CN113832709A - Antistatic fiber and preparation method thereof - Google Patents
Antistatic fiber and preparation method thereof Download PDFInfo
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- CN113832709A CN113832709A CN202111147409.2A CN202111147409A CN113832709A CN 113832709 A CN113832709 A CN 113832709A CN 202111147409 A CN202111147409 A CN 202111147409A CN 113832709 A CN113832709 A CN 113832709A
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- antistatic
- fiber
- terylene
- antioxidant
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- 239000000835 fiber Substances 0.000 title claims abstract description 96
- 238000002360 preparation method Methods 0.000 title description 9
- 229920004933 Terylene® Polymers 0.000 claims abstract description 38
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 38
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 34
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 34
- 239000002216 antistatic agent Substances 0.000 claims abstract description 33
- 229920000728 polyester Polymers 0.000 claims abstract description 33
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 32
- 239000003054 catalyst Substances 0.000 claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 32
- 239000000853 adhesive Substances 0.000 claims abstract description 31
- 230000001070 adhesive effect Effects 0.000 claims abstract description 31
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 28
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 28
- 239000002994 raw material Substances 0.000 claims abstract description 28
- 238000001035 drying Methods 0.000 claims abstract description 27
- 239000011259 mixed solution Substances 0.000 claims abstract description 22
- 238000002156 mixing Methods 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims abstract description 12
- 239000012535 impurity Substances 0.000 claims abstract description 6
- 238000012216 screening Methods 0.000 claims abstract description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 20
- 238000009941 weaving Methods 0.000 claims description 20
- 239000011701 zinc Substances 0.000 claims description 20
- 229910052725 zinc Inorganic materials 0.000 claims description 20
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 10
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 7
- -1 ethoxylated aliphatic alkylamine Chemical class 0.000 claims description 6
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 5
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 5
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 238000007493 shaping process Methods 0.000 claims description 5
- 229920001897 terpolymer Polymers 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 7
- 239000012990 dithiocarbamate Substances 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 230000005611 electricity Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 239000012209 synthetic fiber Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/372—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing etherified or esterified hydroxy groups ; Polyethers of low molecular weight
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/425—Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/09—Cellulose ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Woven Fabrics (AREA)
Abstract
The invention discloses an antistatic fiber, which comprises 60-75 parts of terylene, 25-35 parts of graphene, 10-20 parts of polyester fiber, 20-35 parts of silver powder, 6-18 parts of catalyst, 170 parts of compatilizer 140, 3-6 parts of adhesive, 5-9 parts of anti-aging agent, 15-25 parts of antistatic agent and 8-15 parts of antioxidant. Screening terylene, graphene, polyester fiber and silver powder, and removing impurities; simultaneously putting the terylene, the graphene, the polyester fiber and the silver powder into mixing equipment for stirring, uniformly mixing the raw materials and standing for 2-3 h; stirring the catalyst, the compatilizer, the adhesive, the anti-aging agent, the antistatic agent and the antioxidant uniformly, putting the raw materials after standing and the catalyst, the compatilizer, the adhesive, the anti-aging agent, the antistatic agent and the antioxidant which are stirred uniformly into a reaction kettle for reaction, wherein the reverse time is 2.5 hours, and the reaction temperature is 230-240 ℃ to obtain a mixed solution; and (3) putting the obtained mixed solution into a drying box for drying treatment for 1.5-2.5 h to obtain the antistatic terylene.
Description
Technical Field
The invention relates to the technical field of textile processing, in particular to an antistatic fiber and a preparation method thereof.
Background
Antistatic fiber: the antistatic fiber is a synthetic fiber capable of reducing or eliminating static electricity generated in the use process, and the volume specific resistance is usually 107-108 omega cm. The conductive fiber is a functional fiber that eliminates static electricity by electron conduction and corona discharge, and is generally a fiber having a volume specific resistance of 107 Ω · cm or less in a standard state (20 ℃, relative humidity 65%). At present, because common synthetic fiber products are easy to generate static electricity due to friction and induction in production, processing and use, the generated electric charge is not easy to dissipate, and the wearing comfort and the working safety are influenced, therefore, an antistatic fiber and a preparation method thereof are provided for solving the problems.
Disclosure of Invention
The invention aims to provide an antistatic fiber and a preparation method thereof, which aim to solve the problems in the background technology.
In order to solve the technical problems, the invention adopts the following technical scheme: the antistatic fiber comprises the following raw materials in parts by weight: 60-75 parts of terylene, 25-35 parts of graphene, 10-20 parts of polyester fiber, 20-35 parts of silver powder, 6-18 parts of catalyst, 170 parts of compatilizer 140, 3-6 parts of adhesive, 5-9 parts of anti-aging agent, 15-25 parts of antistatic agent and 8-15 parts of antioxidant.
Preferably, 65 parts of terylene, 28 parts of graphene, 13 parts of polyester fiber, 22 parts of silver powder, 8 parts of catalyst, 150 parts of compatilizer, 4 parts of adhesive, 7 parts of anti-aging agent, 17 parts of antistatic agent and 9 parts of antioxidant.
Preferably, the polyester comprises 70 parts of terylene, 31 parts of graphene, 16 parts of polyester fiber, 28 parts of silver powder, 12 parts of catalyst, 155 parts of compatilizer, 5 parts of adhesive, 6 parts of anti-aging agent, 20 parts of antistatic agent and 11 parts of antioxidant.
Preferably, the modified polyester comprises 72 parts of terylene, 35 parts of graphene, 19 parts of polyester fiber, 30 parts of silver powder, 15 parts of catalyst, 142 parts of compatilizer, 3 parts of adhesive, 9 parts of anti-aging agent, 19 parts of antistatic agent and 13 parts of antioxidant.
Preferably, the catalyst is one of manganese dioxide or iron oxide, and the compatilizer is one of acrylonitrile or styrene and maleic anhydride terpolymer.
Preferably, the binder is one of polyvinyl alcohol or carboxymethyl cellulose, and the anti-aging agent is one of zinc dialkyl dithiophosphate or zinc dialkyl dithiocarbamate.
Preferably, the antistatic agent is one of an ethoxylated aliphatic alkylamine or an alkyl sulfonic acid and the antioxidant is one of zinc dialkyldithiophosphate or zinc dialkyldithiocarbamate, for example.
A preparation method of antistatic fiber comprises the following steps:
s1, preparing raw materials: screening terylene, graphene, polyester fiber and silver powder, and removing impurities;
s2, mixing the raw materials: simultaneously putting the terylene, the graphene, the polyester fiber and the silver powder into mixing equipment for stirring, uniformly mixing the raw materials, and standing for 2-3 h;
s3, preparing a mixed solution: stirring the catalyst, the compatilizer, the adhesive, the anti-aging agent, the antistatic agent and the antioxidant uniformly, putting the raw materials after standing and the catalyst, the compatilizer, the adhesive, the anti-aging agent, the antistatic agent and the antioxidant which are stirred uniformly into a reaction kettle for reaction, wherein the reverse time is 2.5 hours, and the reaction temperature is 230-240 ℃ to obtain a mixed solution;
s4, drying the mixed solution; putting the obtained mixed solution into a drying box for drying treatment for 1.5-2.5 h to obtain antistatic terylene;
s5, weaving fibers: weaving the antistatic terylene by a weaving machine to obtain an antistatic fiber blank;
s6, fiber shaping: and (3) placing the antistatic fiber blank into a setting machine for setting, and obtaining the antistatic fiber finished product after setting is finished.
Preferably, in step S4, the temperature of the drying box for drying the mixed liquid is 200 ℃ to 220 ℃, and in step S5, the distance between the antistatic fibers woven by the weaving machine is 0.3 mm.
Preferably, in step S6, the setting time of the setting machine on the antistatic fiber blank is 1.5 h.
Compared with the prior art, the invention has the beneficial effects that:
according to the invention, the graphene, the silver powder, the polyester fiber and the antistatic agent are added into the raw materials for preparing the fiber, so that an antistatic film is formed on the surface of the fiber blank, the prepared fiber is antistatic and radiation-resistant, and meanwhile, the adhesive, the anti-aging agent and the antioxidant are added in proportion to improve the wear resistance of the antistatic fiber and prolong the service life of the antistatic fiber.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The invention provides an antistatic fiber which comprises the following raw materials in parts by weight: 60-75 parts of terylene, 25-35 parts of graphene, 10-20 parts of polyester fiber, 20-35 parts of silver powder, 6-18 parts of catalyst, 170 parts of compatilizer 140, 3-6 parts of adhesive, 5-9 parts of anti-aging agent, 15-25 parts of antistatic agent and 8-15 parts of antioxidant.
Further, 65 parts of terylene, 28 parts of graphene, 13 parts of polyester fiber, 22 parts of silver powder, 8 parts of catalyst, 150 parts of compatilizer, 4 parts of adhesive, 7 parts of anti-aging agent, 17 parts of antistatic agent and 9 parts of antioxidant.
Further, the catalyst is one of manganese dioxide or ferric oxide, and the compatilizer is one of acrylonitrile or styrene and maleic anhydride terpolymer.
Furthermore, the adhesive is one of polyvinyl alcohol or carboxymethyl cellulose, and the anti-aging agent is one of zinc dialkyl dithiophosphate or zinc dialkyl dithiocarbamate.
Further, the antistatic agent is one of ethoxylated aliphatic alkylamine or alkylsulfonic acid, and the antioxidant is one of zinc dialkyl dithiophosphate or zinc dialkyl dithiocarbamate.
A preparation method of antistatic fiber comprises the following steps:
s1, preparing raw materials: screening terylene, graphene, polyester fiber and silver powder, and removing impurities;
s2, mixing the raw materials: simultaneously putting the terylene, the graphene, the polyester fiber and the silver powder into mixing equipment for stirring, uniformly mixing the raw materials, and standing for 2-3 h;
s3, preparing a mixed solution: stirring the catalyst, the compatilizer, the adhesive, the anti-aging agent, the antistatic agent and the antioxidant uniformly, putting the raw materials after standing and the catalyst, the compatilizer, the adhesive, the anti-aging agent, the antistatic agent and the antioxidant which are stirred uniformly into a reaction kettle for reaction, wherein the reverse time is 2.5 hours, and the reaction temperature is 230-240 ℃ to obtain a mixed solution;
s4, drying the mixed solution; putting the obtained mixed solution into a drying box for drying treatment for 1.5-2.5 h to obtain antistatic terylene;
s5, weaving fibers: weaving the antistatic terylene by a weaving machine to obtain an antistatic fiber blank;
s6, fiber shaping: and (3) placing the antistatic fiber blank into a setting machine for setting, and obtaining the antistatic fiber finished product after setting is finished.
Further, in step S4, the temperature of the drying box for drying the mixed liquid is 200-220 ℃, and in step S5, the distance between the antistatic fibers woven by the weaving machine is 0.3 mm.
Further, in step S6, the setting time of the setting machine for the antistatic fiber blank is 1.5 h.
Example 2
The invention provides an antistatic fiber which comprises the following raw materials in parts by weight: 60-75 parts of terylene, 25-35 parts of graphene, 10-20 parts of polyester fiber, 20-35 parts of silver powder, 6-18 parts of catalyst, 170 parts of compatilizer 140, 3-6 parts of adhesive, 5-9 parts of anti-aging agent, 15-25 parts of antistatic agent and 8-15 parts of antioxidant.
Further, 70 parts of terylene, 31 parts of graphene, 16 parts of polyester fiber, 28 parts of silver powder, 12 parts of catalyst, 155 parts of compatilizer, 5 parts of adhesive, 6 parts of anti-aging agent, 20 parts of antistatic agent and 11 parts of antioxidant.
Further, the catalyst is one of manganese dioxide or ferric oxide, and the compatilizer is one of acrylonitrile or styrene and maleic anhydride terpolymer.
Furthermore, the adhesive is one of polyvinyl alcohol or carboxymethyl cellulose, and the anti-aging agent is one of zinc dialkyl dithiophosphate or zinc dialkyl dithiocarbamate.
Further, the antistatic agent is one of ethoxylated aliphatic alkylamine or alkylsulfonic acid, and the antioxidant is one of zinc dialkyl dithiophosphate or zinc dialkyl dithiocarbamate.
A preparation method of antistatic fiber comprises the following steps:
s1, preparing raw materials: screening terylene, graphene, polyester fiber and silver powder, and removing impurities;
s2, mixing the raw materials: simultaneously putting the terylene, the graphene, the polyester fiber and the silver powder into mixing equipment for stirring, uniformly mixing the raw materials, and standing for 2-3 h;
s3, preparing a mixed solution: stirring the catalyst, the compatilizer, the adhesive, the anti-aging agent, the antistatic agent and the antioxidant uniformly, putting the raw materials after standing and the catalyst, the compatilizer, the adhesive, the anti-aging agent, the antistatic agent and the antioxidant which are stirred uniformly into a reaction kettle for reaction, wherein the reverse time is 2.5 hours, and the reaction temperature is 230-240 ℃ to obtain a mixed solution;
s4, drying the mixed solution; putting the obtained mixed solution into a drying box for drying treatment for 1.5-2.5 h to obtain antistatic terylene;
s5, weaving fibers: weaving the antistatic terylene by a weaving machine to obtain an antistatic fiber blank;
s6, fiber shaping: and (3) placing the antistatic fiber blank into a setting machine for setting, and obtaining the antistatic fiber finished product after setting is finished.
Further, in step S4, the temperature of the drying box for drying the mixed liquid is 200-220 ℃, and in step S5, the distance between the antistatic fibers woven by the weaving machine is 0.3 mm.
Further, in step S6, the setting time of the setting machine for the antistatic fiber blank is 1.5 h.
Example 3
The invention provides an antistatic fiber which comprises the following raw materials in parts by weight: 60-75 parts of terylene, 25-35 parts of graphene, 10-20 parts of polyester fiber, 20-35 parts of silver powder, 6-18 parts of catalyst, 170 parts of compatilizer 140, 3-6 parts of adhesive, 5-9 parts of anti-aging agent, 15-25 parts of antistatic agent and 8-15 parts of antioxidant.
Further, 72 parts of terylene, 35 parts of graphene, 19 parts of polyester fiber, 30 parts of silver powder, 15 parts of catalyst, 142 parts of compatilizer, 3 parts of adhesive, 9 parts of anti-aging agent, 19 parts of antistatic agent and 13 parts of antioxidant.
Further, the catalyst is one of manganese dioxide or ferric oxide, and the compatilizer is one of acrylonitrile or styrene and maleic anhydride terpolymer.
Furthermore, the adhesive is one of polyvinyl alcohol or carboxymethyl cellulose, and the anti-aging agent is one of zinc dialkyl dithiophosphate or zinc dialkyl dithiocarbamate.
Further, the antistatic agent is one of ethoxylated aliphatic alkylamine or alkylsulfonic acid, and the antioxidant is one of zinc dialkyl dithiophosphate or zinc dialkyl dithiocarbamate.
A preparation method of antistatic fiber comprises the following steps:
s1, preparing raw materials: screening terylene, graphene, polyester fiber and silver powder, and removing impurities;
s2, mixing the raw materials: simultaneously putting the terylene, the graphene, the polyester fiber and the silver powder into mixing equipment for stirring, uniformly mixing the raw materials, and standing for 2-3 h;
s3, preparing a mixed solution: stirring the catalyst, the compatilizer, the adhesive, the anti-aging agent, the antistatic agent and the antioxidant uniformly, putting the raw materials after standing and the catalyst, the compatilizer, the adhesive, the anti-aging agent, the antistatic agent and the antioxidant which are stirred uniformly into a reaction kettle for reaction, wherein the reverse time is 2.5 hours, and the reaction temperature is 230-240 ℃ to obtain a mixed solution;
s4, drying the mixed solution; putting the obtained mixed solution into a drying box for drying treatment for 1.5-2.5 h to obtain antistatic terylene;
s5, weaving fibers: weaving the antistatic terylene by a weaving machine to obtain an antistatic fiber blank;
s6, fiber shaping: and (3) placing the antistatic fiber blank into a setting machine for setting, and obtaining the antistatic fiber finished product after setting is finished.
Further, in step S4, the temperature of the drying box for drying the mixed liquid is 200-220 ℃, and in step S5, the distance between the antistatic fibers woven by the weaving machine is 0.3 mm.
Further, in step S6, the setting time of the setting machine for the antistatic fiber blank is 1.5 h.
It will be apparent to those skilled in the art that various changes and modifications may be made in the present invention without departing from the spirit and scope of the invention. Thus, if such modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalents, the present invention is also intended to include such modifications and variations.
Claims (10)
1. The antistatic fiber comprises the following raw materials in parts by weight: 60-75 parts of terylene, 25-35 parts of graphene, 10-20 parts of polyester fiber, 20-35 parts of silver powder, 6-18 parts of catalyst, 170 parts of compatilizer 140, 3-6 parts of adhesive, 5-9 parts of anti-aging agent, 15-25 parts of antistatic agent and 8-15 parts of antioxidant.
2. The antistatic fiber as claimed in claim 1, wherein the polyester fiber comprises 65 parts of terylene, 28 parts of graphene, 13 parts of polyester fiber, 22 parts of silver powder, 8 parts of catalyst, 150 parts of compatilizer, 4 parts of adhesive, 7 parts of anti-aging agent, 17 parts of antistatic agent and 9 parts of antioxidant.
3. The antistatic fiber of claim 1, wherein the polyester fiber comprises 70 parts of terylene, 31 parts of graphene, 16 parts of polyester fiber, 28 parts of silver powder, 12 parts of catalyst, 155 parts of compatilizer, 5 parts of adhesive, 6 parts of anti-aging agent, 20 parts of antistatic agent and 11 parts of antioxidant.
4. The antistatic fiber as claimed in claim 1, wherein the polyester comprises 72 parts of terylene, 35 parts of graphene, 19 parts of polyester fiber, 30 parts of silver powder, 15 parts of catalyst, 142 parts of compatilizer, 3 parts of adhesive, 9 parts of anti-aging agent, 19 parts of antistatic agent and 13 parts of antioxidant.
5. The antistatic fiber of claim 1 wherein the catalyst is one of manganese dioxide or iron oxide and the compatibilizer is one of acrylonitrile or a terpolymer of styrene and maleic anhydride.
6. The antistatic fiber of claim 1 wherein the binder is one of polyvinyl alcohol or carboxymethylcellulose and the antioxidant is one of zinc dialkyldithiophosphate or zinc dialkyldithiocarbamate.
7. The method of claim 1, wherein the antistatic agent is one of ethoxylated aliphatic alkylamine and alkylsulfonic acid, and the antioxidant is one of zinc dialkyldithiophosphate or zinc dialkyldithiocarbamate.
8. The method for preparing antistatic fiber according to claim 1, comprising the steps of:
s1, preparing raw materials: screening terylene, graphene, polyester fiber and silver powder, and removing impurities;
s2, mixing the raw materials: simultaneously putting the terylene, the graphene, the polyester fiber and the silver powder into mixing equipment for stirring, uniformly mixing the raw materials, and standing for 2-3 h;
s3, preparing a mixed solution: stirring the catalyst, the compatilizer, the adhesive, the anti-aging agent, the antistatic agent and the antioxidant uniformly, putting the raw materials after standing and the catalyst, the compatilizer, the adhesive, the anti-aging agent, the antistatic agent and the antioxidant which are stirred uniformly into a reaction kettle for reaction, wherein the reverse time is 2.5 hours, and the reaction temperature is 230-240 ℃ to obtain a mixed solution;
s4, drying the mixed solution; putting the obtained mixed solution into a drying box for drying treatment for 1.5-2.5 h to obtain antistatic terylene;
s5, weaving fibers: weaving the antistatic terylene by a weaving machine to obtain an antistatic fiber blank;
s6, fiber shaping: and (3) placing the antistatic fiber blank into a setting machine for setting, and obtaining the antistatic fiber finished product after setting is finished.
9. The method of claim 8, wherein the temperature of the drying oven for drying the mixture is 200 ℃ to 220 ℃ in step S4, and the distance between the antistatic fibers woven by the weaving machine is 0.3mm in step S5.
10. The method of claim 8, wherein in step S6, the setting time of the setting machine for the antistatic fiber blank is 1.5 h.
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