CN114381946A - High-temperature cloth for processing solar cell module and preparation method thereof - Google Patents

High-temperature cloth for processing solar cell module and preparation method thereof Download PDF

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Publication number
CN114381946A
CN114381946A CN202111613792.6A CN202111613792A CN114381946A CN 114381946 A CN114381946 A CN 114381946A CN 202111613792 A CN202111613792 A CN 202111613792A CN 114381946 A CN114381946 A CN 114381946A
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parts
temperature cloth
coating material
weight
solar cell
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CN114381946B (en
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沙嫣
沙晓林
马立国
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Nantong Qs Solar Technology Co ltd
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Nantong Qs Solar Technology Co ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0065Organic pigments, e.g. dyes, brighteners
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/0481Encapsulation of modules characterised by the composition of the encapsulation material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Physics & Mathematics (AREA)
  • Power Engineering (AREA)
  • Electromagnetism (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Inorganic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a high-temperature cloth for processing a solar cell module and a preparation method thereof, wherein the method comprises the following steps: firstly, preparing raw materials, preparing a coating material containing graphene, and uniformly coating the coating material on the surface of high-temperature cloth; the components of the coating material comprise graphene compound copolymer mother liquor, a stabilizer, an acidity regulator and water. The components of the coating material preferably comprise 35-44 parts of graphene compound copolymer mother liquor, 16-20 parts of stabilizing agent, 0.5-2 parts of acidity regulator and 40-45 parts of water. The invention also provides the high-temperature cloth prepared by the method for processing the solar cell module. According to the high-temperature cloth for processing the solar cell module and the preparation method thereof, the prepared coating material with the graphene material on the surface can effectively prevent EVA from being adhered to the high-temperature cloth, and the high-temperature cloth has the characteristics of reasonable design, simple structure, reduction of labor intensity of operators and the like.

Description

High-temperature cloth for processing solar cell module and preparation method thereof
Technical Field
The invention relates to novel high-temperature cloth used in the technical field of solar modules and a preparation method thereof, in particular to high-temperature cloth used for processing solar modules and a preparation method thereof.
Background
Solar cells are devices that directly convert light energy into electrical energy by the photoelectric or photochemical effect. The voltage and the current can be output instantly as long as the lamp is illuminated. Physically called solar photovoltaic, referred to as photovoltaic for short.
A production process of the solar cell panel; battery detection, front welding, inspection, back series connection, inspection, laying, laminating, deburring, border installation, junction box welding, high-voltage testing, component testing, appearance inspection and packaging and warehousing. In the lamination process, in order to prevent that EVA from gluing on the laminator under high temperature, need place the high temperature cloth respectively in solar PV modules's the superiors and the lower floor, the high temperature cloth can effectually prevent that EVA from gluing on the laminator, but the high temperature cloth is after finishing using at every turn, can not used repeatedly at once, but need wait to cool off completely the back, the EVA that will remain on the high temperature cloth again clears away totally, then just can use once more, if the EVA that remains on the high temperature cloth does not obtain thoroughly to clear away, when the high temperature cloth is used once more, can make and remain EVA and glue on battery pack's glass, EVA that glues on battery pack is at the clear-out in-process, very easily harm battery pack's glass, and glue very easily the dust of adsorbing on EVA battery pack's glass, the dust can block the battery piece on the battery pack, solar cell panel's practicality has been seriously influenced.
Disclosure of Invention
Aiming at the defects of the prior art, the surface of the high-temperature cloth contains a layer of coating material made of graphene, so that EVA can be prevented from being adhered to the high-temperature cloth.
In order to achieve the above object, the present invention provides a method for preparing a high temperature cloth for processing a solar cell module, wherein the method comprises: firstly, preparing raw materials, preparing a coating material containing graphene, and uniformly coating the coating material on the surface of high-temperature cloth; the components of the coating material comprise graphene compound copolymer mother liquor, a stabilizer, an acidity regulator and water.
The preparation method of the high-temperature cloth for processing the solar cell module comprises the following steps of 35-44 parts of graphene compound copolymer mother liquor, 16-20 parts of a stabilizer, 0.5-2 parts of an acidity regulator and 40-45 parts of water in parts by weight.
The preparation method of the high-temperature cloth for processing the solar cell module comprises the step of uniformly mixing 15-18 parts by weight of methyl hydrogen-containing siloxane emulsion, 15-18 parts by weight of hydroxyl silane emulsion and 5-8 parts by weight of graphene oxide to obtain graphene compound copolymer mother liquor.
In the preparation method of the high-temperature cloth for processing the solar cell module, the graphene oxide is prepared by any one of a mechanical stripping method, a chemical vapor deposition method and a redox method.
The preparation method of the high-temperature cloth for processing the solar cell module is characterized in that the stabilizer is obtained by uniformly mixing 7-10 parts by weight of ethanolamine and 9-10 parts by weight of a cross-linking agent.
In the preparation method of the high-temperature cloth for processing the solar cell module, the cross-linking agent is hydroxymethyl acrylate or ethyl acrylate.
In the preparation method of the high-temperature cloth for processing the solar cell module, the acidity regulator is citric acid or acetic acid.
The invention also provides the high-temperature cloth prepared by the method for processing the solar cell module.
The high-temperature cloth for processing the solar cell module and the preparation method thereof provided by the invention have the following advantages:
compared with the prior art, the EVA adhesive can effectively prevent the EVA from being adhered to the high-temperature cloth, only the paper pad needs to be replaced, and the high-temperature cloth is free from cleaning. Another advantage lies in, the paper pad is whole can the off-line operation, the effectual intensity of labour who reduces operating personnel and go up the unloading.
Detailed Description
The following further describes embodiments of the present invention.
The invention provides a preparation method of high-temperature cloth for processing a solar cell module, which comprises the following steps: firstly, preparing raw materials, preparing a coating material containing graphene, and uniformly coating the coating material on the surface of high-temperature cloth; the components of the coating material comprise graphene compound copolymer mother liquor, a stabilizer, an acidity regulator and water.
Preferably, the components of the coating material comprise 35-44 parts of graphene compound copolymer mother liquor, 16-20 parts of stabilizing agent, 0.5-2 parts of acidity regulator and 40-45 parts of water in parts by weight.
The graphene compound copolymer mother liquor is prepared by uniformly mixing 15-18 parts by weight of methyl hydrogen-containing siloxane emulsion, 15-18 parts by weight of hydroxyl silane emulsion and 5-8 parts by weight of graphene oxide.
The graphene oxide is prepared by any one of a mechanical stripping method, a chemical vapor deposition method and a redox method.
The stabilizer is prepared by uniformly mixing 7-10 parts of ethanolamine and 9-10 parts of cross-linking agent in parts by weight.
The cross-linking agent is hydroxymethyl acrylate or ethyl acrylate.
The acidity regulator is citric acid or acetic acid.
The equipment and other process conditions and parameters used in the present invention are known to those skilled in the art.
The invention also provides the high-temperature cloth prepared by the method for processing the solar cell module.
The high temperature cloth for processing a solar cell module and the preparation method thereof according to the present invention will be further described with reference to the following examples.
Example 1
A preparation method of high-temperature cloth for processing a solar cell module comprises the following steps: firstly, preparing raw materials, preparing a coating material containing graphene, and uniformly coating the coating material on the surface of high-temperature cloth. The components of the coating material comprise graphene compound copolymer mother liquor, a stabilizer, an acidity regulator and water.
Preferably, the components of the coating material comprise 35 parts of graphene compound copolymer mother liquor, 16 parts of stabilizing agent, 0.5 part of acidity regulator and 40 parts of water in parts by weight.
The graphene compound copolymer mother liquor is prepared by uniformly mixing 15 parts of methyl hydrogen-containing siloxane emulsion, 15 parts of hydroxyl silane emulsion and 5 parts of graphene oxide according to parts by weight.
The graphene oxide is prepared by a mechanical exfoliation method.
The stabilizer is prepared by uniformly mixing 7 parts of ethanolamine and 9 parts of cross-linking agent in parts by weight.
The cross-linking agent is hydroxymethyl acrylate. The acidity regulator is citric acid.
The embodiment also provides the high-temperature cloth prepared by the method for processing the solar cell module.
Example 2
A preparation method of high-temperature cloth for processing a solar cell module comprises the following steps: firstly, preparing raw materials, preparing a coating material containing graphene, and uniformly coating the coating material on the surface of high-temperature cloth. The components of the coating material comprise graphene compound copolymer mother liquor, a stabilizer, an acidity regulator and water.
Preferably, the components of the coating material comprise 38 parts of graphene compound copolymer mother liquor, 17 parts of stabilizing agent, 0.8 part of acidity regulator and 42 parts of water in parts by weight.
The graphene compound copolymer mother liquor is prepared by uniformly mixing 16 parts by weight of methyl hydrogen-containing siloxane emulsion, 16 parts by weight of hydroxyl silane emulsion and 6 parts by weight of graphene oxide.
The graphene oxide is prepared by a chemical vapor deposition method.
The stabilizer is prepared by uniformly mixing 8 parts of ethanolamine and 9 parts of cross-linking agent in parts by weight.
The cross-linking agent is ethyl acrylate. The acidity regulator is acetic acid.
The embodiment also provides the high-temperature cloth prepared by the method for processing the solar cell module.
Example 3
A preparation method of high-temperature cloth for processing a solar cell module comprises the following steps: firstly, preparing raw materials, preparing a coating material containing graphene, and uniformly coating the coating material on the surface of high-temperature cloth. The components of the coating material comprise graphene compound copolymer mother liquor, a stabilizer, an acidity regulator and water.
Preferably, the components of the coating material comprise 40 parts of graphene compound copolymer mother liquor, 18 parts of stabilizing agent, 1 part of acidity regulator and 43 parts of water in parts by weight.
The graphene compound copolymer mother liquor is prepared by uniformly mixing 16.5 parts by weight of methyl hydrogen-containing siloxane emulsion, 16.5 parts by weight of hydroxyl silane emulsion and 7 parts by weight of graphene oxide.
The graphene oxide is prepared by a redox method.
The stabilizer is prepared by uniformly mixing 8.5 parts of ethanolamine and 9.5 parts of cross-linking agent in parts by weight.
The cross-linking agent is hydroxymethyl acrylate. The acidity regulator is acetic acid.
The embodiment also provides the high-temperature cloth prepared by the method for processing the solar cell module.
Example 4
A preparation method of high-temperature cloth for processing a solar cell module comprises the following steps: firstly, preparing raw materials, preparing a coating material containing graphene, and uniformly coating the coating material on the surface of high-temperature cloth. The components of the coating material comprise graphene compound copolymer mother liquor, a stabilizer, an acidity regulator and water.
Preferably, the components of the coating material comprise 31.5 parts of graphene compound copolymer mother liquor, 19 parts of stabilizing agent, 1.5 parts of acidity regulator and 44 parts of water in parts by weight.
The graphene compound copolymer mother liquor is prepared by uniformly mixing 17 parts by weight of methyl hydrogen-containing siloxane emulsion, 17 parts by weight of hydroxyl silane emulsion and 7.5 parts by weight of graphene oxide.
The graphene oxide is prepared by a mechanical exfoliation method.
The stabilizer is prepared by uniformly mixing 9 parts of ethanolamine and 10 parts of cross-linking agent in parts by weight.
The cross-linking agent is ethyl acrylate. The acidity regulator is citric acid.
The embodiment also provides the high-temperature cloth prepared by the method for processing the solar cell module.
Example 5
A preparation method of high-temperature cloth for processing a solar cell module comprises the following steps: firstly, preparing raw materials, preparing a coating material containing graphene, and uniformly coating the coating material on the surface of high-temperature cloth. The components of the coating material comprise graphene compound copolymer mother liquor, a stabilizer, an acidity regulator and water.
Preferably, the components of the coating material comprise 44 parts of graphene compound copolymer mother liquor, 20 parts of stabilizing agent, 2 parts of acidity regulator and 45 parts of water in parts by weight.
The graphene compound copolymer mother liquor is prepared by uniformly mixing 18 parts of methyl hydrogen-containing siloxane emulsion, 18 parts of hydroxyl silane emulsion and 8 parts of graphene oxide according to parts by weight.
The graphene oxide is prepared by a redox method.
The stabilizer is prepared by uniformly mixing 10 parts of ethanolamine and 10 parts of cross-linking agent in parts by weight.
The cross-linking agent is hydroxymethyl acrylate or ethyl acrylate.
The acidity regulator is citric acid or acetic acid.
The embodiment also provides the high-temperature cloth prepared by the method for processing the solar cell module.
The high-temperature cloth for processing the solar cell module prepared in each embodiment of the invention is tested, and the specific results are shown in table 1 below.
Table 1 table of test results.
Figure BDA0003436165200000051
Figure BDA0003436165200000061
According to the high-temperature cloth for processing the solar cell module and the preparation method thereof, the surface of the prepared high-temperature cloth contains a layer of coating material made of graphene, so that EVA can be prevented from being adhered to the high-temperature cloth. The EVA adhesive tape has the advantages of reasonable design and simple structure, can effectively prevent EVA from being adhered to high-temperature cloth, and reduces the labor intensity of operators.
While the present invention has been described in detail with reference to the preferred embodiments, it should be understood that the above description should not be taken as limiting the invention. Various modifications and alterations to this invention will become apparent to those skilled in the art upon reading the foregoing description. Accordingly, the scope of the invention should be determined from the following claims.

Claims (8)

1. A preparation method of high-temperature cloth for processing a solar cell module is characterized by comprising the following steps: firstly, preparing raw materials, preparing a coating material containing graphene, and uniformly coating the coating material on the surface of high-temperature cloth; the components of the coating material comprise graphene compound copolymer mother liquor, a stabilizer, an acidity regulator and water.
2. The method according to claim 1, wherein the coating material comprises, by weight, 35-44 parts of graphene compound copolymer mother liquor, 16-20 parts of a stabilizer, 0.5-2 parts of an acidity regulator, and 40-45 parts of water.
3. The method according to claim 2, wherein the graphene compound copolymer mother liquor is prepared by uniformly mixing 15 to 18 parts by weight of methyl hydrogen-containing siloxane emulsion, 15 to 18 parts by weight of hydroxyl silane emulsion and 5 to 8 parts by weight of graphene oxide.
4. The method according to claim 3, wherein the graphene oxide is prepared by any one of a mechanical exfoliation method, a chemical vapor deposition method, and a redox method.
5. The method according to claim 2, wherein the stabilizer is prepared by uniformly mixing 7-10 parts by weight of ethanolamine and 9-10 parts by weight of a cross-linking agent.
6. The method according to claim 5, wherein the crosslinking agent is hydroxymethyl acrylate or ethyl acrylate.
7. The method according to claim 2, wherein the acidity regulator is citric acid or acetic acid.
8. A high-temperature cloth for solar cell module processing prepared by the method of any one of claims 1 to 7.
CN202111613792.6A 2021-12-27 High-temperature cloth for solar cell module processing and preparation method thereof Active CN114381946B (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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CN114381946B CN114381946B (en) 2024-09-27

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101921425A (en) * 2010-08-30 2010-12-22 苏州度辰新材料有限公司 Ethylene vinyl acetate adhesive film and solar battery assembly
JP2016058473A (en) * 2014-09-08 2016-04-21 三井化学東セロ株式会社 Encapsulation sheet for solar cell and solar cell module
CN206076267U (en) * 2016-08-29 2017-04-05 海宁正泰新能源科技有限公司 A kind of slotting master mode for solar module production exempts to clean high temperature cloth
CN107652817A (en) * 2017-10-24 2018-02-02 广东工业大学 A kind of modified graphene oxide/polyacrylate nano-composite coating and preparation method thereof
CN110904686A (en) * 2019-11-28 2020-03-24 浙江圣山科纺有限公司 Application of environment-friendly fluorine-free waterproof agent to umbrella surface cloth

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101921425A (en) * 2010-08-30 2010-12-22 苏州度辰新材料有限公司 Ethylene vinyl acetate adhesive film and solar battery assembly
JP2016058473A (en) * 2014-09-08 2016-04-21 三井化学東セロ株式会社 Encapsulation sheet for solar cell and solar cell module
CN206076267U (en) * 2016-08-29 2017-04-05 海宁正泰新能源科技有限公司 A kind of slotting master mode for solar module production exempts to clean high temperature cloth
CN107652817A (en) * 2017-10-24 2018-02-02 广东工业大学 A kind of modified graphene oxide/polyacrylate nano-composite coating and preparation method thereof
CN110904686A (en) * 2019-11-28 2020-03-24 浙江圣山科纺有限公司 Application of environment-friendly fluorine-free waterproof agent to umbrella surface cloth

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