CN114545699B - Light-adjusting film, light-adjusting glass with large camber and application of light-adjusting film and light-adjusting glass - Google Patents
Light-adjusting film, light-adjusting glass with large camber and application of light-adjusting film and light-adjusting glass Download PDFInfo
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- CN114545699B CN114545699B CN202210168604.1A CN202210168604A CN114545699B CN 114545699 B CN114545699 B CN 114545699B CN 202210168604 A CN202210168604 A CN 202210168604A CN 114545699 B CN114545699 B CN 114545699B
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1334—Constructional arrangements; Manufacturing methods based on polymer dispersed liquid crystals, e.g. microencapsulated liquid crystals
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1343—Electrodes
- G02F1/134309—Electrodes characterised by their geometrical arrangement
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/153—Constructional details
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/153—Constructional details
- G02F1/155—Electrodes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B80/00—Architectural or constructional elements improving the thermal performance of buildings
Abstract
The invention provides a light-adjusting film, high-camber light-adjustable glass and application thereof. The dimming film comprises two layers of base films, a color-changing film, two electrodes and at least one annular reinforcing layer; wherein: the color-changing film is positioned between the two base films; the annular reinforcing layer is arranged at the edge or the area within the edge of one layer of base film. The invention also provides a high-camber adjustable glass which comprises the dimming film. The invention also provides application of the high-camber adjustable glass as vehicle glass. The dimming film can reduce the possibility of generating wrinkles in a dimming visible area when being applied to glass with large camber. For high camber glass, the possibility of wrinkles generated by the membrane extending into the viewable area can be reduced by adjusting the electrodes or increasing the spacing and stiffness of the stiffening layers.
Description
Technical Field
The invention relates to a dimming film and high-camber dimmable glass, and belongs to the technical field of dimming glass.
Background
Dimming glass has become a trend today, and more automobiles will choose to choose a dimmable glass on a sunroof or side window. Current dimming technology, whether PDLC, EC, SPD or future LC, uses flexible dimming films sandwiched in two layers of glass to form a dimmable glass.
The structure of the dimming film, whether PDLC, EC, SPD or LC dimming, is substantially as shown in fig. 1. The light modulation film is generally of a three-layer structure: and a layer of color-changing substance is sandwiched between two symmetrical PET flexible films with ITO conductive layers. The periphery of the PET flexible film is provided with a circle of electrodes used for conducting electricity, and the electrodes can be conductive silver colloid or conductive copper strips. The electrodes are arranged on the periphery or part of the PET flexible film, as shown in fig. 2, the arrangement mode is mainly based on PDLC, SPD and LC, because the color change speed is high, and the electrodes do not need to be increased to improve the conduction speed.
The existing skylight glass, especially the awning glass, is large in size, has a large arch height which is basically more than 20mm/M, and has a tendency of being flat in the middle and bent at the edges, as shown in fig. 3 and 4.
In both types of color-changing films, the film is flexible PET, and the film is thin (not more than 0.4 mm), so that when the film is glued into bent glass, the film is wrinkled due to the extrusion of the glass. Further, since the most curved points of the glass are all at the edges, the resulting fold shape is such that it extends inward from the edges, and the more the edges are, the shallower the folds are, as shown in fig. 5.
Disclosure of Invention
In order to solve the above-mentioned problems, an object of the present invention is to provide a light control film, which can reduce the possibility of wrinkles generated when the light control film is laminated between glass plates by providing a reinforcing region.
To achieve the above object, a first aspect of the present invention provides a light modulation film, wherein the light modulation film comprises two base films, a color-changing film, two electrodes, and at least one annular reinforcing layer; wherein:
the color-changing film is positioned between the two base films;
the annular reinforcing layer is arranged at the edge or the area within the edge of one layer of base film.
In the above-described light modulation film of the first aspect, preferably, the light modulation film includes at least two annular reinforcing layers, and the reinforcing layers are respectively provided on surfaces of the two base films facing away from each other; and at least one of the reinforcing layers is arranged at the edge of one base film, and at least one of the reinforcing layers is arranged in an area inside the edge of the other base film.
In the light control film according to the first aspect, the annular reinforcing layer is provided on the surface of the base film, so that a certain wrinkle reducing effect can be achieved; when the surfaces of the two layers of base films are provided with the reinforcing layers, the effect of reducing wrinkles can be better achieved, namely, the surfaces of the two layers of base films, which are opposite to each other, are respectively provided with at least one annular reinforcing layer, at least one of the reinforcing layers is arranged at the edge of the base film, at least one of the reinforcing layers is arranged in an area within the edge of the base film, and the distance between the two layers of reinforcing layers is 5mm-300mm.
In the above-described light control film according to the first aspect, on the basis of not changing the structure of the existing light control film, by providing the reinforcing layer on the surface of the base film and controlling the positions thereof, the reinforcing layer on the surface of one base film is located at the edge of the base film and corresponds to the electrode on the other side, and the position of the reinforcing layer on the surface of the other base film is moved inward with respect to the edge position, and the distance between the two reinforcing layers is controlled, so that the possibility of wrinkles generated when the light control film is laminated between the two glass plates can be reduced.
In the present invention, both the reduction of wrinkles and the reduction of the possibility of wrinkles generated when the dimming film is laminated between two glass plates means that: the inventive solution has a lower probability of wrinkling than the solution in which the non-inventive dimming film is laminated between two glass plates.
In the present invention, the term "distance" refers to a distance along the surface of the base film unless otherwise specified. In the above-described light modulation film of the first aspect, the distance between the two reinforcing layers refers to the vertical distance between the edges of the same side of the two reinforcing layers, for example, L in fig. 8. The distance between the two reinforcing layers of the present invention is preferably 5mm to 300mm, which means that the distance between each side of the reinforcing layers is controlled within the above range. The specific value of the distance can be specifically selected according to the camber of the glass edge in practical application.
In the above-described light modulation film of the first aspect, preferably, the reinforcing layer has a width of 3mm to 20mm.
In the above-described light modulation film of the first aspect, preferably, the reinforcing layer has a thickness of 0.01mm to 0.2mm.
In the above-described light control film according to the first aspect, the reinforcing layer is preferably made of a material having a rigidity greater than that of the base film, and is preferably made of a metal or a nonmetal having a high rigidity. Specifically, the material of the reinforcing layer may be one or a combination of more than two of copper, silver, steel, epoxy resin and acrylic resin.
In the above-described dimming film of the first aspect, preferably, the color-changing film is one or a combination of two or more of an EC film, a PDLC film, an SPD film, and an LC film.
In the above-described light modulation film of the first aspect, it is preferable that the two electrodes are ring electrodes, respectively, and the two ring electrodes are provided on surfaces of the two base films, respectively, facing each other. The method is suitable for the technical scheme that the color-changing film is an EC film, and when the color-changing film is a PDLC film, an SPD film or an LC film, the technical scheme of arranging the annular electrode can be omitted.
In the above-described light modulation film of the first aspect, it is preferable that at least a part of the two ring electrodes in positions of the respective base film surfaces are overlapped. Overlapping here refers to: when viewed in a line of sight perpendicular to the surface of the base film, there is an overlap region between the two ring electrodes.
In the above-described light modulation film of the first aspect, it is preferable that the periphery of one base film has regions beyond the other base film, respectively (i.e., one base film completely covers the other base film and has regions beyond the periphery, respectively, where covering means that there is a portion where the two base films overlap or partially overlap when viewed at an angle perpendicular to the base films, but the two base films are not required to contact each other), the two ring electrodes are located at the edges of the respective base films, and the two ring electrodes have a certain distance therebetween, as shown in fig. 6. In this case, there is no overlap region between the two ring electrodes, i.e., there is no overlap region between the two ring electrodes when viewed in a line of sight perpendicular to the surface of the base film. According to a specific embodiment of the invention, preferably, the distance between the two ring electrodes is between 5mm and 300mm. The distance between the two annular electrodes refers to the vertical distance between the edges of the same side of the two reinforcing layers, and reference may be made to the definition of the distance between the two annular reinforcing layers.
In the above-described light control film of the first aspect, it is preferable that the two base films have a dislocation region in a lateral direction or a longitudinal direction, and the two electrodes are located in the dislocation region, respectively, as shown in fig. 7.
In the present invention, the edge provided to the base film means that the outer edge of the reinforcing layer or the electrode is completely or substantially completely overlapped with the edge (outermost edge line) of the base film; the region located within the edge of the base film means that the outer edge of the reinforcement layer or electrode is at a distance from the edge of the base film (the outermost edge line).
In the above-described light modulation film of the first aspect, it is preferable that the two reinforcement layers correspond to positions of the two ring electrodes, respectively. The positions mutually correspond to each other means: the positions between the reinforcing layers and the annular electrodes are respectively corresponding, and the positions between the reinforcing layers and the annular electrodes arranged on the two side surfaces of the same base film are overlapped or completely overlapped, namely, when the base film is observed with the line of sight perpendicular to the surface of the base film, an overlapped area exists between the corresponding reinforcing layers and the annular electrodes or the corresponding reinforcing layers and the annular electrodes are completely overlapped.
In the above-described light modulation film of the first aspect, the reinforcing layer may be adhered to the surface of the base film by glue, and the kind of glue used is not limited.
According to the specific embodiment of the invention, the dimming film provided by the first aspect of the invention can be prepared by correspondingly arranging the reinforcing layers in the preparation process, and meanwhile, the position of the formed electrode can be adjusted together to prepare the optimized dimming film, and particularly, the electrode on one side can be normally formed on the edge of the base film, and the position of the electrode on the other side can be moved inwards. The second aspect of the present invention provides a light modulation film, wherein the light modulation film comprises two layers of base films, a color-changing film and two electrodes; wherein:
the color-changing film is an EC film and is positioned between two layers of base films;
the two electrodes are annular and are respectively arranged on the surfaces of the two layers of base films facing each other, and are respectively positioned at the edges of the base films, and the distance between the two electrodes is 5mm-300mm.
In the light control film of the first and second aspects described above, preferably, the electrode is a copper foil, a silver foil, or the like. The copper foil, silver foil, etc. as the electrode has high rigidity and can be adhered on the ITO layer inside the base film by conductive silver paste. The arrangement of the ITO layer may be performed in a conventional manner.
According to a specific embodiment of the present invention, the dimming film provided in the second aspect of the present invention may be prepared by adjusting the position of forming the electrode during the preparation process, specifically, the electrode on one side is normally formed on the edge of the base film, and the position of the electrode on the other side is moved to the inner side.
In the dimming film provided by the present invention, preferably, the base film is a PET film. More preferably, the thickness of the PET film is 0.4mm or less.
A third aspect of the present invention provides a high camber dimmable glass, wherein the high camber dimmable glass comprises two glass plates and a dimming film; the dimming film is the dimming film provided by the invention.
In the large-camber dimmable glass provided in the above third aspect, preferably, the camber of the large-camber dimmable glass is 20mm/M or more.
According to a specific embodiment of the present invention, it is preferable that the selvedge of the high camber tunable glass covers 5mm or more of the reinforcing layer or electrode provided in the region within the edge of the base film.
The high camber adjustable glass provided by the invention can be prepared according to the following modes: the dimming diaphragm is clamped with glass with large camber, and the printing edge of the glass exceeds an electrode or a reinforcing layer on the inner side by more than 5mm, so that the dimming glass with large camber with flat surface and low possibility of wrinkling can be prepared.
In a fourth aspect, the present invention provides a method for reducing wrinkling in the visible area of a high camber, dimmable glass, comprising the steps of:
at least one annular reinforcing layer is respectively arranged on the surfaces of the two base films of the dimming film, which are opposite to each other, and at least one reinforcing layer is arranged at the edge of one base film and at least one reinforcing layer is arranged in the area inside the edge of the other base film.
In the method provided in the fourth aspect described above, preferably, the distance between the two reinforcing layers is 5mm to 300mm.
In the method provided in the fourth aspect, preferably, the method further includes:
the light modulation film is an EC film, the electrode of which is a ring electrode, and: at least a portion of the two ring electrodes in the locations of the respective base film surfaces are overlapped.
In the method provided in the fourth aspect, preferably, the method further includes:
the light modulation film is an EC film, the electrode of which is a ring electrode, and: one ring electrode is positioned at the edge of one layer of base film, and the other ring electrode is positioned at the area inside the edge of the base film; preferably, the distance between the two ring electrodes is 5mm-300mm.
In the method provided in the fourth aspect, preferably, during the process of laminating the bonding sheet, the edge of the large-arch tunable optical glass covers a reinforcing layer or an electrode provided in an area within the edge of the base film by 5mm or more.
By adopting the method provided by the fourth aspect of the invention, the possibility of wrinkling in the visible area of the high-camber adjustable glass can be reduced.
A fifth aspect of the present invention provides the use of a high camber dimmable glass as described above as a vehicle glazing.
The technical scheme of the invention has the following advantages:
1. the dimming film can reduce the possibility of generating wrinkles in a dimming visible area when being applied to glass with large camber. The possibility of wrinkles generated by the membrane extending into the viewable area can be reduced by adjusting the electrodes or increasing the spacing and stiffness of the stiffening layers, regardless of the height of the dome of the glass.
2. For the EC membrane, the two layers of electrodes are staggered, so that the risks of generating bubbles and cracking glass due to overlapping of the two layers of electrodes and excessive thickness of the edges are avoided.
Drawings
Fig. 1 is a schematic structural view of a dimming film provided in comparative example 1.
Fig. 2 is a schematic diagram of an electrode arrangement of a conventional light modulation film.
Fig. 3 and 4 are schematic diagrams of the doming test results for high doming glass.
Fig. 5 is a schematic representation of the folds created by a high camber glass.
Fig. 6 is a schematic structural diagram of a light modulation film provided in embodiment 1.
Fig. 7 is a schematic structural diagram of a light modulation film provided in embodiment 2.
Fig. 8 is a schematic structural diagram of a light modulation film provided in embodiment 1.
Fig. 9 is a schematic structural diagram of a light modulation film provided in embodiment 2.
Fig. 10 is a schematic structural diagram of a light modulation film provided in embodiment 3.
Reference numerals illustrate:
dimming film 1 first base film 2 second base film 3 first electrode 4 second electrode 5,51 color changing film 6 first reinforcing layer 7 second reinforcing layer 8
Detailed Description
The technical solution of the present invention will be described in detail below for a clearer understanding of technical features, objects and advantageous effects of the present invention, but should not be construed as limiting the scope of the present invention.
Comparative example 1
This comparative example 1 provides a light modulation film having a structure as shown in fig. 1. The light modulation film 1 includes: a first base film 2, a second base film 3, a first electrode 4, a second electrode 5, and a color-changing film 6; wherein:
the first base film 2 and the second base film 3 are PET films with ITO layers on the surfaces;
the color-changing film 6 is an EC film, a PDLC film, an SPD film or an LC film, located between the first base film 2 and the second base film 3;
the first electrode 4 is located at the edge of the side surface of the first base film 2 facing the second base film 3;
the second electrode 5 is located at an edge of a side surface of the second base film 3 facing the first base film 2.
Example 1
The present embodiment provides a light modulation film 1 whose structure is shown in fig. 6 and 8. The light modulation film 1 includes: a first base film 2, a second base film 3, a first electrode 4, a second electrode 51, and a color-changing film 6; wherein:
the first base film 2 and the second base film 3 are PET films with ITO layers on the surfaces, wherein the thickness of the PET films is below 0.4 mm; the first base film 2 and the second base film 3 do not completely overlap;
the color-changing film 6 is an EC film and is positioned between the first base film 2 and the second base film 3;
the first electrode 4 is positioned at the edge of the side surface of the second base film 3 facing the first base film 2 and is not overlapped with the first base film 2, and is a rectangular ring surrounding the periphery of the color-changing film 6; the first electrode 4 is copper foil or silver foil and is connected with the ITO layer through conductive silver adhesive;
the second electrode 51 is positioned on the surface of the first base film 2 facing the second base film 3 and close to the color-changing film 6, and is shaped as a rectangular ring; the second electrode 51 is copper foil or silver foil and is connected with the color-changing film 6 through conductive silver adhesive;
the distance between the first electrode 4 and the second electrode 51 is 5mm-300mm.
Example 2
The present embodiment provides a light modulation film 1 whose structure is shown in fig. 7 and 9. The light modulation film 1 includes: a first base film 2, a second base film 3, a first electrode 4, a second electrode 5, a color-changing film 6, a first reinforcing layer 7 and a second reinforcing layer 8; wherein:
the first base film 2 and the second base film 3 are PET films with ITO layers on surfaces with the thickness below 0.4mm, and the first base film 2 and the second base film 3 are in a mutually crossed position relation;
the color-changing film 6 is an EC film, a PDLC film, an SPD film or an LC film, located between the first base film 2 and the second base film 3;
the first electrode 4 is located at a partial region of the edge of the side surface of the second base film 3 facing the first base film 2 and not overlapping the first base film 2; the first electrode 4 is connected with the ITO layer through conductive silver paste;
the second electrode 5 is located at a partial region of the edge of the side surface of the first base film 2 facing the second base film 3 and not overlapping the second base film 3; the second electrode 5 is connected with the ITO layer through conductive silver paste;
the first reinforcement layer 7 is positioned at the edge of the side surface of the second base film 3 facing away from the first base film 2 and corresponds to the first electrode 4, and is a rectangular ring surrounding the color-changing film 6;
the second reinforcing layer 8 is positioned at the position, close to the color-changing film 6, of the surface of one side, facing away from the second base film 3, of the first base film 2, and is in the shape of a rectangular ring;
the widths of the first reinforcing layer 7 and the second reinforcing layer 8 are 3mm-20mm respectively, the material is metal or nonmetal with higher rigidity, and the reinforcing layers are formed by bonding glue.
Example 3
The present embodiment provides a light modulation film 1 whose structure is shown in fig. 10. The light modulation film 1 includes: a first base film 2, a second base film 3, a first electrode 4, a second electrode 51, a color-changing film 6, a first reinforcing layer 7, a second reinforcing layer 8; wherein:
the first base film 2 and the second base film 3 are PET films with ITO layers on the surfaces, wherein the thickness of the PET films is below 0.4 mm;
the color-changing film 6 is an EC film and is positioned between the first base film 2 and the second base film 3;
the first electrode 4 is positioned at the edge of the side surface of the second base film 3 facing the first base film 2, and is a rectangular ring surrounding the periphery of the color-changing film 6; the first electrode 4 is copper foil or silver foil and is connected with the ITO layer through conductive silver adhesive;
the second electrode 51 is positioned on the surface of the first base film 2 facing the second base film 3 and close to the color-changing film 6, and is shaped as a rectangular ring; the second electrode 51 is copper foil or silver foil and is connected with the ITO layer through conductive silver adhesive;
the distance between the first electrode 4 and the second electrode 51 is 5mm to 300mm;
the first reinforcement layer 7 is positioned at the edge of the side surface of the second base film 3 facing away from the first base film 2 and corresponds to the first electrode 4, and is a rectangular ring surrounding the periphery of the color-changing film 6;
the second reinforcing layer 8 is positioned on the surface of one side of the first base film 2 facing away from the second base film 3, close to the color-changing film 6 and corresponds to the position of the second electrode 51, and is in the shape of a rectangular ring;
the widths of the first reinforcing layer 7 and the second reinforcing layer 8 are 3mm-20mm respectively, the material is metal or nonmetal with higher rigidity, and the reinforcing layers are formed by bonding glue.
Example 4
The embodiment provides a large-camber adjustable light glass, which comprises a first glass plate, a second glass plate and a light adjusting film;
the light modulation film is provided between the first glass plate and the second glass plate, and is the light modulation film of embodiment 1 or 2 or 3.
The arch height of the large-arch adjustable light glass is more than 20 mm/M.
The high camber adjustable glass is prepared according to the following modes:
and (3) clamping the processed dimming film with a first glass plate and a second glass plate with large camber, wherein the printed edge of the glass exceeds the second electrode or the reinforcing layer by more than 5mm, so that the dimming glass with flat surface and no fold and large camber can be prepared.
After the completion of the preparation, no wrinkles were generated at all in the dimming visible region of the large camber dimmable glass of example 4, and no bubbles were generated even when the dimming film using the color-changing film as EC film, and there was no risk of glass cracking.
In the present invention, fig. 6 to 10 are schematic views for the structure of the light modulation film, and do not represent the dimensions (especially the ratio between the dimensions) and the relative positions of the respective parts in the actual light modulation film, which are to be completely consistent with the dimensions and the relative positions shown in the drawings.
The technical features of the above embodiments may be arbitrarily combined, and for brevity, all of the possible combinations of the technical features of the above embodiments are not described, however, as long as there is no contradiction between the combinations of the technical features, they should be considered as the scope of the description.
The above examples illustrate only a few embodiments of the invention, which are described in detail and are not to be construed as limiting the scope of the claims. It should be noted that it will be apparent to those skilled in the art that several variations and modifications can be made without departing from the spirit of the invention, which are all within the scope of the invention. Accordingly, the scope of protection of the present invention is to be determined by the appended claims.
Claims (18)
1. The dimming film is characterized by comprising two layers of base films, a color-changing film, two electrodes and at least one annular reinforcing layer; wherein:
the color-changing film is positioned between the two base films;
the annular reinforcing layer is arranged at the edge or an area within the edge of one layer of base film;
the dimming film is applied to the high-camber adjustable glass to reduce the occurrence of wrinkles of the high-camber adjustable glass.
2. The dimming film according to claim 1, wherein the dimming film comprises at least two annular reinforcing layers, and the reinforcing layers are respectively arranged on surfaces of the two base films facing away from each other; and at least one of the reinforcing layers is arranged at the edge of one base film, and at least one of the reinforcing layers is arranged in an area inside the edge of the other base film.
3. A dimming film as claimed in claim 1 or 2, wherein the distance between the two reinforcing layers is 5mm to 300mm.
4. A dimming film as claimed in claim 1 or 2, wherein the reinforcing layer has a width of 3mm to 20mm.
5. A dimming film as claimed in claim 1 or 2, wherein the thickness of the reinforcing layer is 0.01mm to 0.2mm.
6. A dimming film as claimed in claim 1 or 2, wherein the material of the reinforcing layer is a material having a rigidity greater than that of the base film.
7. The light control film according to claim 6, wherein the material of the reinforcing layer is one or a combination of two or more of copper, silver, steel, epoxy resin and acrylic resin.
8. A dimming film as claimed in claim 1, wherein the two electrodes are ring electrodes, respectively, and the two ring electrodes are provided on surfaces of the two base films facing each other, respectively.
9. The dimming film as claimed in claim 8, wherein at least a part of the two ring electrodes in positions of the respective base film surfaces are overlapped;
alternatively, two ring electrodes are positioned at the edges of the respective base films with a certain distance between them, the distance between them being 5mm-300mm.
10. A dimming film as claimed in claim 8 or 9, wherein two of the reinforcing layers correspond to positions of two of the ring electrodes, respectively.
11. The dimming film of claim 1, wherein the color-changing film is one or a combination of two or more of an EC film, a PDLC film, an SPD film and an LC film.
12. The high-camber adjustable light glass is characterized by comprising two layers of glass plates and a light adjusting film;
wherein the light modulation film is the light modulation film according to any one of claims 1 to 11; the arch height of the large-arch adjustable light glass is more than 20 mm/M.
13. The high camber tunable glass according to claim 12, wherein the rim of the high camber tunable glass covers more than 5mm of the reinforcing layer provided in the area inside the edge of the base film.
14. A method of reducing wrinkling in a visible area of a high camber adjustable glazing, the method comprising:
at least one annular reinforcing layer is respectively arranged on the surfaces of the two base films of the dimming film, which are opposite to each other, and at least one reinforcing layer is arranged at the edge of one base film and at least one reinforcing layer is arranged in the area inside the edge of the other base film.
15. The method of claim 14, wherein the two reinforcement layers are spaced from 5mm to 300mm.
16. The method of claim 14, further comprising:
the light modulation film is an EC film, the electrode of which is a ring electrode, and:
at least a portion of the two ring electrodes in the locations of the respective base film surfaces are overlapped;
or alternatively, the process may be performed,
two ring electrodes are located at the edges of the respective base films, and the distance between the two ring electrodes is 5mm to 300mm.
17. The method of any one of claims 14-16, wherein the selvedge of the high camber dimmable glass covers more than 5mm of the reinforcing layer provided in the area inside the edge of the base film during the sandwiching of the glue sheet.
18. Use of the high camber dimmable glass of claim 12 or 13 as a vehicle glass.
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CN202210168604.1A CN114545699B (en) | 2022-02-23 | 2022-02-23 | Light-adjusting film, light-adjusting glass with large camber and application of light-adjusting film and light-adjusting glass |
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CN202210168604.1A CN114545699B (en) | 2022-02-23 | 2022-02-23 | Light-adjusting film, light-adjusting glass with large camber and application of light-adjusting film and light-adjusting glass |
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