CN113830964A - Method for treating livestock and poultry breeding wastewater based on autotrophic denitrification process - Google Patents

Method for treating livestock and poultry breeding wastewater based on autotrophic denitrification process Download PDF

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Publication number
CN113830964A
CN113830964A CN202110984994.5A CN202110984994A CN113830964A CN 113830964 A CN113830964 A CN 113830964A CN 202110984994 A CN202110984994 A CN 202110984994A CN 113830964 A CN113830964 A CN 113830964A
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sewage
reactor
sludge
tank
nitrogen removal
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黄翀
黄东辉
刘超
蒋永丰
凌锐
徐静斌
申晨希
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Jiangsu Yulong Environment Protection Co ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/20Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes

Abstract

The invention discloses a method for treating livestock and poultry breeding wastewater based on an autotrophic nitrogen removal process, which comprises the following steps of; the method comprises the following steps: feeding the breeding wastewater into a mechanical grid, conveying the sewage into a liquid storage tank through a solid-liquid separator, and discharging solid residues into a residue storage tank; discharging the sewage in the liquid storage tank into a UASB reactor through the bottom of the UASB reactor, introducing the sewage in the UASB reactor into the bottom of the reactor as uniformly as possible, wherein the anaerobic reaction is carried out in the process of contacting the sewage with sludge particles; and thirdly, precipitating the sewage in a middle sedimentation tank, discharging the precipitated sludge into a CSTR reactor, and feeding the sewage into a biochemical tank for autotrophic nitrogen removal. The invention can construct two different systems in a biochemical pool: the integrated anaerobic ammonia oxidation system or the multi-stage anoxic/aerobic alternate autotrophic denitrification system realizes autotrophic denitrification so as to realize carbon neutralization, can effectively treat livestock and poultry breeding wastewater, and reduces the concentrations of organic matters, total nitrogen and ammonia nitrogen.

Description

Method for treating livestock and poultry breeding wastewater based on autotrophic denitrification process
Technical Field
The invention relates to the technical field of sewage treatment, in particular to a method for treating livestock and poultry breeding wastewater based on an autotrophic nitrogen removal process.
Background
Excessive ammonia nitrogen discharged into water body can cause eutrophication of water body, reduce ornamental value of water body, and nitrate and nitrite generated by oxidation can influence the health of aquatic organisms and even human beings, therefore, the denitrification treatment of the wastewater is widely concerned by people, the main denitrification methods comprise biological nitrification and denitrification, breakpoint chlorination, gas stripping and air stripping, ion exchange and the like, the nitrification sludge dewatering liquid, the landfill leachate, the wastewater of a catalyst production plant, the meat processing wastewater, the wastewater of synthetic ammonia chemical industry and the like contain ammonia nitrogen with extremely high concentration, some ammonia nitrogen concentration reaches more than 500mg/L, some ammonia nitrogen concentration even reaches thousands of mg/L, the treatment method can be limited in application due to the biological inhibition of free ammonia nitrogen or cost, and the treatment method of high-concentration ammonia nitrogen wastewater can be divided into a physical-chemical method, a biochemical combined method and a novel biological denitrification method;
the livestock and poultry breeding wastewater has the characteristics of high organic matter concentration, high total nitrogen and high ammonia nitrogen, and the anaerobic reactor and aerobic biochemical treatment are mostly adopted in the treatment method of the livestock and poultry breeding wastewater.
Disclosure of Invention
The invention aims to provide a method for treating livestock and poultry breeding wastewater based on an autotrophic nitrogen removal process, so as to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: a method for treating livestock and poultry breeding wastewater based on an autotrophic nitrogen removal process comprises the following steps;
the method comprises the following steps: feeding the breeding wastewater into a mechanical grid, conveying the sewage into a liquid storage tank through a solid-liquid separator, and discharging solid residues into a residue storage tank;
step two, discharging the sewage in the liquid storage tank into a UASB reactor through the bottom of the UASB reactor, introducing the sewage of the UASB reactor into the bottom of the reactor as uniformly as possible, wherein the anaerobic reaction is generated in the process of contacting the sewage with sludge particles, the biogas generated in the anaerobic state causes internal circulation, some gas formed in a sludge layer is attached to sludge particles, the attached and unattached gas rises to the top of the reactor, the sludge rising to the surface impacts the bottom of a gas emitter of the three-phase reactor to cause degassing of sludge flocs attached with bubbles, the sludge particles are precipitated on the surface of a sludge bed after the bubbles are released, the attached and unattached gas is collected into a gas collection chamber of a three-phase separator at the top of the reactor, the biogas is collected by a gas collection cabinet, the residual sludge is discharged into a CSTR reactor, and the sewage is discharged into a settling tank for primary precipitation;
precipitating the sewage in a middle sedimentation tank for 50-60 min, discharging the precipitated sludge into a CSTR reactor, and feeding the sewage into a biochemical tank for autotrophic nitrogen removal;
and step four, the wastewater treated by the biochemical tank enters a secondary sedimentation tank, after the wastewater is precipitated in the secondary sedimentation tank, the residual sludge is sent into the CSTR reactor through a return pipeline, the upper clear liquid enters a disinfection tank, and is discharged into a recycling tank for temporary storage after being disinfected in the disinfection tank, and the treated wastewater is flushed after the index reaches the discharge standard.
Preferably, the biogas generated by the CSTR reactor enters a gas collection cabinet for collection, the biogas in the gas collection cabinet can be used for biogas power generation, and the biogas residues generated by the CSTR reactor are recycled.
Preferably, the biochemical tank adopts an autotrophic nitrogen removal process, and an integrated anaerobic ammonia oxidation system or a multi-stage anoxic/aerobic alternate autotrophic nitrogen removal system is constructed by relying on MBBR carriers to realize autotrophic nitrogen removal.
Preferably, the mechanism of the integrated anammox system is as follows: high ammonia nitrogen generates high-concentration Free Ammonia (FA) to inhibit Nitrate Oxidizing Bacteria (NOB), stable NO2 & lt- & gt is provided, and under the anoxic condition, the anaerobic ammonia oxidizing bacteria oxidize NH4 & lt + & gt-N into N2 by taking NO2 & lt- & gt-N as an oxidizing agent.
Preferably, the mechanism of the multistage anoxic/aerobic alternate autotrophic nitrogen removal system is as follows: when the oxygen deficiency and the oxygen deficiency are alternated, the activity recovery of the NOB is slower than that of the AOB when the oxygen deficiency is changed into the oxygen deficiency, the NOB is gradually eliminated through multi-stage oxygen deficiency and oxygen deficiency alternation, and the NOB can provide stable NO after being inhibited2 -And stable short-cut nitrification and denitrification are realized.
Preferably, the MBBR carrier comprises the following components in percentage by weight: 97% +/-0.5% of high-density polyethylene or polypropylene, 2.5% +/-0.2% of activated carbon powder and 0.5% +/-0.1% of broken magnet powder.
Preferably, the middle sedimentation tank and the secondary sedimentation tank are both provided with sludge discharge devices.
The method for treating livestock and poultry breeding wastewater based on the autotrophic nitrogen removal process has the beneficial effects that:
1. the invention can construct two different systems in the biochemical pool to realize autotrophic nitrogen removal, an integrated anaerobic ammonia oxidation system or a multi-stage anoxic/aerobic alternate autotrophic nitrogen removal system to realize carbon neutralization, can effectively treat livestock and poultry breeding wastewater, and reduce the concentrations of organic matters, total nitrogen and ammonia nitrogen;
2. according to the invention, the intermediate sedimentation tank is arranged behind the UASB reactor, so that firstly, anaerobic sludge overflowing from the UASB is prevented from entering a subsequent biochemical tank, and the sludge is prevented from being decomposed again and treated again; secondly, discharging phosphorus through the precipitated sludge to reduce the consumption of a carbon source for subsequent biochemical phosphorus removal;
3. the CSTR reactor converts most of organic carbon into biogas through anaerobic fermentation, the biogas is used for power generation, and the biogas residues are used for backfilling;
4. the outlet water after the disinfection treatment is used for washing the pigsty to realize the recycling of the water.
Drawings
FIG. 1 is a schematic process flow diagram of the present invention;
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1, please refer to fig. 1, the present invention provides a technical solution: a method for treating livestock and poultry breeding wastewater based on an autotrophic nitrogen removal process comprises the following steps;
the method comprises the following steps: feeding the breeding wastewater into a mechanical grid, conveying the sewage into a liquid storage tank through a solid-liquid separator, and discharging solid residues into a residue storage tank;
step two, discharging the sewage in the liquid storage tank into a UASB reactor through the bottom of the UASB reactor, introducing the sewage of the UASB reactor into the bottom of the reactor as uniformly as possible, generating an anaerobic reaction in the process of contacting the sewage with sludge particles, generating internal circulation by the methane generated in an anaerobic state, attaching some gas formed in a sludge layer to the sludge particles, ascending the attached and unattached gas to the top of the reactor, impacting the sludge on the surface to the bottom of a gas emitter of the three-phase reactor to cause degassing of sludge floc attached with bubbles, depositing the sludge particles on the surface of a sludge bed after the bubbles are released, collecting the attached and unattached gas to a gas collection chamber of a three-phase separator at the top of the reactor, collecting the methane by the gas collection chamber, discharging the residual sludge into a CSTR reactor, collecting the methane generated by the CSTR reactor into the gas collection chamber, biogas in the gas collecting cabinet can be used for biogas power generation, biogas residues generated by the CSTR reactor are recycled, and sewage is discharged into a sedimentation tank for primary sedimentation;
precipitating the sewage in a middle sedimentation tank for 50min, discharging the precipitated sludge into a CSTR reactor, feeding the sewage into a biochemical tank for autotrophic nitrogen removal, wherein the biochemical tank adopts an autotrophic nitrogen removal process and depends on an MBBR carrier, and the MBBR carrier comprises the following components in parts by weight: 97 percent +/-0.5 percent of high-density polyethylene or polypropylene, 2.5 percent +/-0.2 percent of activated carbon powder and 0.5 percent +/-0.1 percent of broken magnet powder, an integrated anaerobic ammonia oxidation system is constructed to realize autotrophic nitrogen removal, and the mechanism of the integrated anaerobic ammonia oxidation system is as follows: high ammonia nitrogen generates high-concentration Free Ammonia (FA) to inhibit Nitrate Oxidizing Bacteria (NOB), stable NO 2-is provided, and under the anoxic condition, the anaerobic ammonia oxidizing bacteria takes NO 2-N as an oxidant to oxidize NH4+ -N into N2;
step four, the wastewater treated by the biochemical tank enters a secondary sedimentation tank, after the wastewater is precipitated in the secondary sedimentation tank, the residual sludge is sent into the CSTR reactor through a return pipeline, the upper clear liquid enters a disinfection tank, and is discharged into a recycling tank for temporary storage after being disinfected in the disinfection tank, and the treated wastewater is flushed after the index reaches the discharge standard;
the mechanism of the multi-stage anoxic/aerobic alternate autotrophic nitrogen removal system is as follows: when the oxygen deficiency and the oxygen deficiency are alternated, the activity recovery of the NOB is slower than that of the AOB when the oxygen deficiency is changed into the oxygen deficiency, the NOB is gradually eliminated through multi-stage oxygen deficiency and oxygen deficiency alternation, and the NOB can provide stable NO after being inhibited2 -And stable short-cut nitrification and denitrification are realized.
Embodiment 2, please refer to fig. 1, the present invention provides a technical solution: a method for treating livestock and poultry breeding wastewater based on an autotrophic nitrogen removal process comprises the following steps;
the method comprises the following steps: feeding the breeding wastewater into a mechanical grid, conveying the sewage into a liquid storage tank through a solid-liquid separator, and discharging solid residues into a residue storage tank;
step two, discharging the sewage in the liquid storage tank into a UASB reactor through the bottom of the UASB reactor, introducing the sewage of the UASB reactor into the bottom of the reactor as uniformly as possible, generating an anaerobic reaction in the process of contacting the sewage with sludge particles, generating internal circulation by the methane generated in an anaerobic state, attaching some gas formed in a sludge layer to the sludge particles, ascending the attached and unattached gas to the top of the reactor, impacting the sludge on the surface to the bottom of a gas emitter of the three-phase reactor to cause degassing of sludge floc attached with bubbles, depositing the sludge particles on the surface of a sludge bed after the bubbles are released, collecting the attached and unattached gas to a gas collection chamber of a three-phase separator at the top of the reactor, collecting the methane by the gas collection chamber, discharging the residual sludge into a CSTR reactor, collecting the methane generated by the CSTR reactor into the gas collection chamber, biogas in the gas collecting cabinet can be used for biogas power generation, biogas residues generated by the CSTR reactor are recycled, and sewage is discharged into a sedimentation tank for primary sedimentation;
precipitating the sewage in a middle sedimentation tank for 60min, discharging the precipitated sludge into a CSTR reactor, feeding the sewage into a biochemical tank for autotrophic nitrogen removal, wherein the biochemical tank adopts an autotrophic nitrogen removal process and depends on an MBBR carrier, and the MBBR carrier comprises the following components in parts by weight: 97 percent +/-0.5 percent of high-density polyethylene or polypropylene, 2.5 percent +/-0.2 percent of activated carbon powder and 0.5 percent +/-0.1 percent of broken magnet powder, a multistage anoxic/aerobic alternate autotrophic denitrification system is constructed to realize autotrophic denitrification, and the mechanism of the multistage anoxic/aerobic alternate autotrophic denitrification system is as follows: when the anoxic/aerobic alternation is performed, the activity recovery of the Nitrate Oxidizing Bacteria (NOB) is slower than that of the Ammonia Oxidizing Bacteria (AOB) from anoxic to aerobic activity, the Nitrate Oxidizing Bacteria (NOB) are gradually eliminated through multi-stage anoxic/aerobic alternation, and the Nitrate Oxidizing Bacteria (NOB) can provide stable NO 2-after being inhibited, so that stable short-cut nitrification and denitrification are realized;
step four, the wastewater treated by the biochemical tank enters a secondary sedimentation tank, after the wastewater is precipitated in the secondary sedimentation tank, the residual sludge is sent into the CSTR reactor through a return pipeline, the upper clear liquid enters a disinfection tank, and is discharged into a recycling tank for temporary storage after being disinfected in the disinfection tank, and the treated wastewater is flushed after the index reaches the discharge standard;
the mechanism of the multi-stage anoxic/aerobic alternate autotrophic nitrogen removal system is as follows: when the oxygen deficiency and the oxygen deficiency are alternated, the activity recovery of the NOB is slower than that of the AOB when the oxygen deficiency is changed into the oxygen deficiency, the NOB is gradually eliminated through multi-stage oxygen deficiency and oxygen deficiency alternation, and the NOB can provide stable NO after being inhibited2 -And stable short-cut nitrification and denitrification are realized.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (7)

1. A method for treating livestock and poultry breeding wastewater based on an autotrophic nitrogen removal process is characterized by comprising the following steps: comprises the following steps;
the method comprises the following steps: feeding the breeding wastewater into a mechanical grid, conveying the sewage into a liquid storage tank through a solid-liquid separator, and discharging solid residues into a residue storage tank;
step two, discharging the sewage in the liquid storage tank into a UASB reactor through the bottom of the UASB reactor, introducing the sewage of the UASB reactor into the bottom of the reactor as uniformly as possible, wherein the anaerobic reaction is generated in the process of contacting the sewage with sludge particles, the biogas generated in the anaerobic state causes internal circulation, some gas formed in a sludge layer is attached to sludge particles, the attached and unattached gas rises to the top of the reactor, the sludge rising to the surface impacts the bottom of a gas emitter of the three-phase reactor to cause degassing of sludge flocs attached with bubbles, the sludge particles are precipitated on the surface of a sludge bed after the bubbles are released, the attached and unattached gas is collected into a gas collection chamber of a three-phase separator at the top of the reactor, the biogas is collected by a gas collection cabinet, the residual sludge is discharged into a CSTR reactor, and the sewage is discharged into a settling tank for primary precipitation;
precipitating the sewage in a middle sedimentation tank for 50-60 min, discharging the precipitated sludge into a CSTR reactor, and feeding the sewage into a biochemical tank for autotrophic nitrogen removal;
and step four, the wastewater treated by the biochemical tank enters a secondary sedimentation tank, after the wastewater is precipitated in the secondary sedimentation tank, the residual sludge is sent into the CSTR reactor through a return pipeline, the upper clear liquid enters a disinfection tank, and is discharged into a recycling tank for temporary storage after being disinfected in the disinfection tank, and the treated wastewater is flushed after the index reaches the discharge standard.
2. The method for treating livestock and poultry breeding wastewater based on the autotrophic nitrogen removal process according to claim 1, wherein the method comprises the following steps: biogas generated by the CSTR reactor enters a gas collection cabinet to be collected, the biogas in the gas collection cabinet can be used for biogas power generation, and biogas residues generated by the CSTR reactor are recycled.
3. The method for treating livestock and poultry breeding wastewater based on the autotrophic nitrogen removal process according to claim 1, wherein the method comprises the following steps: the biochemical tank adopts an autotrophic nitrogen removal process, and an integrated anaerobic ammonia oxidation system or a multi-stage anoxic/aerobic alternate autotrophic nitrogen removal system is constructed by relying on MBBR carriers to realize autotrophic nitrogen removal.
4. The method for treating livestock and poultry breeding wastewater based on the autotrophic nitrogen removal process according to claim 1, wherein the method comprises the following steps: the mechanism of the integrated anaerobic ammonia oxidation system is as follows: high ammonia nitrogen generates high-concentration Free Ammonia (FA) to inhibit Nitrate Oxidizing Bacteria (NOB), stable NO2 & lt- & gt is provided, and under the anoxic condition, the anaerobic ammonia oxidizing bacteria oxidize NH4 & lt + & gt-N into N2 by taking NO2 & lt- & gt-N as an oxidizing agent.
5. The method for treating livestock and poultry breeding wastewater based on the autotrophic nitrogen removal process according to claim 1, wherein the method comprises the following steps: the mechanism of the multi-stage anoxic/aerobic alternate autotrophic nitrogen removal system is as follows: when the oxygen deficiency and the oxygen deficiency are alternated, the activity recovery of the NOB is slower than that of the AOB when the oxygen deficiency is changed into the oxygen deficiency, the NOB is gradually eliminated through multi-stage oxygen deficiency and oxygen deficiency alternation, and the NOB can provide stable NO after being inhibited2 -And stable short-cut nitrification and denitrification are realized.
6. The method for treating livestock and poultry breeding wastewater based on the autotrophic nitrogen removal process according to claim 1, wherein the method comprises the following steps: the MBBR carrier comprises the following components in percentage by weight: 97% +/-0.5% of high-density polyethylene or polypropylene, 2.5% +/-0.2% of activated carbon powder and 0.5% +/-0.1% of broken magnet powder.
7. The method for treating livestock and poultry breeding wastewater based on the autotrophic nitrogen removal process according to claim 1, wherein the method comprises the following steps: and sludge discharge devices are arranged in the intermediate sedimentation tank and the secondary sedimentation tank.
CN202110984994.5A 2021-08-25 2021-08-25 Method for treating livestock and poultry breeding wastewater based on autotrophic denitrification process Pending CN113830964A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115403143A (en) * 2022-08-08 2022-11-29 江苏裕隆环保有限公司 Low-carbon treatment system and process for realizing deep denitrification of high-ammonia-nitrogen wastewater

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Publication number Priority date Publication date Assignee Title
CN106242162A (en) * 2016-08-18 2016-12-21 南方创业(天津)科技发展有限公司 The dirt of livestock and poultry farms in scale excrement and the recycling treatment process of waste water
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CN110451743A (en) * 2019-01-25 2019-11-15 四川能投水务投资有限公司 A kind of municipal wastewater plant excess sludge method of resource
CN110482803A (en) * 2019-09-21 2019-11-22 山东和正环保工程有限公司 A kind of cultivating wastewater purification device
CN111115822A (en) * 2020-01-20 2020-05-08 青岛思普润水处理股份有限公司 PN/A integrated autotrophic nitrogen removal system based on MBBR and quick starting method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20170291839A1 (en) * 2014-09-24 2017-10-12 Veolia Water Solutions & Technologies Support Anammox process at waste water plant
CN106242162A (en) * 2016-08-18 2016-12-21 南方创业(天津)科技发展有限公司 The dirt of livestock and poultry farms in scale excrement and the recycling treatment process of waste water
CN110451743A (en) * 2019-01-25 2019-11-15 四川能投水务投资有限公司 A kind of municipal wastewater plant excess sludge method of resource
CN110482803A (en) * 2019-09-21 2019-11-22 山东和正环保工程有限公司 A kind of cultivating wastewater purification device
CN111115822A (en) * 2020-01-20 2020-05-08 青岛思普润水处理股份有限公司 PN/A integrated autotrophic nitrogen removal system based on MBBR and quick starting method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115403143A (en) * 2022-08-08 2022-11-29 江苏裕隆环保有限公司 Low-carbon treatment system and process for realizing deep denitrification of high-ammonia-nitrogen wastewater

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