CN114276860A - A kind of graphene oil with improved thermal conductivity and adsorption and preparation method thereof - Google Patents
A kind of graphene oil with improved thermal conductivity and adsorption and preparation method thereof Download PDFInfo
- Publication number
- CN114276860A CN114276860A CN202210022702.4A CN202210022702A CN114276860A CN 114276860 A CN114276860 A CN 114276860A CN 202210022702 A CN202210022702 A CN 202210022702A CN 114276860 A CN114276860 A CN 114276860A
- Authority
- CN
- China
- Prior art keywords
- graphene
- oil
- thermal conductivity
- metal powder
- microspheres
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 63
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 238000001179 sorption measurement Methods 0.000 title abstract description 21
- 239000004005 microsphere Substances 0.000 claims abstract description 56
- 229910052751 metal Inorganic materials 0.000 claims abstract description 41
- 239000002184 metal Substances 0.000 claims abstract description 41
- 239000000843 powder Substances 0.000 claims abstract description 41
- 239000002199 base oil Substances 0.000 claims abstract description 40
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000012964 benzotriazole Substances 0.000 claims abstract description 26
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- OSPSWZSRKYCQPF-UHFFFAOYSA-N dibutoxy(oxo)phosphanium Chemical compound CCCCO[P+](=O)OCCCC OSPSWZSRKYCQPF-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000010687 lubricating oil Substances 0.000 claims abstract description 21
- -1 HSD Chemical compound 0.000 claims abstract description 18
- 239000010705 motor oil Substances 0.000 claims abstract description 15
- 238000003756 stirring Methods 0.000 claims description 60
- 238000010438 heat treatment Methods 0.000 claims description 42
- 239000011265 semifinished product Substances 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 17
- 239000000047 product Substances 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 239000004327 boric acid Substances 0.000 claims description 11
- 239000003973 paint Substances 0.000 claims description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
- 238000011049 filling Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims 1
- 239000003921 oil Substances 0.000 abstract description 24
- 230000001050 lubricating effect Effects 0.000 abstract description 6
- 230000009286 beneficial effect Effects 0.000 abstract description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 239000010696 ester oil Substances 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 4
- 238000005461 lubrication Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001642 boronic acid derivatives Chemical group 0.000 description 1
- OEWUNMOSJRYWLH-UHFFFAOYSA-N butyl dihydroxyphosphanyl hydrogen phosphite Chemical compound CCCCOP(O)OP(O)O OEWUNMOSJRYWLH-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
Images
Landscapes
- Lubricants (AREA)
Abstract
本发明公开了一种提高导热性和吸附性的石墨烯机油及其制备方法，配方包括：石墨烯、HSD、硼酸脂、金属粉微球、苯骈三氮唑、亚磷酸二正丁酯以及余量的润滑油基础油，各组分的质量百分比分别是：0.05‑0.1％的石墨烯、0.8‑1％的HSD、10‑14％的硼酸脂、0.03‑0.05％的金属粉微球、0.01‑0.04％的苯骈三氮唑、0.01‑0.02％的亚磷酸二正丁酯以及余量的润滑油基础油；该发明，通过在机油中加入了一定量的石墨烯，利用石墨烯具有的导热性以及吸附性，从而提高了该石墨烯机油的导热性以及吸附性，同时在制备的过程中，加入了一定量的纳米金属粉末，利用添加的纳米金属粉末，有利于使纳米金属粉末附着在机械结构中，从而提高了润滑效果，降低了机械之间的摩擦，提高了该机油的实用性。
The invention discloses a graphene oil with improved thermal conductivity and adsorption and a preparation method thereof. The formula comprises: graphene, HSD, borate, metal powder microspheres, benzotriazole, di-n-butyl phosphite and The rest of the lubricating oil base oil, the mass percentage of each component is: 0.05-0.1% graphene, 0.8-1% HSD, 10-14% borate, 0.03-0.05% metal powder microspheres, 0.01-0.04% of benzotriazole, 0.01-0.02% of di-n-butyl phosphite and the balance of lubricating oil base oil; this invention, by adding a certain amount of graphene in the engine oil, using graphene to have The thermal conductivity and adsorption of the graphene oil are improved, and the thermal conductivity and adsorption of the graphene oil are improved. At the same time, during the preparation process, a certain amount of nano metal powder is added, and the added nano metal powder is beneficial to make the nano metal powder. Attached to the mechanical structure, thereby improving the lubricating effect, reducing the friction between the machines, and improving the practicability of the oil.
Description
技术领域technical field
本发明涉及机油技术领域，具体为一种提高导热性和吸附性的石墨烯机油及其制备方法。The invention relates to the technical field of engine oil, in particular to a graphene engine oil with improved thermal conductivity and adsorption and a preparation method thereof.
背景技术Background technique
机油用于内燃机的润滑。机油的主要功能是减少运动部件的摩擦和磨损，并清除发动机中的污泥(分散剂的功能之一)和油漆(清洁剂)。它还中和来自燃料和润滑剂氧化产生的酸(清洁剂)，改善活塞环的密封性，并通过从运动部件带走热量来冷却发动机，但现有的机油种类繁多，同时机油的导热性以及吸附性不佳，无法满足现有对机油的需求，因此设计一种提高导热性和吸附性的石墨烯机油及其制备方法是很有必要的。Oil is used for the lubrication of internal combustion engines. The main function of engine oil is to reduce friction and wear on moving parts and to remove sludge (one of the functions of dispersant) and paint (cleaner) from the engine. It also neutralizes acids (cleaners) from oxidation of fuels and lubricants, improves piston ring sealing, and cools the engine by removing heat from moving parts, but there are many types of oils available, along with the thermal conductivity of oil And the adsorption is not good enough to meet the existing demand for oil, so it is necessary to design a graphene oil with improved thermal conductivity and adsorption and a preparation method thereof.
发明内容SUMMARY OF THE INVENTION
本发明的目的在于提供一种提高导热性和吸附性的石墨烯机油及其制备方法，以解决上述背景技术中提出的问题。The object of the present invention is to provide a graphene oil that improves thermal conductivity and adsorption and a preparation method thereof, to solve the problems raised in the above-mentioned background technology.
为实现上述目的，本发明提供如下技术方案：一种提高导热性和吸附性的石墨烯机油，配方包括：石墨烯、HSD、硼酸脂、金属粉微球、苯骈三氮唑、亚磷酸二正丁酯以及余量的润滑油基础油，各组分的质量百分比分别是：0.05-0.1％的石墨烯、0.8-1％的HSD、10-14％的硼酸脂、0.03-0.05％的金属粉微球、0.01-0.04％的苯骈三氮唑、0.01-0.02％的亚磷酸二正丁酯以及余量的润滑油基础油。In order to achieve the above object, the present invention provides the following technical solutions: a graphene oil that improves thermal conductivity and adsorption, the formula includes: graphene, HSD, borate, metal powder microspheres, benzotriazole, diphosphite n-Butyl ester and the balance of lubricating base oil, the mass percentages of each component are: 0.05-0.1% graphene, 0.8-1% HSD, 10-14% borate, 0.03-0.05% metal powder microspheres, 0.01-0.04% of benzotriazole, 0.01-0.02% of di-n-butyl phosphite and the balance of lubricating oil base oil.
优选的，所述石墨烯的直径为1-5um，厚度为1-10nm，同时比表面积为500-1000m2/g。Preferably, the graphene has a diameter of 1-5um, a thickness of 1-10nm, and a specific surface area of 500-1000m 2 /g.
优选的，所述金属粉微球是由铬粉微球、氧化铁微球和钼粉微球按照重量比1∶1∶1混合制备而成，且使用的微球粒径为20-40nm。Preferably, the metal powder microspheres are prepared by mixing chromium powder microspheres, iron oxide microspheres and molybdenum powder microspheres in a weight ratio of 1:1:1, and the diameter of the used microspheres is 20-40 nm.
一种提高导热性和吸附性的石墨烯机油的制备方法，包括以下步骤：步骤一，材料选取；步骤二，加热搅拌；步骤三，混合；步骤四，得到半成品；步骤五，灌装；A method for preparing graphene oil with improved thermal conductivity and adsorption, comprising the following steps: step 1, material selection; step 2, heating and stirring; step 3, mixing; step 4, obtaining semi-finished products; step 5, filling;
其中上述步骤一中，首先按照各组分的质量百分比分别选取0.05-0.1％的石墨烯、0.8-1％的HSD、10-14％的硼酸脂、0.03-0.05％的金属粉微球、0.01-0.04％的苯骈三氮唑、0.01-0.02％的亚磷酸二正丁酯以及余量的润滑油基础油备用，且选取的物料均为合格产品；In the above step 1, according to the mass percentage of each component, 0.05-0.1% of graphene, 0.8-1% of HSD, 10-14% of borate, 0.03-0.05% of metal powder microspheres, 0.01 -0.04% benzotriazole, 0.01-0.02% di-n-butyl phosphite and the balance of lubricating oil base oil for use, and the selected materials are all qualified products;
其中上述步骤二中，将步骤一中选取的硼酸脂首先进行加热处理，随后将加热后得到的硼酸脂和润滑油基础油首先放置在搅拌机中，随后在搅拌温度为50-60℃的环境下搅拌分散25-30min得到分散基础油，且搅拌转速为3000r/min；In the above step 2, the boric acid ester selected in the step 1 is first heated, and then the boric acid ester and the lubricating oil base oil obtained after heating are first placed in a mixer, and then the stirring temperature is 50-60 ℃. Stir and disperse for 25-30min to obtain dispersed base oil, and the stirring speed is 3000r/min;
其中上述步骤三中，将步骤一中选取的HSD加入到步骤二中的分散基础油中进行电磁搅拌30min，当电磁搅拌完成后，即可停止加热；Wherein in the above-mentioned step 3, the HSD selected in the step 1 is added to the dispersed base oil in the step 2 to carry out electromagnetic stirring for 30min, and when the electromagnetic stirring is completed, the heating can be stopped;
其中上述步骤四中，将步骤三中得到的混合料中加入步骤一中选取的石墨烯、金属粉微球、苯骈三氮唑以及亚磷酸二正丁酯加入到步骤三中得到的混合料中随后搅拌得到半成品；Wherein in the above-mentioned step 4, adding graphene, metal powder microspheres, benzotriazole and di-n-butyl phosphite selected in step 1 to the mixture obtained in step 3 and adding to the mixture obtained in step 3 and then stirring to obtain semi-finished products;
其中上述步骤五中，将步骤四中得到的半成品放置在干燥的房间中静置10-20min后，即可将半成品进行灌装处理得到成品，同时干燥的房间中湿度为20-30％。In the above step 5, the semi-finished product obtained in step 4 is placed in a dry room for 10-20 minutes, and then the semi-finished product can be filled to obtain a finished product, and the humidity in the dry room is 20-30%.
优选的，所述步骤二中，加热温度为50-60℃，同时加热时间为10-15min。Preferably, in the second step, the heating temperature is 50-60° C., and the heating time is 10-15 min.
优选的，所述步骤三中，搅拌转速为3000r/min，同时在搅拌的过程中，需要不断的对分散基础油进行加热处理得到混合料，同时加热温度为40-50℃。Preferably, in the third step, the stirring speed is 3000 r/min, and during the stirring process, the dispersed base oil needs to be continuously heated to obtain the mixture, and the heating temperature is 40-50 °C.
优选的，所述步骤四中，搅拌利用油漆分散机进行搅拌30min后即可，同时搅拌转速为3500r/min。Preferably, in the step 4, the stirring is carried out by using a paint disperser for 30 minutes, and the stirring speed is 3500 r/min at the same time.
与现有技术相比，本发明的有益效果是：该发明，通过在机油中加入了一定量的石墨烯，利用石墨烯具有的导热性以及吸附性，从而提高了该石墨烯机油的导热性以及吸附性，同时在制备的过程中，加入了一定量的纳米金属粉末，利用添加的纳米金属粉末，有利于使纳米金属粉末附着在机械结构中，从而提高了润滑效果，降低了机械之间的摩擦，提高了该机油的实用性，且在制备的过程中，通过加热的方式或者限制环境湿度的方式，充分的降低了硼酸脂与水的接触，进而降低了硼酸脂遇水分解的几率，从而提高了该机油的品质。Compared with the prior art, the beneficial effects of the present invention are: the invention, by adding a certain amount of graphene in the oil, utilizes the thermal conductivity and adsorption properties of the graphene, thereby improving the thermal conductivity of the graphene oil At the same time, in the process of preparation, a certain amount of nano-metal powder is added, and the added nano-metal powder is beneficial to make the nano-metal powder adhere to the mechanical structure, thereby improving the lubrication effect and reducing the mechanical The friction of the oil improves the practicability of the oil, and in the preparation process, the contact between the borate and the water is fully reduced by heating or limiting the environmental humidity, thereby reducing the probability of decomposition of the borate with water. , thereby improving the quality of the oil.
附图说明Description of drawings
图1为本发明的方法流程图。FIG. 1 is a flow chart of the method of the present invention.
具体实施方式Detailed ways
下面将结合本发明实施例中的附图，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, but not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.
请参阅图1，本发明提供的一种实施例：Please refer to Fig. 1, an embodiment provided by the present invention:
实施例1：Example 1:
一种提高导热性和吸附性的石墨烯机油，配方包括：石墨烯、HSD、硼酸脂、金属粉微球、苯骈三氮唑、亚磷酸二正丁酯以及余量的润滑油基础油，各组分的质量百分比分别是：0.05％的石墨烯、0.8％的HSD、10％的硼酸脂、0.03％的金属粉微球、0.01％的苯骈三氮唑、0.01％的亚磷酸二正丁酯以及余量的润滑油基础油；其中石墨烯的直径为1-5um，厚度为1-10nm，同时比表面积为500-1000m2/g；金属粉微球是由铬粉微球、氧化铁微球和钼粉微球按照重量比1∶1∶1混合制备而成，且使用的微球粒径为20-40nm。A graphene engine oil for improving thermal conductivity and adsorption, the formula comprising: graphene, HSD, borate, metal powder microspheres, benzotriazole, di-n-butyl phosphite and the balance of lubricating oil base oil, The mass percentage of each component is: 0.05% graphene, 0.8% HSD, 10% borate, 0.03% metal powder microspheres, 0.01% benzotriazole, 0.01% diorthophosphite Butyl ester and the balance of lubricating oil base oil; wherein the diameter of graphene is 1-5um, the thickness is 1-10nm, and the specific surface area is 500-1000m 2 /g; the metal powder microspheres are composed of chromium powder microspheres, oxidized The iron microspheres and the molybdenum powder microspheres are prepared by mixing in a weight ratio of 1:1:1, and the particle size of the used microspheres is 20-40 nm.
一种提高导热性和吸附性的石墨烯机油的制备方法,包括以下步骤：步骤一，材料选取；步骤二，加热搅拌；步骤三，混合；步骤四，得到半成品；步骤五，灌装；A method for preparing graphene oil with improved thermal conductivity and adsorption, comprising the following steps: step 1, material selection; step 2, heating and stirring; step 3, mixing; step 4, obtaining semi-finished products; step 5, filling;
其中上述步骤一中，首先按照各组分的质量百分比分别选取0.05％的石墨烯、0.8％的HSD、10％的硼酸脂、0.03％的金属粉微球、0.01％的苯骈三氮唑、0.01％的亚磷酸二正丁酯以及余量的润滑油基础油备用，且选取的物料均为合格产品；In the above-mentioned step 1, firstly select 0.05% graphene, 0.8% HSD, 10% borate, 0.03% metal powder microspheres, 0.01% benzotriazole, 0.01% di-n-butyl phosphite and the balance of lubricating base oil are reserved, and the selected materials are qualified products;
其中上述步骤二中，将步骤一中选取的硼酸脂首先进行加热处理，且加热温度为50-60℃，同时加热时间为10-15min，随后将加热后得到的硼酸脂和润滑油基础油首先放置在搅拌机中，随后在搅拌温度为50-60℃的环境下搅拌分散25-30min得到分散基础油，且搅拌转速为3000r/min；Wherein in the above-mentioned step 2, the boric acid ester selected in step 1 is first heated, and the heating temperature is 50-60 ° C, and the heating time is 10-15min, and then the boric acid ester and lubricating oil base oil obtained after heating are first Place in a mixer, and then stir and disperse for 25-30min under a stirring temperature of 50-60°C to obtain a dispersed base oil, and the stirring speed is 3000r/min;
其中上述步骤三中，将步骤一中选取的HSD加入到步骤二中的分散基础油中进行电磁搅拌30min，搅拌转速为3000r/min，同时在搅拌的过程中，需要不断的对分散基础油进行加热处理得到混合料，同时加热温度为40-50℃，当电磁搅拌完成后，即可停止加热；In the above step 3, the HSD selected in step 1 is added to the dispersed base oil in step 2 for electromagnetic stirring for 30min, and the stirring speed is 3000r/min. The mixture is obtained by heating treatment, and the heating temperature is 40-50 ° C. When the electromagnetic stirring is completed, the heating can be stopped;
其中上述步骤四中，将步骤三中得到的混合料中加入步骤一中选取的石墨烯、金属粉微球、苯骈三氮唑以及亚磷酸二正丁酯加入到步骤三中得到的混合料中随后搅拌得到半成品，且搅拌利用油漆分散机进行搅拌30min后即可，同时搅拌转速为3500r/min；Wherein in the above-mentioned step 4, adding graphene, metal powder microspheres, benzotriazole and di-n-butyl phosphite selected in step 1 to the mixture obtained in step 3 and adding to the mixture obtained in step 3 Then stir to obtain a semi-finished product, and the stirring is performed after 30 minutes by using a paint disperser, and the stirring speed is 3500 r/min;
其中上述步骤五中，将步骤四中得到的半成品放置在干燥的房间中静置10-20min后，即可将半成品进行灌装处理得到成品，同时干燥的房间中湿度为20-30％。In the above step 5, the semi-finished product obtained in step 4 is placed in a dry room for 10-20 minutes, and then the semi-finished product can be filled to obtain a finished product, and the humidity in the dry room is 20-30%.
实施例2：Example 2:
一种提高导热性和吸附性的石墨烯机油，配方包括：石墨烯、HSD、硼酸脂、金属粉微球、苯骈三氮唑、亚磷酸二正丁酯以及余量的润滑油基础油，各组分的质量百分比分别是：0.1％的石墨烯、1％的HSD、14％的硼酸脂、0.05％的金属粉微球、0.04％的苯骈三氮唑、0.02％的亚磷酸二正丁酯以及余量的润滑油基础油；其中石墨烯的直径为1-5um，厚度为1-10nm，同时比表面积为500-1000m2/g；金属粉微球是由铬粉微球、氧化铁微球和钼粉微球按照重量比1∶1∶1混合制备而成，且使用的微球粒径为20-40nm。A graphene engine oil for improving thermal conductivity and adsorption, the formula comprising: graphene, HSD, borate, metal powder microspheres, benzotriazole, di-n-butyl phosphite and the balance of lubricating oil base oil, The mass percentages of each component are: 0.1% graphene, 1% HSD, 14% borate, 0.05% metal powder microspheres, 0.04% benzotriazole, 0.02% di-n-phosphite Butyl ester and the balance of lubricating oil base oil; wherein the diameter of graphene is 1-5um, the thickness is 1-10nm, and the specific surface area is 500-1000m 2 /g; the metal powder microspheres are composed of chromium powder microspheres, oxidized The iron microspheres and the molybdenum powder microspheres are prepared by mixing in a weight ratio of 1:1:1, and the particle size of the used microspheres is 20-40 nm.
一种提高导热性和吸附性的石墨烯机油的制备方法,包括以下步骤：步骤一，材料选取；步骤二，加热搅拌；步骤三，混合；步骤四，得到半成品；步骤五，灌装；A method for preparing graphene oil with improved thermal conductivity and adsorption, comprising the following steps: step 1, material selection; step 2, heating and stirring; step 3, mixing; step 4, obtaining semi-finished products; step 5, filling;
其中上述步骤一中，首先按照各组分的质量百分比分别选取0.1％的石墨烯、1％的HSD、14％的硼酸脂、0.05％的金属粉微球、0.04％的苯骈三氮唑、0.02％的亚磷酸二正丁酯以及余量的润滑油基础油备用，且选取的物料均为合格产品；In the above-mentioned step 1, firstly select 0.1% graphene, 1% HSD, 14% borate, 0.05% metal powder microspheres, 0.04% benzotriazole, 0.02% di-n-butyl phosphite and the balance of lubricating base oil are reserved, and the selected materials are all qualified products;
其中上述步骤二中，将步骤一中选取的硼酸脂首先进行加热处理，且加热温度为50-60℃，同时加热时间为10-15min，随后将加热后得到的硼酸脂和润滑油基础油首先放置在搅拌机中，随后在搅拌温度为50-60℃的环境下搅拌分散25-30min得到分散基础油，且搅拌转速为3000r/min；Wherein in the above-mentioned step 2, the boric acid ester selected in step 1 is first heated, and the heating temperature is 50-60 ° C, and the heating time is 10-15min, and then the boric acid ester and lubricating oil base oil obtained after heating are first Place in a mixer, and then stir and disperse for 25-30min under a stirring temperature of 50-60°C to obtain a dispersed base oil, and the stirring speed is 3000r/min;
其中上述步骤三中，将步骤一中选取的HSD加入到步骤二中的分散基础油中进行电磁搅拌30min，搅拌转速为3000r/min，同时在搅拌的过程中，需要不断的对分散基础油进行加热处理得到混合料，同时加热温度为40-50℃，当电磁搅拌完成后，即可停止加热；In the above step 3, the HSD selected in step 1 is added to the dispersed base oil in step 2 for electromagnetic stirring for 30min, and the stirring speed is 3000r/min. The mixture is obtained by heat treatment, and the heating temperature is 40-50 ° C. When the electromagnetic stirring is completed, the heating can be stopped;
其中上述步骤四中，将步骤三中得到的混合料中加入步骤一中选取的石墨烯、金属粉微球、苯骈三氮唑以及亚磷酸二正丁酯加入到步骤三中得到的混合料中随后搅拌得到半成品，且搅拌利用油漆分散机进行搅拌30min后即可，同时搅拌转速为3500r/min；Wherein in the above-mentioned step 4, adding graphene, metal powder microspheres, benzotriazole and di-n-butyl phosphite selected in step 1 to the mixture obtained in step 3 and adding to the mixture obtained in step 3 Then stir to obtain a semi-finished product, and the stirring is performed after 30 minutes by using a paint disperser, and the stirring speed is 3500 r/min;
其中上述步骤五中，将步骤四中得到的半成品放置在干燥的房间中静置10-20min后，即可将半成品进行灌装处理得到成品，同时干燥的房间中湿度为20-30％。In the above step 5, the semi-finished product obtained in step 4 is placed in a dry room for 10-20 minutes, and then the semi-finished product can be filled to obtain a finished product, and the humidity in the dry room is 20-30%.
实施例3：Example 3:
一种提高导热性和吸附性的石墨烯机油，配方包括：石墨烯、HSD、硼酸脂、金属粉微球、苯骈三氮唑、亚磷酸二正丁酯以及余量的润滑油基础油，各组分的质量百分比分别是：0.05％的石墨烯、1％的HSD、14％的硼酸脂、0.03％的金属粉微球、0.01％的苯骈三氮唑、0.02％的亚磷酸二正丁酯以及余量的润滑油基础油；其中石墨烯的直径为1-5um，厚度为1-10nm，同时比表面积为500-1000m2/g；金属粉微球是由铬粉微球、氧化铁微球和钼粉微球按照重量比1∶1∶1混合制备而成，且使用的微球粒径为20-40nm。A graphene engine oil for improving thermal conductivity and adsorption, the formula comprising: graphene, HSD, borate, metal powder microspheres, benzotriazole, di-n-butyl phosphite and the balance of lubricating oil base oil, The mass percentages of each component are: 0.05% graphene, 1% HSD, 14% borate, 0.03% metal powder microspheres, 0.01% benzotriazole, 0.02% di-n-phosphite Butyl ester and the balance of lubricating oil base oil; wherein the diameter of graphene is 1-5um, the thickness is 1-10nm, and the specific surface area is 500-1000m 2 /g; the metal powder microspheres are composed of chromium powder microspheres, oxidized The iron microspheres and the molybdenum powder microspheres are prepared by mixing in a weight ratio of 1:1:1, and the particle size of the used microspheres is 20-40 nm.
一种提高导热性和吸附性的石墨烯机油的制备方法,包括以下步骤：步骤一，材料选取；步骤二，加热搅拌；步骤三，混合；步骤四，得到半成品；步骤五，灌装；A method for preparing graphene oil with improved thermal conductivity and adsorption, comprising the following steps: step 1, material selection; step 2, heating and stirring; step 3, mixing; step 4, obtaining semi-finished products; step 5, filling;
其中上述步骤一中，首先按照各组分的质量百分比分别选取0.05％的石墨烯、1％的HSD、14％的硼酸脂、0.03％的金属粉微球、0.01％的苯骈三氮唑、0.02％的亚磷酸二正丁酯以及余量的润滑油基础油备用，且选取的物料均为合格产品；In the above-mentioned step 1, firstly select 0.05% graphene, 1% HSD, 14% borate, 0.03% metal powder microspheres, 0.01% benzotriazole, 0.02% di-n-butyl phosphite and the balance of lubricating base oil are reserved, and the selected materials are all qualified products;
其中上述步骤二中，将步骤一中选取的硼酸脂首先进行加热处理，且加热温度为50-60℃，同时加热时间为10-15min，随后将加热后得到的硼酸脂和润滑油基础油首先放置在搅拌机中，随后在搅拌温度为50-60℃的环境下搅拌分散25-30min得到分散基础油，且搅拌转速为3000r/min；Wherein in the above-mentioned step 2, the boric acid ester selected in step 1 is first heated, and the heating temperature is 50-60 ° C, and the heating time is 10-15min, and then the boric acid ester and lubricating oil base oil obtained after heating are first Place in a mixer, and then stir and disperse for 25-30min under a stirring temperature of 50-60°C to obtain a dispersed base oil, and the stirring speed is 3000r/min;
其中上述步骤三中，将步骤一中选取的HSD加入到步骤二中的分散基础油中进行电磁搅拌30min，搅拌转速为3000r/min，同时在搅拌的过程中，需要不断的对分散基础油进行加热处理得到混合料，同时加热温度为40-50℃，当电磁搅拌完成后，即可停止加热；In the above step 3, the HSD selected in step 1 is added to the dispersed base oil in step 2 for electromagnetic stirring for 30min, and the stirring speed is 3000r/min. The mixture is obtained by heat treatment, and the heating temperature is 40-50 ° C. When the electromagnetic stirring is completed, the heating can be stopped;
其中上述步骤四中，将步骤三中得到的混合料中加入步骤一中选取的石墨烯、金属粉微球、苯骈三氮唑以及亚磷酸二正丁酯加入到步骤三中得到的混合料中随后搅拌得到半成品，且搅拌利用油漆分散机进行搅拌30min后即可，同时搅拌转速为3500r/min；Wherein in the above-mentioned step 4, adding graphene, metal powder microspheres, benzotriazole and di-n-butyl phosphite selected in step 1 to the mixture obtained in step 3 and adding to the mixture obtained in step 3 Then stir to obtain a semi-finished product, and the stirring is performed after 30 minutes by using a paint disperser, and the stirring speed is 3500 r/min;
其中上述步骤五中，将步骤四中得到的半成品放置在干燥的房间中静置10-20min后，即可将半成品进行灌装处理得到成品，同时干燥的房间中湿度为20-30％。In the above step 5, the semi-finished product obtained in step 4 is placed in a dry room for 10-20 minutes, and then the semi-finished product can be filled to obtain a finished product, and the humidity in the dry room is 20-30%.
实施例4：Example 4:
一种提高导热性和吸附性的石墨烯机油，配方包括：石墨烯、HSD、硼酸脂、金属粉微球、苯骈三氮唑、亚磷酸二正丁酯以及余量的润滑油基础油，各组分的质量百分比分别是：0.08％的石墨烯、0.9％的HSD、13％的硼酸脂、0.04％的金属粉微球、0.03％的苯骈三氮唑、0.01％的亚磷酸二正丁酯以及余量的润滑油基础油；其中石墨烯的直径为1-5um，厚度为1-10nm，同时比表面积为500-1000m2/g；金属粉微球是由铬粉微球、氧化铁微球和钼粉微球按照重量比1∶1∶1混合制备而成，且使用的微球粒径为20-40nm。A graphene engine oil for improving thermal conductivity and adsorption, the formula comprising: graphene, HSD, borate, metal powder microspheres, benzotriazole, di-n-butyl phosphite and the balance of lubricating oil base oil, The mass percentages of each component are: 0.08% graphene, 0.9% HSD, 13% borate, 0.04% metal powder microspheres, 0.03% benzotriazole, 0.01% di-n-phosphite Butyl ester and the balance of lubricating oil base oil; wherein the diameter of graphene is 1-5um, the thickness is 1-10nm, and the specific surface area is 500-1000m 2 /g; the metal powder microspheres are composed of chromium powder microspheres, oxidized The iron microspheres and the molybdenum powder microspheres are prepared by mixing in a weight ratio of 1:1:1, and the particle size of the used microspheres is 20-40 nm.
一种提高导热性和吸附性的石墨烯机油的制备方法,包括以下步骤：步骤一，材料选取；步骤二，加热搅拌；步骤三，混合；步骤四，得到半成品；步骤五，灌装；A method for preparing graphene oil with improved thermal conductivity and adsorption, comprising the following steps: step 1, material selection; step 2, heating and stirring; step 3, mixing; step 4, obtaining semi-finished products; step 5, filling;
其中上述步骤一中，首先按照各组分的质量百分比分别选取0.08％的石墨烯、0.9％的HSD、13％的硼酸脂、0.04％的金属粉微球、0.03％的苯骈三氮唑、0.01％的亚磷酸二正丁酯以及余量的润滑油基础油备用，且选取的物料均为合格产品；In the above-mentioned step 1, firstly select 0.08% graphene, 0.9% HSD, 13% borate, 0.04% metal powder microspheres, 0.03% benzotriazole, 0.01% di-n-butyl phosphite and the balance of lubricating base oil are reserved, and the selected materials are qualified products;
其中上述步骤二中，将步骤一中选取的硼酸脂首先进行加热处理，且加热温度为50-60℃，同时加热时间为10-15min，随后将加热后得到的硼酸脂和润滑油基础油首先放置在搅拌机中，随后在搅拌温度为50-60℃的环境下搅拌分散25-30min得到分散基础油，且搅拌转速为3000r/min；Wherein in the above-mentioned step 2, the boric acid ester selected in step 1 is first heated, and the heating temperature is 50-60 ° C, and the heating time is 10-15min, and then the boric acid ester and lubricating oil base oil obtained after heating are first Place in a mixer, and then stir and disperse for 25-30min under a stirring temperature of 50-60°C to obtain a dispersed base oil, and the stirring speed is 3000r/min;
其中上述步骤三中，将步骤一中选取的HSD加入到步骤二中的分散基础油中进行电磁搅拌30min，搅拌转速为3000r/min，同时在搅拌的过程中，需要不断的对分散基础油进行加热处理得到混合料，同时加热温度为40-50℃，当电磁搅拌完成后，即可停止加热；In the above step 3, the HSD selected in step 1 is added to the dispersed base oil in step 2 for electromagnetic stirring for 30min, and the stirring speed is 3000r/min. The mixture is obtained by heat treatment, and the heating temperature is 40-50 ° C. When the electromagnetic stirring is completed, the heating can be stopped;
其中上述步骤四中，将步骤三中得到的混合料中加入步骤一中选取的石墨烯、金属粉微球、苯骈三氮唑以及亚磷酸二正丁酯加入到步骤三中得到的混合料中随后搅拌得到半成品，且搅拌利用油漆分散机进行搅拌30min后即可，同时搅拌转速为3500r/min；Wherein in the above-mentioned step 4, adding graphene, metal powder microspheres, benzotriazole and di-n-butyl phosphite selected in step 1 to the mixture obtained in step 3 and adding to the mixture obtained in step 3 Then stir to obtain a semi-finished product, and the stirring is performed after 30 minutes by using a paint disperser, and the stirring speed is 3500 r/min;
其中上述步骤五中，将步骤四中得到的半成品放置在干燥的房间中静置10-20min后，即可将半成品进行灌装处理得到成品，同时干燥的房间中湿度为20-30％。In the above step 5, the semi-finished product obtained in step 4 is placed in a dry room for 10-20 minutes, and then the semi-finished product can be filled to obtain a finished product, and the humidity in the dry room is 20-30%.
将上述实施例所得产品分别给100位使用者进行使用，随后统计使用者的使用评价，所得结果如下表：The products obtained from the above-mentioned embodiment are used by 100 users respectively, and then the user's use evaluations are counted, and the obtained results are as follows:
基于上述，本发明的优点在于，在制备的过程中，在配方中加入了一定量的石墨烯，利用石墨烯具有的导热性以及吸附性，继而提高了该机油的导热性以及吸附性，且在制备的过程中，通过加热的方式以及现在空气湿度的方式，降低了硼酸脂与水的接触，继而降低了硼酸脂水解的情况反应，从而保证了该机油的品质，同时在配方中加入了一定量的纳米金属粉末，利用纳米金属粉末的添加，有利于使纳米金属粉末附着在机械结构中，从而提高了润滑效果，降低了机械之间的摩擦，提高了该机油的实用性，Based on the above, the advantage of the present invention is that, during the preparation process, a certain amount of graphene is added to the formula, and the thermal conductivity and adsorption properties of graphene are used to improve the thermal conductivity and adsorption properties of the oil, and In the preparation process, the contact between borate and water is reduced by heating and the current air humidity, which in turn reduces the hydrolysis reaction of borate, thereby ensuring the quality of the oil. A certain amount of nano metal powder, using the addition of nano metal powder, is conducive to making the nano metal powder adhere to the mechanical structure, thereby improving the lubrication effect, reducing the friction between the machines, and improving the practicability of the oil.
对于本领域技术人员而言，显然本发明不限于上述示范性实施例的细节，而且在不背离本发明的精神或基本特征的情况下，能够以其他的具体形式实现本发明。因此，无论从哪一点来看，均应将实施例看作是示范性的，而且是非限制性的，本发明的范围由所附权利要求而不是上述说明限定，因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。不应将权利要求中的任何附图标记视为限制所涉及的权利要求。It will be apparent to those skilled in the art that the present invention is not limited to the details of the above-described exemplary embodiments, but that the present invention may be embodied in other specific forms without departing from the spirit or essential characteristics of the invention. Therefore, the embodiments are to be regarded in all respects as illustrative and not restrictive, and the scope of the invention is to be defined by the appended claims rather than the foregoing description, which are therefore intended to fall within the scope of the claims. All changes within the meaning and range of the equivalents of , are included in the present invention. Any reference signs in the claims shall not be construed as limiting the involved claim.
Claims (7)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210022702.4A CN114276860A (en) | 2022-01-10 | 2022-01-10 | A kind of graphene oil with improved thermal conductivity and adsorption and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210022702.4A CN114276860A (en) | 2022-01-10 | 2022-01-10 | A kind of graphene oil with improved thermal conductivity and adsorption and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114276860A true CN114276860A (en) | 2022-04-05 |
Family
ID=80880671
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210022702.4A Pending CN114276860A (en) | 2022-01-10 | 2022-01-10 | A kind of graphene oil with improved thermal conductivity and adsorption and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114276860A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105602654A (en) * | 2016-02-05 | 2016-05-25 | 四川碳世界科技有限公司 | Graphene lubricating oil additive and preparation method thereof |
| CN107532101A (en) * | 2015-11-27 | 2018-01-02 | 深圳纳伟力科技有限公司 | Lubrication oil antiwear agent, lubricating oil complexing agent, lubricating oil and application |
| CN107686768A (en) * | 2017-09-29 | 2018-02-13 | 成都新柯力化工科技有限公司 | A kind of abrasion-proof lubricant oil and preparation method thereof |
| KR20190072186A (en) * | 2017-12-15 | 2019-06-25 | 현대자동차주식회사 | Graphene oxide derivative and method for fabricating the same |
| CN111363609A (en) * | 2020-05-06 | 2020-07-03 | 李义飞 | A kind of modified graphene lubricating oil and preparation method thereof |
| CN112920878A (en) * | 2021-01-28 | 2021-06-08 | 魏世晋 | Modified anti-friction graphene lubricating oil and preparation process thereof |
-
2022
- 2022-01-10 CN CN202210022702.4A patent/CN114276860A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107532101A (en) * | 2015-11-27 | 2018-01-02 | 深圳纳伟力科技有限公司 | Lubrication oil antiwear agent, lubricating oil complexing agent, lubricating oil and application |
| CN105602654A (en) * | 2016-02-05 | 2016-05-25 | 四川碳世界科技有限公司 | Graphene lubricating oil additive and preparation method thereof |
| CN107686768A (en) * | 2017-09-29 | 2018-02-13 | 成都新柯力化工科技有限公司 | A kind of abrasion-proof lubricant oil and preparation method thereof |
| KR20190072186A (en) * | 2017-12-15 | 2019-06-25 | 현대자동차주식회사 | Graphene oxide derivative and method for fabricating the same |
| CN111363609A (en) * | 2020-05-06 | 2020-07-03 | 李义飞 | A kind of modified graphene lubricating oil and preparation method thereof |
| CN112920878A (en) * | 2021-01-28 | 2021-06-08 | 魏世晋 | Modified anti-friction graphene lubricating oil and preparation process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109370751A (en) | A new type of stainless steel rolling oil and its preparation method and use method | |
| CN106566640B (en) | A kind of magnesium alloy sheet and strip rolling emulsion and preparation method thereof | |
| CN111363609A (en) | A kind of modified graphene lubricating oil and preparation method thereof | |
| CN101698808B (en) | Plate-strip steel cold-rolling emulsified oil containing nanometer hexagonal boron nitride particles, and preparation method | |
| CN116143829B (en) | High extreme pressure proton type ionic liquid, preparation method and application thereof as oil-based additive | |
| CN111808660B (en) | Low-friction-coefficient composite calcium sulfonate lubricating grease composition and preparation method thereof | |
| CN114276860A (en) | A kind of graphene oil with improved thermal conductivity and adsorption and preparation method thereof | |
| CN115386407B (en) | Choline modified graphene oxide, lubricating oil and preparation method | |
| CN104818103A (en) | Cold extrusion forming lubricant for low carbon steel part used for automobile and preparation method thereof | |
| CN115161103A (en) | High-lubricity graphite/polytetrafluoroethylene lubricant and preparation method thereof | |
| CN112111321A (en) | Functionalized graphene lubricant for metal plastic processing and preparation method thereof | |
| CN111534358A (en) | A thermally conductive grease and its preparation method and application | |
| CN104450007A (en) | High temperature-resistant lubricating grease for electric conduction and preparation method thereof | |
| CN114874406B (en) | Multifunctional nano lubricating oil additive and preparation method and application thereof | |
| CN110437918A (en) | A kind of antioxygen body self-restoring lubricating oil and preparation method thereof containing graphene oxide | |
| CN108179052A (en) | A kind of nano magnetic lubricating oil and preparation method thereof | |
| CN114752204A (en) | Wear-resistant polyphenyl ether self-lubricating composite material and preparation method and application thereof | |
| CN118879381B (en) | A kind of grease composition for bearing and preparation method thereof | |
| CN111423916A (en) | CTAB modified nano molybdenum disulfide, preparation method and application thereof, lithium-based lubricating grease and preparation method thereof | |
| CN108559597A (en) | A kind of punching press lubricating fluid of clean type stainless steel multilayer composite plate and preparation method thereof | |
| CN116042286B (en) | Preparation method and application of glucosyl/amino acid composite carbon sphere | |
| CN118064202B (en) | Cold rolling oil special for limiting working condition of galvanized substrate | |
| CN115746938B (en) | High-dropping-point perfluoropolyether lubricating grease composition and preparation method thereof | |
| CN117343780A (en) | A kind of carbon steel rolling oil with strong and stable dispersion emulsification system | |
| CN104449948A (en) | Graphene-oxide-based zinc borate and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |