CN113866101A - Method and device for detecting sulfur content in diesel oil and electronic equipment - Google Patents

Method and device for detecting sulfur content in diesel oil and electronic equipment Download PDF

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Publication number
CN113866101A
CN113866101A CN202110956943.1A CN202110956943A CN113866101A CN 113866101 A CN113866101 A CN 113866101A CN 202110956943 A CN202110956943 A CN 202110956943A CN 113866101 A CN113866101 A CN 113866101A
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sulfur content
diesel
current
diesel oil
detecting
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刘军
冯海娣
杜长刚
孙启航
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Weichai Power Co Ltd
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Weichai Power Co Ltd
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/26Oils; Viscous liquids; Paints; Inks
    • G01N33/28Oils, i.e. hydrocarbon liquids
    • G01N33/2835Specific substances contained in the oils or fuels
    • G01N33/287Sulfur content

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  • General Health & Medical Sciences (AREA)
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  • Oil, Petroleum & Natural Gas (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
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  • Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)

Abstract

The invention relates to a method and a device for detecting sulfur content in diesel oil and electronic equipment, belonging to the technical field of sulfur content detection, wherein the detection method comprises the following steps: acquiring current parameters of diesel oil; obtaining the current sulfur content of the diesel according to the current parameters of the diesel; comparing the current sulfur content of the diesel with a sulfur content threshold value; and sending an alarm instruction according to the condition that the current sulfur content of the diesel is more than or equal to the sulfur content threshold value. The method has the effects of solving the problems that the detection period for measuring the sulfur content in the diesel oil is long, the process is complicated, and the method is not suitable for detecting the sulfur content on line or quickly.

Description

Method and device for detecting sulfur content in diesel oil and electronic equipment
Technical Field
The invention relates to the technical field of sulfur content detection, in particular to a method and a device for detecting sulfur content in diesel oil and electronic equipment.
Background
This section provides background information related to the present disclosure only and is not necessarily prior art.
The sulfur content in diesel oil is high, and sulfide in tail gas generated by combustion can poison a post-treatment catalyst, so that the emission exceeds the standard. Active sulfur can directly corrode metal, and no matter active sulfide or inactive sulfide, sulfur dioxide and sulfur trioxide generated after combustion meet water and water vapor generated by combustion, sulfurous acid and sulfuric acid can be formed at high temperature, and engine parts are seriously corroded. In addition, the acid substances can cause the total base number of the engine oil to be reduced quickly, and the oil change period is greatly shortened. Based on the problems, it is necessary to research an online rapid detection method for sulfur content in diesel oil and develop a corresponding control strategy to protect the engine.
At present, sulfur content in diesel oil is measured off-line, main measuring methods comprise an X-ray fluorescence method, a near infrared spectroscopy method and the like, but the methods are common laboratory chemical methods, and the methods are complex, have long detection period and are not suitable for on-line or rapid detection of sulfur content.
Disclosure of Invention
The invention aims to at least solve the problems that the detection period of the sulfur content measurement in the diesel oil is long, the process is complicated, and the method is not suitable for on-line or rapid detection of the sulfur content. The purpose is realized by the following technical scheme:
the invention provides a method for detecting the content of sulfur in diesel oil, which comprises the following steps:
acquiring current parameters of diesel oil;
obtaining the current sulfur content of the diesel according to the current parameters of the diesel;
comparing the current sulfur content of the diesel with a sulfur content threshold value;
and sending an alarm instruction according to the condition that the current sulfur content of the diesel is more than or equal to the sulfur content threshold value.
According to the method for detecting the sulfur content in the diesel oil, the concentration of the current sulfur content in the diesel oil is judged by comparing the current sulfur content of the diesel oil with the sulfur content threshold value, the method is simple and convenient, the current sulfur content of the diesel oil can be rapidly identified, and the problems that the detection period of the measurement of the current sulfur content of the diesel oil is long, the process is complicated, and the method is not suitable for online or rapid detection of the sulfur content are solved.
In addition, the method for detecting the sulfur content in the diesel oil can also have the following additional technical characteristics:
in some embodiments of the invention, the current parameter is a current chromaticity value of diesel.
In some embodiments of the present invention, the step of obtaining the current sulfur content of the diesel oil according to the current parameters of the diesel oil comprises:
calling a relation curve of chromatic value-sulfur content;
corresponding the current chromaticity value of the diesel to a chromaticity value-sulfur content relation curve;
obtaining the theoretical sulfur content corresponding to the current chromatic value of the diesel in a chromatic value-sulfur content relation curve;
the theoretical sulfur content is set as the current sulfur content of the diesel.
In some embodiments of the present invention, after the step of issuing an alarm command according to the sulfur content of diesel oil being greater than or equal to the sulfur content threshold value, the method further includes:
recording the current refueling position;
matching the refueling position with the current sulfur content of the diesel to form single sulfur content distribution data;
and forming a regional diesel oil sulfur content distribution diagram or a regional diesel oil sulfur content distribution table according to the multiple sulfur content distribution data.
In some embodiments of the invention, in the step of comparing the current sulfur content of the diesel fuel with the threshold sulfur content, the threshold sulfur content is 100 ppm.
The second aspect of the present invention provides a device for detecting a sulfur content in diesel oil, where the device for detecting a sulfur content in diesel oil is used to implement the method of the first aspect of the present invention, and the device for detecting a sulfur content in diesel oil includes:
the acquisition module is used for acquiring the current parameters of the diesel oil;
and the control module is electrically connected with the acquisition module, is used for acquiring the current sulfur content of the diesel according to the current parameters of the diesel, is used for comparing the current sulfur content of the diesel with a sulfur content threshold value, and is used for sending an alarm instruction according to the condition that the current sulfur content of the diesel is more than or equal to the sulfur content threshold value.
In some embodiments of the present invention, the device for detecting sulfur content in diesel further includes: and the alarm module is electrically connected with the control module and used for receiving the alarm instruction and sending alarm information.
In some embodiments of the invention, the acquisition module is a colorimetric sensor;
and or the alarm module is a buzzer and/or a warning light.
Another aspect of the invention provides an electronic device comprising at least one processor; and a memory communicatively coupled to the at least one processor; wherein the memory stores instructions for execution by the at least one processor; the instructions are executable by the at least one processor to enable the at least one processor to perform the detection method set forth in the first aspect of the invention.
In some embodiments of the invention, the computer storage medium stores a computer program for executing the detection method set forth in the first aspect of the invention.
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Various other advantages and benefits will become apparent to those of ordinary skill in the art upon reading the following detailed description of the preferred embodiments. The drawings are only for purposes of illustrating the preferred embodiments and are not to be construed as limiting the invention. Also, like parts are designated by like reference numerals throughout the drawings. In the drawings:
FIG. 1 is a schematic flow chart of a method for detecting sulfur content in diesel fuel according to the present application;
FIG. 2 is a graph showing a relationship between a colorimetric value and a sulfur content in the detection method of the present application;
FIG. 3 is a schematic flow chart illustrating the logic of the intelligent diagnosis in the detection method of the present application;
fig. 4 is a schematic structural diagram of a chromaticity detection apparatus and a mounting position of a controller according to the present application.
Reference numerals:
1. an oil tank; 2. a filling port; 3. a colorimetric sensor; 4. an engine; 5. a processor; 6. a wire harness.
Detailed Description
Exemplary embodiments of the present disclosure will be described in more detail below with reference to the accompanying drawings. While exemplary embodiments of the present disclosure are shown in the drawings, it should be understood that the present disclosure may be embodied in various forms and should not be limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the disclosure to those skilled in the art.
It is to be understood that the terminology used herein is for the purpose of describing particular example embodiments only, and is not intended to be limiting. As used herein, the singular forms "a", "an" and "the" may be intended to include the plural forms as well, unless the context clearly indicates otherwise. The terms "comprises," "comprising," "including," and "having" are inclusive and therefore specify the presence of stated features, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, steps, operations, elements, components, and/or groups thereof. The method steps, processes, and operations described herein are not to be construed as necessarily requiring their performance in the particular order described or illustrated, unless specifically identified as an order of performance. It should also be understood that additional or alternative steps may be used.
Although the terms first, second, third, etc. may be used herein to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers and/or sections should not be limited by these terms. These terms may be only used to distinguish one element, component, region, layer or section from another region, layer or section. Terms such as "first," "second," and other numerical terms when used herein do not imply a sequence or order unless clearly indicated by the context. Thus, a first element, component, region, layer or section discussed below could be termed a second element, component, region, layer or section without departing from the teachings of the example embodiments.
For convenience of description, spatially relative terms, such as "inner", "outer", "lower", "below", "upper", "above", and the like, may be used herein to describe one element or feature's relationship to another element or feature as illustrated in the figures. Such spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. For example, if the device in the figures is turned over, elements described as "below" or "beneath" other elements or features would then be oriented "above" or "over" the other elements or features. Thus, the example term "below … …" can include both an orientation of above and below. The device may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein interpreted accordingly.
As shown in fig. 1 to 3, according to an embodiment of the present invention, a method for detecting sulfur content in diesel oil is provided, the method includes the following steps:
acquiring current parameters of diesel oil;
obtaining the current sulfur content of the diesel according to the current parameters of the diesel;
comparing the current sulfur content of the diesel with a sulfur content threshold value;
and sending an alarm instruction according to the condition that the current sulfur content of the diesel is more than or equal to the sulfur content threshold value.
According to the method for detecting the sulfur content in the diesel oil, the concentration of the current sulfur content in the diesel oil is judged by comparing the current sulfur content in the diesel oil with the sulfur content threshold value. The method is simple and convenient, can quickly identify the current sulfur content of the diesel oil, and solves the problems that the detection period of the current sulfur content measurement of the diesel oil is long, the process is complicated, and the method is not suitable for online or quick detection of the sulfur content. In the detection process, when the current sulfur content of the diesel oil is larger than or equal to the set sulfur content threshold value, an alarm instruction that the current sulfur content of the diesel oil exceeds the standard is sent out, so that a user is informed to stop filling the diesel oil, parts of the engine are protected from being corroded, the loss of the engine is reduced, and the user cost is saved.
In some embodiments of the invention, the current parameter is a current chromaticity value of diesel.
In some embodiments of the present invention, the step of obtaining the current sulfur content of the diesel fuel according to the current parameters of the diesel fuel comprises calling a chromaticity value-sulfur content relation curve; corresponding the current chromaticity value of the diesel to a chromaticity value-sulfur content relation curve; obtaining the theoretical sulfur content corresponding to the current chromatic value of the diesel in a chromatic value-sulfur content relation curve; the theoretical sulfur content is set as the current sulfur content of the diesel.
Specifically, colorimetric values of diesel oil with different sulfur contents are measured by using a colorimeter, actual values of the diesel oil with different sulfur contents are detected by using ultraviolet fluorescence, relation curves of the different colorimetric values and the sulfur contents are obtained, and a corresponding rule is fitted. When a user refuels, the current chromaticity value of the diesel is corresponded to the chromaticity value-sulfur content relation curve by obtaining the current chromaticity value of the diesel and utilizing the chromaticity value-sulfur content relation curve, and the unique theoretical sulfur content corresponding to the current chromaticity value of the diesel in the chromaticity value-sulfur content relation curve is identified. The obtained unique theoretical sulfur content is set as the current sulfur content of the diesel oil, and the unique theoretical sulfur content is compared with a preset sulfur content threshold value, so that whether the current sulfur content of the diesel oil exceeds the standard or not can be judged. The method is simple and convenient, and can quickly identify the current sulfur content of the diesel oil.
The ultraviolet fluorescence method is used as a method based on a chemiluminescence technology, and under appropriate experimental conditions, the ultraviolet fluorescence method for determining the sulfur content in the oil product has high precision, accuracy and recovery rate, and samples with different sulfur contents can be measured by establishing different curves.
In some embodiments of the present invention, after the step of issuing the alarm command according to the sulfur content of the diesel oil being greater than or equal to the sulfur content threshold value, the method further includes: recording the current refueling position; matching the refueling position with the current sulfur content of the diesel to form single sulfur content distribution data; and forming a regional diesel oil sulfur content distribution diagram or a regional diesel oil sulfur content distribution table according to the multiple sulfur content distribution data.
Specifically, when the current sulfur content concentration of diesel oil is judged to exceed the standard, OBD (On Board Diagnostics, which is a detection system extending for automobile fault diagnosis) diagnoses, and reminds a user filling the diesel oil by sending an alarm instruction, and simultaneously records the actual oil filling position of the current user, so that data support can be provided for subsequent analysis problems. The actual refueling position of the user at each time corresponds to the current sulfur content of the diesel at the actual refueling position, the refueling habit of the user is determined, meanwhile, a regional diesel sulfur content distribution graph or a regional diesel sulfur content distribution table is formed according to the data of the actual refueling positions and the current sulfur content of the diesel for many times, and the distribution levels of the sulfur content in different regions can be roughly determined. It should be noted that the actual fueling position of the current user is recorded, including but not limited to GPS positioning and/or beidou satellite positioning.
In some embodiments of the invention, in the step of comparing the current sulfur content of the diesel fuel to the threshold sulfur content, the threshold sulfur content is 100 ppm. It should be noted that ppm (parts per million) is a concentration expressed by mass of solute in parts per million of the total solution mass, and is also referred to as parts per million concentration. Specifically, by setting a sulfur content threshold, when the current sulfur content of the diesel is less than 100ppm, the user normally operates; and when the sulfur content is more than or equal to 100ppm, judging that the current sulfur content of the diesel exceeds the standard, and sending an alarm instruction to remind a user who is filling the diesel to stop filling. By setting a specific sulfur content threshold value, the detection of the sulfur content in the diesel oil is more accurate, and the service life of the engine can be prolonged.
The second aspect of the present invention provides a device for detecting sulfur content in diesel oil, wherein the device for detecting sulfur content in diesel oil is used for implementing the detection method of the first aspect of the present invention, and the device for detecting sulfur content in diesel oil comprises:
the acquisition module is used for acquiring the current parameters of the diesel oil;
and the control module is electrically connected with the acquisition module, is used for acquiring the current sulfur content of the diesel according to the current parameters of the diesel, is used for comparing the current sulfur content of the diesel with a sulfur content threshold value, and sends an alarm instruction according to the condition that the current sulfur content of the diesel is more than or equal to the sulfur content threshold value.
Specifically, the acquisition module acquires current parameters of the diesel oil, feeds the acquired data back to the control module, and the control module compares the current sulfur content of the diesel oil with a sulfur content threshold value to obtain the only theoretical sulfur content and judges the current sulfur content of the diesel oil. When the current sulfur content of the diesel is judged to be more than or equal to the set sulfur content threshold value, an alarm instruction that the current sulfur content of the diesel exceeds the standard is sent out to inform a user to stop the filling of the diesel, so that the real-time monitoring of the current sulfur content of the diesel is realized, and the defects of long off-line detection period and complicated process are avoided.
In some embodiments of the present invention, the apparatus for detecting sulfur content in diesel further comprises: and the alarm module is electrically connected with the control module and is used for receiving the alarm instruction and sending out alarm information.
Further, in some embodiments of the present invention, the acquisition module is a colorimetric sensor 3; and or the alarm module is a buzzer and/or a warning lamp.
Specifically, the colorimetric sensor 3 can detect a current colorimetric value of the diesel oil, convert the detected current colorimetric value of the diesel oil into an electrical signal, and transmit the electrical signal to the control module. The alarm module is electrically connected with the control module, and when the current sulfur content of the diesel oil is judged to be more than or equal to the set sulfur content threshold value, an alarm instruction is sent out through the buzzer and/or the warning lamp to inform a user to stop filling the diesel oil. The buzzer and/or the warning lamp are/is arranged, the sound and visual warning effects are considered, a user can be reminded of filling the current sulfur content detection result of the diesel oil in time, the real-time monitoring on the current sulfur content of the diesel oil is realized, the loss of the engine 4 is reduced, and the user cost is saved.
It should be understood that the colorimetric sensor 3, also called a color recognition sensor or a color sensor, is a sensor that compares the color of an object to be detected with a reference color that has been already taught to detect the color, and outputs a detection result when the two colors match within a certain error range.
Another aspect of the invention proposes an electronic device comprising at least one processor 5; and a memory communicatively coupled to the at least one processor 5; wherein the memory stores instructions for execution by the at least one processor 5; the instructions are executable by the at least one processor 5 to enable the at least one processor 5 to perform the detection method set forth in the first aspect of the invention.
Further, in some embodiments of the present invention, a computer storage medium stores a computer program for executing the detection method set forth in the first aspect of the present invention.
Specifically, the processor 5 is an ECU (Electronic control unit), an Electronic control unit (also called "traveling computer", "on-board computer", etc.), and is a microcomputer controller dedicated for automobiles. A colorimetric sensor 3 is provided at the filler port 2 of the fuel tank 1, and the colorimetric sensor 3 is electrically connected to the ECU through a wire harness 6. The ECU is internally provided with a memory, the memory stores instructions, and the processor 5 executes the instructions to realize the method for detecting the sulfur content in the diesel oil according to the first aspect of the invention. In this embodiment, the electronic device has all the technical effects of the method for detecting sulfur content in diesel oil, and is not described herein again.
Those skilled in the art will appreciate that all or part of the steps in the method according to the above embodiments may be implemented by a computer program, and the computer program is stored in a memory and includes several instructions to make a processor (which may be a single chip, a chip, etc.) or a processor execute all or part of the steps in the method according to the embodiments of the present application. And the aforementioned memories include, but are not limited to: a U-disk, a removable hard disk, a Read-only Memory (ROM), a Random Access Memory (RAM), a magnetic disk or an optical disk, and other various media capable of storing program codes.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any changes or substitutions that can be easily conceived by those skilled in the art within the technical scope of the present invention are included in the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the claims.

Claims (10)

1. A method for detecting the content of sulfur in diesel oil is characterized by comprising the following steps:
acquiring current parameters of diesel oil;
obtaining the current sulfur content of the diesel according to the current parameters of the diesel;
comparing the current sulfur content of the diesel with a sulfur content threshold value;
and sending an alarm instruction according to the condition that the current sulfur content of the diesel is more than or equal to the sulfur content threshold value.
2. The method for detecting the sulfur content in the diesel oil according to claim 1, wherein the current parameter is a current colorimetric value of the diesel oil.
3. The method for detecting the sulfur content in the diesel oil according to claim 2, wherein the step of obtaining the current sulfur content of the diesel oil according to the current parameters of the diesel oil comprises:
calling a relation curve of chromatic value-sulfur content;
corresponding the current chromaticity value of the diesel to a chromaticity value-sulfur content relation curve;
obtaining the theoretical sulfur content corresponding to the current chromatic value of the diesel in a chromatic value-sulfur content relation curve;
the theoretical sulfur content is set as the current sulfur content of the diesel.
4. The method for detecting the sulfur content in the diesel oil according to claim 1, wherein after the step of issuing an alarm command according to the sulfur content of the diesel oil being greater than or equal to the threshold value of the sulfur content, the method further comprises:
recording the current refueling position;
matching the refueling position with the current sulfur content of the diesel to form single sulfur content distribution data;
and forming a regional diesel oil sulfur content distribution diagram or a regional diesel oil sulfur content distribution table according to the multiple sulfur content distribution data.
5. The method for detecting sulfur content in diesel fuel according to claim 1, wherein in the step of comparing the current sulfur content of diesel fuel with the sulfur content threshold value, the sulfur content threshold value is 100 ppm.
6. A device for detecting the sulfur content in diesel oil, wherein the device for detecting the sulfur content in diesel oil is used for implementing the method for detecting the sulfur content in diesel oil according to any one of claims 1 to 5, and the device for detecting the sulfur content in diesel oil comprises:
the acquisition module is used for acquiring the current parameters of the diesel oil;
and the control module is electrically connected with the acquisition module, is used for acquiring the current sulfur content of the diesel according to the current parameters of the diesel, is used for comparing the current sulfur content of the diesel with a sulfur content threshold value, and is used for sending an alarm instruction according to the condition that the current sulfur content of the diesel is more than or equal to the sulfur content threshold value.
7. The device for detecting the sulfur content in the diesel oil according to claim 6, wherein the device for detecting the sulfur content in the diesel oil further comprises: and the alarm module is electrically connected with the control module and used for receiving the alarm instruction and sending alarm information.
8. The device for detecting the sulfur content in the diesel oil according to claim 7, wherein the acquisition module is a colorimetric sensor;
and or the alarm module is a buzzer and/or a warning light.
9. An electronic device comprising at least one processor; and a memory communicatively coupled to the at least one processor; wherein the memory stores instructions for execution by the at least one processor; the instructions are executable by the at least one processor to enable the at least one processor to perform the method of any one of claims 1-5.
10. A computer storage medium, characterized in that the computer storage medium stores a computer program for performing the method according to any one of claims 1-5.
CN202110956943.1A 2021-08-19 2021-08-19 Method and device for detecting sulfur content in diesel oil and electronic equipment Pending CN113866101A (en)

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CN114689824A (en) * 2022-03-25 2022-07-01 潍柴动力股份有限公司 On-line detection method and detection device for sulfur content of automobile oil

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