CN114261221A - Thermal sublimation color band for printing reflective mark, preparation method and reflective mark - Google Patents
Thermal sublimation color band for printing reflective mark, preparation method and reflective mark Download PDFInfo
- Publication number
- CN114261221A CN114261221A CN202111517064.5A CN202111517064A CN114261221A CN 114261221 A CN114261221 A CN 114261221A CN 202111517064 A CN202111517064 A CN 202111517064A CN 114261221 A CN114261221 A CN 114261221A
- Authority
- CN
- China
- Prior art keywords
- printing
- coating
- reflective
- resin
- ribbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000859 sublimation Methods 0.000 title claims abstract description 60
- 230000008022 sublimation Effects 0.000 title claims abstract description 59
- 238000007639 printing Methods 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title abstract description 14
- 239000000975 dye Substances 0.000 claims abstract description 61
- 239000011347 resin Substances 0.000 claims abstract description 54
- 229920005989 resin Polymers 0.000 claims abstract description 54
- 239000011248 coating agent Substances 0.000 claims abstract description 52
- 238000000576 coating method Methods 0.000 claims abstract description 52
- 239000011521 glass Substances 0.000 claims abstract description 49
- 239000011324 bead Substances 0.000 claims abstract description 48
- 239000000758 substrate Substances 0.000 claims abstract description 7
- 239000010410 layer Substances 0.000 claims description 56
- 239000000463 material Substances 0.000 claims description 19
- 238000001035 drying Methods 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000002270 dispersing agent Substances 0.000 claims description 10
- 239000011247 coating layer Substances 0.000 claims description 9
- 239000003960 organic solvent Substances 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000004962 Polyamide-imide Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 239000003208 petroleum Substances 0.000 claims description 5
- 229920002312 polyamide-imide Polymers 0.000 claims description 5
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 5
- 238000005299 abrasion Methods 0.000 claims description 4
- 239000002562 thickening agent Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims 2
- 239000004005 microsphere Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 28
- 230000032683 aging Effects 0.000 abstract description 11
- 238000012360 testing method Methods 0.000 description 34
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 5
- 239000012752 auxiliary agent Substances 0.000 description 5
- 230000009286 beneficial effect Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000002216 antistatic agent Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 230000001795 light effect Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 238000007774 anilox coating Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Images
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
The invention relates to the technical field of printing, in particular to a thermal sublimation color band for printing a reflective mark, a preparation method and the reflective mark. The ribbon comprises a substrate, a back coating and a bottom coating which are arranged on two sides of the substrate, wherein the bottom coating is provided with a dye layer; the dye layer comprises glass beads, resin and dye, wherein the mass of the glass beads is 3-11% of that of the resin. The thermal sublimation ribbon for printing the reflective mark has the advantages that the printed light emitting mark has good reflective effect, the printed patterns have small color difference and high color density, the printed colorful patterns have high quality, and the thermal sublimation ribbon can be widely used for printing reflective marks of various types and patterns. In addition, the reflective mark printed by the thermal sublimation color band also has good ultraviolet aging resistance, so that the reflective mark printed by the thermal sublimation color band has long service life and wider application scene, and can be widely used for printing outdoor reflective marks.
Description
Technical Field
The invention relates to the technical field of printing, in particular to a thermal sublimation color band for printing a reflective mark, a preparation method and the reflective mark.
Background
Thermal sublimation ribbons are often used for highly demanding photographic printing due to their excellent true color rendering and ultra-high color resolution. However, due to poor weather resistance and poor light reflection capability of thermal sublimation, the thermal sublimation printing method is generally difficult to be used for printing outdoor signs or reflective signs.
The resin carbon ribbon is widely applied, can be printed on various materials such as PVC, PET, high-temperature label paper, copper paper and the like, and simultaneously has the advantages of good temperature resistance, wear resistance, corrosion resistance, light reflection and the like, so that the resin carbon ribbon can be used for printing outdoor light-reflecting marks. However, the resin thermal transfer ribbon is in a full transfer mode, and cannot print true colors, so that the resin thermal transfer ribbon cannot be applied to a marking scene needing color printing.
Disclosure of Invention
The invention aims to provide a thermal sublimation color band for printing a reflective mark, a preparation method and the reflective mark.
The technical scheme for solving the technical problems is as follows:
the invention provides a thermal sublimation ribbon for printing a reflective mark, which comprises a base material, and a back coating and a bottom coating which are arranged on two sides of the base material, wherein a dye layer is arranged on the bottom coating; the dye layer comprises glass beads, resin and dye, wherein the mass of the glass beads is 3-10% of that of the resin.
The invention has the beneficial effects that the glass beads in the mass range are added, so that the reflective mark printed by the thermal sublimation color band has good reflective effect; if the amount of the glass beads added is less than 3% by mass of the resin, poor light reflecting effect will result, and if it exceeds 11%, poor quality of the printed pattern will result.
The invention can be implemented by the following further technical scheme:
further, the mass of the glass beads is 5% of the mass of the resin.
The further technical scheme has the advantages that the printed reflective mark has the best reflective effect due to the addition of the glass beads with the content, and meanwhile, the printed pattern has small color difference and high pattern quality.
Further, the average particle size range of the glass beads is 5-15 μm.
The further technical scheme has the beneficial effects that the glass beads with the average grain size are added, and have the characteristics of good dispersibility, good light reflection and stability under the condition that the thickness of the dye layer is fixed.
Further, the components of the dye layer also comprise an anti-UV agent.
The beneficial effect of adopting the further technical scheme is that the reflective mark has good ultraviolet aging resistance.
Further, the dye layer comprises, by mass, 0.6-2.2 parts of glass beads, 6-10 parts of petroleum resin, 10-14 parts of EVA resin, 18-22 parts of dye, 1-3 parts of a dispersing agent, 0.5-1.5 parts of a thickening agent and 0.5-1.5 parts of an anti-UV agent.
The further technical scheme has the advantages that in order to ensure that the color ribbon has good chromaticity and printing effect during printing, the components of the dye layer and the content of the dye are required to be appropriate; the reflection mark printed by the hot ornamental flower ribbon with the formula has the best printing effect and reflection effect through testing; if the amount of the auxiliary agents such as resin or dispersing agent is too much relative to the amount of the dye, the color is diluted, the visual effect of the printed reflective mark is poor, and even the reflective effect is influenced; on the other hand, if the amount of the auxiliary agent such as a resin or a dispersant is too small relative to the amount of the dye, the dye layer does not adhere well to the undercoat layer 3, and the quality of the thermal biochemical ribbon is poor, and the printing effect is still impaired.
Furthermore, the thickness of the back coating is 0.5-1.2 μm, the thickness of the base material is 4-10 μm, the thickness of the bottom coating is 0.2-0.7 μm, and the thickness of the dye layer is 0.7-1.5 μm.
The technical scheme has the advantages that the overall thickness and the thickness of each layer of the thermal sublimation carbon ribbon have important influence on the quality and the printing effect of the color ribbon; if the dye layer is too thin, the printed pattern may be incomplete, and if the dye layer is too thick, problems such as too long drying time and uneven drying of the dye layer during the manufacturing process may be caused, and the manufacturing efficiency may be reduced. Through tests, the thermal sublimation color band with the thickness of each layer has the best printing effect, and meanwhile, the preparation process is easy to operate and high in preparation efficiency.
Further, the back coating is a wear-resistant heat transfer coating, and the components of the wear-resistant heat transfer coating comprise polyamide-imide resin, zinc stearate and silica particles.
The beneficial effect of adopting the further technical scheme is that the components can ensure that the back coating has good wear resistance.
Further, the components of the primer layer include a resin.
The invention provides a preparation method of the thermal sublimation color band, which comprises the following steps:
1) preparing solutions of the back coating layer, the base coating layer and the dye layer by using organic solvents respectively;
2) applying corona to two sides of the base material, coating a back coating solution on one side of the base material, and drying to remove an organic solvent, wherein the drying temperature is 60-120 ℃; after the solution of the back coating is dried, coating the solution of the bottom coating on the other side of the base material and drying to remove the organic solvent, wherein the drying temperature is 60-120 ℃; and after the solution of the bottom coating is dried, coating the solution of the dye layer on the bottom coating, and drying to remove the organic solvent, wherein the drying temperature is 90-150 ℃.
The invention provides a reflective mark, which is printed by the thermal sublimation ribbon.
Drawings
FIG. 1 is a schematic view of a thermal vaporization ribbon of the present invention;
FIG. 2 is a color gamut diagram for a color difference test of a full tone map printed by a thermalation ribbon of the present invention, wherein the positive y-axis side is a yellow region, the negative x-axis side is a cyan region, and the positive x-axis side is a red region;
FIG. 3 is a color density test curve for a yellow tint in a full tint chart printed with a thermalizing tape of the present invention;
FIG. 4 is a color density test curve for a red color tone in a full tone map printed with a thermalizing ribbon of the present invention;
FIG. 5 is a color density test curve for a cyan color tone in a full tone map printed with a thermalizable ribbon of the present invention.
In the drawings, the components represented by the respective reference numerals are listed below:
1. back coating, 2, substrate, 3, bottom coating, 4 and dye layer.
Detailed Description
The principles and features of this invention are described below in conjunction with the following drawings, which are set forth by way of illustration only and are not intended to limit the scope of the invention.
The thermal sublimation ribbon for printing the reflective mark comprises a base material 2, and a back coating layer 1 and a bottom coating layer 3 which are arranged on two sides of the base material 2, wherein a dye layer 4 is arranged on the bottom coating layer 3; the dye layer 4 comprises glass beads, resin and dye, wherein the mass of the glass beads is 3-11% of that of the resin; the glass beads in the mass range are added, so that the reflective mark printed by the thermal sublimation color band has a good reflective effect; if the amount of the glass beads added is less than 3% by mass of the resin, poor light reflecting effect will result, and if it exceeds 11%, poor quality of the printed pattern will result.
Preferably, the mass of the glass beads is 5% of the mass of the resin, and the average particle size (D50) of the glass beads is 5-15 μm; the glass beads with the addition amount can enable the printed reflective mark to have a good reflective effect.
Preferably, the components of the dye layer 4 further comprise an anti-UV agent; the addition of the anti-UV agent can enable the reflective mark to have good ultraviolet aging resistance.
Preferably, the dye layer 4 comprises, by mass, 0.6-2.2 parts of glass beads, 6-10 parts of petroleum resin, 10-14 parts of EVA resin, 18-22 parts of dye, 1-3 parts of a dispersant, 0.5-1.5 parts of a thickener and 0.5-1.5 parts of an anti-UV agent; in order to ensure that the color ribbon has good chromaticity and printing effect during printing, the components of the dye layer 4 and the content of the dye need to be proper; the reflection mark printed by the hot ornamental flower ribbon with the formula has the best printing effect and reflection effect through testing; if the amount of the auxiliary agents such as resin or dispersing agent is too much relative to the amount of the dye, the color is diluted, the visual effect of the printed reflective mark is poor, and even the reflective effect is influenced; on the other hand, if the amount of the auxiliary agent such as a resin or a dispersant is too small relative to the amount of the dye, the dye layer 4 may not be satisfactorily attached to the undercoat layer 3, and the quality of the thermal biochemical ribbon may be poor, and the printing effect may be still impaired.
Preferably, the thickness of the back coating 1 is 0.5-1.2 μm, the thickness of the substrate 2 is 4-10 μm, the thickness of the bottom coating 3 is 0.2-0.7 μm, and the thickness of the dye layer 4 is 0.7-1.5 μm; the overall thickness and each layer thickness of the thermal sublimation carbon ribbon also have important influence on the quality and the printing effect of the color ribbon; if the dye layer 4 is too thin, the printed pattern may be incomplete, and if the dye layer 4 is too thick, problems such as too long drying time and uneven drying of the dye layer 4 during the manufacturing process may be caused, and the manufacturing efficiency may be reduced. Through tests, the thermal sublimation color band with the thickness of each layer has the best printing effect, and meanwhile, the preparation process is easy to operate and high in preparation efficiency.
Preferably, the back coating 1 is an abrasion-resistant heat transfer coating, and the abrasion-resistant heat transfer coating comprises polyamide-imide resin, zinc stearate and silica particles; by adding the components, the back coating 1 has good wear resistance and heat transfer and anti-friction performance.
Preferably, the components of the primer layer 3 include resin, 2-butanone, and toluene.
The preparation method of the thermal sublimation carbon ribbon comprises the following steps:
1) respectively preparing each coating solution;
the preparation method of the back coating 1 comprises the steps of dissolving the polyamideimide resin with 2-butanone and toluene, adding zinc stearate and silicon dioxide particles, dispersing the silicon dioxide particles in the solution, adding the leveling agent, the dispersing agent and the antistatic agent, and mixing to obtain the solution of the back coating 1.
The solution of the undercoat layer 3 is prepared by dissolving petroleum resin and EVA resin in 2-butanone and toluene, and mixing and stirring them uniformly to obtain a solution of the undercoat layer 3.
The preparation method of the solution of the dye layer 4 comprises the steps of dissolving petroleum resin and EVA resin with 2-butanone and toluene, adding 1.0-10 wt% of single dye or multiple dyes in single color of thermal sublimation dye, mixing, adding 3-10% of glass beads in resin content, adding a dispersing agent, a thickening agent and an anti-UV agent, and uniformly mixing to prepare the dye layer coating.
2) Preparing a thermal sublimation carbon ribbon:
corona is applied to the two sides of the base material 2, and the solution of the back coating layer 1 is coated on one side of the base material 2 and dried, wherein the drying temperature is 60-120 ℃.
After the solution of the back coating layer 1 is dried, the solution of the bottom coating layer 3 is coated on the other side of the base material 2 and dried, and the drying temperature is 60-120 ℃.
After the solution of the base coat layer 3 is dried, the solution of the dye layer 4 is coated on the base coat layer 3 and dried, and the drying temperature is 90-150 ℃.
The coating of each layer adopts a ceramic anilox roller with 100-200 lines and a gravure coater for coating.
The reflective mark is obtained by printing the thermal sublimation color band; the reflective mark has good reflective effect, good ultraviolet aging resistance effect and wide application range.
The effect of the thermal sublimation ribbon for printing the reflective mark of the invention is specifically described by the thermal sublimation ribbon of the embodiments 1 to 27 and various tests as follows:
when preparing the thermal sublimation ribbon, the solution of the back coating 1, the solution of the bottom coating 3 and the solution of the dye layer 4 are prepared respectively.
In examples 1 to 27, the solution components and the parts by mass of each component of the back coat layer 1 were 2-butanone 100 parts, toluene 100 parts, polyamideimide resin 5 parts, EVA resin 5 parts, zinc stearate 2 parts, leveling agent 0.5 part, dispersant 0.5 part, and antistatic agent 0.5 part.
In examples 1 to 27, the substrate 2 was a PET substrate.
In examples 1 to 27, the solution components and the parts by mass of each component of the undercoat layer 3 are shown in table 1:
TABLE 1
In examples 1 to 27, the components of the solution of the dye layer 4 and the parts by mass of each component are shown in table 2:
TABLE 2
In conversion, in example 1/10/19, the mass of the glass beads accounted for 3% of the total resin, in example 2/11/2, the mass of the glass beads accounted for 4% of the total resin, in example 3/12/21, the mass of the glass beads accounted for 5% of the total resin, in example 4/13/22, the mass of the glass beads accounted for 6% of the total resin, in example 5/14/23, the mass of the glass beads accounted for 7% of the total resin, in example 6/15/24, the mass of the glass beads accounted for 8% of the total resin, in example 7/16/25, the mass of the glass beads accounted for 9% of the total resin, in example 8/17/26, the mass of the glass beads accounted for 10% of the total resin, in example 9/18/27, the mass of the glass beads accounts for 11 percent of the total mass of the resin.
The dye layer 4 was tested for color difference and color density for two sublimation ribbons with no and 5% by weight (5phr) of resin added and not added, respectively.
The thermal sublimation color bands of the embodiments 1 to 27 are respectively prepared by the preparation method of the thermal sublimation color band for printing the reflective mark.
In the test, an Alice I1 color difference instrument is used for carrying out color difference test and color density test on full color tone diagrams printed by the thermal sublimation color bands with or without glass beads, the color gamut curve chart of the test is shown in figure 2, and the color density test is shown in figures 3-5.
In fig. 2, the y-axis positive axis side is a yellow region, the x-axis negative axis side is a cyan region, and the x-axis positive axis side is a red region; the color value tests of a plurality of points are respectively carried out on the images printed by the thermal sublimation color bands added with the glass beads and the thermal sublimation color bands not added with the glass beads in the three areas, so that the coincidence degree of the color values of the two images is very high, and the printed image color difference is small compared with the thermal sublimation color bands not added with the glass beads, namely, the images printed by the thermal sublimation color bands added with the glass beads can meet the requirement of good pattern color.
Fig. 3 to 5 are color density curves of yellow (Dy) red (Dm) and cyan (Dc) hues, respectively, and it can be seen from fig. 3 to 5 that the pattern color density of the thermal sublimation ribbon of the present invention is greater in each of the hues than that of the ribbon without glass beads added.
The above tests show that the sublimation ribbon with 5% (5phr) of glass beads added has good printing effect.
And respectively carrying out a light reflection test on the light reflection marks printed by the thermal sublimation carbon ribbons with and without the added glass beads and with dyes of different colors.
And (4) testing standard: GB/T18833 + 2012 road traffic reflective film, test equipment: STT-101A retroreflective marker measuring instrument (HTQC/YQ-TC-031).
The test results are shown in tables 3 and 4:
table 3 test results of dye layer 4 without glass beads
Table 4 test results of adding glass beads to dye layer 4
It can be seen through the test result of table 3 and table 4 that, in the thermal sublimation typewriter ribbon of not adding glass bead, no matter which kind of colour's dyestuff is adopted, the reflection of light effect of its pattern of printing is all ineligible, and after adding glass bead, the pattern that thermal sublimation typewriter ribbon of each colour dyestuff printed all has good reflection of light effect.
detection standard: GB/T16422.3-2014 Plastic laboratory light Source Exposure test method part 3: fluorescent ultraviolet lamp (UV lamp); the detection device comprises: JY-UV-UV1 ultraviolet ray acceleration weather-proof tester (HTQC/YQ-003). The test results are shown in tables 5 and 6:
TABLE 5 UV aging resistance test results without and with addition of UV inhibitor
It can be seen from the test results in table 5 that, in the thermal sublimation ribbon added with the glass beads, no matter which color dye is used, the ultraviolet aging resistance of the thermal sublimation ribbon not added with the anti-UV agent is not qualified, and the ultraviolet aging resistance of the thermal sublimation ribbon added with the anti-UV agent is qualified, which indicates that the thermal sublimation ribbon has better ultraviolet aging resistance after the anti-UV agent is added.
The above test conducted the thermal transfer ribbon only for the addition of 5% by mass of glass beads to the mass of resin. However, the heat band with the mass of other glass beads being between 3 and 10 percent of the mass of the resin has similar effects. Meanwhile, the other thermal transfer printing color bands without different resins and auxiliary agents have the light reflection effect and the ultraviolet aging resistance which are similar to the test results.
In summary, the sublimation ribbon for printing reflective marks of the invention has the advantages that the printed reflective marks have good reflective effect, the printed patterns have small color difference and high color density, the printed color patterns have high quality, and the sublimation ribbon can be widely used for printing reflective marks of various types and patterns. In addition, the reflective mark printed by the thermal sublimation color band also has good ultraviolet aging resistance, so that the reflective mark printed by the thermal sublimation color band has long service life and wider application scene, and can be widely used for printing outdoor reflective marks.
In the description of the present invention, it should be noted that the terms "thickness", "upper", "lower", etc. indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience in describing the present invention and simplifying the description, but do not indicate or imply that the referred device or element must have a specific orientation, be constructed in a specific orientation, and be operated, and thus, should not be construed as limiting the present invention.
In the description herein, references to the description of the term "one embodiment," "some embodiments," "an example," "a specific example," or "some examples," etc., mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above are not necessarily intended to refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Furthermore, various embodiments or examples and features of different embodiments or examples described in this specification can be combined and combined by one skilled in the art without contradiction.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.
Claims (10)
1. A thermal sublimation ribbon for printing a reflective mark comprises a base material (2), and a back coating (1) and a bottom coating (3) which are arranged on two sides of the base material (2), and is characterized in that a dye layer (4) is arranged on the bottom coating (3);
the dye layer (4) comprises glass beads, resin and dye, wherein the mass of the glass beads is 3-11% of that of the resin.
2. The sublimation ribbon for printing retroreflective signs as claimed in claim 1, wherein the glass microspheres are 5% by mass of the resin.
3. The sublimation ribbon for printing the reflective mark according to claim 1, wherein the glass beads have an average particle size ranging from 5 to 15 μm.
4. The dye-sublimation ribbon for printing reflective marks according to claim 1, wherein the composition of the dye layer (4) further comprises a UV-resistant agent.
5. The thermal sublimation ribbon for printing the reflective mark according to claim 4, wherein the dye layer (4) comprises, by mass, 0.6-2.2 parts of glass beads, 6-10 parts of petroleum resin, 10-14 parts of EVA resin, 18-22 parts of dye, 1-3 parts of dispersant, 0.5-1.5 parts of thickener and 0.5-1.5 parts of UV resistant agent.
6. The sublimation ribbon for printing reflective marks according to any one of claims 1 to 5, wherein the thickness of the back coating layer (1) is 0.5 to 1.2 μm, the thickness of the substrate (2) is 4 to 10 μm, the thickness of the primer layer (3) is 0.2 to 0.7 μm, and the thickness of the dye layer (4) is 0.7 to 1.5 μm.
7. The sublimation ribbon for printing the reflective mark according to any one of claims 1 to 5, wherein the back coating (1) is an abrasion-resistant heat transfer coating, and the components of the abrasion-resistant heat transfer coating comprise polyamide-imide resin, zinc stearate and silica particles.
8. The sublimation ribbon for printing retroreflective signs according to any one of claims 1 to 5, wherein the composition of the primer layer (3) includes a resin.
9. A method for producing a thermal sublimation ribbon according to any one of claims 1 to 8, comprising the steps of:
1) preparing solutions of the back coating (1), the base coating (3) and the dye layer (4) with organic solvents respectively;
2) coating corona on two sides of the base material (2), coating a solution of a back coating (1) on one side of the base material (2), and drying to remove an organic solvent, wherein the drying temperature is 60-120 ℃;
after the solution of the back coating (1) is dried, coating the solution of the bottom coating (3) on the other side of the base material (2) and drying to remove the organic solvent, wherein the drying temperature is 60-120 ℃;
after the solution of the bottom coating (3) is dried, the solution of the dye layer (4) is coated on the bottom coating (3) and dried to remove the organic solvent, and the drying temperature is 90-150 ℃.
10. A reflective mark printed from the sublimation ribbon according to any one of claims 1 to 8.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111517064.5A CN114261221B (en) | 2021-12-07 | 2021-12-07 | Thermal sublimation ribbon for printing reflective marks, preparation method and reflective marks |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111517064.5A CN114261221B (en) | 2021-12-07 | 2021-12-07 | Thermal sublimation ribbon for printing reflective marks, preparation method and reflective marks |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114261221A true CN114261221A (en) | 2022-04-01 |
| CN114261221B CN114261221B (en) | 2023-12-19 |
Family
ID=80826807
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111517064.5A Active CN114261221B (en) | 2021-12-07 | 2021-12-07 | Thermal sublimation ribbon for printing reflective marks, preparation method and reflective marks |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114261221B (en) |
Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5114904A (en) * | 1987-07-27 | 1992-05-19 | Toppan Printing Co. | Thermal transfer recording medium and image forming body |
| JPH07219266A (en) * | 1993-12-06 | 1995-08-18 | Xerox Corp | Formation method of picture |
| US5564843A (en) * | 1993-12-17 | 1996-10-15 | Brother Kogyo Kabushiki Kaisha | Reflective print label and method of producing the same |
| WO2000050248A1 (en) * | 1999-02-26 | 2000-08-31 | Imperial Chemical Industries Plc | Improvements in or relating to mass transfer printing |
| JP2000303011A (en) * | 1999-04-22 | 2000-10-31 | Komatsu Process:Kk | Reflective ability printing ink composition and reflective ability article using the same |
| WO2007004751A1 (en) * | 2005-05-04 | 2007-01-11 | Sang-Yun Jung | Colored retro-reflective material for spray printing |
| CN101054077A (en) * | 2001-06-15 | 2007-10-17 | 希尔斯牌照公司 | Identifiaction plates |
| CN101612843A (en) * | 2009-07-23 | 2009-12-30 | 焦作市卓立烫印材料有限公司 | A kind of sublimation banner thermal transfer ribbons (TTR) and preparation method thereof |
| CN201442388U (en) * | 2009-06-16 | 2010-04-28 | 高本强 | Thermosensitive sublimating color strip |
| JP2011062824A (en) * | 2009-09-15 | 2011-03-31 | Toppan Printing Co Ltd | Sublimation type thermal transfer medium |
| CN102616023A (en) * | 2012-03-28 | 2012-08-01 | 焦作市卓立烫印材料有限公司 | Care label thermal transfer ribbon and preparation method thereof |
| CN105315816A (en) * | 2015-11-12 | 2016-02-10 | 合肥安奎思成套设备有限公司 | Corrosion-resistant light-reflecting paint |
| CN210722315U (en) * | 2019-07-11 | 2020-06-09 | 中钢集团武汉安全环保研究院有限公司 | Industrial pipeline reflecting mark belt |
| CN112980266A (en) * | 2019-12-13 | 2021-06-18 | 立邦涂料（中国）有限公司 | Water-based self-luminous reflective rain and night marking coating and preparation method thereof, road marking and construction method thereof |
| CN113444405A (en) * | 2020-03-27 | 2021-09-28 | 湖南鼎一致远科技发展有限公司 | Thermal sublimation color band, back coating liquid for thermal sublimation color band and preparation method of back coating liquid |
| CN113442611A (en) * | 2020-03-27 | 2021-09-28 | 湖南鼎一致远科技发展有限公司 | Thermal transfer ribbon and preparation method thereof |
-
2021
- 2021-12-07 CN CN202111517064.5A patent/CN114261221B/en active Active
Patent Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5114904A (en) * | 1987-07-27 | 1992-05-19 | Toppan Printing Co. | Thermal transfer recording medium and image forming body |
| JPH07219266A (en) * | 1993-12-06 | 1995-08-18 | Xerox Corp | Formation method of picture |
| US5564843A (en) * | 1993-12-17 | 1996-10-15 | Brother Kogyo Kabushiki Kaisha | Reflective print label and method of producing the same |
| WO2000050248A1 (en) * | 1999-02-26 | 2000-08-31 | Imperial Chemical Industries Plc | Improvements in or relating to mass transfer printing |
| JP2000303011A (en) * | 1999-04-22 | 2000-10-31 | Komatsu Process:Kk | Reflective ability printing ink composition and reflective ability article using the same |
| CN101054077A (en) * | 2001-06-15 | 2007-10-17 | 希尔斯牌照公司 | Identifiaction plates |
| WO2007004751A1 (en) * | 2005-05-04 | 2007-01-11 | Sang-Yun Jung | Colored retro-reflective material for spray printing |
| CN201442388U (en) * | 2009-06-16 | 2010-04-28 | 高本强 | Thermosensitive sublimating color strip |
| CN101612843A (en) * | 2009-07-23 | 2009-12-30 | 焦作市卓立烫印材料有限公司 | A kind of sublimation banner thermal transfer ribbons (TTR) and preparation method thereof |
| JP2011062824A (en) * | 2009-09-15 | 2011-03-31 | Toppan Printing Co Ltd | Sublimation type thermal transfer medium |
| CN102616023A (en) * | 2012-03-28 | 2012-08-01 | 焦作市卓立烫印材料有限公司 | Care label thermal transfer ribbon and preparation method thereof |
| CN105315816A (en) * | 2015-11-12 | 2016-02-10 | 合肥安奎思成套设备有限公司 | Corrosion-resistant light-reflecting paint |
| CN210722315U (en) * | 2019-07-11 | 2020-06-09 | 中钢集团武汉安全环保研究院有限公司 | Industrial pipeline reflecting mark belt |
| CN112980266A (en) * | 2019-12-13 | 2021-06-18 | 立邦涂料（中国）有限公司 | Water-based self-luminous reflective rain and night marking coating and preparation method thereof, road marking and construction method thereof |
| CN113444405A (en) * | 2020-03-27 | 2021-09-28 | 湖南鼎一致远科技发展有限公司 | Thermal sublimation color band, back coating liquid for thermal sublimation color band and preparation method of back coating liquid |
| CN113442611A (en) * | 2020-03-27 | 2021-09-28 | 湖南鼎一致远科技发展有限公司 | Thermal transfer ribbon and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN114261221B (en) | 2023-12-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4889560A (en) | Phase change ink composition and phase change ink produced therefrom | |
| EP2425970A1 (en) | Waterproof self-luminescent airbrushing film | |
| CN1466616A (en) | Inks exhibiting expanded color-space characteristics for water-based printing | |
| CN104530832A (en) | Plastic glazing system having a promotion of ink adhesion on the surface thereof | |
| CN113178128A (en) | High-temperature-resistant label for thermal transfer printing and preparation method thereof | |
| CN111662592B (en) | Antistatic flame-retardant thermal transfer printing ink for carbon ribbon and preparation method thereof | |
| CN107207886A (en) | Print the method for polychrome printing pattern | |
| KR19980702078A (en) | Compositions and heat transfer donor elements used to make signal articles | |
| CN107389194B (en) | Color high-fidelity digital imaging system under opening luminous environment based on colour atla | |
| CN114261222B (en) | Carbon ribbon for increasing applicable base material of thermal sublimation ribbon and preparation method thereof | |
| CN114261221B (en) | Thermal sublimation ribbon for printing reflective marks, preparation method and reflective marks | |
| JPH0671835B2 (en) | Thermal transfer sheet, dye mixture and transfer method | |
| CN112480743A (en) | Weather-proof thermal sublimation thermal transfer printing ink and preparation method thereof | |
| BRPI0608414B1 (en) | ink set, and inkjet printing method | |
| CN109693463B (en) | Pearlescent printing medium and preparation method thereof | |
| Chovancova et al. | Color and lightfastness performance of different epson ink sets | |
| CN109554004B (en) | Pigment dispersants and their use | |
| CN114274683A (en) | Gasoline-resistant resin carbon ribbon for traffic printing and preparation method thereof | |
| CN114261228A (en) | Thermal transfer printing soft label printing method, pattern receiving thermal transfer ribbon and auxiliary thermal transfer ribbon | |
| CN114312063B (en) | Thermal transfer resin ribbon suitable for traffic sign board, preparation method thereof and traffic sign board | |
| CN113122056A (en) | Ink-jet coating liquid, preparation method thereof and waterproof ink-jet polypropylene film | |
| CN114193950B (en) | Structural color resin carbon ribbon and preparation method thereof | |
| CN114274682A (en) | Carbon ribbon with protective layer for reflective film and preparation method thereof | |
| JPS5938087A (en) | Material to be recorded | |
| CN114277606B (en) | Inkless printing paper and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |