CN114324281A - Soil organic pollutant is fluorescence collection device for in situ monitoring analysis - Google Patents
Soil organic pollutant is fluorescence collection device for in situ monitoring analysis Download PDFInfo
- Publication number
- CN114324281A CN114324281A CN202111661561.2A CN202111661561A CN114324281A CN 114324281 A CN114324281 A CN 114324281A CN 202111661561 A CN202111661561 A CN 202111661561A CN 114324281 A CN114324281 A CN 114324281A
- Authority
- CN
- China
- Prior art keywords
- fluorescence
- lens
- optical
- module
- light
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Landscapes
- Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)
Abstract
The invention discloses a fluorescence collecting device for in-situ monitoring and analysis of soil organic pollutants, which comprises a shell, and a light source module, a preposed fluorescence collecting module, a fluorescence imaging module and a spectrum detection module which are arranged in the shell in sequence from bottom to top, wherein an optical window is arranged on the side wall of the shell at one side of the preposed fluorescence collecting module, and the soil to be detected is placed outside the optical window; the method is simple and convenient to measure, does not need complex operations such as sample collection, laboratory pretreatment and the like, realizes synchronous collection of the fluorescence image and the three-dimensional fluorescence spectrum through the combined work of the imaging camera and the optical fiber coupling probe system, realizes the integrated measurement of the fluorescence image and the three-dimensional fluorescence spectrum, more comprehensively obtains the spectral characteristic information of the soil organic pollutants, and improves the accuracy and the reliability of detection.
Description
Technical Field
The invention relates to the field of environmental detection, in particular to a fluorescence collecting device for in-situ monitoring and analysis of soil organic pollutants.
Background
Polycyclic aromatic hydrocarbon toxic organic substances PAHs are typical pollutants of soil in China, and the pollution degree of the PAHs is second to that of heavy metals. PAHs are easy to be adsorbed by soil particles for long-term accumulation to form persistent environmental pollutants, and are subjected to carcinogenic, teratogenic, genogenic mutation and other hazards to a human body through migration and enrichment of food chains, and are listed as priority pollutants in the soil pollution risk control standard of soil environmental quality agricultural land. The soil pollution control action plan issued by the state institute clearly provides that organic pollutants such as polycyclic aromatic hydrocarbons and petroleum hydrocarbons in soil are monitored in a key mode, a soil environment monitoring technical system is perfected, and the county and county full coverage of soil environment quality monitoring points is achieved. Therefore, the rapid and effective monitoring of soil PAHs pollution is the foundation of soil pollution investigation, control, treatment and restoration, and the building of a soil quality monitoring network is the premise of mastering the soil pollution condition and developing the soil treatment and restoration work.
At present, the soil PAHs detection is mainly based on laboratory analysis and is assisted by on-site rapid detection. In the laboratory analysis, PAHs multi-component detection is realized by field sampling and laboratory gas-liquid chromatography, mass spectrum and the like, but the operation is complex, the detection efficiency is low, and the rapid in-situ detection of the PAHs in the soil is difficult to realize.
The soil PAHs can be rapidly detected on site by portable gas chromatography-mass spectrometry, infrared spectrometry and the like. The portable gas chromatography-mass spectrometry measurement system can realize field analysis of the PAHs by combining purging and trapping, but the field application range is limited by the problems of poor separation degree and accuracy, high field carrier gas supply, auxiliary equipment operation, high power consumption and the like. The infrared reflection spectrum can be used for quantitative analysis of organic pollution of hydrocarbons such as soil diesel oil, gasoline and the like, but PAHs molecular functional group vibration modes are weak and wide bands are overlapped, so that the infrared reflection spectrum cannot be used for multi-component synchronous detection of PAHs.
Therefore, in order to timely and comprehensively master the soil PAHs pollution condition, research and development of a technology for rapidly measuring the total organic pollution amount and the content of each component of the soil PAHs in situ is urgently needed.
Disclosure of Invention
In order to solve the existing problems, the invention provides a fluorescence collecting device for in-situ monitoring and analysis of soil organic pollutants, which has the following specific scheme:
a fluorescence collection device for in-situ monitoring and analysis of soil organic pollutants comprises a shell, and a light source module, a pre-fluorescence collection module, a fluorescence imaging module and a spectrum detection module which are arranged in the shell in sequence from bottom to top, wherein an optical window is arranged on the side wall of the shell on one side of the pre-fluorescence collection module, and soil to be detected is placed on the outer side of the optical window;
the light source module is used for emitting monochromatic light with different wavelengths for multiple times;
the preposed fluorescence collection module is used for collecting fluorescence obtained by exciting soil pollutants by monochromatic light with different wavelengths, reflecting the fluorescence into the fluorescence imaging module and transmitting the fluorescence into the spectrum detection module through an optical fiber;
the fluorescence imaging module is used for obtaining and presenting ultraviolet visible fluorescence images of soil pollutants excited by monochromatic light with different wavelengths;
the spectrum detection module is used for obtaining a three-dimensional fluorescence spectrum.
Preferably, the light source module comprises a plurality of LED monochromatic light sources with different wavelengths, which are fixed at the bottom end of the shell in sequence from one side to the other side;
a first collimating lens is arranged right above each monochromatic light source, and each first collimating lens is arranged at the same height;
a total reflection mirror forming an angle of 45 degrees with the horizontal plane is arranged right above each collimating lens I, and the total reflection mirrors are sequentially lifted from one side to the other side;
a plurality of optical mirrors are sequentially arranged on the outer side of the side with the lowest height of the total reflection mirror from bottom to top, and the arrangement heights of the optical mirrors from bottom to top sequentially correspond to the total reflection mirror from the lowest height to the highest height one by one;
the optical mirrors positioned at the lowest part and the uppermost part are total reflection mirrors, and the optical mirrors positioned at the middle of the lowest part and the uppermost part are dichroic mirrors;
all the optical mirrors below the uppermost optical mirror are arranged in parallel to a total reflection mirror which is arranged right above the collimating lens and forms an angle of 45 degrees with the horizontal direction; the uppermost optical lens and the lower optical lens are arranged at an angle of 90 degrees;
the light emitted by each LED monochromatic light source is projected onto the upper total reflector after passing through the corresponding collimating lens I above, the light source on the total reflector is reflected onto the optical lens arranged at the same height, and the optical lens at the same height projects the light source upwards until the light source is projected onto the optical lens at the highest position for reflection;
and the optical lens at the highest position is sequentially fixed with a collecting lens and an optical window at the obliquely upper position of the side of the total reflector, and the optical lens at the highest position projects light projected on the optical lens through the collecting lens and then the optical window onto the soil to be detected so as to carry out an excitation test.
Preferably, the dichroic mirrors arranged at the same height as the total reflection mirrors corresponding to the LED monochromatic light sources with different wavelengths only reflect monochromatic light with the wavelength and do not pass through the dichroic mirrors, but the other dichroic mirrors above the dichroic mirrors can transmit light with the wavelength.
Preferably, the pre-fluorescence collection module is located in the shell inside the optical window, and the pre-fluorescence collection module comprises a filter, a lens, a semi-transparent semi-reflective mirror, a focusing lens and an optical fiber which are sequentially arranged in a direction deviating from the optical window, wherein the filter, the lens and the focusing lens are vertically arranged, and the semi-transparent semi-reflective mirror is obliquely arranged at an angle of 45 degrees with the horizontal plane;
monochromatic light projected onto detected soil from the light source module is excited by organic pollutants in the polluted soil to form polychromatic light, the polychromatic light is projected into the preposed fluorescence collection module from the optical window, the polychromatic light is projected onto the semi-transparent semi-reflecting mirror after sequentially passing through the filter and the lens, the light reflected on the semi-transparent semi-reflecting mirror enters the fluorescence imaging module, and the light transmitted on the semi-transparent semi-reflecting mirror is focused by the focusing lens and then is transmitted to the spectrum detection module through the optical fiber.
Preferably, the fluorescence imaging module comprises an imaging lens group and an ultraviolet enhanced ICCD detector which are sequentially arranged from bottom to top;
the light reflected on the semi-transparent semi-reflecting mirror firstly enters the imaging lens group, and the imaging lens group projects the transmitted light onto the ultraviolet enhanced ICCD detector, so that an ultraviolet visible fluorescence image is formed.
Preferably, the spectrum detection module comprises a second collimating lens, a grating, an imaging lens and a back-illuminated CCD, the grating and the second collimating lens are oppositely arranged, the grating is located at the lowest part of the spectrum detection module, and the back-illuminated CCD and the imaging lens are vertically and oppositely arranged at two sides of the grating and the second collimating lens;
the multi-color light projected by the optical fiber is firstly projected into the collimating lens II, the collimating lens II projects the multi-color light onto the grating, the grating is used for dispersing the multi-color light into monochromatic light with different spectrums and projecting the monochromatic light onto the imaging lens, and the imaging lens projects the monochromatic light with different spectrums onto the back-illuminated CCD for polymerization, so that a three-dimensional fluorescence spectrum is formed through the back-illuminated CCD.
The invention has the beneficial effects that:
the invention has simple and convenient measurement, does not need complex operations such as sample collection, laboratory pretreatment and the like, takes the high-power LED with multiple wavelengths and narrow bands as an excitation light source, realizes micro ultraviolet-visible continuous spectrum collection by using the plane diffraction grating, the collimating lens and the back-illuminated CCD, simultaneously realizes ultraviolet-visible fluorescence image acquisition by taking the ultraviolet enhanced ICCD as a detector, and has simple integral structure and high detection sensitivity. Synchronous acquisition of a fluorescence image and a three-dimensional fluorescence spectrum is realized through combined work of an imaging camera and an optical fiber coupling probe system, integrated measurement of the fluorescence image and the three-dimensional fluorescence spectrum is realized, spectral characteristic information of organic pollutants in soil is obtained more comprehensively, and accuracy and reliability of detection are improved.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, and it is obvious that the drawings in the following description are some embodiments of the present invention, and those skilled in the art can also obtain other drawings according to the drawings without creative efforts.
FIG. 1 is a view showing the structure of the apparatus of the present invention.
The reference numbers are as follows:
1. the device comprises a light source module, 101, an LED monochromatic light source, 102, a first collimating lens, 103, a total reflector, 104, an optical lens, 105, a condenser, 2, a pre-fluorescence collection module, 201, a filter, 202, a lens, 203, a half-mirror, 204, a focusing lens, 205, an optical fiber, 3, a fluorescence imaging module, 301, an imaging lens group, 302, an ultraviolet enhanced ICCD detector, 4, a spectrum detection module, 401, a second collimating lens, 402, a grating, 403, an imaging lens, 404, a back-illuminated CCD, 5, an optical window, 6 and a shell.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are some, but not all, embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
As shown in figure 1, the fluorescence collection device for in-situ monitoring and analysis of soil organic pollutants comprises a shell 6, and a light source module 1, a preposed fluorescence collection module 2, a fluorescence imaging module 3 and a spectrum detection module 4 which are arranged in the shell 6 and are sequentially arranged from bottom to top, wherein an optical window 5 is arranged on the side wall of the shell 6 on one side of the preposed fluorescence collection module 2, and soil to be detected is placed outside the optical window 5.
The light source module 1 is used for emitting monochromatic light with different wavelengths for multiple times. The light source module 1 includes a plurality of LED monochromatic light sources 101 having different wavelengths, which are sequentially fixed at the bottom end of the housing 6 from one side to the other.
A first collimating lens 102 is arranged right above each monochromatic light source, and each first collimating lens 102 is arranged at the same height.
And a total reflection mirror 103 forming an angle of 45 degrees with the horizontal is arranged right above each collimating lens I102, and the total reflection mirrors 103 rise from one side to the other side in sequence.
The outer side of the side with the lowest height of the total reflection mirrors 103 is sequentially provided with a plurality of optical mirrors 104 from bottom to top, and the heights of the optical mirrors 104 from bottom to top are sequentially in one-to-one correspondence with the total reflection mirrors 103 from the lowest height to the highest height.
And the optical mirror 104 positioned at the lowermost and uppermost positions is a total reflection mirror, and the optical mirror 104 positioned at the lowermost and uppermost middle positions is a dichroic mirror.
All the optical mirrors 104 positioned below the uppermost optical mirror 104 are arranged in parallel to the total reflection mirror 103 which is right above the collimating lens I102 and forms an angle of 45 degrees with the horizontal plane; and the uppermost optic 104 is disposed at a 90 degree angle to the lower optic 104.
The light emitted by each LED monochromatic light source 101 is projected onto the upper total reflector 103 after passing through the corresponding collimating lens I102, the light source on the total reflector 103 is reflected onto the optical lens 104 arranged at the same height, and the optical lens 104 at the same height projects the light source upwards until the light source is projected onto the optical lens 104 at the highest position for reflection.
The optical lens 104 at the highest position is sequentially fixed with a collecting lens 105 and an optical window 5 at an obliquely upper position on the side of the total reflection mirror 103, and the optical lens 104 at the highest position projects light projected thereon onto the soil to be detected through the optical window 5 after passing through the collecting lens 105, so as to carry out an excitation test.
The dichroic mirrors arranged at the same height of the total reflection mirrors 103 corresponding to the LED monochromatic light sources 101 with different wavelengths only reflect monochromatic light with the wavelength and do not pass through the dichroic mirrors, but the rest of the dichroic mirrors above the dichroic mirrors can transmit the light with the wavelength.
The pre-fluorescence collection module 2 is used for collecting fluorescence obtained by exciting soil pollutants with monochromatic light of different wavelengths, reflecting the fluorescence to the fluorescence imaging module 3, and transmitting the fluorescence to the spectrum detection module 4 through the optical fiber 205. The prepositive fluorescence collection module 2 is positioned in the shell 6 at the inner side of the optical window 5, the prepositive fluorescence collection module 2 comprises a filter 201, a lens 202, a semi-transparent semi-reflecting mirror 203, a focusing lens 204 and an optical fiber 205 which are sequentially arranged in a direction departing from the optical window 5, the filter 201, the lens 202 and the focusing lens 204 are vertically arranged, and the semi-transparent semi-reflecting mirror 203 and a horizontal plane are obliquely arranged at an angle of 45 degrees.
Monochromatic light projected onto detected soil from the light source module 1 is excited by organic pollutants in the polluted soil to form polychromatic light, the polychromatic light is projected into the preposed fluorescence collection module 2 from the optical window 5, the polychromatic light is projected onto the semi-transparent semi-reflecting mirror 203 after sequentially passing through the filter 201 and the lens 202, light reflected on the semi-transparent semi-reflecting mirror 203 enters the fluorescence imaging module 3, and light transmitted on the semi-transparent semi-reflecting mirror 203 is focused by the focusing lens 204 and then is transmitted into the spectrum detection module 4 through the optical fiber 205.
The fluorescence imaging module 3 is used for obtaining and presenting ultraviolet visible fluorescence images of soil pollutants excited by monochromatic light with different wavelengths; the fluorescence imaging module 3 comprises an imaging lens group 301 and an ultraviolet enhanced ICCD detector 302 which are arranged in sequence from bottom to top.
The light reflected by the half mirror 203 firstly enters the imaging lens group 301, and the imaging lens group 301 projects the transmitted light onto the ultraviolet enhanced ICCD detector 302, so as to form an ultraviolet visible fluorescence image.
The spectrum detection module 4 is used for obtaining a three-dimensional fluorescence spectrum. The spectrum detection module 4 comprises a second collimating lens 401, a grating 402, an imaging lens 403 and a back-illuminated CCD404, wherein the grating 402 and the second collimating lens 401 are oppositely arranged, the grating 402 is positioned at the lowest part of the spectrum detection module 4, and the back-illuminated CCD404 and the imaging lens 403 are vertically and oppositely arranged at two sides of the grating 402 and the second collimating lens 401.
The polychromatic light projected by the optical fiber 205 is firstly projected into a second collimating lens 401, the second collimating lens 401 projects the polychromatic light onto a grating 402, the grating 402 is used for dispersing the polychromatic light into monochromatic light with different spectrums and projecting the monochromatic light onto an imaging lens 403, and the imaging lens 403 projects the monochromatic light with different spectrums onto a back-illuminated CCD404 for polymerization, so that a three-dimensional fluorescence spectrum is formed through the back-illuminated CCD 404.
The invention has simple and convenient measurement, does not need complex operations such as sample collection, laboratory pretreatment and the like, takes the high-power LED with multiple wavelengths and narrow bands as an excitation light source, realizes micro ultraviolet-visible continuous spectrum collection by using the plane diffraction grating, the collimating lens and the back-illuminated CCD, simultaneously realizes ultraviolet-visible fluorescence image acquisition by taking the ultraviolet enhanced ICCD as a detector, and has simple integral structure and high detection sensitivity. Synchronous acquisition of a fluorescence image and a three-dimensional fluorescence spectrum is realized through combined work of an imaging camera and an optical fiber coupling probe system, integrated measurement of the fluorescence image and the three-dimensional fluorescence spectrum is realized, spectral characteristic information of organic pollutants in soil is obtained more comprehensively, and accuracy and reliability of detection are improved.
Although the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; and such modifications or substitutions do not depart from the spirit and scope of the corresponding technical solutions of the embodiments of the present invention.
Claims (6)
1. The utility model provides a soil organic pollutant is fluorescence collection device for in situ monitoring analysis which characterized in that: the device comprises a shell (6), and a light source module (1), a preposed fluorescence collection module (2), a fluorescence imaging module (3) and a spectrum detection module (4) which are arranged in the shell (6) in sequence from bottom to top, wherein an optical window (5) is arranged on the side wall of the shell (6) on one side of the preposed fluorescence collection module (2), and soil to be detected is placed on the outer side of the optical window (5);
the light source module (1) is used for emitting monochromatic light with different wavelengths for multiple times;
the preposed fluorescence collection module (2) is used for collecting fluorescence obtained by exciting soil pollutants by monochromatic light with different wavelengths, reflecting the fluorescence into the fluorescence imaging module (3), and transmitting the fluorescence into the spectrum detection module (4) through an optical fiber (205);
the fluorescence imaging module (3) is used for obtaining and presenting ultraviolet visible fluorescence images of soil pollutants excited by monochromatic light with different wavelengths;
the spectrum detection module (4) is used for obtaining a three-dimensional fluorescence spectrum.
2. The fluorescence collecting device for in-situ monitoring and analysis of soil organic pollutants according to claim 1, characterized in that: the light source module (1) comprises a plurality of LED monochromatic light sources (101) with different wavelengths, which are fixed at the bottom end of the shell (6) from one side to the other side in sequence;
a first collimating lens (102) is arranged right above each monochromatic light source, and each first collimating lens (102) is arranged at the same height;
a total reflection mirror (103) forming an angle of 45 degrees with the horizontal is arranged right above each collimating lens I (102), and the total reflection mirrors (103) rise from one side to the other side in sequence;
a plurality of optical mirrors (104) are sequentially arranged on the outer side of the side, with the lowest height, of the total reflecting mirror (103) from bottom to top, and the arrangement heights of the optical mirrors (104) from bottom to top sequentially correspond to the total reflecting mirror (103) from the lowest height to the highest height one by one;
the optical mirror (104) positioned at the lowest part and the uppermost part is a total reflection mirror, and the optical mirror (104) positioned at the middle of the lowest part and the uppermost part is a dichroic mirror;
all the optical mirrors (104) below the uppermost optical mirror (104) are arranged in parallel to a total reflection mirror (103) which is arranged right above the collimating lens I (102) and forms an angle of 45 degrees with the horizontal plane; the uppermost optical lens (104) and the lower optical lens (104) are arranged at an angle of 90 degrees;
the light emitted by each LED monochromatic light source (101) passes through the corresponding collimating lens I (102) above and then is projected onto the total reflecting mirror (103) above, the light source on the total reflecting mirror (103) is reflected onto the optical mirror (104) arranged at the same height, and the optical mirror (104) at the same height projects the light source upwards until the light source is projected onto the optical mirror (104) at the highest position for reflection;
a collecting lens (105) and an optical window (5) are sequentially fixed on the optical lens (104) at the highest position in an obliquely upward position on the side of the total reflection lens (103), and light projected on the optical lens (104) at the highest position passes through the collecting lens (105) and then is projected on the detected soil through the optical window (5) to carry out an excitation test.
3. The fluorescence collecting device for in-situ monitoring and analysis of soil organic pollutants according to claim 2, characterized in that: the dichroic mirrors which are arranged at the same height of the total reflection mirrors (103) corresponding to the LED monochromatic light sources (101) with different wavelengths only reflect monochromatic light with the wavelength but do not pass through the dichroic mirrors, and the rest dichroic mirrors above the dichroic mirrors can transmit the light with the wavelength.
4. The fluorescence collecting device for in-situ monitoring and analysis of soil organic pollutants according to claim 1, characterized in that: the preposed fluorescence collection module (2) is positioned in a shell (6) on the inner side of the optical window (5), the preposed fluorescence collection module (2) comprises a filter (201), a lens (202), a semi-transparent semi-reflecting mirror (203), a focusing lens (204) and an optical fiber (205) which are sequentially arranged in a direction deviating from the optical window (5), the filter (201), the lens (202) and the focusing lens (204) are vertically arranged, and the semi-transparent semi-reflecting mirror (203) is obliquely arranged at an angle of 45 degrees with the horizontal plane;
follow monochromatic light that light source module (1) was projected on being detected soil is excited through the organic pollutant in the contaminated soil and is formed polychromatic light, and follow optical window (5) are thrown into leading fluorescence collection module (2), polychromatic light loops through filter (201) with throw behind the lens on semi-transparent semi-reflecting mirror (203), the light that reflects on semi-transparent semi-reflecting mirror (203) gets into fluorescence imaging module (3), the light that sees through on semi-transparent semi-reflecting mirror (203) passes through behind focusing lens (204) focus by optic fibre (205) transmit in spectrum detection module (4).
5. The fluorescence collecting device for in-situ monitoring and analysis of soil organic pollutants according to claim 1, characterized in that: the fluorescence imaging module (3) comprises an imaging lens group (301) and an ultraviolet enhanced ICCD detector (302) which are sequentially arranged from bottom to top;
the light reflected on the half-transmitting and half-reflecting mirror (203) firstly enters the imaging lens group (301), and the imaging lens group (301) projects the transmitted light to the ultraviolet enhanced ICCD detector (302), so that an ultraviolet visible fluorescence image is formed.
6. The fluorescence collecting device for in-situ monitoring and analysis of soil organic pollutants according to claim 1, characterized in that: the spectrum detection module (4) comprises a second collimating lens (401), a grating (402), an imaging lens (403) and a back-illuminated CCD (404), wherein the grating (402) and the second collimating lens (401) are oppositely arranged, the grating (402) is positioned at the lowest part of the spectrum detection module (4), and the back-illuminated CCD (404) and the imaging lens (403) are vertically and oppositely arranged at two sides of the grating (402) and the second collimating lens (401);
the polychromatic light projected by the optical fiber (205) is firstly projected into the second collimating lens (401), the second collimating lens (401) projects the polychromatic light onto the grating (402), the grating (402) is used for dispersing the polychromatic light into monochromatic light with different spectrums and projecting the monochromatic light onto the imaging lens (403), and the imaging lens (403) projects the monochromatic light with different spectrums onto the back-illuminated CCD (404) for polymerization, so that a three-dimensional fluorescence spectrum is formed through the back-illuminated CCD (404).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111661561.2A CN114324281A (en) | 2021-12-30 | 2021-12-30 | Soil organic pollutant is fluorescence collection device for in situ monitoring analysis |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111661561.2A CN114324281A (en) | 2021-12-30 | 2021-12-30 | Soil organic pollutant is fluorescence collection device for in situ monitoring analysis |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114324281A true CN114324281A (en) | 2022-04-12 |
Family
ID=81019058
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111661561.2A Pending CN114324281A (en) | 2021-12-30 | 2021-12-30 | Soil organic pollutant is fluorescence collection device for in situ monitoring analysis |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114324281A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115290619A (en) * | 2022-08-05 | 2022-11-04 | 南京贻润环境科技有限公司 | Method and device for detecting colloidal active carbon in soil or underground water |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5548115A (en) * | 1995-09-29 | 1996-08-20 | U.S. Army Corps Of Engineers As Represented By The Secretary Of The Army | Probe device for detecting contaminants in subsurface media |
| CN107703616A (en) * | 2016-08-08 | 2018-02-16 | 大连光耀辉科技有限公司 | Multi-channel laser output equipment and fluorescence microscope |
| CN109060755A (en) * | 2018-10-19 | 2018-12-21 | 南京贻润环境科技有限公司 | A kind of soil pollution real-time in-situ detection device based on laser fluorescence inductive technology |
| CN109374590A (en) * | 2018-11-28 | 2019-02-22 | 西北大学 | A kind of hand-held skin canceration early stage optical detection apparatus and its application method |
| CN109827946A (en) * | 2019-02-28 | 2019-05-31 | 华北水利水电大学 | Soil constituent in-situ analysis system and method |
| CN209103019U (en) * | 2018-11-28 | 2019-07-12 | 上海复享光学股份有限公司 | Laser beam merging apparatus |
| CN110441235A (en) * | 2019-09-13 | 2019-11-12 | 中国科学院新疆理化技术研究所 | A kind of Multiple modes coupling original position microspectrum imaging system |
| CN112859315A (en) * | 2021-01-11 | 2021-05-28 | 北京大学 | Multicolor dual-mode structured light illumination microscopic imaging system and imaging method thereof |
-
2021
- 2021-12-30 CN CN202111661561.2A patent/CN114324281A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5548115A (en) * | 1995-09-29 | 1996-08-20 | U.S. Army Corps Of Engineers As Represented By The Secretary Of The Army | Probe device for detecting contaminants in subsurface media |
| CN107703616A (en) * | 2016-08-08 | 2018-02-16 | 大连光耀辉科技有限公司 | Multi-channel laser output equipment and fluorescence microscope |
| CN109060755A (en) * | 2018-10-19 | 2018-12-21 | 南京贻润环境科技有限公司 | A kind of soil pollution real-time in-situ detection device based on laser fluorescence inductive technology |
| CN109374590A (en) * | 2018-11-28 | 2019-02-22 | 西北大学 | A kind of hand-held skin canceration early stage optical detection apparatus and its application method |
| CN209103019U (en) * | 2018-11-28 | 2019-07-12 | 上海复享光学股份有限公司 | Laser beam merging apparatus |
| CN109827946A (en) * | 2019-02-28 | 2019-05-31 | 华北水利水电大学 | Soil constituent in-situ analysis system and method |
| CN110441235A (en) * | 2019-09-13 | 2019-11-12 | 中国科学院新疆理化技术研究所 | A kind of Multiple modes coupling original position microspectrum imaging system |
| CN112859315A (en) * | 2021-01-11 | 2021-05-28 | 北京大学 | Multicolor dual-mode structured light illumination microscopic imaging system and imaging method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 王忠东 等: "基于荧光机理的土壤农药浓度光纤检测系统", 测试技术学报 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115290619A (en) * | 2022-08-05 | 2022-11-04 | 南京贻润环境科技有限公司 | Method and device for detecting colloidal active carbon in soil or underground water |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102967604B (en) | Reflectance spectrum measuring and sampling system and method used for jewel detection | |
| CN100545631C (en) | Multifunctional light absorption, scattering and emission spectrometer based on surface plasma-wave | |
| US7728291B2 (en) | Detection of heavy oil using fluorescence polarization | |
| Wu et al. | Stand-off detection of chemicals by UV Raman spectroscopy | |
| CA2563790A1 (en) | A method and apparatus for a high resolution downhole spectrometer | |
| CN111089852B (en) | Vertical section distribution in-situ detection system for petroleum hydrocarbon pollutants in polluted site | |
| CN205844192U (en) | A kind of double light path water body petroleum hydrocarbon in-situ monitoring device | |
| CN109827946A (en) | Soil constituent in-situ analysis system and method | |
| CN102590171A (en) | System for rapidly detecting ocean oil pollution | |
| CN101477050B (en) | Polycyclic aromatic hydrocarbon three-dimensional fluorescent on-line detecting instrument | |
| CN104931479A (en) | Integrated imageable portable laser-Raman spectrum detector | |
| CN104390943A (en) | Microscopic imaging system capable of simultaneously obtaining appearance image and element distribution image | |
| CN114324281A (en) | Soil organic pollutant is fluorescence collection device for in situ monitoring analysis | |
| CN204666515U (en) | A kind of integrated, can imaging type Portable laser Raman spectrum detector | |
| CN106932373A (en) | Total organic carbon optics home position sensing | |
| CN110160978A (en) | A kind of detection system and detection method of the comprehensive organoleptic indicator of drinking water | |
| CN202869980U (en) | Portable oil spill online detector | |
| CN202512058U (en) | Device for rapidly detecting ocean oil pollution | |
| CN102944547B (en) | Instrument for detecting ozonation liquid phase luminescence spectrum and acquisition method | |
| CN1243233C (en) | Analyser for spark through spectrum medium by laser induced | |
| CN206920339U (en) | Total organic carbon optics home position sensing | |
| JP3858844B2 (en) | Gas monitoring apparatus and gas monitoring method for underground fixation of carbon dioxide gas | |
| CN114646627A (en) | Device and method for classifying and detecting seawater spilled oil by using spectral analysis technology | |
| CN204514810U (en) | Laser-induced fluorescence detection system | |
| WO2017180699A1 (en) | Characterizing petroleum product contamination using fluorescence signal |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |