CN114082434A - Modified carbonitride, preparation and application thereof, and method for degrading pesticide chlorpyrifos - Google Patents
Modified carbonitride, preparation and application thereof, and method for degrading pesticide chlorpyrifos Download PDFInfo
- Publication number
- CN114082434A CN114082434A CN202111415338.XA CN202111415338A CN114082434A CN 114082434 A CN114082434 A CN 114082434A CN 202111415338 A CN202111415338 A CN 202111415338A CN 114082434 A CN114082434 A CN 114082434A
- Authority
- CN
- China
- Prior art keywords
- chlorpyrifos
- modified
- carbonitride
- degradation
- modified carbonitride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005944 Chlorpyrifos Substances 0.000 title claims abstract description 41
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 230000000593 degrading effect Effects 0.000 title claims abstract description 10
- 239000000575 pesticide Substances 0.000 title abstract description 18
- 238000006731 degradation reaction Methods 0.000 claims abstract description 22
- 230000015556 catabolic process Effects 0.000 claims abstract description 19
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 8
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 8
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910002651 NO3 Inorganic materials 0.000 claims abstract description 7
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims abstract description 6
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 10
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 10
- 239000002917 insecticide Substances 0.000 claims description 6
- 238000013033 photocatalytic degradation reaction Methods 0.000 claims description 6
- 235000010333 potassium nitrate Nutrition 0.000 claims description 5
- 239000004323 potassium nitrate Substances 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 235000010344 sodium nitrate Nutrition 0.000 claims description 5
- 239000004317 sodium nitrate Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 5
- 238000005286 illumination Methods 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical class N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 abstract description 3
- 238000000227 grinding Methods 0.000 abstract description 2
- 239000011941 photocatalyst Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 8
- 239000003153 chemical reaction reagent Substances 0.000 description 5
- 238000001514 detection method Methods 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 238000001782 photodegradation Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241001124076 Aphididae Species 0.000 description 1
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000353522 Earias insulana Species 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000255901 Tortricidae Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000003958 fumigation Methods 0.000 description 1
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 229960001952 metrifonate Drugs 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/10—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by subjecting to electric or wave energy or particle or ionizing radiation
- A62D3/17—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by subjecting to electric or wave energy or particle or ionizing radiation to electromagnetic radiation, e.g. emitted by a laser
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/04—Pesticides, e.g. insecticides, herbicides, fungicides or nematocides
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/20—Organic substances
- A62D2101/26—Organic substances containing nitrogen or phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- General Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Electromagnetism (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a modified carbon nitride, a preparation method and application thereof, and a method for degrading a pesticide chlorpyrifos, wherein the preparation process of the modified carbon nitride specifically comprises the following steps: taking melamine, pyromellitic dianhydride and nitrate, grinding and mixing, and then carrying out high-temperature treatment to obtain a target product; in addition, by treating chlorpyrifos with Carbonitride (CN) under the illumination condition, a good degradation effect can be achieved. Compared with the prior art, the photocatalyst is simple and easy to prepare, has mild degradation conditions for the pesticide, can avoid secondary pollution, and has great application prospect and the like.
Description
Technical Field
The invention belongs to the technical field of pesticide degradation, and relates to a modified carbonitride, preparation and application thereof, and a method for degrading a pesticide chlorpyrifos.
Background
With the continuous enhancement of food safety consciousness of consumers, people gradually realize that the large-scale production and application of pesticides provide important guarantee for national food safety, but also bring serious threats to the ecological environment and human health, wherein the organophosphorus pesticides trichlorfon and chlorpyrifosThe pesticide is more used at present, and has larger pollution to the soil environment. Therefore, the research on the degradation effect of the pesticide is an important index for evaluating the residue of the pesticide in the environment, namely chlorpyrifos, also called chlorpyrifos, the chemical name of which is O, O-diethyl-O- (3,5, 6-trichloro-2-pyridyl) thiophosphoric acid and the molecular formula of which is C9H11Cl3NO3PS, white crystals with a slight thiol smell. The chlorpyrifos has the effects of contact poisoning, stomach poisoning, fumigation and the like, can effectively control the pests such as aphids, stem borers, leaf rollers and the like on crops such as cotton, wheat, rice, corn and the like, but the residual chlorpyrifos on the surfaces of the crops has irreversible damage to human bodies while the pests are effectively controlled, and is very important for the effective degradation of the chlorpyrifos in future generations.
Disclosure of Invention
The invention aims to provide a modified carbonitride, a preparation method and an application thereof, and a method for degrading a pesticide chlorpyrifos.
The purpose of the invention can be realized by the following technical scheme:
one of the technical schemes of the invention provides a preparation method of modified carbonitride, which comprises the steps of taking melamine, pyromellitic dianhydride and nitrate, grinding, mixing, and then carrying out high-temperature treatment to obtain a target product.
Further, the mass ratio of melamine to pyromellitic dianhydride is 1: 2.
Further, the process conditions of the high-temperature treatment are as follows: the heat preservation treatment is carried out for 2 to 6 hours at the temperature of 240 to 280 ℃, and the treatment is preferably carried out for 4 hours at the temperature of 260 ℃.
Further, in the high-temperature treatment process, the temperature rise rate is controlled to be 2-2.5 ℃/min, and preferably 2.3 ℃/min.
Further, the nitrate is one or a mixture of potassium nitrate and sodium nitrate, preferably a mixture of potassium nitrate and sodium nitrate, and the specific mixing mass ratio can be 1: 1.
The second technical scheme of the invention provides a modified carbonitride, which is prepared by adopting any one of the preparation methods.
The third technical scheme of the invention provides application of modified carbonitride, wherein the modified carbonitride is used for degrading the pesticide chlorpyrifos.
Further, when the modified carbonitride is used for degrading the insecticide chlorpyrifos, the modification is carried out under the irradiation of visible light. Preferably, the wavelength of visible light is 400-700 nm.
The fourth technical scheme of the invention provides a method for degrading the insecticide chlorpyrifos, which is implemented by putting the modified carbonitride into a solution containing chlorpyrifos, and carrying out photocatalytic degradation under the irradiation of visible light.
Furthermore, the initial concentration of the chlorpyrifos in the solution is preferably 6.5 mug/mL (the concentration is obtained by diluting the standard chlorpyrifos reagent by 1 mg/mL), and the degradation process can be carried out at room temperature; the wavelength of visible light is preferably 400-700 nm; the amount of the modified carbonitride added is preferably 20 to 40mg/30mL of the treatment solution.
Compared with the prior art, the invention has the following advantages:
(1) the CN compound of the invention is a catalyst with simple preparation method, low price, good water solubility, mild degradation condition, capability of avoiding secondary pollution and great application prospect.
(2) Chlorpyrifos is a bipyridyl herbicide, is a pesticide which is used more at present and has larger pollution to the soil environment. Therefore, the research on the degradation effect of the pesticide is an important index for evaluating the residue of the pesticide in the environment, and a small amount of residue is left after the pesticide is used, so that the pesticide has certain pollution to the environment. The method utilizes Carbonitride (CN) to degrade chlorpyrifos within 60min, and has the advantages of 59.8 percent of degradation rate, mild reaction condition, good degradation rate and good application prospect.
Drawings
FIG. 1 is an X-ray diffraction pattern of a modified carbonitride of the present invention;
FIG. 2 is a diagram showing the detection of chlorpyrifos by photocatalytic degradation;
FIG. 3 is a graph of white light versus chlorpyrifos detection at different powers;
FIG. 4 is a graph of the rate of photocatalytic degradation of chlorpyrifos by CN at different concentrations.
Detailed Description
The invention is described in detail below with reference to the figures and specific embodiments. The present embodiment is implemented on the premise of the technical solution of the present invention, and a detailed implementation manner and a specific operation process are given, but the scope of the present invention is not limited to the following embodiments.
In the following examples, the instruments, reagents and sample sources used are specifically as follows:
the instrument comprises the following steps: CD-300-250W; an S10-3 type constant temperature magnetic stirrer; a 100 μ L pipette; UV-2450 ultraviolet-visible spectrophotometer, muffle furnace.
Sample preparation: potassium nitrate (AR, national reagent limited); sodium nitrate (A.R, national reagents ltd); melamine (A.R, mcelin); pyromellitic dianhydride (A.R, Meclin).
Otherwise, unless otherwise specified, all the materials or processing techniques are conventional commercial products or conventional processing techniques in the art.
Example 1:
1) preparation of chlorpyrifos solution
0.2mL of chlorpyrifos standard reagent (1000. mu.g/mL) is dissolved in 30mL of deionized water to prepare a concentration of 6.5 ug/mL. Magnetically stirring for 30min without light.
2) Preparation of photodegradation catalyst
Synthesizing CN powder by using a molten salt low-temperature copolymerization method, which comprises the following steps: melamine and pyromellitic dianhydride were placed in a nitrate system (specifically, melamine: pyromellitic anhydride 1:2, 0.2g and 0.4g were added, respectively, potassium nitrate: sodium nitrate 1:1, 0.5g and 0.5g were added, respectively) in a mortar for 30min, mixed uniformly, and then placed in a muffle furnace at 260 ℃ for 4 hours with a heating rate of 2.3 ℃/min.
3) Preparation of mixed solution of chlorpyrifos and catalyst
The prepared CN powder (20 mg and 30mg respectively) is weighed and dissolved in the previously prepared 30mL of chlorpyrifos solution, then the solution is stirred for half an hour in the dark, and the solution is transferred into a light source for photocatalytic degradation.
4) UV-visible spectrophotometer detection
And (3) placing 2mL of the mixed solution in a cuvette, and detecting within the range of 200-600 nm, wherein the chlorpyrifos detection wavelength is 294 nm.
5) Detection data processing
The degree of absorption is converted into a degradation rate, and the calculation formula of the degradation rate is as follows: chlorpyrifos degradation rate (%) -100 × (initial concentration-residual concentration)/initial concentration. Therefore, an ultraviolet-visible absorption graph and a rate graph of the photocatalytic degradation of the chlorpyrifos are drawn.
The XRD pattern of the material in FIG. 1 shows that the synthesized CNNPs correspond to the main peak (23.5 degrees) of standard card NCCN PDF #72-497, which further demonstrates the successful synthesis of CN NPs as shown in FIG. 1. (it can be seen from the figure that there are also clear peaks of impurities that appear, which may be due to partial molten salts).
As can be clearly seen from the ultraviolet characteristic absorption peaks in FIGS. 2a-b, the 294nm characteristic absorption peak of chlorpyrifos has an obvious downward trend in the 60min degradation process in the presence of light and a catalyst, which indicates that the CN NPs have obvious photodegradation effect
From FIG. 3, it is clear that the power at 100W/cm is2The degradation influence on the chlorpyrifos under the internal illumination can be ignored, so that the light power used in the photodegradation process is 100W/cm2。
It can be seen from FIG. 4 that CN NPs with different concentrations have obvious photodegradation within 45min under the action of light.
In general, under the condition of visible light irradiation, the carbonitride has a good degradation rate to chlorpyrifos, and the optimal degradation conditions are as follows: the temperature is room temperature, the illumination is added, the concentration of the chlorpyrifos is 6.5 mu g/mL, the irradiation is carried out for 60min under the reaction condition, the degradation rate of the chlorpyrifos is 59.8 percent, the reaction operation is simple and convenient, and the degradation of the chlorpyrifos can be promoted at a high level.
The embodiments described above are described to facilitate an understanding and use of the invention by those skilled in the art. It will be readily apparent to those skilled in the art that various modifications to these embodiments may be made, and the generic principles described herein may be applied to other embodiments without the use of the inventive faculty. Therefore, the present invention is not limited to the above embodiments, and those skilled in the art should make improvements and modifications within the scope of the present invention based on the disclosure of the present invention.
Claims (10)
1. A preparation method of modified carbonitride is characterized in that melamine, pyromellitic dianhydride and nitrate are taken, ground and mixed, and then treated at high temperature to obtain a target product.
2. The method for preparing modified carbonitride according to claim 1 wherein the molar ratio of melamine to pyromellitic dianhydride is 1: 2.
3. the method for preparing modified carbonitride according to claim 1 characterized in that the process conditions of the high temperature treatment are as follows: and carrying out heat preservation treatment at 240-280 ℃ for 2-6 h.
4. The method of claim 1, wherein the temperature increase rate is controlled to be 2-2.5 ℃/min during the high temperature treatment.
5. The method for preparing modified carbonitride according to claim 1 wherein the nitrate is one or a mixture of potassium nitrate and sodium nitrate.
6. A modified carbonitride produced by the production method as claimed in any one of claims 1 to 5.
7. Use of a modified carbonitride according to claim 6 for the degradation of the insecticide chlorpyrifos.
8. The use of modified carbonitrides according to claim 7, wherein the modified carbonitrides, when used for the degradation of the insecticide chlorpyrifos, are carried out under visible light irradiation at a wavelength of 400-700 nm.
9. A method for degrading the insecticide chlorpyrifos, which is characterized in that the modified carbonitride is put into the solution containing the chlorpyrifos according to the claim 6, and the photocatalytic degradation is carried out under the irradiation of visible light, thus completing the method.
10. The method for degrading chlorpyrifos as an insecticide of claim 9, wherein the initial concentration of chlorpyrifos in the solution is 6.5 μ g/mL, the degradation process is performed at room temperature, the wavelength of visible light is 400-700nm, and the addition amount of modified carbonitride is 20-40mg/30mL of solution respectively.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111415338.XA CN114082434A (en) | 2021-11-25 | 2021-11-25 | Modified carbonitride, preparation and application thereof, and method for degrading pesticide chlorpyrifos |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111415338.XA CN114082434A (en) | 2021-11-25 | 2021-11-25 | Modified carbonitride, preparation and application thereof, and method for degrading pesticide chlorpyrifos |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114082434A true CN114082434A (en) | 2022-02-25 |
Family
ID=80304736
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111415338.XA Pending CN114082434A (en) | 2021-11-25 | 2021-11-25 | Modified carbonitride, preparation and application thereof, and method for degrading pesticide chlorpyrifos |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114082434A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115155654A (en) * | 2022-06-16 | 2022-10-11 | 湖南农业大学 | Carbon nitride composite photocatalyst, preparation method thereof and treatment method of herbicide wastewater |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108745404A (en) * | 2018-06-14 | 2018-11-06 | 苏州大学 | Carbon nitride films composite material and preparation method and the application in exhaust-gas treatment based on black phosphorus/metal organic frame modification |
| CN108889327A (en) * | 2018-07-19 | 2018-11-27 | 西南石油大学 | A kind of preparation method of metal-doped black amorphous state carbonitride catalysis material |
| CN109012728A (en) * | 2018-08-10 | 2018-12-18 | 复旦大学 | Catalytic oxidation-reduction synthesis peroxidating catalyst for hydrogen and preparation method thereof under visible light |
| CN111960499A (en) * | 2020-07-15 | 2020-11-20 | 广东工业大学 | photocatalysis-Fenton in-situ coupling method for killing bacteria in ballast water |
-
2021
- 2021-11-25 CN CN202111415338.XA patent/CN114082434A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108745404A (en) * | 2018-06-14 | 2018-11-06 | 苏州大学 | Carbon nitride films composite material and preparation method and the application in exhaust-gas treatment based on black phosphorus/metal organic frame modification |
| US20190381487A1 (en) * | 2018-06-14 | 2019-12-19 | Soochow University | Carbon nitride membrane composite material modified by black phosphorus/ metal organic framework, and preparation method thereof and application in waste gas treatment |
| CN108889327A (en) * | 2018-07-19 | 2018-11-27 | 西南石油大学 | A kind of preparation method of metal-doped black amorphous state carbonitride catalysis material |
| CN109012728A (en) * | 2018-08-10 | 2018-12-18 | 复旦大学 | Catalytic oxidation-reduction synthesis peroxidating catalyst for hydrogen and preparation method thereof under visible light |
| CN111960499A (en) * | 2020-07-15 | 2020-11-20 | 广东工业大学 | photocatalysis-Fenton in-situ coupling method for killing bacteria in ballast water |
Non-Patent Citations (4)
| Title |
|---|
| CONGCONG YAN等: "Improved photoremoval performance of boron carbon nitride–pyromellitic dianhydride composite toward tetracycline and Cr(VI) by itself to change the solution pH", 《NEW JOURNAL OF CHEMISTRY》 * |
| JINPENG YANG等: "Carbon nitrides modified with suitable electron withdrawing groups enhancing the visible-light-driven photocatalytic activity for degradation of the Rhodamine B", 《MATERIALS RESEARCH BULLETIN》 * |
| SIVAKUMAR VIGNESHWARAN等: "Removal of chlorpyrifos, an insecticide using metal free heterogeneous graphitic carbon nitride (g-C3N4) incorporated chitosan as catalyst:Photocatalytic and adsorption studies", 《INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES》 * |
| 刘宗梅等: "钾离子掺杂g－C3N4催化剂的制备及其性能研究", 《现代化工》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115155654A (en) * | 2022-06-16 | 2022-10-11 | 湖南农业大学 | Carbon nitride composite photocatalyst, preparation method thereof and treatment method of herbicide wastewater |
| CN115155654B (en) * | 2022-06-16 | 2024-03-22 | 湖南农业大学 | Carbon nitride composite photocatalyst, preparation method thereof and herbicide wastewater treatment method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Dulta et al. | Multifunctional CuO nanoparticles with enhanced photocatalytic dye degradation and antibacterial activity | |
| Lin et al. | Modification-free carbon dots as turn-on fluorescence probe for detection of organophosphorus pesticides | |
| Singh et al. | One pot hydrothermal synthesis of fluorescent NP-carbon dots derived from Dunaliella salina biomass and its application in on-off sensing of Hg (II), Cr (VI) and live cell imaging | |
| Del Buono et al. | Biogenic ZnO nanoparticles synthesized using a novel plant extract: Application to enhance physiological and biochemical traits in maize | |
| Hue et al. | Manganese toxicity in a Hawaiian Oxisol affected by soil pH and organic amendments | |
| Manjunath et al. | Biofabrication of gold nanoparticles using marine endophytic fungus–Penicillium citrinum | |
| Singh et al. | Fe-doped MoS2 nanomaterials with amplified peroxidase mimetic activity for the colorimetric detection of glutathione in human serum | |
| Das et al. | A compact study on impact of multiplicative Streblus asper inspired biogenic silver nanoparticles as effective photocatalyst, good antibacterial agent and interplay upon interaction with human serum albumin | |
| Mesaros et al. | Towards understanding the enhancement of antibacterial activity in manganese doped ZnO nanoparticles | |
| Rahman et al. | Antioxidant and antibacterial studies of phytogenic fabricated ZnO using aqueous leaf extract of Ziziphus mauritiana Lam | |
| Freitas et al. | Synthesis and structural characterization of a zinc (II) complex of the mycobactericidal drug isoniazid–Toxicity against Artemia salina | |
| CN114082434A (en) | Modified carbonitride, preparation and application thereof, and method for degrading pesticide chlorpyrifos | |
| Wu et al. | Nitrogen-doped MoS2 quantum dots: Facile synthesis and application for the assay of hematin in human blood | |
| Gonsalves et al. | Synthesis and characterization of ultrafine spinel ferrite obtained by precursor combustion technique | |
| Zhou et al. | Facile and High‐yield Synthesis of N‐doped Carbon Quantum Dots from Biomass Quinoa Saponin for the Detection of Co2+ | |
| Yadav et al. | Role of bio-based synthesized nanozinc oxide in ameliorating the deleterious effects caused by Lead in Vigna radiata L | |
| Wasly et al. | Novel synthesis, structural, optical properties and antibacterial activity of ZnO nanoparticles | |
| Xu et al. | Natural formation of copper sulfide nanoparticles via microbially mediated organic sulfur mineralization in soil: processes and mechanisms | |
| Li et al. | The age of vanadium-based nanozymes: Synthesis, catalytic mechanisms, regulation and biomedical applications | |
| Yang et al. | “Three-in-one” platform based on Fe-CDs nanozyme for dual-mode/dual-target detection and NIR-assisted bacterial killing | |
| Zhang et al. | Gold-modified ZnO nanocomposites for photo-Fenton-like catalysis of Escherichia coli disinfection | |
| Cepoi et al. | Changes in the Dunaliella salina biomass composition during silver nanoparticles formation | |
| Aouadi et al. | Unveiling the antioxidant power: synthesis and characterization of lemon and orange peel-derived carbon quantum dots with exceptional free radical scavenging activity | |
| Ngeontae et al. | A highly selective fluorescent sensor for manganese (II) ion detection based on N, S-doped carbon dots triggered by manganese oxide | |
| Hassanpour et al. | Toxicity evaluation and preparation of CoWO 4 nanoparticles towards microalga Dunaliella salina |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220225 |