CN114440383B - Disinfection and purification device and purification method thereof - Google Patents
Disinfection and purification device and purification method thereof Download PDFInfo
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- CN114440383B CN114440383B CN202210253350.3A CN202210253350A CN114440383B CN 114440383 B CN114440383 B CN 114440383B CN 202210253350 A CN202210253350 A CN 202210253350A CN 114440383 B CN114440383 B CN 114440383B
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- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 159
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- 230000001699 photocatalysis Effects 0.000 claims abstract description 46
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- 239000011941 photocatalyst Substances 0.000 claims description 14
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 10
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- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
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- 239000007924 injection Substances 0.000 description 2
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- 238000004064 recycling Methods 0.000 description 2
- 239000003206 sterilizing agent Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/20—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation
- F24F8/24—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation using sterilising media
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/18—Absorbing units; Liquid distributors therefor
- B01D53/185—Liquid distributors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/75—Multi-step processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C3/00—Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
- B03C3/017—Combinations of electrostatic separation with other processes, not otherwise provided for
- B03C3/0175—Amassing particles by electric fields, e.g. agglomeration
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F11/00—Control or safety arrangements
- F24F11/89—Arrangement or mounting of control or safety devices
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F13/00—Details common to, or for air-conditioning, air-humidification, ventilation or use of air currents for screening
- F24F13/08—Air-flow control members, e.g. louvres, grilles, flaps or guide plates
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F13/00—Details common to, or for air-conditioning, air-humidification, ventilation or use of air currents for screening
- F24F13/28—Arrangement or mounting of filters
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/10—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering
- F24F8/15—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering by chemical means
- F24F8/167—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering by chemical means using catalytic reactions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Combustion & Propulsion (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention provides a disinfection and purification device and a purification method thereof, wherein the disinfection and purification device comprises a box body, and a filtering unit, a disinfection and purification unit and a photocatalysis deep purification unit are sequentially arranged in the box body along the gas flow direction; the disinfection and purification unit comprises a charged spraying device and at least two porous honeycomb plates, the charged spraying device sprays charged spraying into the box body, the porous honeycomb plates are staggered to form a baffling channel, an ultrasonic transduction device is arranged on each porous honeycomb plate, and the ultrasonic transduction device is used for atomizing liquid on the porous honeycomb plates. The invention respectively carries out charged atomization disinfection and deep photocatalytic purification on the gas in the box body, purifies the gas in the environment, has no harm to the discharged gas, can be used in the environment with people, and has the characteristics of disinfection and deodorization, continuous purification, high safety and the like.
Description
Technical Field
The invention belongs to the technical field of air purification, and relates to a disinfection and purification device and a purification method thereof.
Background
Chemical disinfectants represented by 84 disinfectant, alcohol, hypochlorous acid and the like are the main disinfection materials in the public places at present by virtue of the advantages of high sterilization speed, low cost and the like. The specific disinfection mode comprises the following steps: sterilizing the air and the object surfaces by sterilizing personnel or automatic sterilizing machines through atomizing, spraying or scrubbing the sterilizing agents such as alcohol, hydrogen peroxide, chlorine-containing sterilizing agents, peracetic acid and the like.
However, these chemical disinfectants on the one hand can directly damage human bodies and equipment, and disinfection byproducts can also increase the risk of cancer of human bodies, so that the chemical disinfectants need to be used under unmanned conditions, and due to the short action time of the chemical disinfectants, the problem that bacteria are easy to leak during a disinfection interval in public transportation means and public places (hospitals, schools, banks, airports, stations and the like) with large personnel flow is solved.
In addition, most of atomization disinfection machines are mainly used for atomizing hydrogen peroxide, hypochlorous acid and the like into the air and sterilizing by diffusion, so that the atomization disinfection machines cannot be used under the condition of people; the photocatalysis sterilizer mainly combines ultraviolet irradiation with photocatalysis, is not suitable for killing bacteria gas due to low photochemical conversion efficiency, has low sterilization efficiency, is difficult to meet sterilization requirements, and can generate ozone to cause secondary pollution in the use process of a 254nm ultraviolet lamp.
CN109107381a discloses a photocatalytic air purifier with self-purifying capability, which comprises a power supply, a controller, a shell, a coarse filter screen, a high-efficiency filter screen, an activated carbon screen, a photocatalytic screen, an ultraviolet lamp positioned behind the photocatalytic screen, and a first fan positioned behind the ultraviolet lamp, wherein the coarse filter screen, the high-efficiency filter screen, the activated carbon screen, the photocatalytic screen, the ultraviolet lamp and the first fan are sequentially arranged in parallel; the filter screen disinfection and sterilization device and the active carbon drying device are also included. The filter screen sterilizing device can kill bacteria growing on the filter screen, and the frequency of manually cleaning the filter screen is reduced; the activated carbon drying device can remove the moisture absorbed by the activated carbon, so that the activated carbon recovers part of the activity.
CN213789117U discloses a portable spray sterilizer, which comprises a tank body, wherein the upper end of the tank body is provided with a water inlet and a spray opening, the water inlet is communicated with a water tank in the tank body through a pipeline, the water tank is arranged in an open way, an ultrasonic atomizer is arranged in the water tank, and an ozone generator is arranged in the tank body and outside the water tank; the photocatalytic screen plate is arranged in the box body and at the spraying opening, the blowing fan is arranged in the spraying opening, and the blowing fan, the photocatalytic screen plate and the ozone generator are electrically connected with a power supply. The scheme provides a disinfection system without adding chemical disinfectant, thereby saving the adding cost of the disinfectant.
Therefore, the disinfection purifier in the prior art has the problems of short duration, no need of using an unmanned space, harm of byproducts to human bodies and the like, so that the problem of harm to human bodies can be solved while the continuous disinfection and purification is ensured, and the technical problem of urgent need to be solved at present is also ensured.
Disclosure of Invention
Aiming at the defects existing in the prior art, the invention aims to provide a disinfection and purification device and a purification method thereof, which are used for respectively carrying out charged atomization disinfection and purification and deep photocatalytic purification on gas in a box body, purifying the gas in the environment, and the discharged gas is harmless, can be used in the environment with people, and has the characteristics of disinfection and deodorization, continuous purification, high safety and the like.
To achieve the purpose, the invention adopts the following technical scheme:
in a first aspect, the present invention provides a disinfection and purification apparatus, where the disinfection and purification apparatus includes a case, and a filtration unit, a disinfection and purification unit, and a photocatalytic deep purification unit are sequentially disposed in the case along a gas flow direction.
The disinfection and purification unit comprises a charged spraying device and at least two porous honeycomb plates, the charged spraying device sprays charged spraying into the box body, the porous honeycomb plates are staggered to form a baffling channel, an ultrasonic transduction device is arranged on each porous honeycomb plate, and the ultrasonic transduction device is used for atomizing liquid on the porous honeycomb plates.
According to the invention, the disinfection and purification unit and the photocatalysis deep purification unit are arranged, the disinfection and purification unit is used for carrying out charged atomization on disinfection and purification liquid by using the charged spraying device, then the ultrasonic transduction device is used for carrying out secondary atomization on the disinfection and purification liquid distributed on the porous honeycomb plate, the disinfection and purification liquid is converted into charged fog drops, the dispersion effect of the liquid drops is improved, the combination of the charged fog drops and pollutants is improved, so that the disinfection and purification effect is improved, the photocatalysis deep purification is further utilized, the photocatalysis efficiency is effectively improved, the depth elimination of byproducts and residual pollutants generated by atomization and disinfection is carried out, the harmless effect of discharged gas is ensured, the continuous purification of the gas in the environment is realized, the harm to human bodies is avoided, and the device has the characteristics of simple structure, continuous purification, disinfection and deodorization, high purification efficiency and the like.
It should be noted that, the box body in the invention can be an integral structure or a split structure, and a person skilled in the art adjusts the box body according to the adaptability of the use environment, for example, each unit independently uses one box body, and the box bodies are in butt joint; or each unit is arranged in a box body.
In addition, if a small amount of ozone is generated in the charging process, the small amount of ozone can improve the pollutant removal effect and is consumed and removed in the disinfection process, and the ozone is also consumed in the photocatalysis process, so that no ozone is generated in the charging spray process, or only a small amount of ozone is generated, and the ozone can be completely consumed in the disinfection and purification process.
As a preferable technical scheme of the invention, the charged spraying device comprises at least one charged nozzle arranged between the porous honeycomb plates, and the charged nozzle is used for spraying charged mist drops of the disinfection and purification liquid into the box body.
Preferably, the charging nozzle comprises an atomizing nozzle and an annular electrode, the annular electrode is electrically connected with a direct current power supply, the annular electrode is annularly arranged at the spraying end of the atomizing nozzle, and fog drops sprayed by the atomizing nozzle are sprayed into the annular electrode for charging.
Preferably, the charged mist droplets ejected from the charged spraying device have a positive charge type.
Preferably, a current regulator is arranged on a wire connected with the direct-current power supply through the annular electrode.
As a preferred technical scheme of the invention, the porous honeycomb plate comprises a core plate provided with honeycomb cavities and cover plates arranged on two side surfaces of the core plate, wherein through holes are distributed on the cover plates, and the honeycomb cavities are filled with renewable filter particles.
Preferably, the material of the renewable filtering particles comprises shale ceramsite, fly ash ceramsite, diatomite ceramsite, volcanic rock particles or glass beads.
According to the invention, the renewable filtering particles are arranged in the honeycomb cavities, when gas enters the baffling channel, part of the gas can enter the honeycomb cavities for filtering and sterilizing, and further, the renewable filtering particles are combined with the ultrasonic transduction device to vibrate and disperse in the honeycomb cavities, so that the sterilizing and purifying liquid gathered in the honeycomb cavities is dispersed, and a high-concentration purifying cavity is formed in each honeycomb cavity, and pollutants enter the honeycomb cavities for deep filtering and sterilizing.
According to the invention, the charged nozzle is adopted to atomize the disinfection and purification liquid once, part of the disinfection and purification liquid is attached to the porous honeycomb plate and enters the honeycomb cavity, the ultrasonic transduction device is arranged on the porous honeycomb plate, so that the disinfection and purification liquid attached to the porous honeycomb plate is atomized, and the deep filtration and purification cavity can be formed in the honeycomb cavity; in addition, through the gas in the honeycomb cavity and the flow direction in the baffling channel are staggered, the turbulence effect of the gas is improved, and the dispersibility is further improved.
Preferably, the surface of the regenerable filter particles is loaded with a titania-based photocatalytic material.
Preferably, the porous honeycomb plate is detachably arranged on the box body.
According to the invention, the porous honeycomb plate is detachably arranged, if the purifying effect is poor after the device runs for a period of time, the porous honeycomb plate can be taken out and replaced, and the low-cost renewable filter particles are adopted to load the titanium dioxide-based photocatalysis self-cleaning material, so that organic matters and bacterial viruses adsorbed on the surface can be removed directly through sunlight irradiation, and the recycling is realized.
Preferably, the box body is provided with a socket, a porous honeycomb plate is inserted into the socket, a sealing structure is arranged at the joint of the porous honeycomb plate and the box body, and the porous honeycomb plate is inserted into the socket to be detachably connected.
As a preferable technical scheme of the invention, the charged spraying device is connected to a liquid storage tank, and the liquid storage tank is filled with disinfection and purification liquid.
Preferably, the disinfection and purification liquid comprises one or a combination of at least two of hydrogen peroxide, peracetic acid or hypochlorous acid.
Preferably, a sample injection pump is arranged on a pipeline connected with the liquid storage tank of the charged spraying device.
Preferably, the bottom of the box body positioned in the disinfection and purification unit is connected with a collecting pipeline, the collecting pipeline is connected with a buffer tank, and the buffer tank is connected with the liquid storage tank.
According to the invention, the disinfection and purification liquid accumulated at the bottom of the tank body is recovered by arranging the collecting pipeline, and further the detection can be performed through the liquid collected to the buffer tank, and if the use requirement is met, the liquid can be directly returned to the liquid storage tank for use, so that the occurrence of the volume liquid of the tank is avoided, and the use efficiency of the disinfection and purification liquid is improved.
As a preferred embodiment of the present invention, the liquid atomizing size of the ultrasonic transducer is 1 μm to 10. Mu.m, for example, 1 μm, 2 μm, 3 μm, 4 μm, 5 μm, 6 μm, 7 μm, 8 μm, 9 μm or 10. Mu.m.
Preferably, the filtering unit comprises at least one layer of antibacterial filter screen detachably arranged in the box body;
preferably, the antibacterial filter screen comprises one or a combination of at least two of an antibacterial copper-based filter screen, an antibacterial silver-based metal filter screen or an antibacterial nylon filter screen.
According to the invention, the antibacterial filter screen which is detachably arranged is arranged, so that the particles in the air to be disinfected and purified can be filtered, meanwhile, the bacteria and viruses adsorbed on the surfaces of the particles can be killed, secondary pollution is prevented, and the air purifier can be conveniently detached and replaced.
As a preferable technical scheme of the invention, the photocatalysis deep purifying unit comprises at least two porous substrates which are sequentially arranged along the gas flow direction, wherein the porous substrates are staggered to form baffling channels, and a light source is arranged between the adjacent porous substrates.
Preferably, the porous substrate is provided with a photocatalyst.
It should be noted that the porous substrate in the present invention is made of a porous material, and has a pore structure for supporting a catalyst.
Preferably, the porous substrate comprises porous ceramics and/or foam metal.
Preferably, the photocatalyst comprises a titania-based photocatalytic material.
According to the invention, the photocatalyst is loaded on the porous substrate, so that the load of the photocatalyst and the contact time of pollutants and the photocatalyst can be improved, the low-concentration disinfection and purification byproducts generated by the disinfection and purification unit are catalytically decomposed, and in addition, the combination of the photocatalytic reaction and the disinfection and purification liquid plays an enhancement role, so that the byproducts and the low-concentration harmful gases are further removed.
Preferably, the wavelength of the light source is not less than 365nm, for example 365nm, 370nm, 380nm, 390nm, 400nm or 500nm.
According to the invention, the wavelength of the light source is controlled to be more than or equal to 365nm, ozone is not generated in the process of photocatalytic reaction between the light source and the photocatalyst in the wavelength range, so that the harm of ozone emission to human bodies is reduced, and the effect of deep purification can be achieved without ozone in the purification treatment process.
As a preferable technical scheme of the invention, turbulence structures are arranged in the baffle channels at intervals.
Preferably, the spoiler structure comprises a spoiler or a spoiler blade.
As a preferred technical scheme of the invention, the disinfection and purification device comprises a gas circulation unit, wherein the gas circulation unit comprises a circulation fan, the circulation fan is connected with a gas outlet of the box body, and the circulation fan drives gas to enter a gas inlet of the box body and sequentially flow through a filtering unit, a disinfection and purification unit and a photocatalysis deep purification unit to be discharged from the gas outlet of the box body.
It should be noted that the specific form of the circulating fan is not required or limited in the invention, and those skilled in the art can reasonably set the circulating fan according to the application environment, for example, the circulating fan is a mute fan.
Preferably, the disinfection and purification device further comprises a detection control unit, the detection control unit comprises a detection module and a control module, the detection module is used for detecting the working parameters of the disinfection and purification device, and the control module is used for adjusting the working parameters of the disinfection and purification device.
Preferably, the detection module comprises a temperature and humidity monitoring sensor, a photoionization total volatile organic compound detection sensor, an electrochemical formaldehyde detection sensor, a fluorescent microorganism aerogel detection sensor and a voltage sensor, and the temperature, the humidity, the concentration of volatile organic compounds, the concentration of formaldehyde, the total number of bacterial colonies in gas and the working voltage of the annular electrode of the gas outlet on the box body are respectively detected.
Preferably, the control module is electrically connected with the detection module, the ultrasonic transduction device, the charged spraying device, the light source, the circulating fan and the current regulator respectively, and receives the detection signal of the detection module, and feeds back and controls the power of the ultrasonic transduction device, the liquid inlet speed of the charged spraying device, the regulation of the light source, the wind speed of the circulating fan and the size of the current regulator.
The invention automatically monitors and automatically controls the disinfection and purification device by arranging the control module and the detection module, monitors the concentration of pollutants by the pollutant on-line monitoring technology, automatically controls the operation of each unit by feeding back in real time, simultaneously records the disinfection process, avoids the disinfection omission caused by manual operation, ensures the disinfection and purification effect, and regulates and controls the working voltage of the annular electrode to ensure that ozone is not generated in the disinfection process.
Preferably, the detection control unit is further electrically connected with a communication module, and the communication module is provided with a remote control terminal, and the remote control terminal is used for receiving the detection signal of the detection control unit and sending a control signal to the control module.
In a second aspect, the present invention provides a method for sterilizing and purifying a gas, the method for sterilizing and purifying a gas using the sterilizing and purifying apparatus according to the first aspect, the method for sterilizing and purifying a gas comprising:
the gas is filtered by the filtering unit and then enters the disinfection and purification unit, the disinfection and purification liquid is sprayed by charge and then is dispersed into the baffling channel, the ultrasonic transduction device atomizes and disperses the disinfection and purification liquid on the porous honeycomb plate, and the gas and the atomized disinfection and purification liquid react and charge and then enter the photocatalysis deep purification unit to carry out photocatalysis reaction, so that the disinfection and purification of the gas are completed.
As a preferred technical scheme of the invention, the method for sterilizing and purifying the gas specifically comprises the following steps:
under the suction effect of a circulating fan, the gas enters a baffling channel of a disinfection and purification unit after filtration, a charged nozzle sprays charged fog drops of disinfection and purification liquid to a porous honeycomb plate, an ultrasonic transduction device atomizes the disinfection and purification liquid on the surface of the porous honeycomb plate, the gas contacts with the gas in the baffling channel to carry out disinfection and purification, and part of the gas enters a honeycomb cavity to contact with renewable filtering particles to carry out ultrasonic filtration and disinfection;
and (II) the positively charged gas discharged in the step (I) enters a baffling channel of the photocatalysis deep purifying unit, and is subjected to deep purification under the action of illumination to finish the disinfection and purification of the gas.
Preferably, the gas discharged from the step (I) comprises a purification by-product.
Preferably, the purification by-products comprise one or a combination of at least two of a pyrogen, bacteriocin, toxin, acetic acid, oxidized volatile organic aerosol or phenol.
Preferably, the volume concentration of the purge by-product in the gas discharged from step (I) is 1ppb to 100ppm, for example 1ppb, 10ppb, 100ppb, 1ppm, 10ppm, 20ppm, 30ppm, 40ppm, 50ppm, 60ppm, 70ppm, 80ppm, 90ppm or 100ppm.
The numerical ranges recited herein include not only the above-listed point values, but also any point values between the above-listed numerical ranges that are not listed, and are limited in space and for the sake of brevity, the present invention is not intended to be exhaustive of the specific point values that the stated ranges include.
Compared with the prior art, the invention has the beneficial effects that:
according to the invention, the disinfection and purification unit and the photocatalysis deep purification unit are arranged, the disinfection and purification unit is used for carrying out charged atomization on disinfection and purification liquid by using the charged spraying device, then the ultrasonic transduction device is used for carrying out secondary atomization on the disinfection and purification liquid distributed on the porous honeycomb plate, the disinfection and purification liquid is converted into charged fog drops, the dispersion effect of the liquid drops is improved, the combination of the charged fog drops and pollutants is improved, so that the disinfection and purification effect is improved, the photocatalysis deep purification is further utilized, the photocatalysis efficiency is effectively improved, the depth elimination of byproducts and residual pollutants generated by atomization and disinfection is carried out, the harmless effect of discharged gas is ensured, the continuous purification of the gas in the environment is realized, the harm to human bodies is avoided, and the device has the characteristics of simple structure, continuous purification, disinfection and deodorization, high purification efficiency and the like.
Drawings
FIG. 1 is a schematic view of a sterilizing purifier according to an embodiment of the present invention;
FIG. 2 is a schematic view of a charging nozzle according to an embodiment of the present invention;
FIG. 3 is a schematic cross-sectional view of a porous honeycomb panel provided in one embodiment of the invention;
FIG. 4 is a graph showing the results of the tests of formaldehyde concentration and total volatile organic compound concentration provided in the application example of the present invention;
FIG. 5 is a graph showing the results of the total colony count test provided in the application example of the present invention.
Wherein, 1-the box body; 2-a filtration unit; 3-a disinfection and purification unit; 4-a photocatalytic deep purification unit; 5-porous honeycomb panel; 6-charging nozzles; 7-a liquid storage tank; 8-a light source; 9-a porous substrate; 10-turbulence structure; 11-a detection control unit; 12-gas inlet; 13-gas outlet; 14-atomizing nozzles; 15-a ring electrode; 16-direct current power supply; 17-core plate; 18-cover plate; 19-regenerable filter particles.
Detailed Description
It is to be understood that in the description of the present invention, the terms "center", "longitudinal", "lateral", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", etc. indicate orientations or positional relationships based on the drawings, are merely for convenience in describing the present invention and simplifying the description, and do not indicate or imply that the devices or elements referred to must have a specific orientation, be configured and operated in a specific orientation, and thus are not to be construed as limiting the present invention.
It should be noted that, in the description of the present invention, unless explicitly specified and limited otherwise, the terms "disposed," "connected," and "connected" are to be construed broadly, and may be, for example, fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; can be directly connected or indirectly connected through an intermediate medium, and can be communication between two elements. The specific meaning of the above terms in the present invention can be understood by those of ordinary skill in the art in a specific case.
It will be appreciated by those skilled in the art that the present invention necessarily includes the necessary piping, conventional valves and general pumping equipment for achieving process integrity, but the foregoing is not a major innovation of the present invention, and that the present invention is not particularly limited thereto as the layout may be added by themselves based on the process flow and the equipment configuration options.
The technical scheme of the invention is further described by the following specific embodiments.
In one embodiment, as shown in fig. 1, the invention provides a disinfection and purification device, which comprises a box body 1, wherein a filtering unit 2, a disinfection and purification unit 3 and a photocatalysis deep purification unit 4 are sequentially arranged in the box body 1 along the gas flow direction.
The disinfection and purification unit 3 comprises a charged spraying device and at least two porous honeycomb plates 5, the charged spraying device sprays charged spraying into the box body 1, the porous honeycomb plates 5 are staggered to form a baffling channel, an ultrasonic transduction device is arranged on the porous honeycomb plates 5, and the ultrasonic transduction device is used for atomizing liquid on the porous honeycomb plates 5.
Alternatively, the case 1 may be a one-piece structure or a split structure, for example, each unit independently uses one case 1, and the case 1 is in butt joint with the case 1; or each unit is provided in one of the cases 1.
In a specific embodiment, the charged spraying device carries out charging in an induction charging mode, so that ozone generation is avoided. Specifically, as shown in fig. 2, the charged spraying device includes at least one charged nozzle 6 disposed between the porous honeycomb plates 5, and the charged nozzle 6 is used for spraying charged mist droplets of the disinfection and purification liquid into the tank 1. Further, the charging nozzle 6 includes an atomizing nozzle 14 and an annular electrode 15, the annular electrode 15 is electrically connected with a dc power supply 16, the annular electrode 15 is annularly disposed at the spraying end of the atomizing nozzle 14, and the mist droplets sprayed from the atomizing nozzle 14 are sprayed into the annular electrode 15 for charging. Further, the charged mist droplets ejected from the charged spraying device are positively charged, and a current regulator is arranged on a wire connecting the ring electrode 15 and the dc power supply 16.
Specifically, as shown in fig. 3, the porous honeycomb panel 5 includes a core plate 17 provided with honeycomb cavities, and cover plates 18 provided on both side surfaces of the core plate 17, wherein through holes are spread over the cover plates 18, and the honeycomb cavities are filled with regenerable filter particles 19; according to the invention, the renewable filtering particles 19 are arranged in the honeycomb cavity, and the renewable filtering particles 19 are made of shale ceramsite, fly ash ceramsite, diatomite ceramsite, volcanic rock particles or glass beads. When the gas enters the baffling channel, part of the gas can enter the honeycomb cavity for filtration and disinfection, and further, the ultrasonic transduction device is combined, the renewable filtering particles 19 vibrate and disperse in the honeycomb cavity to disperse the disinfection and purification liquid gathered in the honeycomb cavity, so that a high-concentration purification cavity is formed in each honeycomb cavity, and pollutants enter the honeycomb cavity for deep filtration and disinfection.
According to the invention, the charge nozzle 6 is adopted to atomize the disinfection and purification liquid once, part of the disinfection and purification liquid is attached to the porous honeycomb plate 5 and enters the honeycomb cavity, the ultrasonic transduction device is arranged on the porous honeycomb plate 5, so that the disinfection and purification liquid attached to the porous honeycomb plate 5 is atomized, and the deep filtration and purification cavity can be formed in the honeycomb cavity; in addition, through the gas in the honeycomb cavity and the flow direction in the baffling channel are staggered, the turbulence effect of the gas is improved, and the dispersibility is further improved.
Specifically, the surface of the renewable filtering particles 19 is loaded with titanium dioxide-based photocatalytic materials, the porous honeycomb plate 5 is detachably arranged on the box body 1, a socket is formed in the box body 1, the porous honeycomb plate 5 is inserted into the socket, a sealing structure is arranged at the joint of the porous honeycomb plate 5 and the box body 1, and the porous honeycomb plate 5 is inserted into the socket to be detachably connected. According to the invention, the porous honeycomb plate 5 is detachably arranged, if the purifying effect is poor after the device is operated for a period of time, the porous honeycomb plate 5 can be taken out and replaced, and the surface of the renewable filtering particles 19 is loaded with the titanium dioxide-based photocatalysis self-cleaning material, so that partial organic matters and bacterial viruses adsorbed on the surface can be removed by sunlight irradiation, and the recycling is realized.
Specifically, the charge spraying device is connected to a liquid storage tank 7, disinfection and purification liquid is injected into the liquid storage tank 7, and a sample injection pump is arranged on a pipeline connected with the charge spraying device and the liquid storage tank 7; further, a collecting pipeline is connected to the bottom of the tank body 1 located at the disinfection and purification unit 3, the collecting pipeline is connected to a buffer tank, the buffer tank is connected to the liquid storage tank 7, and the disinfection and purification liquid comprises one or a combination of at least two of hydrogen peroxide, peracetic acid or hypochlorous acid.
According to the invention, the disinfection and purification liquid accumulated at the bottom of the box body 1 is recovered by arranging the collecting pipeline, and further the detection can be performed through the liquid collected to the buffer tank, and if the use requirement is met, the liquid can be directly returned to the liquid storage tank 7 for use, so that the occurrence of the liquid accumulation of the box body 1 is avoided, and the use efficiency of the disinfection and purification liquid is improved.
Specifically, the liquid atomization size of the ultrasonic transduction device is 1-10 μm.
Specifically, the filtering unit 2 includes at least one layer of antibacterial filter screen detachably disposed in the case 1, and further, the antibacterial filter screen includes one or a combination of at least two of an antibacterial copper-based filter screen, an antibacterial silver-based metal filter screen, or an antibacterial nylon filter screen. According to the invention, the antibacterial filter screen which is detachably arranged is arranged, so that the particles in the air to be disinfected and purified can be filtered, meanwhile, the bacteria and viruses adsorbed on the surfaces of the particles can be killed, secondary pollution is prevented, and the air purifier can be conveniently detached and replaced.
Specifically, the photocatalytic deep purification unit 4 comprises at least two porous substrates 9 sequentially arranged along the gas flow direction, the porous substrates 9 are staggered to form baffling channels, a light source 8 is arranged between adjacent porous substrates 9, and a photocatalyst is arranged on the porous substrates 9; further, the porous substrate 9 may be made of porous ceramics and/or foam metal, and the photocatalyst may be made of titanium dioxide-based photocatalytic material.
According to the invention, the photocatalyst is supported on the porous substrate 9, so that the load of the photocatalyst and the contact time of pollutants and the photocatalyst can be improved, the low-concentration disinfection and purification byproducts generated by the disinfection and purification unit 3 are catalytically decomposed, and in addition, the combination of the photocatalytic reaction and the disinfection and purification liquid plays an enhancement role, so that the further removal of the byproducts and the low-concentration harmful gases is realized.
Specifically, the wavelength of the light source 8 is more than or equal to 365nm. According to the invention, the wavelength of the light source 8 is controlled to be more than or equal to 365nm, in the wavelength range, ozone is not generated in the process of the photocatalytic reaction between the light source 8 and the photocatalyst, so that the harm of ozone emission to human bodies is reduced, and the effect of deep purification can be achieved without ozone in the purification treatment process.
Specifically, turbulence structures 10 are arranged in the baffle channels at intervals; further, the spoiler structure 10 includes a spoiler or a spoiler blade.
Specifically, the disinfection and purification device comprises a gas circulation unit, the gas circulation unit comprises a circulation fan, the circulation fan is connected into a gas outlet 13 of the box body 1, the circulation fan drives gas to enter a gas inlet 12 of the box body 1 and sequentially flows through the filtering unit 2, the disinfection and purification unit 3 and the photocatalysis deep purification unit 4, and is discharged from the gas outlet 13 of the box body 1.
Specifically, the disinfection and purification device further comprises a detection control unit 11, the detection control unit 11 comprises a detection module and a control module, the detection module is used for detecting the working parameters of the disinfection and purification device, and the control module is used for adjusting the working parameters of the disinfection and purification device.
Further, the detection module includes a temperature and humidity monitoring sensor, a photoionization total volatile organic compound detection sensor, an electrochemical formaldehyde detection sensor, a fluorescent microorganism aerogel detection sensor and a voltage sensor, and detects the temperature, humidity, volatile organic compound concentration, formaldehyde concentration, total number of bacterial colonies in the gas and working voltage of the ring electrode 15 of the gas outlet 13 on the box body 1 respectively.
Further, the control module is electrically connected with the detection module, the ultrasonic transduction device, the charged spraying device, the light source 8, the circulating fan and the current regulator respectively, and receives detection signals of the detection module, and feeds back and controls the power of the ultrasonic transduction device, the liquid inlet speed of the charged spraying device, the adjustment of the light source 8, the wind speed of the circulating fan and the current regulator.
The invention automatically monitors and automatically controls the sterilizing and purifying device by arranging the control module and the detection module, monitors the concentration of pollutants by the pollutant on-line monitoring technology, automatically controls the operation of each unit by feeding back in real time, simultaneously records the sterilizing process, avoids sterilizing omission caused by manual operation, ensures the sterilizing and purifying effect, and regulates and controls the working voltage of the annular electrode 15 to ensure that ozone is not generated in the sterilizing process.
Specifically, the detection control unit 11 is further electrically connected to a communication module, and the communication module is provided with a remote control terminal, and the remote control terminal is configured to receive the detection signal of the detection control unit 11 and send a control signal to the control module.
In another embodiment, the invention provides a method for sterilizing and purifying gas, which adopts the sterilizing and purifying device, and specifically comprises the following steps:
under the suction effect of a circulating fan, the gas enters a baffling channel of a disinfection and purification unit 3 after being filtered, a charged nozzle 6 sprays charged fog drops of disinfection and purification liquid to a porous honeycomb plate 5, an ultrasonic transduction device atomizes the disinfection and purification liquid on the surface of the porous honeycomb plate 5, the gas contacts with the charge in the baffling channel to disinfect and purify, and part of the gas enters a honeycomb cavity to contact with renewable filtering particles 19 to carry out ultrasonic filtration and disinfection;
step (II), discharging positively charged gas, wherein the discharged gas comprises purification byproducts, and the purification byproducts enter a baffling channel of a photocatalysis deep purification unit 4 to be deeply purified under the action of illumination so as to finish the disinfection and purification of the gas;
wherein the purification by-product comprises one or a combination of at least two of pyrogen, bacteriocin, toxin, acetic acid, oxidized volatile organic aerosol or phenol, and the volume concentration of the purification by-product is 1 ppb-100 ppm.
Application example
The application example provides an application of the disinfection and purification device provided in one specific embodiment to purifying gas, wherein the application is 30m 3 In the room, the formaldehyde concentration, the total volatile organic compound concentration and the total colony count in the environment gas are detected every ten minutes, the test results are respectively shown in fig. 4 and 5, it can be seen that the requirements of the room air microorganisms on the environment are met after 20 minutes, and the colonies in the environment are basically removed after 60 minutes.
According to the invention, through a specific implementation mode and an application example, the disinfection and purification unit 3 and the photocatalysis deep purification unit 4 are arranged, the disinfection and purification unit 3 is used for carrying out charged atomization on disinfection and purification liquid by using a charged spraying device, then the disinfection and purification liquid distributed on the porous honeycomb plate 5 is subjected to secondary atomization by using an ultrasonic transduction device, the disinfection and purification liquid is converted into charged fog drops, so that the dispersion effect of the liquid drops is improved, the combination of the charged fog drops with pollutants is improved, the disinfection and purification effect is improved, the photocatalysis deep purification is further used, the photocatalysis efficiency is effectively improved by combining the charged fog drops, the byproducts and residual pollutants generated by atomization and disinfection are deeply eliminated, the discharged gas is ensured to be harmless, the gas in the environment is continuously purified, the harm to human body is avoided, and the characteristics of simple structure, continuous purification, disinfection and deodorization, high purification efficiency and the like are realized.
The applicant declares that the above is only a specific embodiment of the present invention, but the scope of the present invention is not limited thereto, and it should be apparent to those skilled in the art that any changes or substitutions that are easily conceivable within the technical scope of the present invention disclosed by the present invention fall within the scope of the present invention and the disclosure.
Claims (27)
1. The disinfection and purification device is characterized by comprising a box body, wherein a filtering unit, a disinfection and purification unit and a photocatalysis deep purification unit are sequentially arranged in the box body along the gas flow direction;
the disinfection and purification unit comprises a charged spraying device and at least two porous honeycomb plates, wherein the charged spraying device sprays charged spraying into the box body, the porous honeycomb plates are staggered to form baffling channels, an ultrasonic transduction device is arranged on each porous honeycomb plate, and the ultrasonic transduction device is used for atomizing liquid on the porous honeycomb plates;
the charged spraying device comprises at least one charged nozzle arranged between the porous honeycomb plates, and the charged nozzle is used for spraying charged fog drops of disinfection and purification liquid into the box body; the charge type of the charged mist drops sprayed by the charged spraying device is positive; the charged spraying device is connected to a liquid storage tank, and disinfection and purification liquid is injected into the liquid storage tank; the disinfection and purification liquid comprises one or a combination of at least two of hydrogen peroxide, peracetic acid or hypochlorous acid;
the porous honeycomb plate comprises a core plate provided with honeycomb cavities and cover plates arranged on the surfaces of two sides of the core plate, through holes are distributed on the cover plates, and the honeycomb cavities are filled with renewable filtering particles;
the photocatalysis deep purification unit comprises at least two porous substrates which are sequentially arranged along the gas flow direction, wherein the porous substrates are staggered to form baffling channels, and a light source is arranged between every two adjacent porous substrates; the porous substrate is provided with a photocatalyst.
2. The disinfection and purification apparatus of claim 1, wherein the charging nozzle comprises an atomizing nozzle and an annular electrode, the annular electrode is electrically connected with a dc power supply, the annular electrode is annularly arranged at the spraying end of the atomizing nozzle, and mist droplets sprayed from the atomizing nozzle are sprayed into the annular electrode for charging.
3. A disinfection and purification apparatus as claimed in claim 2, wherein said ring electrode is provided with a current regulator on a wire connected to a dc power supply.
4. The disinfection and purification apparatus of claim 1, wherein said renewable filter particles comprise shale ceramisites, fly ash ceramisites, diatomaceous earth ceramisites, volcanic rock particles or glass microspheres.
5. A disinfection and purification apparatus as claimed in claim 1, wherein the surface of said regenerable filter particles is loaded with a titania-based photocatalytic material.
6. The disinfection and purification apparatus of claim 1, wherein said porous honeycomb panel is removably disposed on a housing.
7. The disinfection and purification apparatus of claim 1, wherein the housing is provided with a socket, a porous honeycomb plate is inserted into the socket, a sealing structure is provided at a joint of the porous honeycomb plate and the housing, and the porous honeycomb plate is inserted into the socket to be detachably connected.
8. The disinfection and purification apparatus of claim 1, wherein a sample pump is provided on a line connecting the charged spray apparatus and the reservoir.
9. The disinfection and purification apparatus of claim 1, wherein the bottom of the tank body in the disinfection and purification unit is connected with a collecting pipeline, the collecting pipeline is connected to a buffer tank, and the buffer tank is connected to the liquid storage tank.
10. The disinfection and purification apparatus of claim 1, wherein the ultrasonic transducer has a liquid atomizing size of 1 μm to 10 μm.
11. A disinfection and purification apparatus as claimed in claim 1, wherein said filter unit comprises at least one layer of antimicrobial filter mesh removably arranged in said housing.
12. The disinfection and purification apparatus of claim 11, wherein said antimicrobial filter comprises one or a combination of at least two of an antimicrobial copper-based filter, an antimicrobial silver-based metal filter, or an antimicrobial nylon filter.
13. A disinfection and purification apparatus as claimed in claim 1, wherein the porous substrate comprises porous ceramic and/or metal foam.
14. A disinfection and purification apparatus as claimed in claim 13, wherein said photocatalyst comprises a titania-based photocatalytic material.
15. A disinfection and purification apparatus as claimed in claim 1, wherein the wavelength of said light source is at least 365nm.
16. The disinfection and purification apparatus of claim 1, wherein turbulence structures are provided in the baffle channels at intervals.
17. The decontamination apparatus of claim 16, wherein the turbulence structures comprise turbulence baffles or turbulence blades.
18. The disinfection and purification apparatus of claim 1, wherein the disinfection and purification apparatus comprises a gas circulation unit comprising a circulation fan, the circulation fan being connected to the gas outlet of the tank, the circulation fan driving gas into the gas inlet of the tank and flowing through the filtration unit, the disinfection and purification unit and the photocatalytic deep purification unit in that order, being discharged from the gas outlet of the tank.
19. The decontamination apparatus of claim 1, further comprising a detection control unit comprising a detection module for detecting an operating parameter of the decontamination apparatus and a control module for adjusting an operating parameter of the decontamination apparatus.
20. The decontamination apparatus of claim 19, wherein said detection module comprises a temperature and humidity sensor, a photo-ionization total volatile organic compound sensor, an electrochemical formaldehyde sensor, a fluorescent microbial aerogel sensor, and a voltage sensor, which respectively detect the temperature, humidity, volatile organic compound concentration, formaldehyde concentration, total number of colonies in the gas, and the operating voltage of the ring electrode at the gas outlet on said housing.
21. The disinfection and purification apparatus of claim 19, wherein said control module is electrically connected to said detection module, said ultrasonic transducer, said charged spray device, said light source, said circulating fan, and said current regulator, respectively, and said control module receives said detection signals from said detection module and feedback controls the power of said ultrasonic transducer, the liquid feed rate of said charged spray device, the regulation of said light source, the wind speed of said circulating fan, and the magnitude of said current regulator.
22. The disinfection and purification apparatus of claim 19, wherein said detection control unit is further electrically connected to a communication module, said communication module being provided with a remote control terminal for receiving the detection signal of the detection control unit and transmitting a control signal to the control module.
23. A method of disinfecting and purifying a gas, wherein the method of disinfecting and purifying a gas employs the disinfecting and purifying apparatus according to any one of claims 1 to 22, the method of disinfecting and purifying a gas comprising:
the gas is filtered by the filtering unit and then enters the disinfection and purification unit, the disinfection and purification liquid is sprayed by charge and then is dispersed into the baffling channel, the ultrasonic transduction device atomizes and disperses the disinfection and purification liquid on the porous honeycomb plate, and the gas and the atomized disinfection and purification liquid react and charge and then enter the photocatalysis deep purification unit to carry out photocatalysis reaction, so that the disinfection and purification of the gas are completed.
24. A method of disinfection and purification of a gas according to claim 23, characterized in that said method of disinfection and purification of a gas comprises in particular the steps of:
under the suction effect of a circulating fan, the gas enters a baffling channel of a disinfection and purification unit after filtration, a charged nozzle sprays charged fog drops of disinfection and purification liquid to a porous honeycomb plate, an ultrasonic transduction device atomizes the disinfection and purification liquid on the surface of the porous honeycomb plate, the gas contacts with the gas in the baffling channel to carry out disinfection and purification, and part of the gas enters a honeycomb cavity to contact with renewable filtering particles to carry out ultrasonic filtration and disinfection;
and (II) the positively charged gas discharged in the step (I) enters a baffling channel of the photocatalysis deep purifying unit, and is subjected to deep purification under the action of illumination to finish the disinfection and purification of the gas.
25. The method of claim 24, wherein the gas exhausted from step (i) comprises purge byproducts.
26. The method of claim 25, wherein the purification by-products comprise one or a combination of at least two of pyrogens, bacteriocins, toxins, acetic acid, oxidized volatile organic aerosols, or phenols.
27. The method of claim 25, wherein the volume concentration of the purification by-product in the gas exhausted from step (i) is 1ppb to 100ppm.
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