CN114152713A - Device and method for collecting and detecting gaseous and granular heavy metals of fixed pollution source - Google Patents

Device and method for collecting and detecting gaseous and granular heavy metals of fixed pollution source Download PDF

Info

Publication number
CN114152713A
CN114152713A CN202111339674.0A CN202111339674A CN114152713A CN 114152713 A CN114152713 A CN 114152713A CN 202111339674 A CN202111339674 A CN 202111339674A CN 114152713 A CN114152713 A CN 114152713A
Authority
CN
China
Prior art keywords
fly ash
flue gas
heavy metals
cyclone separator
gaseous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202111339674.0A
Other languages
Chinese (zh)
Inventor
韩立鹏
钟犁
屈志强
陈飞云
彭文乾
唐荣富
李昱喆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Huaneng Changjiang Environmental Protection Technology Research Institute Co Ltd
Huaneng Chongqing Luohuang Power Generation Co Ltd
Original Assignee
Beijing Huaneng Changjiang Environmental Protection Technology Research Institute Co Ltd
Huaneng Chongqing Luohuang Power Generation Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing Huaneng Changjiang Environmental Protection Technology Research Institute Co Ltd, Huaneng Chongqing Luohuang Power Generation Co Ltd filed Critical Beijing Huaneng Changjiang Environmental Protection Technology Research Institute Co Ltd
Priority to CN202111339674.0A priority Critical patent/CN114152713A/en
Publication of CN114152713A publication Critical patent/CN114152713A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004Gaseous mixtures, e.g. polluted air
    • G01N33/0009General constructional details of gas analysers, e.g. portable test equipment
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/10Devices for withdrawing samples in the liquid or fluent state
    • G01N1/14Suction devices, e.g. pumps; Ejector devices
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/22Devices for withdrawing samples in the gaseous state
    • G01N1/2202Devices for withdrawing samples in the gaseous state involving separation of sample components during sampling
    • G01N1/2205Devices for withdrawing samples in the gaseous state involving separation of sample components during sampling with filters
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N15/00Investigating characteristics of particles; Investigating permeability, pore-volume or surface-area of porous materials
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N5/00Analysing materials by weighing, e.g. weighing small particles separated from a gas or liquid
    • G01N5/04Analysing materials by weighing, e.g. weighing small particles separated from a gas or liquid by removing a component, e.g. by evaporation, and weighing the remainder
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/10Devices for withdrawing samples in the liquid or fluent state
    • G01N1/14Suction devices, e.g. pumps; Ejector devices
    • G01N2001/1418Depression, aspiration
    • G01N2001/1427Positive displacement, piston, peristaltic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Pathology (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Engineering & Computer Science (AREA)
  • Dispersion Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Food Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Molecular Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

A device and a method for collecting and detecting gaseous and granular heavy metals of a fixed pollution source. In the prior art, the problem of adsorption of the fly ash isolated by the filter membrane on gaseous heavy metals exists, and the accurate recognition of heavy metal migration, transformation and control rules is influenced by the distortion of basic data. The invention comprises the following components: convex sampling mouth (1), convex sampling mouth top is connected with cyclone (3), its below is connected with coarse ash storehouse (2), the one end of P type connecting bend (4) has been inserted at the cyclone top, the P type connecting bend other end is strained a section of thick bamboo (6) with quartzy and is connected, quartzy section of thick bamboo internally mounted has filter mantle (5), quartzy section of thick bamboo is strained and is connected with rotary vane vacuum pump (7) through the pipeline, rotary vane vacuum pump passes through pipeline and mass flow meter (8), mass flow meter passes through the pipeline and is connected with gas-liquid contact ball (10), the lower part at striking bottle (9) is installed to gas-liquid contact ball. The invention is used for collecting and detecting the gaseous and granular heavy metals of the fixed pollution source.

Description

Device and method for collecting and detecting gaseous and granular heavy metals of fixed pollution source
Technical Field
The invention relates to the technical field of environmental monitoring and analysis of fixed pollution sources, in particular to a device and a method for collecting and detecting gaseous and granular heavy metals of fixed pollution sources.
Background
Heavy metals arsenic, mercury and the like can cause serious threats to the ecological environment such as water, atmosphere, soil and the like, the ecological environment and the human health are influenced, a great deal of research work is carried out by people aiming at the emission, migration, conversion, sedimentation and control of related heavy metals and compounds thereof, arsenic and mercury are toxic heavy metal elements with high volatility widely existing in coal, a great amount of coal combustion in China is one of main artificial emission sources of arsenic and mercury, so that the control of the emission of heavy metals in the coal combustion process is of great importance, the harmful element content classification in GB20475 coal carries out strict classification on arsenic and mercury, the coal used for a GB7562 power generation pulverized coal boiler also carries out use limitation on the arsenic and mercury contents, the heavy metals such as arsenic, mercury and the like are separated out in a high-temperature area in the coal combustion process, are easy to be adsorbed on fly ash particles along with the cooling and cooling of flue gas, the occurrence state comprises a gaseous state and a particle state, and the heavy metal fly ash is easy to be adsorbed on the fly ash, in the sample collection process, the adsorption of a large amount of gaseous heavy metals on fly ash is difficult to avoid, so that the concentration of the gaseous heavy metals monitored by a fixed pollution source is lower than that of the particulate heavy metals;
at present, an environment-friendly monitoring system capable of effectively preventing fly ash from adsorbing heavy metals is not available at home and abroad, and some documents and patents propose a method for removing fly ash by filter membrane isolation, but related devices have the problem of adsorption of fly ash isolated by filter membranes on gaseous heavy metals, and the correct recognition of heavy metal migration, transformation and control rules is influenced by the distortion of basic data. Therefore, a monitoring system for the concentration of the heavy metal in a fixed pollution source gas state and a particle state is urgently needed to be developed to solve the problems; based on the analysis, no scheme for solving the problem of data distortion of monitoring of the gaseous and granular heavy metals of the fixed pollution source exists in the prior art.
Disclosure of Invention
The invention aims to provide a device and a method for collecting and detecting gaseous and granular heavy metals of a fixed pollution source.
The above purpose is realized by the following technical scheme:
the utility model provides a detection device is gathered to fixed pollution sources gaseous state and particulate heavy metal, its constitution includes: the device comprises a convex sampling nozzle, wherein the upper part of the convex sampling nozzle is connected with a cyclone separator, the lower part of the convex sampling nozzle is connected with a coarse ash bin, one end of a P-shaped connecting elbow is inserted into the top of the cyclone separator, the other end of the P-shaped connecting elbow is connected with a quartz filter cylinder, a filter cover is arranged inside the quartz filter cylinder, the quartz filter cylinder is connected with a rotary vane vacuum pump through a pipeline, the rotary vane vacuum pump is connected with a mass flow meter through a pipeline, the mass flow meter is connected with a gas-liquid contact ball through a pipeline, and the gas-liquid contact ball is arranged on the lower part of an impact bottle.
Fixed pollution source gaseous state and granular state heavy metal gather detection device, striking bottle top install the gas vent, the outside toper that is of convex sampling mouth, its inside cylindrical passage structure that is, P type connecting bend be the curved streamline structure of semicircle, the spherical surface of gas-liquid contact a set of round hole has to evenly arrange.
The device for collecting and detecting the gaseous and granular heavy metals of the fixed pollution source comprises a convex sampling nozzle, a cyclone separator, a P-shaped connecting bent pipe and a quartz filter cylinder which are fixed inside a source flue wall.
A device and a method for collecting and detecting gaseous and granular heavy metals of a fixed pollution source comprise the following steps:
firstly, flue gas in a cyclone separator enters at a constant speed, the lower end of the cyclone separator is connected with a coarse ash bin which is used for cutting off large-particle fly ash, namely, the large-particle fly ash rotationally sinks under the action of centrifugal force and gravity and enters the coarse ash bin, one end of a P-shaped connecting bent pipe is inserted into the cyclone separator, the other end of the P-shaped connecting bent pipe is connected with a quartz filter cylinder for filtering small-particle fly ash, a convex sampling nozzle is matched with the size of the inner diameter according to the flow rate of the flue gas and the size specification of the inner diameter, constant-speed sampling is ensured, the selection is carried out according to the calculation result of the convex sampling nozzle, the cyclone separator, the P-shaped connecting bent pipe, the quartz filter cylinder and a filter cover are fixed in the source flue wall, the large-particle fly ash and the small-particle fly ash are ensured to be representative, and an impact bottle is filled with hydrogen peroxide and nitric acid solution with specified concentration and reacts with gaseous heavy metals in the flue gas for absorption;
the inner diameter D of the convex sampling nozzle is selected according to the formula:
Figure DEST_PATH_IMAGE001
wherein Q isSFor sample collection flow, VSCollecting the flow rate for the sample;
Figure 78575DEST_PATH_IMAGE002
wherein, KPCorrection factor for pitot tube, P, for speed measurementa、PdRespectively dynamic and static pressure, M, of the flue gasSTo fix the source flue gas molecular weight, TSFor fixing the source flue gas temperature, BaIs at atmospheric pressure;
the convex sampling nozzle vertically faces the flow direction of the flue gas, the flue gas from the fixed source enters the cyclone separator at a constant speed, large-particle fly ash in the flue gas rotationally sinks under the action of centrifugal force and gravity and enters the coarse ash bin, and the mass of a large-particle fly ash sample collected by the coarse ash bin is M1 and is used for analyzing the content of heavy metal in the fly ash;
the flue gas without large particle fly ash enters a P-type connecting bent pipe and enters a quartz filter cylinder to filter small particle fly ash, and the mass of the flue gas serving as a heavy metal content analysis sample is M2 and the flue gas is used for heavy metal content analysis in fly ash.
Has the advantages that:
1. the invention relates to a device and a method for collecting and detecting gaseous and granular heavy metals of a fixed pollution source.
The system has the two-stage fly ash filtering function, can efficiently separate gaseous and granular heavy metal samples of the fixed pollution source, avoids monitoring data distortion caused by adsorption of a large amount of gaseous heavy metals on fly ash, improves the representativeness and reliability of the monitoring data of the heavy metals in different forms of the fixed pollution source, is a stable system for monitoring the gaseous and granular heavy metals of the fixed pollution source, and has the advantage of high accuracy.
The P-shaped connecting bend adopts a semicircular bent flow line structure, aims to prevent coalescence or spalling of small fly ash particles, filters the small fly ash particles through the quartz filter cylinder connected with the other end and the built-in filter cover to serve as a sample for analyzing the content of heavy metal, and has simple and practical structure.
The gas-liquid contact ball is provided with the plurality of round holes which are uniformly arranged, the structure can increase the mass transfer of the flue gas and the solution, ensure the full reaction of the heavy metal in the flue gas and the absorption liquid, arrange the leaf vacuum pump close to the front to extract a fixed source sample, and prevent the fixed source from causing liquid backflow suck-back due to negative pressure.
The thin wall of the air inlet of the convex sampling nozzle is adopted, so that the disturbance of flue gas disorder can be avoided, and the sampling representativeness is ensured.
Description of the drawings:
FIG. 1 is a schematic structural diagram of the present invention.
Fig. 2 is a schematic view of the convex sampling nozzle of fig. 1.
Wherein: 1. the device comprises a convex sampling nozzle, 2, a coarse ash bin, 3, a cyclone separator, 4, a P-shaped connecting bent pipe, 5, a filter cover, 6, a quartz filter cylinder, 7, a rotary vane vacuum pump, 8, a mass flowmeter, 9, an impact bottle, 10, a gas-liquid contact ball, 11, an exhaust port, 12 and a flue wall.
The specific implementation mode is as follows:
example 1:
the utility model provides a detection device is gathered to fixed pollution sources gaseous state and particulate heavy metal, its constitution includes: the device comprises a convex sampling nozzle 1, wherein the upper part of the convex sampling nozzle is connected with a cyclone separator 3, the lower part of the convex sampling nozzle is connected with a coarse ash bin 2, one end of a P-shaped connecting bent pipe 4 is inserted into the top of the cyclone separator, the other end of the P-shaped connecting bent pipe is connected with a quartz filter cylinder 6, a filter cover 5 is arranged inside the quartz filter cylinder, the quartz filter cylinder is connected with a rotary vane vacuum pump 7 through a pipeline, the rotary vane vacuum pump is connected with a mass flow meter 8 through a pipeline, the mass flow meter is connected with a gas-liquid contact ball 10 through a pipeline, and the gas-liquid contact ball is arranged on the lower part of an impact bottle 9.
Example 2:
according to embodiment 1 fixed pollution sources gaseous state and particulate heavy metal gather detection device, striking bottle top install gas vent 11, the outside toper that is of convex sampling mouth, its inside cylindrical passage structure that is, P type connecting bend be the curved streamline structure of semicircle, the spherical outer surface of gas-liquid contact a set of round hole has to evenly arrange.
Example 3:
according to the device for collecting and detecting the gaseous and particulate heavy metals of the fixed pollution source in the embodiment 2, the convex sampling nozzle, the cyclone separator, the P-shaped connecting elbow and the quartz filter cylinder are fixed inside the source flue wall 12.
Example 4:
the detection method of the device for collecting and detecting the heavy metals in the gaseous state and the particulate state of the fixed pollution source according to the embodiments 1-3 comprises the following steps:
firstly, flue gas in a cyclone separator enters at a constant speed, the lower end of the cyclone separator is connected with a coarse ash bin which is used for cutting off large-particle fly ash, namely, the large-particle fly ash rotationally sinks under the action of centrifugal force and gravity and enters the coarse ash bin, one end of a P-shaped connecting bent pipe is inserted into the cyclone separator, the other end of the P-shaped connecting bent pipe is connected with a quartz filter cylinder for filtering small-particle fly ash, a convex sampling nozzle is matched with the size of the inner diameter according to the flow rate of the flue gas and the size specification of the inner diameter, constant-speed sampling is ensured, the selection is carried out according to the calculation result of the convex sampling nozzle, the cyclone separator, the P-shaped connecting bent pipe, the quartz filter cylinder and a filter cover are fixed in the source flue wall, the large-particle fly ash and the small-particle fly ash are ensured to be representative, and an impact bottle is filled with hydrogen peroxide and nitric acid solution with specified concentration and reacts with gaseous heavy metals in the flue gas for absorption;
the inner diameter D of the convex sampling nozzle is selected according to the formula:
Figure DEST_PATH_IMAGE003
wherein Q isSFor sample collection flow, VSCollecting the flow rate for the sample;
Figure 920629DEST_PATH_IMAGE004
wherein, KPCorrection factor for pitot tube, P, for speed measurementa、PdRespectively dynamic and static pressure, M, of the flue gasSTo fix the source flue gas molecular weight, TSFor fixing the source flue gas temperature, BaIs at atmospheric pressure;
the convex sampling nozzle vertically faces the flow direction of the flue gas, the flue gas from the fixed source enters the cyclone separator at a constant speed, large-particle fly ash in the flue gas rotationally sinks under the action of centrifugal force and gravity and enters the coarse ash bin, and the mass of a large-particle fly ash sample collected by the coarse ash bin is M1 and is used for analyzing the content of heavy metal in the fly ash;
the flue gas from which the large-particle fly ash is removed enters a P-type connecting bent pipe and enters a quartz filter cylinder to filter the small-particle fly ash, and the mass of the small-particle fly ash as a heavy metal content analysis sample is M2 and is used for analyzing the heavy metal content in the fly ash;
mass flow meter corrects sample volume to standard V for recorded temperature and pressure valuesb
The content of particulate heavy metals was calculated using the following formula:
Figure 315838DEST_PATH_IMAGE005
wherein H1 is the heavy metal content in large-particle fly ash, H2 is the heavy metal content in small-particle fly ash;
the gaseous heavy metal content was calculated using the following formula:
Figure 130210DEST_PATH_IMAGE006
wherein V is the volume of the absorption liquid in the impact bottle, and y is the heavy metal content of the absorption liquid; vbSample volume to standard state.

Claims (4)

1. The utility model provides a detection device is gathered to fixed pollution sources gaseous state and particulate heavy metal, its constitution includes: convex sampling mouth, characterized by: the device comprises a convex sampling nozzle, a cyclone separator, a coarse ash bin, a P-shaped connecting elbow, a quartz filter cylinder, a filter cover, a rotary vane vacuum pump, a mass flow meter, a gas-liquid contact ball and a gas-liquid contact ball, wherein the upper part of the convex sampling nozzle is connected with the cyclone separator, the lower part of the convex sampling nozzle is connected with the coarse ash bin, one end of the P-shaped connecting elbow is inserted into the top of the cyclone separator, the other end of the P-shaped connecting elbow is connected with the quartz filter cylinder, the filter cover is arranged inside the quartz filter cylinder, the quartz filter cylinder is connected with the rotary vane vacuum pump through a pipeline, the rotary vane vacuum pump is connected with the mass flow meter through a pipeline, the mass flow meter is connected with the gas-liquid contact ball through a pipeline, and the gas-liquid contact ball is arranged on the lower part of an impact bottle.
2. The device for collecting and detecting the gaseous and granular heavy metals in the fixed pollution source according to claim 1, which is characterized in that: striking bottle top install the gas vent, convex sampling mouth outside be the toper, its inside cylindrical passage structure that is, P type connecting bend be the curved streamline structure of semicircle, the gas-liquid contact ball outer surface a set of round hole has to evenly arrange.
3. The device for collecting and detecting the heavy metals in the fixed pollution source gaseous state and the particulate state as claimed in claim 2, wherein: the convex sampling nozzle, the cyclone separator, the P-shaped connecting bent pipe and the quartz filter cylinder are fixed inside the source flue wall.
4. The device and the method for collecting and detecting the gaseous and granular heavy metals in the fixed pollution source according to one of the claims 1 to 3, wherein the device comprises: the method comprises the following steps:
firstly, flue gas in a cyclone separator enters at a constant speed, the lower end of the cyclone separator is connected with a coarse ash bin which is used for cutting off large-particle fly ash, namely, the large-particle fly ash rotationally sinks under the action of centrifugal force and gravity and enters the coarse ash bin, one end of a P-shaped connecting bent pipe is inserted into the cyclone separator, the other end of the P-shaped connecting bent pipe is connected with a quartz filter cylinder for filtering small-particle fly ash, a convex sampling nozzle is matched with the size of the inner diameter according to the flow rate of the flue gas and the size specification of the inner diameter, constant-speed sampling is ensured, the selection is carried out according to the calculation result of the convex sampling nozzle, the cyclone separator, the P-shaped connecting bent pipe, the quartz filter cylinder and a filter cover are fixed in the source flue wall, the large-particle fly ash and the small-particle fly ash are ensured to be representative, and an impact bottle is filled with hydrogen peroxide and nitric acid solution with specified concentration and reacts with gaseous heavy metals in the flue gas for absorption;
the inner diameter D of the convex sampling nozzle is selected according to the formula:
Figure 960766DEST_PATH_IMAGE001
wherein Q isSFor sample collection flow, VSCollecting the flow rate for the sample;
Figure 877906DEST_PATH_IMAGE002
wherein, KPCorrection factor for pitot tube, P, for speed measurementa、PdRespectively dynamic and static pressure, M, of the flue gasSTo fix the source flue gas molecular weight, TSFor fixing the source flue gas temperature, BaIs at atmospheric pressure;
the convex sampling nozzle vertically faces the flow direction of the flue gas, the flue gas from the fixed source enters the cyclone separator at a constant speed, large-particle fly ash in the flue gas rotationally sinks under the action of centrifugal force and gravity and enters the coarse ash bin, and the mass of a large-particle fly ash sample collected by the coarse ash bin is M1 and is used for analyzing the content of heavy metal in the fly ash;
the flue gas without large particle fly ash enters a P-type connecting bent pipe and enters a quartz filter cylinder to filter small particle fly ash, and the mass of the flue gas serving as a heavy metal content analysis sample is M2 and the flue gas is used for heavy metal content analysis in fly ash.
CN202111339674.0A 2021-11-12 2021-11-12 Device and method for collecting and detecting gaseous and granular heavy metals of fixed pollution source Pending CN114152713A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202111339674.0A CN114152713A (en) 2021-11-12 2021-11-12 Device and method for collecting and detecting gaseous and granular heavy metals of fixed pollution source

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111339674.0A CN114152713A (en) 2021-11-12 2021-11-12 Device and method for collecting and detecting gaseous and granular heavy metals of fixed pollution source

Publications (1)

Publication Number Publication Date
CN114152713A true CN114152713A (en) 2022-03-08

Family

ID=80460219

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202111339674.0A Pending CN114152713A (en) 2021-11-12 2021-11-12 Device and method for collecting and detecting gaseous and granular heavy metals of fixed pollution source

Country Status (1)

Country Link
CN (1) CN114152713A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115406726A (en) * 2022-10-26 2022-11-29 北京慧荣和科技有限公司 Air aerosol sampler

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115406726A (en) * 2022-10-26 2022-11-29 北京慧荣和科技有限公司 Air aerosol sampler
CN115406726B (en) * 2022-10-26 2023-01-31 北京慧荣和科技有限公司 Air aerosol sampler

Similar Documents

Publication Publication Date Title
CN101464232B (en) Semi-volatile organic matter sampling technique in exhaust emission pipe
CN203929555U (en) A kind of high precision fine particle density monitoring system
CN107941718B (en) Flue gas pollutant environment monitoring system
CN207248581U (en) A kind of sampling system for being used to measure escape ammonia density total in flue gas
CN203455200U (en) Air particulate matter sampler
CN111397977B (en) System and method for sampling and testing selenium and selenium compounds in waste gas of fixed pollution source
CN101813579B (en) Constant-speed sampling device of fly ash
CN204214696U (en) Condensable particle sampling device
CN214471933U (en) Portable large-flow bioaerosol enrichment and liquid phase acquisition device
CN102323115A (en) Air sampler
CN201837547U (en) Flying ash sampling device at uniform speed
CN114152713A (en) Device and method for collecting and detecting gaseous and granular heavy metals of fixed pollution source
CN108287091A (en) Sampling apparatus and the method for sampling a kind of while that acquire exhaust emission source graded particie object and gas phase organic matter
CN216247389U (en) Gaseous and granular heavy metal collecting and detecting device for fixed pollution source
CN104677700A (en) Sampling system suitable for sampling fine particles in fixed-source droplet-containing flue gas
CN204694486U (en) Heavy duty detergent air conditioning filter performance detecting system
CN204085964U (en) A kind of mobile portable twin-stage is separated constant speed dust sampler
CN206920188U (en) Waste gas sampling apparatus is discharged in a organized way
CN204085966U (en) A kind of portable double-cyclone is separated constant speed dust sampler
CN208026517U (en) A kind of high-temperature high dust bioxin sampling apparatus
CN204479368U (en) A kind of sampling system being applicable to stationary source and gathering containing fine particle in drop flue gas
CN114544272B (en) Cyclone type sand aerosol hierarchical sampling device, method and application
CN206563669U (en) A kind of stationary source particulate Hg and gaseous mercury isokinetic sampling's device
CN212904782U (en) Fixed pollution sources VOCs on-line monitoring device
CN208459091U (en) Sampling apparatus that is a kind of while acquiring exhaust emission source graded particie object and gas phase organic matter

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination