CN114388176B - Preparation method of four-core computer cable - Google Patents
Preparation method of four-core computer cable Download PDFInfo
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- CN114388176B CN114388176B CN202210207059.2A CN202210207059A CN114388176B CN 114388176 B CN114388176 B CN 114388176B CN 202210207059 A CN202210207059 A CN 202210207059A CN 114388176 B CN114388176 B CN 114388176B
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- carbon fluoride
- core computer
- flame retardant
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- 238000002360 preparation method Methods 0.000 title claims abstract description 35
- 229920001971 elastomer Polymers 0.000 claims abstract description 146
- 239000000463 material Substances 0.000 claims abstract description 86
- 239000000806 elastomer Substances 0.000 claims abstract description 73
- 238000011049 filling Methods 0.000 claims abstract description 39
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 claims description 94
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 86
- 239000000835 fiber Substances 0.000 claims description 54
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 claims description 53
- 239000004800 polyvinyl chloride Substances 0.000 claims description 48
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 48
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 45
- 239000003063 flame retardant Substances 0.000 claims description 45
- 235000012424 soybean oil Nutrition 0.000 claims description 44
- 239000003549 soybean oil Substances 0.000 claims description 44
- 229920000459 Nitrile rubber Polymers 0.000 claims description 43
- 239000004698 Polyethylene Substances 0.000 claims description 43
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 43
- -1 polyethylene Polymers 0.000 claims description 43
- 229920000573 polyethylene Polymers 0.000 claims description 43
- 239000000843 powder Substances 0.000 claims description 43
- 235000021355 Stearic acid Nutrition 0.000 claims description 42
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 42
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 42
- 239000008117 stearic acid Substances 0.000 claims description 42
- 239000003381 stabilizer Substances 0.000 claims description 37
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 30
- 239000002994 raw material Substances 0.000 claims description 28
- UBXIPPSTBVKKIK-UHFFFAOYSA-N dinonyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCCC)C=C1 UBXIPPSTBVKKIK-UHFFFAOYSA-N 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 18
- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 claims description 17
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 14
- 238000006116 polymerization reaction Methods 0.000 claims description 14
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 9
- 238000005520 cutting process Methods 0.000 claims description 9
- 238000001125 extrusion Methods 0.000 claims description 9
- 238000005469 granulation Methods 0.000 claims description 9
- 230000003179 granulation Effects 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000004898 kneading Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 claims description 8
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 6
- 239000004917 carbon fiber Substances 0.000 claims description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 4
- 230000032683 aging Effects 0.000 description 14
- 239000004593 Epoxy Substances 0.000 description 7
- 230000000996 additive effect Effects 0.000 description 7
- 229920003023 plastic Polymers 0.000 description 7
- 239000004033 plastic Substances 0.000 description 7
- 229910052787 antimony Inorganic materials 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000009413 insulation Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- DROMNWUQASBTFM-UHFFFAOYSA-N dinonyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCC DROMNWUQASBTFM-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 230000008054 signal transmission Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/02—Disposition of insulation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
- H01B13/22—Sheathing; Armouring; Screening; Applying other protective layers
- H01B13/24—Sheathing; Armouring; Screening; Applying other protective layers by extrusion
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/04—Flexible cables, conductors, or cords, e.g. trailing cables
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/28—Protection against damage caused by moisture, corrosion, chemical attack or weather
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Insulated Conductors (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacturing Of Electric Cables (AREA)
Abstract
The invention relates to a preparation method of a four-core computer cable, which is provided with four cable cores, an insulating layer, a filling layer and a sheath layer made of an antistatic rubber sleeve elastomer sheath material, wherein the insulating layer is coated on the outer surface of each cable core, the filling layer is filled on the outer surface of the insulating layer, and the sheath layer is coated on the outer surface of the filling layer.
Description
Technical Field
The invention relates to the technical field of cables, in particular to a preparation method of a four-core computer cable.
Background
At present, the computer cable is mainly applied to occasions such as signal transmission and detection instruments and meters of power, metallurgical, chemical industry and other industrial and mining enterprises, electronic computer systems and automation systems. The computer cable sold in the market adopts ordinary PVC as a sheath layer, and because the ordinary PVC contains a large amount of plasticizers and fillers, the elasticity and softness of the guiding material are poor, and the computer cable cannot be coiled on a cable drum in the transportation process, and in the laying process, the cable cannot be bent and laid in certain corner places because of the lower elasticity and softness of the cable, so that the laying of the cable by a construction team is inconvenient. And in the bending process of part of the cable, secondary damage to the cable is easy to cause, and the current-carrying capacity of the cable is influenced.
Therefore, in order to solve the deficiencies of the prior art, it is necessary to provide a preparation method of a four-core computer cable.
Disclosure of Invention
The invention aims to avoid the defects of the prior art and provides a preparation method of a four-core computer cable. The four-core computer cable preparation method has good flexibility and elasticity.
The above object of the present invention is achieved by the following technical measures:
the preparation method of the four-core computer cable is provided with four cable cores, an insulating layer, a filling layer and a sheath layer made of antistatic rubber sleeve elastomer sheath materials, wherein the insulating layer is coated on the outer surface of each cable core, the filling layer is filled on the outer surface of the insulating layer, and the sheath layer is coated on the outer surface of the filling layer
Preferably, the raw materials of the antistatic rubber sleeve elastomer sheath material comprise polyvinyl chloride with the polymerization degree of 1600-2500, dioctyl terephthalate, epoxidized soybean oil, polyethylene wax, nitrile rubber powder, stearic acid, nano calcium carbonate, a stabilizer, carbon fluoride fibers and strontium sulfate.
Preferably, the raw materials of the antistatic rubber sleeve elastomer sheath material also contain a flame retardant.
Preferably, the flame retardant is at least one of antimony trioxide, aluminum hydroxide or microencapsulated red phosphorus.
In terms of the weight portions of the components,
Polyvinyl chloride: 40-58 parts;
Dinonyl terephthalate: 25-35 parts;
Epoxidized soybean oil: 0.8 to 2.5 parts;
polyethylene wax: 0.1 to 0.4 part;
nitrile rubber powder: 3-10 parts;
stearic acid: 0.08 to 0.25 part;
Nano calcium carbonate: 28 to 35 parts
Stabilizing agent: 1 to 5 parts;
carbon fluoride fiber: 1 to 3 parts;
Strontium sulfate: 1 to 5 parts of
Flame retardant: 0.5 to 3 parts.
Further, in terms of parts by weight,
Polyvinyl chloride: 45-50 parts;
dinonyl terephthalate: 28-32 parts;
Epoxidized soybean oil: 1 to 2 parts;
polyethylene wax: 0.2 to 0.3 part;
Nitrile rubber powder: 5-8 parts;
Stearic acid: 0.1 to 0.2 part;
nano calcium carbonate: 30 to 33 parts
Stabilizing agent: 2-3 parts;
Carbon fluoride fiber: 1.5 to 2.5 parts;
Strontium sulfate: 2 to 4 parts of
Flame retardant: 1 to 2 parts.
Further, in terms of parts by weight,
Polyvinyl chloride: 48 parts;
Dinonyl terephthalate: 31 parts;
epoxidized soybean oil: 1.6 parts;
polyethylene wax: 0.26 parts;
Nitrile rubber powder: 6.5 parts;
stearic acid: 0.17 parts;
Nano calcium carbonate: 32 parts of
Stabilizing agent: 2.5 parts;
carbon fluoride fiber: 1.9 parts;
Strontium sulfate: 3.5 parts
Flame retardant: 1.6 parts.
Preferably, the preparation method of the carbon fluoride fiber comprises the steps of treating the carbon fiber in a mixed solution of lithium fluoride and hydrochloric acid, and then adjusting the pH value of the carbon fluoride fiber.
Preferably, the diameter of the carbon fluoride fibers is greater than 10 microns.
Preferably, the preparation of the antistatic rubber sleeve elastomer sheath material comprises the following steps:
Firstly, placing polyvinyl chloride, dioctyl terephthalate, epoxidized soybean oil, polyethylene wax, nitrile rubber powder, stearic acid, nano calcium carbonate, a stabilizer, carbon fluoride fibers, strontium sulfate and a flame retardant into a high-speed kneader, heating to 90-110 ℃, kneading and stirring for 8-15 min to obtain a mixture;
and secondly, placing the mixture into a granulator, controlling the temperature to be 130-150 ℃ for extrusion granulation, cutting and cooling to obtain the antistatic rubber sleeve elastomer sheath material.
The preparation method of the four-core computer cable is characterized in that four cable cores, an insulating layer, a filling layer and a sheath layer made of antistatic rubber sleeve elastomer are arranged, the insulating layer is coated on the outer surface of each cable core, the filling layer is filled on the outer surface of the insulating layer, and the sheath layer is coated on the outer surface of the filling layer. According to the invention, the four-core computer cable is acted by the antistatic rubber sleeve elastomer sheath material, so that the flexibility and elasticity of the material are enhanced on the premise of meeting the insulation full performance of the cable, the four-core computer cable can be flexibly moved without damage, and the four-core computer cable also has the advantages of tear resistance, low temperature resistance, wear resistance, aging resistance and the like.
Detailed Description
The technical scheme of the invention is further described with reference to the following examples.
Example 1.
The preparation method of the four-core computer cable is characterized in that four cable cores, an insulating layer, a filling layer and a sheath layer made of antistatic rubber sleeve elastomer sheath materials are arranged, the insulating layer is coated on the outer surface of each cable core, the filling layer is filled on the outer surface of the insulating layer, and the sheath layer is coated on the outer surface of the filling layer
The raw materials of the antistatic rubber sleeve elastomer sheath material comprise polyvinyl chloride with the polymerization degree of 1600-2500, dioctyl terephthalate, epoxidized soybean oil, polyethylene wax, nitrile rubber powder, stearic acid, nano calcium carbonate, a stabilizer, carbon fluoride fibers and strontium sulfate. The raw materials of the antistatic rubber sleeve elastomer sheath material also contain a flame retardant.
The flame retardant is at least one of antimony trioxide, aluminum hydroxide or microencapsulated red phosphorus.
In terms of the weight portions of the components,
Polyvinyl chloride: 40-58 parts;
Dinonyl terephthalate: 25-35 parts;
Epoxidized soybean oil: 0.8 to 2.5 parts;
polyethylene wax: 0.1 to 0.4 part;
nitrile rubber powder: 3-10 parts;
stearic acid: 0.08 to 0.25 part;
Nano calcium carbonate: 28 to 35 parts
Stabilizing agent: 1 to 5 parts;
carbon fluoride fiber: 1 to 3 parts;
Strontium sulfate: 1 to 5 parts of
Flame retardant: 0.5 to 3 parts.
The preparation method of the carbon fluoride fiber comprises the steps of treating the carbon fiber in a mixed solution of lithium fluoride and hydrochloric acid, and then adjusting the pH value of the carbon fluoride fiber. And the diameter of the carbon fluoride fibers is greater than 10 microns.
The invention uses the function of the carbon fluoride fiber to improve the connection strength with other main matrixes of the antistatic rubber sleeve elastomer sheath material. The carbon fiber of the present invention may be obtained by commercially available methods or by conventional production methods.
The preparation method of the carbon fluoride fiber comprises the steps of soaking the carbon fiber in a mixed solution of lithium fluoride with the mass concentration of 12% and hydrochloric acid with the mass concentration of 13% for 30 minutes, then washing the carbon fiber with deionized water until the pH value of a washing liquid is 6.5, and then filtering and drying the carbon fluoride fiber to obtain the carbon fluoride fiber.
The invention mainly uses the synergistic effect of strontium sulfate and carbon fluoride fiber, because the strontium sulfate has lower dielectric constant, the strontium sulfate and the carbon fluoride fiber can form an interactive antistatic network channel when being mutually stacked, and the surface resistance of the strontium sulfate and the carbon fluoride fiber is reduced. Because the diameter of the carbon fluoride fiber is larger, and the strontium sulfate has better lubricating effect on the carbon fluoride fiber, the carbon fluoride fiber is promoted to be uniformly mixed in the antistatic rubber sleeve elastomer sheath material.
The stabilizer of the invention is a calcium-zinc stabilizer.
The polymerization degree of the invention is 1600-2500, and the PVC and nitrile rubber powder can improve the elasticity and the softness. Dinonyl phthalate and epoxidized soybean oil are used as plasticizers to increase the mechanical properties of polyvinyl chloride such as fracture resistance and impact resistance. While polyethylene wax can act as a lubricant to increase compatibility with polyvinyl chloride. The nano calcium carbonate acts with the epoxidized soybean oil to increase the stability of the invention.
The anti-static rubber sleeve elastomer sheath material acts on the four-core computer cable, and the anti-static rubber sleeve elastomer sheath material strengthens the softness and elasticity of the material on the premise of meeting the full insulation performance of the cable, so that the anti-static rubber sleeve elastomer sheath material can flexibly move without damage, and the four-core computer cable also has the advantages of tearing resistance, low temperature resistance, wear resistance, aging resistance and the like.
Example 2.
The preparation method of the four-core computer cable is characterized in that four cable cores, an insulating layer, a filling layer and a sheath layer made of antistatic rubber sleeve elastomer sheath materials are arranged, the insulating layer is coated on the outer surface of each cable core, the filling layer is filled on the outer surface of the insulating layer, and the sheath layer is coated on the outer surface of the filling layer
The raw materials of the antistatic rubber sleeve elastomer sheath material comprise polyvinyl chloride with the polymerization degree of 1600-2500, dioctyl terephthalate, epoxidized soybean oil, polyethylene wax, nitrile rubber powder, stearic acid, nano calcium carbonate, a stabilizer, carbon fluoride fibers and strontium sulfate. The raw materials of the antistatic rubber sleeve elastomer sheath material also contain a flame retardant.
The flame retardant is at least one of antimony trioxide, aluminum hydroxide or microencapsulated red phosphorus.
Polyvinyl chloride: 45-50 parts;
dinonyl terephthalate: 28-32 parts;
Epoxidized soybean oil: 1 to 2 parts;
polyethylene wax: 0.2 to 0.3 part;
Nitrile rubber powder: 5-8 parts;
Stearic acid: 0.1 to 0.2 part;
nano calcium carbonate: 30 to 33 parts
Stabilizing agent: 2-3 parts;
Carbon fluoride fiber: 1.5 to 2.5 parts;
Strontium sulfate: 2 to 4 parts of
Flame retardant: 1 to 2 parts.
Compared with the embodiment 1, the four-core computer cable prepared by the method has better softness, elasticity, tear resistance, low temperature resistance, wear resistance and aging resistance than the four-core computer cable prepared by the embodiment 1.
Example 3.
The preparation method of the four-core computer cable is characterized in that four cable cores, an insulating layer, a filling layer and a sheath layer made of antistatic rubber sleeve elastomer sheath materials are arranged, the insulating layer is coated on the outer surface of each cable core, the filling layer is filled on the outer surface of the insulating layer, and the sheath layer is coated on the outer surface of the filling layer
The raw materials of the antistatic rubber sleeve elastomer sheath material comprise 2000 polyvinyl chloride with polymerization degree, dioctyl terephthalate, epoxidized soybean oil, polyethylene wax, nitrile rubber powder, stearic acid, nano calcium carbonate, a stabilizer, carbon fluoride fibers and strontium sulfate. The raw materials of the antistatic rubber sleeve elastomer sheath material also contain a flame retardant.
Polyvinyl chloride: 48 parts;
Dinonyl terephthalate: 31 parts;
epoxidized soybean oil: 1.6 parts;
polyethylene wax: 0.26 parts;
Nitrile rubber powder: 6.5 parts;
stearic acid: 0.17 parts;
Nano calcium carbonate: 32 parts of
Stabilizing agent: 2.5 parts;
carbon fluoride fiber: 1.9 parts;
Strontium sulfate: 3.5 parts
Flame retardant: 1.6 parts.
The flame retardant is antimony trioxide.
Wherein the polyvinyl chloride is purchased from Shanghai Kaiyan chemical Co., ltd, the nitrile rubber powder is purchased from Hubei Kod chemical Co., ltd, the dinonyl terephthalate is purchased from Rubang plastics additive Co., ltd, the polyethylene wax is purchased from Luolan New materials Co., yangzhou, the nano calcium carbonate is purchased from Zhongshan Deyuan trade Co., ltd, the epoxy soybean oil is purchased from Shandong Chen chemical Co., ltd, the stearic acid is purchased from Shijia Cheng Peng chemical Co., ltd, the strontium sulfate is purchased from Jiangsu Runfeng synthetic technology Co., and the antimony trioxide is purchased from Shanghai Chen Feng antimony trade Co., ltd.
Compared with the embodiment 1, the four-core computer cable prepared by the method has better softness, elasticity, tear resistance, low temperature resistance, wear resistance and aging resistance than the four-core computer cable prepared by the embodiment 1.
Example 4.
The preparation method of the four-core computer cable is characterized in that four cable cores, an insulating layer, a filling layer and a sheath layer made of antistatic rubber sleeve elastomer sheath materials are arranged, the insulating layer is coated on the outer surface of each cable core, the filling layer is filled on the outer surface of the insulating layer, and the sheath layer is coated on the outer surface of the filling layer
The raw materials of the antistatic rubber sleeve elastomer sheath material comprise polyvinyl chloride with the polymerization degree of 1600, dioctyl terephthalate, epoxidized soybean oil, polyethylene wax, nitrile rubber powder, stearic acid, nano calcium carbonate, a stabilizer, carbon fluoride fibers and strontium sulfate. The raw materials of the antistatic rubber sleeve elastomer sheath material also contain a flame retardant.
The flame retardant is antimony trioxide and aluminum hydroxide.
Polyvinyl chloride: 40 parts;
dinonyl terephthalate: 25 parts;
epoxidized soybean oil: 0.8 parts;
polyethylene wax: 0.1 part;
nitrile rubber powder: 3 parts;
stearic acid: 0.08 parts;
nano calcium carbonate: 28 parts;
stabilizing agent: 1 part;
Carbon fluoride fiber: 1 part;
Strontium sulfate: 1 part;
flame retardant: 0.5 part.
Wherein the polyvinyl chloride is purchased from Shanghai Kaiyan chemical Co., ltd, the nitrile rubber powder is purchased from Hubei Kod chemical Co., ltd, the dinonyl terephthalate is purchased from Rubang plastics additive Co., ltd, the polyethylene wax is purchased from Luolan New materials Co., yangzhou, the nano calcium carbonate is purchased from Zhongshan Deyuan trade Co., ltd, the epoxy soybean oil is purchased from Shandong Chen chemical Co., ltd, the stearic acid is purchased from Shijia Cheng Peng chemical Co., ltd, the strontium sulfate is purchased from Jiangsu Runfeng synthetic technology Co., and the antimony trioxide is purchased from Shanghai Chen Feng antimony trade Co., ltd. Aluminum hydroxide was purchased from Shandong Cycloleic chemical Co.
Compared with the embodiment 1, the four-core computer cable prepared by the method has better softness, elasticity, tear resistance, low temperature resistance, wear resistance and aging resistance than the four-core computer cable prepared by the embodiment 1.
Example 5.
The preparation method of the four-core computer cable is characterized in that four cable cores, an insulating layer, a filling layer and a sheath layer made of antistatic rubber sleeve elastomer sheath materials are arranged, the insulating layer is coated on the outer surface of each cable core, the filling layer is filled on the outer surface of the insulating layer, and the sheath layer is coated on the outer surface of the filling layer
The raw materials of the antistatic rubber sleeve elastomer sheath material comprise 2500-degree polyvinyl chloride with polymerization degree, dioctyl terephthalate, epoxidized soybean oil, polyethylene wax, nitrile rubber powder, stearic acid, nano calcium carbonate, a stabilizer, carbon fluoride fibers and strontium sulfate. The raw materials of the antistatic rubber sleeve elastomer sheath material also contain a flame retardant.
The flame retardant is microencapsulated red phosphorus.
Polyvinyl chloride: 58 parts;
Dinonyl terephthalate: 35 parts;
epoxidized soybean oil: 2.5 parts;
Polyethylene wax: 0.4 parts;
Nitrile rubber powder: 10 parts;
stearic acid: 0.25 parts;
Nano calcium carbonate: 35 parts;
Stabilizing agent: 5 parts;
Carbon fluoride fiber: 3 parts;
strontium sulfate: 5 parts;
Flame retardant: 3 parts.
Wherein the polyvinyl chloride is purchased from Shanghai Kaiyan chemical Co., ltd, the nitrile rubber powder is purchased from Hubei Korea chemical Co., ltd, the dinonyl terephthalate is purchased from Rubang plastics additive Co., ltd, the polyethylene wax is purchased from Luolan New materials Co., yangzhou, the nano calcium carbonate is purchased from Zhongshan Deyuan trade Co., ltd, the epoxy soybean oil is purchased from Shandong Chen chemical Co., stearic acid is purchased from Shijia Cheng Peng chemical Co., ltd, the strontium sulfate is purchased from Jiangsu Runfeng synthetic technology Co., ltd, and the microencapsulated red phosphorus is purchased from Ji Nanhui Jinchun chemical Co., ltd.
Compared with the embodiment 1, the four-core computer cable prepared by the method has better softness, elasticity, tear resistance, low temperature resistance, wear resistance and aging resistance than the four-core computer cable prepared by the embodiment 1.
Example 6.
The preparation method of the four-core computer cable is characterized in that four cable cores, an insulating layer, a filling layer and a sheath layer made of antistatic rubber sleeve elastomer sheath materials are arranged, the insulating layer is coated on the outer surface of each cable core, the filling layer is filled on the outer surface of the insulating layer, and the sheath layer is coated on the outer surface of the filling layer
The raw materials of the antistatic rubber sleeve elastomer sheath material comprise 2500-degree polyvinyl chloride with polymerization degree, dioctyl terephthalate, epoxidized soybean oil, polyethylene wax, nitrile rubber powder, stearic acid, nano calcium carbonate, a stabilizer, carbon fluoride fibers and strontium sulfate. The raw materials of the antistatic rubber sleeve elastomer sheath material also contain a flame retardant.
The flame retardant is microencapsulated red phosphorus.
Polyvinyl chloride: 45 parts;
Dinonyl terephthalate: 28 parts;
Epoxidized soybean oil: 1 part;
polyethylene wax: 0.2 parts;
nitrile rubber powder: 5 parts;
stearic acid: 0.1 part;
Nano calcium carbonate: 30 parts;
stabilizing agent: 2 parts;
Carbon fluoride fiber: 1.5 parts;
Strontium sulfate: 2 parts;
flame retardant: 1 part.
Wherein the polyvinyl chloride is purchased from Shanghai Kaiyan chemical Co., ltd, the nitrile rubber powder is purchased from Hubei Korea chemical Co., ltd, the dinonyl terephthalate is purchased from Rubang plastics additive Co., ltd, the polyethylene wax is purchased from Luan New materials Co., yangzhou, the nano calcium carbonate is purchased from Zhongshan Deyuan trade Co., ltd, the epoxy soybean oil is purchased from Shandong Chen chemical Co., stearic acid is purchased from Shijia Cheng Pengpeng chemical Co., ltd, the strontium sulfate is purchased from Jiangsu Runfeng synthetic technology Co., ltd, the antimony trioxide is purchased from Shanghai Chen Feng antimony Co., ltd, and the microencapsulated red phosphorus is purchased from Ji Nanhui Jinchun chemical Co., ltd.
Compared with the embodiment 1, the four-core computer cable prepared by the method has better softness, elasticity, tear resistance, low temperature resistance, wear resistance and aging resistance than the four-core computer cable prepared by the embodiment 1.
Example 7.
The preparation method of the four-core computer cable is characterized in that four cable cores, an insulating layer, a filling layer and a sheath layer made of antistatic rubber sleeve elastomer sheath materials are arranged, the insulating layer is coated on the outer surface of each cable core, the filling layer is filled on the outer surface of the insulating layer, and the sheath layer is coated on the outer surface of the filling layer
The raw materials of the antistatic rubber sleeve elastomer sheath material comprise 2500-degree polyvinyl chloride with polymerization degree, dioctyl terephthalate, epoxidized soybean oil, polyethylene wax, nitrile rubber powder, stearic acid, nano calcium carbonate, a stabilizer, carbon fluoride fibers and strontium sulfate. The raw materials of the antistatic rubber sleeve elastomer sheath material also contain a flame retardant.
The flame retardant is antimony trioxide, aluminum hydroxide and microencapsulated red phosphorus.
Polyvinyl chloride: 50 parts;
Dinonyl terephthalate: 32 parts;
epoxidized soybean oil: 2 parts;
Polyethylene wax: 0.3 parts;
nitrile rubber powder: 8 parts;
stearic acid: 0.2 parts;
Nano calcium carbonate: 33 parts;
Stabilizing agent: 3 parts;
Carbon fluoride fiber: 2.5 parts;
Strontium sulfate: 4 parts;
Flame retardant: 2 parts.
Wherein the polyvinyl chloride is purchased from Shanghai Kaiyin chemical Co., ltd, the nitrile rubber powder is purchased from Hubei Korea chemical Co., ltd, the dinonyl terephthalate is purchased from Rubang plastics additive Co., ltd, the polyethylene wax is purchased from Lulanxin materials Co., yangzhou, the nano calcium carbonate is purchased from Zhongshan Deyuan trade Co., ltd, the epoxy soybean oil is purchased from Shandong Chen chemical Co., stearic acid is purchased from Shijia Cheng Pengpeng chemical Co., ltd, the strontium sulfate is purchased from Jiangsu Runfeng synthetic technology Co., ltd, the antimony trioxide is purchased from Shanghai Chen Feng antimony Co., ltd, the aluminum hydroxide is purchased from Shandong Cyril chemical Co., ltd, and the microencapsulated red phosphorus is purchased from Ji Nanhui Sichuan chemical Co., ltd.
Compared with the embodiment 1, the four-core computer cable prepared by the method has better softness, elasticity, tear resistance, low temperature resistance, wear resistance and aging resistance than the four-core computer cable prepared by the embodiment 1.
Example 8.
The preparation method of the four-core computer cable is characterized in that four cable cores, an insulating layer, a filling layer and a sheath layer made of antistatic rubber sleeve elastomer sheath materials are arranged, the insulating layer is coated on the outer surface of each cable core, the filling layer is filled on the outer surface of the insulating layer, and the sheath layer is coated on the outer surface of the filling layer
The raw materials of the antistatic rubber sleeve elastomer sheath material comprise 2500-degree polyvinyl chloride with polymerization degree, dioctyl terephthalate, epoxidized soybean oil, polyethylene wax, nitrile rubber powder, stearic acid, nano calcium carbonate, a stabilizer, carbon fluoride fibers and strontium sulfate. The raw materials of the antistatic rubber sleeve elastomer sheath material also contain a flame retardant.
The flame retardant is antimony trioxide, aluminum hydroxide and microencapsulated red phosphorus.
Polyvinyl chloride: 48 parts;
Dinonyl terephthalate: 31 parts;
epoxidized soybean oil: 1.6 parts;
polyethylene wax: 0.26 parts;
Nitrile rubber powder: 6.5 parts;
stearic acid: 0.17 parts;
Nano calcium carbonate: 32 parts of
Stabilizing agent: 2.5 parts;
carbon fluoride fiber: 1.9 parts;
Strontium sulfate: 3.5 parts
Flame retardant: 1.6 parts.
Wherein the polyvinyl chloride is purchased from Shanghai Kaiyin chemical Co., ltd, the nitrile rubber powder is purchased from Hubei Korea chemical Co., ltd, the dinonyl terephthalate is purchased from Rubang plastics additive Co., ltd, the polyethylene wax is purchased from Lulanxin materials Co., yangzhou, the nano calcium carbonate is purchased from Zhongshan Deyuan trade Co., ltd, the epoxy soybean oil is purchased from Shandong Chen chemical Co., stearic acid is purchased from Shijia Cheng Pengpeng chemical Co., ltd, the strontium sulfate is purchased from Jiangsu Runfeng synthetic technology Co., ltd, the antimony trioxide is purchased from Shanghai Chen Feng antimony Co., ltd, the aluminum hydroxide is purchased from Shandong Cyril chemical Co., ltd, and the microencapsulated red phosphorus is purchased from Ji Nanhui Sichuan chemical Co., ltd.
Compared with the embodiment 1, the four-core computer cable prepared by the method has better softness, elasticity, tear resistance, low temperature resistance, wear resistance and aging resistance than the four-core computer cable prepared by the embodiment 1.
Example 9.
The preparation method of the four-core computer cable is characterized in that four cable cores, an insulating layer, a filling layer and a sheath layer made of antistatic rubber sleeve elastomer sheath materials are arranged, the insulating layer is coated on the outer surface of each cable core, the filling layer is filled on the outer surface of the insulating layer, and the sheath layer is coated on the outer surface of the filling layer
The raw materials of the antistatic rubber sleeve elastomer sheath material comprise 2500-degree polyvinyl chloride with polymerization degree, dioctyl terephthalate, epoxidized soybean oil, polyethylene wax, nitrile rubber powder, stearic acid, nano calcium carbonate, a stabilizer, carbon fluoride fibers and strontium sulfate. The raw materials of the antistatic rubber sleeve elastomer sheath material also contain a flame retardant.
The flame retardant is antimony trioxide, aluminum hydroxide and microencapsulated red phosphorus.
Polyvinyl chloride: 47.5 parts;
dinonyl terephthalate: 29.7 parts;
epoxidized soybean oil: 1.3 parts;
Polyethylene wax: 0.27 parts;
Nitrile rubber powder: 5.8 parts;
stearic acid: 0.18 parts;
Nano calcium carbonate: 31 parts;
Stabilizing agent: 2.3 parts;
carbon fluoride fiber: 1.9 parts;
Strontium sulfate: 3 parts;
flame retardant: 1.7 parts.
Wherein the polyvinyl chloride is purchased from Shanghai Kaiyin chemical Co., ltd, the nitrile rubber powder is purchased from Hubei Korea chemical Co., ltd, the dinonyl terephthalate is purchased from Rubang plastics additive Co., ltd, the polyethylene wax is purchased from Lulanxin materials Co., yangzhou, the nano calcium carbonate is purchased from Zhongshan Deyuan trade Co., ltd, the epoxy soybean oil is purchased from Shandong Chen chemical Co., stearic acid is purchased from Shijia Cheng Pengpeng chemical Co., ltd, the strontium sulfate is purchased from Jiangsu Runfeng synthetic technology Co., ltd, the antimony trioxide is purchased from Shanghai Chen Feng antimony Co., ltd, the aluminum hydroxide is purchased from Shandong Cyril chemical Co., ltd, and the microencapsulated red phosphorus is purchased from Ji Nanhui Sichuan chemical Co., ltd.
Compared with the embodiment 1, the four-core computer cable prepared by the method has better softness, elasticity, tear resistance, low temperature resistance, wear resistance and aging resistance than the four-core computer cable prepared by the embodiment 1.
Example 10.
The preparation method of the four-core computer cable adopts the raw material proportion of the antistatic rubber sleeve elastomer sheath material in any one of the embodiments 3 to 9, and the preparation steps of the antistatic rubber sleeve elastomer sheath material comprise:
Firstly, placing polyvinyl chloride, dioctyl terephthalate, epoxidized soybean oil, polyethylene wax, nitrile rubber powder, stearic acid, nano calcium carbonate, a stabilizer, carbon fluoride fibers, strontium sulfate and a flame retardant into a high-speed kneader, heating to 90-110 ℃, kneading and stirring for 8-15 min to obtain a mixture;
step two, placing the mixture into a granulator, controlling the temperature to be 130-150 ℃ for extrusion granulation, cutting and cooling to obtain the antistatic rubber sleeve elastomer sheath material;
The anti-static rubber sleeve elastomer sheath material acts on the four-core computer cable, and the anti-static rubber sleeve elastomer sheath material strengthens the softness and elasticity of the material on the premise of meeting the full insulation performance of the cable, so that the anti-static rubber sleeve elastomer sheath material can flexibly move without damage, and the four-core computer cable also has the advantages of tearing resistance, low temperature resistance, wear resistance, aging resistance and the like.
Example 11.
The preparation method of the four-core computer cable adopts the raw material proportion of the antistatic rubber sleeve elastomer sheath material in any one of the embodiments 3 to 9, and the preparation steps of the antistatic rubber sleeve elastomer sheath material comprise:
Firstly, placing polyvinyl chloride, dioctyl terephthalate, epoxidized soybean oil, polyethylene wax, nitrile rubber powder, stearic acid, nano calcium carbonate, a stabilizer, carbon fluoride fibers, strontium sulfate and a flame retardant into a high-speed kneader, heating to 92 ℃, kneading and stirring for 8.5min to obtain a mixture;
and secondly, placing the mixture into a granulator, controlling the temperature to be 140 ℃ for extrusion granulation, and cutting and cooling to obtain the antistatic rubber sleeve elastomer sheath material.
The anti-static rubber sleeve elastomer sheath material acts on the four-core computer cable, and the anti-static rubber sleeve elastomer sheath material strengthens the softness and elasticity of the material on the premise of meeting the full insulation performance of the cable, so that the anti-static rubber sleeve elastomer sheath material can flexibly move without damage, and the four-core computer cable also has the advantages of tearing resistance, low temperature resistance, wear resistance, aging resistance and the like.
Example 12.
The preparation method of the four-core computer cable adopts the raw material proportion of the antistatic rubber sleeve elastomer sheath material in any one of the embodiments 3 to 9, and the preparation steps of the antistatic rubber sleeve elastomer sheath material comprise:
firstly, placing polyvinyl chloride, dioctyl terephthalate, epoxidized soybean oil, polyethylene wax, nitrile rubber powder, stearic acid, nano calcium carbonate, a stabilizer, carbon fluoride fibers, strontium sulfate and a flame retardant into a high-speed kneader, heating to 108 ℃, kneading and stirring for 9min to obtain a mixture;
step two, placing the mixture into a granulator, controlling the temperature to be 148 ℃ for extrusion granulation, and cutting and cooling to obtain the antistatic rubber sleeve elastomer sheath material;
The anti-static rubber sleeve elastomer sheath material acts on the four-core computer cable, and the anti-static rubber sleeve elastomer sheath material strengthens the softness and elasticity of the material on the premise of meeting the full insulation performance of the cable, so that the anti-static rubber sleeve elastomer sheath material can flexibly move without damage, and the four-core computer cable also has the advantages of tearing resistance, low temperature resistance, wear resistance, aging resistance and the like.
Example 13.
The preparation method of the four-core computer cable adopts the raw material proportion of the antistatic rubber sleeve elastomer sheath material in any one of the embodiments 3 to 9, and the preparation steps of the antistatic rubber sleeve elastomer sheath material comprise:
Firstly, placing polyvinyl chloride, dioctyl terephthalate, epoxidized soybean oil, polyethylene wax, nitrile rubber powder, stearic acid, nano calcium carbonate, a stabilizer, carbon fluoride fibers, strontium sulfate and a flame retardant into a high-speed kneader, heating to 110 ℃, kneading and stirring for 10min to obtain a mixture;
Step two, placing the mixture into a granulator, controlling the temperature to 140 ℃ for extrusion granulation, cutting and cooling to obtain the antistatic rubber sleeve elastomer sheath material;
The anti-static rubber sleeve elastomer sheath material acts on the four-core computer cable, and the anti-static rubber sleeve elastomer sheath material strengthens the softness and elasticity of the material on the premise of meeting the full insulation performance of the cable, so that the anti-static rubber sleeve elastomer sheath material can flexibly move without damage, and the four-core computer cable also has the advantages of tearing resistance, low temperature resistance, wear resistance, aging resistance and the like.
The sheath material sample group of the four-core computer cable preparation method is prepared by the raw material proportion of examples 3-9 and the process of obtaining the antistatic rubber sleeve elastomer sheath material of examples 11-13.
Sample group for preparing table one-core and four-core computer cables
Sample group | Raw material proportioning | Preparation method |
Sample 1 | Example 3 | Example 12 |
Sample 2 | Example 4 | Example 12 |
Sample 3 | Example 5 | Example 12 |
Sample 4 | Example 6 | Example 12 |
Sample 5 | Example 7 | Example 12 |
Sample 6 | Example 8 | Example 12 |
Sample 7 | Example 9 | Example 12 |
Sample 8 | Example 7 | Example 11 |
Sample 9 | Example 7 | Example 13 |
Sample 10 | Example 8 | Example 11 |
Sample 11 | Example 8 | Example 13 |
Comparative example 1.
A jacket material comprising the steps of:
Firstly, heating polyvinyl chloride with the polymerization degree of 150050 parts, 23 parts of dinonyl terephthalate, 2 parts of epoxidized soybean oil, 0.3 part of polyethylene wax, 0.3 part of stearic acid, 15 parts of nano calcium carbonate and 3 parts of stabilizer in a high-speed kneader to 92 ℃ and kneading and stirring for 8.5min to obtain a mixture;
And secondly, placing the mixture into a granulator, controlling the temperature to be 140 ℃ for extrusion granulation, cutting and cooling to obtain the sheath material.
Comparative example 2.
A jacket material comprising the steps of:
Firstly, heating 250050 parts of polyvinyl chloride, 32 parts of dinonyl terephthalate, 2 parts of epoxidized soybean oil, 0.3 part of polyethylene wax, 8 parts of nitrile rubber powder, 0.2 part of stearic acid, 33 parts of nano calcium carbonate, 3 parts of stabilizer, 2.5 parts of fluorocarbon fiber and 2 parts of flame retardant in a high-speed kneader to 92 ℃ and kneading and stirring for 8.5min to obtain a mixture;
And secondly, placing the mixture into a granulator, controlling the temperature to be 140 ℃ for extrusion granulation, cutting and cooling to obtain the sheath material.
Comparative example 3.
A jacket material comprising the steps of:
firstly, heating 250050 parts of polyvinyl chloride, 32 parts of dinonyl terephthalate, 2 parts of epoxidized soybean oil, 0.3 part of polyethylene wax, 8 parts of nitrile rubber powder, 0.2 part of stearic acid, 33 parts of nano calcium carbonate, 3 parts of stabilizer, 4 parts of strontium sulfate and 2 parts of flame retardant in a high-speed kneader to 92 ℃ and kneading and stirring for 8.5min to obtain a mixture;
And secondly, placing the mixture into a granulator, controlling the temperature to be 140 ℃ for extrusion granulation, cutting and cooling to obtain the sheath material.
In other cases where the experimental conditions were the same, table 2 shows the performance of the antistatic rubber jacketed elastomer jacket materials of samples 1 to 11 and the jacket materials of comparative examples 1 to 3, and the relevant performance is shown in Table II:
Table two, correlation detection performance after preparing cable with corresponding sample
As can be seen from Table 2, the tensile strength of the antistatic rubber sleeve elastomer sheath material obtained by the combination of the polyvinyl chloride, the nitrile rubber powder and other components in the polymerization degree range of the invention is obviously smaller than that of comparative example 1, and the elongation is obviously higher than that of comparative example 1, so that the antistatic rubber sleeve elastomer sheath material has certain wear resistance under the tensile strength and elongation at break, and meets the requirements of flexibility and elasticity of a computer cable. The invention adds the carbon fluoride fiber and the strontium sulfate at the same time, and the resistivity is at the level of 10 5 when the carbon fluoride fiber and the strontium sulfate are matched for use, so that the resistivity is greatly reduced.
Finally, it should be noted that the above embodiments are only for illustrating the technical solution of the present invention and not for limiting the scope of the present invention, and although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that the technical solution of the present invention may be modified or substituted equally without departing from the spirit and scope of the technical solution of the present invention.
Claims (7)
1. A preparation method of a four-core computer cable is characterized by comprising the following steps: the cable core is provided with four cable cores, an insulating layer, a filling layer and a sheath layer made of antistatic rubber sleeve elastomer, wherein the insulating layer is coated on the outer surface of each cable core, the filling layer is filled on the outer surface of the insulating layer, and the sheath layer is coated on the outer surface of the filling layer;
The raw materials of the antistatic rubber sleeve elastomer sheath material comprise polyvinyl chloride with the polymerization degree of 1600-2500, dioctyl terephthalate, epoxidized soybean oil, polyethylene wax, nitrile rubber powder, stearic acid, nano calcium carbonate, a stabilizer, carbon fluoride fibers and strontium sulfate;
the raw materials of the antistatic rubber sleeve elastomer sheath material also contain a flame retardant;
In terms of the weight portions of the components,
Polyvinyl chloride: 40-58 parts;
Dinonyl terephthalate: 25-35 parts;
Epoxidized soybean oil: 0.8 to 2.5 parts;
polyethylene wax: 0.1 to 0.4 part;
nitrile rubber powder: 3-10 parts;
stearic acid: 0.08 to 0.25 part;
nano calcium carbonate: 28-35 parts;
Stabilizing agent: 1 to 5 parts;
carbon fluoride fiber: 1 to 3 parts;
Strontium sulfate: 1 to 5 parts;
Flame retardant: 0.5 to 3 parts.
2. The method of preparing a four-core computer cable according to claim 1, wherein: the flame retardant is at least one of antimony trioxide, aluminum hydroxide or microencapsulated red phosphorus.
3. The method of preparing a four-core computer cable according to claim 2, wherein: in terms of the weight portions of the components,
Polyvinyl chloride: 45-50 parts;
dinonyl terephthalate: 28-32 parts;
Epoxidized soybean oil: 1 to 2 parts;
polyethylene wax: 0.2 to 0.3 part;
Nitrile rubber powder: 5-8 parts;
Stearic acid: 0.1 to 0.2 part;
Nano calcium carbonate: 30-33 parts;
Stabilizing agent: 2-3 parts;
Carbon fluoride fiber: 1.5 to 2.5 parts;
Strontium sulfate: 2-4 parts;
Flame retardant: 1 to 2 parts.
4. A method of preparing a four-core computer cable according to claim 3, wherein: in terms of the weight portions of the components,
Polyvinyl chloride: 48 parts;
Dinonyl terephthalate: 31 parts;
epoxidized soybean oil: 1.6 parts;
polyethylene wax: 0.26 parts;
Nitrile rubber powder: 6.5 parts;
stearic acid: 0.17 parts;
Nano calcium carbonate: 32 parts of
Stabilizing agent: 2.5 parts;
carbon fluoride fiber: 1.9 parts;
Strontium sulfate: 3.5 parts
Flame retardant: 1.6 parts.
5. The method of preparing a four-core computer cable according to claim 4, wherein: the preparation method of the carbon fluoride fiber comprises the steps of treating the carbon fiber in a mixed solution of lithium fluoride and hydrochloric acid, and then adjusting the pH value of the carbon fluoride fiber.
6. The method of preparing a four-core computer cable according to claim 4, wherein: the carbon fluoride fibers have a diameter greater than 10 microns.
7. The method for preparing the four-core computer cable according to claim 6, wherein the preparation of the antistatic rubber sleeve elastomer sheath material comprises the following steps:
Firstly, placing polyvinyl chloride, dioctyl terephthalate, epoxidized soybean oil, polyethylene wax, nitrile rubber powder, stearic acid, nano calcium carbonate, a stabilizer, carbon fluoride fibers, strontium sulfate and a flame retardant into a high-speed kneader, heating to 90-110 ℃, kneading and stirring for 8-15 min to obtain a mixture;
and secondly, placing the mixture into a granulator, controlling the temperature to be 130-150 ℃ for extrusion granulation, cutting and cooling to obtain the antistatic rubber sleeve elastomer sheath material.
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CN102604260A (en) * | 2012-02-25 | 2012-07-25 | 安徽电缆股份有限公司 | Improved flexible polyvinyl chloride sheath cable material and preparation method thereof |
CN104318986A (en) * | 2014-11-17 | 2015-01-28 | 成都冠禹科技有限公司 | Anti-static, anti-corrosion, waterproof and stretching-resistant insulated cable |
CN106683798A (en) * | 2017-01-12 | 2017-05-17 | 芜湖航天特种电缆厂股份有限公司 | Kaolin modification-based nylon cable protection sleeve and fabrication method thereof |
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