CN114180554A - Preparation method of flaky hexagonal hollow carbon material - Google Patents
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- CN114180554A CN114180554A CN202111493625.2A CN202111493625A CN114180554A CN 114180554 A CN114180554 A CN 114180554A CN 202111493625 A CN202111493625 A CN 202111493625A CN 114180554 A CN114180554 A CN 114180554A
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- 239000003575 carbonaceous material Substances 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 27
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 22
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 21
- 239000008158 vegetable oil Substances 0.000 claims abstract description 21
- 239000002253 acid Substances 0.000 claims abstract description 7
- 238000010000 carbonizing Methods 0.000 claims abstract description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N hydrochloric acid Substances Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 238000010335 hydrothermal treatment Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 235000019483 Peanut oil Nutrition 0.000 claims description 4
- ZBQLSHTXSSTFEW-UHFFFAOYSA-N [C+4].[O-2].[Mg+2].[O-2].[O-2] Chemical compound [C+4].[O-2].[Mg+2].[O-2].[O-2] ZBQLSHTXSSTFEW-UHFFFAOYSA-N 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 4
- 239000000312 peanut oil Substances 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 3
- 235000019498 Walnut oil Nutrition 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- 235000005687 corn oil Nutrition 0.000 claims description 3
- 239000002285 corn oil Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 239000004006 olive oil Substances 0.000 claims description 3
- 235000008390 olive oil Nutrition 0.000 claims description 3
- 239000008170 walnut oil Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000003921 oil Substances 0.000 claims description 2
- 235000019198 oils Nutrition 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 235000020238 sunflower seed Nutrition 0.000 claims description 2
- 239000012298 atmosphere Substances 0.000 abstract description 8
- 230000001699 photocatalysis Effects 0.000 abstract description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003463 adsorbent Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 239000002086 nanomaterial Substances 0.000 description 9
- 239000011941 photocatalyst Substances 0.000 description 6
- 239000002243 precursor Substances 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000010538 cationic polymerization reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- 125000005457 triglyceride group Chemical group 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The invention provides a preparation method of a flaky hexagonal hollow carbon material, which comprises the steps of taking flaky hexagonal magnesium oxide as a template, taking vegetable oil as a carbon source, coating the vegetable oil on the surface of the magnesium oxide, roasting and carbonizing the magnesium oxide by temperature programming under the atmosphere of nitrogen, and removing the magnesium oxide by acid to obtain the hollow two-dimensional hexagonal flaky carbon material. The preparation method has the remarkable advantages of low production cost, simplicity in operation, short production time and the like, and the prepared carbon material is hexagonal hollow, has the advantages of high dispersity, large specific surface area and the like, and can be used as a photocatalytic material or an adsorbent.
Description
Technical Field
The invention belongs to the field of nano material preparation, and particularly relates to a preparation method of a flaky hexagonal hollow carbon material.
Background
The micro-morphology of the nano material has important influence on the application performance of the nano material, and the performance of the nano material can be effectively improved by regulating the micro-morphology of the nano material. For example, carbon materials with developed pore structures have significant advantages when used as adsorbents; the carbon material with the two-dimensional structure or the hollow nano structure is suitable for being used as a photocatalyst carrier. Therefore, the micro morphology of the carbon material is regulated and controlled according to the application field of the carbon material, and the carbon material with different morphological characteristics is important in a plurality of research subjects of nano materials.
The hollow nano structure has huge space inside, so that the photocatalyst can generate light scattering and slow photon effect, thereby being beneficial to light absorption. Meanwhile, the structure has higher specific surface area, and can provide more active sites and larger light receiving area for the photocatalyst. Researchers have demonstrated that photocatalysts with hollow nanostructures exhibit better photocatalytic performance than solid particles. Zhuang et al, using glucose to prepare hollow carbon spheres, and then adding TiO2Covering the surface of the hollow carbon sphere to prepare TiO2A hollow carbon sphere composite photocatalyst having excellent performance in photodegradation of dyes (Zhuang Y, Sun J, Guan M. template free preparation of TiO2/C core-shell pore for high performance photo-catalysis [ J]Journal of Alloys and Compounds 2016,662: 84-88.). The strategy for preparing the carbon material by using the template is widely applied. The invention of xucauhajust et al uses the mixture of graphite phase carbon nitride precursor and carbon point precursor as precursor, and mesoporous silicon dioxide as hard template, and prepares the hollow sphere photocatalyst by in-situ thermal polymerization and template etching. The material prepared by the method shows high-efficiency photocatalytic performance under visible light (application number: 202011564729.3).
Based on the analysis, the preparation of the hollow carbon material with a specific morphology has important significance in research in the fields of light, electricity and catalysis, but documents or patents have few reports about two-dimensional hollow carbon materials.
Disclosure of Invention
The invention aims to solve the problems, and provides a preparation method of a sheet-shaped hexagonal hollow carbon material, which has the advantages of simple process and low cost, the prepared carbon material is hexagonal hollow, has high dispersibility, large specific surface area and the like, and can be used as a photocatalytic material or an adsorbent.
The purpose of the invention is realized by the following technical scheme:
a preparation method of a flaky hexagonal hollow carbon material comprises the steps of taking flaky hexagonal magnesium oxide as a template, taking vegetable oil as a carbon source, coating the vegetable oil on the surface of the magnesium oxide, roasting and carbonizing the magnesium oxide by temperature programming under the nitrogen atmosphere, and removing the magnesium oxide by acid to obtain the hollow two-dimensional hexagonal flaky carbon material.
Further, the preparation method of the flaky hexagonal hollow carbon material specifically comprises the following steps:
(a) putting the flaky hexagonal magnesium oxide and vegetable oil with certain mass together, and stirring and mixing;
(b) heating the obtained mixture in a nitrogen atmosphere, and carbonizing at high temperature to obtain a magnesium oxide-carbon composite;
(c) adding the magnesium oxide carbon compound into acid with a certain concentration, carrying out hydrothermal reaction for a period of time, filtering, and drying to obtain the flaky hexagonal hollow carbon.
Further, the vegetable oil comprises one or more of rapeseed oil, sunflower seed oil, soybean oil, corn oil, peanut oil, olive oil and walnut oil.
Further, the mass ratio of the vegetable oil to the magnesium oxide is 1.0-2.5: 1.
Further, in the step (b), the temperature is raised to 600-800 ℃ at the speed of 1-5/min from the room temperature, and the temperature is kept for 2-4 h.
Further, the acid solution in the step (c) is 1-3 mol-1Hydrochloric acid, sulfuric acid or nitric acid.
Further, in the step (c), the mixture is hydrothermally treated at 100 ℃ for 24 hours, taken out, filtered, washed and dried at 50 ℃.
Compared with the prior art, the invention has the following beneficial effects:
in the prior art, the carbon sources which can be selected by the template method for preparing the hollow carbon material mainly comprise methane, furfuryl alcohol, glucose, asphalt, phenolic resin and the like, most of the carbon sources belong to petrochemical resources, and reports of preparing the hollow carbon by using vegetable oil as the carbon source are not found. The vegetable oil is mainly formed by one molecule of glycerol and three molecules of long-chain fatty acids containing 8-22 carbon atoms respectively, has rich sources, and is a biological resource with great application prospect. In addition, vegetable oils containing triglyceride groups are considered as precursors of synthetic polymers, and different types of polymers, including polyesters, polyamides, epoxy resins and polyurethanes, have been prepared by different polymerization reactions, such as cationic polymerization, condensation polymerization and radical copolymerization, based on vegetable oils or modified vegetable oils.
The invention takes two-dimensional sheet hexagonal magnesium oxide as a template, uses vegetable oil as a carbon source, coats the vegetable oil on the surface of the sheet hexagonal magnesium oxide to generate a polymer, and finally prepares the hollow two-dimensional hexagonal sheet carbon material through high-temperature carbonization.
Drawings
FIG. 1 is a scanning electron microscope image of the flaky hexagonal hollow carbon material prepared in example 1.
Detailed Description
The invention is described in detail below with reference to the figures and specific embodiments.
A preparation method of a flaky hexagonal hollow carbon material comprises the following steps:
(1) mixing the sheet hexagonal magnesium oxide and vegetable oil in porcelain boat in different proportion, N2Calcining in a tubular furnace under the atmosphere to obtain MgO/C;
(2) and adding the carbonized sample into 2M hydrochloric acid, removing magnesium oxide by hydrothermal treatment, performing centrifugal separation, washing with hot water to remove magnesium chloride, filtering, and drying to obtain the flaky hexagonal hollow carbon.
Wherein the nitrogen roasting temperature is 600 ℃, the roasting time is 2 hours, and the mass ratio of the flaky hexagonal magnesium oxide to the vegetable oil is 1: 1.5; adding 50mL of 2M hydrochloric acid, carrying out hydrothermal treatment at 100 ℃ for 12h, drying at 40 ℃ for 24h, and placing in an oven.
Example 1
A preparation method of a flaky hexagonal hollow carbon material comprises the following steps: mixing hexagonal flaky magnesium oxide and peanut oil according to the proportion of 1: 2.5 proportion of N2Roasting in the atmosphere at 800 deg.C for 2 hr to obtain product in 2M hydrochloric acid solutionHydrothermal for 24h at medium 100 ℃ to obtain the hexagonal hollow carbon, wherein the SEM image of the product is shown in figure 1, and the product is flaky hexagonal hollow carbon and has regular appearance.
Example 2
A preparation method of a flaky hexagonal hollow carbon material comprises the following steps: mixing hexagonal flaky magnesium oxide and peanut oil according to the proportion of 1: 1.5, N2Roasting in the atmosphere at 800 ℃ for 2 h.
And (3) carrying out hydrothermal treatment on the roasted product in a 2M hydrochloric acid solution at 100 ℃ for 24 hours to obtain the flaky hexagonal hollow carbon.
Example 3
A preparation method of a flaky hexagonal hollow carbon material comprises the following steps: mixing hexagonal flaky magnesium oxide and rapeseed oil according to the proportion of 1: 1.5, N2Roasting in atmosphere at 850 deg.c for 2 hr.
And (3) carrying out hydrothermal treatment on the roasted product in a 3.0M sulfuric acid solution at 100 ℃ for 24 hours to obtain the flaky hexagonal hollow carbon.
Example 4
A preparation method of a flaky hexagonal hollow carbon material comprises the following steps: mixing hexagonal flaky magnesium oxide and olive oil according to the weight ratio of 1: 1, N2Roasting in the atmosphere at 900 ℃ for 2 h. And (3) carrying out hydrothermal treatment on the roasted product in a 1.0M nitric acid solution at 100 ℃ for 24 hours to obtain the flaky hexagonal hollow carbon.
Example 5
A preparation method of a flaky hexagonal hollow carbon material comprises the following steps: mixing hexagonal flaky magnesium oxide and walnut oil according to the proportion of 1: 2, N2Roasting in the atmosphere at 800 ℃ for 2 h. Hydrothermal reaction of the product obtained after roasting in 2.0M hydrochloric acid solution at 100 ℃ for 24 hours to obtain the flaky hexagonal hollow carbon.
Example 6
A preparation method of a flaky hexagonal hollow carbon material comprises the following steps: mixing hexagonal flaky magnesium oxide and corn oil according to the weight ratio of 1: 2.5 proportion of N2Roasting in the atmosphere at 900 ℃ for 2 h. RoastingThen the obtained product is hydrothermally treated in 2.0M hydrochloric acid solution for 24 hours at 100 ℃ to obtain the flaky hexagonal hollow carbon.
The embodiments described above are described to facilitate an understanding and use of the invention by those skilled in the art. It will be readily apparent to those skilled in the art that various modifications to these embodiments may be made, and the generic principles described herein may be applied to other embodiments without the use of the inventive faculty. Therefore, the present invention is not limited to the above embodiments, and those skilled in the art should make improvements and modifications within the scope of the present invention based on the disclosure of the present invention.
Claims (7)
1. A preparation method of a flaky hexagonal hollow carbon material is characterized in that flaky hexagonal magnesium oxide is used as a template, vegetable oil is used as a carbon source, the surface of the magnesium oxide is coated with the vegetable oil, the mixture is roasted and carbonized through temperature programming under the nitrogen atmosphere, and then the magnesium oxide is removed through acid, so that the hollow two-dimensional hexagonal flaky carbon material is obtained.
2. The method for preparing the flaky hexagonal hollow carbon material according to claim 1, which specifically comprises the following steps:
(a) putting the flaky hexagonal magnesium oxide and vegetable oil with certain mass together, and stirring and mixing;
(b) heating the obtained mixture in a nitrogen atmosphere, and carbonizing at high temperature to obtain a magnesium oxide-carbon composite;
(c) adding the magnesium oxide carbon compound into acid with a certain concentration, carrying out hydrothermal reaction for a period of time, filtering, and drying to obtain the flaky hexagonal hollow carbon.
3. The method for preparing a sheet-like hexagonal hollow carbon material according to claim 2, wherein the vegetable oil comprises one or more of rapeseed oil, sunflower seed oil, soybean oil, corn oil, peanut oil, olive oil, and walnut oil.
4. The method for preparing a sheet-like hexagonal hollow carbon material according to claim 2, wherein the mass ratio of the vegetable oil to the magnesium oxide is 1.0-2.5: 1.
5. The method for preparing a sheet-like hexagonal hollow carbon material according to claim 2, wherein the temperature in step (b) is raised from room temperature to 600 ℃ to 800 ℃ at a rate of 1 to 5/min and maintained for 2 to 4 hours.
6. The method for preparing a sheet-shaped hexagonal hollow carbon material according to claim 2, wherein the acid solution in the step (c) is 1 to 3mol-1Hydrochloric acid, sulfuric acid or nitric acid.
7. The method for preparing a flaky hexagonal hollow carbon material according to claim 2, wherein the hydrothermal treatment is carried out at 100 ℃ for 24 hours in the step (c), and the flaky hexagonal hollow carbon material is taken out, filtered, washed and dried at 50 ℃.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080089828A1 (en) * | 2004-09-22 | 2008-04-17 | Showa Denko K.K. | Method for Producing Vapor Grown Carbon Nanotube |
| CN104528704A (en) * | 2014-12-29 | 2015-04-22 | 上海理工大学 | Preparing method for graphitized ordered mesoporous carbon material |
| JP2018047421A (en) * | 2016-09-21 | 2018-03-29 | 株式会社 ユーテックアプライ | Carbon-carrying porous adsorbent for dioxins, heavy metals, and radioactive substances |
| CN112194112A (en) * | 2020-08-10 | 2021-01-08 | 中国石油大学(北京) | High-capacitance hierarchical pore carbon material and preparation method and application thereof |
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2021
- 2021-12-08 CN CN202111493625.2A patent/CN114180554A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080089828A1 (en) * | 2004-09-22 | 2008-04-17 | Showa Denko K.K. | Method for Producing Vapor Grown Carbon Nanotube |
| CN104528704A (en) * | 2014-12-29 | 2015-04-22 | 上海理工大学 | Preparing method for graphitized ordered mesoporous carbon material |
| JP2018047421A (en) * | 2016-09-21 | 2018-03-29 | 株式会社 ユーテックアプライ | Carbon-carrying porous adsorbent for dioxins, heavy metals, and radioactive substances |
| CN112194112A (en) * | 2020-08-10 | 2021-01-08 | 中国石油大学(北京) | High-capacitance hierarchical pore carbon material and preparation method and application thereof |
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