CN113912334A - Shield muck curing agent, preparation method and use method thereof - Google Patents
Shield muck curing agent, preparation method and use method thereof Download PDFInfo
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- CN113912334A CN113912334A CN202111210698.6A CN202111210698A CN113912334A CN 113912334 A CN113912334 A CN 113912334A CN 202111210698 A CN202111210698 A CN 202111210698A CN 113912334 A CN113912334 A CN 113912334A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/001—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing unburned clay
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/10—Lime cements or magnesium oxide cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00724—Uses not provided for elsewhere in C04B2111/00 in mining operations, e.g. for backfilling; in making tunnels or galleries
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00732—Uses not provided for elsewhere in C04B2111/00 for soil stabilisation
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- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A shield muck curing agent, a preparation method and a use method thereof. The invention discloses a curing agent which comprises the following raw materials in parts by weight: 10-60 parts of curing dispersant, 1-20 parts of high-molecular water-absorbing material and 0-20 parts of excitant; the shield muck curing agent has the advantages that the curing agent generates various chemical reactions under the action of water to form gelatinous hydrate, the structure is filled in muck to improve the compactness, active hydrophilic groups in the curing agent can form an integral structure with water through chemical bonds, the curing agent has strong water retention performance, and can surround and adhere to the surfaces of soil particles to form a framework network structure in a staggered manner to be bonded into a whole, so that the soil curing is realized; the transportation amount of each vehicle is increased, the transportation efficiency is improved, and the muck outward transportation cost is reduced; the curing agent is harmless to soil body, and the residue soil after curing and improvement can be used as reclamation soil and still can be used for agricultural production.
Description
Technical Field
The invention relates to the technical field of shield construction, in particular to a shield muck curing agent, a preparation method and a use method thereof.
Background
Soil pressure and slurry shield are the most common construction methods in subway, railway and urban traffic at present, and in the shield subway tunnel construction, in order to make the dregs have better plasticity, substances such as water, bentonite, foam and the like need to be added into the dregs excavated on the tunnel face. Due to the existence of a large amount of additives such as water, bentonite and foam, the excavated dregs have high water content, and are often overflowed and polluted in the outward transportation process, and the abandoned dregs are easy to cause hazards such as landslide due to high water content. At present, the physical treatment mode of the residue soil with larger water content mainly comprises the steps of performing pressure-division filtration on water in the residue soil to form a mud cake through a mud compression treatment system, and then performing outward transportation.
Disclosure of Invention
In view of the above, the invention aims to overcome the defects in the prior art, and provides a shield muck curing agent, a preparation method and a use method thereof, so that the problem of environmental pollution caused by muddy water leakage and outward flowing when muck with overlarge water content is transported outward is solved, the transport efficiency of muck trucks is improved, the transport cost is reduced, the storage capacity of muck storage yards is improved, and the utilization rate of the storage yards is improved.
The shield muck curing agent comprises the following raw materials in parts by weight: 10-60 parts of curing dispersant, 1-20 parts of high-molecular water-absorbing material and 0-20 parts of excitant;
further, the curing agent comprises the following raw materials in parts by weight: 10-60 parts of curing dispersant, 1-20 parts of high-molecular water-absorbing material and 1-20 parts of excitant;
further, the curing dispersant is any one or a mixture of more than two of cement, lime and bentonite;
further, the high molecular water absorption material is any one or a mixture of more than two of sodium alginate, carboxymethyl cellulose, hydroxypropyl methyl cellulose, sodium polyacrylate, gelatin, polypropylene alcohol, polyethylene oxide and cellulose ether;
further, the excitant is one or a mixture of more than two of sodium chloride, calcium chloride, magnesium chloride, sodium sulfate, calcium sulphoaluminate, sodium hydroxide, alkyl sulfate, triisopropanolamine, sodium dodecyl benzene sulfonate and potassium permanganate;
further, the polymer water-absorbing material is dried at the temperature of 60-105 ℃ before use and has the granularity of 20-140 meshes;
further, the particle size of the exciting agent is 100-300 meshes.
The preparation method of the shield muck curing agent comprises the following steps: mixing the solidified dispersant and the activator, uniformly stirring, then mixing with the high-molecular water-absorbing material, and uniformly stirring for 60-180 s.
The invention also discloses a use method of the shield muck curing agent, which is to mix the shield muck curing agent and the shield muck and stir the mixture for 30 to 90 seconds.
The invention has the beneficial effects that: the invention discloses a shield muck curing agent, a preparation method and a use method thereof, wherein the curing agent generates various chemical reactions under the action of water to form gelatinous hydrate, the gelatinous hydrate is filled in the muck to improve the compactness, active hydrophilic groups in the curing agent can form an integral structure with water through chemical bonds, the integral structure has strong water retention performance, and meanwhile, the integral structure can surround and attach on the surface of soil particles to form a framework network structure in a staggered manner to be bonded into a whole, so that the soil curing is realized. The curing dispersant uniformly disperses the water-absorbing polymer material, prevents the polymer material from agglomerating, improves the utilization rate of the polymer material, and can form a space skeleton structure in a gel system to improve the strength of the cured soil; the macromolecular water-absorbing material provides active groups, forms a network structure to form a tight connection effect with soil, and has strong water retention performance; the activator improves the reaction efficiency of the curing dispersant and improves the performance index of the cured soil. The shield muck curing agent has the advantages of good curing effect, high curing speed, no mud-water dripping phenomenon in the transportation process, no road pollution and no pollution to urban environment; the transportation amount of each vehicle is increased, the transportation efficiency is improved, and the muck outward transportation cost is reduced; the curing agent is harmless to soil body, and the residue soil after curing and improvement can be used as reclamation soil and still can be used for agricultural production.
Detailed Description
The following examples are provided to further illustrate the present invention for better understanding, but the present invention is not limited to the following examples.
In the examples, the experimental methods used were all conventional methods unless otherwise specified, and the materials, reagents and the like used were commercially available without otherwise specified.
Example one
The shield muck curing agent comprises the following raw materials in parts by weight: 50 parts of curing dispersant and 2 parts of high-molecular water-absorbing material.
In the embodiment, the curing dispersant is cement, and in the embodiment, the cement is replaced by one of lime and bentonite or replaced by a mixture of the cement, the lime and the bentonite according to the same weight part, so that qualified products are obtained.
In the embodiment, the high molecular water absorbing material is sodium alginate, and in the embodiment, the sodium alginate is replaced by one of carboxymethyl cellulose, hydroxypropyl methyl cellulose, sodium polyacrylate, gelatin, polypropylene alcohol, polyethylene oxide and cellulose ether or a mixture of sodium alginate, carboxymethyl cellulose, hydroxypropyl methyl cellulose, sodium polyacrylate, gelatin, polypropylene alcohol, polyethylene oxide and cellulose ether according to the same weight part, so that qualified products are obtained.
In this embodiment, the polymer water-absorbing material is dried at 105 ℃ before use and has a particle size of 100 meshes.
The preparation method of the shield muck curing agent comprises the following steps: and mixing the solidified dispersing agent with the exciting agent, uniformly stirring, then mixing with the high-molecular water-absorbing material, and uniformly stirring for 120 s.
According to the using method of the shield muck curing agent, muck with the water content of 50% is taken, added with the curing agent and uniformly stirred.
The water content, bleeding rate and liquidity index of the muck before and after the test were measured and analyzed, and the results are shown in table 1.
Example two
The shield muck curing agent comprises the following raw materials in parts by weight: 60 parts of curing dispersant and 5 parts of high molecular water-absorbing material.
In the embodiment, the solidified dispersant is lime, and in the embodiment, the lime is replaced by one of cement and bentonite or replaced by a mixture of lime, cement and bentonite according to the same weight part, so that qualified products are obtained.
In this embodiment, the high molecular water absorbing material is carboxymethyl cellulose, and in this embodiment, the carboxymethyl cellulose is replaced by one of sodium alginate, hydroxypropyl methyl cellulose, sodium polyacrylate, gelatin, polyallyl alcohol, polyethylene oxide, and cellulose ether, or replaced by a mixture of carboxymethyl cellulose and sodium alginate, hydroxypropyl methyl cellulose, sodium polyacrylate, gelatin, polyallyl alcohol, polyethylene oxide, and cellulose ether, and all the qualified products are obtained.
In this embodiment, the polymer water-absorbing material is dried at 60 ℃ before use and has a particle size of 20 meshes.
The preparation method of the shield muck curing agent comprises the following steps: and mixing the solidified dispersing agent and the exciting agent, uniformly stirring, then mixing with the high-molecular water-absorbing material, and uniformly stirring for 60 s.
In the using method of the shield muck curing agent in the embodiment, muck with the water content of 60% is taken, added with the curing agent and uniformly stirred.
The water content, bleeding rate and liquidity index of the muck before and after the test were measured and analyzed, and the results are shown in table 1.
EXAMPLE III
The shield muck curing agent comprises the following raw materials in parts by weight: 20 parts of curing dispersant and 3 parts of high molecular water-absorbing material.
In the embodiment, the solidified dispersant is bentonite, and the bentonite is replaced by one of lime and cement or replaced by a mixture of the bentonite, the lime and the cement according to the same weight part, so that qualified products are obtained.
In this embodiment, the high molecular water absorbing material is hydroxypropyl methyl cellulose, and in this embodiment, the hydroxypropyl methyl cellulose is replaced by one of carboxymethyl cellulose, sodium alginate, sodium polyacrylate, gelatin, polypropylene glycol, polyethylene oxide, and cellulose ether, or replaced by a mixture of hydroxypropyl methyl cellulose, carboxymethyl cellulose, sodium alginate, sodium polyacrylate, gelatin, polypropylene glycol, polyethylene oxide, and cellulose ether, all of which are acceptable products.
In this embodiment, the polymer water-absorbing material is dried at 70 ℃ before use and has a particle size of 80 mesh.
The preparation method of the shield muck curing agent comprises the following steps: and mixing the solidified dispersing agent and the exciting agent, uniformly stirring, then mixing with the high-molecular water-absorbing material, and uniformly stirring for 150 seconds.
According to the using method of the shield muck curing agent, muck with the water content of 50% is taken, added with the curing agent and uniformly stirred.
The water content, bleeding rate and liquidity index of the muck before and after the test were measured and analyzed, and the results are shown in table 1.
Example four
The shield muck curing agent comprises the following raw materials in parts by weight: 15 parts of curing dispersant and 3 parts of high molecular water-absorbing material.
In the embodiment, the curing dispersant is cement, and in the embodiment, the cement is replaced by one of lime and bentonite or replaced by a mixture of the cement, the lime and the bentonite according to the same weight part, so that qualified products are obtained.
In the embodiment, the high molecular water absorbing material is sodium polyacrylate, and in the embodiment, the sodium polyacrylate is replaced by one of carboxymethyl cellulose, hydroxypropyl methyl cellulose, sodium alginate, gelatin, polypropylene alcohol, polyethylene oxide and cellulose ether or a mixture of sodium polyacrylate, carboxymethyl cellulose, hydroxypropyl methyl cellulose, sodium alginate, gelatin, polypropylene alcohol, polyethylene oxide and cellulose ether according to the same weight part, so that qualified products are obtained.
In this embodiment, the polymer water-absorbing material is dried at 100 ℃ before use and has a particle size of 110 mesh.
The preparation method of the shield muck curing agent comprises the following steps: and mixing the solidified dispersing agent with the exciting agent, uniformly stirring, then mixing with the high-molecular water-absorbing material, and uniformly stirring for 120 s.
According to the using method of the shield muck curing agent, muck with the water content of 65% is taken, added with the curing agent and uniformly stirred.
The water content, bleeding rate and liquidity index of the muck before and after the test were measured and analyzed, and the results are shown in table 1.
EXAMPLE five
The shield muck curing agent comprises the following raw materials in parts by weight: 10 parts of curing dispersant, 1 part of high molecular water-absorbing material and 10 parts of excitant.
In the embodiment, the curing dispersant is cement, and in the embodiment, the cement is replaced by one of lime and bentonite or replaced by a mixture of the cement, the lime and the bentonite according to the same weight part, so that qualified products are obtained.
In the embodiment, the high molecular water absorbing material is gelatin, and in the embodiment, the gelatin is replaced by one of carboxymethyl cellulose, hydroxypropyl methyl cellulose, sodium polyacrylate, sodium alginate, polypropylene alcohol, polyethylene oxide and cellulose ether or by a mixture of gelatin, carboxymethyl cellulose, hydroxypropyl methyl cellulose, sodium polyacrylate, sodium alginate, polypropylene alcohol, polyethylene oxide and cellulose ether according to the same weight part, so that qualified products are obtained.
In this embodiment, the activator is sodium chloride, and in this embodiment, the sodium chloride is replaced by one of calcium chloride, magnesium chloride, sodium sulfate, calcium sulfoaluminate, sodium hydroxide, alkyl sulfate, triisopropanolamine, sodium dodecylbenzenesulfonate and potassium permanganate or a mixture of sodium chloride, magnesium chloride, sodium sulfate, calcium sulfoaluminate, sodium hydroxide, alkyl sulfate, triisopropanolamine, sodium dodecylbenzenesulfonate and potassium permanganate according to the same weight parts, so as to obtain qualified products.
In the embodiment, the polymer water-absorbing material is dried at 100 ℃ before use and has the granularity of 30 meshes; the particle size of the exciting agent is 100 meshes.
The preparation method of the shield muck curing agent comprises the following steps: mixing the solidified dispersing agent with the exciting agent, uniformly stirring, then mixing with the high-molecular water-absorbing material, and uniformly stirring for 180 s.
According to the using method of the shield muck curing agent, muck with the water content of 55% is taken, added with the curing agent and uniformly stirred.
The water content, bleeding rate and liquidity index of the muck before and after the test were measured and analyzed, and the results are shown in table 1.
EXAMPLE six
The shield muck curing agent comprises the following raw materials in parts by weight: 60 parts of curing dispersant, 20 parts of high-molecular water-absorbing material and 20 parts of excitant.
In the embodiment, the solidified dispersant is lime, and in the embodiment, the lime is replaced by one of cement and bentonite or replaced by a mixture of lime, cement and bentonite according to the same weight part, so that qualified products are obtained.
In the embodiment, the high molecular water absorbing material is polyoxyethylene, and in the embodiment, the polyoxyethylene is replaced by one of carboxymethyl cellulose, hydroxypropyl methyl cellulose, sodium polyacrylate, gelatin, sodium alginate, polyallyl alcohol and cellulose ether or a mixture of polyoxyethylene, carboxymethyl cellulose, hydroxypropyl methyl cellulose, sodium polyacrylate, gelatin, sodium alginate, polyallyl alcohol and cellulose ether according to the same weight part, so that qualified products are obtained.
In the embodiment, the excitant is magnesium chloride, and the magnesium chloride is replaced by one of calcium chloride, sodium sulfate, calcium sulphoaluminate, sodium hydroxide, alkyl sulfate, triisopropanolamine, sodium dodecyl benzene sulfonate and potassium permanganate or a mixture of the magnesium chloride, the calcium chloride, the sodium sulfate, the calcium sulphoaluminate, the sodium hydroxide, the alkyl sulfate, the triisopropanolamine, the sodium dodecyl benzene sulfonate and the potassium permanganate according to the same weight part, so that qualified products are obtained.
In the embodiment, the polymer water-absorbing material is dried at 95 ℃ before use and has the granularity of 40 meshes; the particle size of the excitant is 200 meshes.
The preparation method of the shield muck curing agent comprises the following steps: and mixing the solidified dispersing agent and the exciting agent, uniformly stirring, then mixing with the high-molecular water-absorbing material, and uniformly stirring for 80 s.
EXAMPLE seven
The shield muck curing agent comprises the following raw materials in parts by weight: 10-60 parts of curing dispersant, 1-20 parts of high-molecular water-absorbing material and 0-20 parts of excitant.
In the embodiment, the curing dispersant is cement, and in the embodiment, the cement is replaced by one of lime and bentonite or replaced by a mixture of the cement, the lime and the bentonite according to the same weight part, so that qualified products are obtained.
In the embodiment, the high molecular water absorbing material is gelatin, and in the embodiment, the gelatin is replaced by one of carboxymethyl cellulose, hydroxypropyl methyl cellulose, sodium polyacrylate, sodium alginate, polypropylene alcohol, polyethylene oxide and cellulose ether or by a mixture of gelatin, carboxymethyl cellulose, hydroxypropyl methyl cellulose, sodium polyacrylate, sodium alginate, polypropylene alcohol, polyethylene oxide and cellulose ether according to the same weight part, so that qualified products are obtained.
In this embodiment, the activator is sodium chloride, and in this embodiment, the sodium chloride is replaced by one of calcium chloride, magnesium chloride, sodium sulfate, calcium sulfoaluminate, sodium hydroxide, alkyl sulfate, triisopropanolamine, sodium dodecylbenzenesulfonate and potassium permanganate or by a mixture of sodium chloride, calcium chloride, magnesium chloride, sodium sulfate, calcium sulfoaluminate, sodium hydroxide, alkyl sulfate, triisopropanolamine, sodium dodecylbenzenesulfonate and potassium permanganate according to the same weight parts, so as to obtain qualified products.
In the embodiment, the polymer water-absorbing material is dried at 100 ℃ before use and has the granularity of 30 meshes; the particle size of the exciting agent is 100 meshes.
The preparation method of the shield muck curing agent comprises the following steps: mixing the solidified dispersing agent with the exciting agent, uniformly stirring, then mixing with the high-molecular water-absorbing material, and uniformly stirring for 180 s.
According to the using method of the shield muck curing agent, muck with the water content of 55% is taken, added with the curing agent and uniformly stirred.
The water content, bleeding rate and liquidity index of the muck before and after the test were measured and analyzed, and the results are shown in table 1.
Example eight
The shield muck curing agent comprises the following raw materials in parts by weight: 60 parts of curing dispersant, 20 parts of high-molecular water-absorbing material and 20 parts of excitant.
In the embodiment, the curing dispersant is cement, and in the embodiment, the cement is replaced by one of lime and bentonite or replaced by a mixture of the cement, the lime and the bentonite according to the same weight part, so that qualified products are obtained.
In the embodiment, the high molecular water absorbing material is cellulose ether, and in the embodiment, the cellulose ether is replaced by one of carboxymethyl cellulose, hydroxypropyl methyl cellulose, sodium polyacrylate, sodium alginate, polyallyl alcohol, polyethylene oxide and gelatin or a mixture of cellulose ether, carboxymethyl cellulose, hydroxypropyl methyl cellulose, sodium polyacrylate, sodium alginate, polyallyl alcohol, polyethylene oxide and gelatin according to the same weight part, so that qualified products are obtained.
In this embodiment, the activator is sodium sulfate, and in this embodiment, the sodium sulfate is replaced by one of calcium chloride, magnesium chloride, sodium chloride, calcium sulfate, calcium sulphoaluminate, sodium hydroxide, alkyl sulfate, triisopropanolamine, sodium dodecylbenzene sulfonate and potassium permanganate or by a mixture of sodium sulfate, calcium chloride, magnesium chloride, sodium chloride, calcium sulfate, calcium sulphoaluminate, sodium hydroxide, alkyl sulfate, triisopropanolamine, sodium dodecylbenzene sulfonate and potassium permanganate according to the same weight parts, so as to obtain qualified products.
In the embodiment, the polymer water-absorbing material is dried at 100 ℃ before use and has the granularity of 30 meshes; the particle size of the exciting agent is 100 meshes.
The preparation method of the shield muck curing agent comprises the following steps: mixing the solidified dispersing agent with the exciting agent, uniformly stirring, then mixing with the high-molecular water-absorbing material, and uniformly stirring for 180 s.
According to the using method of the shield muck curing agent, muck with the water content of 55% is taken, added with the curing agent and uniformly stirred.
The water content, bleeding rate and liquidity index of the muck before and after the test were measured and analyzed, and the results are shown in table 1.
Example nine
The shield muck curing agent comprises the following raw materials in parts by weight: 10 parts of curing dispersant, 20 parts of high molecular water-absorbing material and 10 parts of excitant.
In the embodiment, the curing dispersant is cement, and in the embodiment, the cement is replaced by one of lime and bentonite or replaced by a mixture of the cement, the lime and the bentonite according to the same weight part, so that qualified products are obtained.
In this embodiment, the high molecular water absorbing material is hydroxypropyl methyl cellulose, and in this embodiment, the hydroxypropyl methyl cellulose is replaced by one of carboxymethyl cellulose, gelatin, sodium polyacrylate, sodium alginate, polyallyl alcohol, polyethylene oxide, and cellulose ether, or replaced by a mixture of hydroxypropyl methyl cellulose, carboxymethyl cellulose, gelatin, sodium polyacrylate, sodium alginate, polyallyl alcohol, polyethylene oxide, and cellulose ether, according to the same weight parts, so as to obtain qualified products.
In this embodiment, the activator is sodium dodecylbenzene sulfonate, and in this embodiment, the sodium dodecylbenzene sulfonate is replaced by one of calcium chloride, magnesium chloride, sodium sulfate, calcium sulfoaluminate, sodium hydroxide, alkyl sulfate, triisopropanolamine, sodium chloride, and potassium permanganate or by a mixture of sodium dodecylbenzene sulfonate, calcium chloride, magnesium chloride, sodium sulfate, calcium sulfoaluminate, sodium hydroxide, alkyl sulfate, triisopropanolamine, sodium chloride, and potassium permanganate according to the same weight parts, and qualified products are obtained.
In the embodiment, the polymer water-absorbing material is dried at 100 ℃ before use and has the granularity of 30 meshes; the particle size of the exciting agent is 100 meshes.
The preparation method of the shield muck curing agent comprises the following steps: mixing the solidified dispersing agent with the exciting agent, uniformly stirring, then mixing with the high-molecular water-absorbing material, and uniformly stirring for 180 s.
According to the using method of the shield muck curing agent, muck with the water content of 55% is taken, added with the curing agent and uniformly stirred.
The water content, bleeding rate and liquidity index of the muck before and after the test were measured and analyzed, and the results are shown in table 1.
Table 1 before and after the tests of examples 1-6, the parameters of the properties of the muck
The shield muck curing agent prepared by the method is convenient to use, the reaction rate is high, the water content of the processed muck is not obviously changed, so that the muck has good water retention, but the tested muck almost has no bleeding, the state is rapidly changed from the initial plastic flowing state to a plastic state, the rapid loading and outward transportation can be realized, and meanwhile, the considerable water content is kept, so that the possibility is provided for plant planting.
Finally, the above embodiments are only for illustrating the technical solutions of the present invention and not for limiting, although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made to the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, and all of them should be covered in the claims of the present invention.
Claims (9)
1. The shield muck curing agent is characterized in that: the curing agent comprises the following raw materials in parts by weight: 10-60 parts of curing dispersant, 1-20 parts of high-molecular water-absorbing material and 0-20 parts of excitant.
2. The shield muck curing agent according to claim 1, wherein: the curing agent comprises the following raw materials in parts by weight: 10-60 parts of curing dispersant, 1-20 parts of high-molecular water-absorbing material and 1-20 parts of excitant.
3. The shield muck curing agent according to claim 1, wherein: the curing dispersant is any one or a mixture of more than two of cement, lime and bentonite.
4. The shield muck curing agent according to claim 3, wherein: the high molecular water-absorbing material is any one or a mixture of more than two of sodium alginate, carboxymethyl cellulose, hydroxypropyl methyl cellulose, sodium polyacrylate, gelatin, polypropylene glycol, polyethylene oxide and cellulose ether.
5. The shield muck curing agent according to claim 4, wherein: the excitant is one or a mixture of more than two of sodium chloride, calcium chloride, magnesium chloride, sodium sulfate, calcium sulphoaluminate, sodium hydroxide, alkyl sulfate, triisopropanolamine, sodium dodecyl benzene sulfonate and potassium permanganate.
6. The shield muck curing agent according to claim 5, wherein: the polymer water-absorbing material is dried at 60-105 ℃ before use and has the granularity of 20-140 meshes.
7. The shield muck curing agent according to claim 6, wherein: the particle size of the excitant is 100-300 meshes.
8. The preparation method of the shield muck curing agent according to claim 1, which is characterized in that: the method comprises the following steps: mixing the solidified dispersant and the activator, uniformly stirring, then mixing with the high-molecular water-absorbing material, and uniformly stirring for 60-180 s.
9. The use method of the shield muck curing agent according to claim 1, characterized in that: and mixing the shield muck curing agent with the shield muck and stirring for 30-90 s.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115196939A (en) * | 2022-08-17 | 2022-10-18 | 徐州中矿岩土技术股份有限公司 | Soft soil curing agent and modified soil material for surface layer of shield muck accumulation area and preparation method thereof |
| CN115432995A (en) * | 2022-06-28 | 2022-12-06 | 广州市北二环交通科技有限公司 | Perforated brick prepared by utilizing engineering waste slurry |
| CN115557774A (en) * | 2022-12-05 | 2023-01-03 | 中国市政工程华北设计研究总院有限公司 | Road subgrade material for solidifying shield muck with high water content and preparation method thereof |
| CN115650690A (en) * | 2022-09-06 | 2023-01-31 | 南京理工大学 | Novel composite polymer shield muck curing agent |
| CN115724622A (en) * | 2022-12-27 | 2023-03-03 | 河南锐实达分离设备科技股份有限公司 | Soil pressure shield argillaceous muck composite curing agent and curing method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107445428A (en) * | 2017-08-31 | 2017-12-08 | 堡森（上海）环境工程有限公司 | Regardless of scattered sludge curing agent under a kind of environment-friendly type water for restoration of the ecosystem |
| CN107602004A (en) * | 2017-11-06 | 2018-01-19 | 安宁兴固环保科技有限公司 | A kind of multi-element, inorganic composite granule soil solidification additive |
| CN108912714A (en) * | 2018-07-27 | 2018-11-30 | 河北动向科技有限公司 | A kind of solid waste forestry plant fiber ecological ground mulching materials curing agent and preparation method thereof and construction method |
| CN109749748A (en) * | 2018-12-20 | 2019-05-14 | 中铁开发投资集团有限公司 | A kind of rich water round gravel stratum shield sediment improvement method and sediment improvement agent |
| CN110470516A (en) * | 2019-08-25 | 2019-11-19 | 天津大学 | A method of solidification effect is studied using orthogonal experiment using compounding curing agent |
| CN113402216A (en) * | 2021-08-10 | 2021-09-17 | 中国市政工程华北设计研究总院有限公司 | Shield muck curing agent and resource utilization method thereof |
-
2021
- 2021-10-18 CN CN202111210698.6A patent/CN113912334A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107445428A (en) * | 2017-08-31 | 2017-12-08 | 堡森（上海）环境工程有限公司 | Regardless of scattered sludge curing agent under a kind of environment-friendly type water for restoration of the ecosystem |
| CN107602004A (en) * | 2017-11-06 | 2018-01-19 | 安宁兴固环保科技有限公司 | A kind of multi-element, inorganic composite granule soil solidification additive |
| CN108912714A (en) * | 2018-07-27 | 2018-11-30 | 河北动向科技有限公司 | A kind of solid waste forestry plant fiber ecological ground mulching materials curing agent and preparation method thereof and construction method |
| CN109749748A (en) * | 2018-12-20 | 2019-05-14 | 中铁开发投资集团有限公司 | A kind of rich water round gravel stratum shield sediment improvement method and sediment improvement agent |
| CN110470516A (en) * | 2019-08-25 | 2019-11-19 | 天津大学 | A method of solidification effect is studied using orthogonal experiment using compounding curing agent |
| CN113402216A (en) * | 2021-08-10 | 2021-09-17 | 中国市政工程华北设计研究总院有限公司 | Shield muck curing agent and resource utilization method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115432995A (en) * | 2022-06-28 | 2022-12-06 | 广州市北二环交通科技有限公司 | Perforated brick prepared by utilizing engineering waste slurry |
| CN115432995B (en) * | 2022-06-28 | 2023-09-12 | 广州市北二环交通科技有限公司 | Porous brick prepared from engineering waste slurry |
| CN115196939A (en) * | 2022-08-17 | 2022-10-18 | 徐州中矿岩土技术股份有限公司 | Soft soil curing agent and modified soil material for surface layer of shield muck accumulation area and preparation method thereof |
| CN115650690A (en) * | 2022-09-06 | 2023-01-31 | 南京理工大学 | Novel composite polymer shield muck curing agent |
| CN115557774A (en) * | 2022-12-05 | 2023-01-03 | 中国市政工程华北设计研究总院有限公司 | Road subgrade material for solidifying shield muck with high water content and preparation method thereof |
| CN115724622A (en) * | 2022-12-27 | 2023-03-03 | 河南锐实达分离设备科技股份有限公司 | Soil pressure shield argillaceous muck composite curing agent and curing method thereof |
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