CN113980330A - Durable fireproof soft material and preparation method and application thereof - Google Patents
Durable fireproof soft material and preparation method and application thereof Download PDFInfo
- Publication number
- CN113980330A CN113980330A CN202111362113.2A CN202111362113A CN113980330A CN 113980330 A CN113980330 A CN 113980330A CN 202111362113 A CN202111362113 A CN 202111362113A CN 113980330 A CN113980330 A CN 113980330A
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- China
- Prior art keywords
- retardant
- flame
- durable
- fire
- resistant flexible
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- 239000007779 soft material Substances 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 53
- 239000003063 flame retardant Substances 0.000 claims abstract description 32
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000005187 foaming Methods 0.000 claims abstract description 14
- 239000006261 foam material Substances 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- 239000011241 protective layer Substances 0.000 claims abstract description 7
- 230000001680 brushing effect Effects 0.000 claims description 9
- 230000009970 fire resistant effect Effects 0.000 claims description 8
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical group FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 6
- 238000005034 decoration Methods 0.000 claims description 6
- 239000010410 layer Substances 0.000 claims description 6
- OWICEWMBIBPFAH-UHFFFAOYSA-N (3-diphenoxyphosphoryloxyphenyl) diphenyl phosphate Chemical group C=1C=CC=CC=1OP(OC=1C=C(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)C=CC=1)(=O)OC1=CC=CC=C1 OWICEWMBIBPFAH-UHFFFAOYSA-N 0.000 claims description 3
- 229910015900 BF3 Inorganic materials 0.000 claims description 3
- 239000004604 Blowing Agent Substances 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- 238000004040 coloring Methods 0.000 claims description 3
- 239000012948 isocyanate Substances 0.000 claims description 3
- 150000002513 isocyanates Chemical class 0.000 claims description 3
- 239000007769 metal material Substances 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 238000005498 polishing Methods 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 229920005862 polyol Polymers 0.000 claims description 3
- 150000003077 polyols Chemical class 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 2
- 230000002452 interceptive effect Effects 0.000 claims 1
- 230000003993 interaction Effects 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 5
- 229910000831 Steel Inorganic materials 0.000 abstract description 4
- 239000010959 steel Substances 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 3
- 238000006748 scratching Methods 0.000 abstract description 2
- 230000002393 scratching effect Effects 0.000 abstract description 2
- 239000004088 foaming agent Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000009194 climbing Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
Abstract
The invention belongs to the technical field of foaming materials, and particularly relates to a durable fireproof soft material and a preparation method and application thereof. The material comprises a flame-retardant soft foam material, wherein a supporting framework material and a toughening material are arranged in the flame-retardant soft foam material, and a dye and a protective layer are coated outside the flame-retardant soft foam material. The material provided by the invention is moderate in hardness, is suitable for an interaction device, avoids scratching people in the interaction operation process, is good in flame retardant effect, avoids the safety problem, and can enlarge the value of the interaction device in use. In addition, the material can be used for manufacturing artware, the cartoon shape can be customized, the cost is low, and compared with a steel die, the material is high in steel die opening speed, durable, flame-retardant and high in safety.
Description
Technical Field
The invention belongs to the technical field of foaming materials, and particularly relates to a durable fireproof soft material and a preparation method and application thereof.
Background
With the development of society, the living standard of people is continuously improved, more and more people pursue physical life and more spiritual satisfaction, particularly the theme park industry is rapidly developed, and particularly in the field of theme park performance, the large and small artware is widely applied more and more.
Because the performance can be watched to the on-the-spot child of having in amusement park, in order to prevent that child from climbing, touching injury, amusement park device and ornamental material need guarantee that the durable fire prevention soft or hard degree of material can not hinder child. However, the amusement park device and the decorative material in the prior art are too hard and not suitable for an interaction device, people are easily scratched in the interaction operation process, potential safety hazards exist, flame retardance cannot be guaranteed mostly, and rapid customization cannot be achieved.
Therefore, a durable fireproof soft material needs to be researched for amusement park devices and decoration, so that children can not touch and be injured when playing, and the safety problem is solved.
Disclosure of Invention
To solve the above problems in the prior art, the present invention provides a durable fire-resistant flexible material for amusement park equipment and decoration.
In order to achieve the purpose, the invention adopts the following technical scheme:
the invention aims to disclose a durable fireproof soft material which comprises a flame-retardant soft foam material, wherein a supporting framework material and a toughening material are arranged in the flame-retardant soft foam material, and a dye and a protective layer are coated outside the flame-retardant soft foam material.
Preferably, the flame-retardant soft foaming material comprises isocyanate, polyether polyol, a foaming agent, a catalyst and a flame retardant.
Preferably, the blowing agent is polyurethane.
Preferably, the catalyst is a boron trifluoride complex.
Preferably, the flame retardant is resorcinol bis (diphenyl phosphate).
Preferably, the supporting framework material is a metal material.
Preferably, the toughening material comprises flame retardant gauze or fibers.
The invention also discloses a preparation method of the durable fireproof soft material, which comprises the following steps:
(1) manufacturing a mold seed;
(2) preparing a flame-retardant soft foaming material, and brushing a first layer of the foaming material on the surface of the mould seeds;
(3) brushing a second layer of the foaming material in the mould seeds, and arranging a support framework material in the mould seeds;
(4) adding a toughening material, and closing the die;
(5) opening the mold after molding;
(6) polishing, coloring and brushing a protective layer.
The invention also discloses application of the durable fireproof soft material to preparation of amusement park devices and decorations, wherein the amusement park devices and the decorations can be played interactively.
Advantageous effects
The invention discloses a durable fireproof soft material which is made of a soft foaming material and can be used for manufacturing outdoor interaction devices of theme parks, exhibition and display interaction devices and large and small artware of theme sculpture parks. The material provided by the invention is moderate in hardness, is suitable for an interaction device, avoids scratching people in the interaction operation process, is good in flame retardant effect, avoids the safety problem, and can enlarge the value of the interaction device in use. In addition, the material can be used for manufacturing artware, the cartoon shape can be customized, the cost is low, and compared with a steel die, the material is high in steel die opening speed, durable, flame-retardant and high in safety.
Drawings
FIG. 1: a photo of the model structure;
FIG. 2: a colored petal structure photo;
FIG. 3: a petal structure photo after mechanism effect is made;
FIG. 4: structural photographs of the petals during assembly;
FIG. 5: the finished structure photograph of flower-shaped ornament.
Detailed Description
Hereinafter, the present invention will be described in detail. Before the description is made, it should be understood that the terms used in the present specification and the appended claims should not be construed as limited to general and dictionary meanings, but interpreted based on the meanings and concepts corresponding to technical aspects of the present invention on the basis of the principle that the inventor is allowed to define terms appropriately for the best explanation. Accordingly, the description proposed herein is just a preferable example for the purpose of illustrations only, not intended to limit the scope of the invention, so it should be understood that other equivalents and modifications could be made thereto without departing from the spirit and scope of the invention.
The following examples are given by way of illustration of embodiments of the invention and are not to be construed as limiting the invention, and it will be understood by those skilled in the art that modifications may be made without departing from the spirit and scope of the invention. Unless otherwise specified, reagents and equipment used in the following examples are commercially available products.
Example 1
The durable fireproof soft material comprises a flame-retardant soft foam material, wherein a supporting framework material and a toughening material are arranged inside the flame-retardant soft foam material, and a dye and a protective layer are coated outside the flame-retardant soft foam material.
The flame-retardant soft foaming material comprises isocyanate, polyether polyol, a foaming agent, a catalyst and a flame retardant. The foaming agent is polyurethane. The catalyst is a boron trifluoride complex. The flame retardant is resorcinol bis (diphenyl phosphate).
The supporting framework material is a metal material. The toughening material comprises flame-retardant gauze.
Example 2
The durable fireproof soft material in the embodiment 1 is applied to preparing flower-shaped ornaments, and the specific preparation method comprises the following steps:
(1) making petal-shaped mold seeds as shown in figure 1;
(2) preparing a flame-retardant soft foaming material, and brushing a first layer of the foaming material on the surface of the mould seeds;
(3) brushing a second layer of the foaming material in the mould seeds, and arranging a support framework material in the mould seeds;
(4) adding a toughening material, and closing the die;
(5) opening the mold after molding;
(6) polishing, coloring, making mechanism effect, and finally brushing a protective layer;
(7) assembling to obtain the finished product of the flower-shaped ornament.
The above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof; and such modifications or substitutions do not depart from the spirit and scope of the corresponding technical solutions.
Claims (10)
1. The durable fireproof soft material is characterized by comprising a flame-retardant soft foam material, wherein a supporting framework material and a toughening material are arranged in the flame-retardant soft foam material, and a dye and a protective layer are coated outside the flame-retardant soft foam material.
2. The durable fire-resistant flexible material of claim 1 wherein the fire-retardant flexible foam material comprises an isocyanate, a polyether polyol, a blowing agent, a catalyst, a fire retardant.
3. The durable fire resistant flexible material of claim 2 wherein said blowing agent is polyurethane.
4. The durable fire-resistant flexible material of claim 2 wherein the catalyst is a boron trifluoride complex.
5. The durable fire-resistant flexible material of claim 2 wherein the fire retardant is resorcinol bis (diphenyl phosphate).
6. The durable fire resistant flexible material of claim 1 wherein said supporting framework material is a metallic material.
7. The durable fire retardant flexible material of claim 1 wherein said toughening material comprises a fire retardant scrim or fiber.
8. A method of making a durable fire-resistant flexible material as claimed in any one of claims 1 to 7, comprising the steps of:
(1) manufacturing a mold seed;
(2) preparing a flame-retardant soft foaming material, and brushing a first layer of the foaming material on the surface of the mould seeds;
(3) brushing a second layer of the foaming material in the mould seeds, and arranging a support framework material in the mould seeds;
(4) adding a toughening material, and closing the die;
(5) opening the mold after molding;
(6) polishing, coloring and brushing a protective layer.
9. Use of the durable fire-resistant flexible material according to any one of claims 1 to 7 for the production of amusement park equipment and decorations.
10. The use of claim 9, wherein the amusement park apparatus and the decoration are capable of interactive play.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111362113.2A CN113980330A (en) | 2021-11-17 | 2021-11-17 | Durable fireproof soft material and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111362113.2A CN113980330A (en) | 2021-11-17 | 2021-11-17 | Durable fireproof soft material and preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113980330A true CN113980330A (en) | 2022-01-28 |
Family
ID=79749049
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111362113.2A Pending CN113980330A (en) | 2021-11-17 | 2021-11-17 | Durable fireproof soft material and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113980330A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1880062A (en) * | 2006-04-29 | 2006-12-20 | 厉朝岳 | Flexible expansion fireproof material |
| CN106189192A (en) * | 2016-08-04 | 2016-12-07 | 合众（佛山）化工有限公司 | A kind of Kafra fiber polyurethane composite foam material and preparation method thereof |
| CN107254029A (en) * | 2017-06-28 | 2017-10-17 | 江苏绿源新材料有限公司 | Bus interior highly effective flame-retardant environment-protective polyurethane soft foamed plastics and preparation method |
| US20190100661A1 (en) * | 2017-10-04 | 2019-04-04 | Walter Dan Stogner | Fire resistant foam composition and method |
-
2021
- 2021-11-17 CN CN202111362113.2A patent/CN113980330A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1880062A (en) * | 2006-04-29 | 2006-12-20 | 厉朝岳 | Flexible expansion fireproof material |
| CN106189192A (en) * | 2016-08-04 | 2016-12-07 | 合众（佛山）化工有限公司 | A kind of Kafra fiber polyurethane composite foam material and preparation method thereof |
| CN107254029A (en) * | 2017-06-28 | 2017-10-17 | 江苏绿源新材料有限公司 | Bus interior highly effective flame-retardant environment-protective polyurethane soft foamed plastics and preparation method |
| US20190100661A1 (en) * | 2017-10-04 | 2019-04-04 | Walter Dan Stogner | Fire resistant foam composition and method |
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|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220128 |