CN114053881A - Preparation method of hydrogel filtering membrane for efficiently loading catalytic organic pollutants - Google Patents
Preparation method of hydrogel filtering membrane for efficiently loading catalytic organic pollutants Download PDFInfo
- Publication number
- CN114053881A CN114053881A CN202111495172.7A CN202111495172A CN114053881A CN 114053881 A CN114053881 A CN 114053881A CN 202111495172 A CN202111495172 A CN 202111495172A CN 114053881 A CN114053881 A CN 114053881A
- Authority
- CN
- China
- Prior art keywords
- membrane
- halloysite
- zero
- ions
- silicon dioxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012528 membrane Substances 0.000 title claims abstract description 45
- 239000000017 hydrogel Substances 0.000 title claims abstract description 32
- 238000001914 filtration Methods 0.000 title claims abstract description 30
- 238000011068 loading method Methods 0.000 title claims abstract description 26
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 23
- 239000002957 persistent organic pollutant Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 72
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 47
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 claims abstract description 44
- 229910052621 halloysite Inorganic materials 0.000 claims abstract description 44
- 239000007864 aqueous solution Substances 0.000 claims abstract description 35
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 34
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 34
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000000243 solution Substances 0.000 claims abstract description 21
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 20
- 230000001276 controlling effect Effects 0.000 claims abstract description 20
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 20
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 20
- 239000000661 sodium alginate Substances 0.000 claims abstract description 20
- 238000005266 casting Methods 0.000 claims abstract description 18
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract description 14
- 230000001105 regulatory effect Effects 0.000 claims abstract description 14
- 238000005406 washing Methods 0.000 claims abstract description 14
- 239000000126 substance Substances 0.000 claims abstract description 9
- 238000004132 cross linking Methods 0.000 claims abstract description 8
- 238000001035 drying Methods 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 238000002791 soaking Methods 0.000 claims abstract description 8
- 238000000967 suction filtration Methods 0.000 claims abstract description 8
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 6
- 239000012279 sodium borohydride Substances 0.000 claims abstract description 6
- 229910000033 sodium borohydride Inorganic materials 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 239000011521 glass Substances 0.000 claims description 24
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 18
- 229910001447 ferric ion Inorganic materials 0.000 claims description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- 230000001112 coagulating effect Effects 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- 125000005613 guluronic acid group Chemical group 0.000 claims description 12
- 150000002500 ions Chemical class 0.000 claims description 12
- 239000011259 mixed solution Substances 0.000 claims description 12
- 239000002071 nanotube Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- -1 iron ions Chemical class 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 238000002386 leaching Methods 0.000 claims description 7
- 238000001179 sorption measurement Methods 0.000 claims description 7
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 230000007062 hydrolysis Effects 0.000 claims description 6
- 238000006460 hydrolysis reaction Methods 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000003638 chemical reducing agent Substances 0.000 claims description 4
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 3
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 229930003268 Vitamin C Natural products 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 229910001422 barium ion Inorganic materials 0.000 claims description 3
- 229910001424 calcium ion Inorganic materials 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 235000019154 vitamin C Nutrition 0.000 claims description 3
- 239000011718 vitamin C Substances 0.000 claims description 3
- 229910052746 lanthanum Inorganic materials 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- 230000003115 biocidal effect Effects 0.000 claims 1
- 238000004042 decolorization Methods 0.000 claims 1
- 239000003054 catalyst Substances 0.000 abstract description 5
- 229920005597 polymer membrane Polymers 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000010865 sewage Substances 0.000 abstract description 3
- 229910021578 Iron(III) chloride Inorganic materials 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract description 2
- 238000007790 scraping Methods 0.000 abstract description 2
- 230000007935 neutral effect Effects 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002114 nanocomposite Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 238000010170 biological method Methods 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- CZMAIROVPAYCMU-UHFFFAOYSA-N lanthanum(3+) Chemical compound [La+3] CZMAIROVPAYCMU-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- STZCRXQWRGQSJD-GEEYTBSJSA-M methyl orange Chemical compound [Na+].C1=CC(N(C)C)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-GEEYTBSJSA-M 0.000 description 1
- 229940012189 methyl orange Drugs 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000001048 orange dye Substances 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/08—Polysaccharides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0079—Manufacture of membranes comprising organic and inorganic components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- B01J31/069—Hybrid organic-inorganic polymers, e.g. silica derivatized with organic groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/58—Fabrics or filaments
- B01J35/59—Membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/30—Cross-linking
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/308—Dyes; Colorants; Fluorescent agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/343—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the pharmaceutical industry, e.g. containing antibiotics
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111495172.7A CN114053881B (en) | 2021-12-09 | 2021-12-09 | Preparation method of hydrogel filtering membrane for efficiently loading and catalyzing organic pollutants |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111495172.7A CN114053881B (en) | 2021-12-09 | 2021-12-09 | Preparation method of hydrogel filtering membrane for efficiently loading and catalyzing organic pollutants |
Publications (2)
Publication Number | Publication Date |
---|---|
CN114053881A true CN114053881A (en) | 2022-02-18 |
CN114053881B CN114053881B (en) | 2024-04-05 |
Family
ID=80228970
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202111495172.7A Active CN114053881B (en) | 2021-12-09 | 2021-12-09 | Preparation method of hydrogel filtering membrane for efficiently loading and catalyzing organic pollutants |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN114053881B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115976689A (en) * | 2023-01-03 | 2023-04-18 | 青岛大学 | Preparation method of algal polysaccharide composite functional fiber |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20140131271A1 (en) * | 2012-11-15 | 2014-05-15 | The Hkust Fok Ying Tung Research Institute | Nanoporous ceramic membrane and preparation method thereof |
CN104528750A (en) * | 2014-12-12 | 2015-04-22 | 景德镇陶瓷学院 | Method for coating whitened kaolin by sol-gel method |
CN104759635A (en) * | 2015-03-12 | 2015-07-08 | 中国科学院福建物质结构研究所 | Preparation method of load type nanometer zero-valent iron composite material |
CN109260970A (en) * | 2018-11-19 | 2019-01-25 | 天津工业大学 | A kind of preparation method of high-intensity inorganic doping calcium alginate hydrogel filter membrane |
CN111111607A (en) * | 2018-10-31 | 2020-05-08 | 中国地质大学(北京) | Preparation method and application of modified kaolinite and nano zero-valent iron/modified kaolinite composite material |
-
2021
- 2021-12-09 CN CN202111495172.7A patent/CN114053881B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20140131271A1 (en) * | 2012-11-15 | 2014-05-15 | The Hkust Fok Ying Tung Research Institute | Nanoporous ceramic membrane and preparation method thereof |
CN104528750A (en) * | 2014-12-12 | 2015-04-22 | 景德镇陶瓷学院 | Method for coating whitened kaolin by sol-gel method |
CN104759635A (en) * | 2015-03-12 | 2015-07-08 | 中国科学院福建物质结构研究所 | Preparation method of load type nanometer zero-valent iron composite material |
CN111111607A (en) * | 2018-10-31 | 2020-05-08 | 中国地质大学(北京) | Preparation method and application of modified kaolinite and nano zero-valent iron/modified kaolinite composite material |
CN109260970A (en) * | 2018-11-19 | 2019-01-25 | 天津工业大学 | A kind of preparation method of high-intensity inorganic doping calcium alginate hydrogel filter membrane |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115976689A (en) * | 2023-01-03 | 2023-04-18 | 青岛大学 | Preparation method of algal polysaccharide composite functional fiber |
Also Published As
Publication number | Publication date |
---|---|
CN114053881B (en) | 2024-04-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103908952B (en) | A kind of load the porous material of nano zero-valence copper particle, preparation method and application | |
CN110170309B (en) | Two-dimensional metal organic framework composite membrane material, preparation method and application | |
CN102616881A (en) | Treatment process for printing and dyeing wastewater | |
CN108126650B (en) | Functional flexible inorganic porous fiber membrane, preparation method and application thereof in simultaneously removing oil stains and heavy metal ions in water | |
Lefebvre et al. | Polydopamine-coated open cell polyurethane foam as an efficient and easy-to-regenerate soft structured catalytic support (S2CS) for the reduction of dye | |
CN112933997B (en) | Preparation method and application of inorganic modified membrane based on in-situ reduction | |
Zhou et al. | BiOCl0. 875Br0. 125/polydopamine functionalized PVDF membrane for highly efficient visible-light-driven photocatalytic degradation of roxarsone and simultaneous arsenic immobilization | |
CN114053881B (en) | Preparation method of hydrogel filtering membrane for efficiently loading and catalyzing organic pollutants | |
CN109453753A (en) | A kind of floating vapor and its preparation method and application | |
CN109092360A (en) | A kind of preparation method of the nano hybridization gel mould for catalytic degradation organic matter | |
CN109304105B (en) | Forward osmosis membrane for efficiently adsorbing and removing heavy metal ions and preparation method and application thereof | |
CN112225382A (en) | Method for removing traditional Chinese medicine and personal care product in wastewater | |
CN115121232B (en) | Titanium dioxide self-cleaning film and preparation method and application thereof | |
Huang et al. | Laccase immobilization on hierarchical micro/nano porous chitin/graphene oxide beads prepared via Pickering emulsion template for dye decolorization | |
CN112206827B (en) | Polyvinyl alcohol supported palladium nano-flower water treatment catalyst and preparation method thereof | |
CN116078191A (en) | Preparation method of nano Jin Gaixing polysulfone membrane loaded on basis of dopamine coating | |
CN105148915A (en) | Fe3O4/Fe<0>/coke biomimetic catalyst capable of degrading POPs (persistent organic pollutants) and preparation method of catalyst | |
CN104907057A (en) | Spinning immobilized carbonyl iron material and application thereof in water treatment | |
CN104628192B (en) | A kind of processing method of oily waste water | |
CN102463108A (en) | Catalyst for processing azo dyes in printing and dyeing waste water and preparation method | |
CN108314174B (en) | Treatment process for degrading dye wastewater by catalyzing ozone | |
CN112316738A (en) | Method for preparing anti-pollution forward osmosis polyamide composite membrane through post-treatment | |
CN108218040B (en) | Treatment process for degrading printing and dyeing wastewater by catalytic ozone | |
CN114452818A (en) | Ultrafiltration membrane based on separation-catalysis structure and preparation method thereof | |
CN110713181A (en) | Modified graphene for removing metal ions in water, preparation method thereof, product containing modified graphene and application of modified graphene |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20240110 Address after: 1003, Building A, Zhiyun Industrial Park, No. 13 Huaxing Road, Henglang Community, Dalang Street, Longhua District, Shenzhen City, Guangdong Province, 518000 Applicant after: Shenzhen Wanzhida Technology Transfer Center Co.,Ltd. Address before: No. 399 Bingshui Road, Xiqing District, Tianjin, Tianjin Applicant before: TIANJIN POLYTECHNIC University |
|
TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20240304 Address after: 201400 floor 1-2, No.7 Lane 1088, Mingcheng Road, Fengxian District, Shanghai Applicant after: Shanghai Yuanyiqing Technology Co.,Ltd. Country or region after: Zhong Guo Address before: 1003, Building A, Zhiyun Industrial Park, No. 13 Huaxing Road, Henglang Community, Dalang Street, Longhua District, Shenzhen City, Guangdong Province, 518000 Applicant before: Shenzhen Wanzhida Technology Transfer Center Co.,Ltd. Country or region before: Zhong Guo |
|
GR01 | Patent grant | ||
GR01 | Patent grant |