CN114236401A - A Battery State Estimation Method Based on Adaptive Particle Swarm Optimization - Google Patents

A Battery State Estimation Method Based on Adaptive Particle Swarm Optimization Download PDF

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CN114236401A
CN114236401A CN202111567822.4A CN202111567822A CN114236401A CN 114236401 A CN114236401 A CN 114236401A CN 202111567822 A CN202111567822 A CN 202111567822A CN 114236401 A CN114236401 A CN 114236401A
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CN114236401B (en
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黄蕾
李睿
郑建
彭程
陈晓琳
孙春胜
李旸熙
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Shanghai Chint Power Systems Co ltd
Shanghai Jiao Tong University
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Abstract

The invention discloses a battery state estimation method based on a self-adaptive particle swarm algorithm, which relates to the field of battery state management and comprises the following steps: step 1, performing constant current pulse experiments at different temperatures, and calibrating initial characteristic parameters of a battery, wherein the characteristic parameters comprise: open circuit voltage-charge state characteristic curve fitting parameters, ohmic internal resistance, concentration polarization capacitance, electrochemical polarization internal resistance and electrochemical polarization capacitance; step 2, putting the battery into actual operation, updating the state of charge of the battery and recording the state data of the battery in operation; and 3, starting a new round of parameter self-correction after the recorded state data reaches a preset threshold value, wherein the new round of parameter self-correction comprises updating the characteristic parameters and the battery capacity parameters of the battery, and the updated characteristic parameters and the updated battery capacity parameters are used for updating the state of charge of the battery.

Description

Battery state estimation method based on adaptive particle swarm optimization
Technical Field
The invention relates to the field of battery state management, in particular to a battery state estimation method based on a self-adaptive particle swarm algorithm.
Background
The State of Charge (SOC) of a battery is a key parameter in the State management of a lithium ion battery. The SOC of the battery is accurately estimated, so that the service efficiency of the battery can be guaranteed, the service safety can be improved, and the method has important significance.
In the Chinese patent application "an SOC estimation method based on particle swarm optimization particle filter algorithm" (application number: CN202110902979.1), Malayan et al provides an SOC estimation method based on particle swarm optimization particle filter algorithm, which comprises the following steps: s1, performing charge and discharge experiments on the battery under the specified working condition, and constructing a battery equivalent circuit model by analyzing and processing experimental data; s2, constructing a state equation and a measurement equation for estimating the SOC of the battery according to the equivalent circuit model obtained by identification; s3, estimating the change of the SOC of the battery by utilizing particle swarm optimization particle filtering; s4, optimizing the positions of the particles in the particle filter by utilizing a particle swarm algorithm; and S5, estimating the SOC of the battery at the next moment again through S3 until the estimation process is finished.
The invention discloses a self-correction SOC estimation method for a mining lithium battery in Chinese patent application No. CN201910414377.4, which carries out self-correction on the SOC prediction of the lithium battery according to the daily charge and discharge conditions of the lithium battery, wherein the self-correction of the system is to correct a battery pack model according to different charge and discharge states of the battery pack, and meanwhile, the realizability of an SOC estimation result is enhanced due to the randomness of particle generation; due to the universality of the battery model, the accuracy of the model can be continuously improved by a recursive least square identification mode of the battery model, and the model inaccuracy caused by overlarge discharge current change can be avoided. But this method only increases the accuracy of SOC estimation for non-gaussian noise scenarios.
Liakyjen et al, in the Chinese patent application "a lithium battery state estimation method and system based on random fragment data" (application number: CN202111031237.2), discloses a lithium battery state estimation method and system based on random fragment data, the estimation method steps include: acquiring first data and second data, and matching the first data with the second data by adopting a particle swarm algorithm to obtain third data of the lithium battery to be estimated, wherein the third data are initial SOC data and SOH data; constructing a first model of the lithium battery to be estimated based on a second-order Thevenin equivalent circuit model, and identifying and obtaining fourth data based on the first model; and estimating the state of charge of the lithium battery to be estimated by adopting extended Kalman filtering based on the third data and the fourth data to obtain the state information of the lithium battery to be estimated.
In the prior art, the method for identifying model parameters by using the particle swarm algorithm has the problem that the particle swarm converges to local optimum, and because the relation between the selected charge state and the open-circuit voltage only adopts one curve to simulate the whole-segment data, the particle swarm algorithm is always in the optimization process under the condition of system errors of extreme charge states (the charge state is close to 1 or close to 0) or multi-platform open-circuit voltages.
Therefore, those skilled in the art have been devoted to developing a battery state estimation method based on an adaptive particle swarm algorithm to solve the above-mentioned problems in the prior art.
Disclosure of Invention
In view of the above-mentioned drawbacks of the prior art, the technical problem to be solved by the present invention is how to converge the particle swarm to the global optimum in the process of estimating the battery state by the particle swarm algorithm, so as to accurately estimate the battery state.
In order to achieve the above object, the present invention provides a battery state estimation method based on an adaptive particle swarm algorithm, the method comprising the following steps:
step 1, performing constant current pulse experiments at different temperatures, and calibrating initial characteristic parameters of a battery, wherein the characteristic parameters comprise: open circuit voltage-charge state characteristic curve fitting parameters, ohmic internal resistance, concentration polarization capacitance, electrochemical polarization internal resistance and electrochemical polarization capacitance;
step 2, putting the battery into actual operation, updating the state of charge of the battery and recording the state data of the battery in operation;
and 3, starting a new round of parameter self-correction after the recorded state data reaches a preset threshold value, wherein the new round of parameter self-correction comprises updating the characteristic parameters and the battery capacity parameters of the battery, and the updated characteristic parameters and the updated battery capacity parameters are used for updating the state of charge of the battery.
Further, the step 1 comprises the following substeps:
step 1.1, determining the different temperatures according to the temperature range of the operation work of the battery and the preset temperature step length; sequentially carrying out a plurality of times of constant current pulse experiments on the battery at different temperatures, and recording current data and voltage data of the battery at different charge states;
step 1.2, according to the tail voltage of the standing section of the constant current pulse experiment and the ratio of the discharged capacity of the constant current pulse experiment to the total discharged capacity of the testSeveral open circuit voltage-state of charge data points at different temperatures are determined and noted as (OCV)1,SOC1),(OCV2,SOC2),...,(OCVn,SOCn);
Step 1.3, fitting each open-circuit voltage-charge state data point by adopting segmented cubic spline interpolation to obtain a fitting curve, and obtaining a fitting parameter [ K ] of the open-circuit voltage-charge state characteristic curve11,K12,K13,K14,K21,...,K(n-1)4]Wherein, K is11,K12,K13,K14Correspondence (OCV)1,SOC1) And (OCV)2,SOC2) Fitting parameters of the connecting lines between the two; k21,K22,K23,K24Correspondence (OCV)2,SOC2) And (OCV)3,SOC3) Fitting parameters of the connecting lines between the two; ...; k(n-1)1,K(n-1)2,K(n-1)3,K(n-1)4Correspondence (OCV)(n-1),SOC(n-1)) And (OCV)n,SOCn) Fitting parameters of the connecting lines between the two;
step 1.4, calibrating the ohmic internal resistance R of the battery by using instantaneous current and voltage data of current pulsedc(ii) a Calibrating the electrochemical polarization internal resistance, the electrochemical polarization capacitance, the concentration polarization internal resistance and the concentration polarization capacitance of the battery by using two sections of zero input and zero state response processes in and after the current pulse process and a double-exponential fitting mode, and sequentially recording as Rep、Cep、RcpAnd Ccp
Further, in the step 2, the following steps are included:
step 2.1, initializing a state of charge estimation particle filter, including selecting an observation noise variance v according to the field environment to which the battery is applied near a corresponding initial state of charge value before the battery is put into actual operation1Setting a convergence threshold ε1And sampling according to a Gaussian distribution to generate N1A first random particle, said N1The first random particles are located between 0 and 1;
step 2.2, setting the iteration times of the first random particles;
step 2.3, according to the observed noise variance v1Calculating a first weight of the first random particle;
step 2.4, carrying out normalization processing on the first weight;
step 2.5, judging whether the first random particles are effective or not, and determining whether resampling is needed or not;
step 2.6, updating the state data of the battery according to the state data of the battery, including current, voltage, temperature, the state of charge at the last moment and the characteristic parameters, and repeating the steps 2.2-2.6 until the state of charge estimation particle filter converges to the preset convergence threshold epsilon1And obtaining the state of charge of the battery.
Further, in the step 3, the following steps are included:
step 3.1, selecting an estimated change proportion eta on the basis of the previous round of parameter self-correction, initializing and standardizing the characteristic parameters of the battery by taking random numbers in a range of (1-eta, 1+ eta) times the characteristic parameters obtained by the previous round of parameter self-correction, and reducing the characteristic parameters to be between-1 and 1 so as to ensure that singularity does not occur when each characteristic parameter is subjected to matrix operation;
step 3.2, calculating a moderate value of the first random particles, and sequencing the first random particles according to the degree of the moderate value; if the number of the high moderate value particles reaches the required cluster precision or reaches the iteration times, outputting the characteristic parameter of the battery corresponding to the highest moderate value particles as the latest characteristic parameter of the battery, otherwise, entering the next step;
step 3.3, judging whether the number of the particles with the high moderate value reaches a given distribution proportion delta or not, if not, reducing the distribution proportion delta, enabling more first random particles to enter a particle swarm algorithm estimation process, and accelerating algorithm convergence; if the given distribution proportion delta is reached, the next step is carried out;
step 3.4, judging whether the distribution proportion delta reaches a set threshold, if the distribution proportion delta reaches the set threshold, keeping the distribution proportion delta unchanged, otherwise, adjusting the distribution proportion delta according to the step 3.3;
3.5, distributing different first random particles according to the adjusted distribution proportion delta, directly adopting a particle swarm algorithm to update the positions and the speeds of the particles of the first random particles higher than the distribution proportion delta, firstly obtaining fitness values of the particles around the first random particles for the first random particles lower than the distribution proportion delta, and then carrying out next judgment;
step 3.6, updating particle parameters according to the highest fitness value which can be obtained by the first random particle;
and 3.7, updating the fitness values of all the first random particles, sequencing and then returning to the step 3.2.
Further, the step 3.6 selects one of the following 4 steps according to the highest fitness value that can be obtained by the first random particle, and updates the particle parameter;
step 3.6.1, randomly selecting a random state within a variable radius according to the current state of the first random particle, if the moderate value of the random state is greater than the current moderate value of the first random particle, the first random particle advances one step towards the selected random state, otherwise, the state is randomly selected again; if N is chosen randomlytryIf the fitness value of the random state is not higher than the current fitness value of the first random particle, go to step 3.6.4;
step 3.6.2, if a particle aggregation center exists in the variation radius of the first random particle, and the ratio of the fitness value of the particle aggregation center to the number of particles existing in the variation radius of the first random particle is lower than a set threshold, moving the first random particle to the particle aggregation center by one step;
3.6.3, if the maximum fitness value particle exists in the variation radius of the first random particle, and the ratio of the number of the particles existing in the variation radius of the maximum fitness value particle to the number of the particles existing in the variation radius of the first random particle is lower than a set threshold, moving the first random particle to the maximum fitness value particle by one step;
at step 3.6.4, if neither of steps 3.6.2 and 3.6.3 can meet the requirement, then a state within the range of particle variation is randomly selected.
Further, the step 3 further comprises the following steps:
step 3.8, updating the battery capacity parameter by utilizing a self-adaptive battery capacity estimation particle filter;
step 3.9, dividing the ohmic internal resistance obtained by updating by the ohmic internal resistance in the initial calibration to obtain the internal resistance health degree of the battery; and according to the updated battery capacity parameter, dividing the updated battery capacity parameter by the initial battery capacity parameter to obtain the capacity health degree of the battery.
Further, in the step 3.8, the following sub-steps are included:
step 3.8.1, initializing the battery capacity estimation particle filter, and selecting an observation noise variance v according to the field environment to which the battery is applied by taking the initial battery capacity of the battery as a reference2Generating N in a Gaussian distribution2A second plurality of random particles;
step 3.8.2, setting the iteration number of the battery capacity estimation particle filter;
step 3.8.3, based on the observed noise variance v2Calculating a second weight of the second random particle;
step 3.8.4: normalizing the second weight value;
step 3.8.5: judging whether the second random particles are effective or not, and determining whether resampling is needed or not;
3.8.6, obtaining the state of charge of the battery according to the state data of the battery, including current, voltage, temperature, and last timeUpdating the state data of the battery and repeating the steps 3.8.2-3.8.6 until the battery capacity estimation particle filter converges to the predetermined convergence threshold epsilon2And obtaining the battery capacity parameter of the battery.
Further, said N2The second random particles are second random particles having a value between 0 and the initial battery capacity.
Further, the estimated variation ratio η has a value range of 0 < η < 1.
Further, the threshold range of the distribution ratio δ is 0.3 < δ < 0.7.
The invention provides a battery state estimation method based on a self-adaptive particle swarm algorithm, which at least has the following technical effects:
1. the technical scheme provided by the invention firstly determines the initial system parameters of the battery pack by utilizing an initial constant current pulse test, and realizes the fitting of the open circuit voltage-charge state relation by adopting segmented cubic spline interpolation, the parameter fitting characteristic is excellent under the extreme charge state, and the parameters are not easy to diverge due to polynomial fitting, so that the method is more suitable for parameter identification by adopting a group intelligent algorithm;
2. in order to avoid the particle swarm from finally falling into local optimization, the technical scheme provided by the invention modifies the optimization process of the particle swarm algorithm and designs the self-adaptive threshold, so that particles below the threshold are globally optimized in a manner similar to an artificial fish swarm, particles above the threshold are continuously optimized by the particle swarm algorithm to converge to an extreme point as soon as possible, and the threshold is continuously adjusted according to the moderate value of each particle in the process, thereby realizing the acceleration of the optimization process;
3. the model provided by the invention is a second-order RC equivalent circuit model based on the battery, has strong parameter interpretability and strong algorithm global optimization capability, and can realize the joint estimation of the charge states, the battery internal resistances and the battery capacity health degrees of different types of lithium batteries.
The conception, the specific structure and the technical effects of the present invention will be further described with reference to the accompanying drawings to fully understand the objects, the features and the effects of the present invention.
Drawings
FIG. 1 is a schematic overall flow chart of a preferred embodiment of the present invention.
Detailed Description
The technical contents of the preferred embodiments of the present invention will be more clearly and easily understood by referring to the drawings attached to the specification. The present invention may be embodied in many different forms of embodiments and the scope of the invention is not limited to the embodiments set forth herein.
In order to solve the problem that the particle swarm converges to local optimum or can not converge in the method for identifying the model parameters by simply adopting the particle swarm algorithm in the prior art, the invention discloses a battery state estimation strategy based on a self-adaptive particle swarm algorithm, which comprises the following steps: firstly, constant current pulse experiments at different temperatures are carried out, and battery model parameter calibration is carried out; then, putting the battery into actual operation, and updating the state of charge of the battery in real time on line by using self-adaptive particle filtering; and finally, updating parameters such as battery polarization internal resistance, polarization capacitance, ohmic internal resistance, open-circuit voltage and state-of-charge relation functions and the like by using a self-adaptive particle swarm optimization according to a given operation cycle, determining the health degree of the battery internal resistance by using the updated ohmic internal resistance of the battery, updating battery capacity parameters by using a particle filter optimization to further determine the health degree of the battery capacity, and using the updated parameters for subsequent updating of the state-of-charge of the battery. The model adopted by the invention is based on a second-order RC equivalent circuit model of the battery, has strong parameter interpretability and strong algorithm global optimization capability, and can realize the joint estimation of the charge states, the internal resistances and the capacity health degrees of different types of lithium batteries.
As shown in fig. 1, which is a schematic overall flow chart of a preferred embodiment of the present invention, a particle swarm algorithm with adaptive thresholds is used to update battery characteristic parameters so as to achieve battery state estimation.
Specifically, the battery state estimation method based on the adaptive particle swarm algorithm provided by the embodiment of the invention comprises the following steps:
step 1, constant current pulse experiments at different temperatures are carried out, and initial characteristic parameters of the battery are calibrated, wherein the characteristic parameters comprise: open circuit voltage-charge state characteristic curve fitting parameters, ohmic internal resistance, concentration polarization capacitance, electrochemical polarization internal resistance and electrochemical polarization capacitance;
step 2, putting the battery into actual operation, updating the state of charge of the battery and recording the state data of the battery in operation;
and 3, starting a new round of parameter self-correction after the recorded state data reaches a preset threshold value, wherein the new round of parameter self-correction comprises updating the characteristic parameters and the battery capacity parameters of the battery, and the updated characteristic parameters and the updated battery capacity parameters are used for updating the charge state of the battery.
Wherein, step 1 comprises the following substeps:
step 1.1, determining different temperatures according to the temperature range of the operation work of the battery and the preset temperature step length; sequentially carrying out a plurality of constant current pulse experiments on the battery at different temperatures, and recording current data and voltage data of the battery at different charge states;
step 1.2, determining a plurality of open circuit voltage-charge state data points at different temperatures according to the tail voltage of the standing section of the constant current pulse experiment and the ratio of the discharged amount of the constant current pulse experiment to the total discharged amount of the test, and recording the data points as (OCV)1,SOC1),(OCV2,SOC2),...,(OCVn,SOCn);
Step 1.3, fitting each open-circuit voltage-charge state data point by adopting segmented cubic spline interpolation to obtain a fitting curve, and obtaining an open-circuit voltage-charge state characteristic curve fitting parameter [ K ]11,K12,K13,K14,K21,...,K(n-1)4]Wherein, K is11,K12,K13,K14Correspondence (OCV)1,SOC1) And (OCV)2,SOC2) Fitting parameters of the connecting lines between the two; k21,K22,K23,K24Correspondence (OCV)2,SOC2) And (OCV)3,SOC3) BetweenFitting parameters of the connecting line; ...; k(n-1)1,K(n-1)2,K(n-1)3,K(n-1)4Correspondence (OCV)(n-1),SOC(n-1)) And (OCV)n,SOCn) Fitting parameters of the connecting lines between the two;
step 1.4, calibrating ohmic internal resistance R of the battery by using instantaneous current and voltage data of current pulsedc(ii) a Calibrating the electrochemical polarization internal resistance, the electrochemical polarization capacitance, the concentration polarization internal resistance and the concentration polarization capacitance of the battery by using two sections of zero input and zero state response processes in and after the current pulse process and using a double-exponential fitting mode, and sequentially recording as Rep、Cep、RcpAnd Ccp
Wherein, in step 2, the method comprises the following steps:
step 2.1, initializing the state of charge estimation particle filter, including selecting observation noise variance v according to the field environment of the battery before the battery is put into practical operation and corresponding to the vicinity of the initial state of charge value1Setting a convergence threshold ε1And sampling according to a Gaussian distribution to generate N1A first random particle, N1The first random particles are located between 0 and 1;
step 2.2, setting the iteration times of the first random particles;
step 2.3, according to the observed noise variance v1Calculating a first weight of the first random particle;
step 2.4, carrying out normalization processing on the first weight;
step 2.5, judging whether the first random particles are effective or not, and determining whether resampling is needed or not;
step 2.6, updating the state data of the battery according to the state data of the battery, including current, voltage, temperature, the state of charge at the last moment and characteristic parameters, and repeating the steps 2.2-2.6 until the state of charge estimation particle filter converges to a preset convergence threshold epsilon1And obtaining the charge state of the battery.
Wherein, in step 3, the method comprises the following steps:
3.1, selecting an estimated change proportion eta on the basis of the previous round of parameter self-correction, initializing and standardizing the characteristic parameters of the battery by taking random numbers in a range of (1-eta, 1+ eta) multiplied by the characteristic parameters obtained by the previous round of parameter self-correction, and reducing the characteristic parameters to be-1 to ensure that singularity does not occur when each characteristic parameter is subjected to matrix operation; estimating the numerical range of the variation ratio eta to be 0 < eta < 1;
step 3.2, calculating a proper value of the first random particles, and sequencing the first random particles according to the height of the proper value; if the number of the particles with the high moderate value reaches the required cluster precision or reaches the iteration times, outputting the characteristic parameters of the battery corresponding to the particles with the highest moderate value as the latest characteristic parameters of the battery, otherwise, entering the next step;
step 3.3, judging whether the number of the particles with the high fitness value reaches a given distribution proportion delta or not, if not, reducing the distribution proportion delta, enabling more first random particles to enter a particle swarm algorithm estimation process, and accelerating algorithm convergence; if the given distribution proportion delta is reached, the next step is carried out; the threshold range of the distribution ratio delta is more than 0.3 and less than 0.7;
step 3.4, judging whether the distribution proportion delta reaches a set threshold, if so, keeping the distribution proportion delta unchanged, otherwise, adjusting the distribution proportion delta according to the step 3.3;
3.5, distributing different first random particles according to the adjusted distribution proportion delta, updating the positions and the speeds of the particles of the first random particles higher than the distribution proportion delta by directly adopting a particle swarm algorithm, firstly obtaining fitness values of the particles around the first random particles for the first random particles lower than the distribution proportion delta, and then carrying out next judgment;
step 3.6, updating the particle parameters according to the highest fitness value which can be obtained by the first random particles;
and 3.7, updating the fitness values of all the first random particles, sequencing, and returning to the step 3.2.
Step 3.6, according to the highest fitness value which can be obtained by the first random particle, selecting one of the following 4 steps to update the particle parameter;
step 3.6.1, randomly selecting a random state within the variable radius according to the current state of the first random particle, if the moderate value of the random state is greater than the current moderate value of the first random particle, the first random particle advances one step towards the selected random state, otherwise, the state is randomly selected again; if N is chosen randomlytryAfter that, if the fitness value of the random state is not higher than the current fitness value of the first random particle, go to step 3.6.4;
step 3.6.2, if a particle aggregation center exists in the variation radius of the first random particle, and the ratio of the fitness value of the particle aggregation center to the number of particles existing in the variation radius of the first random particle is lower than a set threshold, moving the first random particle to the particle aggregation center by one step;
3.6.3, if the maximum fitness value particle exists in the variation radius of the first random particle, and the ratio of the number of the particles existing in the variation radius of the maximum fitness value particle to the number of the particles existing in the variation radius of the first random particle is lower than a set threshold value, moving the first random particle to the maximum fitness value particle by one step;
at step 3.6.4, if neither of steps 3.6.2 and 3.6.3 can meet the requirement, then a state within the range of particle variation is randomly selected.
Wherein, step 3 also includes the following steps:
step 3.8, updating the battery capacity parameter by utilizing a self-adaptive battery capacity estimation particle filter;
3.9, dividing the ohmic internal resistance obtained by updating by the ohmic internal resistance in the initial calibration to obtain the internal resistance health degree of the battery; and according to the updated battery capacity parameter, dividing the updated battery capacity parameter by the initial battery capacity parameter to obtain the capacity health degree of the battery.
Wherein, in step 3.8, the following substeps are included:
step 3.8.1, initializing the battery capacity estimation particle filter, selecting the observation noise variance v according to the field environment of the battery with the initial battery capacity of the battery as the reference2Generating N in a Gaussian distribution2A second plurality of random particles; n is a radical of2The second random particles are second random particles having a value between 0 and the initial battery capacity.
Step 3.8.2, setting the iteration times of the battery capacity estimation particle filter;
step 3.8.3, based on the observed noise variance v2Calculating a second weight of the second random particle;
step 3.8.4: normalizing the second weight value;
step 3.8.5: judging whether the second random particles are effective or not, and determining whether resampling is needed or not;
3.8.6, updating the state data of the battery according to the state data of the battery, including current, voltage, temperature and the state of charge at the last time, and repeating the steps 3.8.2-3.8.6 until the battery capacity estimation particle filter converges to the preset convergence threshold epsilon2And obtaining the battery capacity parameter of the battery.
The foregoing detailed description of the preferred embodiments of the invention has been presented. It should be understood that numerous modifications and variations could be devised by those skilled in the art in light of the present teachings without departing from the inventive concepts. Therefore, the technical solutions available to those skilled in the art through logic analysis, reasoning and limited experiments based on the prior art according to the concept of the present invention should be within the scope of protection defined by the claims.

Claims (10)

1.一种基于自适应粒子群算法的电池状态估计方法,其特征在于,所述方法包括以下步骤:1. A battery state estimation method based on an adaptive particle swarm algorithm, characterized in that the method comprises the following steps: 步骤1、进行不同温度下的恒流脉冲实验,标定电池初始的特性参数,所述特性参数包括:开路电压-荷电状态特征曲线拟合参数、欧姆内阻、浓差极化内阻、浓差极化电容、电化学极化内阻、电化学极化电容;Step 1. Carry out constant current pulse experiments at different temperatures to calibrate the initial characteristic parameters of the battery. The characteristic parameters include: open circuit voltage-state of charge characteristic curve fitting parameters, ohmic internal resistance, concentration polarization internal resistance, concentration Differential polarization capacitance, electrochemical polarization internal resistance, electrochemical polarization capacitance; 步骤2、将所述电池投入实际运行,更新所述电池的荷电状态并记录所述电池在运行中的状态数据;Step 2. Put the battery into actual operation, update the state of charge of the battery and record the state data of the battery in operation; 步骤3、在记录的所述状态数据达到预先设定的阈值后,开始新一轮参数自校正,包括更新所述电池的所述特性参数和电池容量参数,并将更新后的所述特性参数和所述电池容量参数用于更新所述电池的所述荷电状态。Step 3. After the recorded state data reaches the preset threshold, start a new round of parameter self-calibration, including updating the characteristic parameters and battery capacity parameters of the battery, and updating the updated characteristic parameters. and the battery capacity parameter is used to update the state of charge of the battery. 2.如权利要求1所述的基于自适应粒子群算法的电池状态估计方法,其特征在于,所述步骤1包括以下子步骤:2. The battery state estimation method based on the adaptive particle swarm algorithm according to claim 1, wherein the step 1 comprises the following sub-steps: 步骤1.1、根据所述电池的运行工作的温度范围及预先设定的温度步长,确定所述不同温度;在所述不同温度下对所述电池依次进行若干次所述恒流脉冲实验,并记录所述电池在不同荷电状态处的电流数据和电压数据;Step 1.1. Determine the different temperatures according to the operating temperature range of the battery and the preset temperature step size; perform the constant current pulse experiment several times on the battery at the different temperatures in turn, and recording current data and voltage data of the battery at different states of charge; 步骤1.2、根据所述恒流脉冲实验的静置段的末尾电压及所述恒流脉冲实验的所放电量与测试所放总电量之比,确定不同温度下的若干开路电压-荷电状态数据点,并记为(OCV1,SOC1),(OCV2,SOC2),...,(OCVn,SOCn);Step 1.2. Determine several open-circuit voltage-state-of-charge data at different temperatures according to the voltage at the end of the stationary section of the constant-current pulse experiment and the ratio of the discharged amount of the constant-current pulse experiment to the total amount of power discharged by the test points, and denoted as (OCV 1 , SOC 1 ), (OCV 2 , SOC 2 ), ..., (OCV n , SOC n ); 步骤1.3、采用分段三次样条插值拟合所述各个开路电压-荷电状态数据点,得到拟合曲线,获得所述开路电压-荷电状态特征曲线拟合参数[K11,K12,K13,K14,K21,...,K(n-1)4],其中,K11,K12,K13,K14对应(OCV1,SOC1)和(OCV2,SOC2)之间连线的拟合参数;K21,K22,K23,K24对应(OCV2,SOC2)和(OCV3,SOC3)之间连线的拟合参数;...;K(n-1)1,K(n-1)2,K(n-1)3,K(n-1)4对应(OCV(n-1),SOC(n-1))和(OCVn,SOCn)之间连线的拟合参数;Step 1.3, using piecewise cubic spline interpolation to fit each open-circuit voltage-state of charge data point to obtain a fitting curve, and obtain the open-circuit voltage-state of charge characteristic curve fitting parameters [K 11 , K 12 , K 13 , K 14 , K 21 , ..., K (n-1)4 ], where K 11 , K 12 , K 13 , K 14 correspond to (OCV 1 , SOC 1 ) and (OCV 2 , SOC 2 ) ); K 21 , K 22 , K 23 , K 24 correspond to the fitting parameters of the line between (OCV 2 , SOC 2 ) and (OCV 3 , SOC 3 );  …; K (n-1)1 , K (n-1)2 , K (n-1)3 , K (n-1)4 correspond to (OCV (n-1) , SOC (n-1) ) and (OCV n , the fitting parameters of the connection between SOC n ); 步骤1.4、利用电流脉冲瞬间的电流、电压数据标定所述电池的所述欧姆内阻Rdc;利用电流脉冲过程中及过程后的两段零输入和零状态响应过程,利用双指数拟合方式标定所述电池的所述电化学极化内阻、所述电化学极化电容、所述浓差极化内阻和所述浓差极化电容,并依次记为Rep、Cep、Rcp和CcpStep 1.4, calibrate the ohmic internal resistance R dc of the battery by utilizing the current and voltage data at the moment of the current pulse; utilize the two-stage zero input and zero state response process during and after the current pulse process, and utilize the double exponential fitting method The electrochemical polarization internal resistance, the electrochemical polarization capacitance, the concentration polarization internal resistance and the concentration polarization capacitance of the battery are calibrated, and marked as R ep , C ep , R in turn cp and Ccp . 3.如权利要求2所述的基于自适应粒子群算法的电池状态估计方法,其特征在于,在所述步骤2中,包括以下步骤:3. The battery state estimation method based on the adaptive particle swarm algorithm according to claim 2, wherein in the step 2, the method comprises the following steps: 步骤2.1、初始化荷电状态估算粒子滤波器,包括在所述电池投入所述实际运行之前对应的初始荷电状态值附近,根据所述电池所应用的领域环境,选取观测噪声方差v1,设定收敛阈值ε1,并按高斯分布采样生成N1个第一随机粒子,所述N1个所述第一随机粒子位于0~1之间;Step 2.1. Initialize the particle filter for state of charge estimation, including near the corresponding initial state of charge value before the battery is put into the actual operation. According to the field environment in which the battery is applied, select the observed noise variance v 1 , set determining a convergence threshold ε 1 , and sampling according to a Gaussian distribution to generate N 1 first random particles, where the N 1 first random particles are located between 0 and 1; 步骤2.2、设置所述第一随机粒子的迭代次数;Step 2.2, setting the number of iterations of the first random particle; 步骤2.3、根据所述观测噪声方差v1计算所述第一随机粒子的第一权值;Step 2.3, calculating the first weight of the first random particle according to the observed noise variance v 1 ; 步骤2.4、将所述第一权值进行归一化处理;Step 2.4, normalizing the first weight; 步骤2.5、判断所述第一随机粒子是否有效,决定是否需要重新采样;Step 2.5, judge whether the first random particle is valid, and decide whether resampling is required; 步骤2.6、根据所述电池的所述状态数据,包括电流、电压、温度、上一时刻所述荷电状态以及所述特性参数,更新所述电池的所述状态数据,并重复所述步骤2.2~2.6,直至所述荷电状态估算粒子滤波器收敛到预先设定的所述收敛阈值ε1内,得到所述电池的所述荷电状态。Step 2.6: Update the state data of the battery according to the state data of the battery, including current, voltage, temperature, the state of charge at the last moment, and the characteristic parameter, and repeat the step 2.2 ~2.6, until the state-of-charge estimation particle filter converges within the preset convergence threshold ε 1 , to obtain the state of charge of the battery. 4.如权利要求3所述的基于自适应粒子群算法的电池状态估计方法,其特征在于,在所述步骤3中,包括以下步骤:4. The battery state estimation method based on the adaptive particle swarm algorithm according to claim 3, wherein in the step 3, the method comprises the following steps: 步骤3.1、在上一轮所述参数自校正的基础上,选定估算变化比例η,将所述电池的所述特性参数在(1-η,1+η)乘以上一轮所述参数自校正得到的所述特性参数的范围内取随机数进行初始化和标准化,将所述特性参数缩小到-1~1之间以确保各个所述特性参数在进行矩阵运算时不至于出现奇异;Step 3.1. On the basis of the parameter self-calibration in the previous round, select the estimated change ratio η, and multiply the characteristic parameter of the battery by (1-η, 1+η) in the previous round of the parameter self-adjustment. Random numbers are taken within the range of the characteristic parameters obtained by correction for initialization and standardization, and the characteristic parameters are reduced to between -1 and 1 to ensure that each of the characteristic parameters does not appear singular when performing matrix operations; 步骤3.2、计算所述第一随机粒子的适度值,并按照所述适度值的高低对所述第一随机粒子进行排序;如果高适度值粒子数达到所需集群精度,或者达到迭代次数,则将最高适度值粒子对应的所述电池的所述特性参数输出作为最新的所述电池的所述特性参数,否则进入下一步;Step 3.2: Calculate the moderate value of the first random particle, and sort the first random particles according to the moderate value; if the number of particles with high moderate value reaches the required cluster accuracy, or reaches the number of iterations, then Output the characteristic parameter of the battery corresponding to the highest moderate value particle as the latest characteristic parameter of the battery, otherwise go to the next step; 步骤3.3、判断所述高适度值粒子数是否达到给定的分配比例δ,若未达到给定的所述分配比例δ,则减小所述分配比例δ,使更多所述第一随机粒子进入粒子群算法估算过程,加速算法收敛;若达到给定的所述分配比例δ,则进入下一步;Step 3.3. Determine whether the number of high-moderate particles reaches the given distribution ratio δ, and if it does not reach the given distribution ratio δ, reduce the distribution ratio δ to make more of the first random particles Enter the particle swarm algorithm estimation process to accelerate the algorithm convergence; if the given allocation ratio δ is reached, go to the next step; 步骤3.4、判断所述分配比例δ是否达到设定阈值,若已经达到所述设定阈值,则保持所述分配比例δ不变,否则按所述步骤3.3调整所述分配比例δ;Step 3.4, determine whether the distribution ratio δ has reached the set threshold, if it has reached the set threshold, keep the distribution ratio δ unchanged, otherwise adjust the distribution ratio δ according to the step 3.3; 步骤3.5、根据调整后的所述分配比例δ分配不同的所述第一随机粒子,对于高于所述分配比例δ的所述第一随机粒子,直接采用粒子群算法,更新粒子位置与速度,对于低于所述分配比例δ的所述第一随机粒子,首先获得所述第一随机粒子周围粒子的适度值,再进行下一步判断;Step 3.5: Allocate different first random particles according to the adjusted distribution ratio δ, and for the first random particles higher than the distribution ratio δ, directly use particle swarm algorithm to update the particle position and velocity, For the first random particle that is lower than the distribution ratio δ, first obtain the moderate value of the particles around the first random particle, and then perform the next step of judgment; 步骤3.6、根据所述第一随机粒子可以获得的最高适度值,进行粒子参数更新;Step 3.6, update particle parameters according to the highest moderate value that can be obtained by the first random particle; 步骤3.7、更新所有所述第一随机粒子的所述适度值,并排序,然后返回所述步骤3.2。Step 3.7, update the moderate values of all the first random particles, sort them, and then return to the step 3.2. 5.如权利要求4所述的基于自适应粒子群算法的电池状态估计方法,其特征在于,所述步骤3.6根据所述第一随机粒子可以获得的所述最高适度值,选择以下4种步骤中的一种,进行所述粒子参数更新;5. The battery state estimation method based on the adaptive particle swarm algorithm according to claim 4, wherein in step 3.6, the following 4 steps are selected according to the highest moderate value that can be obtained by the first random particle One of the particle parameters is updated; 步骤3.6.1、根据当前所述第一随机粒子的状态,在变化半径内随机选择一个随机状态,如果所述随机状态的适度值大于所述第一随机粒子当前的适度值,则所述第一随机粒子向所选择的所述随机状态方向前进一步,否则重新随机选择状态;如果随机选择Ntry次后,所述随机状态的适度值均未高于所述第一随机粒子当前的适度值,则执行步骤3.6.4;Step 3.6.1. According to the current state of the first random particle, randomly select a random state within the changing radius. If the moderate value of the random state is greater than the current moderate value of the first random particle, the A random particle advances one step in the direction of the selected random state, otherwise the state is randomly selected; if after N try times of random selection, the moderate value of the random state is not higher than the current moderate value of the first random particle , then go to step 3.6.4; 步骤3.6.2、若在所述第一随机粒子的变化半径内存在粒子聚集中心,且所述粒子聚集中心的适度值与所述第一随机粒子的变化半径内存在的粒子数量的比值低于所设阈值,则所述第一随机粒子向所述粒子聚集中心处移动一步;Step 3.6.2. If there is a particle aggregation center within the changing radius of the first random particle, and the ratio of the moderate value of the particle aggregation center to the number of particles existing in the changing radius of the first random particle is lower than If the threshold is set, the first random particle moves one step toward the particle aggregation center; 步骤3.6.3、若在所述第一随机粒子的变化半径内存在最大适度值粒子,且所述最大适度值粒子与所述第一随机粒子的变化半径内存在的粒子数量的比值低于所设阈值,则所述第一随机粒子向所述最大适应度粒子处移动一步;Step 3.6.3. If there is a maximum moderate value particle within the changing radius of the first random particle, and the ratio of the maximum moderate value particle to the number of particles existing within the changing radius of the first random particle is lower than the specified value; If the threshold is set, the first random particle moves one step toward the maximum fitness particle; 步骤3.6.4、若步骤3.6.2及3.6.3均无法满足需求,则随机选择粒子变化范围内的一个状态。Step 3.6.4. If steps 3.6.2 and 3.6.3 cannot meet the requirements, randomly select a state within the particle variation range. 6.如权利要求4所述的基于自适应粒子群算法的电池状态估计方法,其特征在于,所述步骤3还包括以下步骤:6. The battery state estimation method based on the adaptive particle swarm algorithm according to claim 4, wherein the step 3 further comprises the following steps: 步骤3.8、利用自适应的电池容量估算粒子滤波器更新所述电池容量参数;Step 3.8, using an adaptive battery capacity estimation particle filter to update the battery capacity parameter; 步骤3.9、根据更新所得的所述欧姆内阻,除以初始标定时的所述欧姆内阻可得所述电池的内阻健康度;根据更新所得的所述电池容量参数,与初始的所述电池容量参数相除,得到所述电池的容量健康度。Step 3.9: According to the updated ohmic internal resistance, divide the ohmic internal resistance at the initial calibration to obtain the internal resistance health of the battery; according to the updated battery capacity parameter, the same as the initial one. Divide the battery capacity parameter to obtain the capacity health of the battery. 7.如权利要求6所述的基于自适应粒子群算法的电池状态估计方法,其特征在于,在所述步骤3.8中,包括以下子步骤:7. The battery state estimation method based on the adaptive particle swarm algorithm according to claim 6, wherein in the step 3.8, the following sub-steps are included: 步骤3.8.1、初始化所述电池容量估算粒子滤波器,以所述电池的初始电池容量为基准,根据所述电池所应用的领域环境,选取观测噪声方差v2,按高斯分布生成N2个第二随机粒子;Step 3.8.1. Initialize the particle filter for estimating the battery capacity, take the initial battery capacity of the battery as the benchmark, select the observed noise variance v 2 according to the field environment where the battery is applied, and generate N 2 according to the Gaussian distribution the second random particle; 步骤3.8.2、设置所述电池容量估算粒子滤波器的迭代次数;Step 3.8.2, setting the number of iterations of the particle filter for battery capacity estimation; 步骤3.8.3、根据所述观测噪声方差v2计算所述第二随机粒子的第二权值;Step 3.8.3. Calculate the second weight of the second random particle according to the observed noise variance v 2 ; 步骤3.8.4:将所述第二权值进行归一化处理;Step 3.8.4: normalize the second weight; 步骤3.8.5:判断所述第二随机粒子是否有效,决定是否需要重新采样;Step 3.8.5: determine whether the second random particle is valid, and determine whether resampling is required; 步骤3.8.6、根据所述电池的所述状态数据,包括电流、电压、温度、上一时刻所述荷电状态,更新所述电池的所述状态数据,并重复所述步骤3.8.2~3.8.6,直至所述电池容量估算粒子滤波器收敛到预先设定的所述收敛阈值ε2内,得到所述电池的所述电池容量参数。Step 3.8.6. According to the state data of the battery, including current, voltage, temperature, and the state of charge at the last moment, update the state data of the battery, and repeat the steps 3.8.2 to 3.8. 3.8.6, until the battery capacity estimation particle filter converges within the preset convergence threshold ε 2 , obtain the battery capacity parameter of the battery. 8.如权利要求7所述的基于自适应粒子群算法的电池状态估计方法,其特征在于,所述N2个第二随机粒子是值位于0~初始电池容量之间的第二随机粒子。8 . The battery state estimation method based on the adaptive particle swarm algorithm according to claim 7 , wherein the N 2 second random particles are second random particles with a value between 0 and the initial battery capacity. 9 . 9.如权利要求4所述的基于自适应粒子群算法的电池状态估计方法,其特征在于,所述估算变化比例η的数值范围为0<η<1。9 . The battery state estimation method based on the adaptive particle swarm algorithm according to claim 4 , wherein the estimated change ratio η has a numerical range of 0<η<1. 10 . 10.如权利要求4所述的基于自适应粒子群算法的电池状态估计方法,其特征在于,所述分配比例δ的阈值范围为0.3<δ<0.7。10 . The battery state estimation method based on the adaptive particle swarm algorithm according to claim 4 , wherein the threshold range of the distribution ratio δ is 0.3<δ<0.7. 11 .
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