CN114213577A - Isopropyl triolein acyloxy titanate modified acrylic resin and preparation method thereof - Google Patents
Isopropyl triolein acyloxy titanate modified acrylic resin and preparation method thereof Download PDFInfo
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- CN114213577A CN114213577A CN202111615212.7A CN202111615212A CN114213577A CN 114213577 A CN114213577 A CN 114213577A CN 202111615212 A CN202111615212 A CN 202111615212A CN 114213577 A CN114213577 A CN 114213577A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1812—C12-(meth)acrylate, e.g. lauryl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1818—C13or longer chain (meth)acrylate, e.g. stearyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
- C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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Abstract
The invention relates to an isopropyl trioleate acyloxy titanate modified acrylic resin and a preparation method thereof, wherein the isopropyl trioleate acyloxy titanate modified acrylic resin comprises the following components in parts by weight: 10.0-16.0 parts of isopropyl trioleate acyloxy titanate, 3.0-5.0 parts of isoprene, 3.0-6.0 parts of styrene, 2.5-5.0 parts of crosslinking monomer, 0.3-1.0 part of benzoyl peroxide, 20.0-40.0 parts of acrylate hard monomer, 50.0-100.0 parts of acrylate soft monomer, 6.0-15.0 parts of xylene and 100.0-250.0 parts of ethyl acetate; the prepared isopropyl trioleate acyloxy titanate modified acrylic resin has good wear resistance, adhesive force and flexibility, does not need to be added with a scratch-resistant auxiliary agent when being prepared into a coating, and has good scratch resistance.
Description
Technical Field
The invention relates to a modified acrylic resin, in particular to an isopropyl trioleate acyloxy titanate modified acrylic resin and a preparation method thereof, and belongs to the technical field of synthetic resins.
Background
Acrylate resins are a general class of synthetic polymers that, due to their unique advantages: the acrylic resin has the characteristics of light color, high transparency, brightness, fullness, tough coating film, strong adhesive force, corrosion resistance and the like, and is a common coating material. The acrylic resin coating is widely applied to the fields of high-grade consumer goods such as automobiles and the like, and is particularly widely applied to high-grade finishing varnish on the outer layer of an automobile.
However, acrylic coatings can cause defects such as film dulling, fogging, etc. due to insufficient scratch resistance. Currently, the following approaches are generally used to remedy the above drawbacks: 1. inorganic fillers such as glass micropowder and the like are added to enhance the scratch resistance of the outer layer of the paint film; 2. adding an organic silicon auxiliary agent to reduce the surface energy of the paint film so as to reduce the friction coefficient; 3. and (4) waxing and other treatments are carried out on the outer paint film to enhance the surface smoothness. Then, the disadvantages of unstable performance, poor storage stability and the like can occur through an external addition mode.
Chinese patent CN102311526A discloses an acrylic resin, a preparation method thereof and a coating containing the acrylic resin, wherein the acrylic resin comprises an acrylic copolymer, and the acrylic copolymer is composed of structural units represented by I, II, III and IV. The invention also provides a preparation method of the acrylic resin, which comprises the step of polymerizing the monomer 1, the monomer 2, the monomer 3 and the monomer 4 under the action of an initiator to obtain the acrylic resin. The invention also provides a coating which comprises main resin, cross-linked resin, solvent and auxiliary agent, wherein the main resin is the acrylic resin, and the scratch resistance of the coating is mainly provided by silicon.
Disclosure of Invention
In order to solve the technical problems, the invention adopts isopropyl trioleate acyloxy titanate to modify acrylic resin, and the isopropyl trioleate acyloxy titanate is connected with the acrylic resin through a chemical bond, so that the acrylic resin has stable and durable performance, good scratch resistance and good storage stability.
The invention aims to provide an isopropyl trioleate acyloxy titanate modified acrylic resin.
The invention also aims to provide a preparation method of the isopropyl trioleate acyloxy titanate modified acrylic resin.
The invention relates to isopropyl trioleate acyloxy titanate modified acrylic resin, which adopts the following technical scheme: the composition comprises the following components in parts by weight: 10.0-16.0 parts of isopropyl trioleate acyloxy titanate, 3.0-5.0 parts of isoprene, 3.0-6.0 parts of styrene, 2.5-5.0 parts of crosslinking monomer, 0.3-1.0 part of benzoyl peroxide, 20.0-40.0 parts of acrylate hard monomer, 50.0-100.0 parts of acrylate soft monomer, 6.0-15.0 parts of xylene and 100.0-250.0 parts of ethyl acetate.
The acrylate hard monomer is one or a combination of methyl acrylate, methyl methacrylate, isopropyl acrylate, isobornyl acrylate and cyclohexyl methacrylate.
The acrylate soft monomer is one or a combination of butyl methacrylate, isooctyl methacrylate, lauryl methacrylate, tridecyl methacrylate, glycidyl methacrylate, n-octyl methacrylate and stearyl methacrylate.
The crosslinking monomer is hydroxyethyl acrylate, hydroxypropyl acrylate and N- (hydroxymethyl) acrylamide.
The invention provides a preparation method of isopropyl trioleate acyloxy titanate modified acrylic resin, which comprises the following steps:
a. uniformly stirring an acrylate hard monomer, styrene, isoprene and a crosslinking monomer in parts by weight of a formula in a titration tank to obtain a mixed solution I;
b. in a titration tank, uniformly stirring isopropyl trioleate acyloxy titanate, acrylate soft monomer, xylene and 3/4 benzoyl peroxide according to the weight part of the formula to obtain a mixed solution II;
c. adding ethyl acetate and 1/4 benzoyl peroxide into a multifunctional reaction kettle, heating to 78-80 ℃, uniformly stirring, and then simultaneously dropwise adding the mixed solution I and the mixed solution II for 3.5-4.0 hours;
d. and respectively controlling the dropping speed, heating the mixed solution I and the mixed solution II to 86-88 ℃ after the mixed solution I and the mixed solution II are simultaneously dropped, stirring for reaction for 1.5h, detecting and filtering to obtain the isopropyl trioleate acyloxy titanate modified acrylic resin.
The prepared isopropyl trioleate acyloxy titanate modified acrylic resin has good wear resistance, adhesive force and flexibility, does not need to be added with a scratch-resistant auxiliary agent when being prepared into a coating, and has good scratch resistance.
Detailed Description
An isopropyl trioleate acyloxy titanate modified acrylic resin of the invention is further described with reference to the following examples. It is to be understood that the specific embodiments described herein are merely illustrative of the relevant invention and not restrictive of the invention.
The following are specific examples of the present invention, and raw materials, equipments and the like used in the following examples can be obtained by purchasing them unless otherwise specified.
Example 1
An isopropyl trioleate acyloxy titanate modified acrylic resin comprises the following components in parts by weight: 14.0 parts of isopropyl trioleate acyloxy titanate, 4.0 parts of isoprene, 4.0 parts of styrene, 3.0 parts of hydroxyethyl acrylate, 0.6 part of benzoyl peroxide, 30.0 parts of methyl methacrylate, 40.0 parts of butyl methacrylate, 40.0 parts of lauryl methacrylate, 12.0 parts of xylene and 180.0 parts of ethyl acetate.
The preparation method of the isopropyl trioleate acyloxy titanate modified acrylic resin in the embodiment comprises the following steps:
a. uniformly stirring methyl methacrylate, styrene, isoprene and hydroxyethyl acrylate in parts by weight of the formula in a titration tank to obtain a mixed solution I;
b. uniformly stirring isopropyl trioleate acyloxy titanate, butyl methacrylate, lauryl methacrylate, xylene and 3/4 benzoyl peroxide in parts by weight of a formula in a titration tank to obtain a mixed solution II;
c. adding ethyl acetate and 1/4 benzoyl peroxide into a multifunctional reaction kettle, heating to 78-80 ℃, uniformly stirring, and then simultaneously dropwise adding the mixed solution I and the mixed solution II for 3.5 hours;
d. and respectively controlling the dropping speed, heating the mixed solution I and the mixed solution II to 86-88 ℃ after the mixed solution I and the mixed solution II are simultaneously dropped, stirring for reaction for 1.5h, detecting and filtering to obtain the isopropyl trioleate acyloxy titanate modified acrylic resin.
Example 2
An isopropyl trioleate acyloxy titanate modified acrylic resin comprises the following components in parts by weight: 13.0 parts of isopropyl trioleate acyloxy titanate, 3.0 parts of isoprene, 5.0 parts of styrene, 3.5 parts of hydroxypropyl acrylate, 0.7 part of benzoyl peroxide, 40.0 parts of isobornyl acrylate, 50.0 parts of glycidyl methacrylate, 40.0 parts of n-octyl methacrylate, 14.0 parts of xylene and 220.0 parts of ethyl acetate.
The preparation method of the isopropyl trioleate acyloxy titanate modified acrylic resin in the embodiment comprises the following steps:
a. uniformly stirring isobornyl acrylate, styrene, isoprene and hydroxypropyl acrylate in parts by weight of a formula in a titration tank to obtain a mixed solution I;
b. in a titration tank, uniformly stirring isopropyl trioleate acyloxy titanate, glycidyl methacrylate, n-octyl methacrylate, xylene and 3/4 benzoyl peroxide according to the weight part of the formula to obtain a mixed solution II;
c. adding ethyl acetate and 1/4 benzoyl peroxide into a multifunctional reaction kettle, heating to 78-80 ℃, uniformly stirring, and then simultaneously dropwise adding the mixed solution I and the mixed solution II for 4.0 hours;
d. and respectively controlling the dropping speed, heating the mixed solution I and the mixed solution II to 86-88 ℃ after the mixed solution I and the mixed solution II are simultaneously dropped, stirring for reaction for 1.5h, detecting and filtering to obtain the isopropyl trioleate acyloxy titanate modified acrylic resin.
Example 3
An isopropyl trioleate acyloxy titanate modified acrylic resin comprises the following components in parts by weight: 12.0 parts of isopropyl trioleate acyloxy titanate, 5.0 parts of isoprene, 4.0 parts of styrene, 4.0 parts of N- (hydroxymethyl) acrylamide, 0.6 part of benzoyl peroxide, 15.0 parts of methyl methacrylate, 15.0 parts of cyclohexyl methacrylate, 35.0 parts of isooctyl methacrylate, 40.0 parts of stearyl methacrylate, 12.0 parts of xylene and 180.0 parts of ethyl acetate.
The preparation method of the isopropyl trioleate acyloxy titanate modified acrylic resin in the embodiment comprises the following steps:
a. uniformly stirring methyl methacrylate, cyclohexyl methacrylate, styrene, isoprene and N- (hydroxymethyl) acrylamide in parts by weight of a formula in a titration tank to obtain a mixed solution I;
b. in a titration tank, uniformly stirring isopropyl trioleate acyloxy titanate, isooctyl methacrylate, octadecyl methacrylate, xylene and 3/4 benzoyl peroxide according to the weight part of the formula to obtain a mixed solution II;
c. adding ethyl acetate and 1/4 benzoyl peroxide into a multifunctional reaction kettle, heating to 78-80 ℃, uniformly stirring, and then simultaneously dropwise adding the mixed solution I and the mixed solution II for 4.0 hours;
d. and respectively controlling the dropping speed, heating the mixed solution I and the mixed solution II to 86-88 ℃ after the mixed solution I and the mixed solution II are simultaneously dropped, stirring for reaction for 1.5h, detecting and filtering to obtain the isopropyl trioleate acyloxy titanate modified acrylic resin.
Comparative example 1
A conventional modified acrylic resin comprises the following components in parts by weight: 5.0 parts of isoprene, 5.0 parts of styrene, 3.0 parts of hydroxypropyl acrylate, 0.5 part of benzoyl peroxide, 10.0 parts of methyl methacrylate, 20.0 parts of isopropyl acrylate, 35.0 parts of lauryl methacrylate, 35.0 parts of tridecyl methacrylate, 11.0 parts of xylene and 170.0 parts of ethyl acetate.
The preparation method of the conventional modified acrylic resin in the embodiment comprises the following steps:
a. uniformly stirring methyl methacrylate, isopropyl acrylate, styrene, isoprene and hydroxypropyl acrylate in parts by weight of a formula in a titration tank to obtain a mixed solution I;
b. uniformly stirring lauryl methacrylate, tridecyl methacrylate, xylene and 3/4 benzoyl peroxide in parts by weight of the formula in a titration tank to obtain a mixed solution II;
c. adding ethyl acetate and 1/4 benzoyl peroxide into a multifunctional reaction kettle, heating to 78-80 ℃, uniformly stirring, and then simultaneously dropwise adding the mixed solution I and the mixed solution II for 3.5 hours;
d. and respectively controlling the dropping speed, heating the mixed solution I and the mixed solution II to 86-88 ℃ after the mixed solution I and the mixed solution II are simultaneously dropped, stirring for reaction for 1.5h, detecting and filtering to obtain the conventional modified acrylic resin.
And (3) testing performance indexes: the samples of example 1, example 2, example 3 and comparative example 1 above were mixed with a commercial TDI trimer curing agent according to the-OH: -NCO ═ 1:1 was formulated into coatings and their performance was tested separately.
The above examples 1, 2, 3 and comparative example 1 (conventional modified acrylic resin) were subjected to performance index tests according to the relevant national standards, and the test results are shown in table 1.
Table 1: results of Performance testing of samples
It can be seen from table 1 that the scratch resistance, abrasion resistance and drying time of examples 1, 2 and 3 of the present invention are much better than those of comparative example 1 (conventional modified acrylic resin), and the hardness of the examples is also slightly higher than that of comparative example 1 (conventional modified acrylic resin); this shows that the isopropyl trioleate acyloxy titanate modified acrylic resin has good wear resistance and scratch resistance and shorter drying time.
The foregoing description is only a preferred embodiment of the application and is illustrative of the principles of the technology employed; it will be appreciated by a person skilled in the art that the scope of the invention as referred to in the present application is not limited to the embodiments with a specific combination of the above-mentioned features, but also covers other embodiments with any combination of the above-mentioned features or their equivalents without departing from the inventive concept. For example, the above features may be replaced with (but not limited to) features having similar functions disclosed in the present application.
Claims (5)
1. An isopropyl trioleate acyloxy titanate modified acrylic resin is characterized in that: an isopropyl trioleate acyloxy titanate modified acrylic resin comprises the following components in parts by weight: 10.0-16.0 parts of isopropyl trioleate acyloxy titanate, 3.0-5.0 parts of isoprene, 3.0-6.0 parts of styrene, 2.5-5.0 parts of crosslinking monomer, 0.3-1.0 part of benzoyl peroxide, 20.0-40.0 parts of acrylate hard monomer, 50.0-100.0 parts of acrylate soft monomer, 6.0-15.0 parts of xylene and 100.0-250.0 parts of ethyl acetate.
2. The isopropyl trioleate acyloxy titanate modified acrylic resin as claimed in claim 1, wherein: the acrylate hard monomer is one or a combination of methyl acrylate, methyl methacrylate, isopropyl acrylate, isobornyl acrylate and cyclohexyl methacrylate.
3. The isopropyl trioleate acyloxy titanate modified acrylic resin as claimed in claim 1, wherein: the acrylate soft monomer is one or a combination of butyl methacrylate, isooctyl methacrylate, lauryl methacrylate, tridecyl methacrylate, glycidyl methacrylate, n-octyl methacrylate and stearyl methacrylate.
4. The isopropyl trioleate acyloxy titanate modified acrylic resin as claimed in claim 1, wherein: the crosslinking monomer is hydroxyethyl acrylate, hydroxypropyl acrylate and N- (hydroxymethyl) acrylamide.
5. The isopropyl trioleate acyloxy titanate modified acrylic resin as claimed in claim 1, wherein: the preparation method of the isopropyl trioleate acyloxy titanate modified acrylic resin comprises the following steps:
a. uniformly stirring an acrylate hard monomer, styrene, isoprene and a crosslinking monomer in parts by weight of a formula in a titration tank to obtain a mixed solution I;
b. in a titration tank, uniformly stirring isopropyl trioleate acyloxy titanate, acrylate soft monomer, xylene and 3/4 benzoyl peroxide according to the weight part of the formula to obtain a mixed solution II;
c. adding ethyl acetate and 1/4 benzoyl peroxide into a multifunctional reaction kettle, heating to 78-80 ℃, uniformly stirring, and then simultaneously dropwise adding the mixed solution I and the mixed solution II for 3.5-4.0 hours;
d. and respectively controlling the dropping speed, heating the mixed solution I and the mixed solution II to 86-88 ℃ after the mixed solution I and the mixed solution II are simultaneously dropped, stirring for reaction for 1.5h, detecting and filtering to obtain the isopropyl trioleate acyloxy titanate modified acrylic resin.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202111615212.7A CN114213577A (en) | 2021-12-27 | 2021-12-27 | Isopropyl triolein acyloxy titanate modified acrylic resin and preparation method thereof |
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| CN202111615212.7A CN114213577A (en) | 2021-12-27 | 2021-12-27 | Isopropyl triolein acyloxy titanate modified acrylic resin and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114958244A (en) * | 2022-05-06 | 2022-08-30 | 扬州市祥华新材料科技有限公司 | Multi-colour anti-fake electrochemical aluminium |
| CN116606579A (en) * | 2023-03-28 | 2023-08-18 | 湖南子杨建筑装饰材料有限公司 | Floor fireproof paint |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110804133A (en) * | 2019-11-19 | 2020-02-18 | 合众（佛山）化工有限公司 | APAO modified styrene-acrylic emulsion and preparation method thereof |
| CN110903439A (en) * | 2019-11-19 | 2020-03-24 | 合众（佛山）化工有限公司 | Polyether amine derivative modified styrene-acrylic emulsion and preparation method thereof |
| CN112625170A (en) * | 2020-12-18 | 2021-04-09 | 合众（佛山）化工有限公司 | Triplecene derivative modified waterborne acrylic resin and preparation method thereof |
| CN112646084A (en) * | 2020-12-18 | 2021-04-13 | 合众（佛山）化工有限公司 | Tripolyindenone derivative modified waterborne acrylic resin and preparation method thereof |
-
2021
- 2021-12-27 CN CN202111615212.7A patent/CN114213577A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110804133A (en) * | 2019-11-19 | 2020-02-18 | 合众（佛山）化工有限公司 | APAO modified styrene-acrylic emulsion and preparation method thereof |
| CN110903439A (en) * | 2019-11-19 | 2020-03-24 | 合众（佛山）化工有限公司 | Polyether amine derivative modified styrene-acrylic emulsion and preparation method thereof |
| CN112625170A (en) * | 2020-12-18 | 2021-04-09 | 合众（佛山）化工有限公司 | Triplecene derivative modified waterborne acrylic resin and preparation method thereof |
| CN112646084A (en) * | 2020-12-18 | 2021-04-13 | 合众（佛山）化工有限公司 | Tripolyindenone derivative modified waterborne acrylic resin and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114958244A (en) * | 2022-05-06 | 2022-08-30 | 扬州市祥华新材料科技有限公司 | Multi-colour anti-fake electrochemical aluminium |
| CN114958244B (en) * | 2022-05-06 | 2024-01-09 | 扬州市祥华新材料科技有限公司 | Colorful anti-counterfeiting electrochemical aluminum |
| CN116606579A (en) * | 2023-03-28 | 2023-08-18 | 湖南子杨建筑装饰材料有限公司 | Floor fireproof paint |
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