CN113913837A - Novel multi-effect environment-friendly oil stain crawling agent - Google Patents
Novel multi-effect environment-friendly oil stain crawling agent Download PDFInfo
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- CN113913837A CN113913837A CN202111222571.6A CN202111222571A CN113913837A CN 113913837 A CN113913837 A CN 113913837A CN 202111222571 A CN202111222571 A CN 202111222571A CN 113913837 A CN113913837 A CN 113913837A
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- 230000009193 crawling Effects 0.000 title claims abstract description 13
- 239000003921 oil Substances 0.000 claims abstract description 61
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- -1 alkyl dihydroxyethyl ammonium oxide Chemical compound 0.000 claims abstract description 21
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 18
- GSWAOPJLTADLTN-UHFFFAOYSA-N oxidanimine Chemical compound [O-][NH3+] GSWAOPJLTADLTN-UHFFFAOYSA-N 0.000 claims abstract description 15
- BJEBSDPKCMJMEJ-UHFFFAOYSA-N 3-(dodecanoylamino)propyl-oxidoazanium Chemical compound CCCCCCCCCCCC(=O)NCCC[NH2+][O-] BJEBSDPKCMJMEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 claims abstract description 14
- SFBHPFQSSDCYSL-UHFFFAOYSA-N n,n-dimethyltetradecan-1-amine Chemical compound CCCCCCCCCCCCCCN(C)C SFBHPFQSSDCYSL-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011734 sodium Substances 0.000 claims abstract description 14
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 14
- 239000003760 tallow Substances 0.000 claims abstract description 14
- 239000004202 carbamide Substances 0.000 claims abstract description 13
- 235000013877 carbamide Nutrition 0.000 claims abstract description 13
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 claims abstract description 12
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims abstract description 12
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims abstract description 12
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims abstract description 12
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims abstract description 12
- 235000019345 sodium thiosulphate Nutrition 0.000 claims abstract description 12
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 12
- PWCMMIJSBAYEMF-UHFFFAOYSA-N sulfurothioic O-acid urea Chemical compound S(=S)(=O)(O)O.NC(=O)N PWCMMIJSBAYEMF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 150000004996 alkyl benzenes Chemical class 0.000 claims abstract description 10
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims abstract description 8
- HSHXDCVZWHOWCS-UHFFFAOYSA-N N'-hexadecylthiophene-2-carbohydrazide Chemical compound CCCCCCCCCCCCCCCCNNC(=O)c1cccs1 HSHXDCVZWHOWCS-UHFFFAOYSA-N 0.000 claims description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- ZOEHRTNFNALLOL-REOHCLBHSA-N 2-[[(1s)-1-carboxyethyl]amino]propanedioic acid Chemical compound OC(=O)[C@H](C)NC(C(O)=O)C(O)=O ZOEHRTNFNALLOL-REOHCLBHSA-N 0.000 claims description 4
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 claims description 4
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 4
- 244000060011 Cocos nucifera Species 0.000 claims description 4
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 4
- VUQAJHUAVIQPGY-UHFFFAOYSA-N CCO.CCO.CCCCCCCCCCCC(N)=O Chemical compound CCO.CCO.CCCCCCCCCCCC(N)=O VUQAJHUAVIQPGY-UHFFFAOYSA-N 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 11
- 230000008569 process Effects 0.000 abstract description 9
- 239000004094 surface-active agent Substances 0.000 abstract description 3
- 230000001808 coupling effect Effects 0.000 abstract description 2
- 230000004927 fusion Effects 0.000 abstract description 2
- 239000000080 wetting agent Substances 0.000 abstract description 2
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 238000004140 cleaning Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 230000009471 action Effects 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000005238 degreasing Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 238000007127 saponification reaction Methods 0.000 description 4
- 239000003513 alkali Substances 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000009194 climbing Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 159000000011 group IA salts Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000006259 organic additive Substances 0.000 description 2
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 description 2
- 229940048086 sodium pyrophosphate Drugs 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000011538 cleaning material Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000013527 degreasing agent Substances 0.000 description 1
- 238000005237 degreasing agent Methods 0.000 description 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
- C23G1/19—Iron or steel
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides a novel multi-effect environment-friendly oil stain crawling agent. Comprises a component A and a component B, wherein the component A comprises: 40-50 parts of dodecyl dimethyl ammonium oxide, 30-35 parts of cocoamidopropyl ammonium oxide, 20-25 parts of lauramidopropyl ammonium oxide, 10-16 parts of tetradecyl dimethyl ammonium oxide, 8-16 parts of tallow alkyl dihydroxyethyl ammonium oxide, 4-8 parts of diethylene glycol methyl ether, 2-5 parts of isohexane glycol, 8-10 parts of hydroxypropyl methyl cellulose, 4-6 parts of lauramidodiethanol and 3-8 parts of linear alkyl benzene sodium sulfonate; the component B comprises: 8-12 parts of urea thiosulfate, 6-10 parts of carbamide and 2-4 parts of sodium thiosulfate. The surfactant component has certain wetting agent coupling property on oil stains, and has a certain fusion interval with an oil film in a microcosmic dynamic acting force process. After the oil stains are wetted and fused, and the released gas is added, the gas can burst the oil film, tear the oil film, carry the oil film and leave the surface of the workpiece, and the oil film stripping process is completed.
Description
Technical Field
The invention relates to the technical field of chemical industry, in particular to a novel multi-effect environment-friendly oil stain crawling agent.
Background
Chemical oil removal is a technological process for removing oil by utilizing the effects of saponification, emulsification, dispersion and the like, can be realized by adding a chemical agent, and has the characteristics of simple process, easiness in operation, low cost, low toxicity, non-flammability and the like.
Wherein the saponification reaction is a process of generating soap and glycerin by chemical reaction of saponified oil and alkaline substances in the deoiling liquid. When a product having oil stains is put into an alkaline degreasing solution, the oil stains are removed due to the above saponification reaction. For mineral oil or other unsaponifiable oil, the purpose of removing oil can be achieved by adopting an emulsifier: firstly, the emulsifier is adsorbed on the interface of oil and solution, wherein lipophilic oil-based grease has affinity effect; the hydrophilic group is compatible with the deoiling water solution. Under the action of the emulsifier, the adhesive force of an oil stain interface is gradually weakened, under the combined action of fluid dynamic factors, the oil stain is gradually separated from the interface, and fine liquid drops are dispersed in the deoiling liquid to form emulsion, so that the deoiling effect is achieved.
In the prior art, the main components of the chemical degreasing liquid comprise alkali or alkaline salts such as sodium hydroxide, sodium carbonate, sodium phosphate, sodium pyrophosphate, sodium silicate and sodium borate, and in addition, the chemical degreasing liquid also comprises metal chelating agents such as EDTA and sodium citrate, and various organic additives such as emulsifiers. Typically, the alkaline degreasing fluid contains two or more types of alkali or alkaline salts. Sodium hydroxide and sodium carbonate are two inexpensive strong basic substances. Phosphates such as sodium phosphate, sodium pyrophosphate and the like are not only sources of alkali, but also play roles in chelating metal ions such as calcium, magnesium and the like, softening hard water and buffering the pH value of the solution, and a colloid film formed by the silicate can protect amphoteric metals such as aluminum, zinc and the like from being corroded. The organic additive plays a role in assisting in emulsifying and dispersing oil stains.
At present, the traditional oil removal theory only considers the wetting and penetrating action, the emulsifying action, the saponification action, the suspension dispersion action, the foaming and dirt-absorbing anti-deposition action and the solubilization action, and the theory contributes to oil removal. But the cleaning of stubborn oil stains is difficult to remove quickly and thoroughly. Under the circumstances, how to develop a more efficient chemical degreasing agent has been a technical problem to be solved in the art.
Disclosure of Invention
The invention aims to provide a novel multi-effect environment-friendly oil stain crawling agent aiming at the technical defects in the prior art, and aims to solve the technical problem that the oil removing effect of a conventional chemical oil removing agent needs to be improved.
In order to achieve the technical purpose, the invention adopts the following technical scheme:
a novel multi-effect environment-friendly oil stain creeping agent comprises a component A and a component B, wherein the component A comprises the following components in parts by weight: 40-50 parts of dodecyl dimethyl ammonium oxide, 30-35 parts of cocoamidopropyl ammonium oxide, 20-25 parts of lauramidopropyl ammonium oxide, 10-16 parts of tetradecyl dimethyl ammonium oxide, 8-16 parts of tallow alkyl dihydroxyethyl ammonium oxide, 4-8 parts of diethylene glycol methyl ether, 2-5 parts of isohexane glycol, 8-10 parts of hydroxypropyl methyl cellulose, 4-6 parts of lauramidodiethanol and 3-8 parts of linear alkyl benzene sodium sulfonate; the component B comprises the following components in parts by weight: 8-12 parts of urea thiosulfate, 6-10 parts of carbamide and 2-4 parts of sodium thiosulfate.
Preferably, the component A also comprises 12-14 parts by weight of dicarboxymethylalanine.
Preferably, the component A also comprises 6-10 parts by weight of methylglycinediacetic acid.
Preferably, the component A also comprises 2-6 parts by weight of coconut diethanolamide.
Preferably, the component B also comprises 6-8 parts by weight of fatty acid methyl ester sodium sulfonate.
Preferably, the oil stain crawling agent consists of a component A and a component B, wherein the component A consists of the following components in parts by weight: 45 parts of dodecyl dimethyl ammonium oxide, 33 parts of cocamidopropyl ammonium oxide, 22 parts of lauramidopropyl ammonium oxide, 13 parts of tetradecyl dimethyl ammonium oxide, 12 parts of tallow alkyl dihydroxyethyl ammonium oxide, 6 parts of diethylene glycol methyl ether, 4 parts of isohexyl glycol, 9 parts of hydroxypropyl methyl cellulose, 5 parts of lauramidodiethanol and 6 parts of linear alkyl benzene sodium sulfonate; the component B comprises the following components in parts by weight: 10 parts of urea thiosulfate, 8 parts of carbamide and 3 parts of sodium thiosulfate.
Preferably, the oil stain crawling agent consists of a component A and a component B, wherein the component A consists of the following components in parts by weight: 45 parts of dodecyl dimethyl ammonium oxide, 33 parts of cocamidopropyl ammonium oxide, 22 parts of lauramidopropyl ammonium oxide, 13 parts of tetradecyl dimethyl ammonium oxide, 12 parts of tallow alkyl dihydroxyethyl ammonium oxide, 6 parts of diethylene glycol methyl ether, 4 parts of isohexylene glycol, 9 parts of hydroxypropyl methyl cellulose, 5 parts of lauramide diethanol, 6 parts of linear alkylbenzene sulfonate, 13 parts of dicarboxymethylalanine, 8 parts of methylglycine diacetic acid and 4 parts of cocoanut oil diethanol amide; the component B comprises the following components in parts by weight: 10 parts of urea thiosulfate, 8 parts of carbamide, 3 parts of sodium thiosulfate and 7 parts of fatty acid methyl ester sodium sulfonate.
In the technical scheme, surfactants such as dodecyl dimethyl ammonium oxide, cocoamidopropyl ammonium oxide, lauramidopropyl ammonium oxide, tetradecyl dimethyl ammonium oxide, tallow alkyl bishydroxyethyl ammonium oxide and the like have certain wetting agent coupling property on oil stains, and have a certain fusion interval with an oil film in the process of microcosmic dynamic acting force. The addition of hydroxypropyl methylcellulose, lauramide diethanol, and sodium linear alkyl benzene sulfonate can further improve the oil and fat removal efficiency. Surfactants such as dodecyl dimethyl ammonium oxide, cocoamidopropyl ammonium oxide, lauramidopropyl ammonium oxide, tetradecyl dimethyl ammonium oxide, tallow alkyl bis-hydroxyethyl ammonium oxide and the like have certain oxidizability, and thiourea and carbamide have certain reducibility, and undergo micro-trend redox reaction and release gases such as carbon dioxide, nitrogen and the like. After the oil stains are wetted and fused, and the released gas is added, the gas can burst the oil film, tear the oil film, carry the oil film and leave the surface of the workpiece, and the oil film stripping process is completed.
The invention can improve the speed of oil removal and cleaning, save time and save power consumption and energy. The method can realize phosphorus-free cleaning, realizes technical progress in the aspect of phosphorus-free cleaning, and has higher environmental protection degree. In the grabbing and climbing process, the oil stains have small emulsifying tendency, most of the oil stains are in a separated state or a floating state, the oil stains can be separated and salvaged, the consumption of other components of the oil removal agent is reduced, the service life of the agent is prolonged, the preparation frequency of the liquid medicine is reduced, the consumption of water is reduced, and water conservation is realized. In conclusion, the multifunctional water-saving water dispenser can be used for realizing multiple functions.
Detailed Description
Hereinafter, specific embodiments of the present invention will be described in detail. Well-known structures or functions may not be described in detail in the following embodiments in order to avoid unnecessarily obscuring the details. Approximating language, as used herein in the following examples, may be applied to identify quantitative representations that could permissibly vary in number without resulting in a change in the basic function. Unless defined otherwise, technical and scientific terms used in the following examples have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.
Example 1
A novel multi-effect environment-friendly oil stain creeping agent comprises a component A and a component B, wherein the component A comprises the following components in parts by weight: 45 parts of dodecyl dimethyl ammonium oxide, 33 parts of cocamidopropyl ammonium oxide, 22 parts of lauramidopropyl ammonium oxide, 13 parts of tetradecyl dimethyl ammonium oxide, 12 parts of tallow alkyl dihydroxyethyl ammonium oxide, 6 parts of diethylene glycol methyl ether, 4 parts of isohexyl glycol, 9 parts of hydroxypropyl methyl cellulose, 5 parts of lauramidodiethanol and 6 parts of linear alkyl benzene sodium sulfonate; the component B comprises the following components in parts by weight: 10 parts of urea thiosulfate, 8 parts of carbamide and 3 parts of sodium thiosulfate.
Example 2
A novel multi-effect environment-friendly oil stain creeping agent comprises a component A and a component B, wherein the component A comprises the following components in parts by weight: 45 parts of dodecyl dimethyl ammonium oxide, 33 parts of cocamidopropyl ammonium oxide, 22 parts of lauramidopropyl ammonium oxide, 13 parts of tetradecyl dimethyl ammonium oxide, 12 parts of tallow alkyl dihydroxyethyl ammonium oxide, 6 parts of diethylene glycol methyl ether, 4 parts of isohexyl glycol, 9 parts of hydroxypropyl methyl cellulose, 5 parts of lauramidodiethanol and 6 parts of linear alkyl benzene sodium sulfonate; the component B comprises the following components in parts by weight: 10 parts of urea thiosulfate, 8 parts of carbamide and 3 parts of sodium thiosulfate.
Example 3
A novel multi-effect environment-friendly oil stain creeping agent comprises a component A and a component B, wherein the component A comprises the following components in parts by weight: 40 parts of dodecyl dimethyl ammonium oxide, 30 parts of cocamidopropyl ammonium oxide, 20 parts of lauramidopropyl ammonium oxide, 10 parts of tetradecyl dimethyl ammonium oxide, 8 parts of tallow alkyl dihydroxyethyl ammonium oxide, 4 parts of diethylene glycol methyl ether, 2 parts of isohexyl glycol, 8 parts of hydroxypropyl methyl cellulose, 4 parts of lauramidodiethanol and 3 parts of linear alkyl benzene sodium sulfonate; the component B comprises the following components in parts by weight: 8 parts of urea thiosulfate, 6 parts of carbamide and 2 parts of sodium thiosulfate.
Example 4
A novel multi-effect environment-friendly oil stain creeping agent comprises a component A and a component B, wherein the component A comprises the following components in parts by weight: 50 parts of dodecyl dimethyl ammonium oxide, 35 parts of cocamidopropyl ammonium oxide, 25 parts of lauramidopropyl ammonium oxide, 16 parts of tetradecyl dimethyl ammonium oxide, 16 parts of tallow alkyl dihydroxyethyl ammonium oxide, 8 parts of diethylene glycol methyl ether, 5 parts of isohexyl glycol, 10 parts of hydroxypropyl methyl cellulose, 6 parts of lauramidodiethanol and 8 parts of linear alkyl benzene sodium sulfonate; the component B comprises the following components in parts by weight: 12 parts of urea thiosulfate, 10 parts of carbamide and 4 parts of sodium thiosulfate.
Example 5
A novel multi-effect environment-friendly oil stain creeping agent comprises a component A and a component B, wherein the component A comprises the following components in parts by weight: 45 parts of dodecyl dimethyl ammonium oxide, 33 parts of cocamidopropyl ammonium oxide, 22 parts of lauramidopropyl ammonium oxide, 13 parts of tetradecyl dimethyl ammonium oxide, 12 parts of tallow alkyl dihydroxyethyl ammonium oxide, 6 parts of diethylene glycol methyl ether, 4 parts of isohexane glycol and 5 parts of lauramidodiethanol; the component B comprises the following components in parts by weight: 10 parts of urea thiosulfate, 8 parts of carbamide and 3 parts of sodium thiosulfate.
Example 6
The using method of the invention is as follows:
basic cleaning base material: sodium hydroxide: 20%, anhydrous sodium metasilicate: 30%, sodium carbonate: 20%, sodium gluconate: 25%, disodium EDTA: 5 percent.
The proportion of the cleaning agent finished product liquid is as follows: basic cleaning base material: 3 percent of the total weight of the mixture,
the component A of the gripping agent is as follows: 0.5,
and (3) a component B of a creeping agent: 0.5,
water: 96 percent.
Cleaning temperature: at 50 ℃.
The cleaning mode is as follows: and (5) soaking.
Cleaning materials: and the steel part is attached with emulsified oil.
Visual observation: the oil film is grabbed and peeled off completely within 5 minutes, and oil stains can be seen to float to the liquid level in the grabbing and climbing process.
The embodiments of the present invention have been described in detail, but the description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention. Any modification, equivalent replacement, and improvement made within the scope of the application of the present invention should be included in the protection scope of the present invention.
Claims (7)
1. The novel multi-effect environment-friendly oil stain creeping agent comprises a component A and a component B, and is characterized in that the component A comprises the following components in parts by weight: 40-50 parts of dodecyl dimethyl ammonium oxide, 30-35 parts of cocoamidopropyl ammonium oxide, 20-25 parts of lauramidopropyl ammonium oxide, 10-16 parts of tetradecyl dimethyl ammonium oxide, 8-16 parts of tallow alkyl dihydroxyethyl ammonium oxide, 4-8 parts of diethylene glycol methyl ether, 2-5 parts of isohexane glycol, 8-10 parts of hydroxypropyl methyl cellulose, 4-6 parts of lauramidodiethanol and 3-8 parts of linear alkyl benzene sodium sulfonate; the component B comprises the following components in parts by weight: 8-12 parts of urea thiosulfate, 6-10 parts of carbamide and 2-4 parts of sodium thiosulfate.
2. The novel multi-effect environment-friendly oil stain crawling agent according to claim 1, wherein the component A further comprises 12-14 parts by weight of dicarboxymethylalanine.
3. The novel multi-effect environment-friendly oil stain crawling agent according to claim 1, wherein the component A further comprises 6-10 parts by weight of methylglycine diacetic acid.
4. The novel multi-effect environment-friendly oil stain crawling agent according to claim 1, characterized in that the component A further comprises 2-6 parts by weight of coconut diethanolamide.
5. The novel multi-effect environment-friendly oil stain crawling agent according to claim 1, wherein the component B further comprises 6-8 parts by weight of sodium fatty acid methyl ester sulfonate.
6. The novel multi-effect environment-friendly oil stain crawling agent as claimed in claim 1, characterized by consisting of a component A and a component B, wherein the component A consists of the following components in parts by weight: 45 parts of dodecyl dimethyl ammonium oxide, 33 parts of cocamidopropyl ammonium oxide, 22 parts of lauramidopropyl ammonium oxide, 13 parts of tetradecyl dimethyl ammonium oxide, 12 parts of tallow alkyl dihydroxyethyl ammonium oxide, 6 parts of diethylene glycol methyl ether, 4 parts of isohexyl glycol, 9 parts of hydroxypropyl methyl cellulose, 5 parts of lauramidodiethanol and 6 parts of linear alkyl benzene sodium sulfonate; the component B comprises the following components in parts by weight: 10 parts of urea thiosulfate, 8 parts of carbamide and 3 parts of sodium thiosulfate.
7. The novel multi-effect environment-friendly oil stain crawling agent as claimed in claim 1, characterized by consisting of a component A and a component B, wherein the component A consists of the following components in parts by weight: 45 parts of dodecyl dimethyl ammonium oxide, 33 parts of cocamidopropyl ammonium oxide, 22 parts of lauramidopropyl ammonium oxide, 13 parts of tetradecyl dimethyl ammonium oxide, 12 parts of tallow alkyl dihydroxyethyl ammonium oxide, 6 parts of diethylene glycol methyl ether, 4 parts of isohexylene glycol, 9 parts of hydroxypropyl methyl cellulose, 5 parts of lauramide diethanol, 6 parts of linear alkylbenzene sulfonate, 13 parts of dicarboxymethylalanine, 8 parts of methylglycine diacetic acid and 4 parts of cocoanut oil diethanol amide; the component B comprises the following components in parts by weight: 10 parts of urea thiosulfate, 8 parts of carbamide, 3 parts of sodium thiosulfate and 7 parts of fatty acid methyl ester sodium sulfonate.
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| CN1339579A (en) * | 2001-10-10 | 2002-03-13 | 常耀辉 | Water base micro emulsion cleaning agent for heavy oil pollution and its prepn |
| CN101608314A (en) * | 2008-06-16 | 2009-12-23 | 南京科润工业介质有限公司 | Anti-emulsification water-soluble metal washing agent |
| CN105255597A (en) * | 2015-11-14 | 2016-01-20 | 李康 | Environmental-protection range hood detergent and preparation method thereof |
| CN105802756A (en) * | 2016-04-15 | 2016-07-27 | 张向明 | Multifunctional, efficient and environmentally friendly heavy oil contamination detergent |
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2021
- 2021-10-20 CN CN202111222571.6A patent/CN113913837A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1339579A (en) * | 2001-10-10 | 2002-03-13 | 常耀辉 | Water base micro emulsion cleaning agent for heavy oil pollution and its prepn |
| CN101608314A (en) * | 2008-06-16 | 2009-12-23 | 南京科润工业介质有限公司 | Anti-emulsification water-soluble metal washing agent |
| CN105255597A (en) * | 2015-11-14 | 2016-01-20 | 李康 | Environmental-protection range hood detergent and preparation method thereof |
| CN105802756A (en) * | 2016-04-15 | 2016-07-27 | 张向明 | Multifunctional, efficient and environmentally friendly heavy oil contamination detergent |
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Application publication date: 20220111 |