CN114231362B - Antibacterial laundry gel bead and preparation method thereof - Google Patents
Antibacterial laundry gel bead and preparation method thereof Download PDFInfo
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- CN114231362B CN114231362B CN202111636549.6A CN202111636549A CN114231362B CN 114231362 B CN114231362 B CN 114231362B CN 202111636549 A CN202111636549 A CN 202111636549A CN 114231362 B CN114231362 B CN 114231362B
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- fatty alcohol
- polyoxyethylene ether
- sodium sulfate
- ether sodium
- methyl ester
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- 239000011324 bead Substances 0.000 title claims abstract description 33
- 230000000844 anti-bacterial effect Effects 0.000 title claims description 29
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 77
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 77
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 75
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 70
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 70
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 70
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims abstract description 48
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- ARIWANIATODDMH-UHFFFAOYSA-N Lauric acid monoglyceride Natural products CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 claims abstract description 26
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims abstract description 23
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 claims abstract description 21
- -1 alkyl glycoside Chemical class 0.000 claims abstract description 16
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 229930182470 glycoside Natural products 0.000 claims abstract description 11
- 230000003385 bacteriostatic effect Effects 0.000 claims abstract description 10
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims abstract description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 45
- UQDUPQYQJKYHQI-UHFFFAOYSA-N methyl laurate Chemical compound CCCCCCCCCCCC(=O)OC UQDUPQYQJKYHQI-UHFFFAOYSA-N 0.000 claims description 42
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 38
- 239000008367 deionised water Substances 0.000 claims description 24
- 229910021641 deionized water Inorganic materials 0.000 claims description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 230000003472 neutralizing effect Effects 0.000 claims description 3
- 238000004806 packaging method and process Methods 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 2
- 241000191967 Staphylococcus aureus Species 0.000 abstract description 5
- 241000894006 Bacteria Species 0.000 abstract description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 38
- 230000000052 comparative effect Effects 0.000 description 15
- 239000000203 mixture Substances 0.000 description 12
- 238000009472 formulation Methods 0.000 description 11
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 239000003599 detergent Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 5
- 239000003093 cationic surfactant Substances 0.000 description 3
- 238000005202 decontamination Methods 0.000 description 3
- 230000003588 decontaminative effect Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000000022 bacteriostatic agent Substances 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000003013 cytotoxicity Effects 0.000 description 1
- 231100000135 cytotoxicity Toxicity 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 230000002949 hemolytic effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The application provides a bacteriostatic laundry gel bead and a preparation method thereof, wherein the bacteriostatic laundry gel bead comprises the following components in percentage by mass: 30-48% of fatty alcohol polyoxyethylene ether sodium sulfate, 5-16% of dodecylbenzene sulfonic acid, 10-16% of fatty acid methyl ester ethoxylate, 0-20% of alkyl glycoside, 5-8% of lauric acid monoglyceride, 5-15% of cocamidopropyl betaine, 1-10% of triethanolamine and 3-5% of solvent; the balance being water. According to the application, through formula adjustment, the addition amount of the fatty alcohol polyoxyethylene ether sodium sulfate can be effectively increased, and bacteria such as staphylococcus aureus can be effectively inhibited.
Description
Technical Field
The application relates to the technical field of daily chemicals, in particular to a bacteriostatic laundry gel bead and a preparation method thereof.
Background
Compared with the traditional laundry detergent, the laundry detergent has higher content of active substances and stronger decontamination effect. As a novel detergent, the detergent accords with the development trend of the washing industry.
Under the influence of epidemic situation, the demands of consumers on bacteriostasis are increased, and most of bacteriostats are synthesized by chemical substances and have certain irritation. The conventional silver ion bacteriostatic agent has the problems of poor stability, easy oxidation and denaturation and the like in fabric detergents. In the continuous application of the surfactant, some surfactants are found to have excellent antibacterial activity, and the most widely used cationic surfactant bacteriostats, especially quaternary ammonium salt cationic surfactant bacteriostats, are known at present, but from the environmental point of view, the surfactants have hemolytic activity and cytotoxicity, the contact time with aquatic organisms is long, the biodegradation can also increase the toxicity, the formulated laundry gel bead formula is generally weak alkaline, and the cationic surfactant is difficult to play a due role when being added into the formula.
Disclosure of Invention
In order to solve the technical problems, the application provides a bacteriostatic laundry gel bead and a preparation method thereof. The combination of various surfactant combinations is adopted, the synergistic antibacterial effect is achieved, the water content of the formula can be properly increased, and the use amount of the solvent is reduced.
In order to achieve the above purpose, the application adopts the following technical scheme:
the application discloses a bacteriostatic laundry gel bead, which comprises the following components in percentage by mass:
further, the composition comprises the following components in percentage by mass:
further, the carbon chain of fatty alcohol in the fatty alcohol-polyoxyethylene ether sodium sulfate is C12.
Further, the mass percentage of the fatty alcohol with the carbon chain of C12 in the fatty alcohol polyoxyethylene ether sodium sulfate is not less than 60%, and the average addition number of Ethylene Oxide (EO) is 1.5-2.5.
Further, the mass percent of the lauric acid methyl ester ethoxylate in the fatty acid methyl ester ethoxylate is not less than 90%, and the average EO addition number is 8-15.
Further, the mass percent of the lauric acid methyl ester ethoxylate in the fatty acid methyl ester ethoxylate is not less than 90%, and the average EO addition number is 12-15.
Further, the mass percentage of the water is not higher than 30%.
Further, the proportion of the fatty alcohol polyoxyethylene ether sodium sulfate, the fatty acid methyl ester ethoxylate and the lauric acid monoglyceride is 6+/-0.1:2+/-0.1:1.
Further, the solvent is at least one of propylene glycol, glycerol and ethylene glycol.
The second application of the application also discloses a preparation method of the antibacterial laundry bead, wherein the antibacterial laundry bead is the antibacterial laundry bead, and the preparation method comprises the following steps:
adding deionized water, a solvent, fatty acid methyl ester ethoxylate, cocamidopropyl betaine, alkyl glycoside and lauric acid monoglyceride into a reaction kettle in sequence according to the formula amount, controlling the reaction temperature at 40 ℃, and then mixing and stirring to obtain a solution A;
adding dodecylbenzene sulfonic acid and triethanolamine into the solution A according to the formula amount, stirring and neutralizing, and controlling the pH to be approximately equal to 8 to obtain a solution B;
weighing fatty alcohol polyoxyethylene ether sodium sulfate according to the formula amount, slowly adding the fatty alcohol polyoxyethylene ether sodium sulfate into the solution B, and stirring the fatty alcohol polyoxyethylene ether sodium sulfate while adding the fatty alcohol polyoxyethylene ether sodium sulfate to obtain a solution C;
and (3) standing the solution C for defoaming, cooling to room temperature, and packaging.
The alternatives of the application can be used as independent alternatives or can be combined with each other. The structure in any one scheme of the application can be used as an independent technical scheme or can be mutually combined with other technical schemes.
The application has the advantages that: through formula adjustment, the addition amount of the fatty alcohol polyoxyethylene ether sodium sulfate can be effectively improved, and bacteria such as staphylococcus aureus can be effectively inhibited.
Drawings
FIG. 1 is a diagram of the application prior to bacteriostasis testing using the gel bead formulation of example 1;
FIG. 2 is a graph of the application after an antibacterial test using the gel bead formulation of example 1;
FIG. 3 is a diagram of the application prior to a decontamination test using the bead formulation of example 1;
FIG. 4 is a diagram of the application after a decontamination test using the bead formulation of example 1.
Detailed Description
The preferred embodiments of the present application will be described in detail with reference to the accompanying drawings, and in order to enable those skilled in the art to better understand the embodiments of the present application, the following description will clearly and completely describe the embodiments of the present application with reference to the accompanying drawings.
A bacteriostatic laundry gel bead comprises the following components in percentage by mass: 30% -48% of fatty alcohol polyoxyethylene ether sodium sulfate (AES), wherein in the embodiment, the fatty alcohol polyoxyethylene ether sodium sulfate is a directly purchased product, and the content of the fatty alcohol polyoxyethylene ether sodium sulfate in the product is 70%; 5% -16% of dodecylbenzene sulfonic acid (LAS); fatty acid methyl ester ethoxylate (FMEE) 10% -16%; alkyl glycoside (APG) 0% -20%; 5% -8% of lauric acid monoglyceride (GML); 5% -15% of cocamidopropyl betaine (CAB); 1% -10% of triethanolamine; 3% -5% of solvent; the balance of deionized water.
Specifically, the carbon chain of fatty alcohol in the fatty alcohol-polyoxyethylene ether sodium sulfate is C12, the mass percentage of fatty alcohol with the carbon chain of C12 in the fatty alcohol-polyoxyethylene ether sodium sulfate is not less than 60%, and the addition number of Ethylene Oxide (EO) is 1.5-2.5.
Specifically, the mass percentage of methyl laurate ethoxylate in the fatty acid methyl ester ethoxylate is not less than 90%, and the average EO addition number is 8-15, preferably 12-15.
Specifically, the mass percentage of deionized water in the antibacterial laundry gel beads is not higher than 30%.
Specifically, the ratio of the fatty alcohol polyoxyethylene ether sodium sulfate to the fatty acid methyl ester ethoxylate to the lauric acid monoglyceride is controlled to be 6+/-0.1:2+/-0.1:1.
Specifically, the solvent is at least one of propylene glycol, glycerol and ethylene glycol.
The application has the advantages that:
(1) The laundry gel beads can effectively improve the addition amount of the fatty alcohol-polyoxyethylene ether sodium sulfate through formula adjustment, and a plurality of laboratory experiments show that the formula contains more than 30% of fatty alcohol-polyoxyethylene ether sodium sulfate and can effectively inhibit bacteria such as staphylococcus aureus. And thirdly, by adding higher water content, a small amount of solvent and nonionic surfactant, the solubility of the formula is improved, and the gelation of the formula is effectively improved.
(2) The formula can effectively reduce the addition amount of the solvent and improve the upper limit of water by adjusting the corresponding carbon chain, EO addition and addition proportion of the fatty alcohol polyoxyethylene ether sodium sulfate, the fatty acid methyl ester ethoxylate addition product and the lauric acid monoglyceride.
(3) The amphoteric surfactant cocoamidopropyl betaine has relatively excellent antibacterial performance, excellent solubility and strong compatibility with anionic surfactants and nonionic surfactants; the alkyl glycoside is easy to dilute, has no gel phenomenon, can be compounded with any type of surfactant, has obvious synergistic effect, and has strong broad-spectrum antibacterial activity.
Example 1:
in the embodiment, the antibacterial laundry gel comprises the following components in percentage by mass: 30% of fatty alcohol polyoxyethylene ether sodium sulfate; dodecyl benzene sulfonic acid 16%; 10% of fatty acid methyl ester ethoxylate; 5% of lauric acid monoglyceride; cocoamidopropyl betaine 5%; triethanolamine 1%; glycerol 3%; 30% of deionized water.
In the embodiment, the carbon chain of fatty alcohol in the fatty alcohol-polyoxyethylene ether sodium sulfate is C12, the mass percentage of fatty alcohol with the carbon chain of C12 in the fatty alcohol-polyoxyethylene ether sodium sulfate is 70%, and the average EO addition number is 1.5; the mass percent of methyl laurate ethoxylate in the fatty acid methyl ester ethoxylate is 95 percent, and the average EO addition number is 12.
Example 2:
in the embodiment, the antibacterial laundry gel comprises the following components in percentage by mass: 48% of fatty alcohol polyoxyethylene ether sodium sulfate; dodecyl benzene sulfonic acid 16%; fatty acid methyl ester ethoxylate 16%; 8% of lauric acid monoglyceride; cocoamidopropyl betaine 5%; triethanolamine 1%; glycerol 3%; deionized water 3%.
In the embodiment, the carbon chain of fatty alcohol in the fatty alcohol-polyoxyethylene ether sodium sulfate is C12, the mass percentage of fatty alcohol with the carbon chain of C12 in the fatty alcohol-polyoxyethylene ether sodium sulfate is 70%, and the average EO addition number is 1.5; the mass percent of methyl laurate ethoxylate in the fatty acid methyl ester ethoxylate is 95 percent, and the average EO addition number is 12.
Example 3:
in the embodiment, the antibacterial laundry gel comprises the following components in percentage by mass: 39% of fatty alcohol polyoxyethylene ether sodium sulfate; dodecyl benzene sulfonic acid 16%; 13% of fatty acid methyl ester ethoxylate; 6.5% of lauric acid monoglyceride; cocoamidopropyl betaine 5%; triethanolamine 1%; glycerol 3%; 16.5% of deionized water.
In the embodiment, the carbon chain of fatty alcohol in the fatty alcohol-polyoxyethylene ether sodium sulfate is C12, the mass percentage of fatty alcohol with the carbon chain of C12 in the fatty alcohol-polyoxyethylene ether sodium sulfate is 70%, and the average EO addition number is 1.5; the mass percent of methyl laurate ethoxylate in the fatty acid methyl ester ethoxylate is 95 percent, and the average EO addition number is 12.
Example 4:
in the embodiment, the antibacterial laundry gel comprises the following components in percentage by mass: 30% of fatty alcohol polyoxyethylene ether sodium sulfate; 5% of dodecylbenzenesulfonic acid; 10% of fatty acid methyl ester ethoxylate; alkyl glycoside 10%; 5% of lauric acid monoglyceride; 15% of cocamidopropyl betaine; 10% of triethanolamine; propylene glycol 5%; 10% of deionized water.
In the embodiment, the carbon chain of fatty alcohol in the fatty alcohol-polyoxyethylene ether sodium sulfate is C12, the mass percentage of fatty alcohol with the carbon chain of C12 in the fatty alcohol-polyoxyethylene ether sodium sulfate is 70%, and the average EO addition number is 2.5; the mass percent of methyl laurate ethoxylate in the fatty acid methyl ester ethoxylate is 100 percent, and the average EO addition number is 15.
Example 5:
in the embodiment, the antibacterial laundry gel comprises the following components in percentage by mass: 30% of fatty alcohol polyoxyethylene ether sodium sulfate; 10.5% of dodecylbenzenesulfonic acid; 10% of fatty acid methyl ester ethoxylate; alkyl glycoside 20%; 5% of lauric acid monoglyceride; 10% of cocamidopropyl betaine; 10% of triethanolamine; ethylene glycol 5.5%; deionized water 5%.
In the embodiment, the carbon chain of fatty alcohol in the fatty alcohol-polyoxyethylene ether sodium sulfate is C12, the mass percentage of fatty alcohol with the carbon chain of C12 in the fatty alcohol-polyoxyethylene ether sodium sulfate is 70%, and the average EO addition number is 2; the mass percent of methyl laurate ethoxylate in the fatty acid methyl ester ethoxylate is 90 percent, and the average EO addition number is 8.
Comparative example 1:
in the embodiment, the antibacterial laundry gel comprises the following components in percentage by mass: 24% of fatty alcohol polyoxyethylene ether sodium sulfate; 10.5% of dodecylbenzenesulfonic acid; fatty acid methyl ester ethoxylate 8%; alkyl glycoside 20%; 4% of lauric acid monoglyceride; 10% of cocamidopropyl betaine; triethanolamine 5.5%; glycerol 4%; 14% of deionized water.
In the embodiment, the carbon chain of fatty alcohol in the fatty alcohol-polyoxyethylene ether sodium sulfate is C12, the mass percentage of fatty alcohol with the carbon chain of C12 in the fatty alcohol-polyoxyethylene ether sodium sulfate is 70%, and the average EO addition number is 1.5; the mass percent of methyl laurate ethoxylate in the fatty acid methyl ester ethoxylate is 95 percent, and the average EO addition number is 12.
Comparative example 2:
in the embodiment, the antibacterial laundry gel comprises the following components in percentage by mass: 30% of fatty alcohol polyoxyethylene ether sodium sulfate; dodecyl benzene sulfonic acid 16%; 10% of fatty acid methyl ester ethoxylate; 5% of lauric acid monoglyceride; cocoamidopropyl betaine 5%; triethanolamine 1%; glycerol 3%; 30% of deionized water.
In the embodiment, the carbon chain of fatty alcohol in the fatty alcohol-polyoxyethylene ether sodium sulfate is C15, the mass percentage of fatty alcohol with the carbon chain of C15 in the fatty alcohol-polyoxyethylene ether sodium sulfate is 70%, and the average EO addition number is 1.5; the mass percent of methyl laurate ethoxylate in the fatty acid methyl ester ethoxylate is 95 percent, and the average EO addition number is 12.
Comparative example 3:
in the embodiment, the antibacterial laundry gel comprises the following components in percentage by mass: 30% of fatty alcohol polyoxyethylene ether sodium sulfate; dodecyl benzene sulfonic acid 16%; 10% of fatty acid methyl ester ethoxylate; 5% of lauric acid monoglyceride; cocoamidopropyl betaine 5%; triethanolamine 1%; glycerol 3%; 30% of deionized water.
In the embodiment, the carbon chain of fatty alcohol in the fatty alcohol-polyoxyethylene ether sodium sulfate is C12, the mass percentage of fatty alcohol with the carbon chain of C12 in the fatty alcohol-polyoxyethylene ether sodium sulfate is 50%, and the average EO addition number is 1.5; the mass percent of methyl laurate ethoxylate in the fatty acid methyl ester ethoxylate is 95 percent, and the average EO addition number is 12.
Comparative example 4:
in the embodiment, the antibacterial laundry gel comprises the following components in percentage by mass: 30% of fatty alcohol polyoxyethylene ether sodium sulfate; 11% of dodecylbenzenesulfonic acid; 10% of fatty acid methyl ester ethoxylate; 5% of lauric acid monoglyceride; cocoamidopropyl betaine 5%; triethanolamine 1%; glycerol 3%; 35% of deionized water.
In the embodiment, the carbon chain of fatty alcohol in the fatty alcohol-polyoxyethylene ether sodium sulfate is C12, the mass percentage of fatty alcohol with the carbon chain of C12 in the fatty alcohol-polyoxyethylene ether sodium sulfate is 70%, and the average EO addition number is 1.5; the mass percent of methyl laurate ethoxylate in the fatty acid methyl ester ethoxylate is 95 percent, and the average EO addition number is 12.
Comparative example 5:
in the embodiment, the antibacterial laundry gel comprises the following components in percentage by mass: 30% of fatty alcohol polyoxyethylene ether sodium sulfate; dodecyl benzene sulfonic acid 16%; 10% of fatty acid methyl ester ethoxylate; 5% of lauric acid monoglyceride; cocoamidopropyl betaine 5%; triethanolamine 1%; glycerol 3%; 30% of deionized water.
In the embodiment, the carbon chain of fatty alcohol in the fatty alcohol-polyoxyethylene ether sodium sulfate is C12, the mass percentage of fatty alcohol with the carbon chain of C12 in the fatty alcohol-polyoxyethylene ether sodium sulfate is 70%, and the average EO addition number is 1.5; the mass percent of methyl laurate ethoxylate in the fatty acid methyl ester ethoxylate is 80 percent, and the average EO addition number is 12.
Comparative example 6:
in the embodiment, the antibacterial laundry gel comprises the following components in percentage by mass: 30% of fatty alcohol polyoxyethylene ether sodium sulfate; dodecyl benzene sulfonic acid 16%; 10% of fatty acid methyl ester ethoxylate; 5% of lauric acid monoglyceride; cocoamidopropyl betaine 5%; triethanolamine 1%; glycerol 3%; 30% of deionized water.
In the embodiment, the carbon chain of fatty alcohol in the fatty alcohol-polyoxyethylene ether sodium sulfate is C12, the mass percentage of fatty alcohol with the carbon chain of C12 in the fatty alcohol-polyoxyethylene ether sodium sulfate is 70%, and the average EO addition number is 1.5; the mass percent of methyl laurate ethoxylate in the fatty acid methyl ester ethoxylate is 95 percent, and the average EO addition number is 6.
Comparative example 7:
in the embodiment, the antibacterial laundry gel comprises the following components in percentage by mass: 30% of fatty alcohol polyoxyethylene ether sodium sulfate; dodecyl benzene sulfonic acid 16%; 10% of fatty acid methyl ester ethoxylate; 5% of lauric acid monoglyceride; cocoamidopropyl betaine 5%; triethanolamine 1%; glycerol 3%; 30% of deionized water.
In the embodiment, the carbon chain of fatty alcohol in the fatty alcohol-polyoxyethylene ether sodium sulfate is C12, the mass percentage of fatty alcohol with the carbon chain of C12 in the fatty alcohol-polyoxyethylene ether sodium sulfate is 70%, and the average EO addition number is 1.5; the mass percent of methyl laurate ethoxylate in the fatty acid methyl ester ethoxylate is 95 percent, and the average EO addition number is 18.
Comparative example 8:
in the embodiment, the antibacterial laundry gel comprises the following components in percentage by mass: 30% of fatty alcohol polyoxyethylene ether sodium sulfate; dodecyl benzene sulfonic acid 16%; fatty acid methyl ester ethoxylate 5%; 10% of lauric acid monoglyceride; cocoamidopropyl betaine 5%; triethanolamine 1%; glycerol 3%; 30% of deionized water.
In the embodiment, the carbon chain of fatty alcohol in the fatty alcohol-polyoxyethylene ether sodium sulfate is C12, the mass percentage of fatty alcohol with the carbon chain of C12 in the fatty alcohol-polyoxyethylene ether sodium sulfate is 70%, and the average EO addition number is 1.5; the mass percent of methyl laurate ethoxylate in the fatty acid methyl ester ethoxylate is 95 percent, and the average EO addition number is 12.
See in particular table 1:
in table 1, a is sodium fatty alcohol polyoxyethylene ether sulfate, B is dodecylbenzenesulfonic acid, C is fatty acid methyl ester ethoxylate, D is alkyl glycoside, E is lauric acid monoglyceride, F is cocamidopropyl betaine, G is triethanolamine, H is solvent, I is deionized water, J is carbon chain of fatty alcohol in sodium fatty alcohol polyoxyethylene ether sulfate, K is weight percent of fatty alcohol in sodium fatty alcohol polyoxyethylene ether sulfate, L is average EO addition number of sodium fatty alcohol polyoxyethylene ether sulfate, M is weight percent of lauric acid methyl ester ethoxylate in fatty acid methyl ester ethoxylate, and N is average EO addition number of fatty acid methyl ester ethoxylate.
Several laundry beads were prepared according to the ingredient contents of example 1 and comparative examples 1 to 8 in table 1 for testing stability (including film and internal materials), detergency, bacteriostasis rate, water solubility;
wherein, the stability evaluation is carried out by taking 3 laundry beads prepared by the above, placing in an oven at 25deg.C and 50deg.C for 30 days, and observing whether there is a change after recovering to normal temperature; detergency test the detergency of the laundry gel beads of the present application was measured according to GB/T13174-2008 determination of detergency and cycle washing Performance of detergents for clothing; antibacterial rate detection according to QB/T2738-2012 evaluation method of antibacterial effect of daily chemical products, selecting staphylococcus aureus as a strain, and detecting the antibacterial rate of the laundry gel beads; water solubility test 1g of the formulation was dissolved in 99g of water and the solution was stirred for dissolution and the final condition of the solution was observed.
The specific results are shown in Table 2:
as can be seen from the combination of example 1 and comparative example 1, the ability of the bead formulation to inhibit staphylococcus aureus was significantly reduced when the mass percentage of the fatty alcohol polyoxyethylene ether sodium sulfate in each laundry bead was less than 30%, i.e., the formulation of the present application was used.
As can be seen from the combination of example 1 and comparative example 2, the carbon chain of the fatty alcohol in the sodium fatty alcohol-polyoxyethylene ether sulfate is preferably C12, and when the carbon chain of the fatty alcohol is not C12, the viscosity of the gel bead formulation solution is higher, the freezing point is higher, and thus the gel beads are difficult to package into a film, are not easy to dissolve in water, and do not accord with the appearance of transparent liquid.
As can be seen from the combination of example 1 and comparative example 3, the carbon chain of the fatty alcohol in the fatty alcohol-polyoxyethylene ether sodium sulfate is C12, and the mass percentage of the fatty alcohol with the carbon chain of C12 in the fatty alcohol-polyoxyethylene ether sodium sulfate cannot be lower than 60%, when the mass percentage is lower than 60%, the viscosity of the gel bead formula solution is larger, the freezing point is higher, and the gel beads are difficult to package into films, are not easy to dissolve in water, and do not accord with the appearance of transparent liquid.
As can be seen from the combination of example 1 and comparative example 4, the mass percentage of deionized water in each bacteriostatic laundry gel is not higher than 30%, and when the mass percentage of deionized water is higher than 30%, the gel membrane cannot be kept stable, and breakage easily occurs.
As can be seen from the combination of example 1 and comparative examples 5 to 7, the mass percentage of methyl laurate ethoxylate in the fatty acid methyl ester ethoxylate is not less than 90%, the average EO addition number is preferably 8 to 15, and the viscosity of the laundry gel bead formulation solution is higher when the mass percentage of methyl laurate ethoxylate in the fatty acid methyl ester ethoxylate is less than 90%; when the average EO addition number is less than 8 or more than 15, the bead formulation is less water-soluble.
As is clear from the combination of example 1 and comparative example 8, when the ratio of sodium fatty alcohol polyoxyethylene ether sulfate, fatty acid methyl ester ethoxylate, and lauric acid monoglyceride is out of the range of 6.+ -. 0.1:2.+ -. 0.1:1, the gel membrane is not stable and breakage occurs when the moisture content of the formulation solution is kept unchanged.
The application also discloses a preparation method of the antibacterial laundry gel bead, which comprises the following steps:
1) Cleaning and sterilizing equipment such as a reaction kettle, a taking tool, a pre-storage container, a weighing container and the like, and checking whether the equipment operates normally or not;
2) Adding deionized water, a solvent, fatty acid methyl ester ethoxylate, cocamidopropyl betaine, alkyl glycoside and lauric acid monoglyceride into a reaction kettle in sequence according to the formula amount, controlling the reaction temperature to be about 40 ℃ according to the prior art, and then mixing and stirring to obtain a solution A;
3) Adding dodecylbenzene sulfonic acid and triethanolamine into the solution A according to the formula, stirring and neutralizing, and controlling the pH to be approximately equal to 8 according to the existing process to obtain a solution B;
4) Slowly adding sodium fatty alcohol-polyoxyethylene ether sulfate into the solution B according to the formula amount, and stirring while adding to prevent gel to obtain a solution C;
5) And (3) standing the solution C for defoaming, cooling to room temperature, and packaging.
Any embodiment of the present application may be used as an independent technical solution, or may be combined with other embodiments. All patents and publications mentioned in the specification are indicative of those of ordinary skill in the art to which this application pertains and which may be applied. All patents and publications cited herein are hereby incorporated by reference to the same extent as if each individual publication were specifically and individually indicated to be incorporated by reference. The application may be practiced without any element or elements, limitation or limitations, which are not expressly described herein. The terms and expressions which have been employed herein are used as terms of description and not of limitation, and there is no intention in the use of such terms and expressions of excluding any equivalents of the features shown and described, but it is recognized that various modifications are possible within the scope of the application and of the claims. It is to be understood that the embodiments described herein are illustrative of the various embodiments and features of the application and that modifications and variations may be made by those skilled in the art in light of the teachings of this application and are to be considered as falling within the scope of the application and the appended claims.
Claims (4)
1. The antibacterial laundry gel bead is characterized by comprising the following components in percentage by mass:
30 to 48 percent of fatty alcohol polyoxyethylene ether sodium sulfate
5 to 16 percent of dodecyl benzene sulfonic acid
10 to 16 percent of fatty acid methyl ester ethoxylate
0 to 20 percent of alkyl glycoside
Lauric acid monoglyceride 5-8%
5 to 15 percent of cocoamidopropyl betaine
Triethanolamine 1-10%
3 to 5 percent of solvent
Balance of deionized water
The carbon chain of fatty alcohol in the fatty alcohol polyoxyethylene ether sodium sulfate is C12;
the mass percentage of the fatty alcohol with the carbon chain of C12 in the fatty alcohol polyoxyethylene ether sodium sulfate is not less than 60%, and the average EO addition number is 1.5-2.5;
the mass percentage of the lauric acid methyl ester ethoxylate in the fatty acid methyl ester ethoxylate is not less than 90 percent, and the average EO addition number is 8-15;
the mass percentage of the deionized water is not higher than 30%;
the proportion of the fatty alcohol polyoxyethylene ether sodium sulfate to the fatty acid methyl ester ethoxylate to the lauric acid monoglyceride is 6+/-0.1:2+/-0.1:1;
the solvent is at least one of propylene glycol, glycerol and ethylene glycol.
2. The bacteriostatic laundry gel according to claim 1, comprising the following components in percentage by mass:
fatty alcohol polyoxyethylene ether sodium sulfate 39%
Dodecyl benzene sulfonic acid 16%
Fatty acid methyl ester ethoxylate 13%
Lauric acid monoglyceride 6.5%
Cocoamidopropyl betaine 5%
Triethanolamine 1%
Glycerol 3%
And the balance of deionized water.
3. A bacteriostatic laundry gel according to claim 1, wherein the mass percent of methyl laurate ethoxylate in said fatty acid methyl ester ethoxylate is not less than 90% and the average EO addition number is from 12 to 15.
4. A method of preparing a bacteriostatic laundry bead according to any one of claims 1 to 3, comprising the steps of:
adding deionized water, a solvent, fatty acid methyl ester ethoxylate, cocamidopropyl betaine, alkyl glycoside and lauric acid monoglyceride into a reaction kettle in sequence according to the formula amount, controlling the reaction temperature at 40 ℃, and then mixing and stirring to obtain a solution A;
adding dodecylbenzene sulfonic acid and triethanolamine into the solution A according to the formula amount, stirring and neutralizing, and controlling the pH to be approximately equal to 8 to obtain a solution B;
weighing fatty alcohol polyoxyethylene ether sodium sulfate according to the formula amount, slowly adding the fatty alcohol polyoxyethylene ether sodium sulfate into the solution B, and stirring the fatty alcohol polyoxyethylene ether sodium sulfate while adding the fatty alcohol polyoxyethylene ether sodium sulfate to obtain a solution C;
and (3) standing the solution C for defoaming, cooling to room temperature, and packaging.
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003171700A (en) * | 2001-09-26 | 2003-06-20 | Lion Corp | Liquid detergent composition for clothes |
| CN107970939A (en) * | 2017-12-14 | 2018-05-01 | 江苏钟山化工有限公司 | A kind of fatty acid methyl ester ethoxylation catalyst and its preparation method and purposes |
| CN111088129A (en) * | 2018-10-23 | 2020-05-01 | 中国石油化工股份有限公司 | Detergent coagulated bead containing thermoplastic polyvinyl alcohol film and preparation method thereof |
| CN111471543A (en) * | 2020-05-27 | 2020-07-31 | 福建恒安集团有限公司 | Close-fitting clothes washing gel bead and preparation method thereof |
| CN111704965A (en) * | 2020-07-14 | 2020-09-25 | 福建恒安集团有限公司 | Washing gel bead with 8 times of cleaning power and preparation method thereof |
| EP3744819A1 (en) * | 2019-05-26 | 2020-12-02 | Fama Holding AG | Composition with alkoxylated fatty acids |
| CN112646166A (en) * | 2020-12-22 | 2021-04-13 | 赞宇科技集团股份有限公司 | Method for rapidly improving solubility of sodium fatty alcohol-polyoxyethylene ether sulfate |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102012208286A1 (en) * | 2012-05-16 | 2013-11-21 | Henkel Ag & Co. Kgaa | Low-water, liquid detergent with surfactants derived from renewable raw materials |
-
2021
- 2021-12-29 CN CN202111636549.6A patent/CN114231362B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003171700A (en) * | 2001-09-26 | 2003-06-20 | Lion Corp | Liquid detergent composition for clothes |
| CN107970939A (en) * | 2017-12-14 | 2018-05-01 | 江苏钟山化工有限公司 | A kind of fatty acid methyl ester ethoxylation catalyst and its preparation method and purposes |
| CN111088129A (en) * | 2018-10-23 | 2020-05-01 | 中国石油化工股份有限公司 | Detergent coagulated bead containing thermoplastic polyvinyl alcohol film and preparation method thereof |
| EP3744819A1 (en) * | 2019-05-26 | 2020-12-02 | Fama Holding AG | Composition with alkoxylated fatty acids |
| CN111471543A (en) * | 2020-05-27 | 2020-07-31 | 福建恒安集团有限公司 | Close-fitting clothes washing gel bead and preparation method thereof |
| CN111704965A (en) * | 2020-07-14 | 2020-09-25 | 福建恒安集团有限公司 | Washing gel bead with 8 times of cleaning power and preparation method thereof |
| CN112646166A (en) * | 2020-12-22 | 2021-04-13 | 赞宇科技集团股份有限公司 | Method for rapidly improving solubility of sodium fatty alcohol-polyoxyethylene ether sulfate |
Non-Patent Citations (4)
| Title |
|---|
| "Study on the interaction of alkaline protease with main surfactants in detergent";Jian Zhang 等;《Colloid Polym Sci》;第294卷(第2期);第247-255页 * |
| "洗衣凝珠成分分析";黄晴 等;《中国洗涤用品工业》(第12期);第89-93页 * |
| "脂肪酸甲酯磺酸钠与油脂乙氧基化物磺酸钠 /脂肪醇醚硫酸钠的复配性能研究";毛雪彬 等;《中国洗涤用品工业》(第2期);第43-47页 * |
| 改性油脂乙氧基化物在洗衣凝珠配方中的应用;汪传新;张威;王丰收;;日用化学品科学(第09期);第38-41页 * |
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