CN114114038A - Lithium battery SOC and available capacity joint estimation method under full-life and full-temperature conditions - Google Patents

Lithium battery SOC and available capacity joint estimation method under full-life and full-temperature conditions Download PDF

Info

Publication number
CN114114038A
CN114114038A CN202111390776.5A CN202111390776A CN114114038A CN 114114038 A CN114114038 A CN 114114038A CN 202111390776 A CN202111390776 A CN 202111390776A CN 114114038 A CN114114038 A CN 114114038A
Authority
CN
China
Prior art keywords
battery
soc
estimation
square root
model
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202111390776.5A
Other languages
Chinese (zh)
Inventor
申江卫
高承志
陈峥
沈世全
马文赛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kunming University of Science and Technology
Original Assignee
Kunming University of Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kunming University of Science and Technology filed Critical Kunming University of Science and Technology
Priority to CN202111390776.5A priority Critical patent/CN114114038A/en
Publication of CN114114038A publication Critical patent/CN114114038A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R31/00Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
    • G01R31/36Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
    • G01R31/385Arrangements for measuring battery or accumulator variables
    • G01R31/387Determining ampere-hour charge capacity or SoC

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Secondary Cells (AREA)

Abstract

The invention relates to a lithium battery SOC and available capacity joint estimation method under full-life and full-temperature conditions, which comprises the following steps: step 1: collecting charge and discharge data of a lithium ion battery at a preset temperature; step 2: constructing a second-order RC equivalent circuit model with wide dynamic temperature compensation; and step 3: performing self-adaptive identification on the model parameters of the second-order RC equivalent circuit model in the step 2 by utilizing a particle swarm optimization algorithm integrated data and dynamic updating technology; and 4, step 4: carrying out high-precision estimation on the battery capacity by using the long-short term memory neural network to obtain the available capacity of the battery; and 5: and (4) taking the model parameters dynamically updated in the step (3) and the available capacity of the battery obtained in the step (4) as input values to carry out SOC estimation. The method fully considers the influence of battery aging and environmental temperature on SOC estimation, adds a periodic updating strategy in a parameter identification link, and can effectively realize the accurate estimation of SOC and available capacity of the lithium ion battery under the full-life and full-temperature conditions by combining the built model and the available capacity estimation result.

Description

Lithium battery SOC and available capacity joint estimation method under full-life and full-temperature conditions
Technical Field
The invention belongs to the technical field of lithium ion batteries, and particularly relates to a lithium battery SOC and available capacity joint estimation method under full-life and full-temperature conditions.
Background
Lithium ion batteries are a major energy source for electric vehicles due to their high electrical energy potential, high energy density, preferred safety characteristics, and long life. The battery management system is the core and key of the power battery technology, and a fully functional battery management system is crucial to battery state detection, battery internal state estimation, battery energy control management and battery safety protection. The accurate SOC value can more accurately control the charging and discharging current and the cut-off time, avoid overcharge, overdischarge and overload work, effectively protect the battery and prolong the service life of the battery. Meanwhile, accurate available capacity information can improve SOC estimation and promote high-quality management of the battery. Therefore, efficient and accurate SOC and available capacity estimation is critical.
At present, various methods have been developed to estimate the SOC value, and model-based estimation methods have been widely studied and applied because they have better online application capability, higher accuracy and initial error correction capability, but such methods depend on the accuracy of the model to a large extent, and the parameters and capacity of the battery model will change continuously with the aging of the battery and affect the estimation result of the battery SOC, and meanwhile, the change of the working environment temperature of the lithium ion battery also has a coupling effect on the internal parameters of the battery, resulting in further reduction of the estimation accuracy of the lithium ion battery SOC, so in order to ensure the SOC estimation accuracy of the lithium ion battery over the full-life and full-temperature range, it is necessary to study the combined estimation of the lithium ion battery SOC and the available capacity with wide dynamic temperature variation.
Disclosure of Invention
The invention aims to solve the technical problem of providing a lithium battery SOC and available capacity joint estimation method under the full-life and full-temperature conditions to solve the problem that parameters and available capacity of a battery model can change along with the temperature and aging of a battery, so that the estimation result of the battery SOC is influenced in the prior art.
In order to solve the technical problems, the technical scheme of the invention is as follows: the method for jointly estimating the SOC and the available capacity of the lithium battery at the full temperature in the whole service life is characterized by comprising the following steps of:
step 1: collecting charge and discharge data of a lithium ion battery at a preset temperature;
step 2: constructing a second-order RC equivalent circuit model with wide dynamic temperature compensation;
and step 3: performing self-adaptive identification on the model parameters of the second-order RC equivalent circuit model in the step 2 by utilizing a particle swarm optimization algorithm integrated data and dynamic updating technology;
and 4, step 4: selecting the duration of a voltage increase interval of the battery in the constant current charging process as a battery health characteristic quantity, and performing high-precision estimation on the battery capacity by using a long-short term memory neural network to obtain the available capacity of the battery;
and 5: and (4) taking the model parameters dynamically updated in the step (3) and the available capacity of the battery obtained in the step (4) as input values, and performing SOC estimation by using a square root cubature Kalman filter.
Further, the charge and discharge data of the lithium ion battery collected in the step 1 at the preset temperature specifically includes: the battery charging method comprises the steps of charging the battery by adopting a constant-current constant-voltage charging mode, discharging the lithium ion battery by adopting a vehicle working condition in the discharging process, wherein the vehicle working condition is HPPC (high power programmable controller) or UDDS (universal digital data broadcasting) or other working conditions which can be used for discharging the lithium ion battery.
Further, a second-order RC equivalent circuit model with wide dynamic temperature compensation is constructed in the step 2, and the derivation of a model parameter equation is as follows:
because the temperature change has a great influence on the model parameters, the model parameters should be updated along with the temperature change, and the update formula is as follows:
Figure BDA0003366251800000031
in the formula QaIs the available capacity of the battery, f is the relation between SOC and model parameter, T is the temperature of the battery, UocIs an open circuitVoltage OCV, R0Is ohmic resistance, C1、C2Is R1、R2Polarization capacitance at both ends, R1、R2Is C1、C2The polarization resistance across the terminals, SOH is the state of health of the cell, which is defined as
Figure BDA0003366251800000032
CnThe rated capacity of the battery;
the second order equivalent circuit model parametric equation with wide dynamic temperature compensation is expressed as:
Figure BDA0003366251800000033
in the formula of Ut(t) terminal voltage of model at time t, U0(t) is ohmic resistance R0Voltage across, U1(t)、U2(t) is a polarization resistance R1、R2And a polarization capacitor C1、C2The voltage across the two terminals is such that,
the SOC at time t is defined as:
Figure BDA0003366251800000041
where η is coulombic efficiency, i is current value, SOC (t)0) Is the SOC value at the initial time.
Further, in step 3, a particle swarm optimization algorithm is used for integrating data and a dynamic updating technology, model parameters of the second-order RC equivalent circuit model with wide dynamic temperature compensation in step 2 are adaptively identified, and the method specifically comprises the following steps:
(31) identifying model parameters by utilizing a particle swarm optimization algorithm;
(32) setting the accumulated data length required by starting the particle swarm optimization algorithm, recording battery discharge data, activating the particle swarm optimization algorithm when the measured data length is greater than the set accumulated data length, identifying model parameters according to the accumulated current and voltage data, automatically updating the model parameter result identified in the previous period by using an automatic updating technology, and continuing to use the model parameters identified in the previous cycle without triggering the particle swarm optimization algorithm and updating the model parameters when the measured data length is less than the set accumulated data length.
Further, the accumulated data length setting principle is as follows: after a specific model of battery is selected, different data lengths are set to respectively identify and update battery model parameters, the SOC of the battery is estimated based on the same filtering algorithm and is compared with a real SOC value, and the data length selected when the SOC estimation precision is higher is selected as a set standard.
Further, the long-short term memory neural network regression function in step 4 is:
Figure BDA0003366251800000051
in which i, g, O, c and OpkRespectively representing an input gate, a forgetting gate, an output gate, a state unit and an output unit, b represents the deviation of the forgetting gate, IW and OW represent the final input and output weights, sigma represents an activation function, and the limiting output value is [0,1 ]]Tanh is a hyperbolic function, ck-1Representing a unit arranged by elements.
Further, in step 5, the SOC estimation is performed by using a square root cubature kalman filter with the model parameters dynamically updated in step 3 and the available capacity of the battery obtained in step 4 as input values, which specifically includes the following steps:
(51) the discrete formula of the state space function of the square root cubature Kalman filtering algorithm is as follows:
Figure BDA0003366251800000052
wherein x iskAnd ykRespectively representing state and system values, ukRepresenting input values, f (-) and h (-) respectively representing a state equation and a measurement equation, according to the established second-order RC equivalent circuit model with wide dynamic temperature compensation, f (-) and h (·) is expressed as:
Figure BDA0003366251800000053
based on the established second-order RC equivalent circuit model with wide dynamic temperature compensation, the state variable of the system is xk=[U1,k U1,k SOCk]TInput variable is uk=ikThe output variable is yk=Ut,kAt the same time
Figure BDA0003366251800000061
In the formula, delta t is sampling time, and eta is coulombic efficiency;
(52) square root volumetric Kalman filtering algorithm initialization
Figure BDA0003366251800000062
In the formula X0Is an initial value of a state variable, P0Representing the error covariance matrix, S0Represents the square root, chol represents the Cholesky decomposition, and E (. cndot.) represents expectation.
(53) Time update of square root volumetric kalman filter algorithm
The sampling points at time k-1 are expressed as:
Figure BDA0003366251800000063
xi in the formulaiA set of sample points is represented that is,
Figure BDA0003366251800000064
i is 1,2, …, m, m is 2n, n represents the number of states;
the state of each sample point is expressed as:
Figure BDA0003366251800000065
after the trade-off points, the predicted state is determined:
Figure BDA0003366251800000071
error covariance of prior estimates of system state variables
Figure BDA0003366251800000072
Where Tria (. cndot.) represents QR decomposition,
Figure BDA0003366251800000073
and Qk-1Expressed as:
Figure BDA0003366251800000074
(54) measurement update of square root volumetric kalman filter algorithm
Calculating input sampling points of a measurement equation:
Figure BDA0003366251800000075
estimate the measured output of each sample point: y isg,k∣k-1=h(uk,xg,k∣k-1)
Calculating a predicted value of the observation output:
Figure BDA0003366251800000076
observation error covariance mean prediction: syy,k∣k-1=Tria[ζk∣k-1,SR,k]
Wherein SR,kIs measuring the noise RkSquare root of
ζk∣k-1Is defined as
Figure BDA0003366251800000077
Covariance matrix square root calculation:
Figure BDA0003366251800000078
wherein
Figure BDA0003366251800000079
The kalman gain calculation, the state variable estimation value update calculation, and the error covariance square root update calculation are as follows:
kalman gain calculation:
Figure BDA00033662518000000710
updating the state variable estimation value:
Figure BDA0003366251800000081
wherein ekIs composed of
Figure BDA0003366251800000082
Updating the square root of the covariance of the system error: sk∣k=Tria[χk∣k-1-Kkζk∣k-1,KkSR,k]
The SOC is a state variable of a square root cubature Kalman filtering algorithm, the estimation value of the state variable is updated and calculated to finish estimation operation of the SOC, and error covariance square root update calculation is to update system noise of the square root cubature Kalman filtering algorithm to improve accurate estimation of the SOC value by the algorithm.
Compared with the prior art, the invention has the beneficial effects that:
(1) the invention discloses a combined estimation method of lithium ion battery SOC and capacity considering temperature change, which realizes self-adaptive identification of model parameters by establishing a second-order equivalent circuit model considering wide dynamic temperature compensation and combining a particle swarm optimization algorithm with data accumulation and updating, then estimates the battery SOC by utilizing the regenerated model parameters and the regenerated available capacity based on a volume square root Kalman filter algorithm, and effectively ensures the SOC estimation precision of the battery in the whole life cycle at different temperatures.
(2) The invention considers that the temperature change has obvious influence on the model parameters, establishes a second-order equivalent circuit model with wide dynamic temperature compensation, is used for simulating the electrical characteristics of the battery and adapts to the rapid change of the internal and external temperatures.
(3) The method fully considers the influence of aging on the battery model parameters, and adds a periodic updating strategy in the parameter identification link, so that the adaptability of the model parameters to the battery aging and the accuracy of the model in the whole life cycle can be effectively improved.
Drawings
In order to more clearly illustrate the technical solutions in the embodiments of the present invention, the drawings needed to be used in the description of the prior art will be briefly introduced below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art to obtain other drawings based on these drawings without inventive exercise.
Fig. 1 is a flow chart of a framework for jointly estimating the SOC and the available capacity of a lithium battery at full temperature and full life according to the present invention.
FIG. 2 is a schematic diagram of a second-order equivalent circuit model with wide dynamic temperature compensation for use in the present invention.
FIG. 3 is a diagram of a long short term memory neural network used in the present invention.
FIG. 4 is a flow chart of a square root cubature Kalman filter algorithm used in the present invention.
Detailed Description
In order that those skilled in the art will better understand the disclosure, the invention will be further described with reference to the accompanying drawings.
The invention provides a lithium battery SOC and available capacity joint estimation method under the whole service life and the whole temperature, and an estimation framework flow of the method is shown in figure 1. Firstly, acquiring charge and discharge data of a lithium ion battery at a preset temperature; meanwhile, the provided capacity prediction algorithm identifies the available capacity of the battery according to the health quantity generated by the constant-current constant-voltage charging voltage curve; in addition, the charging and discharging data are accumulated until the length of the measured data is greater than the set accumulated data length, and model parameter identification is carried out by adopting a particle swarm optimization algorithm; after the battery capacity and the model parameters are obtained, the SOC is estimated by using an SOC estimation algorithm based on square root volumetric Kalman filtering. On the other hand, when the length of the measured data is smaller than the set accumulated data length, the particle swarm algorithm is not called to update the model parameters. In this case, the SOC estimation algorithm uses the previously determined capacity results to predict SOC, with specific detailed steps described below:
step 1: collecting charge and discharge data of a lithium ion battery at a preset temperature; the collected charging and discharging data of the lithium ion battery at the preset temperature specifically comprises the following steps: the charging process of the battery adopts a constant-current constant-voltage charging mode, the discharging process adopts a vehicle working condition to discharge the lithium ion battery, and the vehicle working condition is HPPC or UDDS or other working conditions which can be used for discharging the lithium ion battery.
Step 2: constructing a second-order RC equivalent circuit model with wide dynamic temperature compensation, wherein the model structure is shown in figure 2, and U in the figureocIs open circuit voltage OCV, R0Is ohmic resistance, C1、C2Is R1、R2Polarization capacitance at both ends, R1、R2Is C1、C2Polarization resistances at both ends; the model parameter equation is derived as follows:
because the temperature change has a great influence on the model parameters, the model parameters should be updated along with the temperature change, and the update formula is as follows:
Figure BDA0003366251800000101
in the formula QaFor the available capacity of the battery, f (.) is a relation between SOC and model parameters, T is the temperature of the battery, SOH is the state of health of the battery, and is defined as
Figure BDA0003366251800000111
CnThe rated capacity of the battery;
further, the second order equivalent circuit model parametric equation with wide dynamic temperature compensation is expressed as:
Figure BDA0003366251800000112
in the formula of Ut(t) terminal voltage of model at time t, U0(t) is ohmic resistance R0Voltage across, U1(t)、U2(t) is a polarization resistance R1、R2And a polarization capacitor C1、C2The voltage across the two terminals is such that,
the SOC at time t is defined as:
Figure BDA0003366251800000113
where η is coulombic efficiency, i is current value, SOC (t)0) Is the SOC value at the initial time.
And step 3: performing adaptive identification on the model parameters of the second-order RC equivalent circuit model with wide dynamic temperature compensation in the step 2 by utilizing a particle swarm optimization algorithm integrated data and dynamic updating technology; the method specifically comprises the following steps:
(31) identifying model parameters by utilizing a particle swarm optimization algorithm;
(32) setting the accumulated data length required by starting the particle swarm optimization algorithm, recording battery discharge data, activating the particle swarm optimization algorithm when the measured data length is greater than the set accumulated data length, identifying model parameters according to the accumulated current and voltage data, automatically updating the model parameter result identified in the previous period by using an automatic updating technology, and continuing to use the model parameters identified in the previous cycle without triggering the particle swarm optimization algorithm and updating the model parameters when the measured data length is less than the set accumulated data length.
Preferably, the accumulated data length setting principle of the present invention is: after a specific model of battery is selected, different data lengths are set to respectively identify and update battery model parameters, the SOC of the battery is estimated based on the same filtering algorithm and is compared with a real SOC value, and the data length selected when the SOC estimation precision is higher is selected as a set standard.
And 4, step 4: selecting the duration of a voltage increase interval of the battery in the constant-current charging process as a battery health characteristic, and performing high-precision prediction on the battery capacity by using a long-short term memory neural network to obtain the available capacity of the battery; FIG. 3 is a common configuration of a long-short term memory neural network. It can be seen that there are three gates, an input gate, a forgetting gate, and an output gate to read or modify current or historical information. Further, a tanh function and a sigmoid function are generally performed to select information.
The primary job in implementing a long-short term memory neural network is to determine which messages will be ignored by the forgetting gate. It will enter IPkAnd OPk-1Compression of 0 to 1, where IPkInput representing the current step, OPk-1Represents the output of the k-1 step, and the upper limit value 1 represents the value which should be completely reserved; conversely, the lower limit value of 0 indicates information that should be completely discarded. The forgetting gate can be expressed as:
fk=σ(bf+IpkWi+Opk-1OWi)
wherein f, i, O and c respectively represent a forgetting gate, an input gate, an output gate and a storage unit, b represents the deviation of the forgetting gate, and OW and IW respectively represent the weights of the last output and input. Then, it is necessary to determine which information should be stored, and this step is divided into two parts, one part is called an "input gate" and determines which values are to be updated; the other part creates a new candidate vector, called "input node", which can be expressed as:
Figure BDA0003366251800000131
accordingly, the current cell state is:
ck=ck-1fk+gkik
finally, the output gate determines the final output information from the updated cell state, input gate and input node information, expressed as:
Figure BDA0003366251800000132
wherein p iskIs an internal variable of the long-short term memory neural network. Battery capacity prediction may be achieved by the above formula based on the selected battery health characteristics.
And 5: using the dynamically updated model parameters in step 3 and the available battery capacity obtained in step 4 as input values, and performing SOC estimation by using a square root cubature kalman filter, where the flow of the square root cubature kalman filter is shown in fig. 4. The method specifically comprises the following steps:
(51) general discrete formula for establishing state space function of square root cubature Kalman filter
The discrete formula of the square root volumetric kalman filter state space function is as follows:
Figure BDA0003366251800000133
wherein x iskAnd ykRespectively representing state and system values, ukRepresenting the input values, f (-) and h (-) respectively representing a state equation and a measurement equation, wherein f (-) and h (-) are expressed as follows according to the second-order RC equivalent circuit model with wide dynamic temperature compensation established in the step 2:
Figure BDA0003366251800000141
based on the established second-order RC equivalent circuit model with wide dynamic temperature compensation, the state variable of the system is xk=[U1,k U1,k SOCk]TInput variable is uk=ikThe output variable is yk=Ut,kAt the same time
Figure BDA0003366251800000142
In the formula, delta t is sampling time, and eta is coulombic efficiency;
(52) square root volumetric Kalman filtering algorithm initialization
Figure BDA0003366251800000143
In the formula X0Is an initial value of a state variable, P0Representing the error covariance matrix, S0Represents the square root, chol represents the Cholesky decomposition, and E (. cndot.) represents expectation.
(53) Time update of square root volumetric kalman filter algorithm
The sampling points at time k-1 are expressed as:
Figure BDA0003366251800000144
xi in the formulaiA set of sample points is represented that is,
Figure BDA0003366251800000145
i is 1,2, …, m, m is 2n, n represents the number of states;
the state of each sample point is expressed as:
Figure BDA0003366251800000151
after the trade-off points, the predicted state is determined:
Figure BDA0003366251800000152
error covariance of prior estimates of system state variables
Figure BDA0003366251800000153
Where Tria (. cndot.) represents QR decomposition,
Figure BDA0003366251800000154
and Qk-1Expressed as:
Figure BDA0003366251800000155
(54) measurement update of square root volumetric kalman filter algorithm
Calculating input sampling points of a measurement equation:
Figure BDA0003366251800000156
estimate the measured output of each sample point: y isg,k∣k-1=h(uk,xg,k∣k-1)
Calculating a predicted value of the observation output:
Figure BDA0003366251800000157
observation error covariance mean prediction: syy,k∣k-1=Tria[ζk∣k-1,SR,k]
Wherein SR,kIs measuring the noise RkSquare root of
ζk∣k-1Is defined as
Figure BDA0003366251800000158
Covariance matrix square root calculation:
Figure BDA0003366251800000159
wherein
Figure BDA00033662518000001510
The kalman gain calculation, the state variable estimation value update calculation, and the error covariance square root update calculation are as follows:
kalman gain calculation:
Figure BDA0003366251800000161
updating the state variable estimation value:
Figure BDA0003366251800000162
wherein ekIs composed of
Figure BDA0003366251800000163
Updating the square root of the covariance of the system error: sk∣k=Tria[χk∣k-1-Kkζk∣k-1,KkSR,k]
The SOC is a state variable of a square root cubature Kalman filtering algorithm, the estimation value of the state variable is updated and calculated to finish estimation operation of the SOC, and error covariance square root update calculation is to update system noise of the square root cubature Kalman filtering algorithm to improve accurate estimation of the SOC value by the algorithm.

Claims (7)

1. A lithium battery SOC and available capacity joint estimation method under the whole service life and the whole temperature is characterized by comprising the following steps:
step 1: collecting charge and discharge data of a lithium ion battery at a preset temperature;
step 2: constructing a second-order RC equivalent circuit model with wide dynamic temperature compensation;
and step 3: performing self-adaptive identification on the model parameters of the second-order RC equivalent circuit model in the step 2 by utilizing a particle swarm optimization algorithm integrated data and dynamic updating technology;
and 4, step 4: selecting the duration of a voltage increase interval of the battery in the constant current charging process as a battery health characteristic quantity, and performing high-precision estimation on the battery capacity by using a long-short term memory neural network to obtain the available capacity of the battery;
and 5: and (4) taking the model parameters dynamically updated in the step (3) and the available capacity of the battery obtained in the step (4) as input values, and performing SOC estimation by using a square root cubature Kalman filter.
2. The method of claim 1, wherein the step 1 of collecting the charge and discharge data of the lithium ion battery at a preset temperature specifically comprises: the battery charging method comprises the steps of charging the battery by adopting a constant-current constant-voltage charging mode, discharging the lithium ion battery by adopting a vehicle working condition in the discharging process, wherein the vehicle working condition is HPPC (high power programmable controller) or UDDS (universal digital data broadcasting) or other working conditions which can be used for discharging the lithium ion battery.
3. The method of claim 1, wherein the method comprises the following steps: in the step 2, a second-order RC equivalent circuit model with wide dynamic temperature compensation is constructed, and the derivation of a model parameter equation is as follows:
because the temperature change has a great influence on the model parameters, the model parameters should be updated along with the temperature change, and the update formula is as follows:
Figure FDA0003366251790000021
in the formula QaIs the available capacity of the battery, f is the relation between SOC and model parameter, T is the temperature of the battery, UocIs open circuit voltage OCV, R0Is ohmic resistance, C1、C2Is R1、R2Polarization capacitance at both ends, R1、R2Is C1、C2The polarization resistance across the terminals, SOH is the state of health of the cell, which is defined as
Figure FDA0003366251790000022
CnThe rated capacity of the battery;
the second order equivalent circuit model parametric equation with wide dynamic temperature compensation is expressed as:
Figure FDA0003366251790000023
in the formula of Ut(t) terminal voltage of model at time t, U0(t) is ohmic resistance R0Voltage across, U1(t)、U2(t) is a polarization resistance R1、R2And a polarization capacitor C1、C2The voltage across the two terminals is such that,
the SOC at time t is defined as:
Figure FDA0003366251790000024
where η is coulombic efficiency, i is current value, SOC (t)0) Is the SOC value at the initial time.
4. The method of claim 1, wherein in the step 3, the particle swarm optimization algorithm is used to integrate data and a dynamic update technology, so as to adaptively identify the model parameters of the second-order RC equivalent circuit model with wide dynamic temperature compensation in the step 2, and the method specifically comprises the following steps:
(31) identifying model parameters by utilizing a particle swarm optimization algorithm;
(32) setting the accumulated data length required by starting the particle swarm optimization algorithm, recording battery discharge data, activating the particle swarm optimization algorithm when the measured data length is greater than the set accumulated data length, identifying model parameters according to the accumulated current and voltage data, automatically updating the model parameter result identified in the previous period by using an automatic updating technology, and continuing to use the model parameters identified in the previous cycle without triggering the particle swarm optimization algorithm and updating the model parameters when the measured data length is less than the set accumulated data length.
5. The method of claim 4, wherein the SOC and the available capacity of the lithium battery at the full temperature are jointly estimated at the full temperature and the full life, and the method comprises the following steps: the setting principle of the accumulated data length is as follows: after a specific model of battery is selected, different data lengths are set to respectively identify and update battery model parameters, the SOC of the battery is estimated based on the same filtering algorithm and is compared with a real SOC value, and the data length selected when the SOC estimation precision is higher is selected as a set standard.
6. The method of claim 1, wherein the method comprises the following steps: the long-short term memory neural network regression function in the step 4 is as follows:
Figure FDA0003366251790000041
in which i, g, O, c and OpkRespectively representing an input gate, a forgetting gate, an output gate, a state unit and an output unit, b represents the deviation of the forgetting gate, IW and OW represent the final input and output weights, sigma represents an activation function, and the limiting output value is [0,1 ]]Tanh is a hyperbolic function, ck-1Representing a unit arranged by elements.
7. The method of claim 1, wherein the method comprises the following steps: in the step 5, the model parameters dynamically updated in the step 3 and the available capacity of the battery obtained in the step 4 are used as input values, and a square root cubature kalman filter is used for SOC estimation, specifically comprising the following steps:
(51) the discrete formula of the state space function of the square root cubature Kalman filtering algorithm is as follows:
Figure FDA0003366251790000042
wherein x iskAnd ykRespectively representing state and system values, ukRepresenting input values, f (-) and h (-) respectively represent a state equation and a measurement equation, and according to the established second-order RC equivalent circuit model with wide dynamic temperature compensation, f (-) and h (-) are expressed as:
Figure FDA0003366251790000043
based on the established second-order RC equivalent circuit model with wide dynamic temperature compensation, the state variable of the system is xk=[U1,k U1,k SOCk]TInput variable is uk=ikThe output variable is yk=Ut,kAt the same time
Figure FDA0003366251790000051
In the formula, delta t is sampling time, and eta is coulombic efficiency;
(52) square root volumetric Kalman filtering algorithm initialization
Figure FDA0003366251790000052
In the formula X0Is an initial value of a state variable, P0Representing the error covariance matrix, S0Represents the square root, chol represents the Cholesky decomposition, and E (. cndot.) represents expectation.
(53) Time update of square root volumetric kalman filter algorithm
The sampling points at time k-1 are expressed as:
Figure FDA0003366251790000053
xi in the formulaiA set of sample points is represented that is,
Figure FDA0003366251790000054
represents the number of states;
the state of each sample point is expressed as:
Figure FDA0003366251790000055
after the trade-off points, the predicted state is determined:
Figure FDA0003366251790000061
error covariance of prior estimates of system state variables
Figure FDA0003366251790000062
Where Tria (. cndot.) represents QR decomposition,
Figure FDA0003366251790000063
and Qk-1Expressed as:
Figure FDA0003366251790000064
(54) measurement update of square root volumetric kalman filter algorithm
Calculating input sampling points of a measurement equation:
Figure FDA0003366251790000065
estimate the measured output of each sample point: y isg,k∣k-1=h(uk,xg,k∣k-1)
Calculating a predicted value of the observation output:
Figure FDA0003366251790000066
observation error covariance mean prediction: syy,k∣k-1=Tria[ζk∣k-1,SR,k]
Wherein SR,kIs measuring the noise RkSquare root of
ζk∣k-1Is defined as
Figure FDA0003366251790000067
Covariance matrix averageAnd (3) square root calculation:
Figure FDA0003366251790000068
wherein
Figure FDA0003366251790000069
The kalman gain calculation, the state variable estimation value update calculation, and the error covariance square root update calculation are as follows:
kalman gain calculation:
Figure FDA00033662517900000610
updating the state variable estimation value:
Figure FDA0003366251790000071
wherein ekIs composed of
Figure FDA0003366251790000072
Updating the square root of the covariance of the system error: sk∣k=Tria[χk∣k-1-Kkζk∣k-1,KkSR,k]
The SOC is a state variable of a square root cubature Kalman filtering algorithm, the estimation value of the state variable is updated and calculated to finish estimation operation of the SOC, and error covariance square root update calculation is to update system noise of the square root cubature Kalman filtering algorithm to improve accurate estimation of the SOC value by the algorithm.
CN202111390776.5A 2021-11-22 2021-11-22 Lithium battery SOC and available capacity joint estimation method under full-life and full-temperature conditions Pending CN114114038A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202111390776.5A CN114114038A (en) 2021-11-22 2021-11-22 Lithium battery SOC and available capacity joint estimation method under full-life and full-temperature conditions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111390776.5A CN114114038A (en) 2021-11-22 2021-11-22 Lithium battery SOC and available capacity joint estimation method under full-life and full-temperature conditions

Publications (1)

Publication Number Publication Date
CN114114038A true CN114114038A (en) 2022-03-01

Family

ID=80439643

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202111390776.5A Pending CN114114038A (en) 2021-11-22 2021-11-22 Lithium battery SOC and available capacity joint estimation method under full-life and full-temperature conditions

Country Status (1)

Country Link
CN (1) CN114114038A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114740386A (en) * 2022-03-08 2022-07-12 中南大学 Lithium ion battery state-of-charge estimation method based on health state
CN117590259A (en) * 2023-11-22 2024-02-23 昆明理工大学 Migration model-based lithium battery pack full-life wide-temperature SOC efficient estimation method
CN117686919A (en) * 2024-02-01 2024-03-12 昆明理工大学 Lithium battery SOC and SOH estimation method based on optimized electrochemical model
CN117825974A (en) * 2024-03-04 2024-04-05 昆明理工大学 Energy storage battery state of charge and state of health collaborative estimation method and device

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114740386A (en) * 2022-03-08 2022-07-12 中南大学 Lithium ion battery state-of-charge estimation method based on health state
CN114740386B (en) * 2022-03-08 2024-05-24 中南大学 Lithium ion battery state of charge estimation method based on state of health
CN117590259A (en) * 2023-11-22 2024-02-23 昆明理工大学 Migration model-based lithium battery pack full-life wide-temperature SOC efficient estimation method
CN117590259B (en) * 2023-11-22 2024-04-16 昆明理工大学 Migration model-based lithium battery pack full-life wide-temperature SOC efficient estimation method
CN117686919A (en) * 2024-02-01 2024-03-12 昆明理工大学 Lithium battery SOC and SOH estimation method based on optimized electrochemical model
CN117686919B (en) * 2024-02-01 2024-04-19 昆明理工大学 Lithium battery SOC and SOH estimation method based on optimized electrochemical model
CN117825974A (en) * 2024-03-04 2024-04-05 昆明理工大学 Energy storage battery state of charge and state of health collaborative estimation method and device

Similar Documents

Publication Publication Date Title
CN110568361B (en) Method for predicting health state of power battery
JP7095110B2 (en) Battery status estimation method
CN109061520B (en) Power battery health and power state online estimation method and system
Chen et al. State-of-charge estimation of lithium-ion batteries based on improved H infinity filter algorithm and its novel equalization method
CN107368619B (en) Extended Kalman filtering SOC estimation method
Chen et al. Battery state of charge estimation based on a combined model of Extended Kalman Filter and neural networks
CN114114038A (en) Lithium battery SOC and available capacity joint estimation method under full-life and full-temperature conditions
CN110596593A (en) Lithium ion battery SOC estimation method based on intelligent adaptive extended Kalman filtering
CN109633472B (en) State of charge estimation algorithm of single lithium battery
CN111581904A (en) Lithium battery SOC and SOH collaborative estimation method considering influence of cycle number
CN111913109B (en) Method and device for predicting peak power of battery
CN111044906B (en) Lithium ion battery energy state estimation method based on maximum likelihood criterion
CN114740386B (en) Lithium ion battery state of charge estimation method based on state of health
CN110795851A (en) Lithium ion battery modeling method considering environmental temperature influence
CN110673037B (en) Battery SOC estimation method and system based on improved simulated annealing algorithm
CN113777510A (en) Lithium battery state of charge estimation method and device
CN112946481A (en) Based on federation H∞Filtering sliding-mode observer lithium ion battery SOC estimation method and battery management system
CN112989690A (en) Multi-time scale state of charge estimation method for lithium battery of hybrid electric vehicle
Qiu et al. Battery hysteresis modeling for state of charge estimation based on Extended Kalman Filter
CN112083333A (en) Power battery pack state of charge estimation method based on machine learning model
Ramezani-al et al. A novel combined online method for SOC estimation of a Li-Ion battery with practical and industrial considerations
CN115656848A (en) Lithium battery SOC estimation method based on capacity correction
CN114720881A (en) Lithium battery parameter identification method based on improved initial value forgetting factor recursive least square method
CN114397578A (en) Lithium ion battery residual capacity estimation method
CN113420444A (en) Lithium ion battery SOC estimation method based on parameter online identification

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination