CN114213111A - Aluminum-carbon soaking water inlet for accidents and preparation method - Google Patents

Aluminum-carbon soaking water inlet for accidents and preparation method Download PDF

Info

Publication number
CN114213111A
CN114213111A CN202111657200.0A CN202111657200A CN114213111A CN 114213111 A CN114213111 A CN 114213111A CN 202111657200 A CN202111657200 A CN 202111657200A CN 114213111 A CN114213111 A CN 114213111A
Authority
CN
China
Prior art keywords
parts
lining
carbon
aluminum
water inlet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202111657200.0A
Other languages
Chinese (zh)
Other versions
CN114213111B (en
Inventor
李志义
张程
吴比
王蕊
潘志鹏
王琼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anshan He Feng Refractory Material Co ltd
Original Assignee
Anshan He Feng Refractory Material Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anshan He Feng Refractory Material Co ltd filed Critical Anshan He Feng Refractory Material Co ltd
Priority to CN202111657200.0A priority Critical patent/CN114213111B/en
Publication of CN114213111A publication Critical patent/CN114213111A/en
Application granted granted Critical
Publication of CN114213111B publication Critical patent/CN114213111B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • C04B35/101Refractories from grain sized mixtures
    • C04B35/103Refractories from grain sized mixtures containing non-oxide refractory materials, e.g. carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/50Pouring-nozzles
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3821Boron carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3826Silicon carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/42Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
    • C04B2235/428Silicon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9607Thermal properties, e.g. thermal expansion coefficient

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Ceramic Products (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)

Abstract

The invention relates to an aluminum-carbon impregnated nozzle for accidents and a preparation method thereof. The invention has the beneficial effects that: the invention provides an aluminum-carbon soaking water inlet for accidents and a preparation method thereof, and the aluminum-carbon soaking water inlet is specially used for temporary replacement and use when the water inlet is in an accident, is free from baking, is convenient to use, and can ensure safe and smooth production.

Description

Aluminum-carbon soaking water inlet for accidents and preparation method
Technical Field
The invention relates to the technical field of metallurgical refractory products, in particular to an aluminum-carbon soaking water inlet for accidents and a preparation method thereof.
Background
Submerged entry nozzles for continuous casting are problematic in their use, and when they do not have a replaceable nozzle, they can cause great difficulties in the production of the customer. The common submerged nozzle needs to be baked before being used online, and the baking time is different from 45 to 90 minutes. If the steel is not baked, the steel can be directly put on the line, and the problems of water gap breakage, explosion, perforation, cold steel wall blockage and the like can be caused due to the heat stability problem.
The prior art has the following defects:
1) the existing baking-free submerged nozzle has high manufacturing cost and complex working procedures.
2) The existing baking-free submerged nozzle is inevitably used when not baked, so that the condition of cold steel is inevitably caused, and the flow blockage is caused.
3) The non-baking-free submerged nozzle cannot be replaced in time when an accident occurs, and continuous accidents are easily caused after replacement.
Disclosure of Invention
The invention provides an aluminum-carbon soaking water inlet for accidents and a preparation method thereof, and the aluminum-carbon soaking water inlet is specially used for temporary replacement and use when the water inlet is in an accident, is free from baking, is convenient to use, and can ensure safe and smooth production.
In order to achieve the purpose, the invention adopts the following technical scheme:
the utility model provides an accident is with aluminium carbon soaks water inlet, includes face, inside lining, body, the inside lining is in the body inboard, the face is in the upper end of inside lining and body, the inside lining is two-layer, and the inlayer is thermite layer, and the skin is the carbon-free slime layer.
The body material comprises the following components in parts by weight: 30-55 parts of brown corundum, 28-18 parts of graphite, 8-18 parts of fused quartz, 4-14 parts of alumina micro powder, 1-5 parts of metal silicon powder, 0.5-4 parts of boron carbide and 19-29 parts of a binding agent. The binder adopts 10-20 parts of solid resin powder and 9 parts of liquid resin.
The board material comprises the following components in parts by weight: 30-65 parts of white corundum, 10-20 parts of graphite, 10-30 parts of fused quartz, 5-15 parts of alumina micro powder, 0.1-3 parts of silicon carbide, 0.5-5 parts of boron carbide, and 5-20 parts of resin powder and liquid resin.
The carbon-free cement layer comprises the following materials in parts by weight: 40-50 parts of fused quartz, 20-40 parts of floating beads, 15-30 parts of alumina hollow spheres and 5-20 parts of phenolic resin.
A preparation method of an aluminum-carbon impregnated water inlet for accidents comprises the following steps:
1) firstly, preparing a lining, placing a layering pipe between a lining core mould and a lining mould, adding a thermite between the layering pipe and the lining core mould, adding a carbon-free mud material between the layering pipe and the lining mould, taking out the layering pipe, and forming by using low pressure of 50-70 MPa;
2) and after the lining is produced, performing integral forming, after the outer die is assembled, putting the lining on the middle core die, sequentially putting the plate fabric and the body material, and finally forming by using 90-130 MPa.
3) And (3) baking and curing the formed semi-finished product for 12-24 hours by using an electric heating drying kiln at the temperature of 200-270 ℃, taking out the semi-finished product after curing, and putting the semi-finished product into a cover type kiln for baking treatment.
Compared with the prior art, the invention has the beneficial effects that:
the invention is specially used for temporarily replacing the nozzle when the nozzle has an accident, is free from baking, is convenient to use and can ensure the safe and smooth production.
The invention does not need to be used for a long time, so a slag line is cancelled. Considering the problem of erosion of the covering slag, the product enhances the erosion resistance of the body to the covering slag, namely, under the condition of ensuring the thermal stability, the granularity ratio of the pug is integrally reduced, the body density is improved, and the addition of silicon carbide and boron carbide is increased.
Because the invention is used for temporary standby in accidents and needs no baking for line feeding, in order to prevent the problem of cold steel solidification after the water gap at room temperature is fed on line, the innermost layer of the lining is added with a thermite layer for thermite reaction, the molten steel reaches the reaction temperature when passing through the inner cavity, and the heat is released to further reduce cold steel condensation.
The invention has simple structure, low cost, no baking, quick line feeding, can quickly solve the water gap accident and ensure the safe and smooth production.
Drawings
FIG. 1 is a schematic view of an aluminum carbon impregnated water inlet for accident in accordance with the present invention.
Fig. 2 is an enlarged view of point I in fig. 1.
In the figure: 1-body, 2-carbon-free slurry layer, 3-plate surface and 4-thermite layer.
Detailed Description
The following further describes embodiments of the present invention with reference to the accompanying drawings:
referring to fig. 1-2, the aluminum carbon immersion water inlet for accidents comprises a plate surface 3, an inner lining and a body 1, wherein the inner lining is arranged on the inner side of the body 1, the plate surface 3 is arranged at the upper ends of the inner lining and the body 1, the inner lining is divided into two layers, the inner layer is a thermite layer 4, and the outer layer is a carbon-free mud material layer 2.
Examples bulk materials are shown in table 1; example panel materials are shown in table 2; examples carbon-free pug layer materials are shown in table 3.
Table 1 examples bulk materials
Raw materials Example 1 (parts) Example 2 (parts) Example 3 (parts) Example 4 (parts)
From 36#、80#Brown corundum with grain size of F180 31 40 45 50
+ 895-198 graphite 19 25 26 23
Fused quartz 10 15 17 25
Alumina micropowder 5 10 12 9
98 metal silicon powder 2 3 5 4
Boron carbide 1 3 3.5 2
Binding agents 20 25 24 26
Table 2 examples example panel materials
Raw materials Example 1 (parts) Example 2 (parts) Example 3 (parts) Example 4 (parts)
White corundum 35 45 60 50
+ 898-198 graphite 12 15 18 13
Fused quartz 11 16 28 25
Alumina micropowder 6 13 14 8
Silicon carbide 2.5 3 0.5 0.9
Boron carbide 3.5 2 4.5 3
Resin powder and liquid resin 6 18 15 10
Table 3 examples carbon-free pug layer materials
Figure BDA0003446037080000031
Figure BDA0003446037080000041
The embodiment provides a preparation method of an aluminum-carbon impregnated water inlet for accidents, which comprises the following steps:
1) preparing mud materials: after the ingredients are mixed and are kept still for 24 hours in the constant-temperature constant-humidity material warehouse, the molding step is carried out in a constant-temperature constant-humidity workshop;
2) firstly, preparing a lining, placing a layering pipe between a lining core mould and a lining mould, adding a thermite between the layering pipe and the lining core mould, adding a carbon-free mud material between the layering pipe and the lining mould, then taking out the layering pipe, and forming by using 70MPa of low pressure;
3) and after the lining is produced, performing integral forming, after the outer die is assembled, putting the lining on the middle core die, sequentially putting the plate fabric and the body material, and finally forming by using 110 MPa.
4) And (3) baking and curing the formed semi-finished product for 16 hours by using an electric heating drying kiln at 250 ℃, taking out the semi-finished product after curing, and putting the semi-finished product into a cover type kiln for firing treatment.
5) And (4) performing car processing on the fired product, coating an anti-oxidation coating and coating refractory cotton, and then completing all working procedures.

Claims (5)

1. The utility model provides an accident soaks water with aluminium carbon, its characterized in that includes face, inside lining, body, the inside lining is in the body inboard, the face is in the upper end of inside lining and body, the inside lining is two-layer, and the inlayer is thermite layer, and the skin is the carbon-free slime layer.
2. The accident aluminum carbon impregnated water inlet of claim 1 wherein said bulk material comprises, in parts by weight: 30-55 parts of brown corundum, 28-18 parts of graphite, 8-18 parts of fused quartz, 4-14 parts of alumina micro powder, 1-5 parts of metal silicon powder, 0.5-4 parts of boron carbide and 19-29 parts of a binding agent.
3. The aluminum-carbon impregnated water inlet for accidents according to claim 1, wherein the plate material comprises the following components in parts by weight: 30-65 parts of white corundum, 10-20 parts of graphite, 10-30 parts of fused quartz, 5-15 parts of alumina micro powder, 0.1-3 parts of silicon carbide, 0.5-5 parts of boron carbide, and 5-20 parts of resin powder and liquid resin.
4. The aluminum-carbon impregnated water inlet for accidents according to claim 1, wherein the carbon-free sludge layer comprises the following materials in parts by weight: 40-50 parts of fused quartz, 20-40 parts of floating beads, 15-30 parts of alumina hollow spheres and 5-20 parts of phenolic resin.
5. The method of making an accident aluminum carbon immersion water according to any one of claims 1 to 4, comprising the steps of:
preparing mud materials: after the ingredients are mixed and are kept still for 24 hours in the constant-temperature constant-humidity material warehouse, the molding step is carried out in a constant-temperature constant-humidity workshop;
1) firstly, preparing a lining, placing a layering pipe between a lining core mould and a lining mould, adding a thermite between the layering pipe and the lining core mould, adding a carbon-free mud material between the layering pipe and the lining mould, taking out the layering pipe, and forming by using low pressure of 50-70 MPa;
2) and after the lining is produced, performing integral forming, after the outer die is assembled, putting the lining on the middle core die, sequentially putting the plate fabric and the body material, and finally forming by using 90-130 MPa.
3) And (3) baking and curing the formed semi-finished product for 12-24 hours by using an electric heating drying kiln at the temperature of 200-270 ℃, taking out the semi-finished product after curing, and putting the semi-finished product into a cover type kiln for baking treatment.
CN202111657200.0A 2021-12-30 2021-12-30 Aluminum-carbon immersion nozzle for accidents and preparation method Active CN114213111B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202111657200.0A CN114213111B (en) 2021-12-30 2021-12-30 Aluminum-carbon immersion nozzle for accidents and preparation method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111657200.0A CN114213111B (en) 2021-12-30 2021-12-30 Aluminum-carbon immersion nozzle for accidents and preparation method

Publications (2)

Publication Number Publication Date
CN114213111A true CN114213111A (en) 2022-03-22
CN114213111B CN114213111B (en) 2023-08-11

Family

ID=80707166

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202111657200.0A Active CN114213111B (en) 2021-12-30 2021-12-30 Aluminum-carbon immersion nozzle for accidents and preparation method

Country Status (1)

Country Link
CN (1) CN114213111B (en)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1424161A (en) * 2002-01-29 2003-06-18 鞍山市胜威高温陶瓷制造有限公司 Non-preheated aluminum-carbon long runner
CN1424162A (en) * 2002-06-13 2003-06-18 鞍山市胜威高温陶瓷制造有限公司 Submarine gate for thin plate continuous casting and manufacture thereof
EP1875979A1 (en) * 2006-07-04 2008-01-09 Indref oy Submerged entry nozzle for molten metal
CN102528010A (en) * 2012-02-22 2012-07-04 河南省西保冶材集团有限公司 Long-life alumina-carbon long nozzle and production process for same
CN103464713A (en) * 2013-09-11 2013-12-25 江苏联峰能源装备有限公司 Method for improving automatic casting ratio and stuffing sand thereof
CN104493117A (en) * 2015-01-12 2015-04-08 河南通宇冶材集团有限公司 Heating start powder for continuous casting of rectangular billet
CN108672693A (en) * 2018-07-24 2018-10-19 鞍山市和丰耐火材料有限公司 A kind of sealing structure and method using the submersed nozzle containing expanded graphite meterial
CN111889664A (en) * 2020-07-29 2020-11-06 辽宁科大东方巨业高级陶瓷有限公司 Self-sealing submerged nozzle and manufacturing method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1424161A (en) * 2002-01-29 2003-06-18 鞍山市胜威高温陶瓷制造有限公司 Non-preheated aluminum-carbon long runner
CN1424162A (en) * 2002-06-13 2003-06-18 鞍山市胜威高温陶瓷制造有限公司 Submarine gate for thin plate continuous casting and manufacture thereof
EP1875979A1 (en) * 2006-07-04 2008-01-09 Indref oy Submerged entry nozzle for molten metal
CN102528010A (en) * 2012-02-22 2012-07-04 河南省西保冶材集团有限公司 Long-life alumina-carbon long nozzle and production process for same
CN103464713A (en) * 2013-09-11 2013-12-25 江苏联峰能源装备有限公司 Method for improving automatic casting ratio and stuffing sand thereof
CN104493117A (en) * 2015-01-12 2015-04-08 河南通宇冶材集团有限公司 Heating start powder for continuous casting of rectangular billet
CN108672693A (en) * 2018-07-24 2018-10-19 鞍山市和丰耐火材料有限公司 A kind of sealing structure and method using the submersed nozzle containing expanded graphite meterial
CN111889664A (en) * 2020-07-29 2020-11-06 辽宁科大东方巨业高级陶瓷有限公司 Self-sealing submerged nozzle and manufacturing method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
吴春;董文全;崔淑风;徐文相;柳勇;: "不烘烤浸入式水口的研制", 山东冶金, no. 1, pages 101 - 102 *

Also Published As

Publication number Publication date
CN114213111B (en) 2023-08-11

Similar Documents

Publication Publication Date Title
US4531705A (en) Composite and durable forming model with permeability
CA1266159A (en) Composite and durable forming model with permeability
CN106077507A (en) The casting die of a kind of automobile water-cooling motor casing foundry goods and casting technique
CN104152777A (en) Method for manufacturing TiC-based steel bond hard alloy composite wear-resisting reinforcing body
CN1300864A (en) Process for preparing foam metal
CN109467437B (en) Metal ceramic composite wear-resistant material and preparation method thereof
CN103933872B (en) Preparation method of multi-channel asymmetric stainless steel membrane
CN109692943B (en) SiC prepared by vacuum pressure infiltration positive pressure method3DMethod for preparing/Al composite material
CN111054916A (en) Forming method and forming die for honeycomb metal ceramic wear-resistant composite prefabricated part
CN111054903A (en) Wear-resistant part with space grid-shaped ceramic-metal composite layer and preparation method thereof
CN114213111A (en) Aluminum-carbon soaking water inlet for accidents and preparation method
CN111390149B (en) Casting ladle for casting aluminum alloy
CN1424162A (en) Submarine gate for thin plate continuous casting and manufacture thereof
CN114835496B (en) Cr (chromium) 3 C 2 Preparation method of block material
CN102503462A (en) Metal continuously cast composite slag line long nozzle and preparing method thereof
CN102632216A (en) Device for centrifugally casting cylinder sleeve
CN208218708U (en) Anti-breaking type combined cone disperse air brick
CN111266535B (en) Riser sleeve for composite heat-insulation casting and preparation process thereof
DE2205694A1 (en) Process for the heat treatment of metallic flat material and support roller therefor
CN110527790A (en) The production method of anti-breaking type combined cone disperse air brick
CN106986619B (en) High-temperature nano unfired sliding plate and processing technology thereof
CN115007796B (en) Riser tube coating for casting aluminum alloy and application method thereof
CN108358618A (en) The production method of combined cone disperse air brick
Ali et al. A review on the effects of ceramic sand particles on most casting defects
CN215879750U (en) Heat-preservation riser sleeve device for metal casting mold

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant