CN114344195B - Antiperspirant composition and antiperspirant cosmetic - Google Patents

Antiperspirant composition and antiperspirant cosmetic Download PDF

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Publication number
CN114344195B
CN114344195B CN202210194205.2A CN202210194205A CN114344195B CN 114344195 B CN114344195 B CN 114344195B CN 202210194205 A CN202210194205 A CN 202210194205A CN 114344195 B CN114344195 B CN 114344195B
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Prior art keywords
parts
polymethylsilsesquioxane
powder
film
sweat
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CN202210194205.2A
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CN114344195A (en
Inventor
毛华丽
雷程玺
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Guangzhou Yuanda Biotechnology Co ltd
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Guangzhou Yuanda Biotechnology Co ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00Anti-perspirants or body deodorants
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions
    • A61K2800/5922At least two compounds being classified in the same subclass of A61K8/18

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

The invention relates to the field of daily chemicals, and provides an antiperspirant composition which consists of polymethyl silsesquioxane oil absorption powder, polymethyl silsesquioxane film forming resin and silicon dioxide; the weight ratio of the polymethylsilsesquioxane oil absorption powder to the polymethylsilsesquioxane film forming resin to the silicon dioxide is 0.8-1.5:3-5:0.5-1.5. The composition is preferably powder with two different effects (film-forming resin and oil-absorbing powder) of polymethylsilsesquioxane and silicon dioxide powder, and the three powders are fully and uniformly mixed according to a certain mass ratio, so that the film-forming and sweat-preventing effects are strong and the sweat-preventing time is long. In addition to forming a soft film to prevent sweat, the sweat can be absorbed effectively. The invention also discloses an antiperspirant cosmetic.

Description

Antiperspirant composition and antiperspirant cosmetic
Technical field:
the invention relates to the field of daily chemicals, in particular to an antiperspirant composition and an antiperspirant cosmetic.
The background technology is as follows:
The most similar products on the market at present are that the resin of the polymethylsilsesquioxane is matched with oil absorption powder to prevent sweat, and the sweat prevention effect is not ideal.
CN201510292344.9 discloses a deodorant antiperspirant composition which is effective for up to 72 hours and comprises an oil absorbing agent selected from the group consisting of aluminum starch octenyl succinate, tapioca starch and polymethylsilsesquioxane; silicon dioxide; antiperspirant agents; an ether compound; and at least one surfactant having an average HLB value of from about 5 to about 12.
CN201910698938.8 discloses a waterproof antiperspirant composition and a sunscreen agent containing the same, the waterproof antiperspirant composition comprises trimethylsiloxysilicate/polymethylsilsesquioxane, tara gum, sodium styrene/acrylic acid (ester) copolymer, polyacrylamide, acrylic acid (ester) and C10-30 alcohol acrylate crosslinked polymer potassium salt and acrylic copolymer. The invention combines trimethylsiloxy silicate/polymethylsilsesquioxane, styrene/acrylic acid (ester) copolymer sodium and polyacrylamide, acrylic acid (ester) and C10-30 alcohol acrylic ester cross-linked polymer potassium salt and Caesalpinia spinosa to form a double-layer film, and the film has a paster-like three-dimensional structure. The defending effect of ultraviolet rays is not reduced when the product is contacted with sweat, grease and the like, meanwhile, the film forming of the product is thicker and more uniform due to the recombination of the spatial structures among molecules when the product is contacted with the sweat and the grease, so that the defending effect of the ultraviolet rays is improved, and meanwhile, the three-dimensional film forming system formed by the product is breathable and comfortable.
The technical problems to be solved by the application are as follows: how to further improve the sweat-proof effect.
The invention comprises the following steps:
In order to solve the problems, the invention provides an antiperspirant composition, which is preferably powder with two different effects (film-forming resin and oil-absorbing powder) of polymethylsilsesquioxane and silicon dioxide powder, wherein the three powders are fully and uniformly mixed according to a certain mass ratio, and can absorb sweat while forming a film to prevent sweat, so that the antiperspirant composition has strong antiperspirant effect and long antiperspirant time. In addition to forming a soft film to prevent sweat, the sweat can be absorbed effectively. The invention also discloses an antiperspirant cosmetic.
The invention is realized by the following technical scheme:
an antiperspirant composition comprises polymethyl silsesquioxane oil absorbing powder, polymethyl silsesquioxane film forming resin, and silicon dioxide;
the weight ratio of the polymethylsilsesquioxane oil absorption powder to the polymethylsilsesquioxane film forming resin to the silicon dioxide is 0.8-1.5:3-5:0.5-1.5.
In the above antiperspirant composition, the polymethylsilsesquioxane oil absorbing powder is of the company Guangzhou standard America
In the antiperspirant compositions described above, the polymethylsilsesquioxane film forming resin is of the Wake companyPMS MK Powder。
In the antiperspirant compositions described above, the silica is available from Wake CorpN 20。
Meanwhile, the invention also discloses an antiperspirant cosmetic, which comprises the following components in parts by weight: 0.5-0.8 part of magnesium stearate; 3-6 parts of cetyl ethyl hexanoate; 3-5 parts of cetyl PEG/PPG-10/1 polydimethylsiloxane; 0.5-3 parts of polydimethylsiloxane (KF-96A-6T); 3-5 parts of polymethyl silsesquioxane film forming resin; 0.8-1.5 parts of polymethylsilsesquioxane oil absorption powder; 0.5-1.5 parts of silicon dioxide; 5-10 parts of titanium dioxide; 0.5-3 parts of a colorant; 0.3-1.2 parts of disteardimonium hectorite; 0.5-5 parts of ethanol; 4-8 parts of glycerol; 4-8 parts of 1, 3-butanediol; 0.5-2 parts of sodium chloride; 25-40 parts of water; 0.3-0.8 part of phenoxyethanol.
The beneficial effects of the invention are as follows:
The composition of the invention is preferably powder with two different effects (film-forming resin and oil-absorbing powder) of polymethylsilsesquioxane and silicon dioxide powder, and the three powders are fully and uniformly mixed according to a certain mass ratio, so that the composition can form a film and prevent sweat and absorb sweat, and the sweat-preventing effect is strong and the sweat-preventing time is long. In addition to forming a soft film to prevent sweat, the sweat can be absorbed effectively. The invention also discloses an antiperspirant cosmetic.
Drawings
Fig. 1 is an initial photograph of oily skin;
FIG. 2 is a skin view of the product of example 1 (left) after combined use and without use (right);
FIG. 3 is a skin chart of example 1 (left) after combined use and comparative example 1 (right) after use;
FIG. 4 is a skin chart of example 1 (left) after combined use and comparative example 2 (right) after use;
FIG. 5 is a skin chart of example 1 (left) after combined use and comparative example 3 after use (right);
FIG. 6 is a skin chart of example 1 after 4 hours of use;
Fig. 7 is a skin chart of example 18 h after use.
The specific embodiment is as follows:
The embodiments described below are intended to be further illustrative of the invention and not limiting, and any variations based on the gist of the invention that would be understood by a person skilled in the art are within the scope of the invention.
Preparation process
The preparation process of all examples and comparative examples of the present invention is as follows:
① The components are as follows: adding magnesium stearate, cetyl ethyl hexanoate, cetyl PEG/PPG-10/1 polydimethylsiloxane, polymethylsilsesquioxane (resin), polymethylsilsesquioxane (powder), silicon dioxide, titanium dioxide, colorant, distearyldimethyl ammonium hectorite and ethanol into oil phase, heating to 80-85deg.C, homogenizing, and keeping temperature;
② Adding glycerol, 1, 3-butanediol, sodium chloride and water into water phase, heating to 80-85 deg.C, dissolving, and maintaining the temperature;
③ Slowly pouring the water phase into the oil phase, uniformly stirring, homogenizing, emulsifying completely, cooling to about 50 ℃, adding phenoxyethanol, and uniformly stirring.
Examples 1 to 3
Preparation method reference preparation process the formulations of examples 1-3 can be referred to in table 1 below.
Table 1 formulation tables of examples 1-3
Examples 4 to 6
Preparation method reference preparation process the formulations of examples 4-6 can be referred to in table 1 below.
Table 2 formulation tables of examples 4-6
Comparative examples 1 to 2
The formulation table of comparative examples 1-2 can be referred to Table 3
Table 3 formulation of comparative examples 1-2
Performance testing
Oil absorption test
The test method is as follows: oily skin, corresponding products were applied by applying to example 1, comparative example 2, comparative example 3 and blank. And observing the dryness of the smeared skin.
Second, oil control performance test
The test method is as follows: after the corresponding products are smeared for 4 hours and 8 hours, the dryness of the smeared skin is observed.
Test results
1. Skin picture visible fig. 1 is skin without any treatment, visible oil; the left side of fig. 2 shows the effect after using example 1, and the right side shows the skin without any treatment; as can be seen from fig. 2, the product shown in the examples has an oil absorbing effect.
2. The left side of fig. 3 shows the effect after using example 1, and the right side shows the effect after using comparative example 1; the left side of FIG. 4 shows the effect after using example 1, and the right side shows the effect after using comparative example 2; the left side of fig. 5 shows the effect after using example 1, and the right side shows the effect after using comparative example 3. From the three figures, it can be seen that the oil absorption effect of the products shown in the examples is better than that of the comparative examples.
3. Fig. 6 is a picture after 4 hours of use of example 1, and fig. 7 is a picture after 8 hours of use of example 1; the skin is extremely slight in oil after 4 hours, and slight oil appears after 8 hours, so that the oil control effect is obvious.
Conclusion:
1. the test of example 1 and comparative example 1 led to the conclusion that: the polymethylsilsesquioxane (resin) is important for improving the oil absorption and control effect, is used as a main component of film formation, has the auxiliary effect of oil absorption, and can obviously improve the oil absorption and control effect when being matched with the polymethylsilsesquioxane (powder).
2. The test of example 1 and comparative example 2 led to the conclusion that: the polymethylsilsesquioxane (powder) is indispensable as a main component of oil absorption, and the oil control effect is remarkably deteriorated due to the lack of the component.
3. The test of example 1 and comparative example 3 led to the conclusion that: in the cosmetic system of the present invention, the polydimethylsiloxane can promote the film formation of the polymethylsilsesquioxane (resin), which is effective for improving the film formation of the polymethylsilsesquioxane (resin) and oil absorption and control effects.

Claims (1)

1. An antiperspirant cosmetic characterized by: comprises the following components in parts by weight: 0.5-0.8 part of magnesium stearate; 3-6 parts of cetyl ethyl hexanoate; 3-5 parts of cetyl PEG/PPG-10/1 polydimethylsiloxane; 0.5-3 parts of polydimethylsiloxane; 3-5 parts of polymethyl silsesquioxane film forming resin; 0.8-1.5 parts of polymethylsilsesquioxane oil absorption powder; 0.5-1.5 parts of silicon dioxide; 5-10 parts of titanium dioxide; 0.5-3 parts of a colorant; 0.3-1.2 parts of disteardimonium hectorite; 0.5-5 parts of ethanol; 4-8 parts of glycerol; 4-8 parts of 1, 3-butanediol; 0.5-2 parts of sodium chloride; 25-40 parts of water; 0.3-0.8 part of phenoxyethanol; the polymethylsilsesquioxane oil absorption powder is Cosmethicone SF-6066 of Guangzhou standard and Mei company; the polymethylsilsesquioxane film-forming resin is BELSIL ℃ PMS MK Powder of Wake company; the silicon dioxide is HDK cube N20 of Wake company.
CN202210194205.2A 2022-02-28 2022-02-28 Antiperspirant composition and antiperspirant cosmetic Active CN114344195B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111603402A (en) * 2020-04-20 2020-09-01 广东汉谱科技有限公司 Silicon powder composite gel with oil control, protection and moistening effects and preparation method thereof
CN112675054A (en) * 2020-12-26 2021-04-20 广州集妍化妆品科技有限公司 Film-forming oil-control composition and cosmetic
CN113350228A (en) * 2021-06-28 2021-09-07 广州卡迪莲化妆品科技有限公司 Makeup pre-emulsion capable of improving dullness of foundation makeup
CN114042023A (en) * 2021-12-01 2022-02-15 浙江宜格企业管理集团有限公司 Cosmetic film-forming composition with lotus leaf effect

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102211786B1 (en) * 2019-01-03 2021-02-04 씨큐브 주식회사 Composition for cosmetics having improved water absorbability and oil absorbability

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111603402A (en) * 2020-04-20 2020-09-01 广东汉谱科技有限公司 Silicon powder composite gel with oil control, protection and moistening effects and preparation method thereof
CN112675054A (en) * 2020-12-26 2021-04-20 广州集妍化妆品科技有限公司 Film-forming oil-control composition and cosmetic
CN113350228A (en) * 2021-06-28 2021-09-07 广州卡迪莲化妆品科技有限公司 Makeup pre-emulsion capable of improving dullness of foundation makeup
CN114042023A (en) * 2021-12-01 2022-02-15 浙江宜格企业管理集团有限公司 Cosmetic film-forming composition with lotus leaf effect

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
防晒增效途径的探讨;赵金虎;陈庆生;陈宇霞;孟潇;龚盛昭;;广东化工(第09期);140-141 *

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