CN114010527A - Artificial melanin hair dye with moisturizing function and preparation method and use method thereof - Google Patents
Artificial melanin hair dye with moisturizing function and preparation method and use method thereof Download PDFInfo
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- CN114010527A CN114010527A CN202111539480.5A CN202111539480A CN114010527A CN 114010527 A CN114010527 A CN 114010527A CN 202111539480 A CN202111539480 A CN 202111539480A CN 114010527 A CN114010527 A CN 114010527A
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- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 239000000118 hair dye Substances 0.000 title claims abstract description 26
- 230000003020 moisturizing effect Effects 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 102
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 57
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 55
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 34
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 34
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims abstract description 34
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 34
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 34
- 239000008117 stearic acid Substances 0.000 claims abstract description 34
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 32
- SGNZYJXNUURYCH-UHFFFAOYSA-N 5,6-dihydroxyindole Chemical compound C1=C(O)C(O)=CC2=C1NC=C2 SGNZYJXNUURYCH-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 22
- 102000011782 Keratins Human genes 0.000 claims abstract description 19
- 108010076876 Keratins Proteins 0.000 claims abstract description 19
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 18
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 18
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 claims abstract description 18
- 235000018417 cysteine Nutrition 0.000 claims abstract description 18
- 229940082500 cetostearyl alcohol Drugs 0.000 claims abstract description 17
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 claims abstract description 17
- 230000007062 hydrolysis Effects 0.000 claims abstract description 15
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 15
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical compound [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims description 17
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 4
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 239000012071 phase Substances 0.000 claims 6
- 239000008346 aqueous phase Substances 0.000 claims 2
- 238000001816 cooling Methods 0.000 claims 2
- 230000002209 hydrophobic effect Effects 0.000 abstract description 5
- 206010019049 Hair texture abnormal Diseases 0.000 abstract description 4
- 230000002194 synthesizing effect Effects 0.000 abstract description 2
- 229940081733 cetearyl alcohol Drugs 0.000 description 17
- 238000004043 dyeing Methods 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 12
- 230000014759 maintenance of location Effects 0.000 description 8
- 230000000694 effects Effects 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- PMBXCGGQNSVESQ-UHFFFAOYSA-N 1-Hexanethiol Chemical compound CCCCCCS PMBXCGGQNSVESQ-UHFFFAOYSA-N 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000003906 humectant Substances 0.000 description 2
- 239000011664 nicotinic acid Substances 0.000 description 2
- YCOZIPAWZNQLMR-UHFFFAOYSA-N pentadecane Chemical compound CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- 241001391944 Commicarpus scandens Species 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- 208000010340 Sleep Deprivation Diseases 0.000 description 1
- 206010042674 Swelling Diseases 0.000 description 1
- 206010000496 acne Diseases 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- VTXVGVNLYGSIAR-UHFFFAOYSA-N decane-1-thiol Chemical compound CCCCCCCCCCS VTXVGVNLYGSIAR-UHFFFAOYSA-N 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 210000003128 head Anatomy 0.000 description 1
- ORTRWBYBJVGVQC-UHFFFAOYSA-N hexadecane-1-thiol Chemical compound CCCCCCCCCCCCCCCCS ORTRWBYBJVGVQC-UHFFFAOYSA-N 0.000 description 1
- 238000000338 in vitro Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 230000008099 melanin synthesis Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- ZVEZMVFBMOOHAT-UHFFFAOYSA-N nonane-1-thiol Chemical compound CCCCCCCCCS ZVEZMVFBMOOHAT-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229940038384 octadecane Drugs 0.000 description 1
- QJAOYSPHSNGHNC-UHFFFAOYSA-N octadecane-1-thiol Chemical compound CCCCCCCCCCCCCCCCCCS QJAOYSPHSNGHNC-UHFFFAOYSA-N 0.000 description 1
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000001024 permanent hair color Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- GEKDEMKPCKTKEC-UHFFFAOYSA-N tetradecane-1-thiol Chemical compound CCCCCCCCCCCCCCS GEKDEMKPCKTKEC-UHFFFAOYSA-N 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
- A61K8/492—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid having condensed rings, e.g. indol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/447—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
- A61K2800/882—Mixing prior to application
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- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses an artificial melanin hair dye with a moisturizing function, a preparation method and a use method thereof, wherein the hair dye comprises a first agent and a second agent, and the first agent comprises the following components: six to eighteen mercapto carbon: 1% -2%, 5, 6-dihydroxyindole: 1% -3%, stearic acid: 5% -10%, cetostearyl alcohol: 5% -10%, sodium dodecyl benzene sulfonate: 0.2% -1.5%, propylene glycol: 4% -9%, cysteine: 1% -4%, hydrolysis of keratin: 1% and a proper amount of ammonia water for adjusting the pH to 9-10; the balance of water; the second agent consists of the following components: hydrogen peroxide: 8% -20%, stearic acid: 5% -10%, cetostearyl alcohol: 5% -10%, propylene glycol: 4% -9%, sodium dodecyl benzene sulfonate: 0.2 to 1.5 percent of water and the balance of water. In the process of synthesizing melanin, the hydrophobic sulfhydryl carbon chain can reduce water loss in hair, so that the hair is kept moist and not dry, and the hair dye is particularly suitable for people who easily dry hair.
Description
Technical Field
The invention belongs to the field of daily chemicals, and particularly relates to an artificial melanin hair dye with a moisturizing function, and a preparation method and a use method thereof.
Background
With the ever-increasing pace of life and increasing pressure on life, graying of hair occurs not only in the elderly population but also gradually in youthful maturity. The hair dyeing can change the color and brightness of hair, and becomes an important choice for people to have healthy and bright hair. The traditional hair dyeing products on the market at present generally contain raw materials of p-phenylenediamine chemical sources, and once the hair dyeing products are stained on the surface of scalp, the hair dyeing products not only easily cause allergic reactions such as pimples, red swelling, pruritus, scurf and the like, but also have certain carcinogenic effect. In addition, the traditional hair dyeing products cannot give consideration to the problem of dry hair after dyeing. And factors such as ultraviolet ray invasion in sunlight, chemical substance damage, insufficient sleep for a long time, excessive fatigue and the like can cause the hair to lose moisture and moisten grease, so that the hair is withered, yellow, dry and easy to break.
The existing hair dye containing 5, 6-dihydroxyindole melanin gradually exposes the horns of the head. Research shows that tyrosine in human body is catalyzed and oxidized to form active intermediate 5, 6-dihydroxyindole, which is further oxidized to form melanin. Due to the activity of the 5, 6-dihydroxyindole intermediate, the intermediate is easy to oxidize and self-polymerize under the conditions of alkalinity and air, and does not need the stimulation of an initiator. The bionic hair dye is used for bionic hair dyeing by using the active intermediate in vitro, is green and safe, and can be used as a permanent hair dye. However, the existing hair dye of 5, 6-dihydroxyindole melanin cannot avoid the problem that hair is damaged and easy to dry after hair dyeing.
Disclosure of Invention
The invention aims to provide an artificial melanin hair dye with a moisturizing function, and a preparation method and a use method thereof.
The technical scheme of the invention is as follows:
the artificial melanin hair dye with the moisturizing function comprises a first agent and a second agent;
the first agent consists of the following components in percentage by mass:
six to eighteen mercapto carbon: 1% -2%, 5, 6-dihydroxyindole: 1% -3%, stearic acid: 5% -10%, cetostearyl alcohol: 5% -10%, sodium dodecyl benzene sulfonate: 0.2% -1.5%, propylene glycol: 4% -9%, cysteine: 1% -4%, hydrolysis of keratin: 1% and a proper amount of ammonia water for adjusting the pH to 9-10; the balance of water, the mass percent of each component is 100 percent;
the second agent comprises the following components in percentage by mass:
hydrogen peroxide: 8% -20%, stearic acid: 5% -10%, cetostearyl alcohol: 5% -10%, propylene glycol: 4% -9%, sodium dodecyl benzene sulfonate: 0.2 to 1.5 percent of water, and the balance of water, wherein the mass percent of all the components is 100 percent.
The chemical formulas of six to eighteen mercapto carbons are shown in Table 1.
TABLE 1 chemical formula of six-eighteen mercapto carbon
| Categories | Molecular formula | Categories | Molecular formula |
| Mercapto group carbon six | Hexanethiol: CH (CH)3(CH2)5SH | Mercapto group C thirteen | Tridecethiol: CH (CH)3(CH2)12SH |
| Mercapto carbon seven | Heptathiol: CH (CH)3(CH2)6SH | Mercapto carbon fourteen | Tetradecanethiol: CH (CH)3(CH2)13SH |
| Mercapto group carbon eight | Octyl mercaptan: CH (CH)3(CH2)7SH | Mercapto-carbon pentadecane | Pentadecathiol: CH (CH)3(CH2)14SH |
| Mercapto group carbon nine | Nonanethiol: CH (CH)3(CH2)8SH | Mercapto carbon sixteen | Hexadecanethiol: CH (CH)3(CH2)15SH |
| Mercapto group carbon ten | Decyl mercaptan: CH (CH)3(CH2)9SH | Mercapto-carbon seventeen | Heptadecamercaptan: CH (CH)3(CH2)16SH |
| Mercapto-carbon eleven | Undecanol: CH (CH)3(CH2)10SH | Mercapto carbo-octadecane | Octadecanethiol: CH (CH)3(CH2)17SH |
| Mercapto carbon twelve | Dodecyl mercaptan: CH (CH)3(CH2)11SH |
Preferably, the first agent of the artificial melanin hair dye consists of the following components:
nine to eighteen mercapto carbons: 1% -2%, 5, 6-dihydroxyindole: 1% -3%, stearic acid: 5% -10%, cetostearyl alcohol: 5% -10%, sodium dodecyl benzene sulfonate: 0.2% -1.5%, propylene glycol: 4% -9%, cysteine: 1% -4%, hydrolysis of keratin: 1% and a proper amount of ammonia water for adjusting the pH to 9-10; the balance of water, the mass percent of each component is 100 percent.
As a further preference, the artificial melanin hair dye first agent is composed of the following components:
tetradecyl to eighteen mercapto groups: 1% -2%, 5, 6-dihydroxyindole: 1% -3%, stearic acid: 5% -10%, cetostearyl alcohol: 5% -10%, sodium dodecyl benzene sulfonate: 0.2% -1.5%, propylene glycol: 4% -9%, cysteine: 1% -4%, hydrolysis of keratin: 1% and a proper amount of ammonia water for adjusting the pH to 9-10; the balance of water, the mass percent of each component is 100 percent.
In the first agent, sulfhydryl carbon chain is hydrophobic agent, 5, 6-dihydroxyindole is coloring agent, stearic acid and cetostearyl alcohol are solubilizer, sodium dodecyl benzene sulfonate and cysteine are reducing agents, propylene glycol is humectant, hydrolyzed keratin is hair conditioner, and ammonia water is pH regulator. In the second agent, hydrogen peroxide is used as an oxidizing agent, stearic acid and cetearyl alcohol are used as solubilizers, propylene glycol is used as a humectant, and sodium dodecyl benzene sulfonate is used as a reducing agent.
In the invention, 5, 6-dihydroxyindole acts on hair keratin fibers, and the hydrophobic sulfydryl carbon chain can reduce water loss in hair in the process of synthesizing melanin, keep the hair moist and not dry, and reduce or even eliminate hair dryness.
The preparation method of the artificial melanin hair dye with the moisturizing function comprises the preparation of a first agent, and comprises the following steps:
(1-1) mixing stearic acid, cetostearyl alcohol and mercapto carbon chains, and heating to 70-90 ℃ to obtain an oil phase;
(1-2) mixing and heating sodium dodecyl benzene sulfonate, propylene glycol, cysteine, hydrolyzed keratin and water to 70-90 ℃ to obtain a water phase;
(1-3) adding the water phase into the oil phase, stirring for 2-8 min, and then reducing the temperature to room temperature;
(1-4) adding ammonia water to adjust the pH value to 9-10, adding 5, 6-dihydroxyindole, and mixing to obtain a first agent;
the amounts of the above-mentioned raw materials are referred to the above.
The preparation method of the artificial melanin hair dye with the moisturizing function comprises the preparation of a second agent, and comprises the following steps:
(2-1) mixing stearic acid and cetostearyl alcohol, and heating to 70-90 ℃ to obtain an oil phase;
(2-2) mixing and heating sodium dodecyl benzene sulfonate, propylene glycol and water to 70-90 ℃ to obtain a water phase;
(2-3) adding the water phase into the oil phase, stirring for 2-8 min, and then reducing the temperature to room temperature;
(2-4) adding hydrogen peroxide and mixing to obtain a second agent;
the amounts of the above-mentioned raw materials are referred to the above.
The use method of the artificial melanin hair dye with the moisturizing function comprises the following steps:
cleaning hair, mixing the first agent and the second agent, smearing the mixture on the hair, staying in the air for 30-60 minutes, and cleaning the hair again; wherein, the dosage ratio of the first agent and the second agent is compared with the dosage ratio of the conventional two-agent hair dye, and the dosage ratio is generally 1.5: 1-1: 1.5, preferably according to 1:1.
compared with the prior art, the invention has the following characteristics and beneficial effects:
(1) the non-toxic and safe 5, 6-dihydroxyindole is used as a melanin intermediate of the hair dye, so that the hair dye is more green and safe, and has an excellent hair dyeing effect.
(2) The hydrophobic sulfhydryl carbon chain is introduced, and can reduce water loss in hair in the melanin synthesis process, so that the hair is kept moist and not dry, and the hair conditioner is particularly suitable for people who easily dry hair.
Detailed Description
The technical solution and the technical effect of the present invention will be further explained with reference to the following embodiments. The examples are only for illustrative purposes and are not intended to limit the scope of the present invention. The technical solution of the present invention is further described below with reference to specific examples.
In the following examples and comparative examples, the raw materials used were all purchased directly from the market, wherein 5, 6-dihydroxyindole was a product of Sichuan melanine Polymer materials Co., Ltd., purity was 97%; the other raw materials are all common products in the market.
Example 1
In this example, the first dose component was: mercapto carbon six: 1%, 5, 6-dihydroxyindole: 1%, stearic acid: 6%, cetearyl alcohol: 6%, sodium dodecylbenzenesulfonate: 0.6%, propylene glycol: 5%, cysteine: 4%, hydrolysis of keratin: 1 percent of ammonia water, and adjusting the pH value of the first agent to 9; the balance of water, the mass percent of each component is 100 percent. The second agent comprises the following components: hydrogen peroxide: 10%, stearic acid: 6%, cetearyl alcohol: 6%, propylene glycol: 5%, sodium dodecylbenzenesulfonate: 0.6 percent of water and the balance of water, wherein the mass percent of all the components is 100 percent.
Example 2
In this example, the first dose component was: mercapto carbon nine: 2%, 5, 6-dihydroxyindole: 1%, stearic acid: 6%, cetearyl alcohol: 6%, sodium dodecylbenzenesulfonate: 0.6%, propylene glycol: 5%, cysteine: 4%, hydrolysis of keratin: 1 percent of ammonia water, and adjusting the pH value of the first agent to 9; the balance of water, the mass percent of each component is 100 percent. The second agent comprises the following components: hydrogen peroxide: 10%, stearic acid: 6%, cetearyl alcohol: 6%, propylene glycol: 5%, sodium dodecylbenzenesulfonate: 0.6 percent of water and the balance of water, wherein the mass percent of all the components is 100 percent.
Example 3
In this example, the first dose component was: mercapto carbon nine: 2%, 5, 6-dihydroxyindole: 3%, stearic acid: 6%, cetearyl alcohol: 6%, sodium dodecylbenzenesulfonate: 0.6%, propylene glycol: 5%, cysteine: 4%, hydrolysis of keratin: 1 percent of ammonia water, and adjusting the pH value of the first agent to 9; the balance of water, the mass percent of each component is 100 percent. The second agent comprises the following components: hydrogen peroxide: 10%, stearic acid: 6%, cetearyl alcohol: 6%, propylene glycol: 5%, sodium dodecylbenzenesulfonate: 0.6 percent of water and the balance of water, wherein the mass percent of all the components is 100 percent.
Example 4
In this example, the first dose component was: mercapto-carbon fourteen: 1%, 5, 6-dihydroxyindole: 1%, stearic acid: 6%, cetearyl alcohol: 6%, sodium dodecylbenzenesulfonate: 0.6%, propylene glycol: 5%, cysteine: 4%, hydrolysis of keratin: 1 percent of ammonia water, and adjusting the pH value of the first agent to 9; the balance of water, the mass percent of each component is 100 percent. The second agent comprises the following components: hydrogen peroxide: 10%, stearic acid: 6%, cetearyl alcohol: 6%, propylene glycol: 5%, sodium dodecylbenzenesulfonate: 0.6 percent of water and the balance of water, wherein the mass percent of all the components is 100 percent.
Example 5
In this example, the first dose component was: mercapto-carbon fourteen: 1%, 5, 6-dihydroxyindole: 3%, stearic acid: 6%, cetearyl alcohol: 6%, sodium dodecylbenzenesulfonate: 0.6%, propylene glycol: 5%, cysteine: 4%, hydrolysis of keratin: 1 percent of ammonia water, and adjusting the pH value of the first agent to 9; the balance of water, the mass percent of each component is 100 percent. The second agent comprises the following components: hydrogen peroxide: 10%, stearic acid: 6%, cetearyl alcohol: 6%, propylene glycol: 5%, sodium dodecylbenzenesulfonate: 0.6 percent of water and the balance of water, wherein the mass percent of all the components is 100 percent.
Example 6
In this example, the first dose component was: mercapto carbon eighteen: 2%, 5, 6-dihydroxyindole: 3%, stearic acid: 6%, cetearyl alcohol: 6%, sodium dodecylbenzenesulfonate: 0.6%, propylene glycol: 5%, cysteine: 4%, hydrolysis of keratin: 1 percent of ammonia water, and adjusting the pH value of the first agent to 9; the balance of water, the mass percent of each component is 100 percent. The second agent comprises the following components: hydrogen peroxide: 10%, stearic acid: 6%, cetearyl alcohol: 6%, propylene glycol: 5%, sodium dodecylbenzenesulfonate: 0.6 percent of water and the balance of water, wherein the mass percent of all the components is 100 percent.
Comparative example 1
The first agent in this comparative example consisted of: 5, 6-dihydroxyindole: 1%, stearic acid: 6%, cetearyl alcohol: 6%, sodium dodecylbenzenesulfonate: 0.6%, propylene glycol: 5%, cysteine: 4%, hydrolysis of keratin: 1 percent of ammonia water, and adjusting the pH value of the first agent to 9; the balance of water, the mass percent of each component is 100 percent. The second agent comprises the following components: hydrogen peroxide: 10%, stearic acid: 6%, cetearyl alcohol: 6%, propylene glycol: 5%, sodium dodecylbenzenesulfonate: 0.6 percent of water and the balance of water, wherein the mass percent of all the components is 100 percent.
Comparative example 2
The first agent in this comparative example consisted of: 5, 6-dihydroxyindole: 3%, stearic acid: 6%, cetearyl alcohol: 6%, sodium dodecylbenzenesulfonate: 0.6%, propylene glycol: 5%, cysteine: 4%, hydrolysis of keratin: 1 percent of ammonia water, and adjusting the pH value of the first agent to 9; the balance of water, the mass percent of each component is 100 percent. The second agent comprises the following components: hydrogen peroxide: 10%, stearic acid: 6%, cetearyl alcohol: 6%, propylene glycol: 5%, sodium dodecylbenzenesulfonate: 0.6 percent of water and the balance of water, wherein the mass percent of all the components is 100 percent.
The compositions of examples 1 to 6 and comparative examples 1 to 2 are shown in Table 2.
TABLE 2 Components of examples 1-6 and comparative examples 1-2
The hair dyeing effect of the hair dyes of the examples 1-6 and the comparative examples 1-2 is evaluated, and the method comprises the following steps: cleaning hair, mixing the first and second agents at a ratio of 1:1, applying to hair, standing in air for 30 min, washing hair with shampoo, and air drying. The moisture retention and blackness of the hair were evaluated.
The moisture retention adopts a touch test method, the moisture retention is divided into five grades of A (very wet), B (relatively wet), C (non-dry and non-wet), D (relatively dry) and E (very dry), the moisture retention of the hair after the hair dyeing is just finished is defined as A grade, the dyed hair is placed in the same environment for 24 hours, and then the moisture retention of the hair is felt by touching with hands. The evaluation method of the hair dyeing blackness comprises the following steps: the hair was tested 3 times with a colorimeter and the average value was taken, i.e. the blackness of the hair dyed. The blackness L value range of normal black hair is 16-18, and the smaller the L value, the darker the hair color is.
The data on the moisture retention and blackness of the hair dyed with the hair dye of examples 1-6 and comparative examples 1-2 are shown in Table 3. As can be seen from the table, the hair dyeing effect of examples 1 to 6 is obvious, the moisture retention degree is obviously better than that of a comparative example, and the addition of the hydrophobic mercapto carbon chains can reduce the water loss in the hair and keep the hair moist for a long time after the hair dyeing is finished.
TABLE 3 Hair dyeing moisturization and blackness data
| Degree of blackness | Moisture retention | |
| Example 1 | 21.6 | C |
| Example 2 | 20.3 | B |
| Example 3 | 20.6 | B |
| Example 4 | 21.5 | A |
| Example 5 | 20.8 | B |
| Example 6 | 19.6 | A |
| Comparative example 1 | 20.9 | D |
| Comparative example 2 | 20.8 | D |
The foregoing are merely exemplary embodiments of the present invention, which enable those skilled in the art to understand or practice the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.
Claims (6)
1. The artificial melanin hair dye with the moisturizing function is characterized by comprising a first agent and a second agent;
the first agent consists of the following components in percentage by mass:
six to eighteen mercapto carbon: 1% -2%, 5, 6-dihydroxyindole: 1% -3%, stearic acid: 5% -10%, cetostearyl alcohol: 5% -10%, sodium dodecyl benzene sulfonate: 0.2% -1.5%, propylene glycol: 4% -9%, cysteine: 1% -4%, hydrolysis of keratin: 1% and a proper amount of ammonia water for adjusting the pH to 9-10; the balance of water, the mass percent of each component is 100 percent;
the second agent comprises the following components in percentage by mass:
hydrogen peroxide: 8% -20%, stearic acid: 5% -10%, cetostearyl alcohol: 5% -10%, propylene glycol: 4% -9%, sodium dodecyl benzene sulfonate: 0.2 to 1.5 percent of water, and the balance of water, wherein the mass percent of all the components is 100 percent.
2. The artificial melanin hair dye with moisturizing function of claim 1, which is characterized in that:
the first agent consists of the following components in percentage by mass:
nine to eighteen mercapto carbons: 1% -2%, 5, 6-dihydroxyindole: 1% -3%, stearic acid: 5% -10%, cetostearyl alcohol: 5% -10%, sodium dodecyl benzene sulfonate: 0.2% -1.5%, propylene glycol: 4% -9%, cysteine: 1% -4%, hydrolysis of keratin: 1% and a proper amount of ammonia water for adjusting the pH to 9-10; the balance of water, the mass percent of each component is 100 percent;
the second agent comprises the following components in percentage by mass:
hydrogen peroxide: 8% -20%, stearic acid: 5% -10%, cetostearyl alcohol: 5% -10%, propylene glycol: 4% -9%, sodium dodecyl benzene sulfonate: 0.2 to 1.5 percent of water, and the balance of water, wherein the mass percent of all the components is 100 percent.
3. The artificial melanin hair dye with moisturizing function of claim 1, which is characterized in that:
the first agent consists of the following components in percentage by mass:
tetradecyl to eighteen mercapto groups: 1% -2%, 5, 6-dihydroxyindole: 1% -3%, stearic acid: 5% -10%, cetostearyl alcohol: 5% -10%, sodium dodecyl benzene sulfonate: 0.2% -1.5%, propylene glycol: 4% -9%, cysteine: 1% -4%, hydrolysis of keratin: 1% and a proper amount of ammonia water for adjusting the pH to 9-10; the balance of water, the mass percent of each component is 100 percent;
the second agent comprises the following components in percentage by mass:
hydrogen peroxide: 8% -20%, stearic acid: 5% -10%, cetostearyl alcohol: 5% -10%, propylene glycol: 4% -9%, sodium dodecyl benzene sulfonate: 0.2 to 1.5 percent of water, and the balance of water, wherein the mass percent of all the components is 100 percent.
4. The method for preparing the artificial melanin hair dye with the moisturizing function of any one of claims 1 to 3, which is characterized by comprising the steps of preparing a first agent and a second agent;
the preparation of the first agent comprises the steps of:
(1-1) mixing stearic acid, cetostearyl alcohol and mercapto carbon six-eighteen, and heating to 70-90 ℃ to obtain an oil phase;
(1-2) mixing and heating sodium dodecyl benzene sulfonate, propylene glycol, cysteine, hydrolyzed keratin and water to 70-90 ℃ to obtain a water phase;
(1-3) adding the aqueous phase to the oil phase, stirring, and then cooling to room temperature;
(1-4) adding ammonia water to adjust the pH value to 9-10, adding 5, 6-dihydroxyindole, and mixing to obtain a first agent;
the preparation of the second agent comprises the steps of:
(2-1) mixing stearic acid and cetostearyl alcohol, and heating to 70-90 ℃ to obtain an oil phase;
(2-2) mixing and heating sodium dodecyl benzene sulfonate, propylene glycol and water to 70-90 ℃ to obtain a water phase;
(2-3) adding the aqueous phase to the oil phase, stirring, and then cooling to room temperature;
and (2-4) adding hydrogen peroxide and mixing to obtain a second agent.
5. The use method of the artificial melanin hair dye with moisturizing function as claimed in any one of claims 1 to 3, is characterized in that:
cleaning hair, mixing the first agent and the second agent according to the dosage ratio of 1.5: 1-1: 1.5, smearing the mixture on the hair, staying in the air for 30-60 minutes, and cleaning the hair again.
6. The method of use of claim 5, wherein:
mixing the first dose and the second dose according to the ratio of 1:1 in a mixing ratio.
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| US20080274069A1 (en) * | 2004-10-22 | 2008-11-06 | Basf Aktiengesellschaft | Cosmetic Preparations Containing Copolymers of Ethyl Methacrylate and at Least One Monoethylenically Unsaturated Carboxylic Acid |
| US20100135918A1 (en) * | 2005-08-11 | 2010-06-03 | Basf Se | Copolymers for cosmetic applications |
| US20190254955A1 (en) * | 2018-02-20 | 2019-08-22 | Living Proof, Inc. | Covalent treatment with thiols of keratin-containing materials |
| CN111920696A (en) * | 2020-09-14 | 2020-11-13 | 四川大学 | Artificial melanin hair-perming and dyeing agent and preparation and hair-perming and dyeing integrated use method thereof |
| WO2020264257A1 (en) * | 2019-06-28 | 2020-12-30 | Living Proof, Inc. | Additives for coloring agents and methods of use thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US20080274069A1 (en) * | 2004-10-22 | 2008-11-06 | Basf Aktiengesellschaft | Cosmetic Preparations Containing Copolymers of Ethyl Methacrylate and at Least One Monoethylenically Unsaturated Carboxylic Acid |
| US20100135918A1 (en) * | 2005-08-11 | 2010-06-03 | Basf Se | Copolymers for cosmetic applications |
| US20190254955A1 (en) * | 2018-02-20 | 2019-08-22 | Living Proof, Inc. | Covalent treatment with thiols of keratin-containing materials |
| WO2020264257A1 (en) * | 2019-06-28 | 2020-12-30 | Living Proof, Inc. | Additives for coloring agents and methods of use thereof |
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