CN113829759A - Color ink-jet printing method based on polystyrene microsphere array structure - Google Patents
Color ink-jet printing method based on polystyrene microsphere array structure Download PDFInfo
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- CN113829759A CN113829759A CN202111001867.5A CN202111001867A CN113829759A CN 113829759 A CN113829759 A CN 113829759A CN 202111001867 A CN202111001867 A CN 202111001867A CN 113829759 A CN113829759 A CN 113829759A
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- 239000004793 Polystyrene Substances 0.000 title claims abstract description 42
- 239000004005 microsphere Substances 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 23
- 229920002223 polystyrene Polymers 0.000 title claims abstract description 21
- 238000007641 inkjet printing Methods 0.000 title claims abstract description 13
- 239000002245 particle Substances 0.000 claims abstract description 37
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000000725 suspension Substances 0.000 claims abstract description 21
- 239000010931 gold Substances 0.000 claims abstract description 19
- 229910052737 gold Inorganic materials 0.000 claims abstract description 19
- 239000002105 nanoparticle Substances 0.000 claims abstract description 15
- 239000000843 powder Substances 0.000 claims abstract description 13
- 238000007639 printing Methods 0.000 claims abstract description 10
- 239000000758 substrate Substances 0.000 claims abstract description 9
- 239000007921 spray Substances 0.000 claims abstract description 5
- 239000010409 thin film Substances 0.000 claims abstract description 5
- 239000003086 colorant Substances 0.000 claims abstract description 4
- 239000011858 nanopowder Substances 0.000 claims abstract 3
- 238000005507 spraying Methods 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000008188 pellet Substances 0.000 claims description 9
- 239000011324 bead Substances 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 6
- 239000010408 film Substances 0.000 abstract description 6
- 238000010521 absorption reaction Methods 0.000 abstract description 5
- 230000003595 spectral effect Effects 0.000 abstract description 3
- 238000002198 surface plasmon resonance spectroscopy Methods 0.000 abstract description 3
- 238000003491 array Methods 0.000 abstract description 2
- 239000011805 ball Substances 0.000 abstract 4
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000011806 microball Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 4
- 239000002356 single layer Substances 0.000 description 4
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920000891 common polymer Polymers 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000000835 electrochemical detection Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002082 metal nanoparticle Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/21—Ink jet for multi-colour printing
- B41J2/2107—Ink jet for multi-colour printing characterised by the ink properties
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
本发明公开了基于聚苯乙烯微球阵列结构的彩色喷墨打印方法，所述方法包括：利用不同粒径的白色PS小球粉末制备多种浓度且包含不同粒径小球的悬浮液；在需要打印的基板上划分不同区域，根据颜色需要将不同悬浮液喷涂到各个区域；待悬浮液蒸发后，各个区域形成了不同粒径小球构成的薄膜阵列；根据颜色需求再在各个区域喷涂不同厚度的金纳米粉末，由于薄膜阵列和小球缝隙中不同厚度的金粉形成不同颜色，实现彩色打印。本发明基于PS小球构成的结构色薄膜，并在均匀划分的小球阵列喷涂不同厚度金纳米粉末于小球缝隙中；利用聚苯乙烯微球构成的有序阵列和金纳米颗粒的局域表面等离子体激元共振特性即对紫外可见光区的光谱吸收效应来实现颜色的改变。
The invention discloses a color inkjet printing method based on a polystyrene microsphere array structure, the method comprising: preparing a suspension of various concentrations and containing the different particle diameters by using white PS small ball powders of different particle sizes; Different areas are divided on the substrate to be printed, and different suspensions are sprayed to each area according to the color requirements; after the suspension is evaporated, each area forms a thin film array composed of spheres of different particle sizes; according to the color requirements, different areas are sprayed differently The thickness of gold nanopowders can achieve color printing due to the formation of different colors of gold powders with different thicknesses in the thin film array and the gaps of the beads. The invention is based on a structural color film composed of PS small balls, and sprays gold nano-powders with different thicknesses in the uniformly divided ball arrays in the gaps of the small balls; the ordered array composed of polystyrene micro balls and the local area of gold nanoparticles are used. The surface plasmon resonance characteristic is the spectral absorption effect on the ultraviolet-visible region to realize the color change.
Description
Technical Field
The invention relates to a color ink-jet printing method based on a polystyrene microsphere array structure, belonging to the technical field.
Background
Polystyrene microspheres, namely PS beads, are a common polymer microsphere material, and a preparation method of polystyrene microspheres with narrow particle size distribution is reported for the first time in 1955 by Vanderhoff and Brodford, and then the preparation and research of polymer microspheres become a new field of polymer science research. The polystyrene microsphere has the general characteristics of a polymer microsphere material, such as small particle size, large specific surface area, strong adsorbability, good dispersibility, easy modification and the like. The method is widely applied to the fields of biochemistry, electrochemical detection, catalysts, adsorbents, chromatographic fillers, coatings and the like. The reason why the noble metal nanoparticles have bright colors is that the nanoparticles have strong scattering and absorption effects on light in the ultraviolet and visible light region, and have strong absorption bands in the ultraviolet and visible light region, which is the localized surface plasmon resonance effect.
The ink-jet printer forms images and texts by spraying ink into fine particles through a nozzle onto printing paper. Conventional ink jet printers typically employ thermal inkjet technology, which utilizes a thin film resistor to heat less than 0.5% of the ink in the ink ejection area to form a vapor bubble. The thermal ink-jet technology is constructed by such an integrated cyclic technical program, but because the ink is easy to change chemically at high temperature, the directionality and the volume of ink particles are not well known, the edges of printing lines are easy to be uneven, and the printing quality is influenced to a certain extent, which is a disadvantage.
Disclosure of Invention
The invention aims to provide a color ink-jet printing method based on a polystyrene microsphere array structure, which aims to overcome the defects of complicated color printing and insufficient printing precision of the traditional ink-jet printer in the prior art.
A color inkjet printing method based on a polystyrene microsphere array structure, the method comprising:
preparing suspensions with various concentrations and containing the small balls with different particle sizes by using white PS small ball powder with different particle sizes;
dividing different areas on a substrate to be printed, and spraying different suspensions to each area according to color requirements;
after the suspension is evaporated, forming a film array consisting of small balls with different particle sizes in each area;
and spraying gold nano powder with different thicknesses in each area according to color requirements, wherein the gold powder with different thicknesses in the film array and the small ball gap forms different colors, so that color printing is realized.
Further, the method adopts two nozzles, one is used for spraying the suspension liquid of the small balls with different particle sizes to different divided areas on the substrate, and the other is used for spraying the gold nanoparticle powder with different thicknesses.
Further, the particle size of the gold nanoparticles is 15 nm-25 nm.
Furthermore, the thickness of the spraying bottom of the gold nano powder is 0 nm-600 nm.
Further, the particle size of the PS beads is 220 nm-690 nm.
Further, the preparation method of the suspension of the small balls with different particle sizes comprises the following steps: dissolving the white PS bead powder with different particle sizes in absolute ethyl alcohol to prepare suspension of the beads with different particle sizes.
Compared with the prior art, the invention has the following beneficial effects:
the method is based on a structural color film formed by PS pellets, and gold nano powder with different thicknesses is sprayed in uniformly divided pellet arrays to form pellet gaps; the color is changed by utilizing the ordered array formed by the PS beads and the local surface plasmon resonance characteristic of the gold nanoparticles, namely the spectral absorption effect on an ultraviolet visible light region.
Drawings
FIG. 1 is a top view of the present invention uniformly differentiating the print locations into different regions;
FIG. 2 is a cross-sectional view of the present invention sprayed on a substrate using three nozzles containing solutions of PS beads of different particle sizes;
FIG. 3 is a cross-sectional view of a monolayer array of PS beads of different particle sizes according to the present invention;
FIG. 4 is a cross-sectional view of a single-layer array composed of PS beads of the same particle size and coated with gold nanoparticles of different thicknesses in various regions according to the present invention;
FIG. 5 is a cross-sectional view of a single-layer array formed by PS beads with different particle sizes and sprayed with gold nanoparticles of the same thickness in each region according to the present invention;
FIG. 6 is a cross-sectional view of a single-layer array formed by PS beads with different particle sizes and sprayed with gold nanoparticles with different thicknesses in each region according to the present invention;
FIG. 7 is a schematic view of a suspension formed by spraying PS beads with different particle sizes on gold powder.
Detailed Description
In order to make the technical means, the creation characteristics, the achievement purposes and the effects of the invention easy to understand, the invention is further described with the specific embodiments.
As shown in fig. 1-6, a color inkjet printing method based on a polystyrene microsphere array structure, the method comprising:
dissolving white PS (polystyrene) microsphere powder with different particle sizes in absolute ethyl alcohol to prepare a plurality of suspensions with certain concentration and containing the microspheres with different particle sizes, dividing different areas on a substrate to be printed, and spraying different suspensions to each area through a nozzle according to color requirements; after the solution is spread and evaporated, a layer of film array consisting of small balls with different particle sizes can be obtained on the surface of the substrate;
at the moment, gold nanoparticle powder with different thicknesses is sprayed on the surface of the regularly divided small ball array through another nozzle to be in the gap between the adjacent small balls;
PS pellets with different grain diameters and gold nano powder with different thicknesses are sprayed on each area, so that the color of each area is changed, and color printing is realized;
for the method, the specific preparation steps of the invention are as follows:
a) the printing positions are uniformly divided into several regions. The positions to be printed are evenly divided into 2500 squares as shown in fig. 1.
b) Dissolving polystyrene microspheres with different particle sizes in absolute ethyl alcohol to form polystyrene ethanol suspension with a certain concentration, and placing the prepared polystyrene ethanol suspension with different particle sizes in different ink boxes, wherein PS microsphere suspensions with the particle sizes of 220nm, 450nm and 690nm are respectively prepared as shown in FIG. 2.
c) And uniformly spraying a thin layer to the surfaces of different areas from a nozzle according to the color requirement of a required pattern. After the solvent is evaporated at room temperature, a film composed of an array of PS beads with different particle sizes can be prepared on the surface of the substrate, as shown in fig. 3.
d) According to the color requirement of the required pattern, another nozzle sprays prepared 15 nm-25 nm gold nanoparticle powder in the uniformly divided area to the gap between the adjacent small balls, and in the embodiment, 20nm gold nanoparticle powder is adopted;
e) adjusting the spraying thickness of the gold nanoparticles in different blocks according to the spraying time, so as to adjust the spectral absorption effect of a visible light area to realize color change, wherein in the step, the spraying thickness of the gold nanoparticles is 0-600 nm; as shown in fig. 4, 5, and 6.
The above description is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, several modifications and variations can be made without departing from the technical principle of the present invention, and these modifications and variations should also be regarded as the protection scope of the present invention.
Claims (6)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111001867.5A CN113829759B (en) | 2021-08-30 | 2021-08-30 | Color inkjet printing method based on polystyrene microsphere array structure |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111001867.5A CN113829759B (en) | 2021-08-30 | 2021-08-30 | Color inkjet printing method based on polystyrene microsphere array structure |
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| Publication Number | Publication Date |
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| CN113829759A true CN113829759A (en) | 2021-12-24 |
| CN113829759B CN113829759B (en) | 2023-02-28 |
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| CN202111001867.5A Active CN113829759B (en) | 2021-08-30 | 2021-08-30 | Color inkjet printing method based on polystyrene microsphere array structure |
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Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105206175A (en) * | 2015-10-23 | 2015-12-30 | 浙江大学 | Anti-counterfeit label based on patterned metal nanocomposite and production method of anti-counterfeit label |
| CN106042377A (en) * | 2016-06-03 | 2016-10-26 | 陕西科技大学 | Colorating method for dynamic structure of colorful coating of 3D-printed product |
| CN106626376A (en) * | 2016-11-07 | 2017-05-10 | 广东工业大学 | Color inkjet three-dimensional printing method |
| CN106905552A (en) * | 2017-02-23 | 2017-06-30 | 苏州贝彩纳米科技有限公司 | A kind of method of utilization microballoon to 3D printing product coloring |
| CN107688015A (en) * | 2017-07-13 | 2018-02-13 | 北京工业大学 | A kind of preparation method for being used to strengthen the transparent dielectric microballoon fexible film of Raman diffused light spectral intensity |
| CN109031476A (en) * | 2018-08-30 | 2018-12-18 | 浙江理工大学 | Have both the preparation method of stable structure and brightly painted patterning photon crystal structure chromogenic materials |
| CN110023087A (en) * | 2016-11-17 | 2019-07-16 | 3M创新有限公司 | Composition comprising polymer and ceramic microspheres and the method for preparing three-dimensional article |
| CN110449329A (en) * | 2019-08-08 | 2019-11-15 | 吉林大学 | A kind of preparation method of the non-iris schemochrome film of super-hydrophobicity |
| CN110983424A (en) * | 2019-11-19 | 2020-04-10 | 上海交通大学 | Method for preparing large-area crack-free thick film photonic crystal on porous substrate |
| CN112048213A (en) * | 2019-06-05 | 2020-12-08 | 上海大学 | A kind of inkjet 3D printing material, ink and preparation method thereof |
-
2021
- 2021-08-30 CN CN202111001867.5A patent/CN113829759B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105206175A (en) * | 2015-10-23 | 2015-12-30 | 浙江大学 | Anti-counterfeit label based on patterned metal nanocomposite and production method of anti-counterfeit label |
| CN106042377A (en) * | 2016-06-03 | 2016-10-26 | 陕西科技大学 | Colorating method for dynamic structure of colorful coating of 3D-printed product |
| CN106626376A (en) * | 2016-11-07 | 2017-05-10 | 广东工业大学 | Color inkjet three-dimensional printing method |
| CN110023087A (en) * | 2016-11-17 | 2019-07-16 | 3M创新有限公司 | Composition comprising polymer and ceramic microspheres and the method for preparing three-dimensional article |
| CN106905552A (en) * | 2017-02-23 | 2017-06-30 | 苏州贝彩纳米科技有限公司 | A kind of method of utilization microballoon to 3D printing product coloring |
| CN107688015A (en) * | 2017-07-13 | 2018-02-13 | 北京工业大学 | A kind of preparation method for being used to strengthen the transparent dielectric microballoon fexible film of Raman diffused light spectral intensity |
| CN109031476A (en) * | 2018-08-30 | 2018-12-18 | 浙江理工大学 | Have both the preparation method of stable structure and brightly painted patterning photon crystal structure chromogenic materials |
| CN112048213A (en) * | 2019-06-05 | 2020-12-08 | 上海大学 | A kind of inkjet 3D printing material, ink and preparation method thereof |
| CN110449329A (en) * | 2019-08-08 | 2019-11-15 | 吉林大学 | A kind of preparation method of the non-iris schemochrome film of super-hydrophobicity |
| CN110983424A (en) * | 2019-11-19 | 2020-04-10 | 上海交通大学 | Method for preparing large-area crack-free thick film photonic crystal on porous substrate |
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| CN113829759B (en) | 2023-02-28 |
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Application publication date: 20211224 Assignee: Nanjing changchengyang Network Technology Co.,Ltd. Assignor: Nanjing University of Information Science and Technology Contract record no.: X2024980008036 Denomination of invention: Color inkjet printing method based on polystyrene microsphere array structure Granted publication date: 20230228 License type: Common License Record date: 20240625 |
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Application publication date: 20211224 Assignee: Jiangsu Wanrui high tech Material Technology Co.,Ltd. Assignor: Nanjing University of Information Science and Technology Contract record no.: X2024980015205 Denomination of invention: Color inkjet printing method based on polystyrene microsphere array structure Granted publication date: 20230228 License type: Common License Record date: 20240913 |
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