CN1138080A - 玻璃防霜液 - Google Patents
玻璃防霜液 Download PDFInfo
- Publication number
- CN1138080A CN1138080A CN 95106847 CN95106847A CN1138080A CN 1138080 A CN1138080 A CN 1138080A CN 95106847 CN95106847 CN 95106847 CN 95106847 A CN95106847 A CN 95106847A CN 1138080 A CN1138080 A CN 1138080A
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- CN
- China
- Prior art keywords
- frost
- liquor
- total amount
- soap
- adopts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 15
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 7
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 7
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000011187 glycerol Nutrition 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 6
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims abstract description 6
- 235000019345 sodium thiosulphate Nutrition 0.000 claims abstract description 6
- 239000003960 organic solvent Substances 0.000 claims abstract description 5
- 230000000694 effects Effects 0.000 claims abstract description 3
- 239000002304 perfume Substances 0.000 claims abstract 3
- 239000000344 soap Substances 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 239000003112 inhibitor Substances 0.000 claims description 6
- 239000013543 active substance Substances 0.000 claims description 5
- 235000013599 spices Nutrition 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229940114930 potassium stearate Drugs 0.000 claims description 4
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 claims description 4
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims 3
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims 2
- 235000011150 stannous chloride Nutrition 0.000 claims 2
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 claims 2
- 238000002156 mixing Methods 0.000 abstract description 2
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- 241001074085 Scophthalmus aquosus Species 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000010257 thawing Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 230000036651 mood Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
玻璃防霜液适用于机动车辆、学校、医院、车站候车室等公共场所的门窗玻璃防霜。防霜液由表面活性剂硬脂酸钠或硬脂酸钾、防冻剂甘油或异丙醇、抗氧剂大苏打、展开剂正丁醇或正戊醇、有机溶剂a-蒎烯和少量香料混合配制而成。本发明配制操作工艺简单,原料易得,成本低廉,使用方便,防霜效果明显,对人安全无毒,无腐蚀性,不污染环境。
Description
本发明采用表面活性剂、展开剂、抗氧剂和有机溶剂为原料,加少量香料混合配制成防霜液。它适用于机动车辆、学校、医院、车站候车室等公共场所的门窗玻璃防霜。本发明属于化工工艺方面的技术。
在此之前,已有CN1060670、CN1048052、CN8610679、CN1076711等有关汽车玻璃防霜除霜消冰的专利申请,其中大多数侧重于解决除霜消冰方面的问题,有的配方复杂,成本高,不便于推广生产。在寒冷的冬季,行驶中的机动车辆(尤其是客车)、正在上课的教室、医院的病房和车站的候车室等公共场所的门窗玻璃,由于其内外温差较大,人们呼出的气体附着在玻璃上遇冷成霜。冰霜挡住了司机的视线,影响汽车的娄全行驶、乘客的情绪、学生学习的积极性;和病人的康复等等。鉴此,本发明的目的,旨在提供一种成本低、使用方便、效果显著的适用于玻璃(尤其是适用行驶中机动车辆的玻璃)的防霜液。
本防霜液喷擦在玻璃上,外界温度在0℃至-40℃条件下不结霜,可维持1-15天(以上)。
本发明利用甘油吸湿后降低冰点的防冻原理,采用表面活性剂、展开剂和抗氧剂,加速肥皂溶解,防止其氧化凝固,便于喷擦,以保证防霜液贮存时的稳定性。
本防霜液的配方及工艺流程为:
a.配方成份及其剂量:
10%-45%硬脂酸钠、或硬脂酸钾(也可用肥皂替代)50-100ml;甘油(或异丙醇)20-50ml(根据所要求的冰点高低而定);正丁醇(或正戊醇)10-30ml(根据肥皂的量而定);大苏打占总量的5-10%(也可省去不用);a-蒎烯5-20%(也可省去不用);香料0.1-0.5%。
b.配制工艺流程为:
取30%的肥皂(或软皂)58ml加大苏打5g,加正丁醇(或正戊醇)12ml,隔水加热便肥皂熔溶为止,加a-蒎烯6ml(也可省去不加),加甘油(或异丙醇)24ml,香料少许,过滤,分装。
本防霜液与目前同类产品相比,具有所需原料易得、配制工艺简单、成本造价低廉、使用操作简便、防霜效果显著、对人安全无毒、对门窗无腐蚀性、对环境无污染,是目前较为理想的玻璃防霜液。
Claims (5)
1.玻璃防霜液是由表面活性剂、防冻剂、抗氧剂、展开剂、有机溶剂和少量香料配合而成。其组成特征是:
a.表面活性剂采用硬脂酸钠或硬脂酸钾;
b.防冻剂采用甘油或异丙醇;
c.抗氧剂采用大苏打或氯化亚锡;
d.展开剂采用正丁醇或正戊醇;
e.有机溶剂采用a-蒎烯,加少量香料。
2.按权利要求1所述的配合液,其中硬脂酸钠或硬脂酸钾占配合液总量的10-45%;甘油或异丙醇占总量的10-70%;大苏打或氯化亚锡占总量的5-10%;正丁醇或正戊醇占总量的10-30%;a-蒎烯占总量的10-20%;香料占0.1-0.5%。
3.按权利要求1配合液的工艺流程为:
表面活性剂(加抗氧剂)--->加展开剂--->隔水加热熔溶--->加有机溶剂--->加防冻剂--->加香料--->过滤--->分装。
4.为降低成本,防霜液配方中的硬脂酸钠或硬脂酸钾可用肥皂(或软皂)替代。也可省去抗氧剂大苏打和有机溶剂a-蒎烯,不影响防霜效果。
5.按权利要求4所述,防霜液的组成和工艺流程为:
a.防霜液的组成:
肥皂(或软皂)占总量的10-45%;甘油(或异丙醇)占10-70%;正
丁醇(或正戊醇)占10-30%;香料占0.1-0.5%。
b.工艺流程为:
肥皂-->加展开剂-->隔水加热熔溶-->加防冻剂-->加香料-->
过滤-->分装。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 95106847 CN1138080A (zh) | 1995-06-14 | 1995-06-14 | 玻璃防霜液 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 95106847 CN1138080A (zh) | 1995-06-14 | 1995-06-14 | 玻璃防霜液 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1138080A true CN1138080A (zh) | 1996-12-18 |
Family
ID=5076081
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 95106847 Pending CN1138080A (zh) | 1995-06-14 | 1995-06-14 | 玻璃防霜液 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1138080A (zh) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004039910A3 (en) * | 2002-10-28 | 2004-10-21 | Battelle Memorial Institute | Biobased deicing/anti-icing fluids |
| WO2005105945A3 (en) * | 2004-04-28 | 2005-12-15 | Battelle Memorial Institute | Deicing/anti-icing fluids |
| US8562854B2 (en) | 2010-02-17 | 2013-10-22 | Battelle Memorial Institute | Compositions for deicing/anti-icing |
| US9080092B2 (en) | 2010-02-17 | 2015-07-14 | Battelle Memorial Institute | Compositions for deicing/anti-icing |
| US9243176B2 (en) | 2010-02-17 | 2016-01-26 | Battelle Memorial Institute | Compositions for deicing/anti-icing |
-
1995
- 1995-06-14 CN CN 95106847 patent/CN1138080A/zh active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004039910A3 (en) * | 2002-10-28 | 2004-10-21 | Battelle Memorial Institute | Biobased deicing/anti-icing fluids |
| US7105105B2 (en) | 2002-10-28 | 2006-09-12 | Battelle Memorial Institute | Deicing/anti-icing fluids |
| US7169321B2 (en) | 2002-10-28 | 2007-01-30 | Battelle Memorial Institute | Biobased deicing/anti-icing fluids |
| EP2264116A3 (en) * | 2002-10-28 | 2012-07-18 | Battelle Memorial Institute | Biobased deicing/anti-icing fluids |
| NO340830B1 (no) * | 2002-10-28 | 2017-06-26 | Battelle Memorial Institute | Rullebaneavisningsfluid |
| WO2005105945A3 (en) * | 2004-04-28 | 2005-12-15 | Battelle Memorial Institute | Deicing/anti-icing fluids |
| US8562854B2 (en) | 2010-02-17 | 2013-10-22 | Battelle Memorial Institute | Compositions for deicing/anti-icing |
| US9080092B2 (en) | 2010-02-17 | 2015-07-14 | Battelle Memorial Institute | Compositions for deicing/anti-icing |
| US9243176B2 (en) | 2010-02-17 | 2016-01-26 | Battelle Memorial Institute | Compositions for deicing/anti-icing |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |