CN114031348B - High-performance marine material concrete based on vitrified aggregate and preparation method and application thereof - Google Patents

High-performance marine material concrete based on vitrified aggregate and preparation method and application thereof Download PDF

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Publication number
CN114031348B
CN114031348B CN202111376289.3A CN202111376289A CN114031348B CN 114031348 B CN114031348 B CN 114031348B CN 202111376289 A CN202111376289 A CN 202111376289A CN 114031348 B CN114031348 B CN 114031348B
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aggregate
parts
concrete
porcelainized
cement
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CN114031348A (en
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王启春
许建华
朱英
李静
马近伟
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Shandong Shanke Ecological Environment Research Institute Co ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02Agglomerated materials, e.g. artificial aggregates
    • C04B18/023Fired or melted materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/24Sea water resistance
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention provides a high-performance marine material concrete based on vitrified aggregate and a preparation method and application thereof, belonging to the technical field of concrete preparation. The marine material high-performance concrete comprises the following raw materials: cement, vitrified aggregate, water, a rust inhibitor, a composite admixture and a high-efficiency water reducing agent. The vitrified aggregate prepared by adding the solid waste into the concrete raw material is used for replacing the traditional natural aggregate, so that the concrete has the functions of recycling the solid waste, protecting the environment and reducing the cost while ensuring the performances of the concrete such as durability, compressive strength, breaking strength and the like, and has good practical application value.

Description

High-performance marine material concrete based on vitrified aggregate and preparation method and application thereof
Technical Field
The invention belongs to the technical field of concrete preparation, and particularly relates to a high-performance concrete of a marine engineering material based on vitrified aggregates, and a preparation method and application thereof.
Background
The information disclosed in this background section is only for enhancement of understanding of the general background of the invention and is not necessarily to be construed as an admission or any form of suggestion that this information forms the prior art that is already known to a person of ordinary skill in the art.
In coastal areas of China, a large number of reinforced concrete structures of marine engineering work directly in marine environments, and concrete bears load and chloride ion corrosion for a long time, the durability problem is increasingly prominent, and particularly, the problem of reinforcement corrosion caused by chloride ions is one of important factors influencing the durability of concrete. However, with the continuous progress of concrete material science, people begin to research the concrete with high workability, high durability and good volume stability, namely high-performance concrete, and the high reinforcement is the direction of the concrete development for hundreds of years, especially in the marine environment and the pouring of high-temperature and high-humidity conditions and bridge piers and wharfs of the sea-crossing bridge.
As a concrete capable of meeting special performance and special purpose, the high-performance concrete marine material can not meet the performance requirement only by adopting the measures of conventional materials, common mixing, pouring, maintenance and the like, but can improve the long-term mechanical property, the initial strength, the rigidity and the volume stability of the concrete and prolong the service life of the concrete in a severe environment by improving the pouring and tamping methods, and the high-performance concrete not only needs high strength, but also has other important properties such as high durability, chemical corrosion resistance and the like, such as high volume stability, high elastic modulus, low dry shrinkage, low creep, low temperature strain, high impermeability and high working performance. Among them, the concrete with good dimensional stability is mainly characterized by high elastic modulus, low drying shrinkage, creep and small temperature strain rate. The concrete with good dimensional stability can reduce the loss of prestress and reduce the primary cracks of the concrete. In order to obtain good dimensional stability, it is necessary to limit the amount of cement used and to use a high-modulus, high-strength coarse aggregate. The high-performance marine concrete belongs to a cement-based porous building material, and in the composition, coarse aggregate and fine aggregate account for about 70% of the concrete, and are the main components of the concrete. But the corresponding manufacturing cost is obviously improved, so the cost of the high-performance concrete is further reduced while the high performance of the concrete is maintained.
Disclosure of Invention
Based on the defects of the prior art, the invention provides the marine engineering material high-performance concrete based on the porcelainized aggregate and the preparation method and the application thereof.
The invention provides a high-performance concrete of marine engineering materials based on vitrified aggregate, which comprises the following raw materials: cement, vitrified aggregate, water, a rust inhibitor, a composite admixture and a high-efficiency water reducing agent.
The marine material high-performance concrete is prepared from the following raw materials in parts by weight:
90-120 parts of cement, 520-300 parts of coarse porcelainized aggregate, 180-200 parts of fine porcelainized aggregate, 40-60 parts of water, 3-5 parts of rust inhibitor, 14-32 parts of composite admixture and 1-1.6 parts of high-efficiency water reducing agent.
Wherein the cement is portland cement or aluminate cement;
the grain diameter of the coarse porcelainized aggregate is 5-31.5 mm, and the grain diameter of the fine porcelainized aggregate is 1-5 mm (not containing 5 mm);
the rust inhibitor is a composite amino alcohol steel bar rust inhibitor.
The composite admixture is a mixture of silica fume, manganese slag and slag. More specifically, the mass ratio of the three components is 10-20:40-55:30-50.
In a second aspect of the present invention, there is provided a method for preparing the marine material high performance concrete, the method comprising:
uniformly mixing cement, a rust inhibitor, a composite admixture, a high-efficiency water reducing agent and water according to a proportion to obtain a mixture; adding the vitrified aggregate into the mixture, uniformly mixing, pouring into a mould, and curing and molding.
The third aspect of the invention provides the application of the marine material high-performance concrete in the field of building engineering.
The beneficial technical effects of one or more technical schemes are as follows:
(1) The marine engineering material high-performance concrete of the porcelain aggregate prepared by the technical scheme utilizes the porcelain aggregate and manganese slag to the maximum extent, realizes resource utilization and solves the environmental problems caused by the resource utilization.
(2) The marine material high-performance concrete of the porcelainized aggregate prepared by the technical scheme has the advantages of recycling solid wastes, saving cost and having good economic benefit.
(3) Compared with the traditional high-performance concrete, the marine material high-performance concrete with the porcelainized aggregate prepared by the technical scheme has the advantages that the volume stability, the high elastic modulus, the low shrinkage rate, the low creep, the low temperature strain, the high impermeability and the high working performance are obviously improved, and therefore, the marine material high-performance concrete has good practical application value.
Detailed Description
It should be noted that the following detailed description is exemplary and is intended to provide further explanation of the invention. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.
It is noted that the terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of example embodiments in accordance with the present application. As used herein, the singular forms "a", "an", and "the" are intended to include the plural forms as well, and it should be understood that when the terms "comprises" and/or "comprising" are used in this specification, they specify the presence of stated features, steps, operations, devices, components, and/or combinations thereof, unless the context clearly indicates otherwise.
In an exemplary embodiment of the invention, a marine material high-performance concrete based on vitrified aggregate is provided, and the marine material high-performance concrete comprises the following raw materials: cement, vitrified aggregate, water, a rust inhibitor, a composite admixture and a high-efficiency water reducing agent.
The marine material high-performance concrete is prepared from the following raw materials in parts by weight:
90-120 parts of cement, 520-300 parts of coarse porcelainized aggregate, 180-200 parts of fine porcelainized aggregate, 40-60 parts of water, 3-5 parts of rust inhibitor, 14-32 parts of composite admixture and 1-1.6 parts of high-efficiency water reducing agent.
Wherein the cement is portland cement or aluminate cement;
the grain diameter of the coarse porcelainized aggregate is 5-31.5 mm, and the grain diameter of the fine porcelainized aggregate is 1-5 mm (not containing 5 mm);
the rust inhibitor is a composite amino alcohol steel bar rust inhibitor.
The composite admixture is a mixture of silica fume, manganese slag and slag. More specifically, the mass ratio of the three components is 10-20:40-55:30-50.
In another embodiment of the present invention, the preparation method of the vitrified aggregate comprises: adding a binder into the solid waste, drying, grinding, sieving and forming; and sintering the formed biscuit aggregate at a sintering temperature of 1200 ℃ or above (such as 1300 ℃).
In another embodiment of the present invention, the prepared porcelainized aggregate is pulverized to obtain coarse porcelainized aggregate and fine porcelainized aggregate satisfying the above particle size requirements.
In another embodiment of the present invention, there is provided a method for preparing the marine material high performance concrete, the method comprising:
uniformly mixing cement, a rust inhibitor, a composite admixture, a high-efficiency water reducing agent and water according to a proportion to obtain a mixture; adding the vitrified aggregate into the mixture, uniformly mixing, pouring into a mould, and curing and molding.
In still another embodiment of the present invention, the surface of the molded article is covered with a plastic film during curing.
In another embodiment of the present invention, the application of the marine material high performance concrete in the field of building engineering is provided.
In yet another embodiment of the present invention, the construction engineering is marine construction engineering.
The invention is further illustrated by the following examples, which are not to be construed as limiting the invention thereto. It should be understood that these examples are for illustrative purposes only and are not intended to limit the scope of the present invention.
Example 1
A marine material high-performance concrete based on vitrified aggregate comprises the following components in parts by weight: 100 parts of Portland cement, 450 parts of coarse porcelainized aggregate (the particle size is 5-31.5 mm), 200 parts of fine porcelainized aggregate (the particle size is 1-5 mm), 45 parts of water, 4 parts of composite amino alcohol steel bar rust inhibitor, 23 parts of composite admixture and 1.4 parts of naphthalene water reducer.
The composite admixture is prepared by mixing 20 parts of silica fume, 40 parts of manganese slag and 40 parts of slag in parts by mass.
The preparation method of the vitrified aggregate comprises the following steps: adding the building solid waste into a binder, drying, grinding, sieving and forming; sintering the molded biscuit aggregate, wherein the sintering temperature is controlled to be 1300 ℃; and crushing and screening to obtain the coarse porcelainized aggregate and the fine porcelainized aggregate.
The preparation method of the marine material high-performance concrete based on the vitrified aggregate comprises the following steps:
cleaning the test mold, and coating a thin layer of engine oil on the inner wall of the test mold, so that the test mold is convenient to remove; cleaning and soaking the stirrer; rinsing the chamber, adding cement, water, the compound amino alcohol steel bar rust inhibitor, the compound admixture and the naphthalene water reducing agent according to the mass ratio of the materials, and uniformly stirring for 2min; making the surface of the paste in a saturated dry state; adding the vitrified aggregate into the stirrer in proportion, and uniformly stirring for 2min; the concrete preparation method of the uniformly stirred recycled concrete is the same as that of example 1.
Discharging from the blender; and discharging to obtain the vitrified aggregate concrete.
The vitrified aggregate concrete provided by the invention adopts vitrified aggregate to replace natural aggregate, ensures the dimensional stability, and has good dimensional stability, and the concrete with good dimensional stability is mainly characterized by high elastic modulus, low drying shrinkage, creep and small temperature strain rate, and the concrete with good dimensional stability can reduce the prestress loss and reduce the primary cracks of the concrete. Therefore, the durability, the compressive strength and the breaking strength of the vitrified aggregate concrete are improved, so that the solid waste is recycled, the environment is protected, the durability and the mechanical property of the prepared concrete are improved, and the vitrified aggregate concrete can be better applied to constructional engineering.
Example 2
A manufacturing method of marine material high-performance concrete based on vitrified aggregate comprises the following steps: 100 parts of portland cement, 300 parts of coarse porcelainized aggregate (the particle size is 5-31.5 mm), 200 parts of fine porcelainized aggregate (the particle size is 1-5 mm), 60 parts of water, 3 parts of composite amino alcohol steel bar rust inhibitor, 14 parts of composite admixture and 1 part of naphthalene water reducer.
The composite admixture is prepared by mixing 20 parts of silica fume, 40 parts of manganese slag and 40 parts of slag in parts by mass.
The specific preparation method is the same as that of example 1.
Example 3
A high-performance marine material concrete based on vitrified aggregate comprises the following components in parts by weight: 100 parts of portland cement, 500 parts of coarse porcelainized aggregate (the particle size is 5-31.5 mm), 180 parts of fine porcelainized aggregate (the particle size is 1-5 mm), 40 parts of water, 3 parts of composite amino alcohol steel bar rust inhibitor, 14 parts of composite admixture and 1 part of naphthalene water reducer.
The composite admixture is prepared by mixing 20 parts of silica fume, 40 parts of manganese slag and 40 parts of slag in parts by mass.
The specific preparation method is the same as that of example 1.
Example 4
A method for manufacturing marine material high-performance concrete based on vitrified aggregate comprises the following steps: 100 parts of portland cement, 450 parts of coarse porcelain aggregate (the particle size is 5-31.5 mm), 180 parts of fine porcelain aggregate (the particle size is 1-5 mm), 40 parts of water, 3 parts of composite amino alcohol steel bar rust inhibitor, 16 parts of composite admixture and 1.6 parts of naphthalene water reducer.
The composite admixture is prepared by mixing 20 parts of silica fume, 40 parts of manganese slag and 40 parts of slag in parts by mass.
The specific preparation method is the same as that of example 1.
Comparative example 1
The components, the mass ratio and the preparation method of the marine material high-performance concrete based on the vitrified aggregate are the same as those in the embodiment 1, and the difference is that the marine material high-performance concrete does not contain silica fume and manganese slag.
Comparative example 2
The components, mass ratio and preparation method of the marine material high-performance concrete based on the vitrified aggregate are the same as those of the embodiment 1, except that silica fume and slag are not contained.
Comparative example 3
The components, the mass ratio and the preparation method of the marine material high-performance concrete based on the vitrified aggregate are the same as those in the embodiment 1, and the marine material high-performance concrete is different from the marine material high-performance concrete in that the marine material high-performance concrete does not contain silica fume, manganese slag and slag.
Comparative example 4
The components, the mass ratio and the preparation method of the marine material high-performance concrete based on the vitrified aggregate are the same as those in the embodiment 1, and the difference is that manganese slag and slag are not contained.
Performance testing
1. Test method
The concrete prepared in the examples and the comparative examples is put into a mold; the mould filled with the recycled concrete is vibrated in an insertion mode, and the mould is quickly inserted, slowly pulled and slowly moved clockwise or anticlockwise to achieve uniform compaction; after vibration molding, standing the test piece in an indoor environment for natural maintenance, watering the periphery of the mold, and covering the surface of the mold with a waterproof plastic film; standing for 24 hours, removing the mold, continuously standing the test piece in an indoor environment for natural maintenance, watering the test piece no less than twice a day during the maintenance period, and keeping the surface of the test piece moist; after 7 days of curing, the test piece was taken out and left to stand for 1 day.
(1) And (3) testing the compressive strength: CO88PN100/AZ/0001 model press, G/B loading rate 0.5MPa/s.
(2) And (3) testing the breaking strength: the G/B loading rate of the electro-hydraulic servo fatigue testing machine is 0.5MPa/s.
(3) Durability soak test: a large-scale marine soaking durability test system is simulated, and the accelerated corrosion temperature is 40 ℃.
2. Test results
TABLE 1 concrete test piece Performance test results of examples and comparative examples (7 d)
Figure BDA0003364040610000081
Figure BDA0003364040610000091
As can be seen from the results in table 1, the compressive strength and flexural strength of the vitrified aggregate concrete prepared in examples 1 to 4 are improved to a certain extent and also improved to a certain extent in durability compared to the concrete without silica fume, manganese slag and slag in comparative example 3, the concrete with slag only in comparative example 1, manganese slag only in comparative example 2, and silica fume only in comparative example 4 may cause too low early strength and ultimate tensile value of the concrete, so that the concrete cannot withstand early temperature stress and dry shrinkage stress to cause structural cracking and loss of concrete strength, the mechanical properties of the concrete are improved to a certain extent by adding silica fume only, and the mechanical properties of the concrete are not improved to the best effect, possibly due to the alkali-aggregate reaction between silica in silica fume and alkaline substances in cement, although the mechanical properties of the concrete are not improved, the slag or silica fume or manganese slag alone are not improved greatly, while the concrete with no mineral admixture in comparative example 3 is added, and the mechanical properties of the concrete are improved to a certain extent, but the best effect is not achieved. The compressive strength of the large-doping-amount manganese slag, the slag and the silica fume which are mixed in different proportions is higher than the strength and the durability of concrete without doping. The composite mineral admixture forms good micro-gradation in the concrete, and the morphological effect, the interface effect, the micro-aggregate effect, the volcanic ash effect and the like are interactively superposed, so that the corrosion resistance and the durability of the concrete are obviously improved. Based on the interactive additive effect of the composite mineral admixture, through the matching of the mineral admixture, the parameters such as the mixing amount proportion of the mineral admixture and the like are reasonably controlled, and the composite effect of the composite mineral admixture is exerted to the maximum extent so as to meet the technical requirements of maritime work high-performance concrete and form the obvious gain effect on the corrosion resistance and the durability of the concrete, such as the chlorine ion corrosion resistance and the like. Aiming at the gain effect of the composite mineral admixture with large mixing amount on the marine high-performance concrete, the ceramic aggregate concrete has certain enhancement effect on the compressive strength and the flexural strength of the ceramic aggregate concrete, and has better durability.
Finally, it should be noted that, although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that modifications may be made to the embodiments described in the foregoing embodiments, or equivalents may be substituted for elements thereof. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention. Although the present invention has been described with reference to the specific embodiments, it should be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention.

Claims (3)

1. The marine material high-performance concrete based on the vitrified aggregate is characterized by comprising cement, the vitrified aggregate, water, a rust inhibitor, a composite admixture and a high-efficiency water reducing agent;
the cement is portland cement or aluminate cement;
the rust inhibitor is a composite amino alcohol steel bar rust inhibitor;
the composite admixture is a mixture of silica fume, manganese slag and slag; the mass ratio of the silica fume to the manganese slag to the slag is 10-20:40-55:30-50;
the preparation method of the porcelainized aggregate comprises the following steps: adding the solid waste into a binder, drying, grinding, sieving and forming; sintering the molded biscuit aggregate at the sintering temperature of 1200 ℃ or above, and crushing and screening to obtain coarse porcelainized aggregate and fine porcelainized aggregate;
the marine material high-performance concrete comprises the following raw materials in parts by weight:
90-120 parts of cement, 520-300 parts of coarse porcelainized aggregate, 180-200 parts of fine porcelainized aggregate, 40-60 parts of water, 3-5 parts of rust inhibitor, 14-32 parts of composite admixture and 1-1.6 parts of high-efficiency water reducing agent;
the high-performance concrete of the marine material is applied to marine construction engineering.
2. The marine material high performance concrete of claim 1, wherein the coarse porcelainized aggregate has a particle size of 5 to 31.5mm, and the fine porcelainized aggregate has a particle size of 1 to 5mm, excluding 5 mm.
3. A method for preparing a high performance concrete of marine material as claimed in any one of claims 1-2, said method comprising:
uniformly mixing cement, a rust inhibitor, a composite admixture, a high-efficiency water reducing agent and water according to a proportion to obtain a mixture; adding the vitrified aggregate into the mixture, uniformly mixing, pouring into a mould, and curing and molding.
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