CN114274502A - The method of using 3D printing technology to quickly prepare master mold and remake glass fiber reinforced plastic mold - Google Patents

The method of using 3D printing technology to quickly prepare master mold and remake glass fiber reinforced plastic mold Download PDF

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CN114274502A
CN114274502A CN202111623793.9A CN202111623793A CN114274502A CN 114274502 A CN114274502 A CN 114274502A CN 202111623793 A CN202111623793 A CN 202111623793A CN 114274502 A CN114274502 A CN 114274502A
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fiber reinforced
mold
resin
glass fiber
die
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杨文元
张鑫
聂祥樊
杨大祥
王强
邓方行
蔺诗韵
李玉福
成莹
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Chongqing Jiaotong University
Air Force Engineering University of PLA
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Abstract

本发明公开了一种利用3D打印技术快速制备母模及翻制玻璃钢模具的方法,包括母模的制备:利用三维建模软件设计母模模型图纸并进行模型切片,将切片后的3D模型图纸以短切纤维增强树脂为原料利用3D设备打印出树脂模具;翻制玻璃钢模具:在母模表面喷涂胶衣,固化后抛光打磨,然后以母模为模板逐层铺设被模具树脂浸润的连续玻璃纤维布,然后加热固化模具;采用短切纤维增强3D打印树脂材料为母模材料解决材料尺寸稳定性差的问题,结合3D打印快速成型技术解决模具传统成型工艺复杂、周期长的问题。The invention discloses a method for quickly preparing a master mold and reproducing a glass fiber reinforced plastic mold by using 3D printing technology, including the preparation of the master mold: using three-dimensional modeling software to design a master mold model drawing and slicing the model, and slice the 3D model drawing. Use chopped fiber reinforced resin as raw material to print resin mold with 3D equipment; remake FRP mold: spray gel coat on the surface of master mold, polish and polish after curing, and then use master mold as template to lay continuous glass infiltrated with mold resin layer by layer Fiber cloth, and then heat to solidify the mold; use chopped fiber reinforced 3D printing resin material as the master mold material to solve the problem of poor dimensional stability of the material, and combine 3D printing rapid prototyping technology to solve the traditional molding process of the mold. Complex and long cycle problems.

Description

利用3D打印技术快速制备母模及翻制玻璃钢模具的方法The method of using 3D printing technology to quickly prepare master mold and remake glass fiber reinforced plastic mold

技术领域technical field

本发明涉及模具加工领域,具体涉及一种利用3D打印技术快速制备母模及翻制玻璃钢模具的方法。The invention relates to the field of mold processing, in particular to a method for rapidly preparing a master mold and remaking a glass fiber reinforced plastic mold by using a 3D printing technology.

背景技术Background technique

3D打印技术的基本原理是数字光源以面光的形式在液态光敏树脂表面进行层层投影,层层固化成型,该技术具有打印成型速度快、精度高、材料利用率高等优点;短切纤维增强树脂材料是以短切纤维为增强体增加传统3D打印树脂的高性能、高尺寸稳定性树脂材料。专利CN113320073A《一种3D打印制造发泡模具腔体使用化学发泡剂的航模成型制造方法》中,制备模具所用材料为传统3D打印树脂,该材料制备的制件长时间使用存在相对较大模具形变风险,而且该专利是直接利用3D打印技术打印模具,并非打印母模和翻制可长期使用的玻璃钢模具;专利CN109135152A《一种玻璃钢吸塑模具的制作方法》中,母模是先石膏粉混合物制作石膏板,经激光雕刻成母模,再手糊成型玻璃钢模具,该方法制备模具工艺复杂、周期长。The basic principle of 3D printing technology is that the digital light source projects layer by layer on the surface of the liquid photosensitive resin in the form of surface light, and solidifies layer by layer. This technology has the advantages of fast printing speed, high precision, and high material utilization; chopped fiber reinforced The resin material is a high-performance, high-dimensionally stable resin material that uses chopped fibers as reinforcement to add traditional 3D printing resins. In the patent CN113320073A "A 3D Printing Manufacturing Method for Manufacture of Foamed Mould Cavity Using Chemical Foaming Agent", the material used for preparing the mould is traditional 3D printing resin, and the parts prepared from this material have relatively large moulds when used for a long time. There is a risk of deformation, and the patent is to directly use 3D printing technology to print molds, not to print master molds and remake FRP molds that can be used for a long time. The mixture is used to make gypsum board, which is engraved into a master mold by laser, and then hand-laid to form a glass fiber reinforced plastic mold.

发明内容SUMMARY OF THE INVENTION

有鉴于此,本发明的目的在于提供一种利用3D打印技术快速制备母模及翻制玻璃钢模具的方法,采用短切纤维增强3D打印树脂材料为母模材料解决材料尺寸稳定性差的问题,结合3D打印快速成型技术解决模具传统成型工艺复杂、周期长的问题。In view of this, the purpose of the present invention is to provide a method for quickly preparing a master mold and remaking a glass fiber reinforced plastic mold by using 3D printing technology, using chopped fiber reinforced 3D printing resin material as the master mold material to solve the problem of poor material dimensional stability, combined with 3D printing rapid prototyping technology solves the problems of complex traditional molding process and long cycle.

本发明的利用3D打印技术快速制备母模及翻制玻璃钢模具的方法,包括以下步骤:The method for rapidly preparing a master mold and remaking a glass fiber reinforced plastic mold by utilizing the 3D printing technology of the present invention comprises the following steps:

a.母模的制备:利用三维建模软件设计母模模型图纸并进行模型切片,将切片后的3D模型图纸以短切纤维增强树脂为原料利用3D设备打印出树脂模具;a. Preparation of master mold: use 3D modeling software to design master mold model drawings and slice the model, and use chopped fiber reinforced resin as raw material to print the resin mold with 3D equipment after the sliced 3D model drawings;

b.翻制玻璃钢模具:在母模表面喷涂胶衣,固化后抛光打磨,然后以母模为模板逐层铺设被模具树脂浸润的连续玻璃纤维布,然后加热固化模具;b. Remaking the glass fiber reinforced plastic mold: spray gel coat on the surface of the master mold, polish and polish after curing, and then use the master mold as a template to lay continuous glass fiber cloth infiltrated with mold resin layer by layer, and then heat and cure the mold;

进一步,步骤a中,打印层厚0.02-0.15mm,打印速度1-120cm/h;Further, in step a, the printing layer thickness is 0.02-0.15mm, and the printing speed is 1-120cm/h;

进一步,步骤a中,所述短切纤维增强树脂为玻璃纤维增强树脂、碳纤维增强树脂、玄武岩纤维增强树脂、芳纶纤维增强树脂中的一种或两种以上混合物;Further, in step a, the chopped fiber reinforced resin is one or more mixtures of glass fiber reinforced resin, carbon fiber reinforced resin, basalt fiber reinforced resin, and aramid fiber reinforced resin;

进一步,步骤a中,所述的三维建模软件包括CATIA、UG、Solidworks、PRO/E、3D Max中的一种或几种,所述3D打印设备包含DLP、SLS、SLA、FDM中的一种或几种;Further, in step a, the three-dimensional modeling software includes one or more of CATIA, UG, Solidworks, PRO/E, and 3D Max, and the 3D printing device includes one or more of DLP, SLS, SLA, and FDM. species or several;

进一步,步骤a中,对于尺寸超过3D打印设备的单次打印范围的母模模型,可以对其进行模块化拆分,待打印完全后使用机械连接或者胶粘结粘接;Further, in step a, for the master mold model whose size exceeds the single printing range of the 3D printing equipment, it can be divided into modules, and after the printing is completed, mechanical connection or adhesive bonding is used;

进一步,步骤b中,所述连续玻璃纤维布的规格为150g/㎡、450g/㎡、600g/㎡、1200g/㎡、1250g/㎡中的至少一种;Further, in step b, the specification of the continuous glass fiber cloth is at least one of 150g/㎡, 450g/㎡, 600g/㎡, 1200g/㎡, and 1250g/㎡;

进一步,步骤b中,所述模具树脂为环氧模具树脂、酚醛模具树脂、乙烯基模具树脂、不饱和模具树脂、零收缩模具树脂中的一种或两种以上混合物。Further, in step b, the mold resin is one or more mixtures of epoxy mold resin, phenolic mold resin, vinyl mold resin, unsaturated mold resin, and zero-shrinkage mold resin.

本发明的有益效果:本发明的利用3D打印技术快速制备母模及翻制玻璃钢模具的方法,使用该方法制备的玻璃钢模具具有工艺步骤简单、材料尺寸稳定性高不易变形、满足批量生产的特点。其中,采用短切纤维增强树脂作为打印的母模原材料,相对传统3D打印树脂具有力学性能更高、产品尺寸稳定性高好的优点;而且母模使用的原材料尺寸稳定行越高,后续制备的玻璃钢模具一致性越好。将模型图纸通过3D打印技术打印成型母模,相比传统减少了大尺寸物料准备和激光雕刻等工序,工艺流程更简单,工序耗时更少,效率更高。Beneficial effects of the present invention: the present invention uses 3D printing technology to rapidly prepare master molds and remake FRP molds, and the FRP molds prepared by using the method have the characteristics of simple process steps, high dimensional stability of materials, not easy to deform, and satisfying mass production. . Among them, the use of chopped fiber reinforced resin as the raw material for printing the master mold has the advantages of higher mechanical properties and higher product dimensional stability than traditional 3D printing resins; and the higher the dimensional stability of the raw materials used in the master mold, the subsequent preparation The consistency of the FRP mold is better. The model drawings are printed with 3D printing technology to form the master mold, which reduces the preparation of large-size materials and laser engraving compared with the traditional process. The process is simpler, the process is less time-consuming, and the efficiency is higher.

具体实施方式Detailed ways

为更好的理解本发明,下面的实施例是对本发明的进一步说明,但本发明的内容不仅仅局限于下面的实施例。For better understanding of the present invention, the following examples are further descriptions of the present invention, but the content of the present invention is not limited to the following examples.

实施例中,所使用的实验方法如无特殊说明,均为常规方法,所用的材料、试剂等,如无特殊说明,均可从商业途径得到。In the examples, the experimental methods used are conventional methods unless otherwise specified, and the materials, reagents, etc. used can be obtained from commercial sources unless otherwise specified.

本发明材料的力学性能测试的标准如下:The standard of the mechanical property test of the material of the present invention is as follows:

拉伸性能和断裂延伸率的测试标准:GB/T 1447-2005《纤维增强塑料拉伸性能试验方法》Test standard for tensile properties and elongation at break: GB/T 1447-2005 "Test methods for tensile properties of fiber-reinforced plastics"

样件尺寸稳定性测试方法:将标准拉伸试样样条在室温环境放置30天,然后使用游标卡尺测试试样投影长度和投影宽度;Test method for dimensional stability of the sample: place the standard tensile sample bar at room temperature for 30 days, and then use a vernier caliper to test the projected length and projected width of the sample;

为了体现出本发明的优势,重点对比使用短切纤维增强树脂与常规树脂打印标准拉伸样条进行对比(控制打印设备和四周环境相同);对比本发明和传统方法制备玻璃钢模具的工艺流程。每个实施实例都有对比试验,在本发明中称为实施例。In order to demonstrate the advantages of the present invention, it is important to compare the use of chopped fiber reinforced resin and conventional resin to print standard tensile splines (the control printing equipment and surrounding environment are the same); Each example has a comparative test, which is referred to as an example in the present invention.

实施例一Example 1

本实施例的3D打印技术快速制备母模及翻制玻璃钢模具的方法,包括以下步骤:The 3D printing technology of this embodiment quickly prepares a master mold and a method for remaking a FRP mold, including the following steps:

a.模型打印:将尺寸为50cm×50cm母模模型图纸进行切片切片,层厚为0.025mm,将切片后的3D模型图纸导入,设备打印层厚为0.025mm,选用短切玻璃纤维增强树脂作为母模材料,开始打印,然后进行清理,确认模具的最终形状。a. Model printing: Slice and slice the master mold model drawings with a size of 50cm×50cm, with a layer thickness of 0.025mm, import the sliced 3D model drawings, and the equipment printing layer thickness is 0.025mm, using chopped glass fiber reinforced resin as the Master mold material, start printing, then clean up to confirm the final shape of the mold.

b.翻制玻璃钢模具:在母模表面喷涂模具胶衣树脂,树脂类型为乙烯基胶衣树脂,喷涂厚度为0.5mm;模具胶衣初步凝固后,逐层铺设玻璃纤维织物,规格包括150g/㎡、450g/㎡、600g/㎡、1200g/㎡、1250g/㎡,同时要用铁辊赶平织物,排走气泡,使胶均匀,达到指定厚度后,铺层结束;加热固化模具,最后使用高压气或者人工起模,获得玻璃钢模具。b. Remaking the FRP mold: spray the mold gel coat resin on the surface of the master mold, the resin type is vinyl gel coat resin, and the spray thickness is 0.5mm; after the mold gel coat is initially solidified, lay glass fiber fabric layer by layer, the specifications include 150g/ ㎡, 450g/㎡, 600g/㎡, 1200g/㎡, 1250g/㎡, at the same time, iron rollers should be used to flatten the fabric to remove air bubbles to make the glue uniform. After reaching the specified thickness, the layering is completed; the mold is heated and cured, and finally used High-pressure air or manual mold removal to obtain FRP molds.

利用短切玻璃纤维增强树脂打印标准拉伸试样,测试力学性能和尺寸稳定性。Standard tensile specimens were printed using chopped glass fiber reinforced resin to test mechanical properties and dimensional stability.

对比例1:使用传统工艺制备玻璃钢模具Comparative Example 1: Preparation of FRP Mould Using Traditional Process

1、制备石膏板:使用木材或硅胶订制一个矩形框,然后向框内倒入石膏粉混合物制作石膏板,静置待其固化。1. Preparation of gypsum board: Use wood or silicone to order a rectangular frame, then pour the gypsum powder mixture into the frame to make gypsum board, and let it sit for curing.

2、母模粗修:将图纸导入车床对石膏板进行雕刻,这一过程主要是对母模整体做基本的处理,以保证木模在尺寸及形式上与图纸相吻合。2. Rough repair of the master mold: import the drawings into the lathe to carve the gypsum board. This process is mainly to do the basic treatment of the master mold as a whole to ensure that the size and form of the wooden mold are consistent with the drawings.

3、母模表面精修:这一过程主要是对母模整体做表面精细处理,主要有整体打磨、抛光、打脱模蜡等。3. Refining the surface of the master mold: This process is mainly to do fine surface treatment of the master mold as a whole, mainly including overall grinding, polishing, and demoulding wax.

4、翻制玻璃钢模具:在母模表面喷涂模具胶衣树脂,树脂类型为乙烯基胶衣树脂,喷涂厚度为0.5mm;模具胶衣初步凝固后,逐层铺设玻璃纤维织物,规格包括150g/㎡、450g/㎡、600g/㎡、1200g/㎡、1250g/㎡,同时要用铁辊赶平织物,排走气泡,使胶均匀,达到指定厚度后,铺层结束;加热固化模具。4. Remaking the glass fiber reinforced plastic mold: spray the mold gel coat resin on the surface of the master mold, the resin type is vinyl gel coat resin, and the spray thickness is 0.5mm; ㎡, 450g/㎡, 600g/㎡, 1200g/㎡, 1250g/㎡, at the same time, iron rollers should be used to flatten the fabric, remove air bubbles, and make the glue uniform. After reaching the specified thickness, the layering is completed; the mold is heated and cured.

5、玻璃钢模具脱模:使用高压气或者人工起模,获得玻璃钢模具。5. FRP mold demoulding: use high-pressure gas or artificial mold to obtain FRP mold.

利用传统树脂(无短切纤维增强)打印标准拉伸试样,测试力学性能和尺寸稳定性。Standard tensile specimens were printed using conventional resins (without chopped fiber reinforcement) and tested for mechanical properties and dimensional stability.

表1实施例1与对比例1的工艺步骤对比情况Table 1 Embodiment 1 and comparative example 1 process steps comparison situation

Figure BDA0003438362660000041
Figure BDA0003438362660000041

由实施例1和对比例1的对比情况来看,按本发明所述,可利用3D打印技术制备母模并翻制玻璃钢模具,而且翻制玻璃钢模具的工艺步骤相比传统更少、工艺流程相对简单、效率更高。Judging from the comparison between Example 1 and Comparative Example 1, according to the present invention, the master mold can be prepared by 3D printing technology and the FRP mold can be remade, and the process steps of remaking the FRP mold are fewer than the traditional ones, and the process flow is less. Relatively simple and more efficient.

表2实施例1与对比例1的性能对比情况Table 2 Performance comparison of embodiment 1 and comparative example 1

Figure BDA0003438362660000042
Figure BDA0003438362660000042

Figure BDA0003438362660000051
Figure BDA0003438362660000051

由实施例2和对比例2的对比来看,按本发明所述,利用短切纤维增强树脂材料结合3D打印技术实现打印制件的尺寸稳定性更好。From the comparison of Example 2 and Comparative Example 2, according to the present invention, the use of chopped fiber reinforced resin material combined with 3D printing technology to achieve better dimensional stability of printed parts.

最后说明的是,以上实施例仅用以说明本发明的技术方案而非限制,尽管参照较佳实施例对本发明进行了详细说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的宗旨和范围,其均应涵盖在本发明的权利要求范围当中。Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention and not to limit them. Although the present invention has been described in detail with reference to the preferred embodiments, those of ordinary skill in the art should understand that the technical solutions of the present invention can be Modifications or equivalent substitutions without departing from the spirit and scope of the technical solutions of the present invention should be included in the scope of the claims of the present invention.

Claims (7)

1. A method for rapidly preparing a female die and duplicating a glass fiber reinforced plastic die by using a 3D printing technology is characterized by comprising the following steps of: the method comprises the following steps:
a. preparing a female die: designing a female die model drawing by using three-dimensional modeling software, carrying out model slicing, and printing a sliced 3D model drawing into a resin die by using 3D equipment by using chopped fiber reinforced resin as a raw material;
b. copying a glass fiber reinforced plastic mold: and spraying gel coat on the surface of the female die, polishing and grinding after curing, then paving continuous glass fiber cloth soaked by the resin of the die layer by taking the female die as a template, and then heating and curing the die.
2. The method for rapidly preparing the female die and reproducing the glass fiber reinforced plastic die by using the 3D printing technology as claimed in claim 1, wherein: in the step a, the thickness of the printing layer is 0.02-0.15 mm.
3. The method for rapidly preparing the female die and reproducing the glass fiber reinforced plastic die by using the 3D printing technology as claimed in claim 2, wherein: in the step a, the chopped fiber reinforced resin is one or a mixture of more than two of glass fiber reinforced resin, carbon fiber reinforced resin, basalt fiber reinforced resin and aramid fiber reinforced resin.
4. The method for rapidly preparing the female die and reproducing the glass fiber reinforced plastic die by using the 3D printing technology as claimed in claim 3, wherein: in the step a, the three-dimensional modeling software comprises one or more of CATIA, UG, Solidworks, PRO/E and 3D Max, and the 3D printing equipment comprises one or more of DLP, SLS, SLA and FDM.
5. The method for rapidly preparing the female die and reproducing the glass fiber reinforced plastic die by using the 3D printing technology as claimed in claim 4, wherein the method comprises the following steps: in the step a, a female die model with the size exceeding the single printing range of the 3D printing equipment can be split in a modularized mode, and after the female die model is completely printed, mechanical connection or adhesive bonding is used.
6. The method for rapidly preparing the female die and reproducing the glass fiber reinforced plastic die by using the 3D printing technology as claimed in claim 1, wherein: in the step b, the continuous glass fiber cloth has at least one specification of 150 g/square meter, 450 g/square meter, 600 g/square meter, 1200 g/square meter and 1250 g/square meter.
7. The method for rapidly preparing the female die and reproducing the glass fiber reinforced plastic die by using the 3D printing technology as claimed in claim 6, wherein: in the step b, the mold resin is one or a mixture of more than two of epoxy mold resin, phenolic mold resin, vinyl mold resin, unsaturated mold resin and zero shrinkage mold resin.
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CN105666750A (en) * 2016-03-17 2016-06-15 路文虎 Preparation process and casting mould for cast product based on 3D printing technology
CN111361172A (en) * 2020-03-11 2020-07-03 东风柳州汽车有限公司 Hand-pasted glass fiber reinforced plastic punching device and manufacturing method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105666750A (en) * 2016-03-17 2016-06-15 路文虎 Preparation process and casting mould for cast product based on 3D printing technology
CN111361172A (en) * 2020-03-11 2020-07-03 东风柳州汽车有限公司 Hand-pasted glass fiber reinforced plastic punching device and manufacturing method thereof

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