CN114275780B - Activated carbon for flue gas desulfurization, preparation method and preparation device - Google Patents

Activated carbon for flue gas desulfurization, preparation method and preparation device Download PDF

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CN114275780B
CN114275780B CN202111609808.6A CN202111609808A CN114275780B CN 114275780 B CN114275780 B CN 114275780B CN 202111609808 A CN202111609808 A CN 202111609808A CN 114275780 B CN114275780 B CN 114275780B
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fixedly connected
driving motor
activated carbon
rotating shaft
feeding mechanism
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CN114275780A (en
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武斌
李进
王敏
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Jiangsu Landian Environmental Protection Co ltd
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Jiangsu Landian Environmental Protection Co ltd
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Abstract

The invention discloses activated carbon for flue gas desulfurization, a preparation method and a preparation device, wherein the preparation device comprises a feeding mechanism, an angle adjusting mechanism is arranged below the feeding mechanism, a crushing mechanism is further arranged on the feeding mechanism, a material guide plate is arranged below the feeding mechanism, a stirring barrel is arranged on one side of the material guide plate, and a stirring mechanism is arranged in the stirring barrel; the preparation device of the invention improves the production efficiency of the activated carbon, and simultaneously greatly saves manpower and material resources; the invention also provides an activated carbon for flue gas desulfurization, wherein the activated carbon comprises brown coal dust, sawdust, high-temperature modified asphalt, starch and vanadium pentoxide; the preparation method comprises mixing the materials, molding, adding vanadium pentoxide, carbonizing, and activating; the preparation of the activated carbon for flue gas desulfurization reduces the environment to the atmosphere, so that the preparation of the activated carbon is more environment-friendly and the cost is lower.

Description

Activated carbon for flue gas desulfurization, preparation method and preparation device
Technical Field
The invention belongs to the technical field of emission control of smoke pollutants, and particularly relates to activated carbon for smoke desulfurization, a preparation method and a preparation device.
Background
SO 2 Is colorless and has strong pungent smell, and is dispersed in air 2 Has serious harm to human health and ecological environment, and is one of main atmospheric pollutants which cause the continuous deterioration of air quality. Currently, the desulfurization pathways are respectively pre-combustion, mid-combustion and post-combustion desulfurization (also known as flue gas desulfurization), where flue gas desulfurization is considered to be the most effective control S0 2 The way. The flue gas desulfurization method comprises a dry method, a semi-dry method and a flue gas desulfurization methodWet desulfurizing. The wet desulfurization generally uses a limestone-gypsum method, which is a method used in a large amount in the industry in China, and the method can corrode equipment, cause secondary pollution, produce byproducts and prevent wastewater from being treated. Semi-dry desulfurization is usually performed by spray drying, which requires periodic cleaning of the pipeline, and is costly. The dry desulfurization is most commonly used as active carbon adsorption desulfurization, the method has simple process, can be recycled, hardly generates waste gas, waste water and waste residue, has lower cost, and can adsorb SO on the basis of no water consumption 2 The strong adsorptivity and certain catalytic activity of the activated carbon can also realize the removal of NO, heavy metal, dust and dioxin at the same time, and the recycling of the activated carbon can also be realized through the regeneration process, so that the whole process has NO pollution.
As early as the middle of 20 th century, several companies in Japan and Germany gradually apply the active carbon combined desulfurization and denitrification process to coal-fired power plants, coal-fired boilers and steel sintering machines, and the desulfurization and denitrification rate can reach more than 90%. In 1979, the Hubei pine lawn power plant of China introduces an active carbon desulfurization technology for the first time, and uses iodine-containing active carbon as a catalyst to adsorb on a fixed bed, however, the technology cannot be successfully applied due to serious iodine loss. The Shanxi Tai steel adopts an active carbon moving bed sulfur denitration integrated process of Sumitomo company in 2011 at home, integrates desulfurization, denitration and dust removal, obtains 98% concentrated sulfuric acid byproducts by using a submerged combustion method, and realizes recycling of resources to a certain extent.
Nevertheless, the flue gas desulfurization by the activated carbon method has some defects, mainly the adsorption capacity of common industrial activated carbon to sulfur dioxide is limited and is generally only 1-2%, so that the problems of huge equipment, frequent regeneration and the like are caused; the efficiency is not high when producing and preparing the activated carbon, for example, a large amount of blocky materials are still contained when materials are mixed and stirred, so that the stirring and mixing efficiency is not high.
Disclosure of Invention
Aiming at the prior art, an activated carbon for flue gas desulfurization and a preparation method thereof are provided, wherein the activated carbon comprises the following components in parts by weight: 100 parts of brown coal dust, 80-120 parts of saw dust, 10-35 parts of high-temperature modified asphalt, 5-20 parts of starch and 1-2 parts of vanadium pentoxide, wherein the preparation method of the activated carbon comprises the steps of mixing and molding 100 parts of brown coal dust, 80-120 parts of saw dust, 10-35 parts of high-temperature modified asphalt and 5-20 parts of starch, adding 1-2 parts of vanadium pentoxide, and carbonizing and activating.
Preferably, the carbonization temperature of the activated carbon is 400-700 ℃.
Preferably, the activated carbon activation temperature is 800-1100 ℃.
Preferably, the preparation facilities of activated carbon for flue gas desulfurization, preparation facilities includes feed mechanism, feed mechanism's below is equipped with angle adjustment mechanism, one side of feed mechanism is equipped with infrared emitter, infrared emitter's opposite the feed mechanism is last still to be equipped with infrared receiver, infrared receiver's one side feed mechanism is last still to be equipped with crushing mechanism, feed mechanism's below is equipped with the stock guide, one side of stock guide is equipped with the agitator, be equipped with rabbling mechanism in the agitator.
Preferably, the feeding mechanism comprises two symmetrical brackets, one side of each symmetrical bracket is connected with a driving roller through a bearing, one side of each driving roller is provided with a first driving motor, the other side of each bracket is connected with a driven roller through a bearing, and the driving rollers and the driven rollers are connected with a belt in a transmission manner.
Preferably, the adjusting mechanism comprises two vertical rods, a rotating shaft is fixedly connected between the two vertical rods, two sides of the rotating shaft are respectively connected with the support through bearings, one side of each vertical rod is provided with a first cylinder, the driving end of each first cylinder is hinged with a moving block, the moving blocks are connected with a connecting rod in a sliding mode, the connecting rod is fixedly connected with an adjusting box, and the adjusting box is arranged below the support.
Preferably, the crushing mechanism comprises a first connecting frame, the first connecting frame is fixedly connected to the support, a first chassis is arranged in the middle of the first connecting frame, a second driving motor is fixedly connected in the first chassis, a driving end of the second driving motor is fixedly connected with an incomplete gear, the incomplete gear is meshed with two racks, the two racks are respectively arranged on the upper side and the lower side of the annular frame, a connecting rod is further arranged at one end of the annular frame, and one end of the connecting rod penetrates through the first chassis and is fixedly connected with a pressing plate.
Preferably, the stirring mechanism comprises a third driving motor, the third driving motor is arranged at the middle part of the stirring barrel, the driving end of the third driving motor penetrates through the stirring barrel and is fixedly connected with a rotating shaft, a plurality of stirring shafts are further arranged on the rotating shaft, a second machine case is arranged above the third driving motor, the second machine case is fixedly connected with a second connecting frame, the second connecting frame is arranged on the stirring barrel, two sides of the second machine case are fixedly connected with connecting plates, one side bearing of each connecting plate is connected with a first rotating shaft, one end of each first rotating shaft is provided with a fourth driving motor, annular protruding blocks are further arranged on the first rotating shaft and are slidably connected in connecting blocks, the connecting blocks are fixedly connected to the second rotating shaft, two ends of each second rotating shaft are connected with the connecting plates in a bearing mode, and one end of each second rotating shaft penetrates through the second machine case and is fixedly connected with the upper part of each third driving motor.
The beneficial effects are that:
(1) According to the activated carbon for flue gas desulfurization, the coal, the high-temperature modified asphalt and the starch are mixed according to a certain proportion, and the starch coal tar is used for replacing products to prepare the activated carbon, so that the atmospheric environment is improved, the pollution is reduced, the preparation of the activated carbon is more environment-friendly, and the cost is lower.
(2) The preparation device disclosed by the invention improves the production efficiency of the activated carbon, and simultaneously greatly saves manpower and material resources: judging the size of the material through an infrared emitter and an infrared receiver so as to determine whether to crush the material or not; the angle of the feeding mechanism is adjusted through the angle adjusting mechanism, so that the stacking time of materials on the feeding mechanism is reduced, and the production efficiency is improved; the materials are uniformly and rapidly stirred through the stirring operation of up-and-down movement.
Drawings
FIG. 1 is a schematic diagram of the structure of the present invention;
FIG. 2 is a schematic view of the internal structure of the regulating box of the present invention;
FIG. 3 is a schematic view of the structure of the moving block of the present invention;
FIG. 4 is a schematic view of the internal structure of the first chassis of the present invention;
FIG. 5 is a schematic view of the internal structure of the stirring barrel of the present invention;
fig. 6 is a schematic diagram of the internal structure of the second chassis of the present invention.
In the figure: 1. a feeding mechanism; 11. a material guide plate; 12. a bracket; 13. a drive roll; 14. a first driving motor; 15. driven roller; 16. a belt; 2. an angle adjusting mechanism; 21. a vertical rod; 22. a rotating shaft; 23. a first cylinder; 24. a moving block; 25. a connecting rod; 26. an adjustment box; 3. an infrared emitter; 4. an infrared receiver; 5. a crushing mechanism; 51. a first connection frame; 52. a first chassis; 53. a second driving motor; 54. an incomplete gear; 55. a rack; 56. an annular frame; 57. a connecting rod; 58. a pressing plate; 6. a stirring barrel; 7. a stirring mechanism; 71. a third driving motor; 72. a rotation shaft; 73. a stirring shaft; 74. a second chassis; 741. a connecting plate; 742. a first rotating shaft; 743. a fourth driving motor; 744. annular protruding blocks; 745. a connecting block; 746. a second rotating shaft; 75. a second connecting frame;
Detailed Description
In the description of the present invention, unless otherwise indicated, the meaning of "a plurality" is two or more; the terms "upper," "lower," "left," "right," "inner," "outer," "front," "rear," "head," "tail," and the like are used as an orientation or positional relationship based on that shown in the drawings, merely to facilitate description of the invention and to simplify the description, and do not indicate or imply that the devices or elements referred to must have a particular orientation, be constructed and operated in a particular orientation, and therefore should not be construed as limiting the invention. Furthermore, the terms "first," "second," "third," and the like are used for descriptive purposes only and are not to be construed as indicating or implying relative importance.
In the description of the present invention, it should be noted that, unless explicitly specified and limited otherwise, the terms "connected," "connected," and "connected" are to be construed broadly, and may be either fixedly connected, detachably connected, or integrally connected, for example; can be mechanically or electrically connected; can be directly connected or indirectly connected through an intermediate medium. The specific meaning of the above terms in the present invention will be understood in specific cases by those of ordinary skill in the art.
The invention is further explained below with reference to the drawings. An activated carbon for flue gas desulfurization and a preparation method thereof are provided, wherein the activated carbon comprises the following components in parts by weight: 100 parts of brown coal dust, 80-120 parts of saw dust, 10-35 parts of high-temperature modified asphalt, 5-20 parts of starch and 1-2 parts of vanadium pentoxide, wherein the preparation method of the activated carbon comprises the steps of mixing and molding 100 parts of brown coal dust, 80-120 parts of saw dust, 10-35 parts of high-temperature modified asphalt and 5-20 parts of starch, adding 1-2 parts of vanadium pentoxide, and carbonizing and activating.
The carbonization temperature of the activated carbon is 400-700 ℃.
The activation temperature of the activated carbon is 800-1100 ℃.
And respectively carrying out saturated sulfur capacity test on the active carbon with different ingredients:
1. the active carbon comprises the following ingredients: 200g of lignite powder, 200g of sawdust, 20g of high-temperature modified asphalt, 6g of starch and 4g of vanadium pentoxide, wherein the carbonization temperature is 600 ℃, and the activation temperature is 800 ℃ to prepare the activated carbon A.
2. The active carbon comprises the following ingredients: 200g of lignite powder, 160g of sawdust, 15g of high-temperature modified asphalt, 80g of starch and 5g of vanadium pentoxide, wherein the carbonization temperature is 400 ℃, and the activation temperature is 1000 ℃ to prepare the activated carbon B.
3. The active carbon comprises the following ingredients: 200g of lignite powder, 240g of sawdust, 13g of high-temperature modified asphalt, 5g of starch and 8.8g of vanadium pentoxide, wherein the carbonization temperature is 500 ℃, and the activation temperature is 1100 ℃ to prepare the activated carbon C.
4. The active carbon comprises the following ingredients: 200g of lignite powder, 200g of sawdust, 10g of high-temperature modified asphalt, 10g of starch and 5g of vanadium pentoxide, wherein the carbonization temperature is 700 ℃, and the activation temperature is 900 ℃ to prepare the activated carbon D.
5. The active carbon comprises the following ingredients: 200g of lignite powder, 200g of sawdust, 20g of high-temperature modified asphalt, 10g of starch and 6g of vanadium pentoxide, wherein the carbonization temperature is 550 ℃, and the activation temperature is 1000 ℃ to prepare the activated carbon E.
By N 2 Preparing SO-containing gas as bottom gas 2 3000mg/Nm 3 The saturated sulfur capacities of various activated carbons were measured at normal temperature, and the results were as follows:
it can be seen that the mixture ratio of lignite powder, sawdust, high-temperature modified asphalt, starch and vanadium pentoxide is 10:10:1:1:0.5: and 0.3, the carbonization temperature is 550 ℃, the activation temperature is 1000 ℃, and the saturated sulfur capacity of the prepared active carbon E is maximum.
Please refer to fig. 1-6: the preparation device of the activated carbon for flue gas desulfurization comprises a feeding mechanism 1, wherein an angle adjusting mechanism 2 is arranged below the feeding mechanism 1, an infrared emitter 3 is arranged on one side of the feeding mechanism 1, an infrared receiver 4 is arranged on the opposite side of the infrared emitter 3 and on the feeding mechanism 1, a crushing mechanism 5 is further arranged on one side of the infrared receiver 4 and on the feeding mechanism 1, a material guide plate 11 is arranged below the feeding mechanism 1, a stirring barrel 6 is arranged on one side of the material guide plate 11, and a stirring mechanism 7 is arranged in the stirring barrel 6.
The feeding mechanism 1 comprises two symmetrical brackets 12, one side of each of the two symmetrical brackets 12 is connected with a driving roller 13 through a bearing, one side of each driving roller 13 is provided with a first driving motor 14, the other side of each of the two brackets 12 is connected with a driven roller 15 through a bearing, and the driving rollers 13 and the driven rollers 15 are connected with a belt 16 in a transmission manner. The first driving motor 14 is started to drive the driving roller 13 to rotate, so that the driven roller 15 and the belt 16 are driven to move, materials on the belt 16 are moved, meanwhile, the infrared emitter 3 continuously emits infrared rays to the infrared receiver 4, the infrared receiver 4 receives the infrared rays to indicate that the size of the materials is qualified, the materials are not required to be crushed, and otherwise, the crushing mechanism 5 is started to crush the materials.
The adjusting mechanism 2 comprises two vertical rods 21, a rotating shaft 22 is fixedly connected between the two vertical rods 21, two sides of the rotating shaft 22 are respectively connected with a support 12 through bearings, one side of each vertical rod 21 is provided with a first air cylinder 23, the driving end of each first air cylinder 23 is hinged with a moving block 24, the moving blocks 24 are slidably connected with a connecting rod 25, the connecting rod 25 is fixedly connected with an adjusting box 26, and the adjusting box 26 is arranged below the support 12. By activating the first cylinder 23, the driving end of the first cylinder 23 drives the moving block 24 to move, so that the two symmetrical brackets 12 rotate around the rotating shaft 22, and the angle of the belt 16 is adjusted, so that the material is not blocked on the belt 16.
The smashing mechanism 5 comprises a first connecting frame 51, the first connecting frame 51 is fixedly connected to the support 12, a first machine box 52 is arranged in the middle of the first connecting frame 51, a second driving motor 53 is fixedly connected in the first machine box 52, a driving end of the second driving motor 53 is fixedly connected with an incomplete gear 54, the incomplete gear 54 is connected with two racks 55 in a meshed mode, the incomplete gear 54 is connected with the two racks 55 in a meshed mode, the two racks 55 are respectively arranged above and below the annular frame 56, a connecting rod 57 is further arranged at one end of the annular frame 56, and one end of the connecting rod 57 penetrates through the first machine box 52 and is fixedly connected with a pressing plate 58. The second driving motor 53 is started, the driving end of the second driving motor 53 drives the incomplete gear 54 to rotate, and the incomplete gear 54 is connected to the two racks 55 in a meshed mode, so that the annular frame 56 moves in a reciprocating mode, and materials on the belt 16 are crushed.
The stirring mechanism 7 comprises a third driving motor 71, the third driving motor 71 is arranged in the middle of the stirring barrel 6, the driving end of the third driving motor 7 penetrates through the stirring barrel 6 and is fixedly connected with a rotating shaft 72, a plurality of stirring shafts 73 are further arranged on the rotating shaft 72, a second machine case 74 is arranged above the third driving motor 71, the second machine case 74 is fixedly connected with a second connecting frame 75, the second connecting frame 75 is arranged on the stirring barrel 6, two sides of the second machine case 74 are fixedly connected with a connecting plate 741, one side bearing of the two connecting plates 741 is connected with a first rotating shaft 742, one end of the first rotating shaft 742 is provided with a fourth driving motor 743, an annular protruding block 744 is further arranged on the first rotating shaft 742 and is connected in the connecting block 745 in a sliding mode, the connecting block 745 is fixedly connected with the second rotating shaft 746, two ends of the second rotating shaft 746 are connected with the connecting plates 741 in a bearing mode, and one end of the second rotating shaft 746 penetrates through the second machine case 74 and is fixedly connected to the upper portion of the third driving motor 71. By starting the fourth driving motor 743, the driving end of the fourth driving motor 743 drives the first rotating shaft 742 and the protruding block 744 to rotate, the protruding block 744 is slidably connected in the connecting block 745, and the connecting block 745 is driven to move up and down when the protruding block 744 rotates, so as to drive the third driving motor 71 and the rotating shaft 72 to move up and down, so that stirring is more uniform.
Principle of operation: firstly, preventing materials on a belt 16, starting a first driving motor 14 to drive a driving roller 13 to rotate, driving a driven roller 15 and the belt 16 to move, moving the materials on the belt 16, and simultaneously, continuously transmitting infrared rays to an infrared ray receiver 4 by an infrared ray transmitter 3, wherein the infrared ray receiver 4 receives the infrared rays to indicate that the size of the materials is qualified and the materials are not required to be crushed, otherwise, starting a crushing mechanism 5 to crush the materials;
the second driving motor 53 is started, the driving end of the second driving motor 53 drives the incomplete gear 54 to rotate, and the incomplete gear 54 is connected to the two racks 55 in a meshed mode, so that the annular frame 56 moves in a reciprocating mode, and materials on the belt 16 are crushed.
When materials are accumulated on the belt 16, a first air cylinder 23 is started, and the driving end of the first air cylinder 23 drives a moving block 24 to move, so that the two symmetrical brackets 12 rotate around the rotating shaft 22, the angle of the belt 16 is adjusted, and the materials are poured into the stirring barrel 6;
by starting the fourth driving motor 743, the driving end of the fourth driving motor 743 drives the first rotating shaft 742 and the protruding block 744 to rotate, the protruding block 744 is slidably connected in the connecting block 745, and the connecting block 745 is driven to move up and down when the protruding block 744 rotates, so as to drive the third driving motor 71 and the rotating shaft 72 to move up and down, so that stirring is more uniform.
The foregoing is merely a preferred embodiment of the present invention and it should be noted that modifications and adaptations to those skilled in the art may be made without departing from the principles of the present invention, which are intended to be comprehended within the scope of the present invention.

Claims (2)

1. The preparation device of the activated carbon for flue gas desulfurization is characterized by comprising a feeding mechanism (1), wherein an angle adjusting mechanism (2) is arranged below the feeding mechanism (1), an infrared emitter (3) is arranged on one side of the feeding mechanism (1), an infrared receiver (4) is further arranged on the opposite side of the infrared emitter (3) and on the feeding mechanism (1), a crushing mechanism (5) is further arranged on one side of the infrared receiver (4) and on the feeding mechanism (1), a material guide plate (11) is arranged below the feeding mechanism (1), a stirring barrel (6) is arranged on one side of the material guide plate (11), and a stirring mechanism (7) is arranged in the stirring barrel (6);
the feeding mechanism (1) comprises two symmetrical brackets (12), one sides of the two symmetrical brackets (12) are respectively connected with a driving roller (13) through bearings, a first driving motor (14) is arranged on one side of the driving roller (13), the other sides of the two brackets (12) are respectively connected with a driven roller (15) through bearings, and a belt (16) is connected on the driving roller (13) and the driven roller (15) in a transmission manner;
the adjusting mechanism (2) comprises two vertical rods (21), a rotating shaft (22) is fixedly connected between the two vertical rods (21), two sides of the rotating shaft (22) are respectively connected with the support (12) through bearings, one side of each of the two vertical rods (21) is provided with a first air cylinder (23), the driving end of each first air cylinder (23) is hinged with a moving block (24), the moving blocks (24) are slidably connected with connecting rods (25), the connecting rods (25) are fixedly connected in an adjusting box (26), and the adjusting box (26) is arranged below the support (12);
the crushing mechanism (5) comprises a first connecting frame (51), the first connecting frame (51) is fixedly connected to the support (12), a first chassis (52) is arranged in the middle of the first connecting frame (51), a second driving motor (53) is fixedly connected in the first chassis (52), an incomplete gear (54) is fixedly connected to the driving end of the second driving motor (53), the incomplete gear (54) is connected to two racks (55) in a meshed mode, the two racks (55) are respectively arranged below and above the annular frame (56), a connecting rod (57) is further arranged at one end of the annular frame (56), and one end of the connecting rod (57) penetrates through the first chassis (52) and is fixedly connected with a pressing plate (58).
2. The device for preparing activated carbon for flue gas desulfurization according to claim 1, wherein the stirring mechanism (7) comprises a third driving motor (71), the third driving motor (71) is arranged in the middle of the stirring barrel (6), the driving end of the third driving motor (7) penetrates through the stirring barrel (6) and is fixedly connected with a rotating shaft (72), a plurality of stirring shafts (73) are further arranged on the rotating shaft (72), a second machine case (74) is arranged above the third driving motor (71), the second machine case (74) is fixedly connected with a second connecting frame (75), the second connecting frame (75) is arranged on the stirring barrel (6), two sides of the second machine case (74) are fixedly connected with connecting plates (741), one side of each connecting plate (741) is connected with a first rotating shaft (742) through a bearing, one end of each first rotating shaft (742) is provided with a fourth driving motor (743), the first rotating shaft (72) is further provided with a ring-shaped protruding block (744), the ring-shaped protruding block (742) is fixedly connected with the two connecting plates (745) on the two connecting plates (745) and fixedly connected with the two connecting plates (745), one end of the second rotating shaft (746) penetrates through the second machine case (74) and is fixedly connected above the third driving motor (71).
CN202111609808.6A 2021-12-24 2021-12-24 Activated carbon for flue gas desulfurization, preparation method and preparation device Active CN114275780B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101993066A (en) * 2010-02-11 2011-03-30 赵建勋 Desulfurated and denitrated activated coke and preparation method thereof
CN103911168A (en) * 2014-04-09 2014-07-09 江苏河海科技工程集团有限公司 Integral rapid carbonizing treatment technology for municipal waste
CN106192504A (en) * 2016-07-05 2016-12-07 上海勤琨信息科技有限公司 A kind of paper oleo stock reverse mould shaping equipment
CN106672967A (en) * 2016-12-28 2017-05-17 神华集团有限责任公司 Preparation method for activated carbon for desulfurization and denitrification and activated carbon for desulfurization and denitrification and application
CN208036746U (en) * 2018-04-12 2018-11-02 江苏高生生物饲料有限公司 A kind of yeast product automatic packaging line
CN112275207A (en) * 2020-11-22 2021-01-29 禹州市金品建材有限公司 Raw material stirring device for production of building waste pressed brick and use method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101993066A (en) * 2010-02-11 2011-03-30 赵建勋 Desulfurated and denitrated activated coke and preparation method thereof
CN103911168A (en) * 2014-04-09 2014-07-09 江苏河海科技工程集团有限公司 Integral rapid carbonizing treatment technology for municipal waste
CN106192504A (en) * 2016-07-05 2016-12-07 上海勤琨信息科技有限公司 A kind of paper oleo stock reverse mould shaping equipment
CN106672967A (en) * 2016-12-28 2017-05-17 神华集团有限责任公司 Preparation method for activated carbon for desulfurization and denitrification and activated carbon for desulfurization and denitrification and application
CN208036746U (en) * 2018-04-12 2018-11-02 江苏高生生物饲料有限公司 A kind of yeast product automatic packaging line
CN112275207A (en) * 2020-11-22 2021-01-29 禹州市金品建材有限公司 Raw material stirring device for production of building waste pressed brick and use method thereof

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