CN114525053A - Settling type paint and degumming agent and paint and degumming treatment process - Google Patents

Settling type paint and degumming agent and paint and degumming treatment process Download PDF

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Publication number
CN114525053A
CN114525053A CN202111678190.9A CN202111678190A CN114525053A CN 114525053 A CN114525053 A CN 114525053A CN 202111678190 A CN202111678190 A CN 202111678190A CN 114525053 A CN114525053 A CN 114525053A
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CN
China
Prior art keywords
paint
sedimentation type
degumming
type paint
agent
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202111678190.9A
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Chinese (zh)
Inventor
成天忠
熊豪
况金权
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Bo Luo Xian Domin Chemical Co ltd
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Bo Luo Xian Domin Chemical Co ltd
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Publication date
Application filed by Bo Luo Xian Domin Chemical Co ltd filed Critical Bo Luo Xian Domin Chemical Co ltd
Priority to CN202111678190.9A priority Critical patent/CN114525053A/en
Publication of CN114525053A publication Critical patent/CN114525053A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D9/00Chemical paint or ink removers
    • C09D9/005Chemical paint or ink removers containing organic solvents

Abstract

The invention belongs to the technical field of metal surface treatment, and discloses a sedimentation type paint and degumming agent and a paint and degumming treatment process, wherein the sedimentation type paint and degumming agent comprises the following components in percentage by volume: 15-25% of strong base, 5-15% of complexing agent, 3-8% of alkane solvent oil, 3-8% of environment-friendly solvent and the balance of water. The sedimentation type paint removing and degumming agent provided by the invention is non-soluble, and paint or powder spraying or glue spraying swelling on the surface of a workpiece is separated from the workpiece after the paint or powder spraying or glue spraying swelling is carried out through the synergistic effect of the components in the formula, and the separated paint slag and the like are directly separated by a physical method, so that the sedimentation type paint removing and degumming agent can be recycled for multiple times, the service life of the sedimentation type paint removing and degumming agent is prolonged, the using amount of the sedimentation type paint removing and degumming agent is reduced, the waste liquid is reduced, the environmental pollution is reduced, and the wastewater treatment cost is reduced.

Description

Settling type paint and degumming agent and paint and degumming treatment process
Technical Field
The invention relates to the technical field of metal surface treatment, in particular to a sedimentation type paint and degumming agent and a paint and degumming treatment process.
Background
The metal is widely applied to a plurality of fields such as automobiles, building materials, 3C electronic products, mobile phones and the like. More and more products pursue fashionable appearance, surface processing treatment is diversified, corrosion resistance is enhanced, spraying, powder spraying or paint spraying is one of necessary processes for obtaining good appearance and ensuring product yield, and when the products are poor in spraying, powder spraying or paint spraying, a paint removing and powder removing cleaning agent is produced.
The conventional paint strippers have the following main disadvantages: (1) the halogenated hydrocarbon is mainly used as a solvent, so that the environmental pollution is great, the ozone layer is damaged, and with the increasing importance of the country on the environmental protection, the halogenated hydrocarbon is used as the main solvent, so that the sewage treatment pressure of enterprises is increased, and the sewage treatment cost is increased; (2) the traditional paint remover mainly adopts a dissolving mode to remove the sprayed powder or the painted paint on the metal surface, thereby causing the short service life of the paint remover and undoubtedly further increasing the environmental pollution and the production cost.
Based on the problems of the prior art, the development of an environment-friendly paint remover with long service life is needed by the research and development personnel in the field.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention aims to provide a sedimentation type paint removing and degumming agent, which can strip the paint or powder spraying on the metal surface in a non-dissolving manner, so that the paint removing agent can be recycled, the service life of the paint removing agent is prolonged, and the environmental pollution and the enterprise cost are reduced.
Another object of the present invention is to provide a method for paint removal using the above-mentioned paint-removing and paint-removing agent
In order to achieve the purpose, the invention adopts the following technical scheme:
a sedimentation type paint and glue removing agent comprises the following components in percentage by volume: 18-22% of strong base, 5-15% of complexing agent, 3-8% of alkane solvent oil, 3-8% of environment-friendly solvent and the balance of water.
Further, the sedimentation type paint and glue removing agent comprises the following components in percentage by volume: 20% of strong base, 10% of complexing agent, 5% of alkane solvent oil, 5% of environment-friendly solvent and the balance of water.
Further, the strong base is at least one of sodium hydroxide, potassium hydroxide and the like.
Further, the complexing agent is at least one of triethanolamine, monoethanolamine, diethanolamine, and the like.
Further, the initial boiling point of the alkane solvent oil is more than 200 ℃, and the density of the alkane solvent oil is less than 0.85g/cm3
The alkane solvent oil is at least one of D80 solvent oil, D90 solvent oil and the like.
Further, the environment-friendly solvent is at least one of ethylene glycol monobutyl ether, ethylene glycol dibutyl ether and the like.
Further, the volume ratio of the alkane solvent oil to the environment-friendly solvent is 1: 1.
The invention also provides a paint-removing and degumming treatment process adopting the sedimentation type paint-removing and degumming agent,
the paint removal and degumming treatment process comprises the following steps: and (3) immersing the workpiece needing degumming and depainting into the sedimentation type depainting and depainting agent, and soaking for 5-30 min at 75-85 ℃.
Compared with the prior art, the invention has the following advantages:
(1) the invention provides a sedimentation type paint and gel removing agent, which comprises the following components in percentage by volume: 15-25% of strong base, 5-15% of complexing agent, 3-8% of alkane solvent oil, 3-8% of environment-friendly solvent and the balance of water. The sedimentation type paint removing and degumming agent provided by the invention is non-soluble, and paint or powder spraying or glue spraying swelling on the surface of a workpiece is separated from the workpiece after the paint or powder spraying or glue spraying swelling is carried out through the synergistic effect of the components in the formula, and the separated paint slag and the like are directly separated by a physical method, so that the sedimentation type paint removing and degumming agent can be recycled for multiple times, the service life of the sedimentation type paint removing and degumming agent is prolonged, the using amount of the sedimentation type paint removing and degumming agent is reduced, the waste liquid is reduced, the environmental pollution is reduced, and the wastewater treatment cost is reduced.
(2) The paint-removing and degumming treatment process provided by the invention has the characteristics of simple operation, and the specific use method comprises the steps of heating the sedimentation type paint-removing and degumming agent, directly soaking the metal workpiece to be treated in the sedimentation type paint-removing and degumming agent, gradually swelling the paint or powder or glue on the surface of the metal workpiece to a certain extent, enabling the paint or powder or glue to fall off from the metal workpiece, then precipitating to the bottom of the container, fishing and filtering sediments at the bottom of the container by using a filter screen at regular time, collecting the sediments after draining, and uniformly treating the sediments as solid wastes, thereby saving the treatment cost.
Drawings
FIG. 1 is a diagram showing the effect of the sludge after the depainting and degumming treatment is performed on a sample workpiece in example 1 of the present invention;
FIG. 2 is a graph showing the effect of the treating fluid after the sample workpiece is subjected to paint-removing and degumming treatment according to comparative example 1 of the present invention.
Detailed Description
The present invention will be described in further detail below with reference to specific embodiments and examples in conjunction with the accompanying drawings, but the embodiments of the present invention are not limited thereto. All the raw materials and reagents used in the present invention are commercially available raw materials and reagents, unless otherwise specified. In the examples, the components are used in g and mL in parts by mass.
The D80 solvent and the D90 solvent oil adopted in the embodiment of the invention are purchased from China petrochemical metallocene petrochemical company.
In the embodiment and the proportion of the invention, the hanger is adopted as a sample to carry out paint removal and degumming treatment, wherein the hanger is usually made of 316 type stainless steel, has high hardness, corrosion resistance and tensile lifting force, is not easy to bend and has high bearing capacity, then a product to be sprayed is hung on the hanger to carry out paint spraying or powder spraying on the product, and then the product is baked and shaped, the hanger can be sprayed on the product inevitably in the spraying process, and a thick layer of sprayed powder or paint is formed on the hanger in the past.
Example 1
The sedimentation type paint and glue removing agent comprises the following components in percentage by volume: 20% of sodium hydroxide, 10% of triethanolamine, 5% of D80 solvent oil, 5% of ethylene glycol monobutyl ether and the balance of water.
Paint removal and degumming treatment: heating the sedimentation type paint and glue removing agent to 80 ℃, then putting the hanger into the tank, soaking for 20min, taking out the workpiece, cleaning the workpiece with clear water, and drying.
Example 2
The sedimentation type paint and glue removing agent comprises the following components in percentage by volume: 22% of sodium hydroxide, 15% of triethanolamine, 3% of D80 solvent oil, 3% of ethylene glycol monobutyl ether and the balance of water.
Depainting and degumming treatment: heating the sedimentation type paint and glue removing agent to 85 ℃, then putting the hanger into the rack, soaking for 20min, taking out the workpiece, cleaning the workpiece with clear water, and drying.
Example 3
The sedimentation type paint and glue removing agent comprises the following components in percentage by volume: 18% of sodium hydroxide, 5% of triethanolamine, 8% of D80 solvent oil, 8% of ethylene glycol monobutyl ether and the balance of water.
Depainting and degumming treatment: heating the sedimentation type paint and glue removing agent to 80 ℃, then putting the hanger into the tank, soaking for 30min, taking out the workpiece, cleaning the workpiece with clear water, and drying.
Example 4
The sedimentation type paint and glue removing agent comprises the following components in percentage by volume: 20% of potassium hydroxide, 10% of diethanolamine, 5% of D90 solvent oil, 5% of ethylene glycol monobutyl ether and the balance of water.
Depainting and degumming treatment: heating the sedimentation type paint and glue removing agent to 80 ℃, then putting the hanger into the tank, soaking for 20min, taking out the workpiece, cleaning the workpiece with clear water, and drying.
Comparative example 1
The traditional paint remover is adopted and comprises the following components in percentage by volume: 20% of sodium hydroxide, 10% of water for preventing white water, 10% of triethanolamine and the balance of water.
Depainting and degumming treatment: heating the traditional paint remover to 80 ℃, then putting the hanger in the traditional paint remover, soaking for 20min, taking out the workpiece, cleaning the workpiece with clear water, and drying.
Comparative example 2
The composite material comprises the following components in percentage by volume: 25% of sodium hydroxide, 10% of triethanolamine, 5% of D40 solvent oil, 5% of ethylene glycol monobutyl ether and the balance of water.
Depainting and degumming treatment: heating the sedimentation type paint and glue removing agent to 80 ℃, then putting the hanger into the rack, soaking for 20min, taking out the workpiece, cleaning the workpiece with clear water, and drying.
Comparative example 3
The composite material comprises the following components in percentage by volume: 20% of sodium hydroxide, 10% of triethanolamine, 5% of benzyl alcohol, 5% of sodium dodecyl benzene sulfonate and the balance of water.
Depainting and degumming treatment: heating the sedimentation type paint and glue removing agent to 80 ℃, then putting the hanger into the tank, soaking for 20min, taking out the workpiece, cleaning the workpiece with clear water, and drying.
The results of the depainting and degumming agents after the depainting and degumming treatments of examples 1 to 4 and comparative examples 1 to 3 were evaluated, and are specifically shown in table 1.
TABLE 1 results of depainting and degumming treatments of different examples and comparative examples
Item Temperature of treatment Paint removal effect Whether or not to precipitate State of paint stripper
Example 1 80℃ Complete removal of Is that Clear and transparent
Example 2 80℃ Complete removal of Is that Clear and transparent
Example 3 75℃ Complete removal of Is that Clear and transparent
Example 4 80℃ Slightly remains Is that Clear and transparent
Comparative example 1 80℃ Complete removal of Whether or not Complete turbidity
Comparative example 2 80℃ Complete removal of Is that Slightly cloudy
Comparative example 3 80℃ A little residue The amount of precipitate is less Complete turbidity
As can be seen from the data in Table 1, the paint removing and degumming agent of the embodiment of the invention can keep clear solution after processing samples, and can remove the spray paint on the surface of a hanger in a precipitation manner, as shown in the state of the solution after processing the hanger in the embodiment 1 in FIG. 1, the sediment is precipitated at the bottom of a container, and the solution still keeps clear and transparent; comparative example 1 is a conventional paint remover which is completely a soluble paint remover and can finally remove the painted paint on the surface of the hanger tightly, but the solution is completely turbid after the removal, as shown in fig. 2; comparative example 2 using D40 mineral spirits and a higher level of strong base, whilst also being able to remove the paint from the surface of the hanger, the final solution was slightly cloudy indicating that part of the paint still dissolved in the paint stripper; the comparison result shows that the paint remover in the comparison example 3 can partially dissolve paint residues to ensure that a solvent is turbid when the hanger is removed, and the sedimentation type paint remover provided by the invention can remove the paint on the surface of the hanger in a non-dissolving manner under the synergistic action of specific components and specific dosage proportion, so that the sediments can be directly filtered, and the effect of the paint remover is not greatly influenced, so that the service life of the sedimentation type paint remover can be prolonged, the generation of waste liquid is reduced, and the environmental pollution and the waste liquid treatment cost are reduced.
The above embodiments are the best mode for carrying out the present invention, but the embodiments of the present invention are not limited to the above embodiments, and any other changes, modifications, substitutions, combinations, and simplifications which do not depart from the spirit and principle of the present invention should be regarded as equivalent substitutions and are included in the scope of the present invention.

Claims (10)

1. A sedimentation type paint and glue removing agent is characterized by comprising the following components in percentage by volume: 18-22% of strong base, 5-15% of complexing agent, 3-8% of alkane solvent oil, 3-8% of environment-friendly solvent and the balance of water.
2. A sedimentation type paint stripper as claimed in claim 1, characterized by comprising, in volume percent: 20% of strong base, 10% of complexing agent, 5% of alkane solvent oil, 5% of environment-friendly solvent and the balance of water.
3. A sedimentation type paint stripper as defined in claim 1, characterized in that: the strong base is at least one of sodium hydroxide and potassium hydroxide.
4. A sedimentation type paint stripper as defined in claim 1, characterized in that: the complexing agent is at least one of triethanolamine, monoethanolamine and diethanolamine.
5. A sedimentation type paint stripper as defined in claim 1, characterized in that: the initial boiling point of the alkane solvent oil is more than 200 ℃, and the density of the alkane solvent oil is less than 0.85g/cm3
6. A sedimentation type paint stripper as defined in claim 5, characterized in that: the alkane solvent oil is at least one of D80 solvent oil and D90 solvent oil.
7. A sedimentation type paint stripper as defined in claim 6, characterized in that: the environment-friendly solvent is at least one of ethylene glycol monobutyl ether and ethylene glycol dibutyl ether.
8. A sedimentation type paint stripper as defined in claim 7, characterized in that: the volume ratio of the alkane solvent oil to the environment-friendly solvent is 1: 1.
9. A paint-removing and degumming treatment process is characterized in that: use of a sedimentation type paint stripper as claimed in any one of claims 1 to 8.
10. The paint stripping and degumming process according to claim 9, comprising the following steps: and (3) immersing the workpiece needing degumming and depainting into the sedimentation type depainting and depainting agent, and soaking for 5-30 min at 75-85 ℃.
CN202111678190.9A 2021-12-31 2021-12-31 Settling type paint and degumming agent and paint and degumming treatment process Pending CN114525053A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202111678190.9A CN114525053A (en) 2021-12-31 2021-12-31 Settling type paint and degumming agent and paint and degumming treatment process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111678190.9A CN114525053A (en) 2021-12-31 2021-12-31 Settling type paint and degumming agent and paint and degumming treatment process

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CN114525053A true CN114525053A (en) 2022-05-24

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101139474A (en) * 2007-10-18 2008-03-12 珠海顺泽电子实业有限公司 Printed circuit board green paint scavenging agent and method for producing the same
CN101921502A (en) * 2009-06-11 2010-12-22 宝山钢铁股份有限公司 Paint remover for removing cathodic electrophoretic paint film on surface of steel plate
CN102634247A (en) * 2011-02-15 2012-08-15 关西涂料株式会社 Method of stripping coated film
CN103937322A (en) * 2014-04-23 2014-07-23 中国人民解放军第五七一九工厂 Anhydrous paint remover composition
CN110218477A (en) * 2019-06-13 2019-09-10 肇庆市哈力化工有限公司 A kind of ultraviolet-curing paint paint stripper of metal universal and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101139474A (en) * 2007-10-18 2008-03-12 珠海顺泽电子实业有限公司 Printed circuit board green paint scavenging agent and method for producing the same
CN101921502A (en) * 2009-06-11 2010-12-22 宝山钢铁股份有限公司 Paint remover for removing cathodic electrophoretic paint film on surface of steel plate
CN102634247A (en) * 2011-02-15 2012-08-15 关西涂料株式会社 Method of stripping coated film
CN103937322A (en) * 2014-04-23 2014-07-23 中国人民解放军第五七一九工厂 Anhydrous paint remover composition
CN110218477A (en) * 2019-06-13 2019-09-10 肇庆市哈力化工有限公司 A kind of ultraviolet-curing paint paint stripper of metal universal and preparation method thereof

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Application publication date: 20220524