CN113969506A - Illumination-resistant fabric foil and preparation method thereof - Google Patents
Illumination-resistant fabric foil and preparation method thereof Download PDFInfo
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- CN113969506A CN113969506A CN202111280294.4A CN202111280294A CN113969506A CN 113969506 A CN113969506 A CN 113969506A CN 202111280294 A CN202111280294 A CN 202111280294A CN 113969506 A CN113969506 A CN 113969506A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/042—Acrylic polymers
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/06—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
- D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1678—Resistive to light or to UV
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention relates to an illumination-resistant fabric foil and a preparation method thereof, wherein the illumination-resistant fabric foil comprises acrylic resin, an ultraviolet absorbent, nitrocellulose, a solvent and an auxiliary agent.
Description
Technical Field
The invention relates to the technical field of alumite, in particular to a light-resistant fabric foil and a preparation method thereof.
Background
The electrochemical aluminum product has undergone many improvements since its birth, and is now widely used in the fields of packaging, printing, weaving, decoration, etc., and no alternative product has appeared so far due to its unique decorative effect and simple usage method.
The fabric foil is one of numerous products related to the alumite, is used for gold stamping on fabrics and fabrics, and the product after gold stamping has bright metallic luster. The bronzing of the cloth is favored by more and more people due to the unique decorative effect of the fabric for the purpose of capturing the brilliance; however, the existing production components of the anodized aluminum coating film are less considered in the aspect of light resistance, so that the phenomena of fading, cracking and the like easily occur after the hot stamping cloth is illuminated for a long time, and the service life of the hot stamping cloth is seriously influenced.
Therefore, a new illumination-resistant fabric foil needs to be provided to solve the problem that the gilding part cannot resist long-time illumination.
Disclosure of Invention
The invention aims to provide a light-resistant fabric foil and a preparation method thereof, and overcomes the defects of the existing fabric foil.
The technical scheme adopted by the invention for solving the technical problems is as follows: the composition comprises the following components in parts by mass: 25-45 parts of acrylic resin, 4-10 parts of nitrocellulose, 0.2-0.8 part of ultraviolet absorbent, 75-85 parts of solvent and 0.1-0.4 part of auxiliary agent.
Preferably, the acrylic resin is one or more of a methyl methacrylate copolymer, a butyl methacrylate copolymer, methacrylic acid and butyl acrylate.
Preferably, the nitrocellulose is 35-45% by mass of cellulose nitrate solution.
Preferably, the ultraviolet absorbent is one or more of ultraviolet absorbent UV9, ultraviolet absorbent UVP327, ultraviolet absorbent RMB, salicylic acid and benzophenone.
Preferably, the solvent is one or more of ethyl acetate, butyl acetate, butanone, butyl ester and toluene.
Preferably, the adjuvant is polydimethylsiloxane.
A preparation method of a light-resistant fabric foil comprises the following steps:
preparation of production: weighing raw materials, and preparing the raw materials according to the mass parts of the components;
heating and mixing: firstly, pouring a solvent into a reaction kettle, heating to 30-45 ℃, and uniformly mixing; then pouring the acrylic resin, the nitrocellulose and the ultraviolet absorbent into a reaction kettle together, heating the reaction kettle to 50-70 ℃, controlling the stirring speed to be 150-200rpm, adding the auxiliary agent after stirring to be uniform and transparent, and stirring to be uniform at the temperature and the rotating speed;
cooling and coating: maintaining the stirring speed, naturally cooling the mixture to room temperature, filtering the mixture and coating the mixture on a base film;
aluminum plating and gluing: and after the base film is coated, carrying out mould pressing and drying, putting the dried base film into a vacuum aluminizing machine for aluminizing, and finally gluing to obtain the illumination-resistant fabric foil.
The invention has the following beneficial effects: the ultraviolet absorber is added into the fabric foil coating, so that the ultraviolet in external illumination can be absorbed and shielded, the aging damage of the fabric foil caused by the ultraviolet absorber is reduced, and the service life of the fabric foil is prolonged; the nitrocellulose can effectively improve the peeling strength of the fabric foil and facilitate the transfer printing of the fabric foil.
Detailed Description
Example 1
Taking 30 parts of acrylic resin, 5 parts of 35% cellulose nitrate solution by mass fraction, 0.6 part of ultraviolet absorbent, 75 parts of solvent and 0.3 part of auxiliary agent, wherein the acrylic resin comprises 18 parts of methyl methacrylate copolymer and 12 parts of butyl acrylate; the ultraviolet absorbent is ultraviolet absorbent UVP 327; the solvent comprises 30 parts of ethyl acetate and 45 parts of butanone.
Firstly, pouring a solvent into a reaction kettle, heating to 35 ℃, and uniformly mixing; then pouring acrylic resin, cellulose nitrate solution and ultraviolet absorbent into a reaction kettle, heating the reaction kettle to 60 ℃, controlling the stirring speed to be 160rpm, stirring until the mixture is uniform and transparent, adding auxiliary agent polydimethylsiloxane, stirring until the mixture is uniform while maintaining the temperature and the rotating speed, stopping heating and continuously stirring, taking out the mixture after the temperature of the mixture is reduced to room temperature, filtering, and coating the mixture on a base film; and (3) after the base film is coated, carrying out mould pressing and drying, putting the dried base film into a vacuum aluminizing machine for aluminizing, and finally gluing to obtain the sample 1.
Example 2
Taking 35 parts of acrylic resin, 6 parts of 40% cellulose nitrate solution, 0.8 part of ultraviolet absorbent, 80 parts of solvent and 0.3 part of auxiliary agent, wherein the acrylic resin comprises 20 parts of butyl methacrylate copolymer and 15 parts of methacrylic acid; the ultraviolet absorber comprises 0.4 parts of ultraviolet absorber UV9 and 0.4 parts of ultraviolet absorber RMB; the solvent comprises 55 parts of butyl acetate and 25 parts of toluene.
Firstly, pouring a solvent into a reaction kettle, heating to 35 ℃, and uniformly mixing; then pouring acrylic resin, cellulose nitrate solution and ultraviolet absorbent into a reaction kettle, heating the reaction kettle to 65 ℃, controlling the stirring speed to be 180rpm, stirring until the mixture is uniform and transparent, adding auxiliary agent polydimethylsiloxane, stirring until the mixture is uniform while maintaining the temperature and the rotating speed, stopping heating and continuously stirring, taking out the mixture after the temperature of the mixture is reduced to room temperature, filtering, and coating the mixture on a base film; and (3) after the base film is coated, carrying out mould pressing and drying, putting the dried base film into a vacuum aluminizing machine for aluminizing, and finally gluing to obtain a sample 2.
Example 3
Taking 40 parts of acrylic resin, 8 parts of 45 mass percent cellulose nitrate solution, 0.8 part of ultraviolet absorbent, 85 parts of solvent and 0.4 part of auxiliary agent, wherein the acrylic resin comprises 18 parts of methyl methacrylate copolymer, 12 parts of butyl methacrylate copolymer and 10 parts of methacrylic acid; the ultraviolet absorbent comprises 0.4 part of phenyl salicylate and 0.4 part of 2, 4-dihydroxy benzophenone; the solvent comprises 40 parts of ethyl acetate, 20 parts of toluene and 25 parts of butyl ester.
Firstly, pouring a solvent into a reaction kettle, heating to 35 ℃, and uniformly mixing; then pouring acrylic resin, 45 mass percent of cellulose nitrate solution and ultraviolet absorbent into a reaction kettle, heating the reaction kettle to 70 ℃, controlling the stirring speed to be 200rpm, stirring until the mixture is uniform and transparent, adding auxiliary agent polydimethylsiloxane, keeping the temperature and the rotating speed, stirring until the mixture is uniform, stopping heating and continuously stirring, taking out the mixture after the temperature of the mixture is reduced to room temperature, filtering, and coating the mixture on a base film; and (3) after the base film is coated, carrying out mould pressing and drying, putting the dried base film into a vacuum aluminizing machine for aluminizing, and finally gluing to obtain a sample 3.
Comparative example 1
Taking 35 parts of acrylic resin, 6 parts of 40% cellulose nitrate solution, 80 parts of solvent and 0.3 part of auxiliary agent, wherein the acrylic resin comprises 20 parts of butyl methacrylate copolymer and 15 parts of methacrylic acid; the solvent comprises 55 parts of butyl acetate and 25 parts of toluene.
Firstly, pouring a solvent into a reaction kettle, heating to 35 ℃, and uniformly mixing; then pouring acrylic resin and cellulose nitrate solution into a reaction kettle, heating the reaction kettle to 65 ℃, controlling the stirring speed to be 180rpm, stirring until the mixture is uniform and transparent, adding auxiliary agent polydimethylsiloxane, stirring until the mixture is uniform while maintaining the temperature and the rotating speed, stopping heating and continuously stirring, taking out the mixture after the temperature of the mixture is reduced to room temperature, filtering, and coating the mixture on a base membrane; and (3) after the base film is coated, carrying out mould pressing and drying, putting the dried base film into a vacuum aluminizing machine for aluminizing, and finally gluing to obtain a sample 4.
Comparative example 2
A conventional textile foil product was purchased on the market as sample 5.
The fabric foil samples of examples 1 to 3 and comparative examples 1 to 2 were placed in an ultraviolet aging oven and irradiated with ultraviolet light for 2400min, and the color of the coating film was measured and the color difference Δ E was calculated according to the method for measuring the color of the coating film in GB/T11186-1989, and the specific data are shown in Table 1.
TABLE 1 color difference of illumination of fabric foil
| Numbering | Color difference (Delta E) |
| Sample 1 | 2.6 |
| Sample 2 | 2.2 |
| Sample 3 | 2.3 |
| Sample No. 4 | 3.9 |
| Sample No. 5 | 4.2 |
It can be seen from the data in the table that the color difference after the samples 1-3 are subjected to uv aging is significantly lower than that of the samples 4 and 5, compared to the samples 4 and 5 without uv absorber, and it can be seen that the fabric foil prepared by the method of the present invention has good photo aging performance and can maintain good color after a long illumination time.
Claims (7)
1. A light-fast textile foil, characterized in that: the composition comprises the following components in parts by mass: 25-45 parts of acrylic resin, 4-10 parts of nitrocellulose, 0.2-0.8 part of ultraviolet absorbent, 75-85 parts of solvent and 0.1-0.4 part of auxiliary agent.
2. A light-fast textile foil as claimed in claim 1, wherein: the acrylic resin is one or more of methyl methacrylate copolymer, butyl methacrylate copolymer, methacrylic acid and butyl acrylate.
3. A light-fast textile foil as claimed in claim 1, wherein: the nitrocellulose is 35-45% by weight of cellulose nitrate solution.
4. A light-fast textile foil as claimed in claim 1, wherein: the ultraviolet absorbent is one or more of ultraviolet absorbent UV9, ultraviolet absorbent UVP327, ultraviolet absorbent RMB, salicylic acids and benzophenone.
5. A light-fast textile foil as claimed in claim 1, wherein: the solvent is one or more of ethyl acetate, butyl acetate, butanone, butyl ester and toluene.
6. A light-fast textile foil as claimed in claim 1, wherein: the auxiliary agent is polydimethylsiloxane.
7. A method of making a light fast textile foil according to claim 1, characterized in that: the method comprises the following steps:
preparation of production: weighing raw materials, and preparing the raw materials according to the mass parts of the components;
heating and mixing: firstly, pouring a solvent into a reaction kettle, heating to 30-45 ℃, and uniformly mixing; then pouring the acrylic resin, the nitrocellulose and the ultraviolet absorbent into a reaction kettle together, heating the reaction kettle to 50-70 ℃, controlling the stirring speed to be 150-200rpm, adding the auxiliary agent after stirring to be uniform and transparent, and stirring to be uniform at the temperature and the rotating speed;
cooling and coating: maintaining the stirring speed, naturally cooling the mixture to room temperature, filtering the mixture and coating the mixture on a base film;
aluminum plating and gluing: and after the base film is coated, carrying out mould pressing and drying, putting the dried base film into a vacuum aluminizing machine for aluminizing, and finally gluing to obtain the illumination-resistant fabric foil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111280294.4A CN113969506B (en) | 2021-11-01 | 2021-11-01 | Illumination-resistant fabric foil and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111280294.4A CN113969506B (en) | 2021-11-01 | 2021-11-01 | Illumination-resistant fabric foil and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113969506A true CN113969506A (en) | 2022-01-25 |
| CN113969506B CN113969506B (en) | 2023-03-28 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN202111280294.4A Active CN113969506B (en) | 2021-11-01 | 2021-11-01 | Illumination-resistant fabric foil and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108384370A (en) * | 2018-03-27 | 2018-08-10 | 汕头市嘉信包装材料有限公司 | A kind of anodized aluminium chromatograph coating and preparation method thereof |
| CN108779368A (en) * | 2015-12-18 | 2018-11-09 | 德莎欧洲股份公司 | The method of reactive the two component adhesive system and binder adhesive of form membrane |
| CN109321041A (en) * | 2018-09-17 | 2019-02-12 | 浙江大高包装材料有限公司 | A kind of release coating of boiling hot cloth type anodized aluminium and preparation method |
| CN109593494A (en) * | 2018-12-17 | 2019-04-09 | 云南玉溪东魅包装材料有限公司 | High speed thermoprint gloss oil type tipping paper electrochemical aluminum foil hot melt adhesive and preparation method thereof |
-
2021
- 2021-11-01 CN CN202111280294.4A patent/CN113969506B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108779368A (en) * | 2015-12-18 | 2018-11-09 | 德莎欧洲股份公司 | The method of reactive the two component adhesive system and binder adhesive of form membrane |
| CN108384370A (en) * | 2018-03-27 | 2018-08-10 | 汕头市嘉信包装材料有限公司 | A kind of anodized aluminium chromatograph coating and preparation method thereof |
| CN109321041A (en) * | 2018-09-17 | 2019-02-12 | 浙江大高包装材料有限公司 | A kind of release coating of boiling hot cloth type anodized aluminium and preparation method |
| CN109593494A (en) * | 2018-12-17 | 2019-04-09 | 云南玉溪东魅包装材料有限公司 | High speed thermoprint gloss oil type tipping paper electrochemical aluminum foil hot melt adhesive and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 吴世敏等: "《简明精细化工大辞典》", 30 June 1999 * |
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