CN114410049A - High-weather-resistance synthetic polymer waterproof coiled material and preparation method thereof - Google Patents

High-weather-resistance synthetic polymer waterproof coiled material and preparation method thereof Download PDF

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Publication number
CN114410049A
CN114410049A CN202210095625.5A CN202210095625A CN114410049A CN 114410049 A CN114410049 A CN 114410049A CN 202210095625 A CN202210095625 A CN 202210095625A CN 114410049 A CN114410049 A CN 114410049A
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preparation
parts
raw materials
synthetic polymer
extruder
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曲学平
李建芳
田继斌
张晓明
刘雪培
郭岩
包毓含
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Beijing Yuyangzeli Waterproof Material Co ltd
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Beijing Yuyangzeli Waterproof Material Co ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/06Elements
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

The invention provides a high weather-resistant synthetic polymer waterproof coiled material and a preparation method thereof, wherein the preparation method comprises the following steps: checking, checking whether water, electricity, heat conducting oil and the like can normally run before production, confirming that the water, electricity, heat conducting oil and the like meet production control requirements, checking used raw materials, confirming the quantity of the raw materials and ensuring that the quantity of the raw materials is in an effective period; preheating an extruder for 2 hours, wherein the preheating of the extruder comprises a screw, a die head and three rollers; mixing materials, weighing the polyurethane grafted acrylate polymer, the asphalt-based carbon fiber, the coupling agent, the antioxidant, the anti-aging agent and the softener according to a certain proportion, sequentially putting the components into a mixer, and mixing for 30-50 min. The high weather-resistant synthetic polymer waterproof coiled material and the preparation method thereof have the advantages of easily available raw materials, low price, simple and feasible preparation method, mild reaction conditions, low requirements on reaction equipment and suitability for industrial production.

Description

High-weather-resistance synthetic polymer waterproof coiled material and preparation method thereof
Technical Field
The invention relates to the field of waterproof coiled materials, and particularly discloses a high weather-resistant synthetic polymer waterproof coiled material and a preparation method thereof.
Background
The waterproof coiled material is mainly used for building walls, roofs, tunnels, highways, refuse landfills and the like, can be curled into a roll-shaped flexible building material product for resisting external rainwater and underground water leakage, is used as a leakage-free connection between an engineering foundation and a building, is a first barrier for waterproofing of the whole engineering, and plays a vital role in the whole engineering;
asphalt waterproof materials or polymer waterproof materials are soaked on a tire body, and the manufactured waterproof material product is provided in a roll form and is called a waterproof roll. According to different main composition materials, the waterproof material is divided into an asphalt waterproof coiled material, a high polymer modified asphalt waterproof coiled material and a synthetic polymer waterproof coiled material; the coiled materials are divided into coiled materials without a matrix, coiled materials with a paper matrix, coiled materials with a glass fiber matrix, coiled materials with a glass cloth matrix and coiled materials with a polyethylene matrix according to different matrixes.
The weather resistance of the existing waterproof coiled material is not ideal, so that a high weather resistance synthetic polymer waterproof coiled material and a preparation method thereof are provided.
Disclosure of Invention
In view of the above-mentioned defects or shortcomings in the prior art, the present application aims to provide a high weather-resistant synthetic polymer waterproof roll and a preparation method thereof, wherein the polymer waterproof roll is prepared from the following components in parts by weight: 100 parts of polyurethane grafted acrylic polymer, 5-7 parts of asphalt-based carbon fiber, 2-5 parts of coupling agent, 2-3 parts of antioxidant, 1-2 parts of anti-aging agent and 1-5 parts of softener.
Preferably, the preparation method comprises the following steps:
checking, checking whether water, electricity, heat conducting oil and the like can normally run before production, confirming that the water, electricity, heat conducting oil and the like meet production control requirements, checking used raw materials, confirming the quantity of the raw materials and ensuring that the quantity of the raw materials is in an effective period;
step two, preheating the extruder for 2 hours, wherein the preheating of the extruder comprises a screw, a die head and three rollers;
step three, mixing materials, namely weighing the polyurethane grafted acrylate polymer, the asphalt-based carbon fiber, the coupling agent, the antioxidant, the anti-aging agent and the softener according to a certain proportion, sequentially putting the components into a mixer, and mixing for 30-50 min;
adjusting the die heads, simultaneously starting the extruder, starting the three rollers, running at a low speed, and allowing the sheets to pass through the three rollers, a cooling transition frame and a cloth storage frame until the sheets are rolled;
adjusting at a low speed until the thickness of the sheet is uniform, preparing for normal production, and increasing the rotating speed of the extruder and the rotating speed of the corresponding three rollers;
step six, when the production is normal, detecting the thickness of the sheet, and when the thickness meets the standard requirement, informing a technical center to carry out first roll inspection together and recording;
seventhly, carrying out batch production after the first coil is detected to be qualified, detecting the temperature, the appearance, the thickness and the length every 1 hour, making a record, and conveying the coiled material to a semi-finished product area;
and step eight, performing performance detection on the finished product, packaging and warehousing.
Preferably, the coupling agent consists of two parts: a part is an inorganic group which can act with an inorganic filler or a reinforcing material; the other part is an organophilic group which can interact with the synthetic resin.
Preferably, the softening agent can be one of paraffin, cyclane, aromatic hydrocarbon and complex mixture composed of small amount of asphalt substance, nitrogen-containing organic base, etc.
Preferably, the pitch-based carbon fiber is prepared by using substances rich in polycyclic aromatic hydrocarbons, such as pitch, as raw materials through polymerization, spinning, infusibility and carbonization.
Has the advantages that: the high weather-resistant synthetic polymer waterproof coiled material and the preparation method thereof have the advantages of easily available raw materials, low price, simple and feasible preparation method, mild reaction conditions, low requirements on reaction equipment and suitability for industrial production. The waterproof coating has the advantages of higher tensile strength, higher tearing strength, better heat resistance, homogeneity, aging resistance, corrosion resistance, low-temperature flexibility, better weather resistance, lower price, more obvious waterproof effect, better use safety and more environmental protection, and simultaneously combines the advantages of polyurethane materials and acrylate materials, so that the adhesive force is strong, and the waterproof effect is more obvious.
Detailed Description
The present application will be described in further detail with reference to examples. It is to be understood that the specific embodiments described herein are merely illustrative of the relevant invention and not restrictive of the invention.
A high weather-resistant synthetic polymer waterproof coiled material and a preparation method thereof are disclosed, wherein the polymer waterproof coiled material is prepared from the following components in parts by weight: 100 parts of polyurethane grafted acrylic polymer, 5-7 parts of asphalt-based carbon fiber, 2-5 parts of coupling agent, 2-3 parts of antioxidant, 1-2 parts of anti-aging agent and 1-5 parts of softener.
Preferably, the preparation method comprises the following steps:
checking, checking whether water, electricity, heat conducting oil and the like can normally run before production, confirming that the water, electricity, heat conducting oil and the like meet production control requirements, checking used raw materials, confirming the quantity of the raw materials and ensuring that the quantity of the raw materials is in an effective period;
step two, preheating the extruder for 2 hours, wherein the preheating of the extruder comprises a screw, a die head and three rollers;
step three, mixing materials, namely weighing the polyurethane grafted acrylate polymer, the asphalt-based carbon fiber, the coupling agent, the antioxidant, the anti-aging agent and the softener according to a certain proportion, sequentially putting the components into a mixer, and mixing for 30-50 min;
adjusting the die heads, simultaneously starting the extruder, starting the three rollers, running at a low speed, and allowing the sheets to pass through the three rollers, a cooling transition frame and a cloth storage frame until the sheets are rolled;
adjusting at a low speed until the thickness of the sheet is uniform, preparing for normal production, and increasing the rotating speed of the extruder and the rotating speed of the corresponding three rollers;
step six, when the production is normal, detecting the thickness of the sheet, and when the thickness meets the standard requirement, informing a technical center to carry out first roll inspection together and recording;
seventhly, carrying out batch production after the first coil is detected to be qualified, detecting the temperature, the appearance, the thickness and the length every 1 hour, making a record, and conveying the coiled material to a semi-finished product area;
and step eight, performing performance detection on the finished product, packaging and warehousing.
Wherein, the coupling agent consists of two parts: a part is an inorganic group which can act with an inorganic filler or a reinforcing material; the other part is an organophilic group which can interact with the synthetic resin.
Wherein the softening agent can be one of complex mixtures composed of paraffin, cyclane, aromatic hydrocarbon, a small amount of asphaltic substances, nitrogen-containing organic alkali and the like.
Wherein, the pitch-based carbon fiber is prepared by using substances such as pitch and the like rich in polycyclic aromatic hydrocarbon as raw materials through polymerization, spinning, non-melting and carbonization.
The raw materials are easy to obtain, the price is low, the preparation method is simple and easy to implement, the reaction condition is mild, the requirement on reaction equipment is not high, and the method is suitable for industrial production. The waterproof coating has the advantages of higher tensile strength, higher tearing strength, better heat resistance, homogeneity, aging resistance, corrosion resistance, low-temperature flexibility, better weather resistance, lower price, more obvious waterproof effect, better use safety and more environmental protection, and simultaneously combines the advantages of polyurethane materials and acrylate materials, so that the adhesive force is strong, and the waterproof effect is more obvious.
Example 1
The polymer waterproof coiled material is prepared from the following components in parts by weight: 100 parts of polyurethane grafted acrylic polymer, 5 parts of asphalt-based carbon fiber, 3 parts of coupling agent, 3 parts of antioxidant, 1 part of anti-aging agent and 2 parts of softener.
Example 2
The polymer waterproof coiled material is prepared from the following components in parts by weight: 100 parts of polyurethane grafted acrylic polymer, 6 parts of asphalt-based carbon fiber, 5 parts of coupling agent, 3 parts of antioxidant, 2 parts of anti-aging agent and 3 parts of softener.
Example 3
When the high weather-resistant synthetic polymer waterproof coiled material is prepared, firstly, before production, point inspection is carried out, whether water, electricity, heat-conducting oil and the like can normally run is checked, the condition that the water, electricity, heat-conducting oil and the like meet the production control requirement is confirmed, the used raw materials are checked, the quantity of the raw materials is confirmed, and the quantity of the raw materials is ensured to be in the valid period; preheating an extruder for 2 hours, wherein the preheating of the extruder comprises a screw, a die head and three rollers; mixing materials, weighing the polyurethane grafted acrylate polymer, the asphalt-based carbon fiber, the coupling agent, the antioxidant, the anti-aging agent and the softener according to a certain proportion, sequentially putting the components into a mixer, and mixing for 36 min; adjusting the die head, simultaneously starting the extruder, starting the three rollers, running at a low speed, and allowing the sheet to pass through the three rollers, the cooling transition frame and the cloth storage frame until the sheet is rolled; adjusting at low speed until the thickness of the sheet is uniform, then preparing for normal production, and increasing the rotating speed of the extruder and the corresponding three-roller rotating speed; when the production is normal, detecting the thickness of the sheet, and when the thickness meets the standard requirement, informing a technical center to carry out first roll inspection together and recording; carrying out batch production after the first coil is detected to be qualified, detecting the temperature, the appearance, the thickness and the length every 1 hour, making a record, and conveying the coiled material to a semi-finished product area; and (5) carrying out performance detection on the finished product, and packaging and warehousing.
Wherein, the coupling agent consists of two parts: a part is an inorganic group which can act with an inorganic filler or a reinforcing material; the other part is an organophilic group which can react with synthetic resin, and the softening agent can be selected from paraffin, pitch-based carbon fiber which is prepared by taking substances rich in polycyclic aromatic hydrocarbon such as pitch as raw materials through polymerization, spinning, infusible and carbonization treatment.
Through detection, the thickness/mm of the resin layer on the upper surface of the intermediate fabric of the prepared waterproof coiled material is more than or equal to 0.4, and the maximum tensile force/N/cm is more than or equal to 250.
Example 4
When the high weather-resistant synthetic polymer waterproof coiled material is prepared, firstly, before production, point inspection is carried out, whether water, electricity, heat-conducting oil and the like can normally run is checked, the condition that the water, electricity, heat-conducting oil and the like meet the production control requirement is confirmed, the used raw materials are checked, the quantity of the raw materials is confirmed, and the quantity of the raw materials is ensured to be in the valid period; preheating an extruder for 2 hours, wherein the preheating of the extruder comprises a screw, a die head and three rollers; mixing materials, weighing the polyurethane grafted acrylate polymer, the asphalt-based carbon fiber, the coupling agent, the antioxidant, the anti-aging agent and the softener according to a certain proportion, sequentially putting the components into a mixer, and mixing for 50 min; adjusting the die head, simultaneously starting the extruder, starting the three rollers, running at a low speed, and allowing the sheet to pass through the three rollers, the cooling transition frame and the cloth storage frame until the sheet is rolled; adjusting at low speed until the thickness of the sheet is uniform, then preparing for normal production, and increasing the rotating speed of the extruder and the corresponding three-roller rotating speed; when the production is normal, detecting the thickness of the sheet, and when the thickness meets the standard requirement, informing a technical center to carry out first roll inspection together and recording; carrying out batch production after the first coil is detected to be qualified, detecting the temperature, the appearance, the thickness and the length every 1 hour, making a record, and conveying the coiled material to a semi-finished product area; and (5) carrying out performance detection on the finished product, and packaging and warehousing.
Wherein, the coupling agent consists of two parts: a part is an inorganic group which can act with an inorganic filler or a reinforcing material; the other part is an organophilic group which can react with synthetic resin, and the softening agent can be selected from paraffin, pitch-based carbon fiber which is prepared by taking substances rich in polycyclic aromatic hydrocarbon such as pitch as raw materials through polymerization, spinning, infusible and carbonization treatment.
Through detection, the thickness/mm of the resin layer on the upper surface of the intermediate fabric of the prepared waterproof coiled material is more than or equal to 0.5, and the maximum tension/N/cm is more than or equal to 260.
Example 5
The equipment preheating comprises a screw, a die head and three rollers, the preheating time is 2 hours, and the preheating and production temperature is set as follows:
interval of screw Region 1 Zone 2 Zone 3 Zone 4 Zone 5 Zone 6 Zone 7
Temperature of 170-190 170-190 170-190 170-190 170-190 170-190 170-190
Figure RE-GDA0003542312340000071
It should be noted that the embodiments and features of the embodiments in the present application may be combined with each other without conflict.
The above description is only a preferred embodiment of the application and is illustrative of the principles of the technology employed. It will be appreciated by a person skilled in the art that the scope of the invention as referred to in the present application is not limited to the embodiments with a specific combination of the above-mentioned features, but also covers other embodiments with any combination of the above-mentioned features or their equivalents without departing from the inventive concept. For example, the above features may be replaced with (but not limited to) features having similar functions disclosed in the present application.

Claims (5)

1. The utility model provides a synthetic polymer waterproofing membrane of high resistant time which characterized in that: the polymer waterproof coiled material is prepared from the following components in parts by weight: 100 parts of polyurethane grafted acrylic polymer, 5-7 parts of asphalt-based carbon fiber, 2-5 parts of coupling agent, 2-3 parts of antioxidant, 1-2 parts of anti-aging agent and 1-5 parts of softener.
2. The preparation method of the high weather-resistant synthetic polymer waterproof roll according to claim 1, characterized in that: the preparation method comprises the following steps:
checking, checking whether water, electricity, heat conducting oil and the like can normally run before production, confirming that the water, electricity, heat conducting oil and the like meet production control requirements, checking used raw materials, confirming the quantity of the raw materials and ensuring that the quantity of the raw materials is in an effective period;
step two, preheating the extruder for 2 hours, wherein the preheating of the extruder comprises a screw, a die head and three rollers;
step three, mixing materials, namely weighing the polyurethane grafted acrylate polymer, the asphalt-based carbon fiber, the coupling agent, the antioxidant, the anti-aging agent and the softener according to a certain proportion, sequentially putting the components into a mixer, and mixing for 30-50 min;
adjusting the die heads, simultaneously starting the extruder, starting the three rollers, running at a low speed, and allowing the sheets to pass through the three rollers, a cooling transition frame and a cloth storage frame until the sheets are rolled;
adjusting at a low speed until the thickness of the sheet is uniform, preparing for normal production, and increasing the rotating speed of the extruder and the rotating speed of the corresponding three rollers;
step six, when the production is normal, detecting the thickness of the sheet, and when the thickness meets the standard requirement, informing a technical center to carry out first roll inspection together and recording;
seventhly, carrying out batch production after the first coil is detected to be qualified, detecting the temperature, the appearance, the thickness and the length every 1 hour, making a record, and conveying the coiled material to a semi-finished product area;
and step eight, performing performance detection on the finished product, packaging and warehousing.
3. The preparation method of the high weather-resistant synthetic polymer waterproof roll according to claim 1, characterized in that: the coupling agent is composed of two parts: a part is an inorganic group which can act with an inorganic filler or a reinforcing material; the other part is an organophilic group which can interact with the synthetic resin.
4. The preparation method of the high weather-resistant synthetic polymer waterproof roll according to claim 1, characterized in that: the softening agent can be one of paraffin, cyclane, aromatic hydrocarbon, small amount of asphalt substance, nitrogen-containing organic base and the like.
5. The preparation method of the high weather-resistant synthetic polymer waterproof roll according to claim 1, characterized in that: the pitch-based carbon fiber is prepared by taking substances rich in polycyclic aromatic hydrocarbons, such as pitch, as raw materials through polymerization, spinning, non-melting and carbonization.
CN202210095625.5A 2022-01-26 2022-01-26 High-weather-resistance synthetic polymer waterproof coiled material and preparation method thereof Pending CN114410049A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115584642A (en) * 2022-09-29 2023-01-10 北京宇阳泽丽防水材料有限责任公司 Low-energy-consumption processing technology of environment-friendly asphalt waterproof coiled material

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CN111500000A (en) * 2020-05-29 2020-08-07 宁波江东碧辰环保科技有限公司 Preparation method of rubber softener

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CN1896168A (en) * 2005-07-04 2007-01-17 日东电工株式会社 Adhesive tape or sheet
CN103014919A (en) * 2012-12-28 2013-04-03 陕西师范大学 Preparation method of general purpose pitch-based carbon fiber
CN108485164A (en) * 2018-04-21 2018-09-04 湖南辰砾新材料有限公司 A kind of waterproof macromolecule coiled material and preparation method thereof
CN111500000A (en) * 2020-05-29 2020-08-07 宁波江东碧辰环保科技有限公司 Preparation method of rubber softener

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Publication number Priority date Publication date Assignee Title
CN115584642A (en) * 2022-09-29 2023-01-10 北京宇阳泽丽防水材料有限责任公司 Low-energy-consumption processing technology of environment-friendly asphalt waterproof coiled material

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Application publication date: 20220429