CN114466645A - Liquid temporary hair dye composition - Google Patents
Liquid temporary hair dye composition Download PDFInfo
- Publication number
- CN114466645A CN114466645A CN202080068907.5A CN202080068907A CN114466645A CN 114466645 A CN114466645 A CN 114466645A CN 202080068907 A CN202080068907 A CN 202080068907A CN 114466645 A CN114466645 A CN 114466645A
- Authority
- CN
- China
- Prior art keywords
- component
- mass
- hair dye
- dye composition
- temporary hair
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000001027 temporary hair color Substances 0.000 title claims abstract description 74
- 239000007788 liquid Substances 0.000 title claims abstract description 73
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- HDFGOPSGAURCEO-UHFFFAOYSA-N N-ethylmaleimide Chemical compound CCN1C(=O)C=CC1=O HDFGOPSGAURCEO-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229910020442 SiO2—TiO2 Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 241000934878 Sterculia Species 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- UHHXUPJJDHEMGX-UHFFFAOYSA-K azanium;manganese(3+);phosphonato phosphate Chemical compound [NH4+].[Mn+3].[O-]P([O-])(=O)OP([O-])([O-])=O UHHXUPJJDHEMGX-UHFFFAOYSA-K 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000001058 brown pigment Substances 0.000 description 1
- CYHOWEBNQPOWEI-UHFFFAOYSA-L calcium 3-carboxy-1-phenyldiazenylnaphthalen-2-olate Chemical compound OC=1C(=CC2=CC=CC=C2C1N=NC1=CC=CC=C1)C(=O)[O-].OC=1C(=CC2=CC=CC=C2C1N=NC1=CC=CC=C1)C(=O)[O-].[Ca+2] CYHOWEBNQPOWEI-UHFFFAOYSA-L 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- VQWFNAGFNGABOH-UHFFFAOYSA-K chromium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Cr+3] VQWFNAGFNGABOH-UHFFFAOYSA-K 0.000 description 1
- 229910000152 cobalt phosphate Inorganic materials 0.000 description 1
- LFSBSHDDAGNCTM-UHFFFAOYSA-N cobalt(2+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[Ti+4].[Co+2] LFSBSHDDAGNCTM-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 235000012732 erythrosine Nutrition 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- TVFJAZCVMOXQRK-UHFFFAOYSA-N ethenyl 7,7-dimethyloctanoate Chemical compound CC(C)(C)CCCCCC(=O)OC=C TVFJAZCVMOXQRK-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- JCDAAXRCMMPNBO-UHFFFAOYSA-N iron(3+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Ti+4].[Fe+3].[Fe+3] JCDAAXRCMMPNBO-UHFFFAOYSA-N 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- 235000010494 karaya gum Nutrition 0.000 description 1
- 239000000231 karaya gum Substances 0.000 description 1
- 229940039371 karaya gum Drugs 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000004750 melt-blown nonwoven Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 1
- 239000008108 microcrystalline cellulose Substances 0.000 description 1
- 229940016286 microcrystalline cellulose Drugs 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000006864 oxidative decomposition reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- AZJPTIGZZTZIDR-UHFFFAOYSA-L rose bengal Chemical compound [K+].[K+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 AZJPTIGZZTZIDR-UHFFFAOYSA-L 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- LLELVHKMCSBMCX-UHFFFAOYSA-M sodium 1-[(4-chloro-5-methyl-2-sulfophenyl)diazenyl]naphthalen-2-olate Chemical compound [Na+].Cc1cc(N=Nc2c(O)ccc3ccccc23)c(cc1Cl)S([O-])(=O)=O LLELVHKMCSBMCX-UHFFFAOYSA-M 0.000 description 1
- 235000013759 synthetic iron oxide Nutrition 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 208000001072 type 2 diabetes mellitus Diseases 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
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- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
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- A61K2800/436—Interference pigments, e.g. Iridescent, Pearlescent
Landscapes
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- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
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- Veterinary Medicine (AREA)
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Abstract
The present invention provides a liquid temporary hair dye composition, which contains the following components (A) to (C), wherein the content of the component (C) is more than 50 mass percent, and the component (A): a pigment, (B): crystalline cellulose, (C): a C1-4 monohydric alcohol.
Description
Technical Field
The present invention relates to a liquid temporary hair dye composition.
Background
The temporary hair dye is a hair dye that is colored by forming a coloring film containing a coloring agent (mainly a pigment) on hair, and is less harmful to hair, easily removable by shampooing, and convenient to use, and therefore, is popular as a hair dye that can easily enjoy hair dyeing.
Conventionally, in order to develop a temporary hair dye beautifully on hair and maintain the color development, a sufficient amount of a coloring agent such as a pigment and a fixing agent (polymer or the like) for fixing the coloring agent to the hair in the form of a colored film have been used (for example, patent document 1). In addition, in order to apply the hair dye composition to hair easily and beautifully, it is often used in combination with a carrier such as a nonwoven fabric, paper, sponge, or the like (for example, patent document 2).
(patent document 1) Japanese patent laid-open publication No. 2017-114815
(patent document 2) Japanese patent laid-open publication No. 2018-033935
Disclosure of Invention
The invention provides a liquid temporary hair dye composition, which contains the following components (A) to (C), wherein the content of the component (C) is more than 50 mass percent,
(A) the method comprises the following steps Pigment, a,
(B) The method comprises the following steps Crystalline cellulose,
(C) The method comprises the following steps A C1-4 monohydric alcohol.
The present invention also provides a temporary hair dye cosmetic in which the liquid temporary hair dye composition is supported on a fibrous structure.
Detailed Description
In some conventional temporary hair dyes, a sufficient amount of pigment or fixing agent is added to cause the pigment to coagulate with time, and thus sufficient color development may not be ensured. In particular, in the case of using a large amount of a lower alcohol as a solvent, coagulation or precipitation of the pigment is liable to occur. In order to suppress the aggregation of the pigment, a dispersant, a thickener, or the like is used as a base, but these base often cause changes in the properties of the preparation such as stickiness or adhesion, adversely affect spreadability, or inhibit the fixing ability to hair, and thus sufficient color development may not be maintained.
In particular, when a hair dye composition using a large amount of a lower alcohol as a solvent is used in combination with a carrier, there are problems as follows: the pigment is aggregated or precipitated in the carrier, and thus the pigment cannot be properly discharged, and sufficient spreadability and manageability cannot be ensured.
Accordingly, the present invention relates to a liquid temporary hair dye composition which is less likely to cause coagulation or precipitation of pigments in spite of containing a large amount of lower alcohols and can ensure sufficient color development.
In view of the above circumstances, the present inventors have made extensive studies to suppress the aggregation and precipitation of a pigment in a large amount of a lower alcohol, and as a result, have found that: by using crystalline cellulose together with a pigment, the aggregation and precipitation of the pigment can be suppressed, and the color development can be maintained without impairing the spreadability and color development.
The liquid temporary hair dye composition of the present invention does not easily cause coagulation or precipitation of pigments despite containing a large amount of lower alcohol, and ensures sufficient color development.
[ component (A): pigment ]
The pigment as the component (a) is not particularly limited, and may be any pigment commonly used in cosmetics, regardless of its shape (spherical, needle-like, plate-like, etc.), particle diameter, and particle structure (porous, non-porous, etc.), and examples thereof include inorganic pigments, organic pigments, lake pigments of organic pigments, pearl pigments, metal powder pigments, and bright powders.
Specific examples of the inorganic pigment include: inorganic black pigments such as carbon black, iron oxide black and titanium oxide black; inorganic red pigments such as iron oxide (red oxide), iron hydroxide, and iron titanate; inorganic brown pigments such as gamma-iron oxide; inorganic yellow pigments such as yellow iron oxide and ochre; inorganic blue pigments such as ultramarine blue and iron blue; inorganic violet pigments such as manganese violet and cobalt violet; inorganic green pigments such as chromium oxide, chromium hydroxide, and cobalt titanate; inorganic white pigments such as titanium oxide, zinc oxide, cerium oxide and talc. Of these, carbon black, iron oxide black, titanium oxide black, iron oxide (red iron oxide), iron oxide yellow, ultramarine, iron blue, titanium oxide, and talc are preferable.
As the organic pigment, there can be mentioned: red 201, red 202, red 203, red 204, red 205, red 206, red 207, red 208, red 219, red 220, red 221, red 226, red 228, red 404, red 405, orange 203, orange 204, orange 401, yellow 205, yellow 401, blue 404, etc., of which red 201, red 202, red 226, red 404, yellow 205, yellow 401, blue 404, etc., are preferred.
Examples of the lake pigment of the organic pigment include: the lake pigments of organic pigments such as red No. 2, red No. 3, red No. 102, red No. 104 (1), red No. 105 (1), red No. 106, yellow No. 4, yellow No. 5, green No. 3, blue No. 1, blue No. 2, and the like, and among these, the lake pigment of yellow No. 4 is preferable.
As pearlescent pigments, there can be mentioned: pearl powder, bismuth oxychloride, mica, synthetic mica coated with a metal oxide, mica coated with a metal oxide (e.g., mica titanium, mica coated with iron oxide, mica coated with red oxide, mica titanium coated with iron oxide, mica titanium coated with red oxide, mica coated with iron oxide black, mica titanium coated with iron oxide black, mica coated with iron oxide yellow, mica titanium coated with iron oxide/iron oxide black, mica titanium coated with iron blue, mica titanium coated with iron oxide/iron blue, mica titanium coated with red oxide/iron blue, mica titanium coated with carmine, mica titanium coated with barium sulfate, etc.), aluminum oxide flakes coated with a metal oxide, silica coated with a metal oxide (e.g., silica coated with titanium oxide, silica flake coated with a metal oxide, mica coated with a metal oxide, Iron oxide-coated silica, iron pellet-coated silica), metal oxide-coated silicaGlass flakes, metal oxide-coated glass (e.g., titanium oxide-coated glass, iron oxide-coated glass, titanium oxide/iron oxide-coated glass), multi-coated pearlescent pigments (e.g., TiO/iron oxide-coated glass), and multi-coated pearlescent pigments2-SiO2-TiO2Mica (Mica), TiO2-SiO2Mica (Mica), TiO2-SiO2Glass (Glass), mica coated with titanium oxide/silicic anhydride, Glass coated with titanium oxide/silicic anhydride, etc.), borosilicate/silica/metal oxide mixtures (e.g. borosilicate/silica/titanium oxide mixtures), borosilicate/metal oxide mixtures (e.g. borosilicate/titanium oxide mixtures), etc. Of these, preferred are bismuth oxychloride, metal oxide-coated synthetic mica, metal oxide-coated silica, metal oxide-coated glass, multicoat pearlescent pigment, borosilicate/silica/metal oxide mixture, and borosilicate/metal oxide mixture. Still more preferred are bismuth oxychloride, mica titanium, mica coated with iron oxide, mica titanium coated with iron oxide yellow, mica titanium coated with iron oxide/iron oxide black, mica titanium coated with iron blue, mica titanium coated with iron oxide/iron blue, mica titanium coated with iron red, mica titanium coated with carmine, mica titanium coated with barium sulfate, silica coated with titanium oxide, silica coated with iron red, glass coated with titanium oxide, glass coated with iron red, glass coated with titanium oxide/iron oxide, glass coated with titanium oxide/iron red, mica titanium oxide/silicic anhydride, mica titanium oxide, silicic anhydride, titanium oxide, iron oxide, titanium dioxide, and the like, Glass coated with titanium oxide/silicic anhydride, borosilicate/silica/titanium oxide mixtures, borosilicate/titanium oxide mixtures.
As the metal powder pigment, there can be mentioned: gold powder, silver powder, copper powder, aluminum powder, brass powder, and the like.
Examples of the glittering powder include: polyethylene terephthalate/aluminum/epoxy laminate, polyethylene terephthalate/polyolefin laminate, and the like.
The pigment of component (a) may be used alone or in combination of two or more. The content of the component (a) in the liquid temporary hair dye composition of the present invention is preferably 0.5% by mass, more preferably 1% by mass or more, even more preferably 2.5% by mass or more, and even more preferably 3.5% by mass or more, from the viewpoint of hiding the original hair color regardless of the original hair color, and developing a vivid color such as red, blue or the like completely different from the original hair color. In addition, from the viewpoint of not impairing the feel of the hair, the hair is preferably 20% by mass or less, more preferably 15% by mass or less, still more preferably 10% by mass or less, and yet more preferably 8% by mass or less, from the viewpoint of facilitating the treatment of the hair after application.
[ component (B): crystalline cellulose ]
The crystalline cellulose as the component (B) is a cellulose crystal grain aggregate having a substantially constant polymerization degree obtained by subjecting cellulose to acid hydrolysis or alkaline oxidative decomposition, and examples thereof include those defined in the description of the 42 th page 502 to the 507 th page (1950) of industrial and engineering chemistry. In order to further enhance the effect of the present invention, it is preferable to use microcrystalline cellulose in which particles having a stokes diameter of 1 μm or less are present in a proportion of 5 mass% or more.
Further, crystalline cellulose may be obtained by milling and kneading with a water-soluble gum (e.g., karaya gum, xanthan gum, etc.) or sodium carboxymethylcellulose in the presence of water, followed by drying (e.g., Japanese patent publication No. 40-12174, Japanese patent application No. 4-259396, Japanese patent application No. 5-3183223, etc.); further, the cellulose-containing aqueous suspension may be an aqueous suspension of fine cellulose obtained by grinding a cellulose raw material in water (Japanese patent laid-open publication No. 56-100801, Japanese patent laid-open publication No. 3-163135, etc.). Commercially available products such as "Ceolus (registered trademark)" SC-42, RC-N30, RC-A591NF, "Avicel (registered trademark)" RC-51, RC-N81, RC-N30, CL-611 (manufactured by Asahi Kasei corporation), "CELLULOBEADS (registered trademark)" MC 200, MC 500, and MC 700 (manufactured by Dandow Kasei corporation) can also be used as appropriate.
The crystalline cellulose of the component (B) may be used alone or in combination of two or more. The content of the component (B) in the liquid temporary hair dye composition of the present invention is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, even more preferably 0.25% by mass or more, and even more preferably 1.0% by mass or more, from the viewpoint of suppressing aggregation or precipitation of the pigment in the presence of a large amount of a lower alcohol; from the viewpoint of not impairing the natural feel of the hair, the content is preferably 10% by mass or less, more preferably 7.5% by mass or less, still more preferably 5% by mass or less, and still more preferably 2.5% by mass or less. In the case where a raw material containing crystalline cellulose as the component (B) is used as described above, the content of the component (B) in the liquid temporary hair dye composition of the present invention is calculated from the content of crystalline cellulose in the raw material.
The mass ratio (B)/(a) of the component (B) to the component (a) is preferably 0.02 or more, more preferably 0.05 or more, and still more preferably 0.10 or more, from the viewpoint of suppressing the coagulation or precipitation of the pigment in the presence of a large amount of lower alcohol and not inhibiting the discharge of the pigment from the support; from the viewpoint of not impairing the vivid color development of the pigment, it is preferably 1.0 or less, more preferably 0.8 or less, and still more preferably 0.5 or less.
The pigment of the component (A) and the crystalline cellulose of the component (B) may be used as a mixture, or a raw material obtained by coating the component (B) on the component (A) in advance may be used as the component (A) and the component (B). Commercially available products such as C2-5 Ti2 CR-50, C2-2 Ti2 CR-50 and C2-5 YELLOW LL-100P (manufactured by Dadong chemical Co., Ltd.) can also be used conveniently.
[ component (C): c1-4 monohydric alcohol ]
The monohydric alcohol having 1 to 4 carbon atoms as the component (C) includes ethanol, propanol, and isopropanol, and ethanol is preferable among them.
The monohydric alcohol of component (C) may be used alone or in combination of two or more. The content of the component (C) in the liquid temporary hair dye composition of the present invention is 50 mass% or more, preferably 55 mass% or more, and more preferably 65.5 mass% or more, from the viewpoint of uniformly transferring the pigment to the hair; from the same viewpoint, the content is preferably 99% by mass or less, more preferably 97% by mass or less, still more preferably 90% by mass or less, and still more preferably 85% by mass or less.
The mass ratio (C)/(a) of the component (C) to the component (a) is preferably 5 or more, more preferably 6.5 or more, even more preferably 7.5 or more, even more preferably 8.5 or more, from the viewpoint of efficiently discharging the pigment from the carrier and uniformly applying the pigment to the hair; from the viewpoint of not impairing the quick drying property after application, it is preferably 100 or less, more preferably 70 or less, still more preferably 50 or less, and still more preferably 25 or less.
[ component (D): thickening polysaccharides
The thickening polysaccharides as the component (D) are not particularly limited, and thickening polysaccharides include: xanthan gum, carrageenan, guar gum, locust bean gum, tamarind gum, glucomannan, cationized starch, cationized guar gum, quince seed, agar, methyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose stearyloxy ether, carboxymethyl cellulose or its salt, maltodextrin, and the like. Among these, xanthan gum is most preferable from the viewpoint of thickening property, dispersibility, and feeling upon use.
The thickening polysaccharides of component (D) may be used alone or in combination of two or more. The content of component (D) in the liquid temporary hair dye composition of the present invention is preferably 0.06% by mass or more, more preferably 0.08% by mass or more, even more preferably 0.30% by mass or more, even more preferably 0.40% by mass or more, from the viewpoint of promoting the aggregation-inhibiting effect or precipitation-inhibiting effect of the pigment exerted by crystalline cellulose; from the viewpoint of satisfying the requirement of non-stickiness and not inhibiting the migration resistance from the hair, the content is preferably 1.0% by mass or less, more preferably 0.80% by mass or less, still more preferably 0.70% by mass or less, and still more preferably 0.55% by mass or less.
[ component (E): film-Forming Polymer
Examples of the coating-forming polymer of the component (E) include coating-forming polymers having a silicone skeleton, and examples of such polymers include: silicone-9 such as poly (N-formylethyleneimine) organopolysiloxane, poly (N-acetylethyleneimine) organopolysiloxane, poly (N-propionylethyleneimine) organopolysiloxane, etc.; organopolysiloxane graft polymers described in International publication No. 2014/002707, such as silicone-28; silicone-17 such as Silsoft Spread TT (manufactured by MOMENTIVE corporation); silicone-6; alkyl acrylate-methacrylic acid-silicone copolymers such as Luviflex Silk (manufactured by BASF); and alkyl acrylate copolymers such as KP-545 (manufactured by shin-Etsu chemical industries, Ltd.) such as methylpolysiloxane.
Examples of the coating forming polymer of the component (E) other than the above include: an alkylacrylamide/acrylate/alkylaminoalkylacrylamide/polyethylene glycol methacrylate copolymer described in Japanese patent laid-open No. 2-180911; an alkylacrylamide/alkylaminoalkylacrylamide/polyethylene glycol methacrylate copolymer described in Japanese patent laid-open No. 8-291206; (methacryloyloxyethylcarboxybetaine/alkyl methacrylate) copolymers such as Yukafmer M-75, Yukafmer R205, Yukafmer 301 (manufactured by Mitsubishi chemical corporation), and RAM resins (manufactured by Osaka organic chemical corporation); copolymers (acrylate/lauryl acrylate/stearyl acrylate/ethyl methacrylate amine oxide) such as Diaforder Z-651 (manufactured by Mitsubishi chemical corporation); acrylic acid/acrylamide/ethyl acrylate copolymers such as UltraHold 8 and UltraHold Strong (manufactured by BASF Co., Ltd.); (dimethylacrylamide/hydroxyethyl acrylate/methoxyethyl acrylate) copolymers such as Plas-size L-2714 (available from Stratagene chemical industries Co., Ltd.); acrylic resin alkanolamine solutions such as Plas-size L-9540B (available from Stratagene chemical industries, Ltd.); polyurethanes such as Luviset p.u.r. (manufactured by BASF Japan); polyvinyl caprolactam such as Luviskol Plus (manufactured by BASF); (octylacrylamide/hydroxypropyl acrylate/butylaminoethyl methacrylate) copolymers such as Amphomer28-4910 and Amphomer LV-71 (manufactured by Akzo Nobel Co., Ltd.); copolymers of (alkyl acrylate/octylacrylamide) such as Amphomer HC (manufactured by Akzo Nobel Co.); (vinyl acetate/crotonic acid/vinyl neodecanoate) copolymers such as Resyn 28-2930 (manufactured by Akzo Nobel Co.); urethane-14/acrylic acid (ester) copolymer AMP salts such as DynamX (manufactured by Akzo Nobel Co.); copolymers such as Aquaflex SF-40 (manufactured by Ashland corporation) (PVP/vinylcaprolactam/DMAPA acrylate); (isobutylene/ethylmaleimide/hydroxyethylmaleimide) copolymers such as Aquaflex FX-64 (manufactured by ISP Japan); (vinylpyrrolidone/acrylic acid DMAPA) copolymer such as Styleze CC-10 (manufactured by Ashland corporation); (vinylpyrrolidone/vinyl acetate) copolymers such as PVP/VA E-735 (manufactured by Ashland corporation) and Luviskol VA64P (manufactured by BASF corporation); polyvinyl pyrrolidones such as polyquaternium-11 (manufactured by Ashland corporation), Luviskol K-17 (manufactured by Ashland corporation), and Luviskol K-30 (manufactured by BASF corporation), Gafquat 440, Gafquat 734, and 755 (manufactured by Ashland corporation); (VP/methacrylamide/vinylimidazole) copolymers such as Luviset Clear (manufactured by BASF); copolymers (vinyl methyl ether/ethyl maleate) such as Gantrez ES-225 (manufactured by Ashland corporation); and a copolymer of vinyl methyl ether and butyl maleate such as Gantrez ES-425 (manufactured by Ashland).
Among them, from the viewpoint of setting properties, no sticky feeling during drying, and flexibility after application, it is preferably selected from a film-forming polymer having a silicone skeleton, an alkylacrylamide/acrylate/alkylaminoalkylacrylamide/polyethylene glycol methacrylate copolymer described in Japanese patent application laid-open No. 2-180911, an alkylacrylamide/alkylaminoalkylacrylamide/polyethylene glycol methacrylate copolymer, (methacryloyloxyethylcarboxybetaine/alkyl methacrylate) copolymer, (vinylpyrrolidone/vinyl acetate) copolymer, polyquaternium-11, polyvinylpyrrolidone, a dimethylacrylamide/hydroxyethyl acrylate/methoxyethyl acrylate) copolymer, a copolymer of a silicone skeleton, a copolymer of an alkylacrylamide/acrylate/alkylaminoalkylacrylamide/polyethylene glycol methacrylate described in Japanese patent application laid-open No. 8-291206, a copolymer of a silicone skeleton and a copolymer of a methacrylic skeleton and a copolymer of a hydroxyethyl acrylate/methoxyethyl acrylate, One or two or more film-forming polymers of a (vinyl methyl ether/butyl maleate) copolymer, more preferably one or two or more film-forming polymers selected from the group consisting of a film-forming polymer having a silicone skeleton, polyvinylpyrrolidone, and a dimethylacrylamide/hydroxyethyl acrylate/methoxyethyl acrylate) copolymer, and still more preferably an organopolysiloxane graft polymer described in international publication No. 2014/002707, such as silicone-9 and silicone-28.
The coating film-forming polymer of the component (E) may be used alone or in combination of two or more. The content of the component (E) in the liquid temporary hair dye composition of the present invention is preferably 2% by mass or more, more preferably 4% by mass or more, even more preferably 8% by mass or more, even more preferably 10% by mass or more, from the viewpoint of improving the rubbing resistance; from the viewpoint of suppressing the hair hardness or the dry feeling, it is preferably 50% by mass or less, more preferably 40% by mass or less, further preferably 35% by mass or less, and further more preferably 30% by mass or less.
[ production method ]
The liquid temporary hair dye composition of the present invention can be produced by, for example, the following production methods a, b, or c, but is not limited to these methods. As the media mill used in these production methods, a bead mill, a ball mill, an attritor, a sand mill, or the like can be used.
Production method a
After the component (a), the component (B) and the component (D) were crushed using a media mill in the presence of the component (C), the component (E) and other components were added to the crushed mixture and mixed to obtain a liquid temporary hair dye composition.
Production method b
After the component (B) and the component (D) were crushed using a media mill in the presence of the component (C), the component (a) was added to the crushed composition and mixed, and further, the component (E) and other components were added and mixed to obtain a liquid temporary hair dye composition.
Production method c
The liquid temporary hair dye composition is obtained by crushing the component (a) using a media mill in the presence of the component (C), and also crushing the component (B) and the component (D) in the presence of the component (C) in the same manner, after which the mixture of the crushed component (a) and the component (C) is mixed with the mixture of the crushed component (B), the component (C), and the component (D), the component (E) and the other components are added and mixed.
[ fiber Structure ]
The liquid temporary hair dye composition of the present invention can be used by being carried on a fiber structure in order to easily and beautifully apply the composition to hair. As the fiber structure, any material capable of holding the liquid temporary hair dye composition can be used. For example, a fibrous sheet made of a fibrous material such as a nonwoven fabric, a woven fabric, or paper is preferably used.
As the nonwoven fabric used as the fiber structure, nonwoven fabrics produced by various production methods, such as spunlace nonwoven fabric, melt-blown nonwoven fabric, needle-punched nonwoven fabric, and hot-air nonwoven fabric, can be used. As the paper, paper produced by a dry paper making method, a wet paper making method, or the like can be used.
In terms of the retention property as a liquid temporary hair dye composition, a fibrous structure such as a nonwoven fabric or paper preferably contains cellulose fibers as its constituent fibers. As the cellulose-based fibers, for example, hydrophilic fibers such as natural fibers and regenerated fibers can be used. Examples of the natural cellulose fibers include pulp fibers and cotton fibers. Examples of the regenerated cellulose fibers include rayon, cuprammonium fiber, Lyocell (Lyocell), Tencel (Tencel), and the like. These cellulose fibers may be used alone or in combination of two or more.
In addition, the fiber structure preferably contains synthetic fibers such as thermoplastic resin fibers in addition to cellulose fibers, from the viewpoints of enhancing the strength of the nonwoven fabric and preventing fuzz and the like when applied to hair, and suppressing adhesion of fibers to hair. As the thermoplastic resin fibers, there can be mentioned: polyolefins such as polypropylene and polyethylene; polyesters such as polyethylene terephthalate; polyamides such as nylon. The synthetic fiber may be a core-sheath type or side-by-side type composite fiber composed of a plurality of resin components. Thermosetting fibers may also be used instead of or in addition to thermoplastic resin fibers. These synthetic fibers may be used alone or in combination of two or more.
In view of contact with hair, the fiber structure may preferably have a rectangular shape in plan view, and may have a shape other than a rectangular shape, for example, a circular shape, an elliptical shape, a polygonal shape such as a triangular shape, a square shape, or a pentagonal shape, or a heart shape. The fiber structure may be composed of one fiber sheet, but is preferably a multilayer sheet obtained by laminating a plurality of sheets.
From the viewpoint of ensuring the amount of the liquid temporary hair dye composition to be retained, further improving the application workability to hair, or improving the portability, the thickness of the fiber structure made of the fiber material is preferably 0.4mm or more, more preferably 1.0mm or more, and still more preferably 1.5mm or more; further, it is preferably 15mm or less, more preferably 10mm or less, and further preferably 5mm or less. The thickness of the fiber structure mentioned here is 0.8cN/cm2The thickness under load of (a) means the thickness measured using a digital indicator. When a plurality of sheets are stacked, the thickness of the stacked sheets is referred to.
From the same viewpoint, the basis weight of the fibrous structure composed of the fibrous material is preferably 10g/m2Above, more preferably 20g/m2The above; further, it is preferably 300g/m2Hereinafter, more preferably 200g/m2The following. When a plurality of sheets are stacked, the basis weight of the stacked sheets is referred to.
When the liquid temporary hair dye composition of the present invention is used for hair dressing by supporting it on a fiber structure, the supporting ratio on the fiber structure is preferably 60% or more, more preferably 140% or more, and still more preferably 250% or more; further, it is preferably 600% or less, more preferably 500% or less, and still more preferably 400% or less. The supporting ratio herein means a ratio (percentage,%) of the mass of the liquid temporary hair dye composition to the mass of the fiber structure before impregnation.
[ cosmetics for temporary Hair dyeing ]
The present invention provides a temporary hair dye cosmetic in which the liquid temporary hair dye composition is supported on a fiber structure. In this case, the amount of the liquid temporary hair dye composition carried on the fiber structure is preferably in the above range, and the fiber structure carrying the liquid temporary hair dye composition is preferably sealed by a package comprising a liquid-impermeable sheet. As the package, a sheet made of a liquid impermeable material such as an aluminum foil or a thermoplastic resin film is selected, and among these, a thermoplastic resin film or a film obtained by laminating a metal film such as aluminum on the film is preferable.
Preferred embodiments of the present invention are further disclosed below with respect to the above-described embodiments.
< 1 > a liquid temporary hair dye composition which comprises the following components (A) to (C) and contains the component (C) in an amount of 50% by mass or more,
(A) the method comprises the following steps Pigment, a,
(B) The method comprises the following steps Crystalline cellulose,
(C) The method comprises the following steps A C1-4 monohydric alcohol.
< 2 > the liquid temporary hair dye composition according to < 1 >, wherein the component (A) is preferably at least one selected from the group consisting of inorganic pigments, organic pigments, lake pigments of organic pigments, pearl pigments, metal powder pigments and glitter powders.
< 3 > the liquid temporary hair dye composition as < 1 > or < 2 >, wherein the content of the component (A) is preferably 0.5% by mass or more, more preferably 1% by mass or more, further preferably 2.5% by mass or more, further preferably 3.5% by mass or more; further, it is preferably 20% by mass or less, more preferably 15% by mass or less, further preferably 10% by mass or less, and further more preferably 8% by mass or less.
The liquid temporary hair dye composition of any one of < 4 > such as < 1 > to < 3 >, wherein the content of the component (B) is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, further preferably 0.25% by mass or more, further preferably 1.0% by mass or more; further, it is preferably 10% by mass or less, more preferably 7.5% by mass or less, further preferably 5% by mass or less, and further more preferably 2.5% by mass or less.
< 5 > the liquid temporary hair dye composition according to any one of < 1 > to < 4 >, wherein the mass ratio (B)/(a) of the component (B) to the component (a) is preferably 0.02 or more, more preferably 0.05 or more, and still more preferably 0.10 or more; further, it is preferably 1.0 or less, more preferably 0.8 or less, and further preferably 0.5 or less.
The liquid temporary hair dye composition of < 6 > such as < 1 > to < 5 >, wherein component (C) is preferably one or more selected from the group consisting of ethanol, propanol, and isopropanol.
The liquid temporary hair dye composition of < 7 > such as < 1 > to < 6 > wherein the content of the component (C) is preferably 55% by mass or more, more preferably 65.5% by mass or more; further, it is preferably 99% by mass or less, more preferably 97% by mass or less, further preferably 90% by mass or less, and further preferably 85% by mass or less.
< 8 > the liquid temporary hair dye composition according to any one of < 1 > to < 7 >, wherein the mass ratio (C)/(a) of the component (C) to the component (a) is preferably 5 or more, more preferably 6.5 or more, further preferably 7.5 or more, further more preferably 8.5 or more; further, it is preferably 100 or less, more preferably 70 or less, further preferably 50 or less, further more preferably 25 or less.
The liquid temporary hair dye composition according to any one of < 9 > to < 1 > to < 8 >, wherein a thickening polysaccharide is preferably further contained as the component (D).
< 10 > and < 9 > in the liquid temporary hair dye composition, the component (D) is preferably at least one selected from xanthan gum, carrageenan, guar gum, locust bean gum, tamarind gum, glucomannan, cationized starch, cationized guar gum, quince seed, agar, methyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose stearyloxy ether, carboxymethyl cellulose or a salt thereof, and maltodextrin.
< 11 > the liquid temporary hair dye composition according to < 10 >, wherein the content of the component (D) is preferably 0.06% by mass or more, more preferably 0.08% by mass or more, further preferably 0.30% by mass or more, further more preferably 0.40% by mass or more; further, it is preferably 1.0% by mass or less, more preferably 0.80% by mass or less, further preferably 0.70% by mass or less, and further more preferably 0.55% by mass or less.
The liquid temporary hair dye composition of < 12 > such as < 1 > to < 11 >, wherein a film-forming polymer is preferably further contained as the component (E).
< 13 > the liquid temporary hair dye composition according to < 12 >, wherein the component (E) is preferably one or more coating film-forming polymers selected from the group consisting of coating film-forming polymers having a silicone skeleton, polyvinylpyrrolidone, and dimethylacrylamide/hydroxyethyl acrylate/methoxyethyl acrylate) copolymers, and more preferably one or more organopolysiloxane graft polymers selected from the group consisting of silicone-9 and silicone-28.
The liquid temporary hair dye composition of < 14 > such as < 12 > or < 13 > in which the content of the component (E) is preferably 2% by mass or more, more preferably 4% by mass or more, further preferably 8% by mass or more, further preferably 10% by mass or more; further, it is preferably 50% by mass or less, more preferably 40% by mass or less, further preferably 35% by mass or less, and further preferably 30% by mass or less.
< 15 > a cosmetic for temporary hair dyeing, wherein the liquid temporary hair dye composition is supported on a fiber structure, and the liquid temporary hair dye composition is any one of < 1 > to < 14 >.
< 16 > the cosmetic for temporary hair dyeing as < 15 > wherein the fibrous structure is preferably a fibrous sheet composed of a fibrous material selected from the group consisting of nonwoven fabric, woven fabric and paper.
< 17 > the cosmetic for temporary coloring as < 16 > wherein the package formed of a liquid impermeable sheet material is sealed.
[ examples ]
Synthesis example 1: Polysilicone-9A
Diethyl sulfate (0.77 g, 0.005 mol) and 2-ethyl-2-oxazoline (12.9 g, 0.13 mol) were dissolved in dehydrated ethyl acetate (28 g), and the mixture was refluxed under nitrogen atmosphere for 8 hours to synthesize terminal-reactive poly (N-propionylethyleneimine). Number average molecular weight by GPC was 2700. To this terminally reactive poly (N-propionylethyleneimine) was added 100g of a 33% ethyl acetate solution of a side chain primary aminopropyl-modified polydimethylsiloxane (weight average molecular weight 100,000, amine equivalent 20,000) in one portion, and the mixture was heated under reflux for 10 hours. The reaction mixture was concentrated under reduced pressure to obtain N-propionylethyleneimine/dimethylsiloxane copolymer as a colorless solid (108g, yield 95%). The content of the organopolysiloxane segment in the final product was 88 mass%, and the weight-average molecular weight was 114,000. Methanol was used as a solvent, and neutralization titration was performed with hydrochloric acid, and as a result, no amino group remained.
Synthesis example 2: Polysilicone-9B
Diethyl sulfate (6.5 g, 0.042 mol) and 2-ethyl-2-oxazoline (34.4 g, 0.36 mol) were dissolved in dehydrated ethyl acetate (87 g), and the mixture was refluxed under nitrogen atmosphere for 8 hours to synthesize terminal-reactive poly (N-propionylethyleneimine). Number average molecular weight by GPC was 1000. To this terminally reactive poly (N-propionylethyleneimine) was added 100g of a 33% ethyl acetate solution of a side-chain primary aminopropyl-modified polydimethylsiloxane (weight average molecular weight 50,000, amine equivalent 2,000) in one portion, and the mixture was refluxed for 10 hours. The reaction mixture was concentrated under reduced pressure to obtain N-propionylethyleneimine/dimethylsiloxane copolymer as a pale yellow solid (138g, yield 98%). The content of the organopolysiloxane segment in the final product was 71 mass%, and the weight-average molecular weight was 70,000. Neutralization titration was performed using hydrochloric acid with methanol as a solvent, and it was revealed that about 20 mol% of amino groups remained.
Synthesis example 3: Polysilicone-9C
Diethyl sulfate (6.17 g, 0.04 mol) and 2-ethyl-2-oxazoline (93.8 g, 0.947 mol) were dissolved in dehydrated ethyl acetate (203 g), and the mixture was refluxed under nitrogen atmosphere for 8 hours to synthesize terminal-reactive poly (N-propionylethyleneimine). Number average molecular weight was 2500 by GPC. To this terminally reactive poly (N-propionylethyleneimine) was added 100g of a 33% ethyl acetate solution of a side-chain primary aminopropyl-modified polydimethylsiloxane (weight average molecular weight 30,000, amine equivalent 2,000) in one portion, and the mixture was refluxed for 10 hours. The reaction mixture was concentrated under reduced pressure to obtain N-propionylethyleneimine/dimethylsiloxane copolymer as a pale yellow solid (190g, yield 95%). The content of the organopolysiloxane segment in the final product was 50 mass%, and the weight-average molecular weight was 60,000. Neutralization titration was performed using hydrochloric acid with methanol as a solvent, and it was revealed that about 20 mol% of amino groups remained.
Examples 1 to 29 and comparative examples 1 to 4
Liquid temporary hair dye compositions having the compositions shown in tables 1 and 2 were prepared. Further, for each evaluation, a nonwoven fabric carrier was prepared by impregnating a nonwoven fabric carrier with the liquid temporary hair dye composition other than those of example 12 and comparative example 2.
The nonwoven carrier used here had a basis weight of 45.0. + -. 4.5g/m2A nonwoven fabric carrier (SH Crepe 45, manufactured by Potta paper industries, Ltd.) having a thickness of 0.60. + -. 0.20mm and a size of 3cm X5 cm and a basis weight of 60.0. + -. 6.0g/m2A nonwoven fabric carrier (RB8260P, manufactured by Pontian paper industries, Ltd.) having a thickness of 0.54. + -. 0.06mm and a size of 3cm X5 cm.
< manufacturing method >
(preparation of liquid temporary Hair dye composition)
The liquid temporary hair dye composition is produced by the production method a, b or c shown below.
Production method a
Component (A), component (B) and component (D) were crushed in the presence of component (C) using a bead mill (NANOMILL NM-L, manufactured by light Seaman iron Co., Ltd.). Thereafter, the component (E) and other components were added to the crushed mixture and mixed to obtain a liquid temporary hair dye composition. Further, examples 14, 24 and 25 and comparative example 3 were prepared in the same manner as described above except that the component (D) was not added. In comparative examples 1 and 2, the production was carried out in the same manner as described above except that the component (B), the component (D), and the component (E) were not added.
Production method b
Component (B) and component (D) were crushed in the presence of component (C) using a bead mill (NANOMILL NM-L, manufactured by light Seaman iron Co., Ltd.). Thereafter, the component (a) was added to the crushed composition and mixed, and further, the component (E) and other components were added and mixed to obtain a liquid temporary hair dye composition. In comparative example 4, component (a) was added to component (C) and mixed to obtain a liquid temporary hair dye composition.
Production method c
Component (A) was crushed in the presence of component (C) using a bead mill (NANOMILL NM-L, manufactured by light Seaman iron Co., Ltd.). Component (B) and component (D) are also crushed in the presence of component (C) in the same manner. Thereafter, the mixture of the crushed component (a) and component (C) and the mixture of the crushed component (B), component (C), and component (D) are mixed, and the component (E) and the other components are added and mixed to obtain a liquid temporary hair dye composition.
(preparation of nonwoven Carrier)
In the case of using two kinds of nonwoven fabrics, the two kinds of nonwoven fabrics are each stacked in 4 layers for a total of 8 layers; in the case of using only one type of nonwoven fabric, the one type of nonwoven fabric is used by stacking 8 layers and then bonding the stacked layers. For joining the nonwoven fabric layers, a joining method of ultrasonic sealing is used.
(preparation of nonwoven Fabric Carrier)
The liquid temporary hair dye composition mixed uniformly is dropped onto the nonwoven fabric carrier to impregnate the nonwoven fabric carrier with the liquid temporary hair dye composition. The amount of the liquid temporary hair dye composition held on the nonwoven fabric support was adjusted to 333% based on the basis weight of the nonwoven fabric support.
< evaluation method >
(evaluation hair bundle)
A bundle of hair having a length of 25cm and a weight of 1g was produced by straightening Japanese hair without chemical treatment. The hair tresses were cleaned with a sample shampoo of the formula shown below. The hair bundle after 1 minute of towel drying by a hair dryer (hair dryer ion: EH-NE67, manufactured by Panasonic corporation) was used for evaluation.
(method of evaluating the Effect of suppressing the color development Change after storage)
Using a nonwoven fabric support carrying the liquid temporary hair dye composition just produced, 0.3g of each composition was applied from the root to the tip of the hair strand for evaluation as described above. In the liquid temporary hair dye compositions of example 12 and comparative example 2, 0.3g of each composition was applied directly to the evaluation hair bundle from the root to the tip of the hair bundle with the fingers without impregnating the nonwoven fabric support. After application, the hair piece was left to stand at room temperature to sufficiently dry the hair piece, and this was used as a standard product.
On the other hand, the nonwoven fabric support carrying the liquid temporary hair dye composition (liquid temporary hair dye composition in example 12 and comparative example 2) was sealed and stored in a thermostatic bath (EYELA window oven) set at 60 ℃ for 7 days. Thereafter, the sample was taken out from the thermostatic bath and allowed to stand at room temperature for 3 hours to adjust the temperature. The stored sample was applied to evaluation hair strands in the same manner and allowed to dry. The color development (intensity) from one end (upper portion) of the bundled side to the tip (lower portion) of the evaluation hair bundle was compared with a reference product and evaluated by visual observation. The evaluation was set as the following 4-stage visual evaluation by 5 professional panelists, which was collectively shown in the table.
And 4, dividing: exhibits color development (strength) equivalent to that of the reference product
And 3, dividing: the color development (intensity) is slightly reduced from that of the reference product
And 2, dividing: color development (intensity) is reduced relative to the reference
1 minute: the color development (strength) was greatly reduced (color development property) relative to the reference
The following 4-stage visual evaluation was performed by 5 professional panelists regarding the color developability of the colored hair strands, which are collectively shown in the table.
And 4, dividing: the original color is covered and fully developed
And 3, dividing: the original color is slightly masked and developed
And 2, dividing: the original color is hardly covered and hardly developed
1 minute: no color development at all (quick-drying)
For the hair strands for evaluation shown above, 0.3g of each composition was applied from the root to the tip of the hair strand using a nonwoven fabric support carrying a liquid temporary hair dye composition. In the liquid temporary hair dye compositions of example 12 and comparative example 2, 0.3g of each composition was applied directly to the evaluation hair bundle from the root to the tip of the hair bundle with the fingers without impregnating the nonwoven fabric support. After the application, the coating was combed 1 time per second using a Comb (HK 0103B's Set Comb L, manufactured by Bei print Co., Ltd.), for a total of 5 times, and then allowed to stand at room temperature to dry. The rate of drying was evaluated from the state of the hair bundle when the hair bundle was touched with a finger. The evaluation was set as the following 4-stage visual evaluation by 5 professional panelists, which was collectively shown in the table.
And 4, dividing: drying quickly
And 3, dividing: drying is faster
And 2, dividing: dry little quickly
1 minute: slow drying (touch)
Further, the dried colored hair strands after evaluation of the excessively fast drying were combed 1 time per second for a total of 10 times using a Comb (HK 0103B's Set Comb L, manufactured by beige). The hair bundle was touched with a finger and evaluated for stickiness or stiffness according to the following criteria. The evaluation was set as the following 4-stage evaluation by 5 professional panelists, which are collectively shown in the table.
And 4, dividing: it does not feel sticky or hard and smooth
And 3, dividing: hardly feels sticky or hard, and is smooth
And 2, dividing: slightly sticky or stiff and not smooth
1 minute: feel sticky or hard, not smooth (spreadability)
The spreadability of the nonwoven fabric support carrying the liquid temporary hair dye composition (in example 12 and comparative example 2, since the nonwoven fabric support was not impregnated with the liquid temporary hair dye composition, evaluation was not performed) was evaluated by visually observing the manageability from one end (upper portion) to the tip (lower portion) of the bundled side of the hair strand for evaluation. The evaluation was set as the following 4-stage evaluation by 5 professional panelists, which are collectively shown in the table.
And 4, dividing: uniform beating property from upper part to lower part
And 3, dividing: the upper to lower manageability is substantially uniform
And 2, dividing: less uniformity in manageability from top to bottom
1 minute: uneven manageability from top to bottom (evaluation method of redispersibility)
The liquid temporary hair dye composition was stored in a closed container (centrifuge tube) and stored in a thermostatic bath (EYELA window oven) set at 60 ℃ for 7 days. Thereafter, the sample was taken out from the thermostatic bath and allowed to stand at room temperature for 3 hours to adjust the temperature. After the storage, the sample was shaken for 30 seconds, and then the state of the precipitate was visually observed, thereby evaluating redispersibility. The evaluation was set as the following 4-stage evaluation by 5 professional panelists, which are collectively shown in the table.
And 4, dividing: no precipitate remained, and mixed uniformly
And 3, dividing: almost no precipitate remained, and was mixed almost uniformly
And 2, dividing: although the precipitate hardly remained, it was not uniformly mixed
1 minute: more precipitate remained and was not uniformly mixed
*1: tipaque CR-50 (made by stone industries Co., Ltd.)
*2: BC Red 202 number K (Kaihe Kaishi Co., Ltd.)
*3: c43-1810 SUNCROMA ULTRAMARINE BLUE (manufactured by Sun Chemical Co., Ltd.)
*4: UNIPURE BLUE LC685 (manufactured by sensor Cosmetic Technologies, Inc.; iron BLUE 50%, talc 50%)
*5: TAROX synthetic iron oxide R-516P (Titan Industrial Co., Ltd.)
*6: TAROX Synthesis of iron oxide LL-100P (Titan Industrial Co., Ltd.)
*7: ceolus RC-N30 (manufactured by Asahi Kasei corporation; crystalline cellulose 75 mass%, maltodextrin 20 mass%, xanthan gum 5 mass%)
*8: ceolus RC-A591NF (manufactured by Asahi Kasei Co., Ltd.; crystalline cellulose 89 mass%, sodium carboxymethylcellulose 5 mass%)
*9: ceolus PH101 (manufactured by Asahi Kasei corporation)
*10: plas-size L-75CB (manufactured by reciprocity chemical industries Co., Ltd.)
*11: SH Crepe 45 (manufactured by Potta paper industry Co., Ltd.)
*12: RB8260P (manufactured by Potta paper industries Co., Ltd.)
*16: CLOISONNE SUPER GREEN (manufactured by BASF corporation)
*17: colorona Fine Gold MP-20 (manufactured by Merck corporation)
*18: ronafair Balance Gold (Merck Co., Ltd.)
*19: timiron Splendid Gold (manufactured by Merck Co., Ltd.)
*20: timiron Liquid Silver (Merck, 70% by mass of bismuth oxychloride and 30% by mass of ethylhexyl hydroxystearate)
*21: luviskol K30(BASF corporation)
Examples 30 to 38
The liquid temporary hair dye composition produced by the above-mentioned production method a, b or c was stored at 60 ℃ for 7 days and then applied to hair, and as a result, all showed good color development.
[ Table 3]
[ Table 4]
*1: tipaque CR-50 (made by stone industries Co., Ltd.)
*7: ceolus RC-N30 (manufactured by Asahi Kasei corporation; crystalline cellulose 75 mass%, maltodextrin 20 mass%, xanthan gum 5 mass%)
*10: plas-size L-75CB (manufactured by reciprocity chemical industries, Ltd.)
*11: SH Crepe 45 (manufactured by Potta paper industry Co., Ltd.)
*12: RB8260P (manufactured by Potta paper industries Co., Ltd.)
*13: c2-5 Ti2 CR-50 (manufactured by Dadonghuacheng chemical Co., Ltd.)
*14: c2-2 Ti2 CR-50 (manufactured by Dadonghuacheng chemical Co., Ltd.)
*15: c2-5 YELLOW LL-100P (manufactured by Dadong chemical Co., Ltd.)
*22: xirona Golden Sky (Merck company)
*23: REFLECKS MULTIMIDENSIONS SHIFTING SAPPHIRE (BASF corporation)
*24: RB7360M (manufactured by NIDDM PAPER INDUSTRIES, 70% by mass rayon and 30% by mass PP/PE)
Formulation examples 1 to 5
The following shows formulation examples of the present invention. Each formulation example was produced by the production method a of the above example, and exhibited good color development after storage.
[ Table 5]
*1: tipaque CR-50 (manufactured by Shiyuan industries, Ltd.)
*3: c43-1810 SUNCROMA ULTRAMARINE BLUE (manufactured by Sun Chemical Co., Ltd.)
*4: UNIPURE BLUE LC685 (manufactured by sensor Cosmetic Technologies, Inc.; iron BLUE 50%, talc 50%)
*7: ceolus RC-N30 (manufactured by Asahi Kasei corporation; crystalline cellulose 75 mass%, maltodextrin 20 mass%, xanthan gum 5 mass%)
*11: SH Crepe 45 (manufactured by Potta paper industry Co., Ltd.)
*25: KDH-60X (manufactured by Daiwabo Polytec Co., Ltd.; rayon 70% by mass, PET 30% by mass)
*26: RH3-40B (manufactured by Daiwabo Polytec Co., Ltd.; rayon 80% by mass, PP/PE 20% by mass)
*27: cottoace C060S/A01 (manufactured by Unitika corporation; cotton)
*28: escotto C060P/A01 (manufactured by Unitika Co., Ltd.; Cotton 50 mass%, PET/PE 50 mass%)
*29: SG-56N (manufactured by Iye paper Co., Ltd.; pulp 85 mass%, PET 15 mass%)
*30: HJ-33 (manufactured by Iye paper Co., Ltd.; pulp 75 mass%, PP/PE 25 mass%).
Claims (7)
1. A liquid temporary hair dye composition, wherein,
contains the following components (A) to (C) in an amount of 50% by mass or more,
(A) the method comprises the following steps Pigment, a,
(B) The method comprises the following steps Crystalline cellulose,
(C) The method comprises the following steps A C1-4 monohydric alcohol.
2. The liquid temporary hair dye composition of claim 1, wherein,
the mass ratio (C)/(A) of the component (C) to the component (A) is 5 to 100.
3. The liquid temporary hair dye composition as set forth in claim 1 or 2,
the mass ratio (B)/(A) of the component (B) to the component (A) is 0.02 to 1.0.
4. The liquid temporary hair dye composition as set forth in any one of claims 1 to 3,
further contains a thickening polysaccharide as component (D).
5. The liquid temporary hair dye composition as set forth in any one of claims 1 to 4,
further contains a coating film-forming polymer as a component (E).
6. A cosmetic for temporary hair dyeing, wherein,
a temporary liquid hair dye composition according to any one of claims 1 to 5, which is supported on a fiber structure.
7. The cosmetic for temporary hair dyeing according to claim 6, wherein,
is formed by sealing a packaging body formed by a liquid impermeable sheet.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2019188167 | 2019-10-11 | ||
| JP2019-188167 | 2019-10-11 | ||
| PCT/JP2020/038025 WO2021070873A1 (en) | 2019-10-11 | 2020-10-07 | Liquid temporarily hair-dyeing agent composition |
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| Publication Number | Publication Date |
|---|---|
| CN114466645A true CN114466645A (en) | 2022-05-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202080068907.5A Pending CN114466645A (en) | 2019-10-11 | 2020-10-07 | Liquid temporary hair dye composition |
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| Country | Link |
|---|---|
| JP (1) | JP2021063066A (en) |
| CN (1) | CN114466645A (en) |
| TW (1) | TW202120064A (en) |
| WO (1) | WO2021070873A1 (en) |
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| KR102390922B1 (en) * | 2021-11-08 | 2022-04-28 | 한국콜마주식회사 | Composition for oxidative dyeing of hair |
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| JP2004149484A (en) * | 2002-10-31 | 2004-05-27 | Hoyu Co Ltd | Method for dyeing hair and removing hairdye from hair |
| CN1681477A (en) * | 2002-09-20 | 2005-10-12 | Fmc有限公司 | Cosmetic composition containing microcrystalline cellulose |
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| WO2016062467A1 (en) * | 2014-10-23 | 2016-04-28 | Henkel Ag & Co. Kgaa | Temporary changing the colour of hair using pigments, alcohols and zwitterionic or cationic polymers |
| JP2018033935A (en) * | 2016-08-26 | 2018-03-08 | 花王株式会社 | Hair treatment method and hair treatment tool |
| KR20180075094A (en) * | 2016-12-26 | 2018-07-04 | (주)아모레퍼시픽 | Composition for temporary dyeing of hair |
| CN108714113A (en) * | 2018-06-02 | 2018-10-30 | 浙江莱凡化妆品有限公司 | A kind of stamp nail polish and its preparation process and application method |
| CN109689009A (en) * | 2016-08-26 | 2019-04-26 | 花王株式会社 | Hair treatment method and hair treatment utensil |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3693437B2 (en) * | 1995-11-30 | 2005-09-07 | 三菱鉛筆株式会社 | Temporary hair dye and its manufacturing method |
| AU2003218991A1 (en) * | 2002-03-01 | 2003-09-16 | Henkel Kommanditgesellschaft Auf Aktien | Colouring agents |
| JP5243708B2 (en) * | 2006-09-05 | 2013-07-24 | 株式会社トキワ | Temporary hair dye |
-
2020
- 2020-10-07 CN CN202080068907.5A patent/CN114466645A/en active Pending
- 2020-10-07 WO PCT/JP2020/038025 patent/WO2021070873A1/en active Application Filing
- 2020-10-07 JP JP2020170021A patent/JP2021063066A/en active Pending
- 2020-10-08 TW TW109134962A patent/TW202120064A/en unknown
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08143434A (en) * | 1994-11-18 | 1996-06-04 | Chuo Aerosol Kagaku Kk | Hair dyeing agent |
| CN1681477A (en) * | 2002-09-20 | 2005-10-12 | Fmc有限公司 | Cosmetic composition containing microcrystalline cellulose |
| JP2004149484A (en) * | 2002-10-31 | 2004-05-27 | Hoyu Co Ltd | Method for dyeing hair and removing hairdye from hair |
| CN101481424A (en) * | 2009-02-06 | 2009-07-15 | 北京大学 | Ultra-fine microcrystalline cellulose and preparation thereof |
| WO2016062467A1 (en) * | 2014-10-23 | 2016-04-28 | Henkel Ag & Co. Kgaa | Temporary changing the colour of hair using pigments, alcohols and zwitterionic or cationic polymers |
| JP2018033935A (en) * | 2016-08-26 | 2018-03-08 | 花王株式会社 | Hair treatment method and hair treatment tool |
| CN109689009A (en) * | 2016-08-26 | 2019-04-26 | 花王株式会社 | Hair treatment method and hair treatment utensil |
| KR20180075094A (en) * | 2016-12-26 | 2018-07-04 | (주)아모레퍼시픽 | Composition for temporary dyeing of hair |
| CN108714113A (en) * | 2018-06-02 | 2018-10-30 | 浙江莱凡化妆品有限公司 | A kind of stamp nail polish and its preparation process and application method |
Also Published As
| Publication number | Publication date |
|---|---|
| TW202120064A (en) | 2021-06-01 |
| JP2021063066A (en) | 2021-04-22 |
| WO2021070873A1 (en) | 2021-04-15 |
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