CN114292598A - TPU (thermoplastic polyurethane) hot melt adhesive film with high adhesive strength and preparation method thereof - Google Patents

TPU (thermoplastic polyurethane) hot melt adhesive film with high adhesive strength and preparation method thereof Download PDF

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Publication number
CN114292598A
CN114292598A CN202111655149.XA CN202111655149A CN114292598A CN 114292598 A CN114292598 A CN 114292598A CN 202111655149 A CN202111655149 A CN 202111655149A CN 114292598 A CN114292598 A CN 114292598A
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CN
China
Prior art keywords
hot melt
tpu
melt adhesive
adhesive film
parts
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202111655149.XA
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Chinese (zh)
Inventor
宾家荃
宾家齐
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Huiqi New Material Co ltd
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Guangdong Huiqi New Material Co ltd
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Publication date
Application filed by Guangdong Huiqi New Material Co ltd filed Critical Guangdong Huiqi New Material Co ltd
Priority to CN202111655149.XA priority Critical patent/CN114292598A/en
Priority to PCT/CN2022/074677 priority patent/WO2023123607A1/en
Publication of CN114292598A publication Critical patent/CN114292598A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • C09J175/06Polyurethanes from polyesters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • C09J175/08Polyurethanes from polyethers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/10Adhesives in the form of films or foils without carriers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention relates to the field of TPU (thermoplastic polyurethane) hot melt adhesive films, in particular to a TPU hot melt adhesive film with high adhesion strength, which comprises the following raw materials in parts by weight: 50-70 parts of TPU particles, 45-50 parts of tackifying resin, 0-10 parts of modified polyester, 0.1-1 part of anti-hydrolysis agent and 1-2 parts of auxiliary agent. The invention provides a TPU hot melt adhesive film with high adhesive strength; the invention also provides a preparation method of the TPU hot melt adhesive film with high adhesive strength, which has the advantages of simple preparation process, convenient operation and convenient mass production.

Description

TPU (thermoplastic polyurethane) hot melt adhesive film with high adhesive strength and preparation method thereof
Technical Field
The invention relates to the field of TPU (thermoplastic polyurethane) hot melt adhesive films, in particular to a TPU hot melt adhesive film with high adhesive strength and a preparation method thereof.
Background
The hot melt adhesive film is a film product with or without release paper, and can be conveniently operated continuously or intermittently. Can be widely used for bonding various fabrics, soles, nylon cloth, water-proof materials, leather, polyester fibers, high polymer materials and metals.
The TPU hot melt adhesive mold on the market at present has the defects of low adhesive strength and the like, and can not meet the use requirement of higher requirements.
Disclosure of Invention
In order to solve the technical problems, the invention provides a TPU hot melt adhesive film with high adhesive strength.
The invention also provides a preparation method of the TPU hot melt adhesive film with high adhesive strength, which has the advantages of simple preparation process, convenient operation and convenient mass production.
The invention adopts the following technical scheme:
the TPU hot melt adhesive film with high adhesive strength comprises the following raw materials in parts by weight: 50-70 parts of TPU particles, 45-50 parts of tackifying resin, 0-10 parts of modified polyester, 0.1-1 part of anti-hydrolysis agent and 1-2 parts of auxiliary agent.
The technical proposal is further improved in that the TPU particles are one or two of adipic acid polyester TPU granules, polycarbonate polyester TPU granules and polytetrahydrofuran polyether TPU granules.
The technical proposal is further improved in that the tackifying resin is one or more of rosin resin, petroleum resin or terpene resin.
The technical scheme is further improved in that the modified polyester is modified copolyester.
The technical proposal is further improved in that the hydrolysis resistant agent is one of monomer carbodiimide or polymerized carbodiimide.
The technical scheme is further improved in that the auxiliary agent is one or two of an antioxidant, a yellowing resistant agent and an ultraviolet absorbent.
A preparation method of a TPU hot melt adhesive film with high adhesive strength comprises the following steps: drying the raw materials according to the formula amount; and extruding, cooling, coiling and packaging the dried raw materials to obtain the TPU hot melt adhesive film with high adhesive strength.
The technical scheme is further improved in that the drying temperature is 110-130 ℃.
The technical scheme is further improved by adopting an extruder for extruding, wherein the temperature of a charging barrel of the extruder is as follows in sequence: 125 deg.C, 130 deg.C, 145 deg.C, 150 deg.C and 140 deg.C.
The technical proposal is further improved in that the temperature of the die head of the extruder is 140 ℃, 130 ℃, 131 ℃, 132 ℃ and 131 ℃.
The invention has the beneficial effects that:
the TPU hot melt adhesive film has high peel strength after being bonded, can resist water and yellowing and is durable in bonding under outdoor severe environment, and the bonding strength of the TPU hot melt adhesive film attached to various fabrics, soles, nylon cloth, water-repellent materials, leather, polyester fibers, high polymer materials and metals is remarkably improved; the preparation method of the TPU hot melt adhesive film has the advantages of simple process, high production efficiency, convenient operation and convenient mass production.
Detailed Description
The present invention will be further described with reference to the following examples for better understanding of the present invention, but the embodiments of the present invention are not limited thereto.
The TPU hot melt adhesive film with high adhesive strength comprises the following raw materials in parts by weight: 50-70 parts of TPU particles, 45-50 parts of tackifying resin, 0-10 parts of modified polyester, 0.1-1 part of anti-hydrolysis agent and 1-2 parts of auxiliary agent.
The TPU particles are one or two of adipic acid polyester TPU particles, polycarbonate polyester TPU particles and polytetrahydrofuran polyether TPU particles.
The tackifying resin is one or more of rosin resin, petroleum resin or terpene resin.
The modified polyester is modified copolyester.
The hydrolysis resistant agent is one of monomer carbodiimide or polymerized carbodiimide.
The auxiliary agent is one or two of an antioxidant, a yellowing resistant agent and an ultraviolet absorbent.
A preparation method of a TPU hot melt adhesive film with high adhesive strength comprises the following steps: drying the raw materials according to the formula amount; extruding, cooling, coiling and packaging the dried raw materials to obtain a TPU hot melt adhesive film with high adhesive strength; the drying temperature is 110-130 ℃; extruding by using an extruder, wherein the temperature of a charging barrel of the extruder is as follows in sequence: 125 deg.C, 130 deg.C, 145 deg.C, 150 deg.C and 140 deg.C; the die temperatures of the extruders were 140 ℃, 130 ℃, 131 ℃, 132 ℃ and 131 ℃.
Example 1
The TPU hot melt adhesive film with high adhesive strength comprises the following raw materials in parts by weight: 50 parts of adipic acid polyester TPU particles, 45 parts of rosin resin, 2 parts of modified copolyester, 0.1 part of monomer carbodiimide and 1 part of yellowing resistant agent.
A preparation method of a TPU hot melt adhesive film with high adhesive strength comprises the following steps: drying the raw materials according to the formula amount; extruding, cooling, coiling and packaging the dried raw materials to obtain a TPU hot melt adhesive film with high adhesive strength; the drying temperature is 110-130 ℃; extruding by using an extruder, wherein the temperature of a charging barrel of the extruder is as follows in sequence: 125 deg.C, 130 deg.C, 145 deg.C, 150 deg.C and 140 deg.C; the die temperatures of the extruders were 140 ℃, 130 ℃, 131 ℃, 132 ℃ and 131 ℃.
Example 2
The TPU hot melt adhesive film with high adhesive strength comprises the following raw materials in parts by weight: 55 parts of polycarbonate polyester TPU particles, 48 parts of petroleum resin, 5 parts of modified copolyester, 1 part of monomer carbodiimide and 1 part of antioxidant and yellowing resistant agent mixing agent.
A preparation method of a TPU hot melt adhesive film with high adhesive strength comprises the following steps: drying the raw materials according to the formula amount; extruding, cooling, coiling and packaging the dried raw materials to obtain a TPU hot melt adhesive film with high adhesive strength; the drying temperature is 110-130 ℃; extruding by using an extruder, wherein the temperature of a charging barrel of the extruder is as follows in sequence: 125 deg.C, 130 deg.C, 145 deg.C, 150 deg.C and 140 deg.C; the die temperatures of the extruders were 140 ℃, 130 ℃, 131 ℃, 132 ℃ and 131 ℃.
Example 3
The TPU hot melt adhesive film with high adhesive strength comprises the following raw materials in parts by weight: 63 parts of polytetrahydrofuran polyether type TPU particles, 45 parts of rosin resin, 5 parts of modified copolyester, 1 part of polymerized carbodiimide and 1 part of a mixed agent of a yellowing resistant agent and an ultraviolet absorbent.
A preparation method of a TPU hot melt adhesive film with high adhesive strength comprises the following steps: drying the raw materials according to the formula amount; extruding, cooling, coiling and packaging the dried raw materials to obtain a TPU hot melt adhesive film with high adhesive strength; the drying temperature is 110-130 ℃; extruding by using an extruder, wherein the temperature of a charging barrel of the extruder is as follows in sequence: 125 deg.C, 130 deg.C, 145 deg.C, 150 deg.C and 140 deg.C; the die temperatures of the extruders were 140 ℃, 130 ℃, 131 ℃, 132 ℃ and 131 ℃.
Example 4
The TPU hot melt adhesive film with high adhesive strength comprises the following raw materials in parts by weight: 70 parts of polycarbonate polyester TPU particles, 50 parts of terpene resin, 10 parts of modified copolyester, 1 part of polymerized carbodiimide and 2 parts of antioxidant and ultraviolet absorber mixing agent.
A preparation method of a TPU hot melt adhesive film with high adhesive strength comprises the following steps: drying the raw materials according to the formula amount; extruding, cooling, coiling and packaging the dried raw materials to obtain a TPU hot melt adhesive film with high adhesive strength; the drying temperature is 110-130 ℃; extruding by using an extruder, wherein the temperature of a charging barrel of the extruder is as follows in sequence: 125 deg.C, 130 deg.C, 145 deg.C, 150 deg.C and 140 deg.C; the die temperatures of the extruders were 140 ℃, 130 ℃, 131 ℃, 132 ℃ and 131 ℃.
The TPU hot melt adhesive film has high peel strength after being bonded, can resist water and yellowing and is durable in bonding under outdoor severe environment, and the bonding strength of the TPU hot melt adhesive film attached to various fabrics, soles, nylon cloth, water-repellent materials, leather, polyester fibers, high polymer materials and metals is remarkably improved; the preparation method of the TPU hot melt adhesive film has the advantages of simple process, high production efficiency, convenient operation and convenient mass production.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.

Claims (10)

1. The TPU hot melt adhesive film with high adhesive strength is characterized by comprising the following raw materials in parts by weight: 50-70 parts of TPU particles, 45-50 parts of tackifying resin, 0-10 parts of modified polyester, 0.1-1 part of anti-hydrolysis agent and 1-2 parts of auxiliary agent.
2. The high adhesion strength TPU hot melt adhesive film as claimed in claim 1, wherein the TPU particles are one or two of adipic acid polyester TPU particles, polycarbonate polyester TPU particles and polytetrahydrofuran polyether TPU particles.
3. A high tack strength TPU hot melt adhesive film as set forth in claim 1 wherein said tackifying resin is one or more of rosin resin, petroleum resin, or terpene resin.
4. A high adhesion strength TPU hot melt adhesive film as set forth in claim 1 wherein said modified polyester is a modified copolyester.
5. A high adhesion strength TPU hot melt adhesive film as set forth in claim 1 wherein said hydrolysis resistance agent is one of a monomeric carbodiimide or a polymeric carbodiimide.
6. The high adhesion strength TPU hot melt adhesive film as claimed in claim 1, wherein the auxiliary agent is one or two of an antioxidant, a yellowing resistant agent and an ultraviolet absorber.
7. A preparation method of a TPU hot melt adhesive film with high adhesive strength is characterized by comprising the following steps: drying the raw materials according to the formula amount; and extruding, cooling, coiling and packaging the dried raw materials to obtain the TPU hot melt adhesive film with high adhesive strength.
8. The preparation method of the TPU hot melt adhesive film with high adhesive strength as claimed in claim 7, wherein the drying temperature is 110-130 ℃.
9. The method for preparing the TPU hot melt adhesive film with high adhesive strength as claimed in claim 7, wherein an extruder is used for extrusion, and the barrel temperature of the extruder is as follows in sequence: 125 deg.C, 130 deg.C, 145 deg.C, 150 deg.C and 140 deg.C.
10. The method for preparing a high tack strength TPU hot melt adhesive film according to claim 7, wherein the die temperature of the extruder is 140 ℃, 130 ℃, 131 ℃, 132 ℃ and 131 ℃.
CN202111655149.XA 2021-12-30 2021-12-30 TPU (thermoplastic polyurethane) hot melt adhesive film with high adhesive strength and preparation method thereof Pending CN114292598A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN202111655149.XA CN114292598A (en) 2021-12-30 2021-12-30 TPU (thermoplastic polyurethane) hot melt adhesive film with high adhesive strength and preparation method thereof
PCT/CN2022/074677 WO2023123607A1 (en) 2021-12-30 2022-01-28 High adhesion-strength tpu hot melt adhesive film and preparation method therefor

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Application Number Priority Date Filing Date Title
CN202111655149.XA CN114292598A (en) 2021-12-30 2021-12-30 TPU (thermoplastic polyurethane) hot melt adhesive film with high adhesive strength and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114752313A (en) * 2022-05-12 2022-07-15 广东盈通新材料有限公司 Waterproof adhesive tape and preparation method and application thereof
CN115260967A (en) * 2022-07-29 2022-11-01 广东汇齐新材料有限公司 Self-repairing TPU hot melt adhesive film and preparation method thereof

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CN104263259A (en) * 2014-09-18 2015-01-07 东莞市雄林新材料科技股份有限公司 Low-melting-point and high-bonding-strength TPU (thermoplastic polyurethane) hot melt adhesive membrane and preparation method thereof
GB2549104A (en) * 2016-04-04 2017-10-11 Tech 21 Licensing Ltd A screen protector for a mobile electronic device with a touch screen
DE112016001025A5 (en) * 2015-03-04 2017-12-21 Sika Technology Ag Bonding of sealing membranes on electrically conductive substrates by means of induction
CN109679557A (en) * 2018-11-30 2019-04-26 江苏和和新材料股份有限公司 A kind of insole environment-friendly type solidifies TPU hot melt adhesive film and its production method slowly
CN111040711A (en) * 2019-12-05 2020-04-21 广东盈通新材料有限公司 TPU adhesive, hot melt adhesive film and application
CN112574678A (en) * 2020-11-30 2021-03-30 山东一诺威聚氨酯股份有限公司 High-temperature-resistant water-washing TPU (thermoplastic polyurethane) hot melt adhesive film and preparation method thereof

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US20110262753A1 (en) * 2008-10-06 2011-10-27 Taishi Kawasaki Laminated polyester film
CN111868195B (en) * 2018-03-20 2022-05-06 Dic株式会社 Adhesive and synthetic leather
CN112745772A (en) * 2020-12-29 2021-05-04 广东昂斯新材料技术有限公司 High-elasticity hot melt adhesive material made of pure TPU (thermoplastic polyurethane) material and preparation process thereof

Patent Citations (6)

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Publication number Priority date Publication date Assignee Title
CN104263259A (en) * 2014-09-18 2015-01-07 东莞市雄林新材料科技股份有限公司 Low-melting-point and high-bonding-strength TPU (thermoplastic polyurethane) hot melt adhesive membrane and preparation method thereof
DE112016001025A5 (en) * 2015-03-04 2017-12-21 Sika Technology Ag Bonding of sealing membranes on electrically conductive substrates by means of induction
GB2549104A (en) * 2016-04-04 2017-10-11 Tech 21 Licensing Ltd A screen protector for a mobile electronic device with a touch screen
CN109679557A (en) * 2018-11-30 2019-04-26 江苏和和新材料股份有限公司 A kind of insole environment-friendly type solidifies TPU hot melt adhesive film and its production method slowly
CN111040711A (en) * 2019-12-05 2020-04-21 广东盈通新材料有限公司 TPU adhesive, hot melt adhesive film and application
CN112574678A (en) * 2020-11-30 2021-03-30 山东一诺威聚氨酯股份有限公司 High-temperature-resistant water-washing TPU (thermoplastic polyurethane) hot melt adhesive film and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114752313A (en) * 2022-05-12 2022-07-15 广东盈通新材料有限公司 Waterproof adhesive tape and preparation method and application thereof
CN115260967A (en) * 2022-07-29 2022-11-01 广东汇齐新材料有限公司 Self-repairing TPU hot melt adhesive film and preparation method thereof

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Application publication date: 20220408