CN113818022A - Cleaning method and system for microporous titanium alloy pipe - Google Patents

Cleaning method and system for microporous titanium alloy pipe Download PDF

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Publication number
CN113818022A
CN113818022A CN202111228641.9A CN202111228641A CN113818022A CN 113818022 A CN113818022 A CN 113818022A CN 202111228641 A CN202111228641 A CN 202111228641A CN 113818022 A CN113818022 A CN 113818022A
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CN
China
Prior art keywords
titanium alloy
alloy pipe
microporous titanium
pickling
cleaning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202111228641.9A
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Chinese (zh)
Inventor
王海
刘艺
柳红豆
杨晓康
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xi'an Saite Simai Titanium Industry Co ltd
Original Assignee
Xi'an Saite Simai Titanium Industry Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xi'an Saite Simai Titanium Industry Co ltd filed Critical Xi'an Saite Simai Titanium Industry Co ltd
Priority to CN202111228641.9A priority Critical patent/CN113818022A/en
Publication of CN113818022A publication Critical patent/CN113818022A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/10Other heavy metals
    • C23G1/106Other heavy metals refractory metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • B08B3/12Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration by sonic or ultrasonic vibrations
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G3/00Apparatus for cleaning or pickling metallic material
    • C23G3/04Apparatus for cleaning or pickling metallic material for cleaning pipes

Abstract

The invention discloses a cleaning method and a system of a microporous titanium alloy pipe, wherein the microporous titanium alloy pipe to be pickled is fixed in a pickling container; wherein, the microporous titanium alloy pipe is arranged in an inclined manner from top to bottom; adding the pickling solution into a pickling container until the liquid level of the pickling solution is higher than the top end of the microporous titanium alloy pipe; vibrating the pickling solution until the pickling of the microporous titanium alloy is completed; discharging the pickling solution from the pickling container, adding clear water into the pickling container, washing the microporous titanium alloy pipe with water, and drying in the air to obtain a cleaned microporous titanium alloy pipe; according to the invention, the microporous titanium alloy pipe is obliquely placed in the cleaning tank up and down, the cleaning liquid is vibrated, the cleaning liquid generates turbulence under the action of the vibration force, and then permeates into the inner hole through the opening at the upper end of the microporous titanium alloy pipe, and the self-weight action of the cleaning liquid is combined, so that the cleaning liquid flows from the opening at the upper end to the opening at the lower end, thereby realizing the cleaning of the microporous titanium alloy pipe and improving the pickling effect.

Description

Cleaning method and system for microporous titanium alloy pipe
Technical Field
The invention belongs to the technical field of titanium alloy pipe cleaning, and particularly relates to a cleaning method and a system for a microporous titanium alloy pipe.
Background
The titanium alloy pipe is made of titanium alloy, has high mechanical property and excellent stamping property, can be welded in various forms, has the strength of a welded joint reaching 90 percent of that of a base metal, and has good cutting processing property. The titanium tube has high corrosion resistance to chloride, sulfide and ammonia. Titanium has higher corrosion resistance in seawater than aluminum alloy, stainless steel and nickel-based alloy. The titanium also has strong water impact resistance.
The titanium alloy pipe generally needs to be subjected to surface pickling in the production and processing process or before the finished product leaves a factory, and the pickling process is usually arranged before and after intermediate heat treatment (or called annealing). Wherein, the acid cleaning before the heat treatment mainly aims at removing an oxide layer generated in the processing process and simultaneously has the function of removing oil; and acid washing after heat treatment is mainly used for removing an oxide layer generated in the heat treatment stage and avoiding the influence of oxide inclusion in subsequent processing on the performance of the pipe. The acid cleaning of the finished product is generally bright acid cleaning, and aims to improve the surface quality of the pipe.
The microporous titanium alloy pipe generally refers to a pipe with the inner diameter less than or equal to 2mm, the surface tension effect of the conventional titanium alloy pipe has little influence, and acid liquor can smoothly flow in the pipe to realize the pickling process. However, the surface tension of the microporous titanium alloy pipe (the inner diameter of the pipe is less than 2mm) is obviously enhanced, and acid liquid is difficult to flow in the pipe and even can not flow into the inner hole of the pipe, so that the pickling effect is poor.
Disclosure of Invention
The invention aims to provide a method and a system for cleaning a microporous titanium alloy pipe, so that cleaning acid liquid can smoothly enter the microporous titanium alloy pipe and flow, and the pickling effect is improved.
The invention adopts the following technical scheme: a cleaning method of a microporous titanium alloy pipe comprises the following steps:
fixing the microporous titanium alloy pipe to be pickled in a pickling container; wherein, the microporous titanium alloy pipe is arranged in an inclined manner from top to bottom;
adding the pickling solution into a pickling container until the liquid level of the pickling solution is higher than the top end of the microporous titanium alloy pipe;
vibrating the pickling solution until the pickling of the microporous titanium alloy is completed;
and discharging the pickling solution from the pickling container, adding clear water into the pickling container, washing the microporous titanium alloy pipe with water, and drying in the air to obtain the cleaned microporous titanium alloy pipe.
Further, vibrating the pickle liquor comprises:
the pickling solution is vibrated by an ultrasonic device attached to the pickling vessel.
Further, the inclination angle of the micropore titanium alloy pipe is 15-30 degrees.
Further, the step of washing and air-drying the microporous titanium alloy pipe comprises the following steps:
vibrating clear water to clean the inner hole of the microporous titanium alloy pipe;
discharging clear water from the pickling vessel;
and (3) blowing air into the inner hole of the microporous titanium alloy pipe by the air blowing pipe towards the port of the inner hole of the microporous titanium alloy pipe until no residual clear water exists in the inner hole of the microporous titanium alloy pipe.
Further, fixing the microporous titanium alloy tube to be pickled in a pickling vessel comprises:
fixing the microporous titanium alloy pipe on a fixing tool;
and installing the fixing tool in the pickling container.
Furthermore, the washing time is 5-10 s.
Furthermore, the time for blowing air into the inner hole of the microporous titanium alloy pipe is 15-30 min.
Furthermore, the inner diameter of the micropore titanium alloy pipe is 0.8-2 mm.
The other technical scheme of the invention is as follows: a cleaning system for a microporous titanium alloy pipe comprises a cleaning tank, wherein an ultrasonic vibration device is arranged on the cleaning tank and used for acting on cleaning liquid in the cleaning tank so as to vibrate the cleaning liquid;
a fixing tool for the microporous titanium alloy pipe is arranged in the cleaning tank and used for fixing the microporous titanium alloy pipe to be cleaned, so that the microporous titanium alloy pipe is obliquely arranged in the cleaning tank up and down;
the cleaning tank is also respectively connected with a clear water pipeline for putting in/discharging clear water and an acid liquor pipeline for putting in/discharging acid washing liquor.
The cleaning tank further comprises an air blowing pipe, wherein the air blowing pipe faces one end of the microporous titanium alloy pipe in the cleaning tank so as to blow air into an inner hole of the microporous titanium alloy pipe, and the air drying of the microporous titanium alloy pipe is realized.
The invention has the beneficial effects that: according to the invention, the microporous titanium alloy pipe is obliquely placed in the cleaning tank up and down, the cleaning liquid is vibrated, the cleaning liquid generates turbulence under the action of the vibration force, and then permeates into the inner hole through the opening at the upper end of the microporous titanium alloy pipe, and the self-weight action of the cleaning liquid is combined, so that the cleaning liquid flows from the opening at the upper end to the opening at the lower end, thereby realizing the cleaning of the microporous titanium alloy pipe and improving the pickling effect.
Drawings
FIG. 1 is a flow chart of a method for cleaning a microporous titanium alloy pipe according to the present invention;
FIG. 2 is a schematic view showing the flowing direction of the cleaning liquid under the action of no vibration or vibration in the embodiment of the invention;
FIG. 3 is a schematic structural diagram of a cleaning system for a microporous titanium alloy pipe according to the present invention.
Wherein: 1. an air blowing pipe; 2. a cleaning tank; 3. an ultrasonic vibration device; 4. a first centrifugal pump; 5. a second centrifugal pump; 6. an acid mixing tank; 7. a clear water tank.
Detailed Description
The present invention will be described in detail below with reference to the accompanying drawings and specific embodiments.
For microporous titanium alloy pipes, namely pipes with the inner diameter of 2mm or less, a surface layer is formed when acid liquor is contacted with gas in the pipes in the pickling process, molecules in the liquid surface layer are sparser than those in the liquid, and therefore the molecules are acted by force directed to the inside of the liquid, so that the liquid surface has a contraction tendency; meanwhile, the liquid level is automatically contracted under the influence of the energy among liquid molecules, so that the surface area of the acid liquid is reduced as much as possible, the acid liquid does not flow into the inner hole of the titanium alloy pipe, and the acid washing cannot be realized or has poor acid washing effect.
The invention discloses a method for cleaning a microporous titanium alloy pipe, which comprises the following steps of:
fixing the microporous titanium alloy pipe to be pickled in a pickling container; wherein, the microporous titanium alloy pipe is arranged in an inclined manner from top to bottom; adding the pickling solution into a pickling container until the liquid level of the pickling solution is higher than the top end of the microporous titanium alloy pipe; vibrating the pickling solution until the pickling of the microporous titanium alloy is completed; and discharging the pickling solution from the pickling container, adding clear water into the pickling container, washing the microporous titanium alloy pipe with water, and drying in the air to obtain the cleaned microporous titanium alloy pipe.
According to the invention, the microporous titanium alloy pipe is obliquely placed in the cleaning tank up and down, the cleaning liquid is vibrated, the cleaning liquid generates turbulence under the action of the vibration force, and then permeates into the inner hole through the opening at the upper end of the microporous titanium alloy pipe, and the self-weight action of the cleaning liquid is combined, so that the cleaning liquid flows from the opening at the upper end to the opening at the lower end, thereby realizing the cleaning of the microporous titanium alloy pipe and improving the pickling effect.
Specifically, in the embodiment of the present invention, the pickling solution is vibrated by an ultrasonic device attached to the pickling tank. Of course, a vibration pump and the like can be added, and the adjustment can be carried out according to actual requirements.
In the embodiment of the invention, in order to further improve the probability of the pickling solution entering the inner hole, the inclination angle of the microporous titanium alloy pipe is 15-30 degrees.
As a specific implementation manner, the washing and air-drying of the microporous titanium alloy pipe material comprises the following steps:
vibrating clear water to clean the inner hole of the microporous titanium alloy pipe; discharging clear water from the pickling vessel; and (3) blowing air into the inner hole of the microporous titanium alloy pipe by the air blowing pipe towards the port of the inner hole of the microporous titanium alloy pipe until no residual clear water exists in the inner hole of the microporous titanium alloy pipe. The air drying is carried out by using the blowpipe, so that the pickling progress can be accelerated, and the working procedure time can be shortened.
Because the bottom surfaces of the conventional pickling tanks are all flat surfaces, the step of fixing the microporous titanium alloy pipe to be pickled in the pickling container comprises the following steps: fixing the microporous titanium alloy pipe on a fixing tool; and installing the fixing tool in the pickling container. The fixed tooling is used for fixedly mounting the micropore titanium alloy pipe, so that the reconstruction of a pickling tank is avoided, and the reconstruction cost is reduced.
Specifically, the washing time is 5-10 s. And blowing air into the inner hole of the microporous titanium alloy pipe for 15-30 min. Moreover, the microporous titanium alloy pipe provided by the invention specifically refers to a microporous titanium alloy pipe with an inner diameter of 0.8-2 mm.
The invention has novel and reasonable design, low investment cost, simple pickling step, convenient realization and good pickling effect, can simply and conveniently realize the cleaning process of the inner hole of the microporous titanium alloy pipe with the inner diameter of 0.8-2.0 mm, and can simultaneously realize the cleaning process of simultaneously cleaning the inner holes of a plurality of microporous titanium alloy pipes at one time.
According to the invention, a pipe to be cleaned is fixed on a tool with a certain inclination (15-30 degrees), and acid liquor is forced into an inner hole of the microporous titanium alloy pipe under the action of gravity and ultrasonic waves, so that the acid cleaning process is completed. Specifically, the inclination of the tool is given, the acid liquor can flow from the high end of the pipe to the low end of the pipe under the action of gravity, in addition, as shown in fig. 2, when the ultrasonic wave enables the acid liquor to flow from the high end of the pipe to the low end of the pipe, the flow mode of the titanium alloy inner hole is changed from laminar flow to turbulent flow, namely the acid liquor enters the inner hole of the micropore titanium alloy pipe under the action of gravity and ultrasonic wave, and the acid washing purpose is achieved. After the acid cleaning is finished, the switching pump cleans the inner surface and the outer surface of the pipe by using water, and the cleaning time is 5-10 s. And after washing, blowing the inner hole of the titanium alloy pipe by using gas until the inner hole of the titanium alloy pipe is dried, wherein the blowing time is 15-30 min, and finally obtaining the cleaned titanium alloy pipe.
The invention also discloses a cleaning system of the microporous titanium alloy pipe, which comprises a cleaning tank 2, wherein an ultrasonic vibration device 3 is arranged on the cleaning tank 2, and the ultrasonic vibration device 3 is used for acting on the cleaning liquid in the cleaning tank 2 so as to vibrate the cleaning liquid, as shown in figure 3; a fixing tool for the microporous titanium alloy pipe is arranged in the cleaning tank 2, and the fixing tool is used for fixing the microporous titanium alloy pipe to be cleaned, so that the microporous titanium alloy pipe is obliquely arranged in the cleaning tank 2 up and down; the cleaning tank 2 is also connected with a clear water pipeline for putting in/discharging clear water and an acid liquor pipeline for putting in/discharging acid wash respectively.
The system can realize the acid washing of the microporous titanium alloy pipe. This system reasonable in design, simple structure, processing preparation is simple and convenient and the input cost is low, only need to fix micropore titanium alloy tubular product on certain inclination's frock (15 ~ 30%), the submergence is in the ultrasonic cleaning case, through the effect of gravity and the flowing automatically of pickle, force inside the pickle gets into micropore titanium alloy tubular product, accomplish the pickling process, the pickling in-process, the frock plays the fixed action, the supersound makes the pickle flow in-process change the turbulent flow into by the laminar flow at the mobile mode of titanium alloy hole.
For the cleaning tank of this embodiment, specifically square container, once can receive many micropore titanium alloy tubular products, the specification of micropore titanium alloy tubular product can be 0.8 ~ 2.0mm in internal diameter, external diameter 4.0 ~ 20.0mm, length 1.5 ~ 3.0 m.
In the embodiment, the device further comprises an air blowing pipe 1, wherein the air blowing pipe 1 faces one end of the microporous titanium alloy pipe in the cleaning tank 2 to blow air into an inner hole of the microporous titanium alloy pipe, so that air drying of the microporous titanium alloy pipe is realized.
In addition, the bottom of the cleaning tank 2 is connected to the clean water tank 7 through the cleaning pipeline and the second centrifugal pump 5 in sequence, and is connected to the acid preparation tank 6 through the acid liquor pipeline and the first centrifugal pump 4 in sequence, so that the cleaning solution can be conveniently prepared. In addition, washing tank 2 can also be connected with drain pipe and row's acid pipe, carries out recycle to the washing liquid through independently designed drain pipe and row's acid pipe, can reduction in production cost, can also make things convenient for the later stage to the maintenance of system.

Claims (10)

1. The cleaning method of the microporous titanium alloy pipe is characterized by comprising the following steps:
fixing the microporous titanium alloy pipe to be pickled in a pickling container; wherein the microporous titanium alloy pipe is arranged in an inclined manner from top to bottom;
adding a pickling solution into the pickling container until the liquid level of the pickling solution is higher than the top end of the microporous titanium alloy pipe;
vibrating the pickling solution until the pickling of the microporous titanium alloy is completed;
and discharging the pickling solution from the pickling container, adding clear water into the pickling container, washing the microporous titanium alloy pipe with water, and drying the microporous titanium alloy pipe in the air to obtain the cleaned microporous titanium alloy pipe.
2. The method of claim 1, wherein vibrating the pickling solution comprises:
the pickling solution is vibrated by an ultrasonic device attached to the pickling vessel.
3. The method for cleaning the microporous titanium alloy pipe according to claim 2, wherein the inclination angle of the microporous titanium alloy pipe is 15-30 °.
4. The method for cleaning the microporous titanium alloy pipe material according to any one of claims 1 to 3, wherein the step of washing and air-drying the microporous titanium alloy pipe material by water comprises the following steps:
vibrating the clean water to clean the inner hole of the microporous titanium alloy pipe;
discharging the clean water from the pickling vessel;
and (3) enabling the air blowing pipe to face the port of the inner hole of the microporous titanium alloy pipe, and blowing air into the inner hole of the microporous titanium alloy pipe until no residual clear water exists in the inner hole of the microporous titanium alloy pipe.
5. The method of claim 4, wherein the step of securing the microporous titanium alloy tubing to be pickled in a pickling vessel comprises:
fixing the microporous titanium alloy pipe on a fixing tool;
and installing the fixing tool in the pickling container.
6. The method for cleaning the microporous titanium alloy pipe material according to claim 1 or 5, wherein the water washing time is 5-10 s.
7. The method for cleaning the microporous titanium alloy pipe as claimed in claim 6, wherein the time for blowing air into the inner hole of the microporous titanium alloy pipe is 15-30 min.
8. The method for cleaning the microporous titanium alloy pipe material as claimed in claim 1 or 7, wherein the inner diameter of the microporous titanium alloy pipe material is 0.8-2 mm.
9. The cleaning system for the microporous titanium alloy pipe is characterized by comprising a cleaning tank (2), wherein an ultrasonic vibration device (3) is mounted on the cleaning tank (2), and the ultrasonic vibration device (3) is used for acting on cleaning liquid in the cleaning tank (2) so as to vibrate the cleaning liquid;
a fixing tool for the microporous titanium alloy pipe is arranged in the cleaning tank (2), and the fixing tool is used for fixing the microporous titanium alloy pipe to be cleaned so that the microporous titanium alloy pipe is obliquely arranged in the cleaning tank (2) up and down;
the cleaning tank (2) is also respectively connected with a clear water pipeline for putting in/discharging clear water and an acid liquor pipeline for putting in/discharging acid washing liquor.
10. A microporous titanium alloy cleaning system according to claim 9, further comprising an air blowing pipe (1), wherein the air blowing pipe (1) faces one end of the microporous titanium alloy pipe in the cleaning tank (2) to blow air into the inner hole of the microporous titanium alloy pipe, so as to achieve air drying of the microporous titanium alloy pipe.
CN202111228641.9A 2021-10-21 2021-10-21 Cleaning method and system for microporous titanium alloy pipe Pending CN113818022A (en)

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Application Number Priority Date Filing Date Title
CN202111228641.9A CN113818022A (en) 2021-10-21 2021-10-21 Cleaning method and system for microporous titanium alloy pipe

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Application Number Priority Date Filing Date Title
CN202111228641.9A CN113818022A (en) 2021-10-21 2021-10-21 Cleaning method and system for microporous titanium alloy pipe

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Publication Number Publication Date
CN113818022A true CN113818022A (en) 2021-12-21

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03281793A (en) * 1990-03-30 1991-12-12 Shimada Phys & Chem Ind Co Ltd Ultrasonic cleaning and drying device
JP2004255258A (en) * 2003-02-25 2004-09-16 Nippon Steel Corp Ultrasonic cleaner and ultrasonic cleaning method
KR20050120841A (en) * 2004-06-21 2005-12-26 (주)리치스톤 The vacuum suction ultrasonic wave washing method and its equipment of a detailed hole nozzle
CN201012362Y (en) * 2007-03-19 2008-01-30 西部钛业有限责任公司 Ultrasonic cleaning groove for removing oil for the titanium tube
CN202199544U (en) * 2011-07-26 2012-04-25 张家港华裕有色金属材料有限公司 Ultrasonic wave cleaner for titanium and titanium alloy pipe
JP2016073896A (en) * 2014-10-03 2016-05-12 アクトファイブ株式会社 Ultrasonic cleaning device
CN107502900A (en) * 2017-09-11 2017-12-22 苏州盈腾五金制品有限公司 A kind of ultrasonic wave acid cleaning process of cast iron hardware
CN112739465A (en) * 2018-09-26 2021-04-30 日本制铁株式会社 Method and apparatus for cleaning metal pipe
CN216303993U (en) * 2021-10-21 2022-04-15 西安赛特思迈钛业有限公司 Cleaning system of micropore titanium alloy tubular product

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03281793A (en) * 1990-03-30 1991-12-12 Shimada Phys & Chem Ind Co Ltd Ultrasonic cleaning and drying device
JP2004255258A (en) * 2003-02-25 2004-09-16 Nippon Steel Corp Ultrasonic cleaner and ultrasonic cleaning method
KR20050120841A (en) * 2004-06-21 2005-12-26 (주)리치스톤 The vacuum suction ultrasonic wave washing method and its equipment of a detailed hole nozzle
CN201012362Y (en) * 2007-03-19 2008-01-30 西部钛业有限责任公司 Ultrasonic cleaning groove for removing oil for the titanium tube
CN202199544U (en) * 2011-07-26 2012-04-25 张家港华裕有色金属材料有限公司 Ultrasonic wave cleaner for titanium and titanium alloy pipe
JP2016073896A (en) * 2014-10-03 2016-05-12 アクトファイブ株式会社 Ultrasonic cleaning device
CN107502900A (en) * 2017-09-11 2017-12-22 苏州盈腾五金制品有限公司 A kind of ultrasonic wave acid cleaning process of cast iron hardware
CN112739465A (en) * 2018-09-26 2021-04-30 日本制铁株式会社 Method and apparatus for cleaning metal pipe
CN216303993U (en) * 2021-10-21 2022-04-15 西安赛特思迈钛业有限公司 Cleaning system of micropore titanium alloy tubular product

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