Disclosure of Invention
The invention aims to provide a preparation method of plant modified asphalt as a waterproof material, which is simple and has the advantages of strong adhesive force, no cracking, small seepage force and good waterproof effect.
In order to achieve the purpose, the technical scheme of the invention is as follows:
a preparation method of plant modified asphalt used as a waterproof material comprises the following raw materials in parts by weight: 60-90 parts of plant asphalt, 30-40 parts of petroleum asphalt, 2-6 parts of plasticizer, 8-10 parts of rubber powder, 10-15 parts of linearized active rubber, 3-6 parts of talcum powder and 4-8 parts of combined auxiliary agent; the preparation method comprises the following steps:
s1: mixing plant asphalt and plant asphalt in corresponding parts by weight to obtain a mixture A;
s2: heating the mixture A to 200-210 ℃, and shearing and stirring the plasticizer, the rubber powder and the linearized active rubber in corresponding parts by weight for 20-30min to obtain a mixture B;
s3: and cooling the mixture B to 170-180 ℃, adding talcum powder and a combined auxiliary agent, shearing and stirring for 15-20min, cooling to 140-150 ℃, and keeping the temperature and stirring for 60-120min to obtain the waterproof material plant modified asphalt.
Further, the preparation method of the linearized active rubber related to the invention refers to the method of CN109776856A for preparing the linearized active rubber by using waste rubber.
Preferably, the plant asphalt is waste generated in the processing process of soybean oil or rapeseed oil, and is refined by a biological method; the petroleum asphalt is 90# asphalt.
Preferably, the plasticizer is paraffin oil or vaseline.
Preferably, the combination auxiliary agent is prepared by the following steps:
and (3) preparing graphene oxide: dispersing agent: extreme pressure agent: viscosity index improver: accelerator TT: absolute ethanol was mixed at a ratio of 0.58: 0.6: adding the mixture into a stirrer at a ratio of 2:1:4:50 for dispersing to obtain a uniform mixed solution, and drying and granulating the mixed solution by using a spray dryer to obtain the combined auxiliary agent with the average particle size of 40 microns.
Preferably, the dispersant is T154A polyisobutenyl succinimide, the extreme pressure agent is T321 sulfurized isobutylene, and the viscosity index improver is polymethyl methacrylate.
Preferably, the mixing temperature in the step S1 is 170 ℃, the rotation speed of the shearing stirring is 2500-3000r/min, and the time of the shearing stirring is 25-30 min.
Preferably, the rotation speed of the shearing stirring in the step S2 is 2200-; the rotation speed of the shearing and stirring in the step S3 is 3000-3500 r/min; the rotation speed of the heat preservation stirring in the step S3 is 2500-.
The invention has the beneficial effects that: the invention provides a preparation method of plant modified asphalt as a waterproof material, which is simple and has the advantages of strong adhesive force, no cracking, small seepage force and good waterproof effect.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
A preparation method of plant modified asphalt used as a waterproof material comprises the following raw materials in parts by weight: 60 parts of plant asphalt, 30 parts of petroleum asphalt, 2 parts of plasticizer, 8 parts of rubber powder, 10 parts of linearized active rubber, 3 parts of talcum powder and 4 parts of combined auxiliary agent; the preparation method comprises the following steps:
s1: mixing plant asphalt and plant asphalt in corresponding parts by weight to obtain a mixture A;
s2: heating the mixture A to 200-210 ℃, and shearing and stirring the plasticizer, the rubber powder and the linearized active rubber in corresponding parts by weight for 20-30min to obtain a mixture B;
s3: and cooling the mixture B to 170-180 ℃, adding talcum powder and a combined auxiliary agent, shearing and stirring for 15-20min, cooling to 140-150 ℃, and keeping the temperature and stirring for 60-120min to obtain the waterproof material plant modified asphalt.
Preferably, the plant asphalt is waste generated in the processing process of soybean oil, and is refined by a biological method; the petroleum asphalt is 90# asphalt.
Preferably, the plasticizer is paraffin oil.
Preferably, the combination auxiliary agent is prepared by the following steps:
and (3) preparing graphene oxide: dispersing agent: extreme pressure agent: viscosity index improver: accelerator TT: absolute ethanol was mixed at a ratio of 0.58: 0.6: adding the mixture into a stirrer at a ratio of 2:1:4:50 for dispersing to obtain a uniform mixed solution, and drying and granulating the mixed solution by using a spray dryer to obtain the combined auxiliary agent with the average particle size of 40 microns.
Preferably, the dispersant is T154A polyisobutenyl succinimide, the extreme pressure agent is T321 sulfurized isobutylene, and the viscosity index improver is polymethyl methacrylate.
Preferably, the mixing temperature in the step S1 is 170 ℃, the rotation speed of the shearing stirring is 2500-3000r/min, and the time of the shearing stirring is 25-30 min.
Preferably, the rotation speed of the shearing stirring in the step S2 is 2200-; the rotation speed of the shearing and stirring in the step S3 is 3000-3500 r/min; the rotation speed of the heat preservation stirring in the step S3 is 2500-.
Example 2
A preparation method of plant modified asphalt used as a waterproof material comprises the following raw materials in parts by weight: 90 parts of plant asphalt, 40 parts of petroleum asphalt, 6 parts of plasticizer, 10 parts of rubber powder, 15 parts of linearized active rubber, 6 parts of talcum powder and 8 parts of combined auxiliary agent; the preparation method comprises the following steps:
s1: mixing plant asphalt and plant asphalt in corresponding parts by weight to obtain a mixture A;
s2: heating the mixture A to 200-210 ℃, and shearing and stirring the plasticizer, the rubber powder and the linearized active rubber in corresponding parts by weight for 20-30min to obtain a mixture B;
s3: and cooling the mixture B to 170-180 ℃, adding talcum powder and a combined auxiliary agent, shearing and stirring for 15-20min, cooling to 140-150 ℃, and keeping the temperature and stirring for 60-120min to obtain the waterproof material plant modified asphalt.
Preferably, the plant asphalt is waste generated in the processing process of the rapeseed oil, and is refined by a biological method; the petroleum asphalt is 90# asphalt.
Preferably, the plasticizer is petrolatum.
Preferably, the combination auxiliary agent is prepared by the following steps:
and (3) preparing graphene oxide: dispersing agent: extreme pressure agent: viscosity index improver: accelerator TT: absolute ethanol was mixed at a ratio of 0.58: 0.6: adding the mixture into a stirrer at a ratio of 2:1:4:50 for dispersing to obtain a uniform mixed solution, and drying and granulating the mixed solution by using a spray dryer to obtain the combined auxiliary agent with the average particle size of 40 microns.
Preferably, the dispersant is T154A polyisobutenyl succinimide, the extreme pressure agent is T321 sulfurized isobutylene, and the viscosity index improver is polymethyl methacrylate.
Preferably, the mixing temperature in the step S1 is 170 ℃, the rotation speed of the shearing stirring is 2500-3000r/min, and the time of the shearing stirring is 25-30 min.
Preferably, the rotation speed of the shearing stirring in the step S2 is 2200-; the rotation speed of the shearing and stirring in the step S3 is 3000-3500 r/min; the rotation speed of the heat preservation stirring in the step S3 is 2500-.
Example 3
A preparation method of plant modified asphalt used as a waterproof material comprises the following raw materials in parts by weight: 70 parts of plant asphalt, 33 parts of petroleum asphalt, 3 parts of plasticizer, 9 parts of rubber powder, 11 parts of linearized active rubber, 4 parts of talcum powder and 5 parts of combined auxiliary agent; the preparation method comprises the following steps:
s1: mixing plant asphalt and plant asphalt in corresponding parts by weight to obtain a mixture A;
s2: heating the mixture A to 200-210 ℃, and shearing and stirring the plasticizer, the rubber powder and the linearized active rubber in corresponding parts by weight for 20-30min to obtain a mixture B;
s3: and cooling the mixture B to 170-180 ℃, adding talcum powder and a combined auxiliary agent, shearing and stirring for 15-20min, cooling to 140-150 ℃, and keeping the temperature and stirring for 60-120min to obtain the waterproof material plant modified asphalt.
Preferably, the plant asphalt is waste generated in the processing process of soybean oil, and is refined by a biological method; the petroleum asphalt is 90# asphalt.
Preferably, the plasticizer is paraffin oil.
Preferably, the combination auxiliary agent is prepared by the following steps:
and (3) preparing graphene oxide: dispersing agent: extreme pressure agent: viscosity index improver: accelerator TT: absolute ethanol was mixed at a ratio of 0.58: 0.6: adding the mixture into a stirrer at a ratio of 2:1:4:50 for dispersing to obtain a uniform mixed solution, and drying and granulating the mixed solution by using a spray dryer to obtain the combined auxiliary agent with the average particle size of 40 microns.
Preferably, the dispersant is T154A polyisobutenyl succinimide, the extreme pressure agent is T321 sulfurized isobutylene, and the viscosity index improver is polymethyl methacrylate.
Preferably, the mixing temperature in the step S1 is 170 ℃, the rotation speed of the shearing stirring is 2500-3000r/min, and the time of the shearing stirring is 25-30 min.
Preferably, the rotation speed of the shearing stirring in the step S2 is 2200-; the rotation speed of the shearing and stirring in the step S3 is 3000-3500 r/min; the rotation speed of the heat preservation stirring in the step S3 is 2500-.
Example 4
A preparation method of plant modified asphalt used as a waterproof material comprises the following raw materials in parts by weight: 75 parts of plant asphalt, 35 parts of petroleum asphalt, 4 parts of plasticizer, 9 parts of rubber powder, 13 parts of linearized active rubber, 5 parts of talcum powder and 6 parts of combined auxiliary agent; the preparation method comprises the following steps:
s1: mixing plant asphalt and plant asphalt in corresponding parts by weight to obtain a mixture A;
s2: heating the mixture A to 200-210 ℃, and shearing and stirring the plasticizer, the rubber powder and the linearized active rubber in corresponding parts by weight for 20-30min to obtain a mixture B;
s3: and cooling the mixture B to 170-180 ℃, adding talcum powder and a combined auxiliary agent, shearing and stirring for 15-20min, cooling to 140-150 ℃, and keeping the temperature and stirring for 60-120min to obtain the waterproof material plant modified asphalt.
Preferably, the plant asphalt is waste generated in the processing process of the rapeseed oil, and is refined by a biological method; the petroleum asphalt is 90# asphalt.
Preferably, the plasticizer is petrolatum.
Preferably, the combination auxiliary agent is prepared by the following steps:
and (3) preparing graphene oxide: dispersing agent: extreme pressure agent: viscosity index improver: accelerator TT: absolute ethanol was mixed at a ratio of 0.58: 0.6: adding the mixture into a stirrer at a ratio of 2:1:4:50 for dispersing to obtain a uniform mixed solution, and drying and granulating the mixed solution by using a spray dryer to obtain the combined auxiliary agent with the average particle size of 40 microns.
Preferably, the dispersant is T154A polyisobutenyl succinimide, the extreme pressure agent is T321 sulfurized isobutylene, and the viscosity index improver is polymethyl methacrylate.
Preferably, the mixing temperature in the step S1 is 170 ℃, the rotation speed of the shearing stirring is 2500-3000r/min, and the time of the shearing stirring is 25-30 min.
Preferably, the rotation speed of the shearing stirring in the step S2 is 2200-; the rotation speed of the shearing and stirring in the step S3 is 3000-3500 r/min; the rotation speed of the heat preservation stirring in the step S3 is 2500-.
Example 5
A preparation method of plant modified asphalt used as a waterproof material comprises the following raw materials in parts by weight: 88 parts of plant asphalt, 36 parts of petroleum asphalt, 5.5 parts of plasticizer, 9 parts of rubber powder, 14 parts of linearized active rubber, 5 parts of talcum powder and 7 parts of combined auxiliary agent; the preparation method comprises the following steps:
s1: mixing plant asphalt and plant asphalt in corresponding parts by weight to obtain a mixture A;
s2: heating the mixture A to 200-210 ℃, and shearing and stirring the plasticizer, the rubber powder and the linearized active rubber in corresponding parts by weight for 20-30min to obtain a mixture B;
s3: and cooling the mixture B to 170-180 ℃, adding talcum powder and a combined auxiliary agent, shearing and stirring for 15-20min, cooling to 140-150 ℃, and keeping the temperature and stirring for 60-120min to obtain the waterproof material plant modified asphalt.
Preferably, the plant asphalt is waste generated in the processing process of the rapeseed oil, and is refined by a biological method; the petroleum asphalt is 90# asphalt.
Preferably, the plasticizer is petrolatum.
Preferably, the combination auxiliary agent is prepared by the following steps:
and (3) preparing graphene oxide: dispersing agent: extreme pressure agent: viscosity index improver: accelerator TT: absolute ethanol was mixed at a ratio of 0.58: 0.6: adding the mixture into a stirrer at a ratio of 2:1:4:50 for dispersing to obtain a uniform mixed solution, and drying and granulating the mixed solution by using a spray dryer to obtain the combined auxiliary agent with the average particle size of 40 microns.
Preferably, the dispersant is T154A polyisobutenyl succinimide, the extreme pressure agent is T321 sulfurized isobutylene, and the viscosity index improver is polymethyl methacrylate.
Preferably, the mixing temperature in the step S1 is 170 ℃, the rotation speed of the shearing stirring is 2500-3000r/min, and the time of the shearing stirring is 25-30 min.
Preferably, the rotation speed of the shearing stirring in the step S2 is 2200-; the rotation speed of the shearing and stirring in the step S3 is 3000-3500 r/min; the rotation speed of the heat preservation stirring in the step S3 is 2500-.
The plant modified asphalt provided by the invention has excellent waterproof effect, is simple in raw materials and preparation method, has the advantages of good heat resistance, aging resistance, good impermeability, strong cohesive force and good toughness, has the effects of corrosion resistance and mildew resistance, and is suitable for various severe environments.
Finally, the above embodiments are only for illustrating the technical solutions of the present invention and not for limiting, although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made to the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, and all of them should be covered in the claims of the present invention.