CN114524902A - Insect-attracting board adhesive emulsion and preparation method thereof - Google Patents
Insect-attracting board adhesive emulsion and preparation method thereof Download PDFInfo
- Publication number
- CN114524902A CN114524902A CN202210164956.XA CN202210164956A CN114524902A CN 114524902 A CN114524902 A CN 114524902A CN 202210164956 A CN202210164956 A CN 202210164956A CN 114524902 A CN114524902 A CN 114524902A
- Authority
- CN
- China
- Prior art keywords
- parts
- aqueous adhesive
- insect
- adhesive emulsion
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 53
- 239000000853 adhesive Substances 0.000 title claims abstract description 52
- 239000000839 emulsion Substances 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 238000004945 emulsification Methods 0.000 title description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 26
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000000178 monomer Substances 0.000 claims abstract description 19
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 18
- 238000010438 heat treatment Methods 0.000 claims abstract description 17
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 15
- 239000000126 substance Substances 0.000 claims abstract description 13
- 150000003254 radicals Chemical class 0.000 claims abstract description 11
- 238000007720 emulsion polymerization reaction Methods 0.000 claims abstract description 10
- 238000001914 filtration Methods 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 9
- 238000004132 cross linking Methods 0.000 claims abstract description 7
- 239000003999 initiator Substances 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 18
- 239000011734 sodium Substances 0.000 claims description 18
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 14
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 12
- 241000238631 Hexapoda Species 0.000 claims description 12
- -1 acrylic ester Chemical class 0.000 claims description 12
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 8
- 235000019437 butane-1,3-diol Nutrition 0.000 claims description 7
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 6
- LRMHFDNWKCSEQU-UHFFFAOYSA-N ethoxyethane;phenol Chemical compound CCOCC.OC1=CC=CC=C1 LRMHFDNWKCSEQU-UHFFFAOYSA-N 0.000 claims description 6
- 239000001530 fumaric acid Substances 0.000 claims description 6
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 6
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 5
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical compound CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 claims description 5
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 4
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 3
- XOJWAAUYNWGQAU-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCOC(=O)C(C)=C XOJWAAUYNWGQAU-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 3
- ULQMPOIOSDXIGC-UHFFFAOYSA-N [2,2-dimethyl-3-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(C)(C)COC(=O)C(C)=C ULQMPOIOSDXIGC-UHFFFAOYSA-N 0.000 claims description 3
- 229940077388 benzenesulfonate Drugs 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 3
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 239000011976 maleic acid Substances 0.000 claims description 3
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 3
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 claims description 3
- XFTALRAZSCGSKN-UHFFFAOYSA-M sodium;4-ethenylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=C(C=C)C=C1 XFTALRAZSCGSKN-UHFFFAOYSA-M 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 239000012874 anionic emulsifier Substances 0.000 claims description 2
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- UBTITNUVKXQFBF-UHFFFAOYSA-N ethanesulfonic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.CCS(O)(=O)=O UBTITNUVKXQFBF-UHFFFAOYSA-N 0.000 claims description 2
- VZTFVVBTGBLXTR-UHFFFAOYSA-M sodium;2-(prop-2-enoylamino)propane-2-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)C(C)(C)NC(=O)C=C VZTFVVBTGBLXTR-UHFFFAOYSA-M 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 150000008052 alkyl sulfonates Chemical class 0.000 claims 1
- 150000004679 hydroxides Chemical class 0.000 claims 1
- TYLSDQJYPYQCRK-UHFFFAOYSA-N sulfo 4-amino-4-oxobutanoate Chemical compound NC(=O)CCC(=O)OS(O)(=O)=O TYLSDQJYPYQCRK-UHFFFAOYSA-N 0.000 claims 1
- 241000607479 Yersinia pestis Species 0.000 abstract description 2
- 230000008569 process Effects 0.000 abstract description 2
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 230000002087 whitening effect Effects 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- NKEQIYNYTHZJRN-UHFFFAOYSA-N CCCCCCCCCCCCC(C=CC=C1)=C1O.N Chemical compound CCCCCCCCCCCCC(C=CC=C1)=C1O.N NKEQIYNYTHZJRN-UHFFFAOYSA-N 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 239000012943 hotmelt Substances 0.000 description 3
- 241000255925 Diptera Species 0.000 description 2
- 241000256626 Pterygota <winged insects> Species 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- ZNEMGFATAVGQSF-UHFFFAOYSA-N 1-(2-amino-6,7-dihydro-4H-[1,3]thiazolo[4,5-c]pyridin-5-yl)-2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]ethanone Chemical compound NC=1SC2=C(CN(CC2)C(CC=2OC(=NN=2)C=2C=NC(=NC=2)NC2CC3=CC=CC=C3C2)=O)N=1 ZNEMGFATAVGQSF-UHFFFAOYSA-N 0.000 description 1
- UBESITQVAPQMMN-UHFFFAOYSA-N 2-dodecylphenol;sodium Chemical compound [Na].CCCCCCCCCCCCC1=CC=CC=C1O UBESITQVAPQMMN-UHFFFAOYSA-N 0.000 description 1
- 241001124076 Aphididae Species 0.000 description 1
- 241000255967 Helicoverpa zea Species 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical group 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000009193 crawling Effects 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- FBKBIOOBMXQNBA-UHFFFAOYSA-N propane-2-sulfonic acid;prop-2-enamide Chemical compound NC(=O)C=C.CC(C)S(O)(=O)=O FBKBIOOBMXQNBA-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- ZIWRUEGECALFST-UHFFFAOYSA-M sodium 4-(4-dodecoxysulfonylphenoxy)benzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCOS(=O)(=O)c1ccc(Oc2ccc(cc2)S([O-])(=O)=O)cc1 ZIWRUEGECALFST-UHFFFAOYSA-M 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1803—C3-(meth)acrylate, e.g. (iso)propyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1805—C5-(meth)acrylate, e.g. pentyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1806—C6-(meth)acrylate, e.g. (cyclo)hexyl (meth)acrylate or phenyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/062—Copolymers with monomers not covered by C09J133/06
- C09J133/064—Copolymers with monomers not covered by C09J133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polymerisation Methods In General (AREA)
Abstract
The invention belongs to the technical field of emulsion polymerization, and relates to a pest trapping plate adhesive emulsion and a preparation method thereof, wherein the preparation method comprises the following steps: after a polymerization kettle is vacuumized, carrying out free radical emulsion polymerization on an aqueous solution of a mixture of butadiene, an acrylate monomer, styrene, a carboxylic acid monomer, a crosslinking monomer, an emulsifier and an initiator, reacting at 70-90 ℃ for 3-6 hours, heating to 80-90 ℃, keeping the temperature for 2 hours, adjusting the pH of a reaction product to be 6-9 by using an alkaline substance, and filtering to obtain an aqueous adhesive emulsion; is applied to plastic base materials such as PET, PVC, OPP and the like. The adhesive for the insect-attracting board provided by the invention is aqueous and environment-friendly, the process is simple, and the initial adhesion, the permanent adhesion, the weather resistance and the water resistance of the prepared adhesive for the insect-attracting board are good.
Description
Technical Field
The invention relates to the field of adhesives, in particular to a water-based adhesive product, and specifically relates to a pest trapping plate adhesive emulsion and a preparation method thereof.
Background
The acrylate emulsion adhesive is widely applied at present, such as electronic products, paper-plastic coated films, fabric bonding, pressure-sensitive adhesives and the like, and has the advantages of environmental protection, no pollution, no organic solvent, easily obtained raw materials and important position in the adhesive market. At present, hot-melt insect viscose glue is available on the market, but the price is higher, and the heat resistance of the hot-melt glue is not good, so the application range of the hot-melt glue is restricted; the acrylate emulsion copolymer has good heat resistance and high initial viscosity, but the permanent viscosity is not ideal. In the application process, the pesticide is applied to small winged insects such as: adhesion by mosquitoes, aphids, whiteflies, etc. may also be possible, but may break loose facing some crawling insects with larger size.
In order to solve the problems, the invention introduces part of butadiene soft monomer and part of styrene hard monomer into the acrylate emulsion, the butadiene monomer can make the emulsion adhesive force stronger, and the introduction of the styrene monomer can improve the permanent adhesive force of the emulsion. The whole emulsion has rigidity, elasticity and viscoelasticity under the condition of excellent caking property. Not only can stick small winged insects, but also has good effect on some insects with larger body size such as flies and cotton bollworms.
Disclosure of Invention
The invention aims to provide an adhesive emulsion for an insect-attracting board and a preparation method thereof, which have good initial adhesion, permanent adhesion, water resistance and weather resistance and solve the technical problems.
In order to achieve the purpose, the invention adopts the following technical scheme:
the water-based adhesive comprises the following components in parts by weight:
96-114 parts of deionized water; 0.8-2.5 parts of emulsifier A; 0.5-1.5 parts of emulsifier B; 0.8-3 parts of an initiator; 15-25 parts of butadiene; 40-60 parts of acrylic ester; 10-20 parts of styrene; 3-10 parts of carboxylic acid monomer; 2-5 parts of a crosslinking monomer; 3-8 parts of alkaline substances;
the preparation method of the aqueous adhesive emulsion comprises the following steps:
vacuumizing a polymerization kettle, adding deionized water, an emulsifier A, an emulsifier B and an initiator, heating to 70-90 ℃, dropwise adding a mixture solution of butadiene, acrylate, styrene, a carboxylic acid monomer and a crosslinking monomer, carrying out free radical emulsion polymerization, reacting for 3-6 hours, heating to 80-90 ℃, keeping the temperature for 2 hours, cooling, adjusting the pH to 6-9 by using an alkaline substance, and filtering to obtain the aqueous adhesive for the insect-attracting plate.
Preferably, the emulsifier A is an anionic emulsifier, preferably at least one of alkyl sodium sulfate, alkyl sodium sulfonate, sodium alkyl benzene sulfonate, alkyl diphenyl ether disulfonate, alkyl phenol ether ammonium sulfate and alkyl phenol ether sulfosuccinate sodium salt. The alkyl group is preferably C8-C18, more preferably C8-C16, most preferably at least one of C8-C14 sodium alkyl sulfate, C8-C14 sodium alkyl sulfonate, C8-C14 sodium alkyl benzene sulfonate, C8-C14 sodium alkyl diphenyl ether disulfonate, C8-C14 ammonium alkyl phenol ether sulfate, and C8-C14 sodium alkyl phenol ether sulfosuccinate. As a further preferable scheme, the emulsifier A selected by the invention is dodecyl series.
Preferably, the emulsifier B is a reactive emulsifier, preferably at least one of sodium p-styrene sulfonate, 2-acrylamide-2, 2-dimethylethanesulfonic acid sodium salt, sodium alkyl sulfosuccinate, sodium acrylamidoisopropyl sulfonate and sodium alkyl acrylate-2-ethanesulfonic acid salt. The alkyl in the sodium salt of 2-ethanesulfonic acid-alkylacrylate is preferably C10-C18 alkyl, more preferably C12-C18 sodium salt of 2-ethanesulfonic acid-alkylacrylate. As a further preferable scheme, the sodium salt of the alkyl acrylic acid-2-ethanesulfonic acid in the emulsifier B is a hexadecyl series.
Preferably, the initiator is selected from at least one of sodium persulfate, ammonium persulfate and potassium persulfate;
preferably, the acrylate monomer is at least one selected from the group consisting of n-propyl acrylate, n-butyl acrylate, n-hexyl acrylate, and n-pentyl acrylate.
Preferably, the carboxylic acid monomer is selected from at least one of acrylic acid, methacrylic acid, maleic acid, fumaric acid, or itaconic acid.
Preferably, the crosslinking monomer is at least one selected from 1, 3-butanediol dimethyl acrylate, 1, 4-butanediol dimethacrylate, 1, 6-ethylene glycol dimethacrylate and neopentyl glycol dimethacrylate, and the alkaline substance is selected from alkali metal hydroxide.
Preferably, the reaction temperature of the free radical emulsion copolymerization is 70 ℃ to 90 ℃.
In another aspect, the present invention provides an aqueous adhesive emulsion for an insect-attracting board prepared by the above-mentioned preparation method.
The invention has the following beneficial effects:
the inventor finds that the butadiene monomer with lower glass transition temperature is used in the invention, so that the emulsion has better adhesive property, and the cross-linking agent is used to make the emulsion have a denser network structure, so that the water resistance and the weather resistance of the emulsion can be improved. On the other hand, the matching of the emulsifier ensures that the emulsion has no APEO and is more environment-friendly.
Detailed Description
The invention is illustrated below by means of specific examples, without being restricted thereto.
Example 1
The preparation of the aqueous adhesive emulsion comprises the following components in parts by weight:
the aqueous adhesive emulsion comprises the following components in parts by weight:
the preparation method of the water-based adhesive comprises the following steps:
vacuumizing a polymerization kettle, adding deionized water, sodium dodecyl diphenyl ether disulfonate, 2-acrylamide-2, 2-dimethyl ethyl sulfonate and sodium persulfate, starting stirring, heating to 70 ℃, dropwise adding a mixture solution of butadiene, n-propyl acrylate, styrene, acrylic acid and 1, 3-butanediol dimethyl acrylate to carry out free radical emulsion polymerization, wherein the dropwise adding time is 3 hours, heating to 80 ℃, keeping the temperature for 2 hours, cooling, adjusting the pH value to 6-9 by using a sodium hydroxide alkaline substance, and filtering to obtain the aqueous adhesive emulsion for the insect-attracting plate.
Example 2
The preparation of the aqueous adhesive emulsion comprises the following components in parts by weight:
the aqueous adhesive emulsion comprises the following components in parts by weight:
the preparation method of the water-based adhesive comprises the following steps:
and (2) vacuumizing a polymerization kettle, adding deionized water, sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, sodium p-styrene sulfonate, acrylamide isopropyl sulfonate and ammonium persulfate, stirring, heating to 90 ℃, dropwise adding a mixture solution of butadiene, n-butyl acrylate, styrene, maleic acid, itaconic acid, 1, 4-butanediol dimethacrylate and 1, 6-ethylene glycol dimethacrylate to perform free radical emulsion polymerization, heating to 90 ℃ for 2 hours, cooling, adjusting the pH to 6-9 by using a potassium hydroxide alkaline substance, and filtering to obtain the aqueous adhesive emulsion for the insect-attracting plate.
Example 3
The preparation of the aqueous adhesive emulsion comprises the following components in parts by weight:
the aqueous adhesive emulsion comprises the following components in parts by weight:
the preparation method of the water-based adhesive comprises the following steps:
and (2) vacuumizing a polymerization kettle, adding deionized water, sodium dodecyl sulfate, sodium dodecyl phenol ether sulfosuccinate, sodium allyl sulfosuccinate alkyl ester sulfonate, sodium hexadecyl acrylic acid-2-ethyl sulfonate and potassium persulfate, starting stirring, heating to 80 ℃, dropwise adding a mixture solution of butadiene, n-hexyl acrylate, styrene, methacrylic acid, fumaric acid, 1, 3-butanediol dimethyl acrylate and neopentyl glycol dimethacrylate, carrying out free radical emulsion polymerization, wherein the dropwise adding time is 4.5 hours, heating to 85 ℃, keeping the temperature for 2 hours, cooling, adjusting the pH to 6-9 by using a sodium hydroxide alkaline substance, and filtering to obtain the aqueous adhesive emulsion for the insect-attracting plate.
Example 4
The preparation of the aqueous adhesive emulsion comprises the following components in parts by weight:
the aqueous adhesive emulsion comprises the following components in parts by weight:
the preparation method of the aqueous adhesive emulsion comprises the following steps:
and (2) after the polymerization kettle is vacuumized, adding deionized water, sodium dodecyl sulfate, ammonium dodecyl phenol ether sulfate, sodium p-styrene sulfonate, ammonium persulfate and sodium persulfate, starting stirring, heating to 85 ℃, dropwise adding a mixture solution of butadiene, n-butyl acrylate, n-amyl acrylate, styrene, fumaric acid, acrylic acid and 1, 3-butanediol dimethyl acrylate to perform free radical emulsion polymerization, wherein the dropwise adding time is 5 hours, heating to 90 ℃, keeping the temperature for 2 hours, cooling, adjusting the pH to 6-9 by using a potassium hydroxide alkaline substance, and filtering to obtain the aqueous adhesive emulsion for the insect attracting plate.
Example 5
The preparation of the aqueous adhesive emulsion comprises the following components in parts by weight:
the aqueous adhesive emulsion comprises the following components in parts by weight:
the preparation method of the aqueous adhesive emulsion comprises the following steps:
and (2) after the polymerization kettle is vacuumized, adding deionized water, sodium dodecyl sulfate, ammonium dodecyl phenol ether sulfate, sodium p-styrene sulfonate, ammonium persulfate and sodium persulfate, starting stirring, heating to 85 ℃, dropwise adding a mixture solution of butadiene, n-butyl acrylate, n-amyl acrylate, styrene, fumaric acid, acrylic acid and 1, 3-butanediol dimethyl acrylate to perform free radical emulsion polymerization, wherein the dropwise adding time is 5 hours, heating to 90 ℃, keeping the temperature for 2 hours, cooling, adjusting the pH to 6-9 by using a potassium hydroxide alkaline substance, and filtering to obtain the aqueous adhesive emulsion for the insect attracting plate.
Example 6
The preparation of the aqueous adhesive emulsion comprises the following components in parts by weight:
the aqueous adhesive emulsion comprises the following components in parts by weight:
the preparation method of the aqueous adhesive emulsion comprises the following steps:
and (2) after the polymerization kettle is vacuumized, adding deionized water, sodium dodecyl sulfate, ammonium dodecyl phenol ether sulfate, sodium p-styrene sulfonate, ammonium persulfate and sodium persulfate, starting stirring, heating to 85 ℃, dropwise adding a mixture solution of butadiene, n-butyl acrylate, n-amyl acrylate, styrene, fumaric acid, acrylic acid and 1, 3-butanediol dimethyl acrylate to perform free radical emulsion polymerization, wherein the dropwise adding time is 5 hours, heating to 90 ℃, keeping the temperature for 2 hours, cooling, adjusting the pH to 6-9 by using a potassium hydroxide alkaline substance, and filtering to obtain the aqueous adhesive emulsion for the insect attracting plate.
The test method comprises the following steps:
examples 1-6 were tested for initial tack according to the method described in GB/T4852-2002.
The test results are shown in table 1:
TABLE 1
| Numbering | Initial adhesion | Water resistance (Room temperature soaking water) |
| Example 1 | 13 | No whitening after 8 hours, and no reduction of initial adhesion after drying |
| Example 2 | 12 | No whitening after 8 hours, and no reduction of initial adhesion after drying |
| Example 3 | 13 | No whitening after 8 hours, and no reduction of initial adhesion after drying |
| Example 4 | 13 | No whitening after 8 hours, and no reduction of initial adhesion after drying |
| Example 5 | 10 | No whitening after 8 hours, and no reduction of initial adhesion after drying |
| Example 6 | 11 | Slightly whitish in 8 hours, and the initial viscosity after drying is not reduced |
As is clear from the data in Table 1, examples 1 to 4 have better initial tack and water resistance than examples 5 to 6. The superiority of the invention is further proved.
The above is only a preferred embodiment of the present invention, and meets the use requirements of national standard GBT 24689.4-2009, and the above embodiment is not a limitation to the embodiment, and it will be apparent to those skilled in the art that other improvements and optimizations may be made without departing from the technical principle of the present invention, and the improvements and optimizations made thereby should be considered to be within the scope of the present invention.
The foregoing shows and describes the general principles, essential features, and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (9)
1. The aqueous adhesive emulsion for the insect-attracting board is characterized by comprising the following components in parts by weight: 96-114 parts of deionized water; 0.8-2.5 parts of emulsifier A; 0.5-1.5 parts of emulsifier B; 0.8-3 parts of an initiator; 15-25 parts of butadiene; 40-60 parts of acrylic ester; 10-20 parts of styrene; 3-10 parts of carboxylic acid monomer; 2-5 parts of a crosslinking monomer; 3-8 parts of alkaline substances.
2. The preparation method of the aqueous adhesive emulsion for the insect-attracting board as claimed in claim 1, which comprises the following steps:
step one, vacuumizing a polymerization kettle by using a vacuum pump and other devices for two to three times, so that the vacuum degree in the reaction kettle is continuously reduced and finally reaches less than or equal to-0.095 MPa;
step two, adding deionized water, an emulsifier A, an emulsifier B and an initiator, heating to 70-90 ℃, dropwise adding a mixture solution of butadiene, acrylate, styrene, carboxylic acid monomers and crosslinking monomers for free radical emulsion polymerization, wherein the dropwise adding time is 3-6 hours, heating to 80-90 ℃, and keeping the temperature for 2 hours;
and step three, adjusting the pH value to 6-9 by using an alkaline substance after cooling, and filtering to obtain the aqueous adhesive emulsion.
3. The aqueous adhesive emulsion for insect attracting boards as claimed in claim 1, wherein the emulsifier A is an anionic emulsifier, preferably at least one of sodium alkyl sulfate, sodium alkyl sulfonate, sodium alkyl benzene sulfonate, sodium alkyl diphenyl ether disulfonate, ammonium alkyl phenol ether sulfate, and sodium alkyl phenol ether sulfosuccinate.
4. The aqueous adhesive emulsion for insect attracting board of claim 1 wherein the emulsifier B is a reactive emulsifier, preferably at least one of sodium p-styrenesulfonate, sodium 2-acrylamide-2, 2-dimethylethanesulfonate, sodium alkyl sulfosuccinamate, sodium acrylamidoisopropyl sulfonate, and sodium alkyl acrylate-2-ethanesulfonate.
5. The aqueous adhesive emulsion for insect attracting boards as claimed in claim 1, wherein the initiator is at least one selected from the group consisting of sodium persulfate, ammonium persulfate, and potassium persulfate.
6. The aqueous adhesive emulsion for insect attracting boards as claimed in claim 1, wherein the acrylate monomer is at least one selected from the group consisting of n-propyl acrylate, n-butyl acrylate, n-hexyl acrylate and n-pentyl acrylate.
7. The aqueous adhesive emulsion for insect attracting boards as claimed in claim 1, wherein the carboxylic acid monomer is at least one selected from the group consisting of acrylic acid, methacrylic acid, maleic acid, fumaric acid and itaconic acid.
8. The aqueous adhesive emulsion for insect attracting plates as set forth in claim 1, wherein the crosslinking monomer is at least one selected from the group consisting of 1, 3-butanediol dimethyl acrylate, 1, 4-butanediol dimethacrylate, 1, 6-ethylene glycol dimethacrylate and neopentyl glycol dimethacrylate, and the alkaline substance is selected from the group consisting of hydroxides of alkali metals.
9. The method for preparing the aqueous adhesive emulsion for the insect-attracting board as claimed in claim 2, wherein the reaction temperature of the free radical emulsion copolymerization is 70 ℃ to 90 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210164956.XA CN114524902A (en) | 2022-02-23 | 2022-02-23 | Insect-attracting board adhesive emulsion and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210164956.XA CN114524902A (en) | 2022-02-23 | 2022-02-23 | Insect-attracting board adhesive emulsion and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114524902A true CN114524902A (en) | 2022-05-24 |
Family
ID=81624667
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210164956.XA Pending CN114524902A (en) | 2022-02-23 | 2022-02-23 | Insect-attracting board adhesive emulsion and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114524902A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115820167A (en) * | 2022-12-21 | 2023-03-21 | 上海昶法新材料有限公司 | Insect attracting plate AB adhesive and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002060713A (en) * | 2001-08-22 | 2002-02-26 | Nitto Denko Corp | Method for producing water-dispersed type acrylic pressure-sensitive adhesive |
| CN109180847A (en) * | 2018-08-21 | 2019-01-11 | 济宁明升新材料有限公司 | A kind of preparation method of Small-particle-size carboxylic styrene-butadiene latex |
| CN112760067A (en) * | 2021-01-19 | 2021-05-07 | 济宁明升新材料有限公司 | Preparation method of water-based adhesive for stretching and debonding adhesive tape and stretching and debonding adhesive tape |
-
2022
- 2022-02-23 CN CN202210164956.XA patent/CN114524902A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002060713A (en) * | 2001-08-22 | 2002-02-26 | Nitto Denko Corp | Method for producing water-dispersed type acrylic pressure-sensitive adhesive |
| CN109180847A (en) * | 2018-08-21 | 2019-01-11 | 济宁明升新材料有限公司 | A kind of preparation method of Small-particle-size carboxylic styrene-butadiene latex |
| CN112760067A (en) * | 2021-01-19 | 2021-05-07 | 济宁明升新材料有限公司 | Preparation method of water-based adhesive for stretching and debonding adhesive tape and stretching and debonding adhesive tape |
Non-Patent Citations (1)
| Title |
|---|
| 耿耀宗，曹同玉: "《合成聚合物乳液制造与应用技术》", 中国轻工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115820167A (en) * | 2022-12-21 | 2023-03-21 | 上海昶法新材料有限公司 | Insect attracting plate AB adhesive and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4912169A (en) | Adhesive compositions containing low molecular weight polymer additives | |
| EP0312228B1 (en) | Polymeric additives for use in adhesive compositions | |
| JP3431159B2 (en) | Polychloroprene blended composition | |
| CN113025243B (en) | Method for preparing acrylate composite adhesive by soap-free emulsion polymerization method | |
| JPH01234485A (en) | Water-based pressure-sensitive adhesive | |
| CN102140320A (en) | Water-based polyacrylic emulsion laminating adhesive and preparation method thereof | |
| CN104004477A (en) | Room temperature self-crosslinking polyacrylate pressure-sensitive adhesive and preparation method and application thereof | |
| CN114524902A (en) | Insect-attracting board adhesive emulsion and preparation method thereof | |
| CN104449485A (en) | Preparation method of emulsion type polyacrylate pressure-sensitive adhesive for reflecting film | |
| CN111032810B (en) | Aqueous acrylic pressure sensitive adhesive for clothing and method for preparing the same | |
| KR102600008B1 (en) | Aqueous acrylic adhesive for pet film and method for preparing the same | |
| CN108794682B (en) | Normal-temperature ketone hydrazine self-crosslinking acrylic resin emulsion and preparation method and application thereof | |
| CN101857786A (en) | Pressure-sensitive adhesive and preparation method thereof | |
| CN113831439A (en) | Carboxylated butyronitrile latex for papermaking and preparation method thereof | |
| JP2000503335A (en) | Pressure-sensitive adhesive and pressure-sensitive adhesive film using the adhesive | |
| JP2002080809A (en) | Aqueous emulsion pressure-sensitive adhesive | |
| CN115851059B (en) | Primer for epoxy structural adhesive and preparation method thereof | |
| CN114195946A (en) | Printed carpet adhesive and preparation method thereof | |
| CN111909624B (en) | Emulsion type insect attracting plate adhesive for PET (polyethylene terephthalate) base material and preparation method thereof | |
| KR20020083283A (en) | Removable type water-based pressure sensitive adhesive composition and preparation method thereof | |
| CN112760067A (en) | Preparation method of water-based adhesive for stretching and debonding adhesive tape and stretching and debonding adhesive tape | |
| JPH0539328A (en) | Production of synthetic resin emulsion | |
| KR102418592B1 (en) | Acrylic emulsion pressure snsitive adhesive composition | |
| CN115820167A (en) | Insect attracting plate AB adhesive and application thereof | |
| KR102625863B1 (en) | Acrylic emulsion pressure snsitive adhesive composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220524 |