CN113860702B - A multi-field coupled sewage sludge automatic dehydration method - Google Patents
A multi-field coupled sewage sludge automatic dehydration method Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/15—Treatment of sludge; Devices therefor by de-watering, drying or thickening by treatment with electric, magnetic or electromagnetic fields; by treatment with ultrasonic waves
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/14—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
- C02F11/143—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents using inorganic substances
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/14—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
- C02F11/143—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents using inorganic substances
- C02F11/145—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents using inorganic substances using calcium compounds
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Abstract
Description
技术领域Technical field
本发明涉及污水污泥处理领域,具体地说是一种通过多场耦合(超声波场、微波场、 电场、机械应力场)协同耦合作用实现更低含水率的污水污泥脱水方法。The present invention relates to the field of sewage sludge treatment, specifically a sewage sludge dehydration method that achieves lower moisture content through the synergistic coupling effect of multi-field coupling (ultrasonic field, microwave field, electric field, mechanical stress field).
背景技术Background technique
随着我国城镇污水处理设施建设规模的不断扩大,污水处理过程中产生的污泥量急剧增加。截止到2019年底,我国污泥(含水率以80%计)年产量已超过4000万吨,预计2020年将达到6000-8000万吨。很显然,污泥高含水率是制约着污泥处理处置的瓶颈,含水率高的污泥不仅体积庞大,而且所含的大量有机质、重金属和有害微生物也容易腐化或释放到环境中,引起二次污染,对于污泥后续的填埋、焚烧、资源化利用等都造成不利的影响。因此,污泥深度脱水减量化是污泥处理首要目的,是实现污泥“四化”的基础,污泥越干,后续处理处置越有利。With the continuous expansion of the construction scale of urban sewage treatment facilities in my country, the amount of sludge produced during sewage treatment has increased dramatically. As of the end of 2019, my country's annual sludge (moisture content is calculated as 80%) production has exceeded 40 million tons, and it is expected to reach 60-80 million tons in 2020. Obviously, the high moisture content of sludge is a bottleneck restricting sludge treatment and disposal. Sludge with high moisture content is not only bulky, but also contains a large amount of organic matter, heavy metals and harmful microorganisms that are easily corrupted or released into the environment, causing secondary problems. Secondary pollution will have adverse effects on subsequent landfilling, incineration, and resource utilization of sludge. Therefore, deep dehydration and reduction of sludge is the primary purpose of sludge treatment and the basis for realizing the "four modernizations" of sludge. The drier the sludge, the more beneficial it is for subsequent treatment and disposal.
污泥中含有大量由嵌入生物聚合物中的微生物(主要是细菌)组成的絮凝物。其特殊结 构构成含有胶体的高度多孔的分形网状结构,颗粒表现得更像凝胶状材料而不是传统的颗粒悬浮液,该结构使得其难脱水。同时Vesilind、Vesilind和Hsu[Smith和Vesilind]分别对污泥中水分的存在形态进行了定义,Vesilind将污泥中的水分分成四种类型:间隙水又称自由水(free water)、毛细结合水(interstitial water)、表面吸附水(surface orvicinal water)、 内部水(bound or hydration water),而单一机械应力场脱水只能有效脱除污泥中的自由水,但难以从其孔隙中脱除毛细及吸附水,有很大的局限性,大大限制了污泥处理的脱水率。Sludge contains large amounts of flocs composed of microorganisms (mainly bacteria) embedded in biopolymers. Its special structure forms a highly porous fractal network containing colloids. The particles behave more like a gel-like material than a traditional particle suspension. This structure makes it difficult to dehydrate. At the same time, Vesilind, Vesilind and Hsu [Smith and Vesilind] respectively defined the existence form of water in sludge. Vesilind divided the water in sludge into four types: interstitial water, also known as free water, and capillary bound water. (interstitial water), surface adsorbed water (surface orvicinal water), and internal water (bound or hydration water). However, single mechanical stress field dehydration can only effectively remove free water in sludge, but it is difficult to remove capillary water from its pores. and adsorbed water, which has great limitations, greatly limiting the dehydration rate of sludge treatment.
现有污泥深度脱水技术(真空脱水、连续式带滤脱水),物理脱水虽然适用于各种混合污泥的脱水,但是脱水率不高,最终可得到固体含量为19%的脱水污泥饼。这也是单一场脱水方式的局限性,无法去除孔隙中的吸附水。Existing sludge deep dehydration technology (vacuum dehydration, continuous belt filter dehydration) and physical dehydration are suitable for dehydration of various mixed sludges, but the dehydration rate is not high. Finally, a dewatered sludge cake with a solid content of 19% can be obtained. . This is also a limitation of the single-field dehydration method, which cannot remove the adsorbed water in the pores.
本发明的思路基于力场对污泥脱水的作用,在力场的基础上增加了超声波场、电场和微波场,通过多场耦合的方法来增加其脱水率。同时,在装置的结构上,设置进料系统(油缸,电磁阀)实现自动进料的目的,设置卸料系统(双铰式叉型油缸液压升降台、丝杠除泥推进器)实现自动卸料的目的,以提高装置的自动化水平和效率。The idea of the present invention is based on the effect of force field on sludge dehydration. On the basis of force field, ultrasonic field, electric field and microwave field are added, and the dehydration rate is increased through multi-field coupling method. At the same time, in the structure of the device, a feeding system (cylinder, solenoid valve) is set up to achieve the purpose of automatic feeding, and an unloading system (double-hinge fork-type oil cylinder hydraulic lifting platform, screw screw desilting propeller) is set up to achieve automatic unloading. The purpose of the material is to improve the automation level and efficiency of the device.
首先附加电场后,污泥颗粒带负电,而水分子带正电,在电场力作用下,带负电的污 泥颗粒往阳极板运动,而带正电水分子往阴极板运动。在电化学反应作用下,电解水定向 强力移动,细胞内的温度上升、压力增大使得细胞膜破裂,胞内水流出。因此且固体颗粒不易堵塞过滤介质,以此增大了脱水率。First, after applying an electric field, the sludge particles are negatively charged, while the water molecules are positively charged. Under the action of the electric field force, the negatively charged sludge particles move toward the anode plate, while the positively charged water molecules move toward the cathode plate. Under the action of the electrochemical reaction, the electrolyzed water moves strongly in a direction, and the temperature and pressure inside the cell increase, causing the cell membrane to rupture and the intracellular water to flow out. Therefore, solid particles are less likely to block the filter media, thereby increasing the dehydration rate.
继而通过附加微波场,受磁场的作用,当有极分子电介质和无极分子电介质置于微波电磁场中时,介质材料中会形成偶极子或已有的偶极子重新排列,并随着高频交变电磁场 以每秒高达数亿次的速度摆动,分子要随着不断变化的高频电场的方向重新排列,就必须克服分子原有的热运动和分子相互间作用的干扰和阻碍,产生类似于摩擦的作用,这个过程就会使得分子运动大大加剧,同时电磁场能量逐渐转化成新的热能,使介质温度出现大幅度的提升,即熵增大,体系混乱程度变大,子热运动加快,以此增大脱水率。Then, through the addition of microwave fields and the influence of magnetic fields, when polar molecular dielectrics and non-polar molecular dielectrics are placed in microwave electromagnetic fields, dipoles will be formed or existing dipoles will be rearranged in the dielectric material, and with the high frequency The alternating electromagnetic field swings at a speed of hundreds of millions of times per second. To rearrange the molecules with the direction of the ever-changing high-frequency electric field, it is necessary to overcome the interference and obstruction of the original thermal motion of the molecules and the interaction between molecules, resulting in something like Due to the effect of friction, this process will greatly intensify the molecular motion. At the same time, the electromagnetic field energy is gradually converted into new thermal energy, causing the medium temperature to increase significantly, that is, the entropy increases, the degree of system chaos becomes greater, and the thermal motion of the particles accelerates. This increases the dehydration rate.
与此同时,滤布孔隙中嵌入大量污泥,堵塞的出水孔,大大减小了出水的效率,但通过超声波场的超高评率震荡,清理了滤布上的大量污泥,近一步增大了效率,同时超声波场也有利于卸料时对滤布的清洗。At the same time, a large amount of sludge is embedded in the pores of the filter cloth, and the clogged water outlet holes greatly reduce the water outlet efficiency. However, through the ultra-high efficiency vibration of the ultrasonic field, a large amount of sludge on the filter cloth is cleaned, further increasing the efficiency of the water outlet. The efficiency is increased, and the ultrasonic field is also beneficial to cleaning the filter cloth during discharge.
然而,多场耦合脱水技术目前主要还存在着以下问题:(1)电渗透过程中,阳极附近污泥的含水率快速降低,而且电化学反应气体的产生及污泥泥饼中出现裂缝,污泥泥饼与电极板之间的接触面积减小,导致污泥电阻增大,电流下降,脱水效果变差;(2)脱水过程中,电场和微波场使电能转换成热能,使污泥温度升高,实际上存在着能耗偏大问题;(3)泥饼在厚度方向上的含水率分布不均,阳极层污泥含水率较低,水分子积聚在 阴极层而导致阴极板附近污泥含水率较高;(4)脱水过程中,多场同时附加在污泥腔室之中,易发生实验危险。However, the multi-field coupling dehydration technology currently still has the following main problems: (1) During the electroosmosis process, the moisture content of the sludge near the anode decreases rapidly, and the generation of electrochemical reaction gases and cracks in the sludge cake cause the sewage to sludge. The contact area between the mud cake and the electrode plate decreases, causing the sludge resistance to increase, the current to decrease, and the dehydration effect to deteriorate; (2) During the dehydration process, the electric field and microwave field convert electrical energy into thermal energy, which increases the temperature of the sludge. Increase, in fact, there is a problem of excessive energy consumption; (3) The moisture content of the mud cake is unevenly distributed in the thickness direction, the moisture content of the sludge in the anode layer is low, and water molecules accumulate in the cathode layer, causing pollution near the cathode plate. The moisture content of the mud is high; (4) During the dehydration process, multiple fields are attached to the sludge chamber at the same time, which is prone to experimental risks.
因此本发明在多场耦合脱水的同时,增加了实时监测的检测系统,通过传感器以及计算机集成,实时监测液压油缸所输出的推力,油缸推阳极板所产生的最终压力,压强、污泥分层的温度、泥饼厚度。Therefore, the present invention adds a real-time monitoring detection system while coupling dehydration with multiple fields. Through sensor and computer integration, the thrust output by the hydraulic cylinder, the final pressure generated by the cylinder pushing the anode plate, pressure, and sludge stratification are monitored in real time. temperature, mud cake thickness.
发明内容Contents of the invention
本发明要解决的技术问题是,提供一种脱水效果好的多场耦合(超声波场、微波场、电场、机械应力场)污水污泥自动化脱水方法。The technical problem to be solved by the present invention is to provide a multi-field coupling (ultrasonic field, microwave field, electric field, mechanical stress field) sewage sludge automatic dehydration method with good dehydration effect.
本发明的技术解决方案是,提供一种以下多场耦合污水污泥自动化脱水方法方法,包括以下步骤:The technical solution of the present invention is to provide the following multi-field coupling sewage sludge automatic dehydration method, which includes the following steps:
污水污泥在多场耦合脱水前进行添加调理剂及初步脱水,调理后的污泥储存于储泥腔室,开启电磁阀后,启动油缸,使污泥自动压入污泥处理腔室,所述的阳极板在全自动液压系统的驱动下,向阴极板移动,并在达到一定压力时,保持阳极板和阴极板之间的压力;采用直流电源对所述阳极板和阴极板供电,并且采用微波驱动电源对微波磁控管供电,并且采用超声波驱动电源对超声波控制器供电,根据检测系统所检测的污泥温度、污泥厚度和机械压力值,通过计算机计算出多场耦合需要输出功率,以精确的控制参数实现恒电压梯度、恒功率密度微波场和超声场三者的节能耦合脱水;随着耦合脱水的进行,阳极板的污泥相较于阴极板含水率低,污泥干化,此时停止多场耦合脱水;并加大阳极板和阴极板之间的压力,进行高压机械压滤脱水,以进一步降低含水率,达到一定机械压力,含水率分布均匀后,保持阳极板和阴极板之间的压力;启动直流电源、微波系统和超声波系统,再一次重复进行多场耦合污泥脱水;脱水完成后,控制双铰式叉型油缸液压升降台启动,在高压焊接缸的配合下,阴极板缓缓退出污泥处理腔室,此时控制丝杆除泥推进器,在超声波场的作用下,污泥被自动处理掉,完成一个循环。The sewage sludge is added with conditioners and initially dehydrated before multi-field coupling dehydration. The conditioned sludge is stored in the sludge storage chamber. After opening the solenoid valve, the oil cylinder is started to automatically press the sludge into the sludge treatment chamber. The anode plate is driven by a fully automatic hydraulic system to move toward the cathode plate, and when a certain pressure is reached, the pressure between the anode plate and the cathode plate is maintained; a DC power supply is used to power the anode plate and the cathode plate, and A microwave driving power supply is used to power the microwave magnetron, and an ultrasonic driving power supply is used to power the ultrasonic controller. Based on the sludge temperature, sludge thickness and mechanical pressure values detected by the detection system, the output power required for multi-field coupling is calculated through a computer. , achieving energy-saving coupling dehydration of constant voltage gradient, constant power density microwave field and ultrasonic field with precise control parameters; as the coupling dehydration proceeds, the sludge on the anode plate has a lower moisture content than the cathode plate, and the sludge dries out. At this time, stop the multi-field coupling dehydration; and increase the pressure between the anode plate and the cathode plate, and perform high-pressure mechanical press filtration and dehydration to further reduce the moisture content. After reaching a certain mechanical pressure, the moisture content is evenly distributed, and the anode plate is maintained. and the pressure between the cathode plate; start the DC power supply, microwave system and ultrasonic system, and repeat the multi-field coupling sludge dehydration; after the dehydration is completed, control the double-hinge fork-type oil cylinder hydraulic lifting platform to start, and the high-pressure welding cylinder With the cooperation, the cathode plate slowly exits the sludge treatment chamber. At this time, the screw desludge propeller is controlled. Under the action of the ultrasonic field, the sludge is automatically processed, completing a cycle.
可选的,污水污泥在多场耦合脱水前添加调理剂及初步脱水,所添加的调理剂为Fe2(SO4)3、FeCl3、CaO及粉煤灰复合调理剂,调理剂总添加量为污泥干物质质量的 10-20%,Fe2(SO4)3、FeCl3、CaO及粉煤灰四种调理剂质量百分比分别为5-10%,10-15%、 20-30%、30-45%,四种调理剂作用分别为提高污泥电位、增大污泥絮体结构、增强微波加热作用效果、产生排水通道等综合作用,以增强机械压力、电渗透、微波及超声波多场耦合作用效果,在添加调理剂后对污泥进行初步脱水至含水率75%~80%。Optionally, the sewage sludge is added with a conditioning agent and preliminary dehydration before multi-field coupling dehydration. The conditioning agent added is Fe 2 (SO 4 ) 3 , FeCl 3 , CaO and fly ash composite conditioning agent. The total conditioning agent added is The amount is 10-20% of the dry matter mass of the sludge, and the mass percentages of the four conditioners Fe 2 (SO 4 ) 3 , FeCl 3 , CaO and fly ash are 5-10%, 10-15% and 20-30 respectively. %, 30-45%. The functions of the four conditioners are to increase the sludge potential, increase the sludge floc structure, enhance the microwave heating effect, and create drainage channels to enhance mechanical pressure, electroosmosis, microwave and Due to the multi-field coupling effect of ultrasonic waves, the sludge is initially dehydrated to a moisture content of 75% to 80% after adding a conditioner.
可选的,所述的微波系统包括微波磁控管、微波散热风机、微波驱动电源、电磁波导、特氟龙传导螺丝,由微波磁控管产生微波,微波散热风机保持运作,以降低微波磁控管的温度,在耦合脱水的过程中,通过调节微波驱动电源来控制微波场的强度;产生的微波通过圆柱形的电磁波导传导微波,所述电磁波导安置于阴极板下方,阴极板中间置有特氟龙传导螺丝。Optionally, the microwave system includes a microwave magnetron, a microwave cooling fan, a microwave driving power supply, an electromagnetic waveguide, and a Teflon conductive screw. The microwave magnetron generates microwaves, and the microwave cooling fan keeps operating to reduce the microwave magnetism. The temperature of the tube is controlled. During the coupling dehydration process, the intensity of the microwave field is controlled by adjusting the microwave drive power supply; the generated microwave conducts the microwave through the cylindrical electromagnetic waveguide, which is placed below the cathode plate with the cathode plate in the middle. There are Teflon conductive screws.
可选的,所述超声波系统包括超声波振子、超声波控制器、超声波驱动电源在耦合脱水的过程中,超声波驱动电源对所述超声波振子供电,通过调节超声波控制器来控制超声波的强度,超声波振子贴附于阴极板上,其产生的超声波在金属中传播。Optionally, the ultrasonic system includes an ultrasonic vibrator, an ultrasonic controller, and an ultrasonic driving power supply. During the coupling dehydration process, the ultrasonic driving power supply supplies power to the ultrasonic vibrator, and the intensity of the ultrasonic wave is controlled by adjusting the ultrasonic controller. The ultrasonic vibrator is attached Attached to the cathode plate, the ultrasonic waves it generates propagate through the metal.
可选的,可调节微波系统和超声波系统的功率,以及根据污泥厚度调节直流电源的输出电压,可根据不同的进泥量、污泥种类、以及不同脱水阶段动态调节多场耦合的工作参数组合,实现恒电压梯度、恒功率密度微波场和超声场三者的耦合脱水。Optional, the power of the microwave system and ultrasonic system can be adjusted, and the output voltage of the DC power supply can be adjusted according to the sludge thickness. The working parameters of multi-field coupling can be dynamically adjusted according to different sludge input amounts, sludge types, and different dehydration stages. Combination to achieve coupling dehydration of constant voltage gradient, constant power density microwave field and ultrasonic field.
可选的,所述全自动液压系统包括PLC控制装置、液压油缸、低压直动式溢流阀和高压直动式溢流阀,所述的液压油缸的活塞端与阳极板连接,所述的低压直动式溢流阀、高压直动式溢流阀与所述的液压油缸相连通。Optionally, the fully automatic hydraulic system includes a PLC control device, a hydraulic cylinder, a low-pressure direct-acting relief valve and a high-pressure direct-acting relief valve. The piston end of the hydraulic cylinder is connected to the anode plate, and the The low-pressure direct-acting relief valve and the high-pressure direct-acting relief valve are connected with the hydraulic cylinder.
可选的,一种多场耦合污水污泥自动化脱水装置还包括检测系统,所述检测系统包括压力传感器、温度传感器和位移传感器,污泥处理腔室外侧设置有多个凹形环状槽,其内部设置有多圈缠绕式的温度传感器,液压油缸下侧设置有压力传感器,压力传感器上侧设置有拉线式的位移传感器。Optionally, a multi-field coupled sewage sludge automatic dehydration device also includes a detection system, which includes a pressure sensor, a temperature sensor and a displacement sensor. A plurality of concave annular grooves are provided outside the sludge treatment chamber. There is a multi-winding temperature sensor inside, a pressure sensor is installed on the lower side of the hydraulic cylinder, and a pull-wire displacement sensor is installed on the upper side of the pressure sensor.
可选的,所述进料系统包括油缸、储泥腔室和电磁阀,在脱水开始前,开启电磁阀后,启动油缸,污泥自动压入污泥处理腔室。Optionally, the feeding system includes an oil cylinder, a sludge storage chamber and a solenoid valve. Before dehydration starts, after opening the solenoid valve, the oil cylinder is started, and the sludge is automatically pressed into the sludge treatment chamber.
可选的,所述卸料系统包括双铰式叉型油缸液压升降台和丝杠除泥推进器,在耦合脱水结束后,由计算机控制双铰式叉型油缸液压升降台启动,在液压油缸的配合下,阴极板退出污泥处理腔室,此时控制丝杆除泥推进器,在超声波场的配合作用下清理污泥。Optionally, the unloading system includes a double-hinge fork-type oil cylinder hydraulic lifting platform and a screw desludge propeller. After the coupling dehydration is completed, the computer-controlled double-hinge fork-type oil cylinder hydraulic lifting platform is started. With the cooperation of the ultrasonic field, the cathode plate exits the sludge treatment chamber. At this time, the screw rod desludge propeller is controlled to clean the sludge under the cooperation of the ultrasonic field.
采用以上方法,本发明与现有技术相比,具有以下优点:(1)由于市政污泥的带电、胶体及高压缩性的多孔介质,脱水过程非常难,含水率高,通过机械压力应力场、电场、声场等多个场同时在原位进行处理处置,实现高干度脱水;(2)在机械压滤脱水的辅助之下,实现基于传感器检测的参数反馈的精确控制微波场、超声波场和电渗透的多场耦合,与微波、超声波以及电渗透同时作用下,水分子由阳极板往阴极板运动,随着脱水的进行,阳极层污泥变干导致电阻增大同时电流减小,使得电渗透脱水的驱动力减小,电阻变大;此时在微波场的作用下,受电磁场的作用,水分子随着高频交变电磁场以每秒高达数亿次的速度摆动,不断变化并重新排列,部分水分能回流到阳极层,降低污泥电阻,增大电流,使得污泥厚度方向含水率分布均匀,在下一阶段脱水时需要改变电渗透电压;同时,污泥内部水对微波吸收能力很大,造成微波能损失,稍有控制不当,会产生污泥内部受热过度,出现膨胀熟化,而超声波场可以利于空化作用,大量破碎污泥内部絮体结构,增大内部水的流速,并且超声波也会在污泥内部产生热效应,由于声波振子直接贴附于阴极板上,其产生的超声波可在金属中传播,由此可以来补偿微波加热的不均匀,达到提升脱水效果的 目的,使得污泥含水率较为均匀;(3)在污泥脱水过程中,经过试验表明,单位面积的污泥所能吸收的微波和超声波能量有限,所加电场在恒电压梯度时效果最好最节能。所以通过传感器实时采集污泥厚度、污泥温度、机械压力参数用计算机处理后通过计算的控制参数来控制微波、超声波、直流电的输出功率大小,实现在最节能的条件下完成恒功率密 度、恒电压梯度脱水目标。Using the above method, compared with the existing technology, the present invention has the following advantages: (1) Due to the charged, colloid and highly compressible porous medium of municipal sludge, the dehydration process is very difficult and the moisture content is high. Through the mechanical pressure stress field , electric field, sound field and other fields are processed in situ at the same time to achieve high dryness dehydration; (2) With the assistance of mechanical filter press dehydration, precise control of microwave fields and ultrasonic fields based on parameter feedback detected by sensors is achieved Multi-field coupling with electro-osmosis, under the simultaneous action of microwaves, ultrasonic waves and electro-osmosis, water molecules move from the anode plate to the cathode plate. As dehydration proceeds, the sludge in the anode layer dries, causing the resistance to increase and the current to decrease. The driving force of electro-osmotic dehydration decreases and the resistance increases. At this time, under the action of the microwave field and the electromagnetic field, the water molecules swing with the high-frequency alternating electromagnetic field at a speed of hundreds of millions of times per second, constantly changing. And rearrange, part of the water can flow back to the anode layer, reduce the resistance of the sludge, increase the current, and make the moisture content in the thickness direction of the sludge evenly distributed. In the next stage of dehydration, the electroosmotic voltage needs to be changed; at the same time, the water inside the sludge is sensitive to the microwave The absorption capacity is very large, resulting in the loss of microwave energy. If the control is not properly controlled, the interior of the sludge will be overheated, causing expansion and maturation. The ultrasonic field can facilitate cavitation, break up the internal floc structure of the sludge in large quantities, and increase the internal water content. Flow rate, and ultrasonic waves will also produce thermal effects inside the sludge. Since the acoustic vibrator is directly attached to the cathode plate, the ultrasonic waves generated by it can propagate in the metal, which can compensate for uneven microwave heating and improve the dehydration effect. The purpose is to make the sludge moisture content more uniform; (3) During the sludge dehydration process, tests have shown that the microwave and ultrasonic energy absorbed by the unit area of sludge is limited, and the added electric field has the best effect at a constant voltage gradient. Most energy efficient. Therefore, the sludge thickness, sludge temperature, and mechanical pressure parameters are collected in real time by sensors and processed by a computer to control the output power of microwaves, ultrasonics, and direct current through calculated control parameters to achieve constant power density and constant power under the most energy-saving conditions. Voltage gradient dehydration target.
附图说明Description of drawings
图1为多场耦合污水脱水装置的结构示意图;Figure 1 is a schematic structural diagram of a multi-field coupling sewage dehydration device;
图中所示:1、污泥处理腔室,2、全自动液压系统,2.1、液压油缸,2.2、单向节流阀Ⅰ,2.3、单向节流阀Ⅱ,2.4、电磁换向阀Ⅰ,2.5、低压直动式溢流阀,2.6、高压直动式溢流阀,2.7、电磁换向阀Ⅱ,2.8、先导式溢流阀,2.9、液压泵,2.10、PLC控制装置,3、阳极板,4、阴极板,5、直流电源,6、出水孔,6.1、滤布,6.2、固定架,6.3、密封圈,7、 微波系统,7.1、微波磁控管,7.2、微波散热风机,7.3、微波驱动电源,7.4、电磁波导,7.5、特氟龙传导螺丝,8、检测系统,8.1、压力传感器,8.2、温度传感器,8.3、位移传感器,8.4、计算机,9、进料系统,9.1、油缸,9.2、储泥腔室,9.3、电磁阀,10、卸料系统,10.2、双铰式叉型油缸液压升降台,10.1、丝杠除泥推进器,11、超声波系统,11.1、超声波振子,11.2、超声波控制器,11.3、超声波驱动电源。Shown in the picture: 1. Sludge treatment chamber, 2. Fully automatic hydraulic system, 2.1. Hydraulic cylinder, 2.2. One-way throttle valve I, 2.3, One-way throttle valve II, 2.4, Electromagnetic reversing valve I , 2.5. Low-pressure direct-acting relief valve, 2.6. High-pressure direct-acting relief valve, 2.7. Electromagnetic reversing valve II, 2.8. Pilot-operated relief valve, 2.9. Hydraulic pump, 2.10. PLC control device, 3. Anode plate, 4. Cathode plate, 5. DC power supply, 6. Water outlet, 6.1, filter cloth, 6.2, fixed frame, 6.3, sealing ring, 7. Microwave system, 7.1, microwave magnetron, 7.2, microwave cooling fan , 7.3. Microwave drive power supply, 7.4. Electromagnetic waveguide, 7.5. Teflon conduction screw, 8. Detection system, 8.1. Pressure sensor, 8.2. Temperature sensor, 8.3. Displacement sensor, 8.4. Computer, 9. Feeding system, 9.1. Oil cylinder, 9.2. Mud storage chamber, 9.3. Solenoid valve, 10. Unloading system, 10.2. Double-hinge fork-type oil cylinder hydraulic lifting platform, 10.1. Screw desilting propeller, 11. Ultrasonic system, 11.1. Ultrasonic vibrator, 11.2, ultrasonic controller, 11.3, ultrasonic driving power supply.
实施方式Implementation
下面结合附图和具体实施例对本发明作进一步说明。The present invention will be further described below in conjunction with the accompanying drawings and specific embodiments.
本发明涵盖任何在本发明的精髓和范围上做的替代、修改、等效方法以及方案。为了 使公众对本发明有彻底的了解,在以下本发明优选实施例中详细说明了具体的细节,而对 本领域技术人员来说没有这些细节的描述也可以完全理解本发明。此外,本发明之附图中为了示意的需要,并没有完全精确地按照实际比例绘制,在此予以说明。The present invention covers any alternatives, modifications, equivalent methods and solutions within the spirit and scope of the invention. In order to provide the public with a thorough understanding of the present invention, specific details are described in the following preferred embodiments of the present invention, and those skilled in the art can fully understand the present invention without the description of these details. In addition, for the sake of illustration, the drawings of the present invention are not drawn exactly according to the actual scale, and are explained here.
本发明的解决方案是:调理后的污泥储存于储泥腔室9.2,开启电磁阀9.3后,启动油缸9.1,使污泥自动压入污泥处理腔室1,所述的阳极板3在全自动液压系统的驱动下,向阴极板4 移动,并在达到一定压力时,保持阳极板3和阴极板4之间的压力;采用直流电源5对所述阳极板3和阴极板4供电,并且采用微波驱动电源7.3对微波磁控管7.1供电,并且采用超声波驱动电源11.3对超声波控制器11.2供电,根据检测系统8所检测的污泥温度、污泥厚度和机械压力值,通过计算机8.4计算出多场耦合需要输出功率,以精确的控制参数实现恒 电压梯度、恒功率密度微波场和超声场三者的节能耦合脱水;随着耦合脱水的进行,阳极板3的污泥相较于阴极板4含水率低,污泥干化,此时停止多场耦合脱水;并加大阳极板3和阴极板4之间的压力,进行高压机械压滤脱水,以进一步降低含水率,达到一定机械压力,含水率分布均匀后,保持阳极板3和阴极板4之间的压力;启动直流电源5、微波系统7和超声波系统11,再一次重复进行多场耦合污泥脱水。脱水完成后,计算机8.4 控制双铰式叉型油缸液压升降台启动,在HSG高压焊接缸(作为液压油缸2.1的一种实施方式)的配合下,阴极板4缓缓退出污泥处理腔室1,此时控制丝杆除泥推进器10.1,在超声波场的作用下,污泥被自动处理掉,完成一个循环。基于机械压滤的多场耦合污水污泥脱水装置,包括污泥处理腔室1、全自动液压系统2、直流电源5、微波系统7、进料系统9、卸料系统10和超声波系统11,所述的进料系统9连通设置在污泥处理腔室1 的侧部,所述污泥处理腔室1内设有阳极板3和阴极板4,所述的阳极板3设置在污泥处理腔室1的上部,所述的阴极板4设置在污泥处理腔室1的下部,所述的直流电源5的正负极分别与阳极板3和阴极板4连接,所述的阳极板3和阴极板4上均设有出水孔6,在 所述出水孔6上敷设有滤布6.1,所述的微波系统7设置在阴极板4的下部;所述的超声波系统11设置在阴极板4的下部;所述的卸料系统10设置在阴极板4的下方;所述的阳极板3与用以驱动阳极板3运动的全自动液压系统2连接。The solution of the present invention is: the conditioned sludge is stored in the sludge storage chamber 9.2. After opening the solenoid valve 9.3, the oil cylinder 9.1 is started to automatically press the sludge into the sludge treatment chamber 1. The anode plate 3 is Driven by a fully automatic hydraulic system, it moves toward the cathode plate 4, and when a certain pressure is reached, the pressure between the anode plate 3 and the cathode plate 4 is maintained; a DC power supply 5 is used to supply power to the anode plate 3 and cathode plate 4. And the microwave drive power supply 7.3 is used to power the microwave magnetron 7.1, and the ultrasonic drive power supply 11.3 is used to power the ultrasonic controller 11.2. According to the sludge temperature, sludge thickness and mechanical pressure values detected by the detection system 8, it is calculated by the computer 8.4 Multi-field coupling requires output power, and precise control parameters are used to achieve energy-saving coupling dehydration of constant voltage gradient, constant power density microwave field and ultrasonic field; as the coupling dehydration proceeds, the sludge on the anode plate 3 is compared with the cathode The moisture content of plate 4 is low and the sludge is dried. At this time, the multi-field coupling dehydration is stopped; and the pressure between the anode plate 3 and the cathode plate 4 is increased to perform high-pressure mechanical filter dehydration to further reduce the moisture content and reach a certain mechanical After the pressure and moisture content are evenly distributed, maintain the pressure between the anode plate 3 and the cathode plate 4; start the DC power supply 5, the microwave system 7 and the ultrasonic system 11, and repeat the multi-field coupling sludge dehydration again. After the dehydration is completed, the computer 8.4 controls the double-hinge fork-type oil cylinder hydraulic lifting platform to start. With the cooperation of the HSG high-pressure welding cylinder (as an implementation mode of the hydraulic oil cylinder 2.1), the cathode plate 4 slowly exits the sludge treatment chamber 1 , at this time, the screw sludge removal propeller 10.1 is controlled. Under the action of the ultrasonic field, the sludge is automatically processed, completing a cycle. A multi-field coupling sewage sludge dehydration device based on mechanical filter press, including sludge treatment chamber 1, fully automatic hydraulic system 2, DC power supply 5, microwave system 7, feeding system 9, unloading system 10 and ultrasonic system 11, The feeding system 9 is connected to the side of the sludge treatment chamber 1. The anode plate 3 and the cathode plate 4 are provided in the sludge treatment chamber 1. The anode plate 3 is arranged in the sludge treatment chamber 1. In the upper part of the chamber 1, the cathode plate 4 is arranged in the lower part of the sludge treatment chamber 1. The positive and negative poles of the DC power supply 5 are connected to the anode plate 3 and the cathode plate 4 respectively. The anode plate 3 There are water outlets 6 on both the cathode plate and the cathode plate 4. A filter cloth 6.1 is laid on the water outlet holes 6. The microwave system 7 is arranged on the lower part of the cathode plate 4; the ultrasonic system 11 is arranged on the cathode plate 4. The lower part; the unloading system 10 is arranged below the cathode plate 4; the anode plate 3 is connected to the fully automatic hydraulic system 2 used to drive the movement of the anode plate 3.
本发明的思路基于力场对污泥脱水的作用,在力场的基础上增加了超声波场、电场和微波场,通过多场耦合的方法来增加其脱水率。同时,在装置的结构上,设置进料系统(油缸,电磁阀)实现自动进料的目的,设置卸料系统(双铰式叉型油缸液压升降台、丝杠除泥 推进器)实现自动卸料的目的,以提高装置的自动化水平和效率。The idea of the present invention is based on the effect of force field on sludge dehydration. On the basis of force field, ultrasonic field, electric field and microwave field are added, and the dehydration rate is increased through multi-field coupling method. At the same time, in the structure of the device, a feeding system (cylinder, solenoid valve) is set up to achieve the purpose of automatic feeding, and an unloading system (double-hinge fork-type oil cylinder hydraulic lifting platform, screw screw desilting propeller) is set up to achieve automatic unloading. The purpose of the material is to improve the automation level and efficiency of the device.
首先附加电场后,污泥颗粒带负电,而水分子带正电,在电场力作用下,带负电的污泥颗粒往阳极板运动,而带正电水分子往阴极板运动。在电化学反应作用下,电解水定向强力移动,细胞内的温度上升、压力增大使得细胞膜破裂,胞内水流出。因此且固体颗粒不易堵塞过滤介质,以此增大了脱水率。First, after an electric field is applied, the sludge particles are negatively charged, while the water molecules are positively charged. Under the action of the electric field force, the negatively charged sludge particles move toward the anode plate, while the positively charged water molecules move toward the cathode plate. Under the action of the electrochemical reaction, the electrolyzed water moves strongly in a direction, and the temperature and pressure inside the cell increase, causing the cell membrane to rupture and the intracellular water to flow out. Therefore, solid particles are less likely to block the filter media, thereby increasing the dehydration rate.
继而通过附加微波场、超声波场、电磁场的作用,当有极分子电介质和无极分子电介质置于微波电磁场中时,介质材料中会形成偶极子或已有的偶极子重新排列,并随着高频交变电磁场以每秒高达数亿次的速度摆动,分子要随着不断变化的高频电场的方向重新排列,就必须克服分子原有的热运动和分子相互间作用的干扰和阻碍,产生类似于摩擦的作用,这个过程就会使得分子运动大大加剧,同时电磁场能量逐渐转化成新的热能,使介质温度出现大幅度的提升,即熵增大,体系混乱程度变大,子热运动加快,同时超声波场可以利于空化作用,大量破碎污泥内部絮体结构,增大内部水的流速,并且超声波也会在污泥内部产生热效应弥补微波加热的不均匀性,以此提高脱水率。Then, through the action of additional microwave fields, ultrasonic fields, and electromagnetic fields, when polar molecular dielectrics and nonpolar molecular dielectrics are placed in microwave electromagnetic fields, dipoles will be formed or existing dipoles will be rearranged in the dielectric material, and as the The high-frequency alternating electromagnetic field swings at a speed of hundreds of millions of times per second. To rearrange the molecules in the direction of the ever-changing high-frequency electric field, it is necessary to overcome the interference and obstruction of the original thermal motion of the molecules and the interaction between molecules. Producing an effect similar to friction, this process will greatly intensify the molecular motion. At the same time, the electromagnetic field energy will gradually be converted into new thermal energy, causing the temperature of the medium to increase significantly, that is, the entropy will increase, the degree of system chaos will increase, and the sub-thermal motion will At the same time, the ultrasonic field can facilitate cavitation, break up the internal floc structure of the sludge in large quantities, increase the flow rate of internal water, and the ultrasonic waves will also produce thermal effects inside the sludge to compensate for the unevenness of microwave heating, thereby improving the dehydration rate. .
与此同时,滤布孔隙中嵌入大量污泥,堵塞的出水孔,大大减小了出水的效率,但通过超声波场的超高频率震荡,清理了滤布上的大量污泥,近一步增大了效率,同时超声波场也有利于卸料时对滤布的清洗。At the same time, a large amount of sludge is embedded in the pores of the filter cloth, and the clogged water outlet holes greatly reduce the water outlet efficiency. However, through the ultra-high frequency oscillation of the ultrasonic field, a large amount of sludge on the filter cloth is cleaned, further increasing the It improves efficiency, and the ultrasonic field is also beneficial to cleaning the filter cloth during discharge.
本发明在多场耦合脱水的同时,增加了实时监测的检测系统,通过传感器以及计算机集成,实时监测液压油缸所输出的推力,油缸推阳极板所产生的最终压力,压强、污泥分层的温度、泥饼厚度。While coupling dehydration with multiple fields, the present invention adds a real-time monitoring detection system. Through sensor and computer integration, the invention real-time monitors the thrust output by the hydraulic cylinder, the final pressure generated by the cylinder pushing the anode plate, the pressure, and the sludge stratification. Temperature, mud cake thickness.
如图1所示,示意了本发明的多场耦合污水污泥脱水装置。As shown in Figure 1, the multi-field coupling sewage sludge dehydration device of the present invention is schematically illustrated.
当待处理的污水污泥的含水率较高时,则在进入本发明处理之前,需要进行预处理,预处理的具体实施可以采用现有技术实现。所述的预处理是指通过机械压滤脱水,将污泥含水率降至75%~80%,加入复合调理剂(Fe2(SO4)3+FeCl3+CaO)以提高本发明的污水污泥处理效率。在机械压滤之前Fe2(SO4)3+FeCl3+CaO+粉煤灰复合调理剂,其中微波调理后的活性污泥(干基)热值随着微波辐射时间的增长逐渐降低,FeCl3的加入能够达到活性污泥絮体的增大以及EPS的减少的效果,提高活性污泥热值,微波耦合FeCl3调理进一步 增强了活性污泥的脱水性能;同时FeCl3在与超声波耦合过程中污泥比阻,VSS/SS,滤饼含水率以及滤液浊度分别降低到0.29×109s2/g,0.580,82.09%和31.22NTU,提高恒功率密度下超声波作用效率;电渗透过程,有机物从阴极向阳极迁移。加入Fe2(SO4)3后,有机物迁移量增加,阴极泥饼pH变大而阳极泥饼pH变小,阴、阳两极泥饼pH梯度增加,电渗透过程中,原泥的Zeta电位主要受泥饼pH的影响;而调理泥Zeta电位主要受离子强度的影响,Fe2(SO4)3中离子的加入会增加污泥电导率,CaO及粉煤灰则能够增加污泥内部孔道结构,利于内部自由水流出,所以调理剂的加入能够在一定程度上提高电渗透脱水的速率。When the moisture content of the sewage sludge to be treated is high, pretreatment needs to be performed before entering the treatment of the present invention. The specific implementation of the pretreatment can be implemented using existing technology. The pretreatment refers to reducing the sludge moisture content to 75% to 80% through mechanical filter press dehydration, and adding a compound conditioner (Fe 2 (SO 4 ) 3 + FeCl 3 + CaO) to improve the sewage quality of the present invention. Sludge treatment efficiency. Before mechanical press filtration, Fe 2 (SO 4 ) 3 +FeCl 3 +CaO+fly ash composite conditioner, in which the calorific value of activated sludge (dry basis) after microwave conditioning gradually decreases with the increase of microwave radiation time, FeCl 3 The addition of activated sludge floc can increase the activated sludge floc and reduce EPS, and increase the calorific value of activated sludge. Microwave coupling FeCl 3 conditioning further enhances the dehydration performance of activated sludge; at the same time, FeCl 3 is in the process of coupling with ultrasonic waves. The sludge specific resistance, VSS/SS, filter cake moisture content and filtrate turbidity were reduced to 0.29×109s 2 /g, 0.580, 82.09% and 31.22NTU respectively, improving the ultrasonic efficiency under constant power density; during the electroosmosis process, organic matter was removed from The cathode migrates towards the anode. After adding Fe 2 (SO 4 ) 3 , the migration amount of organic matter increases, the pH of the cathode mud cake becomes larger and the pH of the anode mud cake becomes smaller, and the pH gradient of the cathode and anode mud cakes increases. During the electroosmosis process, the Zeta potential of the original mud is mainly Affected by the pH of the mud cake; the Zeta potential of the conditioning mud is mainly affected by the ionic strength. The addition of ions in Fe 2 (SO 4 ) 3 will increase the conductivity of the sludge, while CaO and fly ash can increase the internal pore structure of the sludge. , which is conducive to the free flow of water inside, so the addition of conditioner can increase the rate of electroosmotic dehydration to a certain extent.
污泥储存于储泥腔室9.2,开启电磁阀9.3后,启动油缸9.1,使污泥自动压入污泥处理腔室1,所述的阳极板3在全自动液压系统的驱动下,向阴极板4移动,并在达到一定压力时,保持阳极板3和阴极板4之间的压力;采用直流电源5对所述阳极板3和阴极板4供电,并且采用微波驱动电源7.3对微波磁控管7.1供电,并且采用超声波驱动电源11.3对超声波控制器11.2供电,根据检测系统8所检测的污泥温度、污泥厚度和机械压力值,通过计算机8.4计算出多场耦合需要输出功率,以精确的控制参数实现恒电压、恒功率密度微波场和超声场的耦合脱水;随着耦合脱水的进行,阳极板3的污泥相较于阴极板4含水率低,污泥干化,此时停止多场耦合脱水;并加大阳极板3和阴极板4之间的压力,进行高压机械压滤脱水,以进一步降低含水率,达到一定机械压力,含水率分布均匀后,保持阳极板3和阴极板4之间的压力;启动直流电源5、微波系统7和超声波系统11,再一次重复进行多场耦合污泥脱水。脱水完成后,计算机8.4控制双铰式叉型油缸液压升降台启动,在HSG 高压焊接缸(作为液压油缸2.1的一种实施方式)的配合下,阴极板4缓缓退出污泥处理腔室1,此时控制丝杆除泥推进器10.1,在超声波场的作用下,污泥被自动处理掉,完成一个循环。The sludge is stored in the sludge storage chamber 9.2. After opening the solenoid valve 9.3, the oil cylinder 9.1 is started to automatically press the sludge into the sludge treatment chamber 1. The anode plate 3 is driven by the fully automatic hydraulic system and moves toward the cathode. The plate 4 moves, and when a certain pressure is reached, the pressure between the anode plate 3 and the cathode plate 4 is maintained; a DC power supply 5 is used to power the anode plate 3 and the cathode plate 4, and a microwave driving power supply 7.3 is used to power the microwave magnetron The pipe 7.1 is powered, and the ultrasonic drive power supply 11.3 is used to power the ultrasonic controller 11.2. According to the sludge temperature, sludge thickness and mechanical pressure values detected by the detection system 8, the output power required for multi-field coupling is calculated through the computer 8.4 to accurately The control parameters realize the coupling dehydration of constant voltage, constant power density microwave field and ultrasonic field; as the coupling dehydration proceeds, the sludge on the anode plate 3 has a lower moisture content than the cathode plate 4, and the sludge dries, and stops at this time Multi-field coupling dehydration; and increase the pressure between the anode plate 3 and the cathode plate 4, perform high-pressure mechanical filter dehydration to further reduce the moisture content, reach a certain mechanical pressure, and after the moisture content is evenly distributed, the anode plate 3 and the cathode are maintained The pressure between the plates 4; start the DC power supply 5, the microwave system 7 and the ultrasonic system 11, and repeat the multi-field coupling sludge dehydration again. After the dehydration is completed, the computer 8.4 controls the double-hinge fork-type oil cylinder hydraulic lifting platform to start. With the cooperation of the HSG high-pressure welding cylinder (as an implementation mode of the hydraulic oil cylinder 2.1), the cathode plate 4 slowly exits the sludge treatment chamber 1 , at this time, the screw sludge removal propeller 10.1 is controlled. Under the action of the ultrasonic field, the sludge is automatically processed, completing a cycle.
所述液压系统包括PLC控制装置2.10、液压油缸2.1、低压直动式溢流阀2.5、高压直动式溢流阀2.6,所述的液压油缸2.1的活塞端与阳极板3连接,所述的低压直动式溢流阀2.5、高压直动式溢流阀2.6与所述的液压油缸2.1相连通。由于在不同脱水阶段压力不同,因此通过PLC控制装置来调节液压油缸2.1施加于阳极板3的压力。The hydraulic system includes a PLC control device 2.10, a hydraulic cylinder 2.1, a low-pressure direct-acting relief valve 2.5, and a high-pressure direct-acting relief valve 2.6. The piston end of the hydraulic cylinder 2.1 is connected to the anode plate 3. The low-pressure direct-acting relief valve 2.5 and the high-pressure direct-acting relief valve 2.6 are connected with the hydraulic cylinder 2.1. Since the pressure is different in different dehydration stages, the pressure applied to the anode plate 3 by the hydraulic cylinder 2.1 is adjusted through the PLC control device.
所述微波系统包括微波磁控管7.1、微波散热风机7.2、微波驱动电源7.3、电磁波导 7.4、特氟龙传导螺丝7.5,在耦合脱水的过程中,可以通过调节驱动电源来控制微波场的强度。同时由微波磁控管7.1产生微波,微波散热风机7.2保持运作,降低微波磁控管7.1的温度。产生的微波通过圆柱形电磁波导7.4传导微波,所述电磁波导7.4安置于阴极板4下方,阴极板中间置有特氟龙传导螺丝7.5,特氟龙是良好的微波传导材料,可以在隔离污泥出水的同时传导微波。The microwave system includes a microwave magnetron 7.1, a microwave cooling fan 7.2, a microwave driving power supply 7.3, an electromagnetic waveguide 7.4, and a Teflon conductive screw 7.5. During the coupling dehydration process, the intensity of the microwave field can be controlled by adjusting the driving power supply. . At the same time, the microwave magnetron 7.1 generates microwaves, and the microwave cooling fan 7.2 keeps operating to reduce the temperature of the microwave magnetron 7.1. The generated microwave conducts the microwave through the cylindrical electromagnetic waveguide 7.4, which is placed below the cathode plate 4. A Teflon conductive screw 7.5 is placed in the middle of the cathode plate. Teflon is a good microwave conductive material and can be used to isolate pollution. The mud conducts microwaves as it releases water.
所述超声波系统包括超声波振子11.1、超声波控制器11.2、超声波驱动电源11.3,在耦合脱水的过程中,可以通过调节超声波控制器11.2来控制超声波的强度。同时超声波振子11.1直接贴附于阴极板上,其产生的超声波可在金属中传播,以此起到清理滤布的作用。The ultrasonic system includes an ultrasonic vibrator 11.1, an ultrasonic controller 11.2, and an ultrasonic driving power supply 11.3. During the coupling dehydration process, the intensity of the ultrasonic wave can be controlled by adjusting the ultrasonic controller 11.2. At the same time, the ultrasonic vibrator 11.1 is directly attached to the cathode plate, and the ultrasonic waves generated by it can propagate in the metal, thereby cleaning the filter cloth.
所述卸料系统包括双铰式叉型油缸液压升降台10.2、丝杠除泥推进器10.1,在耦合脱水结束后,计算机8.4控制双铰式叉型油缸液压升降台10.2启动,在液压油缸2.1 的配合下,阴极板4缓缓退出污泥处理腔室,此时控制丝杆除泥推进器10.1,在超声波场的配合作用下,清理污泥,完成一个循环。The unloading system includes a double-hinge fork-type oil cylinder hydraulic lifting platform 10.2 and a screw desludge propeller 10.1. After the coupling dehydration is completed, the computer 8.4 controls the double-hinge fork-type oil cylinder hydraulic lifting platform 10.2 to start. In the hydraulic oil cylinder 2.1 With the cooperation of the ultrasonic field, the cathode plate 4 slowly exits the sludge treatment chamber. At this time, the screw desludge propeller 10.1 is controlled to clean the sludge under the cooperation of the ultrasonic field, completing a cycle.
所述进料系统包括油缸9.1、储泥腔室9.2、电磁阀9.3,在耦合脱水开始前,可以开启电磁阀9.3后,启动油缸9.1,使污泥自动压入污泥处理腔室1。The feeding system includes an oil cylinder 9.1, a mud storage chamber 9.2, and a solenoid valve 9.3. Before the coupling dehydration starts, the solenoid valve 9.3 can be opened and the oil cylinder 9.1 can be started to automatically press the sludge into the sludge treatment chamber 1.
所述的污泥处理腔室1外侧设置有多个凹形环状槽,其内部设置有多圈缠绕式温度传感器8.2,此传感器贴近污泥,灵敏度高,连接计算机后可以实时监测污泥各层温度。There are multiple concave annular grooves on the outside of the sludge treatment chamber 1, and a multi-winding temperature sensor 8.2 is provided inside. This sensor is close to the sludge and has high sensitivity. After being connected to a computer, it can monitor the sludge in real time. layer temperature.
所述的液压油缸2.1下侧设置有压力传感器8.1,此传感器直接接触与污泥阳极板,相对于液压站输出的推力,能更加直观反映压力场大小,灵敏度高,连接计算机后可以实时监测压力大小,并且通过P=F/S计算可能压强大小。A pressure sensor 8.1 is provided on the lower side of the hydraulic cylinder 2.1. This sensor is in direct contact with the sludge anode plate. Compared with the thrust output by the hydraulic station, it can more intuitively reflect the size of the pressure field and has high sensitivity. After being connected to a computer, the pressure can be monitored in real time. size, and calculate the possible pressure through P=F/S.
所述的压力传感器8.1上侧设置有拉线式位移传感器8.3,此传感器能更加直观反映油缸推出距离,灵敏度高,连接计算机后可以实时监测位移大小,并且通过D(泥饼厚度)=H(污泥厚度)-S(位移)来计算泥饼厚度。The pressure sensor 8.1 is provided with a pull-wire displacement sensor 8.3 on the upper side. This sensor can reflect the pushing distance of the oil cylinder more intuitively and has high sensitivity. After being connected to a computer, the displacement can be monitored in real time, and through D (mud cake thickness) = H (contamination Mud thickness)-S (displacement) to calculate the thickness of the mud cake.
所述的污水污泥脱水装置采用交替变压式脱水模式,在所述高压机械压滤脱水后,两 极板间含水率由不均匀变得均匀,则再次进行多场耦合脱水,如此往复循环直至达到预期 污泥含水率要求。由于采用了交替变压式脱水模式,使得阳极板污泥被重新补水,由开始的干污泥变为湿污泥,又可重新恢复到电渗透和机械压滤耦合脱水阶段,此时高低压调节 装置切换到低压,与电渗透共同脱水。The sewage sludge dehydration device adopts an alternating variable pressure dehydration mode. After the high-pressure mechanical filter press dehydration, the moisture content between the two polar plates changes from uneven to uniform, and then multi-field coupling dehydration is performed again, and so on until Meet the expected sludge moisture content requirements. Due to the adoption of the alternating voltage transformer dehydration mode, the anode plate sludge is rehydrated, changing from dry sludge to wet sludge, and then back to the coupling dehydration stage of electroosmosis and mechanical filtration. At this time, high and low pressure The regulating device is switched to low pressure and dehydrated together with electroosmosis.
所述阳极板3和阴极板4与污泥处理腔室1之间分别设置有密封圈6.3,绝缘圈将阳极板3、阴极板4与污泥处理腔室1互相绝缘,阳极板3和阴极板4为耐电腐蚀材料(钛合金)制成。Seal rings 6.3 are respectively provided between the anode plate 3, the cathode plate 4 and the sludge treatment chamber 1. The insulating rings insulate the anode plate 3, the cathode plate 4 and the sludge treatment chamber 1 from each other. The anode plate 3 and the cathode are insulated from each other. Plate 4 is made of electrical corrosion-resistant material (titanium alloy).
所述阳极板3和液压油缸2.1之间采用螺纹连接,可通过PLC控制程序控制油缸的运动,以此来控制阳极板的位置,使得整个装置实现自动退出的机械化操作,大大减少了人工手动 退出的负担,提高装置的自动化水平和效率。The anode plate 3 and the hydraulic cylinder 2.1 are connected by threads, and the movement of the cylinder can be controlled by the PLC control program to control the position of the anode plate, so that the entire device can realize the mechanized operation of automatic withdrawal, greatly reducing the need for manual withdrawal. burden and improve the automation level and efficiency of the device.
所述整个装置外侧增加铝质外壳以及微波检测仪,实时监测空气中微波的泄露浓度, 保证实验的安全。An aluminum shell and a microwave detector are added to the outside of the entire device to monitor the leakage concentration of microwaves in the air in real time to ensure the safety of the experiment.
所述的阴极板4下侧设置有微波系统7,超声波系统11,卸料系统10。其中微波系统7通过特制电磁波导7.4传导至阴极板下侧,微波系统11通过导线连接置于阴极板下侧的微波振子11.1,卸料系统10中,由于双铰式叉型油缸液压升降台10.2受力,其放置于阴极板正下方。滤布6.1在卸料过程中可借助微波系统7和超声波系统10清理滤布表面污泥。A microwave system 7, an ultrasonic system 11, and an unloading system 10 are provided on the lower side of the cathode plate 4. The microwave system 7 is transmitted to the lower side of the cathode plate through a special electromagnetic waveguide 7.4. The microwave system 11 is connected to the microwave vibrator 11.1 placed on the lower side of the cathode plate through a wire. In the unloading system 10, due to the double-hinge fork-type oil cylinder hydraulic lifting platform 10.2 It is placed directly under the cathode plate under force. During the unloading process of the filter cloth 6.1, the microwave system 7 and the ultrasonic system 10 can be used to clean the sludge on the surface of the filter cloth.
所述的污泥处理腔室1也可以采用矩形柱体,污泥处理腔室1的形状并不影响本发明的实施。The sludge treatment chamber 1 may also be a rectangular cylinder, and the shape of the sludge treatment chamber 1 does not affect the implementation of the present invention.
所述的液压系统包括液压实时控制系统以及高低压调节装置。液压实时控制系统是液压系统的一部分,考虑到油缸在工作时受到的外界影响因素,工作状态常常会不稳定。因此,本文设计了液压实时控制系统用于在油缸压滤状态未达标时通过调节液压站的输出压力。本文所设计的液压实时控制系统是基于单片机为核心的嵌入式开发控制系统通过接受 油缸下侧压力传感器的信号对步进电机进行控制。高低压调节装置是液压系统的另一部 分,虽然有很多方式可以实现其功能,但本实施例仍列举了一个详细的较佳的实施例,即所述的高低压调节装置包括单向节流阀Ⅰ2.2、单向节流阀Ⅱ2.3、电磁换向阀Ⅰ2.4、电磁换向阀Ⅱ2.5、低压直动式溢流阀2.6、高压直动式溢流阀2.7、先导式溢流阀2.8及液压泵2.9,所述的单向节流阀Ⅰ2.2、单向节流阀Ⅱ2.3分别与液压油缸2.1的进出油口及电磁换向阀Ⅰ2.4连接,所述的先导式溢流阀2.8与电磁换向阀Ⅰ2.4及电磁换向阀Ⅱ2.7连接,所述的电磁换向阀Ⅱ2.7与低压直动式溢流阀2.5、高压直动式溢流阀2.6连接,所述的低压直动式溢流阀2.5、高压直动式溢流阀2.6通过电磁换向阀Ⅱ2.7用于调节液压泵2.9出口压力,进而调节污泥压榨压力在低压时污泥所受压力为0.05-0.5MPa,在高压压榨时污泥所 受到的压力为3-5MPa。另外还可为高低压调节装置配置马达、油箱、吸油过滤器、冷却器、 空气过滤器、液位计、压力表等零部件。The hydraulic system includes a hydraulic real-time control system and a high and low pressure regulating device. The hydraulic real-time control system is part of the hydraulic system. Considering the external factors affecting the cylinder during operation, the working state is often unstable. Therefore, this paper designs a hydraulic real-time control system to adjust the output pressure of the hydraulic station when the oil cylinder filter pressure state does not meet the standard. The hydraulic real-time control system designed in this article is based on an embedded development control system with a single-chip microcomputer as the core. It controls the stepper motor by receiving signals from the pressure sensor on the lower side of the oil cylinder. The high and low pressure regulating device is another part of the hydraulic system. Although there are many ways to achieve its function, this embodiment still lists a detailed preferred embodiment, that is, the high and low pressure regulating device includes a one-way throttle valve. I2.2, one-way throttle valve II2.3, electromagnetic reversing valve I2.4, electromagnetic reversing valve II2.5, low-pressure direct-acting relief valve 2.6, high-pressure direct-acting relief valve 2.7, pilot-operated overflow valve The flow valve 2.8 and the hydraulic pump 2.9, the one-way throttle valve I2.2 and the one-way throttle valve II2.3 are respectively connected with the inlet and outlet of the hydraulic cylinder 2.1 and the electromagnetic reversing valve I2.4. The pilot relief valve 2.8 is connected with the electromagnetic reversing valve I2.4 and the electromagnetic reversing valve II2.7. The electromagnetic reversing valve II2.7 is connected with the low-pressure direct-acting relief valve 2.5 and the high-pressure direct-acting relief valve. The valve 2.6 is connected. The low-pressure direct-acting relief valve 2.5 and the high-pressure direct-acting relief valve 2.6 are used to adjust the outlet pressure of the hydraulic pump 2.9 through the electromagnetic reversing valve II 2.7, thereby adjusting the sludge pressing pressure at low pressure. The pressure on the sludge is 0.05-0.5MPa, and the pressure on the sludge during high-pressure pressing is 3-5MPa. In addition, the high and low pressure regulating devices can be equipped with motors, oil tanks, oil suction filters, coolers, air filters, liquid level gauges, pressure gauges and other components.
由此可见,本发明可采用以下阶段工作:It can be seen that the present invention can adopt the following stages of work:
①预处理脱水及自动进料阶段:污水污泥进入预处理脱水装置,在预处理脱水装置内受到挤压实现初步机械压滤脱水,将污泥含水率降至75%-80%;该脱水阶段中,能够较大程度地实现污水污泥减量化,在该阶段中,采用中低压的机械压滤,其压力一般为0.1-0.5MPa;该阶段为含水率较高的污水污泥进入本发明装置之前的预处理脱水阶段,但对于含水率低于80%的污泥加入Fe2(SO4)3+FeCl3+CaO复合调理剂,对污泥进行调理改善机械压滤、以及机械保压阶段电渗透、微波、超声波三场耦合脱水特性,调理后的污泥直 接进入本发明的储泥装置进行脱水;① Pretreatment dehydration and automatic feeding stage: sewage sludge enters the pretreatment dehydration device and is squeezed in the pretreatment dehydration device to achieve preliminary mechanical filter press dehydration, reducing the sludge moisture content to 75%-80%; this dehydration In this stage, the reduction of sewage sludge can be achieved to a great extent. In this stage, medium and low pressure mechanical filter press is used, and the pressure is generally 0.1-0.5MPa; in this stage, the sewage sludge with higher moisture content enters. In the pretreatment and dehydration stage before the device of the present invention, Fe 2 (SO 4 ) 3 +FeCl 3 +CaO composite conditioner is added to the sludge with a moisture content lower than 80% to condition the sludge to improve mechanical filter press and mechanical The three-field coupling dehydration characteristics of electroosmosis, microwave, and ultrasonic waves in the pressure-holding stage allow the conditioned sludge to directly enter the mud storage device of the present invention for dehydration;
②多场耦合(超声波场、超声波场、微波场、电场、机械场)脱水阶段:经步骤①处理后,污水污泥储存于储泥腔室,开启电磁阀以及油缸后,污泥自动压入污泥处理腔室,进行初步机械压滤脱水,达到一定压力后,保持对阳极板和阴极板之间的机械压力,以使两极板与污泥接触良好。直流电源正负极分别与阳极板及阴极板电连接,根据污泥处理量大小(泥饼厚度)来确定电源电压,设置电压梯度为10-30V/cm。多场耦合的阳极板和阴极板设置于污泥处理腔室内,采用直流电源对阳极板和阴极板供电,采用微波驱动电源对微波磁控管供电,开启超声波系统;这一步骤处理后污泥含水率可达到50%-60%。在步骤②中,其机械压滤的压力为可变范围,随着压滤的进行,阳极板和阴极板之间的污泥量减少,需要 进一步加压,该阶段中的压力为0.05-0.5MPa。② Multi-field coupling (ultrasonic field, ultrasonic field, microwave field, electric field, mechanical field) dehydration stage: After step ①, the sewage sludge is stored in the mud storage chamber. After opening the solenoid valve and the oil cylinder, the sludge is automatically pressed in In the sludge treatment chamber, preliminary mechanical pressure filtration and dehydration are performed. After reaching a certain pressure, the mechanical pressure between the anode plate and the cathode plate is maintained to ensure good contact between the two plates and the sludge. The positive and negative poles of the DC power supply are electrically connected to the anode plate and cathode plate respectively. The power supply voltage is determined according to the sludge treatment volume (mud cake thickness), and the voltage gradient is set to 10-30V/cm. The multi-field coupled anode plate and cathode plate are placed in the sludge treatment chamber. A DC power supply is used to power the anode plate and cathode plate. A microwave driving power supply is used to power the microwave magnetron and the ultrasonic system is turned on. After this step, the sludge is treated The moisture content can reach 50%-60%. In step ②, the pressure of the mechanical filter press is in a variable range. As the filter press proceeds, the amount of sludge between the anode plate and the cathode plate decreases, requiring further pressurization. The pressure in this stage is 0.05-0.5 MPa.
在脱水过程中,电渗透和机械压滤所流出的水分经敷设于阳极板和阴极板上的滤布并 透过出水孔流出。所述的滤布(其材料不限于传统布,所有能够实现过滤的材料均可认为 是滤布),包裹阴极板的滤布为不锈钢材料制成,有利于提高电渗透脱水效果。During the dehydration process, the water flowing out from electroosmosis and mechanical pressure filtration passes through the filter cloth laid on the anode plate and cathode plate and flows out through the water outlet hole. The filter cloth (the material of which is not limited to traditional cloth, all materials capable of filtering can be considered as filter cloth) and the filter cloth wrapping the cathode plate are made of stainless steel, which is beneficial to improving the electroosmotic dehydration effect.
③多场耦合(超声波场、超声波场、微波场)压滤脱水及卸料阶段:经步骤②处理后,阳极板的污泥含水率低,污泥干化,此时断开多场耦合脱水,并加大阳极板和阴极板之间的压力,实现高压机械压滤脱水,污泥水分往阴极板及阳极板双向流动,使得两极板间含水率均匀。该脱水阶段为高压脱水,提供给污泥的压力为3-5MPa。③ Multi-field coupling (ultrasonic field, ultrasonic field, microwave field) filter press dehydration and discharge stage: After step ②, the sludge moisture content of the anode plate is low and the sludge is dry. At this time, the multi-field coupling dehydration is disconnected , and increase the pressure between the anode plate and the cathode plate to achieve high-pressure mechanical filter dehydration. The sludge moisture flows in both directions to the cathode plate and the anode plate, making the moisture content between the two plates even. This dehydration stage is high-pressure dehydration, and the pressure provided to the sludge is 3-5MPa.
脱水完成后,计算机控制双铰式叉型油缸液压升降台启动,在HSG高压焊接缸的配合下,阴极板缓缓退出污泥处理腔室,此时控制丝杆除泥推进器,在超声波场的配合作用下,清理污泥,完成一个循环。After the dehydration is completed, the computer controls the hydraulic lifting platform of the double-hinge fork-type oil cylinder to start. With the cooperation of the HSG high-pressure welding cylinder, the cathode plate slowly exits the sludge treatment chamber. At this time, the screw desludge propeller is controlled to operate in the ultrasonic field. With the cooperation of , the sludge is cleaned and a cycle is completed.
以上仅就本发明较佳的实施例作了说明,但不能理解为是对权利要求的限制。本发明 不仅局限于以上实施例,其具体结构允许有变化。总之,凡在本发明独立权利要求的保护 范围内所作的各种变化均在本发明的保护范围内。The above only describes the preferred embodiments of the present invention, but should not be understood as limiting the claims. The present invention is not limited to the above embodiments, and its specific structure is allowed to be changed. In short, all changes made within the protection scope of the independent claims of the present invention are within the protection scope of the present invention.
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CN113860702A (en) | 2021-12-31 |
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