CN114381146A - Automobile accessory with wear-resistant coating - Google Patents

Automobile accessory with wear-resistant coating Download PDF

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Publication number
CN114381146A
CN114381146A CN202011130477.3A CN202011130477A CN114381146A CN 114381146 A CN114381146 A CN 114381146A CN 202011130477 A CN202011130477 A CN 202011130477A CN 114381146 A CN114381146 A CN 114381146A
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China
Prior art keywords
parts
wear
percent
resistant coating
self
Prior art date
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Withdrawn
Application number
CN202011130477.3A
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Chinese (zh)
Inventor
谢铁华
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Hunan Qianglong Automobile Technology Co ltd
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Hunan Qianglong Automobile Technology Co ltd
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Filing date
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Priority to CN202011130477.3A priority Critical patent/CN114381146A/en
Publication of CN114381146A publication Critical patent/CN114381146A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

Abstract

The invention discloses an automobile part containing a wear-resistant coating, which comprises the automobile part and the wear-resistant coating and is characterized in that the wear-resistant coating is prepared from the following raw materials in parts by weight: 40-50 parts of self-fluxing alloy powder, 20-30 parts of micron chromium oxide powder, 1-3 parts of antimony trioxide powder, 1-3 parts of tin oxide powder, 10-20 parts of binder and 15-20 parts of solid lubricant, wherein the self-fluxing alloy powder comprises the following components in percentage by mass: 0.9 to 1.8 percent of carbon, 2.8 to 7.2 percent of chromium, 0.2 to 0.8 percent of titanium, 8 to 13 percent of tungsten, 0.2 to 0.8 percent of vanadium and the balance of iron or copper. According to the automobile part containing the wear-resistant coating, the wear-resistant coating and the automobile part are mutually fused, the compactness is high, the wear-resistant performance is good, the problem that the bonding strength of the wear-resistant coating and the automobile part is not high can be solved, and the bonding strength of the wear-resistant coating is greatly improved.

Description

Automobile accessory with wear-resistant coating
Technical Field
The invention belongs to the technical field of automobile parts, and particularly relates to an automobile part containing a wear-resistant coating.
Background
The metal material is the most widely used engineering material, but with the increasingly harsh working conditions of engineering equipment, the single metal material has been difficult to meet the engineering use requirements. The wear-resistant coating is coated on the surface of the metal, so that the synthesized composite material can retain the strength and toughness of the metal, has the characteristics of wear resistance, corrosion resistance, high temperature resistance and the like of the coating, and can greatly improve the service performance of the material.
The methods for preparing the composite coating, which are commonly used in the industry at present, include the following methods: self-propagating high temperature synthesis, thermal spray coating, sol-gel process, and the like. The self-propagating high-temperature synthesis method is to use the high chemical reaction heat generated among reactants to promote the reactants to carry out continuous spontaneous chemical reaction to prepare the ceramic coating, and the single self-propagating high-temperature synthesis method can prepare the high-performance composite material coating, but the prepared coating has poor surface precision, and has the problems of uneven surface, gaps and the like. The thermal spraying technology is a coating method of melting and atomizing a coating material at a high temperature to form a particle flow in a molten or semi-molten state, and spraying the particle flow on the surface of a metal steel plate at an extremely high speed, so that a coating with good performances such as wear resistance, hardness and heat conduction can be prepared, and the influence on the thermal deformation of the steel plate is small. The sol-gel method is that metal alkoxide or inorganic salt which is easy to hydrolyze reacts with water in a certain solvent, forms sol through hydrolytic polycondensation, coats the sol on the surface of a metal steel plate, and forms a coating after drying and heat treatment.
Disclosure of Invention
In view of the above, there is a need for an automotive part comprising a wear resistant coating.
The invention aims to solve the technical problems that: the automobile part containing the wear-resistant coating is provided, the wear-resistant coating and the automobile part are mutually fused, and the automobile part is high in compactness and good in wear resistance.
The invention provides an automobile part containing a wear-resistant coating, which comprises the automobile part and the wear-resistant coating and is characterized in that the wear-resistant coating is prepared from the following raw materials in parts by weight: 40-50 parts of self-fluxing alloy powder, 20-30 parts of micron chromium oxide powder, 1-3 parts of antimony trioxide powder, 1-3 parts of tin oxide powder, 10-20 parts of binder and 15-20 parts of solid lubricant, wherein the self-fluxing alloy powder comprises the following components in percentage by mass: 0.9 to 1.8 percent of carbon, 2.8 to 7.2 percent of chromium, 0.2 to 0.8 percent of titanium, 8 to 13 percent of tungsten, 0.2 to 0.8 percent of vanadium and the balance of iron or copper.
In the embodiment of the invention, the adhesive is epoxy resin, and the weight percentage of the epoxy resin is 45-55%; the solid lubricant is molybdenum disulfide and graphite, wherein the weight percentage of the molybdenum disulfide is 15-25%, and the weight percentage of the graphite is 5-10%.
In this embodiment of the invention, the wear resistant coating has a thickness of 20-60 μm.
In the present embodiment of the present invention, the self-fluxing alloy material is selected from one of aluminum bronze and iron-based alloy.
In this embodiment of the present invention, the wear-resistant coating is made of the following raw materials in parts by weight: 45 parts of self-fluxing alloy powder, 25 parts of micron chromium trioxide powder, 2 parts of antimony trioxide powder, 2 parts of tin oxide powder, 15 parts of binder and 16 parts of solid lubricant, wherein the self-fluxing alloy powder comprises the following components in percentage by mass: 1.2 to 1.7 percent of carbon, 3.1 to 6.5 percent of chromium, 0.3 to 0.6 percent of titanium, 9 to 11 percent of tungsten, 0.3 to 0.6 percent of vanadium and the balance of iron.
In this embodiment of the present invention, the wear-resistant coating is made of the following raw materials in parts by weight: 50 parts of self-fluxing alloy powder, 30 parts of micron chromium trioxide powder, 3 parts of antimony trioxide powder, 3 parts of tin oxide powder, 20 parts of binder and 20 parts of solid lubricant, wherein the self-fluxing alloy powder comprises the following components in percentage by mass: 0.9 to 1.6 percent of carbon, 2.9 to 7 percent of chromium, 0.4 to 0.7 percent of titanium, 10 to 13 percent of tungsten, 0.4 to 0.7 percent of vanadium and the balance of copper.
The automobile part containing the wear-resistant coating has the following advantages: the automobile part containing the wear-resistant coating comprises an automobile part and the wear-resistant coating, wherein the wear-resistant coating comprises: the self-fluxing alloy powder comprises the following components in percentage by mass: carbon, chromium, titanium, tungsten, vanadium, and the balance iron or copper. The self-fluxing alloy powder, the micron chromium trioxide powder, the antimony trioxide powder and the tin oxide powder are added with the binder and the solid lubricant, so that the compactness of the wear-resistant layer and the smoothness of the surface of the wear-resistant layer are improved.
The porosity of the coating is reduced, the flatness grade is improved, and the wear resistance of the coating can be further improved.
The automobile part containing the wear-resistant coating has the following advantages: the automobile part containing the wear-resistant coating comprises an automobile part and the wear-resistant coating, wherein the wear-resistant coating comprises: the self-fluxing alloy powder comprises the following components in percentage by mass: carbon, chromium, titanium, tungsten, vanadium, and the balance iron or copper. According to the wear-resistant coating, the self-fluxing alloy powder, the micron chromium oxide powder, the antimony trioxide powder and the tin oxide powder are added with the binder and the solid lubricant, so that the compactness of the wear-resistant layer and the smoothness of the surface of the wear-resistant layer are improved, the porosity of the coating is reduced, the flatness grade is improved, and the wear-resistant strength of the coating can be further improved.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention. It is to be understood that the described embodiments are merely exemplary of the invention, and not restrictive of the full scope of the invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The invention provides an automobile part containing a wear-resistant coating, which comprises the automobile part and the wear-resistant coating and is characterized in that the wear-resistant coating is prepared from the following raw materials in parts by weight: 40-50 parts of self-fluxing alloy powder, 20-30 parts of micron chromium oxide powder, 1-3 parts of antimony trioxide powder, 1-3 parts of tin oxide powder, 10-20 parts of binder and 15-20 parts of solid lubricant, wherein the self-fluxing alloy powder comprises the following components in percentage by mass: 0.9 to 1.8 percent of carbon, 2.8 to 7.2 percent of chromium, 0.2 to 0.8 percent of titanium, 8 to 13 percent of tungsten, 0.2 to 0.8 percent of vanadium and the balance of iron or copper.
In the embodiment of the invention, the adhesive is epoxy resin, and the weight percentage of the epoxy resin is 45-55%; the solid lubricant is molybdenum disulfide and graphite, wherein the weight percentage of the molybdenum disulfide is 15-25%, and the weight percentage of the graphite is 5-10%.
In this embodiment of the invention, the wear resistant coating has a thickness of 20-60 μm.
In the present embodiment of the present invention, the self-fluxing alloy material is selected from one of aluminum bronze and iron-based alloy.
Example 2
The invention provides an automobile part containing a wear-resistant coating, which comprises the automobile part and the wear-resistant coating, wherein the wear-resistant coating is prepared from the following raw materials in parts by weight: 45 parts of self-fluxing alloy powder, 25 parts of micron chromium trioxide powder, 2 parts of antimony trioxide powder, 2 parts of tin oxide powder, 15 parts of binder and 16 parts of solid lubricant, wherein the self-fluxing alloy powder comprises the following components in percentage by mass: 1.2 to 1.7 percent of carbon, 3.1 to 6.5 percent of chromium, 0.3 to 0.6 percent of titanium, 9 to 11 percent of tungsten, 0.3 to 0.6 percent of vanadium and the balance of iron.
In the embodiment of the invention, the adhesive is epoxy resin, and the weight percentage content of the epoxy resin is 45%; the solid lubricant is molybdenum disulfide and graphite, wherein the weight percentage of the molybdenum disulfide is 15%, and the weight percentage of the graphite is 5%.
In this example of the invention, the wear resistant coating thickness was 40 μm.
In the present embodiment of the invention, the self-fluxing alloy material is selected from one of iron-based alloys.
Example 3
The invention provides an automobile part containing a wear-resistant coating, which comprises the automobile part and the wear-resistant coating, wherein the wear-resistant coating is prepared from the following raw materials in parts by weight: 45 parts of self-fluxing alloy powder, 25 parts of micron chromium trioxide powder, 2 parts of antimony trioxide powder, 2 parts of tin oxide powder, 15 parts of binder and 16 parts of solid lubricant, wherein the self-fluxing alloy powder comprises the following components in percentage by mass: 1.2 to 1.7 percent of carbon, 3.1 to 6.5 percent of chromium, 0.3 to 0.6 percent of titanium, 9 to 11 percent of tungsten, 0.3 to 0.6 percent of vanadium and the balance of iron.
In the embodiment of the invention, the adhesive is epoxy resin, and the weight percentage content of the epoxy resin is 55%; the solid lubricant is molybdenum disulfide and graphite, wherein the weight percentage of the molybdenum disulfide is 25%, and the weight percentage of the graphite is 15%.
In this embodiment of the invention, the wear resistant coating is 60 μm thick.
In the present embodiment of the invention, the self-fluxing alloy material is selected from one of iron-based alloys.
Example 4
The invention provides an automobile part containing a wear-resistant coating, which comprises the automobile part and the wear-resistant coating, wherein the wear-resistant coating is prepared from the following raw materials in parts by weight: 45 parts of self-fluxing alloy powder, 25 parts of micron chromium trioxide powder, 2 parts of antimony trioxide powder, 2 parts of tin oxide powder, 15 parts of binder and 16 parts of solid lubricant, wherein the self-fluxing alloy powder comprises the following components in percentage by mass: 1.2 to 1.7 percent of carbon, 3.1 to 6.5 percent of chromium, 0.3 to 0.6 percent of titanium, 9 to 11 percent of tungsten, 0.3 to 0.6 percent of vanadium and the balance of iron.
In the embodiment of the invention, the adhesive is epoxy resin, and the weight percentage of the epoxy resin is 50%; the solid lubricant is molybdenum disulfide and graphite, wherein the weight percentage of the molybdenum disulfide is 20%, and the weight percentage of the graphite is 8%.
In this embodiment of the invention, the wear resistant coating is 4 μm thick.
In the present embodiment of the invention, the self-fluxing alloy material is selected from one of iron-based alloys.
Example 5
In this embodiment of the present invention, the wear-resistant coating is made of the following raw materials in parts by weight: 50 parts of self-fluxing alloy powder, 30 parts of micron chromium trioxide powder, 3 parts of antimony trioxide powder, 3 parts of tin oxide powder, 20 parts of binder and 20 parts of solid lubricant, wherein the self-fluxing alloy powder comprises the following components in percentage by mass: 0.9 to 1.6 percent of carbon, 2.9 to 7 percent of chromium, 0.4 to 0.7 percent of titanium, 10 to 13 percent of tungsten, 0.4 to 0.7 percent of vanadium and the balance of copper.
In the embodiment of the invention, the adhesive is epoxy resin, and the weight percentage content of the epoxy resin is 55%; the solid lubricant is molybdenum disulfide and graphite, wherein the weight percentage of the molybdenum disulfide is 15%, and the weight percentage of the graphite is 5%.
In this embodiment of the invention, the wear resistant coating is 20 μm thick.
In the present embodiment of the invention, the self-fluxing alloy material is selected from one of aluminum bronze.
Example 6
In this embodiment of the present invention, the wear-resistant coating is made of the following raw materials in parts by weight: 50 parts of self-fluxing alloy powder, 30 parts of micron chromium trioxide powder, 3 parts of antimony trioxide powder, 3 parts of tin oxide powder, 20 parts of binder and 20 parts of solid lubricant, wherein the self-fluxing alloy powder comprises the following components in percentage by mass: 0.9 to 1.6 percent of carbon, 2.9 to 7 percent of chromium, 0.4 to 0.7 percent of titanium, 10 to 13 percent of tungsten, 0.4 to 0.7 percent of vanadium and the balance of copper.
In the embodiment of the invention, the adhesive is epoxy resin, and the weight percentage of the epoxy resin is 50%; the solid lubricant is molybdenum disulfide and graphite, wherein the weight percentage of the molybdenum disulfide is 20%, and the weight percentage of the graphite is 8%.
In this embodiment of the invention, the wear resistant coating is 30 μm thick.
In the present embodiment of the invention, the self-fluxing alloy material is selected from one of aluminum bronze.
Example 6
In this embodiment of the present invention, the wear-resistant coating is made of the following raw materials in parts by weight: 50 parts of self-fluxing alloy powder, 30 parts of micron chromium trioxide powder, 3 parts of antimony trioxide powder, 3 parts of tin oxide powder, 20 parts of binder and 20 parts of solid lubricant, wherein the self-fluxing alloy powder comprises the following components in percentage by mass: 0.9 to 1.6 percent of carbon, 2.9 to 7 percent of chromium, 0.4 to 0.7 percent of titanium, 10 to 13 percent of tungsten, 0.4 to 0.7 percent of vanadium and the balance of copper.
In the embodiment of the invention, the adhesive is epoxy resin, and the weight percentage of the epoxy resin is 50%; the solid lubricant is molybdenum disulfide and graphite, wherein the weight percentage of the molybdenum disulfide is 20%, and the weight percentage of the graphite is 8%.
In this embodiment of the invention, the wear resistant coating is 60 μm thick.
In the present embodiment of the invention, the self-fluxing alloy material is selected from one of aluminum bronze.
The automobile part containing the wear-resistant coating has the following advantages: the automobile part containing the wear-resistant coating comprises an automobile part and the wear-resistant coating, wherein the wear-resistant coating comprises: the self-fluxing alloy powder comprises the following components in percentage by mass: carbon, chromium, titanium, tungsten, vanadium, and the balance iron or copper. According to the wear-resistant coating, the self-fluxing alloy powder, the micron chromium oxide powder, the antimony trioxide powder and the tin oxide powder are added with the binder and the solid lubricant, so that the compactness of the wear-resistant layer and the smoothness of the surface of the wear-resistant layer are improved, the porosity of the coating is reduced, the flatness grade is improved, and the wear-resistant strength of the coating can be further improved. The problem that the bonding strength of the wear-resistant coating and automobile parts is not high can be solved, the bonding strength of the wear-resistant coating is greatly improved, and the wear-resistant coating is added on the wear-resistant coating, so that the wear resistance of the coating can be improved, the void ratio can be reduced, and the flatness can be improved. According to the automobile part containing the wear-resistant coating, the wear-resistant coating and the automobile part are mutually fused, so that the compactness is high, and the wear resistance is good.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.

Claims (6)

1. The automobile part containing the wear-resistant coating comprises the automobile part and the wear-resistant coating, and is characterized in that the wear-resistant coating is prepared from the following raw materials in parts by weight: 40-50 parts of self-fluxing alloy powder, 20-30 parts of micron chromium oxide powder, 1-3 parts of antimony trioxide powder, 1-3 parts of tin oxide powder, 10-20 parts of binder and 15-20 parts of solid lubricant, wherein the self-fluxing alloy powder comprises the following components in percentage by mass: 0.9 to 1.8 percent of carbon, 2.8 to 7.2 percent of chromium, 0.2 to 0.8 percent of titanium, 8 to 13 percent of tungsten, 0.2 to 0.8 percent of vanadium and the balance of iron or copper.
2. The automobile part with the wear-resistant coating according to claim 1, wherein: the adhesive is epoxy resin, and the weight percentage content of the adhesive is 45-55%; the solid lubricant is molybdenum disulfide and graphite, wherein the weight percentage of the molybdenum disulfide is 15-25%, and the weight percentage of the graphite is 5-10%.
3. The automobile part comprising the wear-resistant coating according to claim 1, wherein the thickness of the wear-resistant coating is 20-60 μm.
4. The automobile part with the wear-resistant coating according to claim 1, wherein the self-fluxing alloy material is selected from one of aluminum bronze and iron-based alloy.
5. The automobile part containing the wear-resistant coating according to claim 1, wherein the wear-resistant coating is prepared from the following raw materials in parts by weight: 45 parts of self-fluxing alloy powder, 25 parts of micron chromium trioxide powder, 2 parts of antimony trioxide powder, 2 parts of tin oxide powder, 15 parts of binder and 16 parts of solid lubricant, wherein the self-fluxing alloy powder comprises the following components in percentage by mass: 1.2 to 1.7 percent of carbon, 3.1 to 6.5 percent of chromium, 0.3 to 0.6 percent of titanium, 9 to 11 percent of tungsten, 0.3 to 0.6 percent of vanadium and the balance of iron.
6. The automobile part containing the wear-resistant coating according to claim 1, wherein the wear-resistant coating is prepared from the following raw materials in parts by weight: 50 parts of self-fluxing alloy powder, 30 parts of micron chromium trioxide powder, 3 parts of antimony trioxide powder, 3 parts of tin oxide powder, 20 parts of binder and 20 parts of solid lubricant, wherein the self-fluxing alloy powder comprises the following components in percentage by mass: 0.9 to 1.6 percent of carbon, 2.9 to 7 percent of chromium, 0.4 to 0.7 percent of titanium, 10 to 13 percent of tungsten, 0.4 to 0.7 percent of vanadium and the balance of copper.
CN202011130477.3A 2020-10-21 2020-10-21 Automobile accessory with wear-resistant coating Withdrawn CN114381146A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102943199A (en) * 2012-12-12 2013-02-27 江苏新亚特钢锻造有限公司 High-toughness and abrasion-proof laser cladding nickel-base alloy powder and preparation method thereof
CN103090118A (en) * 2013-01-28 2013-05-08 扬州安泰威合金硬面科技有限公司 Wear-resisting and corrosion-resisting alloy coating long and thin composite tube and production method thereof
CN104151993A (en) * 2014-08-27 2014-11-19 富奥汽车零部件股份有限公司 Wear-resistant coating and workpiece with wear-resistant coating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102943199A (en) * 2012-12-12 2013-02-27 江苏新亚特钢锻造有限公司 High-toughness and abrasion-proof laser cladding nickel-base alloy powder and preparation method thereof
CN103090118A (en) * 2013-01-28 2013-05-08 扬州安泰威合金硬面科技有限公司 Wear-resisting and corrosion-resisting alloy coating long and thin composite tube and production method thereof
CN104151993A (en) * 2014-08-27 2014-11-19 富奥汽车零部件股份有限公司 Wear-resistant coating and workpiece with wear-resistant coating

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张剑锋等: "《摩擦磨损与抗磨技术》", 31 May 1993 *

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Application publication date: 20220422