CN1145343A - Health, sterilizing and deodorizing film and ceramic and glass products - Google Patents

Health, sterilizing and deodorizing film and ceramic and glass products Download PDF

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Publication number
CN1145343A
CN1145343A CN 96106476 CN96106476A CN1145343A CN 1145343 A CN1145343 A CN 1145343A CN 96106476 CN96106476 CN 96106476 CN 96106476 A CN96106476 A CN 96106476A CN 1145343 A CN1145343 A CN 1145343A
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CN
China
Prior art keywords
film
pottery
glass
health
goods
Prior art date
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Pending
Application number
CN 96106476
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Chinese (zh)
Inventor
金宗哲
方锐
许霞
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China Building Materials Academy CBMA
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China Building Materials Academy CBMA
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Filing date
Publication date
Application filed by China Building Materials Academy CBMA filed Critical China Building Materials Academy CBMA
Priority to CN 96106476 priority Critical patent/CN1145343A/en
Publication of CN1145343A publication Critical patent/CN1145343A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/008Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • C04B41/5027Oxide ceramics in general; Specific oxide ceramics not covered by C04B41/5029 - C04B41/5051
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/51Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068Ingredients with a function or property not provided for elsewhere in C04B2103/00

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Catalysts (AREA)
  • Chemically Coating (AREA)

Abstract

An antibacterial, deodouring health-care film is made of optical catalyst, antibacterial metal elements, far infrared elements and their oxides. If coated by said film, ceramic or glass products have antibacterial, deodouring and health-care functions.

Description

Health care, antibiotic, deodorizing film and pottery thereof, glasswork
The present invention relates to a kind of health care of photocatalyst, antibacterial metal element and far infrared composition, antibiotic, deodorizing film of containing, and this film can be used for the plating building material made, particularly pottery, glasswork.
Now, people require day by day to improve to the living environment hygienic quality, and therefore, the environment optimization of public place, living space and medical facilities and purification are paid close attention to by people day by day.Therefore Japan utilizes titanium deoxide catalyst illumination mark sheet to reveal extremely strong oxidation susceptibility since 1994, has sterilization effect, is used as deodorizing, stain remover is useful for building material product.But it is further perfect that this class research is still needed.
The present invention seeks to further to optimize and purify living environment, develop have health care, antibiotic, deodorizing multifunctional composite film and plated film goods thereof.
Feature of the present invention is:
1. thin film composition and proportioning (solids content than):
Photocatalyst (TiO 2) 2 parts
0.2~1 part of antibacterial metal element (gold and silver, copper, zinc) and oxide compound thereof
0.5~2 part of far infrared composition (zirconium, cobalt, manganese and oxide compound thereof)
2. film solution preparation:
Adopting the alkoxide of habitual titanium is base-material, and preparation titanium colloidal sol (Tisol) with antibacterial metal element, far infrared element and oxide sol thereof, by deciding proportioning, adds in the colloidal sol successively, and the limit edged stirs, abundant stir about 1 hour, coated solution stand-by;
3. coating process
At first with pottery to be plated (glass) product surface clean, seasoning is stand-by; Coating process adopts one of spraying commonly used, dipping, spin coating method, gives and has cleaned dry pottery (glass) goods plating of crossing, back seasoning; Go at last in the firing furnace, in being higher than 400 ℃ of sintering temperatures, annealing cooling naturally, goods of the present invention.
Advantage of the present invention:
1. with the fourier transform infrared spectrophotometer thin-film material of the present invention is tested, the result shows that the far-infrared radiation rate of this thin-film material can promote microcirculation in human body greater than 80% in health care, favourable HUMAN HEALTH.
2. through the Beijing Biological Product Inst., Ministry of Public Health this thin-film material is carried out the anti-microbial property test, the result shows that this material all has anti-microbial effect (seeing Fig. 3~6 for details) to bacterial propagule (streptococcus aureus, intestinal bacteria, Pseudomonas aeruginosa), mould (Candida albicans).
3. with pottery (glass) the vessel splendid attire fresh flower of this film plating, still as before bright-coloured in the week, and really withered with the fresh flower of conventional ceramic (glass) vessel while splendid attire.
Description of drawings of the present invention:
Fig. 1: film preparation of the present invention and coating process schema
Fig. 2: the structural representation of health care, antibiotic, deodorizing film goods
Fig. 3: anti-streptococcus aureus Performance Detection table and curve
Among the figure: ABG--is health care, antibiotic, deodorizing glass
ABT--is health care, antibiotic, deodorizing ornamental brick
Data are the sterilizing rate of three empirical averages
Fig. 4: Chinese People's Anti-Japanese Military and Political College's enterobacteria Performance Detection table
Fig. 5: anti Bacillus pyocyaneu Flugge Performance Detection table
Fig. 6: anti-candida albicans (fungi) Performance Detection curve
The embodiment of the invention:
The alkoxide and 1: 3 the volume ratio of thanomin of titanium are made into titanium solution, in this solution 1000ml, add (the AgNo of total amount 30 grams 3, ZrO 2, ZnO colloidal sol, the limit edged stirs, fully stir after 1 hour, the glaze for glazed tile that has cleaned (or sheet glass) placed on the rotary plating machine be coated with film with rotational method, after treating its seasoning, go into stove and be higher than 400 ℃ of sintering temperatures, naturally cooling health care, antibiotic, deodorizing ornamental brick (or sheet glass).

Claims (1)

1. a health care, antibiotic, deodorizing film and pottery, glasswork is characterized in that:
1. thin film composition and proportioning (solids content than):
Photocatalyst (TiO 2) 2 parts
0.2~1 part of antibacterial metal element (gold and silver, copper, zinc) and oxide compound thereof
0.5~2 part of far infrared composition (zirconium, cobalt, manganese) and oxide compound thereof
2. film solution preparation:
Adopting the alkoxide of habitual titanium is base-material, and preparation titanium colloidal sol (Tisol) with antibacterial metal element, far infrared element and oxide sol thereof, by deciding proportioning, adds in the colloidal sol successively, and the limit edged stirs, abundant stir about 1 hour, coated solution stand-by;
3. coating process
At first with pottery to be plated (glass) product surface clean, seasoning is stand-by; Coating process adopts one of spraying commonly used, dipping, spin coating method, gives and has cleaned dry pottery (glass) goods plating of crossing, back seasoning; Go at last in the firing furnace, in being higher than 400 ℃ of sintering temperatures, annealing cooling naturally, goods of the present invention.
CN 96106476 1996-08-14 1996-08-14 Health, sterilizing and deodorizing film and ceramic and glass products Pending CN1145343A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 96106476 CN1145343A (en) 1996-08-14 1996-08-14 Health, sterilizing and deodorizing film and ceramic and glass products

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 96106476 CN1145343A (en) 1996-08-14 1996-08-14 Health, sterilizing and deodorizing film and ceramic and glass products

Publications (1)

Publication Number Publication Date
CN1145343A true CN1145343A (en) 1997-03-19

Family

ID=5119198

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 96106476 Pending CN1145343A (en) 1996-08-14 1996-08-14 Health, sterilizing and deodorizing film and ceramic and glass products

Country Status (1)

Country Link
CN (1) CN1145343A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1079383C (en) * 1999-03-24 2002-02-20 湖南港鹏实业有限公司 Bactericidal glaze and bactericidal ceramic
CN1304336C (en) * 2003-01-29 2007-03-14 河南大学 Technology for producing antibacterial photocatalyst ceramic
CN103447050A (en) * 2013-08-27 2013-12-18 句容亿格纳米材料厂 Nanometer composite titanium dioxide and applications thereof
CN104128101A (en) * 2014-07-18 2014-11-05 南京工业大学 Silver-doped metal ceramic composite membrane and preparation method thereof
CN104906946A (en) * 2015-04-29 2015-09-16 南京工业大学 Preparation method of catalytic membrane for gas purification
CN105272360A (en) * 2015-10-28 2016-01-27 雷志刚 Preparation method of gypsum-based board with anti-microbial and easy-cleaning functions

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1079383C (en) * 1999-03-24 2002-02-20 湖南港鹏实业有限公司 Bactericidal glaze and bactericidal ceramic
CN1304336C (en) * 2003-01-29 2007-03-14 河南大学 Technology for producing antibacterial photocatalyst ceramic
CN103447050A (en) * 2013-08-27 2013-12-18 句容亿格纳米材料厂 Nanometer composite titanium dioxide and applications thereof
CN103447050B (en) * 2013-08-27 2015-12-02 句容亿格纳米材料厂 A kind of Nanometer composite titanium dioxide and application thereof
CN104128101A (en) * 2014-07-18 2014-11-05 南京工业大学 Silver-doped metal ceramic composite membrane and preparation method thereof
CN104906946A (en) * 2015-04-29 2015-09-16 南京工业大学 Preparation method of catalytic membrane for gas purification
CN105272360A (en) * 2015-10-28 2016-01-27 雷志刚 Preparation method of gypsum-based board with anti-microbial and easy-cleaning functions

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