CN1142223C - Prepn of anti-fake meat seal mark and identifying method - Google Patents
Prepn of anti-fake meat seal mark and identifying method Download PDFInfo
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- CN1142223C CN1142223C CNB011283947A CN01128394A CN1142223C CN 1142223 C CN1142223 C CN 1142223C CN B011283947 A CNB011283947 A CN B011283947A CN 01128394 A CN01128394 A CN 01128394A CN 1142223 C CN1142223 C CN 1142223C
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- false proof
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Abstract
The present invention discloses a method for preparing an anti-counterfeit meat stamp mark preparation and an identification method thereof. Medicament in a dienol base class or a derivative of the medicament is used as a main medicine, and anti-counterfeit substrate powder is prepared from the main medicine, mucilage and a coloring agent. The anti-counterfeit substrate powder is dissolved in a solvent prepared from preservative, humectant and distilled water for forming an anti-counterfeit substrate for stamps or marks. Only moisture absorption paper is required to be pasted on the preparation during identification. After the moisture absorption paper is taken off, an identifying agent can be dripped on the moisture absorption paper for identification. Stamp marks are more clear and lasting by the anti-counterfeit substrate. Even if strokes of the marks are blurry, the marks can be identified by the identifying agent. The method has the identification advantages of no need of any instrument, less dosage of reagents, portability, easy operation, rapidness and accuracy. Obvious color reaction can be observed by directly dripping identifying reagents on a sampled sample.
Description
Technical field:
The present invention relates to a kind of manufacturing and discriminating of security stamp sign, especially a kind of dienol base class medicine or derivatives thereof that contains is the false proof preparation and the discrimination method of main ingredient.
Background technology:
At present, the pig ketoboidies that circulates on the market and cutting meat all is stamped the identifier that examines seal mark or meat product distributors of national law enforcement agency, and used seal roughly has three: (1) chop drum; (2) font seal; (3) acupuncture seal.Habitual reagent is the edible coloring agent famille rose basically.Because meat product is soft type, moistening material, have certain fluctuation, deformability and wetting property, add and move, transport, rub or factor that other are artificial, often cause the seal mark stroke fuzzy, be difficult to differentiate the true and false of seal mark.Current, the needle-penetrating seal of use, though increased certain degree of difficulty to the counterfeiter, seal itself has many defectives, for example operation effort, labour intensity is big; Destroy the complete attractive in appearance of meat product; The small area cube meat can't be printed etc.For a long time, departments such as country's tax, industry and commerce, trade, institution for supervision over animal epidemic prevention, and meat product distributors are to the identification of dummy seal sign, lack identification of means quick, authoritative, science, we can say, the false making of mark or sealing of inspection remains incessant after repeated prohibition, and brings heavy losses for country or meat product distributors.
Summary of the invention:
It is clear lasting to the purpose of this invention is to provide a kind of seal mark that can make, differentiating does not need instrument, easy and simple to handle, the preparation of anti-fake meat seal mark preparation and discrimination method fast and accurately, be intended to expand the frontier of anti-false sign, develop in depth and breadth to material object is false proof from package anti-fake, it is sorry to remedy the application of technology aspect the meat product sign such as font evaluation, laser anti-counterfeit trade mark, acupuncture seal.
The technical solution used in the present invention is:
1, the preparation of false proof preparation:
(1) organic compound that will contain the dienol group is that the tinting material of mucilage, the 60-79% of stealthy agent 20-35% and 0.1-3.0% stirs and makes false proof matrix pulvis by weight proportion;
(2) sanitas with 0.10-0.25% is dissolved in the distilled water of 60-80%, and the wetting Agent for Printing Inks that adds 10-20% is again made false proof matrix solvent;
(3) ratio of false proof matrix pulvis in 1: 3 is dissolved in the false proof matrix solvent, constitutes thick false proof preparation jointly.
2, differentiating solvent and discrimination method:
(1) differentiating solvent selects to produce with the group in the false proof preparation saline oxidizing agent solution of color reaction, and the present invention selects silver nitrate solution or phosphorus molybdenum acid solution for use;
(2) discrimination method: stick on the security stamp sign with moistening thieving paper, allow the false proof composition on the seal mark be penetrated on the thieving paper, can produce the saline oxidizing agent solution of color reaction then with differentiating solvent with group in the false proof matrix, aim at the thieving paper titration discriminating that develops the color.
3, the selection of various raw materials:
Tinting material is selected famille rose or amaranth for use, and content is the 60-79% of false proof matrix pulvis.
Stealthy agent promptly contains the medicine or derivatives thereof of dienol group, selects vitamins C, saccharosonic acid or L-SODIUM ASCORBATE for use, and content is the 20-35% of false proof matrix pulvis.
Sanitas is selected Tegosept M, phenylformic acid or Sodium Benzoate for use, and content is the 0.10-0.25% of false proof matrix solvent.
Wetting Agent for Printing Inks is selected propylene glycol, sorbyl alcohol or glycerol for use, and content is the 10-20% of false proof matrix solvent.
Mucilage is selected sodium polyacrylate, beeswax, sodium alginate or Xylo-Mucine for use, and content is the 1.0-3.0% of false proof matrix pulvis.
False proof preparation and discrimination method thereof that to the invention provides a kind of derivative that contains dienol base class medicine or this medicine be main ingredient.False proof preparation is by false proof matrix pulvis and false proof matrix solvent composition; Differentiating solvent is a kind of salt.The discriminating principle is that the dienol group in the stealthy agent molecule has very strong reductibility, can be produced color reaction by the differentiating solvent oxidation.Reaction formula is: (is example with the vitamins C):
The nontoxic odorless of this false proof matrix has no side effect, and meets the food sanitation requirement.Tinting material system adopts standard food additive famille rose.Stealthy agent is a kind of medicine or derivatives thereof that contains the dienol group, such medicine is white or little yellow crystalline powder, and it belongs to the low-molecular-weight organic compound of keeping human body normal physiological function, and its aqueous ph value is 5.7-7.0, approaching with the pH value of meat product, do not influence the color and luster of meat.With the vitamins C is example, the dosage for oral administration of expression is 50-100mg/ time in the Pharmacopoeia of the People's Republic of China (in 2000 version), and every part of false proof matrix pulvis of the present invention is 5 grams, include below stealthy agent 2 grams, the minimum security stamp sign that can make 800 diameter 3.5-4.5cm, so each seal mark contains below this stealth agent 2.5mg, be lower than 20-40 times of the therapeutic dose of stipulating in the pharmacopeia.And the dosage that the therapeutic dose of this stealth agent is following can be considered health substance, is one of nutritive factor that earns a bare living, so no matter consider that from dosage and residual aspect can not have side effects to human body, real is safe and reliable medicine.
Additive sodium benzoate, glycerol, Xylo-Mucine in this false proof matrix; stealthy agent in the matrix is played important stabilization; they can form layer protecting film, stop stealthy agent to participate in the biochemical reactions of meat prematurely, have delayed the lifetime of stealthy agent.Sodium Benzoate, glycerol are defined as sanitas and solvent in the Pharmacopoeia of the People's Republic of China (in 2000 version).Xylo-Mucine is a mucilage.The maximum usage quantity that Sodium Benzoate, Xylo-Mucine are stipulated in the GB2760-86 of People's Republic of China (PRC) standard is respectively 1.0g/kg and 5.0g/kg.Consumption of the present invention is well below this index.Glycerol is as solvent or lubricant, and its dosage is unrestricted.
In the preparation process of this false proof preparation, do not produce waste gas, not blowdown thing, no byproduct meets the environmental protection standard requirement fully.
False proof matrix of the present invention has been added the water-soluble, film-forming auxiliary agent on the one hand, makes seal mark clearer lasting, has overcome simple carmine sign stroke and has soaked into fuzzy shortcoming easily; Owing to added the false proof factor,, also can differentiate out on the other hand by differentiating solvent even the sign stroke is smudgy.Use the present invention, can save great amount of manpower and material resources and financial resources, can reduce and pursue the false making den, many troubles that evidence obtaining links such as verification false making instrument are brought, the stealthy factor that only needs to check from anti-false sign can be told truth from falsehood, and reaches the purpose of eradicating the adulteration behavior.Discriminating advantage of the present invention is without any need for instrument, directly is titrated on the sample of taking with identification reagent, promptly can be observed the obvious color reaction.Reagent dosage is few, and is easy to carry, easy and simple to handle, quick, accurate.
Technical process of the present invention is:
Production site and equipment requirements are not high, 40m
2Factory building, a stirrer, a collection of common appearance tool, packing and wrapping tool, the factory building cleaning, flyproof is dustproof to get final product.
Raw material sources of the present invention are abundant, and are cheap:
The false proof matrix pulvis of every kg can be distributed into 200 parts below 50 yuan, every part 5 gram, 0.25 yuan/part of cost.0.03 yuan of every part material packing charge, workshop are taken 0.02 yuan, 0.02 yuan of enterprise management expense, and the quota cost of every part of false proof matrix pulvis is: 0.25+0.03+0.02+0.02=0.32 unit
2.5 yuan of the false proof matrix solvent of every 1000ml raw materials cost by every part of 15ml, can be distributed into 66 parts, 0.04 yuan every part, whenever packagedly take 0.10 yuan, the workshop is taken 0.02 yuan, 0.02 yuan of enterprise management expense, the quota cost of every part of false proof matrix solvent is: 0.04+0.10+0.02+0.02=0.18 unit.
The quota cost of every part of false proof preparation, i.e. 0.32+0.18=0.50 unit.
34 yuan of every 1000ml differentiating solvent raw materials cost by every part of 0.5ml, can be distributed into 2000 parts, and 0.02 yuan of every part of raw materials cost whenever packagedly takes 0.04 yuan, and the workshop is taken 0.01 yuan, 0.01 yuan of enterprise management expense.The quota cost of every part of differentiating solvent is: 0.02+0.04+0.01+0.01=0.08 unit
In view of this false proof preparation quota cost is cheap, estimate that the producer of this special control products of production is lucrative, rate of gross profit is more than 35%.
Easy to use, simple to operate, the safety of this false proof preparation:
Get false proof matrix pulvis portion (5 gram), with a (15ml) false proof matrix dissolution with solvents, dip in wooden font seal or chop drum then and get on this false proof soup covers at the pig ketoboidies, cuts meat, also can load onto false proof soup and aim at meat product spray word and become anti-false sign with spray gun.
During discriminating, elder generation dips in wet with common thieving paper (as medicated napkin), hygroscopic paper is covered to stick on the anti-false sign then, takes off thieving paper after about one minute, is titrated on the thieving paper with the 0.5ml differentiating solvent, and stain or blackspot appear in thieving paper.Common famille rose sign does not have this color reaction.
Embodiment:
Embodiment:
Example 1: the preparation of false proof matrix pulvis: get main ingredient vitamins C 34.5 grams, add carmine 63.0 grams, Xylo-Mucine 2.50 grams place stirrer to stir jointly, promptly get the false proof matrix pulvis of 100 grams, are distributed into 20 parts, every part 5 gram.
False proof matrix preparing solvent: get Sodium Benzoate 0.25 gram and place container, add 80ml distilled water, be stirred to Sodium Benzoate and all dissolve, add glycerol 20ml again, stir and promptly get false proof matrix solvent, by every part of 15ml packing, packing gets final product.
The preparation of differentiating solvent: get Silver Nitrate 17.50 grams, place container, add an amount of dissolved in distilled water and become 1000ml solution, promptly get the 0.10mol/L silver nitrate solution, as differentiating solvent, by every part of 0.5ml packing, packing gets final product.
Example 2: the ingredients of false proof matrix pulvis: get main ingredient saccharosonic acid 33 grams and add carmine 65.0 grams, Xylo-Mucine 2.0 grams, place stirrer to stir jointly, promptly get the false proof matrix pulvis of 100 grams, be distributed into 20 parts, every part 5 gram.
False proof matrix preparing solvent: with example 1.
The preparation of differentiating solvent: with example 1.
Claims (8)
1, a kind of preparation method of anti-fake meat seal mark preparation is characterized in that:
(1) be that the organic compound that contains the dienol group of 20-35% is that stealthy agent, weight percentage are that mucilage, the weight percentage of 1.0-3.0% is the tinting material of 60-79% with weight percentage, mixing and stirring is made false proof matrix pulvis;
(2) sanitas is dissolved in the distilled water, adds wetting Agent for Printing Inks again and make false proof matrix solvent, wherein the volumn concentration of distilled water and wetting Agent for Printing Inks is respectively 80% and 20%, and the add-on of sanitas is/100 milliliters of false proof matrix solvents of 0.10-0.25 gram;
(3) false proof matrix pulvis and false proof matrix solvent are dissolved by the proportioning of/3 milliliters of 1 grams, constitute thick false proof preparation jointly.
2, the preparation method of anti-fake meat seal mark preparation according to claim 1 is characterized in that: tinting material is selected amaranth or famille rose for use.
3, the preparation method of anti-fake meat seal mark preparation according to claim 1 is characterized in that: stealthy agent promptly contains the medicine or derivatives thereof of dienol group, selects vitamins C, saccharosonic acid or L-SODIUM ASCORBATE for use.
4, the preparation method of anti-fake meat seal mark preparation according to claim 1 is characterized in that; Mucilage is selected sodium polyacrylate, beeswax, sodium alginate or Xylo-Mucine for use.
5, the preparation method of anti-fake meat seal mark preparation according to claim 1 is characterized in that: sanitas is selected Tegosept M, phenylformic acid or Sodium Benzoate for use.
6, the preparation method of anti-fake meat seal mark preparation according to claim 1 is characterized in that: wetting Agent for Printing Inks is selected propylene glycol, sorbyl alcohol or glycerol for use.
7, the colour developing discrimination method of a kind of anti-fake meat seal mark preparation according to claim 1, it is characterized in that: stick on the security stamp sign with moistening thieving paper, allow the false proof composition on the seal mark be penetrated on the thieving paper, can produce the saline oxidizing agent solution of color reaction then with the group in the false proof matrix with differentiating solvent, aim at the thieving paper titration, the discriminating that develops the color of stain or blackspot appears in thieving paper.
8, the colour developing discrimination method of the false proof preparation of meat security stamp sign according to claim 7 is characterized in that: differentiating solvent is that saline oxidizing agent solution is selected silver nitrate solution or phosphorus molybdenum acid solution for use.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011283947A CN1142223C (en) | 2001-08-28 | 2001-08-28 | Prepn of anti-fake meat seal mark and identifying method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011283947A CN1142223C (en) | 2001-08-28 | 2001-08-28 | Prepn of anti-fake meat seal mark and identifying method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1337427A CN1337427A (en) | 2002-02-27 |
| CN1142223C true CN1142223C (en) | 2004-03-17 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011283947A Expired - Fee Related CN1142223C (en) | 2001-08-28 | 2001-08-28 | Prepn of anti-fake meat seal mark and identifying method |
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| Country | Link |
|---|---|
| CN (1) | CN1142223C (en) |
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2001
- 2001-08-28 CN CNB011283947A patent/CN1142223C/en not_active Expired - Fee Related
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| Publication number | Publication date |
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| CN1337427A (en) | 2002-02-27 |
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