CN113897233A - Solubility enhancer and preparation method thereof - Google Patents
Solubility enhancer and preparation method thereof Download PDFInfo
- Publication number
- CN113897233A CN113897233A CN202111255578.8A CN202111255578A CN113897233A CN 113897233 A CN113897233 A CN 113897233A CN 202111255578 A CN202111255578 A CN 202111255578A CN 113897233 A CN113897233 A CN 113897233A
- Authority
- CN
- China
- Prior art keywords
- isomeric alcohol
- isomeric
- adipate
- solubility enhancer
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000008137 solubility enhancer Substances 0.000 title claims abstract description 53
- 238000002360 preparation method Methods 0.000 title description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 75
- 239000010687 lubricating oil Substances 0.000 claims abstract description 20
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 claims abstract description 18
- -1 n-octanol adipate Chemical compound 0.000 claims description 14
- 230000002708 enhancing effect Effects 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 150000001298 alcohols Chemical class 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000012744 reinforcing agent Substances 0.000 claims description 3
- 239000002966 varnish Substances 0.000 abstract description 11
- 239000010802 sludge Substances 0.000 abstract description 9
- 239000007857 degradation product Substances 0.000 abstract description 7
- 230000001050 lubricating effect Effects 0.000 abstract description 7
- 238000012423 maintenance Methods 0.000 abstract description 6
- 239000006184 cosolvent Substances 0.000 abstract description 4
- 238000009825 accumulation Methods 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 3
- 239000003599 detergent Substances 0.000 abstract description 3
- 238000011161 development Methods 0.000 abstract description 3
- 230000007774 longterm Effects 0.000 abstract description 3
- 239000003921 oil Substances 0.000 description 14
- 238000012360 testing method Methods 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- 239000010723 turbine oil Substances 0.000 description 5
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 238000011056 performance test Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- WAXKSBQHHRJJLC-UHFFFAOYSA-N 22-methyltricosan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCCCCCCCO WAXKSBQHHRJJLC-UHFFFAOYSA-N 0.000 description 3
- XCAKLCDEUPZJOI-UHFFFAOYSA-N 24-methylpentacosan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCCCCCCCCCO XCAKLCDEUPZJOI-UHFFFAOYSA-N 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000010705 motor oil Substances 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- ZXUOFCUEFQCKKH-UHFFFAOYSA-N 12-methyltridecan-1-ol Chemical compound CC(C)CCCCCCCCCCCO ZXUOFCUEFQCKKH-UHFFFAOYSA-N 0.000 description 1
- CFSSWEQYBLCBLH-UHFFFAOYSA-N 14-methylpentadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCO CFSSWEQYBLCBLH-UHFFFAOYSA-N 0.000 description 1
- YXHAAEIHLXHTJP-UHFFFAOYSA-N 18-methylnonadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCCCO YXHAAEIHLXHTJP-UHFFFAOYSA-N 0.000 description 1
- PCWGTDULNUVNBN-UHFFFAOYSA-N 4-methylpentan-1-ol Chemical compound CC(C)CCCO PCWGTDULNUVNBN-UHFFFAOYSA-N 0.000 description 1
- PLLBRTOLHQQAQQ-UHFFFAOYSA-N 8-methylnonan-1-ol Chemical compound CC(C)CCCCCCCO PLLBRTOLHQQAQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004440 Isodecyl alcohol Substances 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/04—Hydroxy compounds
- C10M129/06—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/68—Esters
- C10M129/72—Esters of polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/135—Steam engines or turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention provides a solubility enhancer comprising an isomeric alcohol; the isomeric alcohol is selected from one or more of C12-C32 straight chain isomeric alcohol and C12-C32 branched chain isomeric alcohol. Compared with the prior art, the solubility enhancer provided by the invention takes mixed isomeric alcohol as a main body, further adipate as a cosolvent can be added, the dissolving capacity of the lubricating oil to degradation products is enhanced, and the solubility enhancer has good high-temperature performance, is an excellent lubricating oil detergent, is suitable for lubricating systems of equipment with higher working environment temperature, such as a steam turbine and the like, is beneficial to long-term use and maintenance of industrial equipment, solves the problem of varnish sludge accumulation which troubles the lubricating system of the industrial equipment for a long time, reduces the equipment maintenance cost, and has a very considerable development prospect.
Description
Technical Field
The invention belongs to the technical field of lubricating oil, and particularly relates to a solubility enhancer and a preparation method thereof.
Background
Lubricating oils can degrade during their use by a variety of mechanisms, including oxidation, thermal degradation, and hydrolysis. As the concentration increases, such degradation products become insoluble in the lubricating oil and precipitate out of solution onto the metal surfaces and critical mechanical parts of the lubricating system, causing some damage to the equipment, reducing equipment reliability and service life, leading to safety risks in use.
The addition of the solubility enhancer is a better varnish and oil sludge removal scheme, and the solubility of the oil product in varnish and oil sludge can be enhanced by adding a small amount of the solubility enhancer into the oil product. In the operation process of equipment, along with the generation of degradation products such as varnish, oil sludge and the like, the lubricating oil added with the solubility enhancer can dissolve a large amount of degradation products under the condition of keeping the performance of the oil almost unchanged, so that the varnish and the oil sludge are prevented from being attached to the surface of the equipment. The characteristic enables the lubricating oil to be normally used in equipment for a longer time, prolongs the oil change period and reduces the use cost of the equipment. Meanwhile, because varnish and oil sludge attached to the equipment are reduced, the service life of the equipment is prolonged, and the use safety is greatly improved.
Currently, there are few products on the market for solubility enhancers. According to the present data, solubility enhancers can be divided into three types: ester type, ether type and alcohol type. Ester type and ether type solubility enhancers are not available in the market due to the complex synthetic route and high production cost. The alcohol-type solubility enhancer is only a product of American Fluitec company at present, and application cases of the company show that the alcohol-type solubility enhancer has better capability of enhancing the solubility of lubricating oil and has good compatibility with various types of II, III and IV oil.
However, the main problems with alcohol-based solubility enhancers are: 1) the price is high, the Fluitec company monopolizes production and sale, the price per ton is nearly million yuan, and the cost of the oil for equipment is greatly improved; 2) the alcohol-type solubility enhancer has narrow application temperature, poor high-temperature performance and poor low-temperature performance, and cannot adapt to the working conditions of extremely high-temperature or low-temperature environments.
Disclosure of Invention
In view of the above, the technical problem to be solved by the present invention is to provide a solubility enhancer and a preparation method thereof, wherein the solubility enhancer improves the dissolving capacity of oil products to degradation products through compound improvement of various compounds, so that the oil products have good varnish and oil sludge generation resistance while maintaining good performance, and is suitable for equipment with high temperature working conditions such as steam turbines.
The invention provides a solubility enhancer comprising an isomeric alcohol;
the isomeric alcohol is selected from one or more of C12-C32 straight chain isomeric alcohol and C12-C32 branched chain isomeric alcohol.
Preferably, the number of branches in the branched isomeric alcohol is 1-4.
Preferably, the isomeric alcohol is selected from one or more of a linear isomeric alcohol from C12 to C16, a branched isomeric alcohol from C12 to C16, a linear isomeric alcohol from C17 to C22, a branched isomeric alcohol from C17 to C22, a linear isomeric alcohol from C23 to C32 and a branched isomeric alcohol from C23 to C32.
Preferably, the number of branched chains in the branched chain isomeric alcohol of C12-C16 is 1-3; the number of branched chains in the branched chain isomeric alcohol of C17-C22 is 1-2; the number of branched chains in the branched chain isomeric alcohol of C23-C32 is 1-4.
Preferably, further comprising adipate esters; the mass ratio of the isomeric alcohol to the adipate is (90-100): (0.1-10).
Preferably, the adipate is selected from one or more of n-octanol adipate, n-heptanol-n-octanol adipate, isodecanol adipate and isododecanol adipate.
Preferably, the mass ratio of the isomeric alcohol to the adipate is (98-100): (0.1-2).
The invention also provides a preparation method of the solubility enhancer, which comprises the following steps:
the isomeric alcohol is heated and stirred evenly to obtain the solubility reinforcing agent.
Preferably, adipate is also added; the heating temperature is 70-120 ℃.
The invention also provides lubricating oil comprising the solubility enhancer.
The invention provides a solubility enhancer comprising an isomeric alcohol; the isomeric alcohol is selected from one or more of C12-C32 straight chain isomeric alcohol and C12-C32 branched chain isomeric alcohol. Compared with the prior art, the solubility enhancer provided by the invention takes mixed isomeric alcohol as a main body, further adipate as a cosolvent can be added, the dissolving capacity of the lubricating oil to degradation products is enhanced, and the solubility enhancer has good high-temperature performance, is an excellent lubricating oil detergent, is suitable for lubricating systems of equipment with higher working environment temperature, such as a steam turbine and the like, is beneficial to long-term use and maintenance of industrial equipment, solves the problem of varnish sludge accumulation which troubles the lubricating system of the industrial equipment for a long time, reduces the equipment maintenance cost, and has a very considerable development prospect.
Experimental results show that when the solubility enhancer obtained by the invention is added into lubricating oil, the paint film tendency index (MPC value) of the lubricating oil is reduced by more than 50%; the flash point (opening) is more than 200 ℃ and the pour point is less than-30 ℃.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides a solubility enhancer which comprises isomeric alcohol, wherein the isomeric alcohol is one or more of C12-C32 straight chain isomeric alcohol and C12-C32 branched chain isomeric alcohol.
According to the invention, isomeric alcohol is used as a main body, preferably adipate is also added as a cosolvent, and a mixed liquid capable of effectively enhancing the solubility of the lubricating oil is obtained by blending and compounding; the mass ratio of the isomeric alcohol to the adipate is preferably (90-100): (0.1-10), more preferably (98-100): (0.1-2).
The number of branched chains in the branched chain isomeric alcohol of C12-C32 is preferably 1-4; in the present invention, preferably, the isomeric alcohol is one or more of a linear isomeric alcohol having a carbon number of 12 to 16, a branched isomeric alcohol having a carbon number of 12 to 16, a linear isomeric alcohol having a carbon number of 17 to 22, a branched isomeric alcohol having a carbon number of 17 to 22, a linear isomeric alcohol having a carbon number of 23 to 32, and a branched isomeric alcohol having a carbon number of 23 to 32; the number of branched chains in the branched chain isomeric alcohol of C12-C16 is preferably 1-3; the number of branched chains in the branched chain isomeric alcohol of C17-C22 is preferably 1-2; the number of branched chains in the branched chain isomeric alcohol of C23-C32 is preferably 1-4; more preferably, the isomeric alcohol is two or three of C12-C16 straight chain isomeric alcohol, C12-C16 branched chain isomeric alcohol, C17-C22 straight chain isomeric alcohol, C17-C22 branched chain isomeric alcohol, C23-C32 straight chain isomeric alcohol and C23-C32 branched chain isomeric alcohol, and still more preferably, the isomeric alcohol is three of isotetradecanol, isohexadecanol, isooctadecanol, isoeicosanol, isotetracosanol and isohexacosanol; the mass ratio of the three in which the number of carbon atoms is less than or equal to at most (1 to 3.5): (1-3.5): (1-3.5), more preferably (2-3.5): (2-3.5): (2-3.5), preferably (2-3): (3-3.5): (3-3.5).
The adipate is preferably one or more of n-octanol adipate, n-heptanol-n-octanol adipate, isodecanol adipate and isododecanol adipate.
The solubility enhancer provided by the invention takes mixed isomeric alcohol as a main body, and further adipate as a cosolvent can be added, so that the solubility of the lubricating oil on degradation products can be enhanced, and the solubility enhancer also has good high-temperature performance, is an excellent lubricating oil detergent, is suitable for lubricating systems of equipment with higher working environment temperature, such as a steam turbine and the like, is beneficial to long-term use and maintenance of industrial equipment, solves the problem of varnish sludge accumulation which troubles the lubricating system of the industrial equipment for a long time, reduces the equipment maintenance cost, and has a very considerable development prospect.
The invention also provides a preparation method of the solubility enhancer, which comprises the following steps: the isomeric alcohol is heated and stirred evenly to obtain the solubility reinforcing agent.
In the present invention, the sources of all raw materials are not particularly limited, and they may be commercially available.
Preferably, the isomeric alcohol and the adipate are heated and stirred uniformly after being mixed; the types and proportions of the isomeric alcohols and the adipic esters are the same as those described above, and are not described in detail herein.
Mixing isomeric alcohol and adipate, heating and stirring uniformly to obtain a solubility enhancer; the heating and stirring temperature is preferably 70-120 ℃, more preferably 80-110 ℃, and further preferably 90-100 ℃.
The invention also provides lubricating oil comprising the solubility enhancer; preferably further comprises lubricating oil; the mass of the solubility enhancer is 3 to 8 percent of the mass of the lubricating oil, more preferably 3 to 6 percent, and still more preferably 4 to 5 percent.
In order to further illustrate the present invention, a solubility enhancer and a method for preparing the same according to the present invention will be described in detail with reference to examples.
The reagents used in the following examples are all commercially available.
Example 1
Uniformly stirring 100% mixed isomeric alcohol (wherein the ratio of the isohexanol, the isotetracosanol and the isohexacosanol is 3:3.5:3.5) at the temperature of 95 ℃ to obtain the solubility enhancer with uniform and transparent appearance.
The solubility enhancing agent obtained in example 1 was subjected to performance test, and the results are shown in Table 1.
Table 1 solubility enhancer performance test results
The solubility enhancer obtained in example 1 was mixed with synthetic turbine oil No. 46 at a mass ratio of 1:20, and the results of the tests are shown in Table 2, and it can be seen that the viscosity and oxidation resistance were slightly decreased and the formation of a paint film was remarkably suppressed after the addition of the solubility enhancer. The addition of the solubility enhancing agent can achieve the effect of suppressing the varnish formation without affecting the use of the turbine oil itself.
TABLE 2 solubility enhancer and Engine oil mix test results
Example 2
Mixing 98% of mixed isomeric alcohol (wherein the ratio of isooctadecanol, isotetracosanol and isohexacosanol is 2:3:3.5) and 2% of n-octanol adipate, and stirring uniformly at 75 ℃ to obtain the solubility enhancer with uniform and transparent appearance.
The solubility enhancing agent obtained in example 2 was subjected to a performance test, and the results are shown in Table 3.
Table 3 solubility enhancer performance test results
The solubility enhancer obtained in example 2 was mixed with synthetic turbine oil No. 46 at a mass ratio of 1:20, and the results of the tests are shown in Table 4, which shows that the viscosity and oxidation resistance were slightly decreased and the formation of a paint film was remarkably suppressed after the solubility enhancer was added. The addition of the solubility enhancing agent can achieve the effect of suppressing the varnish formation without affecting the use of the turbine oil itself.
TABLE 4 solubility enhancer and Engine oil mix test results
Comparative example 1
Mixing 98% of mixed isomeric alcohol (wherein the ratio of iso-decyl alcohol, iso-eicosyl alcohol and iso-hexacyl alcohol is 2:3:3.5) and 2% of n-octyl alcohol adipate uniformly at 60 deg.C to obtain the solubility enhancer with uniform and transparent appearance.
The solubility enhancing agents obtained in comparative example 1 were examined, and the results are shown in Table 5.
Table 5 test results for solubility enhancer performance of comparative example 1
The solubility enhancer obtained in comparative example 1 was mixed with synthetic turbine oil No. 46 in a mass ratio of 1:20, and the results of the tests are shown in table 6, and it can be seen that the viscosity and oxidation resistance were slightly decreased but the generation of the paint film was not significantly suppressed after the addition of the solubility enhancer. The solubility enhancer with the addition ratio outside the protection range has poor effect of inhibiting the generation of the paint film.
Table 6 comparative example 1 results of testing the solubility enhancer mixed with engine oil
Claims (10)
1. A solubility enhancing agent comprising an isomeric alcohol;
the isomeric alcohol is selected from one or more of C12-C32 straight chain isomeric alcohol and C12-C32 branched chain isomeric alcohol.
2. The solubility enhancer according to claim 1, wherein the number of branches in the branched isomeric alcohol is 1 to 4.
3. The solubility enhancing agent of claim 1, wherein the isomeric alcohol is selected from one or more of the group consisting of C12-C16 linear isomeric alcohols, C12-C16 branched isomeric alcohols, C17-C22 linear isomeric alcohols, C17-C22 branched isomeric alcohols, C23-C32 linear isomeric alcohols, and C23-C32 branched isomeric alcohols.
4. The solubility enhancer according to claim 3, wherein the number of branches in the branched isomeric alcohol having C12-C16 is 1-3; the number of branched chains in the branched chain isomeric alcohol of C17-C22 is 1-2; the number of branched chains in the branched chain isomeric alcohol of C23-C32 is 1-4.
5. The solubility enhancer of claim 1, further comprising an adipate; the mass ratio of the isomeric alcohol to the adipate is (90-100): (0.1-10).
6. The solubility enhancing agent of claim 5, wherein the adipate is selected from one or more of n-octanol adipate, n-heptanol n-octanol adipate, isodecanol adipate, and isododecanol adipate.
7. The solubility enhancer according to claim 5, wherein the mass ratio of the isomeric alcohol to the adipate is (98 to 100): (0.1-2).
8. A method of preparing a solubility enhancing agent, comprising:
the isomeric alcohol is heated and stirred evenly to obtain the solubility reinforcing agent.
9. The method according to claim 8, wherein an adipate is further added; the heating temperature is 70-120 ℃.
10. A lubricating oil comprising the solubility enhancing agent as set forth in any one of claims 1 to 7.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111255578.8A CN113897233A (en) | 2021-10-27 | 2021-10-27 | Solubility enhancer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111255578.8A CN113897233A (en) | 2021-10-27 | 2021-10-27 | Solubility enhancer and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113897233A true CN113897233A (en) | 2022-01-07 |
Family
ID=79027143
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111255578.8A Pending CN113897233A (en) | 2021-10-27 | 2021-10-27 | Solubility enhancer and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113897233A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020243515A1 (en) * | 2019-05-30 | 2020-12-03 | Fluitec International | Solvency enhancer compositions, methods of preparation and methods of use thereof |
-
2021
- 2021-10-27 CN CN202111255578.8A patent/CN113897233A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020243515A1 (en) * | 2019-05-30 | 2020-12-03 | Fluitec International | Solvency enhancer compositions, methods of preparation and methods of use thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101812349B (en) | Lubricating oil and grease base oil, and preparation method and applications thereof | |
| PL203138B1 (en) | Use of 2,4-di-tert.-butylhydroxytoluene for increasing the storage stability of bio-diesel | |
| CN109576063A (en) | A kind of method of one-step synthesis method Low sulfur diesel antiwear additive | |
| CN111205911B (en) | Long-life synthetic high-temperature chain oil and preparation method thereof | |
| CN101994251B (en) | Emulsion type oil solution for terylene industrial yarns | |
| CN113897233A (en) | Solubility enhancer and preparation method thereof | |
| CN110776877A (en) | Water-based energy exchange medium containing hydroxylated graphene and preparation method thereof | |
| WO2024088104A1 (en) | Long carbon chain polyamide composition, and preparation method therefor and use thereof | |
| CN110950756B (en) | Durable antioxidant and anti-coking synthetic ester for high-temperature chain oil and preparation method thereof | |
| CN106381189B (en) | The lube base oil of synthesizing ester compound based on gallic acid and its application | |
| CN111892976A (en) | Anti-corrosion synthetic aviation lubricating oil and production method thereof | |
| CN108795538B (en) | Fluoro-polyester type detergent, preparation method and lubricating oil composition prepared from fluoro-polyester type detergent | |
| CN101812357A (en) | Compressor concentrated amendment | |
| CN112410097A (en) | Preparation and application of high-wear-resistance antifriction molybdenum-containing lubricating oil additive | |
| CN110055124A (en) | A kind of clean type drawing fluid composition and preparation method thereof | |
| CN1364861A (en) | Composite additive for quenching oil | |
| CN104817594A (en) | Molybdenum containing borate derivative, preparation method and application thereof | |
| CN112521999A (en) | Lubricating oil metal deactivator mixture and preparation method thereof | |
| CN112239600B (en) | High-end amino stable polyamide composition containing copper compound and preparation method and application thereof | |
| CN106479611A (en) | A kind of high temperature grease and preparation method thereof | |
| CN115247090A (en) | Ultrahigh-base-number magnesium alkylbenzene sulfonate detergent and preparation method thereof | |
| CN111592864A (en) | High-boiling-point cooling liquid | |
| CN109536246A (en) | A kind of economize on electricity of efficient antifriction is easily dispersed bobbin oil and preparation method thereof | |
| CN109097174A (en) | A kind of water glycol nonflammable hydraulic fluid and preparation method thereof | |
| CN109022105B (en) | Water-soluble fluorocarbon graphene engine oil and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220107 |