer, wherein the back plate, the anode, the organic light emitting layer, the cathode, the packaging layer and the color film layer are stacked on the substrate, the anode is made of metal silver, and the first metal with smaller light reflectivity is doped into the metal silver, so that the light reflectivity of the anode is reduced. Meanwhile, the light transmittance of the color film layer is larger than that of the polarizer, and compared with the polarizer, the light-emitting quantum efficiency of the flexible array substrate is improved and the display power consumption is reduced by using the color film layer.
Drawings
Fig. 1 is a schematic structural diagram of a flexible array substrate according to an exemplary embodiment of the present disclosure.
Detailed Description
Reference will now be made in detail to the exemplary embodiments, examples of which are illustrated in the accompanying drawings. When the following description refers to the accompanying drawings, like numbers in different drawings represent the same or similar elements unless otherwise indicated. The implementations described in the exemplary embodiments below are not intended to represent all implementations consistent with the present disclosure. Rather, they are merely examples of apparatus and methods consistent with certain aspects of the present disclosure, as detailed in the appended claims.
The terminology used in the present disclosure is for the purpose of describing particular embodiments only and is not intended to be limiting of the disclosure. Unless otherwise defined, technical or scientific terms used herein shall have the ordinary meaning as understood by one of ordinary skill in the art to which this disclosure belongs. The use of "first," "second," and similar terms in the description and claims does not indicate any order, quantity, or importance, but rather is used to distinguish one element from another. Also, the use of the terms a, an, etc. do not denote a limitation of quantity, but rather denote the presence of at least one. Unless otherwise indicated, the word "comprise" or "comprises", and the like, means that the element or item listed before "comprises" or "comprising" covers the element or item listed after "comprises" or "comprising" and its equivalents, and does not exclude other elements or items. The terms "connected" or "coupled" and the like are not restricted to physical or mechanical connections, but may include electrical connections, whether direct or indirect.
As used in this disclosure and the appended claims, the singular forms "a", "an", and "the" are intended to include the plural forms as well, unless the context clearly indicates otherwise. It should also be understood that the term "and/or" as used herein refers to and encompasses any and all possible combinations of one or more of the associated listed items.
The embodiment of the disclosure provides a flexible array substrate, which comprises a substrate, and a back plate, an anode, an organic light emitting layer, a cathode, an encapsulation layer and a color film layer which are arranged on the substrate in a laminated manner, wherein the anode is made of metal silver, the metal silver in the anode is doped with a first metal, and the light reflectivity of the first metal is smaller than that of the metal silver.
The first metal with smaller light reflectivity is doped in the metal silver in the anode, the light reflectivity of the anode is reduced by the first metal, and on the basis, the color film layer is used for replacing the polarizer in the conventional flexible array substrate, so that the thickness of the flexible array substrate is reduced and the bending performance of the flexible array substrate is enhanced under the condition that the flexible array substrate has higher contrast. Meanwhile, the light transmittance of the color film layer is larger than that of the polarizer, and compared with the polarizer, the light-emitting quantum efficiency of the flexible array substrate is improved and the display power consumption is reduced by using the color film layer.
In one embodiment, the amount of the first metal in the anode can be set as desired.
For example, in the anode, the mass ratio of metallic silver to the first metal ranges from 1:1 to 9: 1. Optionally, in the anode, the mass ratio of metallic silver to the first metal is 4: 1.
In one embodiment, a variety of first metals are suitable. For example, the first metal comprises at least one of: metal magnesium, metal aluminum, metal gold.
In one embodiment, the material of the cathode comprises metallic silver, the metallic silver in the cathode is doped with a second metal, and the light reflectivity of the second metal is less than the light reflectivity of the metallic silver.
The second metal with smaller light reflectivity is doped into the metal silver in the cathode, so that the light reflectivity of the cathode is reduced, the quantity of reflected light generated by the flexible array substrate is further reduced, and the contrast of the flexible array substrate is improved.
In one embodiment, the amount of the second metal in the cathode can be set as desired.
For example, in the cathode, the mass ratio of metallic silver to the second metal ranges from 1:1 to 9: 1. Optionally, in the cathode, the mass ratio of metallic silver to the second metal is 4: 1.
In one embodiment, a plurality of second metals are suitable. For example, the second metal comprises at least one of: metal magnesium, metal aluminum, metal gold.
In one embodiment, the first metal doped in the anode is the same or different than the second metal doped in the cathode. For example, the light emissivity of metal silver is above 95%, the light emissivity of metal magnesium is about 89%, the light reflectivity of metal silver is greater than that of metal magnesium, and the first metal and the second metal are both metal magnesium, or the first metal is metal magnesium and the second metal is metal aluminum.
In one embodiment, fig. 1 is a schematic structural diagram of a flexible array substrate according to an exemplary embodiment of the present disclosure, where the flexible array substrate shown in fig. 1 is a top-emission flexible array substrate, and includes a substrate, and a back plate, an anode, an organic light-emitting layer, a cathode, a capping layer, an encapsulation layer, a color film layer, and a cover plate, which are stacked on the substrate; wherein the content of the first and second substances,
the anode has an ITO/Ag + Mg/ITO structure, and metal magnesium is doped in the metal silver of the anode. In the anode, the mass ratio of metallic silver to metallic magnesium was 4: 1.
The metal film including Ag and Mg can be formed by magnetron sputtering or the like.
The thickness of the anode can be set as desired, for example, the thickness of the film layer of the anode is 5nm-20 nm.
The organic light-emitting layer comprises a Hole Injection Layer (HIL), a Hole Transport Layer (HTL) and an Electron Transport Layer (ETL) which are arranged in a laminated mode, wherein the hole injection layer is located on one side, far away from the back plate, of the anode, and the electron transport layer is located on one side, far away from the capping layer, of the cathode.
The hole injection layer may be formed of small organic molecules. For example, the material of the hole injection layer includes at least one of: poly (ethylenedioxythiophene) -poly (styrenesulfonate), 2,3,5, 6-tetrafluoro-7, 7',8,8' -tetracyanoquinodimethane (F4-TCNQ).
There are various methods for forming the hole injection layer, for example, a vacuum thermal evaporation method, a one-step spin coating method, an ink jet printing method, a doctor blade method, or the like. The thickness of the hole injection layer may be set as desired, for example, the film thickness of the hole injection layer is 5nm to 30 nm.
The hole transport layer may be formed of a polymer organic material or a small molecule organic material, or the hole transport layer may be formed of a polymer organic material and a small molecule organic material.
For example, the material of the hole transport layer includes at least one of: poly [ (9, 9-di-N-octylfluorenyl-2, 7-diyl) -alt- (4, 4' - (N- (4-N-butyl) phenyl) -diphenylamine) ] (TFB), Poly (9-vinylcarbazole) (PVK), Poly [ N, N ' -bis (4-butylphenyl) -N, N ' -biphenylbenzidine ] (Poly-TPD).
There are various methods for forming the hole transport layer, for example, a vacuum thermal evaporation method, a one-step spin coating method, an ink jet printing method, a doctor blade method, and the like. The thickness of the hole transport layer may be set as desired, for example, the film thickness of the hole transport layer is 20nm to 150 nm.
The hole transport layer is provided with a light emitting layer for emitting red, a light emitting layer for emitting green, and a light emitting layer for emitting blue. The light emitting layer may be formed of an organic small molecule material, and may be host-guest doped.
For example, the material of the light emitting layer includes: tetra (t-butyl) perylene, TBP, 4' - [1, 4-phenylenedi- (1E) -2, 1-ethenediyl ] Bis [ N, N-diphenylaniline ] (1-4-di- [4- (N, N-diphenyl) amino ] styryl-benzene, DSA-PH), Tris (2-phenylpyridine) iridium (Tris (2-phenylpyridine) iridium, (Ir (ppy) iridium, (Bis (1-phenylisoquinoline) (acetylacetate) iridium (iii)), Ir (piq2 (acac)).
There are various methods for producing the light-emitting layer, for example, a vacuum thermal evaporation method, a one-step spin coating method, an ink jet printing method, a blade method, and the like. The perovskite quantum dot solution containing the materials can be prepared into a thin film to obtain a light-emitting layer. The thickness of the light-emitting layer may be set as desired, for example, the film thickness of the light-emitting layer is 20nm to 100 nm.
The electron transport layer may be formed of an organic polymer material. For example, the organic polymer material forming the electron transport layer includes at least one of: zinc oxide (ZnO), magnesium zinc oxide (ZnMgO), titanium oxide (TiO)2) Tin oxide (SnO)2) 2, 2' - (1, 3-phenyl) bis [5- (4-tert-butylphenyl) -1,3, 4-oxadiazole](OXD 7). There are various methods for fabricating an electron transport layer using an organic polymer, for example, a one-step spin coating method, an ink jet printing method, a doctor blade method, and the like.
Alternatively, the electron transport layer may be formed of an organic small molecule material. For example, the organic small molecule material forming the electron transport layer includes at least one of: 1,3, 5-tris (1-phenyl-1H-benzimidazol-2-yl) benzene (TPBi), 4, 7-diphenyl-1, 10-phenanthroline (Bphen), C60, lithium quinoline complex (Liq), 2, 9-dimethyl-4, 7-biphenyl-1, 10-phenanthroline (BCP), Alq31, 3-bis (35-bipyridin-3-yl phenyl) benzene (B)3PyPB), 4, 6-bis (3, 5-di (3-pyrid) ylphenyl) -2-phenylpyrimidine (B)3PyPPM), 3'- [5' - [3- (3-pyridyl) phenyl][1,1':3', 1' -terphenyl]-3,3 "-diyl]Bipyridine (TmPyPB), 1,3, 5-tris (4-pyridin-3-ylphenyl) benzene (TpPyPB), copper phthalocyanine (CuPc), and the like. There are various methods for fabricating the electron transport layer using organic small molecule materials, for example, a vacuum thermal evaporation method.
The thickness of the electron transport layer may be set as desired, for example, the thickness of the film layer of the electron transport layer is 20nm to 100 nm.
The cathode material comprises metallic silver, and metallic magnesium is doped in the metallic silver of the cathode. In the cathode, the mass ratio of metallic silver to metallic magnesium was 4: 1.
There are various methods for manufacturing the cathode, for example, a vacuum thermal evaporation method.
The thickness of the cathode can be set as desired, for example, the thickness of the film layer of the cathode is 5nm-20 nm.
The capping layer (CPL) is used to improve the light extraction. The capping layer may be formed on the cathode by evaporation or the like.
And performing thin film packaging on the sealing layer to form a packaging layer.
And forming a color film layer on the packaging layer to further filter unnecessary light emission spectrum and prevent reflected light generated after the ambient light irradiates the cathode and the anode from being emitted.
And a cover plate is formed on the color film layer and plays a role in protecting the color film layer. The cover plate may be a glass cover plate or a transparent PI (polyimide) or the like.
The substrate may be a transparent PI or the like.
Note that the arrow direction in fig. 1 is a direction of emitting light, and fig. 1 only illustrates the structure of the flexible array substrate, and does not limit the specific structure and size of each layer.
The embodiment of the present disclosure further provides a display panel including the flexible array substrate provided by the above embodiment of the present disclosure.
The display panel has many advantages of the flexible array substrate, such as thin thickness, good bending performance, low display power consumption, and the like.
The embodiment of the disclosure further provides a display screen, which comprises the display panel provided by the embodiment of the disclosure.
The display screen has many advantages of a display panel.
The embodiment of the present disclosure further provides an electronic device, which includes the display screen provided by the above embodiment of the present disclosure.
The electronic device has many advantages of a display screen.
There are many electronic devices, such as mobile phones, televisions, computers, wearable devices, and the like.
The above embodiments of the present disclosure may be complementary to each other without conflict.
The above description is only exemplary of the present disclosure and should not be taken as limiting the disclosure, as any modification, equivalent replacement, or improvement made within the spirit and principle of the present disclosure should be included in the scope of the present disclosure.

Claims (11)

1. The flexible array substrate is characterized by comprising a substrate, a backboard, an anode, an organic light-emitting layer, a cathode, a packaging layer and a color film layer, wherein the backboard, the anode, the organic light-emitting layer, the cathode, the packaging layer and the color film layer are arranged on the substrate in a laminated manner;
the material of the anode comprises metal silver, the metal silver in the anode is doped with a first metal, and the light reflectivity of the first metal is smaller than that of the metal silver.
2. The flexible array substrate of claim 1, wherein the mass ratio of the metallic silver to the first metal in the anode is in a range from 1:1 to 9: 1.
3. The flexible array substrate of claim 2, wherein a mass ratio of the metallic silver to the first metal in the anode is 4: 1.
4. The flexible array substrate of claim 1, wherein the first metal comprises at least one of: metal magnesium, metal aluminum, metal gold.
5. The flexible array substrate of claim 1, wherein the cathode comprises a metal silver, and the metal silver in the cathode is doped with a second metal having a light reflectivity less than that of the metal silver.
6. The flexible array substrate of claim 5, wherein the mass ratio of the metallic silver to the second metal in the cathode is in a range from 1:1 to 9: 1.
7. The flexible array substrate of claim 6, wherein a mass ratio of the metallic silver to the second metal in the cathode is 4: 1.
8. The flexible array substrate of claim 5, wherein the second metal comprises at least one of: metal magnesium, metal aluminum, metal gold.
9. A display panel comprising the flexible array substrate according to any one of claims 1 to 8.
10. A display screen is characterized by comprising the display panel 9.
11. An electronic device characterized by comprising the display screen of claim 10.
CN202011360868.4A 2020-11-27 2020-11-27 Flexible array substrate, display panel, display screen and electronic equipment Pending CN114551749A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1665678A (en) * 2002-05-08 2005-09-07 目标技术有限公司 Silver alloy thin film reflector and transparent electrical conductor
CN103811677A (en) * 2014-02-26 2014-05-21 上海和辉光电有限公司 Light-emitting diode anode reflecting layer and alloy material applied to reflecting layer
CN104009166A (en) * 2013-02-26 2014-08-27 海洋王照明科技股份有限公司 Organic electroluminescent device and preparation method
CN110071144A (en) * 2019-04-08 2019-07-30 深圳市华星光电半导体显示技术有限公司 OLED display and preparation method
CN110911463A (en) * 2019-11-28 2020-03-24 京东方科技集团股份有限公司 OLED display back plate, manufacturing method thereof and OLED display device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1665678A (en) * 2002-05-08 2005-09-07 目标技术有限公司 Silver alloy thin film reflector and transparent electrical conductor
CN104009166A (en) * 2013-02-26 2014-08-27 海洋王照明科技股份有限公司 Organic electroluminescent device and preparation method
CN103811677A (en) * 2014-02-26 2014-05-21 上海和辉光电有限公司 Light-emitting diode anode reflecting layer and alloy material applied to reflecting layer
CN110071144A (en) * 2019-04-08 2019-07-30 深圳市华星光电半导体显示技术有限公司 OLED display and preparation method
CN110911463A (en) * 2019-11-28 2020-03-24 京东方科技集团股份有限公司 OLED display back plate, manufacturing method thereof and OLED display device

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