CN113767159A - Reversible thermochromic microcapsule pigments - Google Patents
Reversible thermochromic microcapsule pigments Download PDFInfo
- Publication number
- CN113767159A CN113767159A CN202080025196.3A CN202080025196A CN113767159A CN 113767159 A CN113767159 A CN 113767159A CN 202080025196 A CN202080025196 A CN 202080025196A CN 113767159 A CN113767159 A CN 113767159A
- Authority
- CN
- China
- Prior art keywords
- microcapsule pigment
- compound
- thermal discoloration
- reversible thermal
- reversible
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000002441 reversible effect Effects 0.000 title claims abstract description 108
- 239000000049 pigment Substances 0.000 title claims abstract description 63
- 239000003094 microcapsule Substances 0.000 title claims abstract description 57
- -1 hydroxyphenyl acetate compound Chemical class 0.000 claims abstract description 154
- 238000002845 discoloration Methods 0.000 claims abstract description 82
- 239000000203 mixture Substances 0.000 claims abstract description 66
- 150000001875 compounds Chemical class 0.000 claims abstract description 37
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 18
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 16
- 238000010438 heat treatment Methods 0.000 claims abstract description 15
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 13
- 239000001257 hydrogen Substances 0.000 claims abstract description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000012429 reaction media Substances 0.000 claims abstract description 7
- 150000008282 halocarbons Chemical class 0.000 claims abstract description 6
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 5
- 230000027756 respiratory electron transport chain Effects 0.000 claims abstract description 5
- 238000006276 transfer reaction Methods 0.000 claims abstract description 5
- 239000007788 liquid Substances 0.000 claims description 14
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 5
- 150000002170 ethers Chemical class 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 230000008859 change Effects 0.000 abstract description 7
- 238000004040 coloring Methods 0.000 abstract description 2
- 239000002245 particle Substances 0.000 description 19
- RHVCAYPGAKFGLL-UHFFFAOYSA-N 3,4-dihydroxyphenyl acetate Natural products CC(=O)OC1=CC=C(O)C(O)=C1 RHVCAYPGAKFGLL-UHFFFAOYSA-N 0.000 description 16
- 238000011161 development Methods 0.000 description 16
- 239000011248 coating agent Substances 0.000 description 13
- 238000000576 coating method Methods 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 9
- 238000005507 spraying Methods 0.000 description 9
- MEAHFJBYWLCGDM-UHFFFAOYSA-N 2-pentadecylpropanedioic acid Chemical compound CCCCCCCCCCCCCCCC(C(O)=O)C(O)=O MEAHFJBYWLCGDM-UHFFFAOYSA-N 0.000 description 8
- 239000004744 fabric Substances 0.000 description 8
- YGMGJMSLLNODQV-UHFFFAOYSA-N 2-tridecylpropanedioic acid Chemical compound CCCCCCCCCCCCCC(C(O)=O)C(O)=O YGMGJMSLLNODQV-UHFFFAOYSA-N 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000004925 Acrylic resin Substances 0.000 description 6
- 229920000178 Acrylic resin Polymers 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 150000005215 alkyl ethers Chemical class 0.000 description 6
- 239000002518 antifoaming agent Substances 0.000 description 6
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
- 238000007650 screen-printing Methods 0.000 description 6
- 239000006096 absorbing agent Substances 0.000 description 5
- 229940067597 azelate Drugs 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 5
- 238000007645 offset printing Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- QNSFPYSRPPFJGJ-UHFFFAOYSA-N spiro[2-benzofuran-3,5'-chromeno[2,3-d]pyrimidine]-1-one Chemical compound C12=CC=CC=C2OC2=NC=NC=C2C11OC(=O)C2=CC=CC=C21 QNSFPYSRPPFJGJ-UHFFFAOYSA-N 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- SRKUMCYSWLWLLS-UHFFFAOYSA-N docosyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC SRKUMCYSWLWLLS-UHFFFAOYSA-N 0.000 description 4
- 239000003822 epoxy resin Substances 0.000 description 4
- FNAZRRHPUDJQCJ-UHFFFAOYSA-N henicosane Chemical compound CCCCCCCCCCCCCCCCCCCCC FNAZRRHPUDJQCJ-UHFFFAOYSA-N 0.000 description 4
- CBFCDTFDPHXCNY-UHFFFAOYSA-N icosane Chemical compound CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 4
- VKOBVWXKNCXXDE-UHFFFAOYSA-M icosanoate Chemical compound CCCCCCCCCCCCCCCCCCCC([O-])=O VKOBVWXKNCXXDE-UHFFFAOYSA-M 0.000 description 4
- 230000001939 inductive effect Effects 0.000 description 4
- 238000000691 measurement method Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- POOSGDOYLQNASK-UHFFFAOYSA-N tetracosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC POOSGDOYLQNASK-UHFFFAOYSA-N 0.000 description 4
- 239000008096 xylene Substances 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- GWFGDXZQZYMSMJ-UHFFFAOYSA-N Octadecansaeure-heptadecylester Natural products CCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC GWFGDXZQZYMSMJ-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 229940116224 behenate Drugs 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 235000012000 cholesterol Nutrition 0.000 description 3
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 150000004676 glycans Chemical class 0.000 description 3
- WNZQDUSMALZDQF-UHFFFAOYSA-N isobenzofuranone Natural products C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 description 3
- 229940070765 laurate Drugs 0.000 description 3
- 239000004611 light stabiliser Substances 0.000 description 3
- 235000021388 linseed oil Nutrition 0.000 description 3
- 239000000944 linseed oil Substances 0.000 description 3
- 239000003550 marker Substances 0.000 description 3
- 229940105132 myristate Drugs 0.000 description 3
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920001282 polysaccharide Polymers 0.000 description 3
- 239000005017 polysaccharide Substances 0.000 description 3
- 229920005990 polystyrene resin Polymers 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- SPURMHFLEKVAAS-UHFFFAOYSA-N 1-docosene Chemical compound CCCCCCCCCCCCCCCCCCCCC=C SPURMHFLEKVAAS-UHFFFAOYSA-N 0.000 description 2
- ADOBXTDBFNCOBN-UHFFFAOYSA-N 1-heptadecene Chemical compound CCCCCCCCCCCCCCCC=C ADOBXTDBFNCOBN-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- PJLHTVIBELQURV-UHFFFAOYSA-N 1-pentadecene Chemical compound CCCCCCCCCCCCCC=C PJLHTVIBELQURV-UHFFFAOYSA-N 0.000 description 2
- KQYZRAZGIRPQJL-UHFFFAOYSA-N 4-docosoxy-4-oxobutanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCOC(=O)CCC(O)=O KQYZRAZGIRPQJL-UHFFFAOYSA-N 0.000 description 2
- PBWGCNFJKNQDGV-UHFFFAOYSA-N 6-phenylimidazo[2,1-b][1,3]thiazol-5-amine Chemical compound N1=C2SC=CN2C(N)=C1C1=CC=CC=C1 PBWGCNFJKNQDGV-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 229920000858 Cyclodextrin Polymers 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 238000012695 Interfacial polymerization Methods 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 229920001214 Polysorbate 60 Polymers 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical compound OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000004931 aggregating effect Effects 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-M behenate Chemical compound CCCCCCCCCCCCCCCCCCCCCC([O-])=O UKMSUNONTOPOIO-UHFFFAOYSA-M 0.000 description 2
- 229940090958 behenyl behenate Drugs 0.000 description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- HOWGUJZVBDQJKV-UHFFFAOYSA-N docosane Chemical compound CCCCCCCCCCCCCCCCCCCCCC HOWGUJZVBDQJKV-UHFFFAOYSA-N 0.000 description 2
- DGXRZJSPDXZJFG-UHFFFAOYSA-N docosanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCCCCCC(O)=O DGXRZJSPDXZJFG-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011209 electrochromatography Methods 0.000 description 2
- 238000004070 electrodeposition Methods 0.000 description 2
- 238000009503 electrostatic coating Methods 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N ethylene glycol monomethyl ether acetate Natural products COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 238000007646 gravure printing Methods 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- TXOKWXJQVFUUDD-UHFFFAOYSA-N haletazole Chemical compound C1=CC(OCCN(CC)CC)=CC=C1C1=NC2=CC(Cl)=CC=C2S1 TXOKWXJQVFUUDD-UHFFFAOYSA-N 0.000 description 2
- YYLACZAXCCJCJO-UHFFFAOYSA-N heptacos-1-ene Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC=C YYLACZAXCCJCJO-UHFFFAOYSA-N 0.000 description 2
- BJQWYEJQWHSSCJ-UHFFFAOYSA-N heptacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCC BJQWYEJQWHSSCJ-UHFFFAOYSA-N 0.000 description 2
- WTJKUFMLQFLJOT-UHFFFAOYSA-N heptadecan-9-one Chemical compound CCCCCCCCC(=O)CCCCCCCC WTJKUFMLQFLJOT-UHFFFAOYSA-N 0.000 description 2
- NDJKXXJCMXVBJW-UHFFFAOYSA-N heptadecane Chemical compound CCCCCCCCCCCCCCCCC NDJKXXJCMXVBJW-UHFFFAOYSA-N 0.000 description 2
- HMSWAIKSFDFLKN-UHFFFAOYSA-N hexacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC HMSWAIKSFDFLKN-UHFFFAOYSA-N 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- JJOJFIHJIRWASH-UHFFFAOYSA-N icosanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCCCC(O)=O JJOJFIHJIRWASH-UHFFFAOYSA-N 0.000 description 2
- SOCXDNMHDNVKIL-UHFFFAOYSA-N icosyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC SOCXDNMHDNVKIL-UHFFFAOYSA-N 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- QSQLTHHMFHEFIY-UHFFFAOYSA-N methyl behenate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OC QSQLTHHMFHEFIY-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- YDLYQMBWCWFRAI-UHFFFAOYSA-N n-Hexatriacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC YDLYQMBWCWFRAI-UHFFFAOYSA-N 0.000 description 2
- VAMFXQBUQXONLZ-UHFFFAOYSA-N n-alpha-eicosene Natural products CCCCCCCCCCCCCCCCCCC=C VAMFXQBUQXONLZ-UHFFFAOYSA-N 0.000 description 2
- NHKDEMRRYWOJOF-UHFFFAOYSA-N n-hexacosanyl n-octadecanoate Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NHKDEMRRYWOJOF-UHFFFAOYSA-N 0.000 description 2
- BAIZLGVGMIENLK-UHFFFAOYSA-N n-hexacosanyl palmitate Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC BAIZLGVGMIENLK-UHFFFAOYSA-N 0.000 description 2
- UBMJSQAFNUWJEG-UHFFFAOYSA-N nonacos-1-ene Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC=C UBMJSQAFNUWJEG-UHFFFAOYSA-N 0.000 description 2
- IGGUPRCHHJZPBS-UHFFFAOYSA-N nonacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCC IGGUPRCHHJZPBS-UHFFFAOYSA-N 0.000 description 2
- NHLUYCJZUXOUBX-UHFFFAOYSA-N nonadec-1-ene Chemical compound CCCCCCCCCCCCCCCCCC=C NHLUYCJZUXOUBX-UHFFFAOYSA-N 0.000 description 2
- LQERIDTXQFOHKA-UHFFFAOYSA-N nonadecane Chemical compound CCCCCCCCCCCCCCCCCCC LQERIDTXQFOHKA-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- ZYURHZPYMFLWSH-UHFFFAOYSA-N octacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC ZYURHZPYMFLWSH-UHFFFAOYSA-N 0.000 description 2
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 2
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000007649 pad printing Methods 0.000 description 2
- SSZBUIDZHHWXNJ-UHFFFAOYSA-N palmityl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC SSZBUIDZHHWXNJ-UHFFFAOYSA-N 0.000 description 2
- YKNWIILGEFFOPE-UHFFFAOYSA-N pentacosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCC YKNWIILGEFFOPE-UHFFFAOYSA-N 0.000 description 2
- YCOZIPAWZNQLMR-UHFFFAOYSA-N pentadecane Chemical compound CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 description 2
- DMCJFWXGXUEHFD-UHFFFAOYSA-N pentatriacontan-18-one Chemical compound CCCCCCCCCCCCCCCCCC(=O)CCCCCCCCCCCCCCCCC DMCJFWXGXUEHFD-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- ZAKVZVDDGSFVRG-UHFFFAOYSA-N prop-1-en-2-ylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CC(=C)C1=CC=CC=C1 ZAKVZVDDGSFVRG-UHFFFAOYSA-N 0.000 description 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 235000010356 sorbitol Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- BILPUZXRUDPOOF-UHFFFAOYSA-N stearyl palmitate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC BILPUZXRUDPOOF-UHFFFAOYSA-N 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- ZDLBWMYNYNATIW-UHFFFAOYSA-N tetracos-1-ene Chemical compound CCCCCCCCCCCCCCCCCCCCCCC=C ZDLBWMYNYNATIW-UHFFFAOYSA-N 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- 239000012749 thinning agent Substances 0.000 description 2
- WMZHDICSCDKPFS-UHFFFAOYSA-N triacont-1-ene Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCC=C WMZHDICSCDKPFS-UHFFFAOYSA-N 0.000 description 2
- OLTHARGIAFTREU-UHFFFAOYSA-N triacontane Natural products CCCCCCCCCCCCCCCCCCCCC(C)CCCCCCCC OLTHARGIAFTREU-UHFFFAOYSA-N 0.000 description 2
- SJDSOBWGZRPKSB-UHFFFAOYSA-N tricos-1-ene Chemical compound CCCCCCCCCCCCCCCCCCCCCC=C SJDSOBWGZRPKSB-UHFFFAOYSA-N 0.000 description 2
- VARQGBHBYZTYLJ-UHFFFAOYSA-N tricosan-12-one Chemical compound CCCCCCCCCCCC(=O)CCCCCCCCCCC VARQGBHBYZTYLJ-UHFFFAOYSA-N 0.000 description 2
- FIGVVZUWCLSUEI-UHFFFAOYSA-N tricosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCC FIGVVZUWCLSUEI-UHFFFAOYSA-N 0.000 description 2
- DUXYWXYOBMKGIN-UHFFFAOYSA-N trimyristin Chemical compound CCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCC DUXYWXYOBMKGIN-UHFFFAOYSA-N 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- 125000001834 xanthenyl group Chemical group C1=CC=CC=2OC3=CC=CC=C3C(C12)* 0.000 description 2
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 1
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- HZVFRKSYUGFFEJ-YVECIDJPSA-N (2r,3r,4s,5r)-7-phenylhept-6-ene-1,2,3,4,5,6-hexol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=CC1=CC=CC=C1 HZVFRKSYUGFFEJ-YVECIDJPSA-N 0.000 description 1
- VKFWQGFYGLIANZ-WOPDTQHZSA-N (2r,3s,4r)-6-phenylhex-5-ene-1,2,3,4,5-pentol Chemical compound OC[C@@H](O)[C@H](O)[C@@H](O)C(O)=CC1=CC=CC=C1 VKFWQGFYGLIANZ-WOPDTQHZSA-N 0.000 description 1
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 description 1
- IOVOJJDSFSXJQN-UHFFFAOYSA-N (3,5-dihydroxyphenyl)acetic acid Chemical compound OC(=O)CC1=CC(O)=CC(O)=C1 IOVOJJDSFSXJQN-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- OIAQMFOKAXHPNH-UHFFFAOYSA-N 1,2-diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC=C1C1=CC=CC=C1 OIAQMFOKAXHPNH-UHFFFAOYSA-N 0.000 description 1
- BIGYLAKFCGVRAN-UHFFFAOYSA-N 1,3,4-thiadiazolidine-2,5-dithione Chemical compound S=C1NNC(=S)S1 BIGYLAKFCGVRAN-UHFFFAOYSA-N 0.000 description 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- XJKSTNDFUHDPQJ-UHFFFAOYSA-N 1,4-diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=C(C=2C=CC=CC=2)C=C1 XJKSTNDFUHDPQJ-UHFFFAOYSA-N 0.000 description 1
- MYMSJFSOOQERIO-UHFFFAOYSA-N 1-bromodecane Chemical compound CCCCCCCCCCBr MYMSJFSOOQERIO-UHFFFAOYSA-N 0.000 description 1
- QYOXLKAKUAASNA-UHFFFAOYSA-N 1-bromodocosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCBr QYOXLKAKUAASNA-UHFFFAOYSA-N 0.000 description 1
- PBLNBZIONSLZBU-UHFFFAOYSA-N 1-bromododecane Chemical compound CCCCCCCCCCCCBr PBLNBZIONSLZBU-UHFFFAOYSA-N 0.000 description 1
- HHSDZLLPIXMEIU-UHFFFAOYSA-N 1-bromoheptadecane Chemical compound CCCCCCCCCCCCCCCCCBr HHSDZLLPIXMEIU-UHFFFAOYSA-N 0.000 description 1
- HNTGIJLWHDPAFN-UHFFFAOYSA-N 1-bromohexadecane Chemical compound CCCCCCCCCCCCCCCCBr HNTGIJLWHDPAFN-UHFFFAOYSA-N 0.000 description 1
- CZASMUMJSKOHFJ-UHFFFAOYSA-N 1-bromoicosane Chemical compound CCCCCCCCCCCCCCCCCCCCBr CZASMUMJSKOHFJ-UHFFFAOYSA-N 0.000 description 1
- WSULSMOGMLRGKU-UHFFFAOYSA-N 1-bromooctadecane Chemical compound CCCCCCCCCCCCCCCCCCBr WSULSMOGMLRGKU-UHFFFAOYSA-N 0.000 description 1
- JKOTZBXSNOGCIF-UHFFFAOYSA-N 1-bromopentadecane Chemical compound CCCCCCCCCCCCCCCBr JKOTZBXSNOGCIF-UHFFFAOYSA-N 0.000 description 1
- KOFZTCSTGIWCQG-UHFFFAOYSA-N 1-bromotetradecane Chemical compound CCCCCCCCCCCCCCBr KOFZTCSTGIWCQG-UHFFFAOYSA-N 0.000 description 1
- BFDNZQUBFCYTIC-UHFFFAOYSA-N 1-bromotridecane Chemical compound CCCCCCCCCCCCCBr BFDNZQUBFCYTIC-UHFFFAOYSA-N 0.000 description 1
- IKPSIIAXIDAQLG-UHFFFAOYSA-N 1-bromoundecane Chemical compound CCCCCCCCCCCBr IKPSIIAXIDAQLG-UHFFFAOYSA-N 0.000 description 1
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 1
- OACXFSZVCDOBKF-UHFFFAOYSA-N 1-chlorodocosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCl OACXFSZVCDOBKF-UHFFFAOYSA-N 0.000 description 1
- CLWAXFZCVYJLLM-UHFFFAOYSA-N 1-chlorohexadecane Chemical compound CCCCCCCCCCCCCCCCCl CLWAXFZCVYJLLM-UHFFFAOYSA-N 0.000 description 1
- AFGNVSCTEXUEJE-UHFFFAOYSA-N 1-chloroicosane Chemical compound CCCCCCCCCCCCCCCCCCCCCl AFGNVSCTEXUEJE-UHFFFAOYSA-N 0.000 description 1
- VUQPJRPDRDVQMN-UHFFFAOYSA-N 1-chlorooctadecane Chemical compound CCCCCCCCCCCCCCCCCCCl VUQPJRPDRDVQMN-UHFFFAOYSA-N 0.000 description 1
- RNHWYOLIEJIAMV-UHFFFAOYSA-N 1-chlorotetradecane Chemical compound CCCCCCCCCCCCCCCl RNHWYOLIEJIAMV-UHFFFAOYSA-N 0.000 description 1
- 229940106006 1-eicosene Drugs 0.000 description 1
- FIKTURVKRGQNQD-UHFFFAOYSA-N 1-eicosene Natural products CCCCCCCCCCCCCCCCCC=CC(O)=O FIKTURVKRGQNQD-UHFFFAOYSA-N 0.000 description 1
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 1
- KMWHQYDMBYABKL-UHFFFAOYSA-N 1-iodohexadecane Chemical compound CCCCCCCCCCCCCCCCI KMWHQYDMBYABKL-UHFFFAOYSA-N 0.000 description 1
- ZNJOCVLVYVOUGB-UHFFFAOYSA-N 1-iodooctadecane Chemical compound CCCCCCCCCCCCCCCCCCI ZNJOCVLVYVOUGB-UHFFFAOYSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- YGUGZXZLWIADHU-UHFFFAOYSA-N 1-pentadecoxypentadecane Chemical compound CCCCCCCCCCCCCCCOCCCCCCCCCCCCCCC YGUGZXZLWIADHU-UHFFFAOYSA-N 0.000 description 1
- DJNJZIFFCJTUDS-UHFFFAOYSA-N 1-phenyldodecan-1-one Chemical compound CCCCCCCCCCCC(=O)C1=CC=CC=C1 DJNJZIFFCJTUDS-UHFFFAOYSA-N 0.000 description 1
- IIOLAWJMOGLOIB-UHFFFAOYSA-N 1-phenylhexadecan-1-one Chemical compound CCCCCCCCCCCCCCCC(=O)C1=CC=CC=C1 IIOLAWJMOGLOIB-UHFFFAOYSA-N 0.000 description 1
- DBLXXVQTWJFJFI-UHFFFAOYSA-N 1-phenyloctadecan-1-one Chemical compound CCCCCCCCCCCCCCCCCC(=O)C1=CC=CC=C1 DBLXXVQTWJFJFI-UHFFFAOYSA-N 0.000 description 1
- LXUIUVLDNRQBQJ-UHFFFAOYSA-N 1-phenyltetradecan-1-one Chemical compound CCCCCCCCCCCCCC(=O)C1=CC=CC=C1 LXUIUVLDNRQBQJ-UHFFFAOYSA-N 0.000 description 1
- ZQYGIPYHSWOVIB-UHFFFAOYSA-N 10-docosoxy-10-oxodecanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCC(O)=O ZQYGIPYHSWOVIB-UHFFFAOYSA-N 0.000 description 1
- WQFYAGVHZYFXDO-UHFFFAOYSA-N 2'-anilino-6'-(diethylamino)-3'-methylspiro[2-benzofuran-3,9'-xanthene]-1-one Chemical compound C=1C(N(CC)CC)=CC=C(C2(C3=CC=CC=C3C(=O)O2)C2=C3)C=1OC2=CC(C)=C3NC1=CC=CC=C1 WQFYAGVHZYFXDO-UHFFFAOYSA-N 0.000 description 1
- KXSFECAJUBPPFE-UHFFFAOYSA-N 2,2':5',2''-terthiophene Chemical compound C1=CSC(C=2SC(=CC=2)C=2SC=CC=2)=C1 KXSFECAJUBPPFE-UHFFFAOYSA-N 0.000 description 1
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical class [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- FLPJVCMIKUWSDR-UHFFFAOYSA-N 2-(4-formylphenoxy)acetamide Chemical compound NC(=O)COC1=CC=C(C=O)C=C1 FLPJVCMIKUWSDR-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- GRIKUIPJBHJPPN-UHFFFAOYSA-N 3',6'-dimethoxyspiro[2-benzofuran-3,9'-xanthene]-1-one Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(OC)C=C1OC1=CC(OC)=CC=C21 GRIKUIPJBHJPPN-UHFFFAOYSA-N 0.000 description 1
- JZEPXWWZAJGALH-UHFFFAOYSA-N 3,3-bis(1-butyl-2-methylindol-3-yl)-2-benzofuran-1-one Chemical compound C1=CC=C2C(C3(C4=CC=CC=C4C(=O)O3)C3=C(C)N(C4=CC=CC=C43)CCCC)=C(C)N(CCCC)C2=C1 JZEPXWWZAJGALH-UHFFFAOYSA-N 0.000 description 1
- FHQWUIZMJXPGRG-UHFFFAOYSA-N 3,5-dichloro-2-fluoropyridine Chemical compound FC1=NC=C(Cl)C=C1Cl FHQWUIZMJXPGRG-UHFFFAOYSA-N 0.000 description 1
- VNUWSDABOKHZAG-UHFFFAOYSA-N 3-(1-butyl-2-methylindol-3-yl)-4,5,6,7-tetrachloro-3-[4-(dimethylamino)-2-methoxyphenyl]-2-benzofuran-1-one Chemical compound C12=CC=CC=C2N(CCCC)C(C)=C1C1(C2=C(C(=C(Cl)C(Cl)=C2Cl)Cl)C(=O)O1)C1=CC=C(N(C)C)C=C1OC VNUWSDABOKHZAG-UHFFFAOYSA-N 0.000 description 1
- XBCTUDRVBSOUQD-UHFFFAOYSA-N 3-(1h-indol-2-yl)-3-phenyl-2-benzofuran-1-one Chemical class C12=CC=CC=C2C(=O)OC1(C=1NC2=CC=CC=C2C=1)C1=CC=CC=C1 XBCTUDRVBSOUQD-UHFFFAOYSA-N 0.000 description 1
- UYMBCDOGDVGEFA-UHFFFAOYSA-N 3-(1h-indol-2-yl)-3h-2-benzofuran-1-one Chemical class C12=CC=CC=C2C(=O)OC1C1=CC2=CC=CC=C2N1 UYMBCDOGDVGEFA-UHFFFAOYSA-N 0.000 description 1
- HOUWRQXIBSGOHF-UHFFFAOYSA-N 3-[4-(diethylamino)phenyl]-3-(1-ethyl-2-methylindol-3-yl)-2-benzofuran-1-one Chemical compound C1=CC(N(CC)CC)=CC=C1C1(C=2C3=CC=CC=C3N(CC)C=2C)C2=CC=CC=C2C(=O)O1 HOUWRQXIBSGOHF-UHFFFAOYSA-N 0.000 description 1
- SVAPVDMWXJVISW-UHFFFAOYSA-N 3h-2-benzofuran-1-one;benzylbenzene Chemical class C1=CC=C2C(=O)OCC2=C1.C=1C=CC=CC=1CC1=CC=CC=C1 SVAPVDMWXJVISW-UHFFFAOYSA-N 0.000 description 1
- QFHQFVJGMQSORR-UHFFFAOYSA-N 4,5,6,7-tetrachloro-3-[4-(diethylamino)-2-ethoxyphenyl]-3-(1-ethyl-2-methylindol-3-yl)-2-benzofuran-1-one Chemical compound CCOC1=CC(N(CC)CC)=CC=C1C1(C=2C3=CC=CC=C3N(CC)C=2C)C(C(Cl)=C(Cl)C(Cl)=C2Cl)=C2C(=O)O1 QFHQFVJGMQSORR-UHFFFAOYSA-N 0.000 description 1
- AUOJLYPIYIAZFA-UHFFFAOYSA-N 4,5,6,7-tetrachloro-3-[4-(diethylamino)-2-ethoxyphenyl]-3-(2-methyl-1-pentylindol-3-yl)-2-benzofuran-1-one Chemical compound C12=CC=CC=C2N(CCCCC)C(C)=C1C1(C2=C(C(=C(Cl)C(Cl)=C2Cl)Cl)C(=O)O1)C1=CC=C(N(CC)CC)C=C1OCC AUOJLYPIYIAZFA-UHFFFAOYSA-N 0.000 description 1
- AYXAHJJONLHBFT-UHFFFAOYSA-N 4,5,6,7-tetrachloro-3-[4-(diethylamino)-2-methylphenyl]-3-(1-ethyl-2-methylindol-3-yl)-2-benzofuran-1-one Chemical compound CC1=CC(N(CC)CC)=CC=C1C1(C=2C3=CC=CC=C3N(CC)C=2C)C(C(Cl)=C(Cl)C(Cl)=C2Cl)=C2C(=O)O1 AYXAHJJONLHBFT-UHFFFAOYSA-N 0.000 description 1
- FEZHAHVBYJXTGF-UHFFFAOYSA-N 4-(4-methoxyquinazolin-2-yl)-n,n-dimethylaniline Chemical compound N=1C2=CC=CC=C2C(OC)=NC=1C1=CC=C(N(C)C)C=C1 FEZHAHVBYJXTGF-UHFFFAOYSA-N 0.000 description 1
- YCDZGJSPPUBDGE-UHFFFAOYSA-N 4-[2,6-bis(2,4-diethoxyphenyl)pyridin-4-yl]-N,N-dimethylaniline Chemical compound C(C)OC1=C(C=CC(=C1)OCC)C1=NC(=CC(=C1)C1=CC=C(C=C1)N(C)C)C1=C(C=C(C=C1)OCC)OCC YCDZGJSPPUBDGE-UHFFFAOYSA-N 0.000 description 1
- KNKCKJLEAAAJQH-UHFFFAOYSA-N 4-[2,6-bis(2-ethoxyphenyl)pyridin-4-yl]-n,n-dimethylaniline Chemical compound CCOC1=CC=CC=C1C1=CC(C=2C=CC(=CC=2)N(C)C)=CC(C=2C(=CC=CC=2)OCC)=N1 KNKCKJLEAAAJQH-UHFFFAOYSA-N 0.000 description 1
- MGBRUEGBVXMDGD-UHFFFAOYSA-N 4-[4-[2-[2-[4-(diethylamino)phenyl]quinazolin-4-yl]oxyethoxy]quinazolin-2-yl]-n,n-diethylaniline Chemical compound C1=CC(N(CC)CC)=CC=C1C1=NC(OCCOC=2C3=CC=CC=C3N=C(N=2)C=2C=CC(=CC=2)N(CC)CC)=C(C=CC=C2)C2=N1 MGBRUEGBVXMDGD-UHFFFAOYSA-N 0.000 description 1
- TTWBMGNNEJOEOJ-UHFFFAOYSA-N 4-chloro-n-fluorocyclohexan-1-amine Chemical compound FNC1CCC(Cl)CC1 TTWBMGNNEJOEOJ-UHFFFAOYSA-N 0.000 description 1
- RJBSTXIIQYFNPX-UHFFFAOYSA-N 4-methoxy-6-phenyl-1,3,5-triazin-2-amine Chemical compound COC1=NC(N)=NC(C=2C=CC=CC=2)=N1 RJBSTXIIQYFNPX-UHFFFAOYSA-N 0.000 description 1
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 1
- CNMJKGUUEVNWNR-UHFFFAOYSA-N 5-docosoxy-5-oxopentanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCC(O)=O CNMJKGUUEVNWNR-UHFFFAOYSA-N 0.000 description 1
- ZDTDGOLJQPSDNM-UHFFFAOYSA-N 6-docosoxy-6-oxohexanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCC(O)=O ZDTDGOLJQPSDNM-UHFFFAOYSA-N 0.000 description 1
- SKVLHBJJOXTLKQ-UHFFFAOYSA-N 7,7-bis[4-(diethylamino)-2-ethoxyphenyl]furo[3,4-b]pyridin-5-one Chemical compound CCOC1=CC(N(CC)CC)=CC=C1C1(C=2C(=CC(=CC=2)N(CC)CC)OCC)C2=NC=CC=C2C(=O)O1 SKVLHBJJOXTLKQ-UHFFFAOYSA-N 0.000 description 1
- CATPNSYLEMYNJK-UHFFFAOYSA-N 7-[2-ethoxy-4-(n-ethylanilino)phenyl]-7-(1-ethyl-2-methylindol-3-yl)furo[3,4-b]pyridin-5-one Chemical compound C=1C=C(C2(C3=NC=CC=C3C(=O)O2)C=2C3=CC=CC=C3N(CC)C=2C)C(OCC)=CC=1N(CC)C1=CC=CC=C1 CATPNSYLEMYNJK-UHFFFAOYSA-N 0.000 description 1
- RCVMSMLWRJESQC-UHFFFAOYSA-N 7-[4-(diethylamino)-2-ethoxyphenyl]-7-(1-ethyl-2-methylindol-3-yl)furo[3,4-b]pyridin-5-one Chemical compound CCOC1=CC(N(CC)CC)=CC=C1C1(C=2C3=CC=CC=C3N(CC)C=2C)C2=NC=CC=C2C(=O)O1 RCVMSMLWRJESQC-UHFFFAOYSA-N 0.000 description 1
- YDYKGVWORCQOTN-UHFFFAOYSA-N 7-[4-(diethylamino)-2-hexoxyphenyl]-7-(1-ethyl-2-methylindol-3-yl)furo[3,4-b]pyridin-5-one Chemical compound CCCCCCOC1=CC(N(CC)CC)=CC=C1C1(C=2C3=CC=CC=C3N(CC)C=2C)C2=NC=CC=C2C(=O)O1 YDYKGVWORCQOTN-UHFFFAOYSA-N 0.000 description 1
- IHKGCRGYJQCCRF-UHFFFAOYSA-N 8-docosoxy-8-oxooctanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCC(O)=O IHKGCRGYJQCCRF-UHFFFAOYSA-N 0.000 description 1
- HMNGPLGXLQFPFN-UHFFFAOYSA-N 9'-(diethylamino)spiro[2-benzofuran-3,12'-benzo[a]xanthene]-1-one Chemical compound O1C(=O)C2=CC=CC=C2C21C1=C3C=CC=CC3=CC=C1OC1=CC(N(CC)CC)=CC=C21 HMNGPLGXLQFPFN-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 239000004953 Aliphatic polyamide Substances 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- HRHWNJCCOLKOJU-UHFFFAOYSA-N CCCCCCCCCCCCC(CC)COC(=O)CC1=CC(=CC(=C1)O)O Chemical compound CCCCCCCCCCCCC(CC)COC(=O)CC1=CC(=CC(=C1)O)O HRHWNJCCOLKOJU-UHFFFAOYSA-N 0.000 description 1
- OOWVNPNKCGTFTB-UHFFFAOYSA-N CCCCCCCCCCCCCCC(C)COC(=O)CC1=CC(=CC(=C1)O)O Chemical compound CCCCCCCCCCCCCCC(C)COC(=O)CC1=CC(=CC(=C1)O)O OOWVNPNKCGTFTB-UHFFFAOYSA-N 0.000 description 1
- WSBMGJXISSCIQB-UHFFFAOYSA-N CCCCCCCCCCCCCCC(CC)COC(=O)CC1=CC(=C(C(=C1)O)O)O Chemical compound CCCCCCCCCCCCCCC(CC)COC(=O)CC1=CC(=C(C(=C1)O)O)O WSBMGJXISSCIQB-UHFFFAOYSA-N 0.000 description 1
- OODMKOYVBIMTQG-UHFFFAOYSA-N CCCCCCCCCCCCCCCCC(CC)COC(=O)CC1=CC(=C(C=C1)O)O Chemical compound CCCCCCCCCCCCCCCCC(CC)COC(=O)CC1=CC(=C(C=C1)O)O OODMKOYVBIMTQG-UHFFFAOYSA-N 0.000 description 1
- WYGKSDROWZKSPP-UHFFFAOYSA-N CCCCCCCCCCCCCCCCCCOC(=O)CC1=CC(=CC(=C1)O)O Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CC1=CC(=CC(=C1)O)O WYGKSDROWZKSPP-UHFFFAOYSA-N 0.000 description 1
- PGXZBAIUYAKKJX-UHFFFAOYSA-N CCCCCCCCCCCCCCCCCOC(=O)CC1=CC(=CC(=C1)O)O Chemical compound CCCCCCCCCCCCCCCCCOC(=O)CC1=CC(=CC(=C1)O)O PGXZBAIUYAKKJX-UHFFFAOYSA-N 0.000 description 1
- GKSFXECEXPOVNY-UHFFFAOYSA-N CCCCCCCCCCCCCCCOC(=O)CC1=CC(=CC(=C1)O)O Chemical compound CCCCCCCCCCCCCCCOC(=O)CC1=CC(=CC(=C1)O)O GKSFXECEXPOVNY-UHFFFAOYSA-N 0.000 description 1
- HCSHZOKUTZOAFB-UHFFFAOYSA-N CCCCCCCCCCCCCCOC(=O)CC1=CC(=CC(=C1)O)O Chemical compound CCCCCCCCCCCCCCOC(=O)CC1=CC(=CC(=C1)O)O HCSHZOKUTZOAFB-UHFFFAOYSA-N 0.000 description 1
- MOLJGVUEAWQCPF-UHFFFAOYSA-N CCCCCCCCCCCCCOC(=O)CC1=CC(=CC(=C1)O)O Chemical compound CCCCCCCCCCCCCOC(=O)CC1=CC(=CC(=C1)O)O MOLJGVUEAWQCPF-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000005152 Cholesterol Laurate Substances 0.000 description 1
- RMLFYKFCGMSLTB-ZBDFTZOCSA-N Cholesteryl laurate Chemical compound C([C@@H]12)C[C@]3(C)[C@@H]([C@H](C)CCCC(C)C)CC[C@H]3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)CCCCCCCCCCC)C1 RMLFYKFCGMSLTB-ZBDFTZOCSA-N 0.000 description 1
- IPAJDLMMTVZVPP-UHFFFAOYSA-N Crystal violet lactone Chemical compound C1=CC(N(C)C)=CC=C1C1(C=2C=CC(=CC=2)N(C)C)C2=CC=C(N(C)C)C=C2C(=O)O1 IPAJDLMMTVZVPP-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- ORAWFNKFUWGRJG-UHFFFAOYSA-N Docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(N)=O ORAWFNKFUWGRJG-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000467686 Eschscholzia lobbii Species 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229920002581 Glucomannan Polymers 0.000 description 1
- WJYIASZWHGOTOU-UHFFFAOYSA-N Heptylamine Chemical compound CCCCCCCN WJYIASZWHGOTOU-UHFFFAOYSA-N 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- SJDMTGSQPOFVLR-UHFFFAOYSA-N Myristinsaeure-cholesterylester Natural products C12CCC3(C)C(C(C)CCCC(C)C)CCC3C2CC=C2C1(C)CCC(OC(=O)CCCCCCCCCCCCC)C2 SJDMTGSQPOFVLR-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- UULYVBBLIYLRCU-UHFFFAOYSA-N Palmitinsaeure-n-tetradecylester Natural products CCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC UULYVBBLIYLRCU-UHFFFAOYSA-N 0.000 description 1
- BBJQPKLGPMQWBU-UHFFFAOYSA-N Palmitinsaeurecholesterylester Natural products C12CCC3(C)C(C(C)CCCC(C)C)CCC3C2CC=C2C1(C)CCC(OC(=O)CCCCCCCCCCCCCCC)C2 BBJQPKLGPMQWBU-UHFFFAOYSA-N 0.000 description 1
- 108010009736 Protein Hydrolysates Proteins 0.000 description 1
- 239000004373 Pullulan Substances 0.000 description 1
- 229920001218 Pullulan Polymers 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000004288 Sodium dehydroacetate Chemical class 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- PLZVEHJLHYMBBY-UHFFFAOYSA-N Tetradecylamine Chemical compound CCCCCCCCCCCCCCN PLZVEHJLHYMBBY-UHFFFAOYSA-N 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 229920002310 Welan gum Polymers 0.000 description 1
- FPBODWXATDKICU-FLFWOSPYSA-N [(3s,8s,9s,10r,13r,14s,17r)-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1h-cyclopenta[a]phenanthren-3-yl] hexanoate Chemical compound C([C@@H]12)C[C@]3(C)[C@@H]([C@H](C)CCCC(C)C)CC[C@H]3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)CCCCC)C1 FPBODWXATDKICU-FLFWOSPYSA-N 0.000 description 1
- SKLBBRQPVZDTNM-SJTWHRLHSA-N [(3s,8s,9s,10r,13r,14s,17r)-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1h-cyclopenta[a]phenanthren-3-yl] octanoate Chemical compound C([C@@H]12)C[C@]3(C)[C@@H]([C@H](C)CCCC(C)C)CC[C@H]3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)CCCCCCC)C1 SKLBBRQPVZDTNM-SJTWHRLHSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 229940023476 agar Drugs 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229920003231 aliphatic polyamide Polymers 0.000 description 1
- 125000005079 alkoxycarbonylmethyl group Chemical group 0.000 description 1
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000008365 aqueous carrier Substances 0.000 description 1
- OMQAAHBXTQQRLA-UHFFFAOYSA-N arachidyl palmitate Chemical compound CCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC OMQAAHBXTQQRLA-UHFFFAOYSA-N 0.000 description 1
- 239000000305 astragalus gummifer gum Substances 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical class C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001746 carotenes Chemical class 0.000 description 1
- 235000005473 carotenes Nutrition 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 229940005759 cetyl behenate Drugs 0.000 description 1
- 229940074979 cetyl palmitate Drugs 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- XHRPOTDGOASDJS-UHFFFAOYSA-N cholesterol n-octadecanoate Natural products C12CCC3(C)C(C(C)CCCC(C)C)CCC3C2CC=C2C1(C)CCC(OC(=O)CCCCCCCCCCCCCCCCC)C2 XHRPOTDGOASDJS-UHFFFAOYSA-N 0.000 description 1
- WBOQXYUYHINMOC-FTAWAYKBSA-N cholesteryl behenate Chemical compound C([C@@H]12)C[C@]3(C)[C@@H]([C@H](C)CCCC(C)C)CC[C@H]3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)CCCCCCCCCCCCCCCCCCCCC)C1 WBOQXYUYHINMOC-FTAWAYKBSA-N 0.000 description 1
- SJDMTGSQPOFVLR-ZPQCIJQQSA-N cholesteryl myristate Chemical compound C([C@@H]12)C[C@]3(C)[C@@H]([C@H](C)CCCC(C)C)CC[C@H]3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)CCCCCCCCCCCCC)C1 SJDMTGSQPOFVLR-ZPQCIJQQSA-N 0.000 description 1
- BBJQPKLGPMQWBU-JADYGXMDSA-N cholesteryl palmitate Chemical compound C([C@@H]12)C[C@]3(C)[C@@H]([C@H](C)CCCC(C)C)CC[C@H]3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)CCCCCCCCCCCCCCC)C1 BBJQPKLGPMQWBU-JADYGXMDSA-N 0.000 description 1
- XHRPOTDGOASDJS-XNTGVSEISA-N cholesteryl stearate Chemical compound C([C@@H]12)C[C@]3(C)[C@@H]([C@H](C)CCCC(C)C)CC[C@H]3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)CCCCCCCCCCCCCCCCC)C1 XHRPOTDGOASDJS-XNTGVSEISA-N 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- DDTBPAQBQHZRDW-UHFFFAOYSA-N cyclododecane Chemical compound C1CCCCCCCCCCC1 DDTBPAQBQHZRDW-UHFFFAOYSA-N 0.000 description 1
- WJTCGQSWYFHTAC-UHFFFAOYSA-N cyclooctane Chemical compound C1CCCCCCC1 WJTCGQSWYFHTAC-UHFFFAOYSA-N 0.000 description 1
- 239000004914 cyclooctane Substances 0.000 description 1
- NMCCNOZOBBWFMN-UHFFFAOYSA-N davicil Chemical class CS(=O)(=O)C1=C(Cl)C(Cl)=NC(Cl)=C1Cl NMCCNOZOBBWFMN-UHFFFAOYSA-N 0.000 description 1
- TUTWLYPCGCUWQI-UHFFFAOYSA-N decanamide Chemical compound CCCCCCCCCC(N)=O TUTWLYPCGCUWQI-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- KSCAZGPKPGSMTR-UHFFFAOYSA-N decyl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCC KSCAZGPKPGSMTR-UHFFFAOYSA-N 0.000 description 1
- DYFFNHCQVRCXAC-UHFFFAOYSA-N decyl icosanoate Chemical compound CCCCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCC DYFFNHCQVRCXAC-UHFFFAOYSA-N 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 125000004915 dibutylamino group Chemical group C(CCC)N(CCCC)* 0.000 description 1
- ZFAKTZXUUNBLEB-UHFFFAOYSA-N dicyclohexylazanium;nitrite Chemical compound [O-]N=O.C1CCCCC1[NH2+]C1CCCCC1 ZFAKTZXUUNBLEB-UHFFFAOYSA-N 0.000 description 1
- GSFUOZYDUVXIKY-UHFFFAOYSA-N didocosyl docosanedioate Chemical compound CCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCCCCCCCC GSFUOZYDUVXIKY-UHFFFAOYSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- QTDJUGJAGNDLKQ-UHFFFAOYSA-N dihexadecyl decanedioate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCCCCCCCCCC QTDJUGJAGNDLKQ-UHFFFAOYSA-N 0.000 description 1
- RQIKFACUZHNEDV-UHFFFAOYSA-N dihexadecyl hexanedioate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCCCCCC RQIKFACUZHNEDV-UHFFFAOYSA-N 0.000 description 1
- ZUUXXAHCTXQXNO-UHFFFAOYSA-N dihexadecyl icosanedioate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC ZUUXXAHCTXQXNO-UHFFFAOYSA-N 0.000 description 1
- GEOJVFYFYMZDJX-UHFFFAOYSA-N dihexadecyl octanedioate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCC(=O)OCCCCCCCCCCCCCCCC GEOJVFYFYMZDJX-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- NTUPDNAURMTJID-UHFFFAOYSA-N dioctadecyl decanedioate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCCCCCCCCCCCC NTUPDNAURMTJID-UHFFFAOYSA-N 0.000 description 1
- GYFBKUFUJKHFLZ-UHFFFAOYSA-N dioctadecyl hexanedioate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCCCCCCCC GYFBKUFUJKHFLZ-UHFFFAOYSA-N 0.000 description 1
- NGXTZZRNVXTTBF-UHFFFAOYSA-N dioctadecyl icosanedioate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCCCC NGXTZZRNVXTTBF-UHFFFAOYSA-N 0.000 description 1
- QCJPMPANDKLQIU-UHFFFAOYSA-N dioctadecyl octanedioate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCC(=O)OCCCCCCCCCCCCCCCCCC QCJPMPANDKLQIU-UHFFFAOYSA-N 0.000 description 1
- XMQXMOKIYVQDNL-UHFFFAOYSA-N dioctadecyl oxalate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(=O)OCCCCCCCCCCCCCCCCCC XMQXMOKIYVQDNL-UHFFFAOYSA-N 0.000 description 1
- SDMLMWQEKBDWFS-UHFFFAOYSA-N dioctadecyl pentanedioate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCC(=O)OCCCCCCCCCCCCCCCCCC SDMLMWQEKBDWFS-UHFFFAOYSA-N 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- DVXXGJIEZNWCNE-UHFFFAOYSA-N ditetradecyl decanedioate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCCCCCCCC DVXXGJIEZNWCNE-UHFFFAOYSA-N 0.000 description 1
- QZQPCVVMCYMSFX-UHFFFAOYSA-N ditetradecyl hexanedioate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCCCC QZQPCVVMCYMSFX-UHFFFAOYSA-N 0.000 description 1
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 1
- KWLPLMOUCWCFOT-UHFFFAOYSA-N docosyl 2-(3,4-dihydroxyphenyl)acetate Chemical compound CCCCCCCCCCCCCCCCCCCCCCOC(=O)CC1=CC(=C(C=C1)O)O KWLPLMOUCWCFOT-UHFFFAOYSA-N 0.000 description 1
- KOFDNENZSXQSAY-UHFFFAOYSA-N docosyl 2-(3,5-dihydroxyphenyl)acetate Chemical compound CCCCCCCCCCCCCCCCCCCCCCOC(=O)CC1=CC(=CC(=C1)O)O KOFDNENZSXQSAY-UHFFFAOYSA-N 0.000 description 1
- RDLSPOZZADEUJT-UHFFFAOYSA-N docosyl dodecanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCC RDLSPOZZADEUJT-UHFFFAOYSA-N 0.000 description 1
- ZZEXXQGRXIUMCA-UHFFFAOYSA-N docosyl tetradecanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC ZZEXXQGRXIUMCA-UHFFFAOYSA-N 0.000 description 1
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 1
- IFLDFHHUUCVKNJ-UHFFFAOYSA-N dodecyl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCC IFLDFHHUUCVKNJ-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 229940046240 glucomannan Drugs 0.000 description 1
- 235000001727 glucose Nutrition 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- JTOGFHAZQVDOAO-UHFFFAOYSA-N henicos-1-ene Chemical compound CCCCCCCCCCCCCCCCCCCC=C JTOGFHAZQVDOAO-UHFFFAOYSA-N 0.000 description 1
- UNRFDARCMOHDBJ-UHFFFAOYSA-N hentriacontan-16-one Chemical compound CCCCCCCCCCCCCCCC(=O)CCCCCCCCCCCCCCC UNRFDARCMOHDBJ-UHFFFAOYSA-N 0.000 description 1
- VCZMOZVQLARCOE-UHFFFAOYSA-N heptacosan-14-one Chemical compound CCCCCCCCCCCCCC(=O)CCCCCCCCCCCCC VCZMOZVQLARCOE-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N heptadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- FUJXKFCTVKZXTJ-UHFFFAOYSA-N hexacosan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCN FUJXKFCTVKZXTJ-UHFFFAOYSA-N 0.000 description 1
- IRHTZOCLLONTOC-UHFFFAOYSA-N hexacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCO IRHTZOCLLONTOC-UHFFFAOYSA-N 0.000 description 1
- AOXKZKUKANXHQY-UHFFFAOYSA-N hexacosyl dodecanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCC AOXKZKUKANXHQY-UHFFFAOYSA-N 0.000 description 1
- DZVFAFYITSEZRK-UHFFFAOYSA-N hexacosyl tetradecanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZVFAFYITSEZRK-UHFFFAOYSA-N 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- HSEMFIZWXHQJAE-UHFFFAOYSA-N hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 1
- PXDJXZJSCPSGGI-UHFFFAOYSA-N hexadecanoic acid hexadecyl ester Natural products CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC PXDJXZJSCPSGGI-UHFFFAOYSA-N 0.000 description 1
- UEDYHQHDUXDFGA-UHFFFAOYSA-N hexadecyl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC UEDYHQHDUXDFGA-UHFFFAOYSA-N 0.000 description 1
- QAKXLTNAJLFSQC-UHFFFAOYSA-N hexadecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC QAKXLTNAJLFSQC-UHFFFAOYSA-N 0.000 description 1
- ALBYIUDWACNRRB-UHFFFAOYSA-N hexanamide Chemical compound CCCCCC(N)=O ALBYIUDWACNRRB-UHFFFAOYSA-N 0.000 description 1
- SZHHTCPIUIMTIX-UHFFFAOYSA-N hexyl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCCCCCC SZHHTCPIUIMTIX-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 238000010191 image analysis Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 150000002596 lactones Chemical group 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 229910052751 metal Chemical class 0.000 description 1
- 239000002184 metal Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 150000002772 monosaccharides Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- FIIGZGVXXBOCPL-UHFFFAOYSA-N n-fluoro-3-methylcyclohexan-1-amine Chemical compound CC1CCCC(NF)C1 FIIGZGVXXBOCPL-UHFFFAOYSA-N 0.000 description 1
- SGDNSPIMHNQUQZ-UHFFFAOYSA-N n-fluoro-n-phenylaniline Chemical compound C=1C=CC=CC=1N(F)C1=CC=CC=C1 SGDNSPIMHNQUQZ-UHFFFAOYSA-N 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PDDANVVLWYOEPS-UHFFFAOYSA-N nitrous acid;n-propan-2-ylpropan-2-amine Chemical compound [O-]N=O.CC(C)[NH2+]C(C)C PDDANVVLWYOEPS-UHFFFAOYSA-N 0.000 description 1
- XGFDHKJUZCCPKQ-UHFFFAOYSA-N nonadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCO XGFDHKJUZCCPKQ-UHFFFAOYSA-N 0.000 description 1
- YUPOCHDBBHTUBJ-UHFFFAOYSA-N nonadecan-10-one Chemical compound CCCCCCCCCC(=O)CCCCCCCCC YUPOCHDBBHTUBJ-UHFFFAOYSA-N 0.000 description 1
- YVTPTBVYGTYTKP-UHFFFAOYSA-N nonadecylcyclohexane Chemical compound CCCCCCCCCCCCCCCCCCCC1CCCCC1 YVTPTBVYGTYTKP-UHFFFAOYSA-N 0.000 description 1
- FJDUDHYHRVPMJZ-UHFFFAOYSA-N nonan-1-amine Chemical compound CCCCCCCCCN FJDUDHYHRVPMJZ-UHFFFAOYSA-N 0.000 description 1
- PFUPABFCHVRLLY-UHFFFAOYSA-N nonanophenone Chemical compound CCCCCCCCC(=O)C1=CC=CC=C1 PFUPABFCHVRLLY-UHFFFAOYSA-N 0.000 description 1
- QBPTYPWUCYWIRI-UHFFFAOYSA-N nonatriacontan-20-one Chemical compound CCCCCCCCCCCCCCCCCCCC(=O)CCCCCCCCCCCCCCCCCCC QBPTYPWUCYWIRI-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 description 1
- QEXZDYLACYKGOM-UHFFFAOYSA-N octacos-1-ene Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCC=C QEXZDYLACYKGOM-UHFFFAOYSA-N 0.000 description 1
- DZLRGXSUDHQIOZ-UHFFFAOYSA-N octacosan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCN DZLRGXSUDHQIOZ-UHFFFAOYSA-N 0.000 description 1
- CNNRPFQICPFDPO-UHFFFAOYSA-N octacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCO CNNRPFQICPFDPO-UHFFFAOYSA-N 0.000 description 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- 229940038384 octadecane Drugs 0.000 description 1
- GAQPWOABOQGPKA-UHFFFAOYSA-N octadecyl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCCCC GAQPWOABOQGPKA-UHFFFAOYSA-N 0.000 description 1
- XPRSWAIUFMEQLF-UHFFFAOYSA-N octadecyl icosanoate Chemical compound CCCCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCCCC XPRSWAIUFMEQLF-UHFFFAOYSA-N 0.000 description 1
- IEDOGKKOPNRRKW-UHFFFAOYSA-N octadecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC IEDOGKKOPNRRKW-UHFFFAOYSA-N 0.000 description 1
- MWWVNZNVTGBKQO-UHFFFAOYSA-N octadecylcyclohexane Chemical compound CCCCCCCCCCCCCCCCCCC1CCCCC1 MWWVNZNVTGBKQO-UHFFFAOYSA-N 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- MWSXIWIELAIOBE-UHFFFAOYSA-N octyl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCCCCCCCC MWSXIWIELAIOBE-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 150000002482 oligosaccharides Chemical class 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 229930184652 p-Terphenyl Natural products 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- ZNUABQHWFGTOCO-UHFFFAOYSA-N pentadecylcyclohexane Chemical compound CCCCCCCCCCCCCCCC1CCCCC1 ZNUABQHWFGTOCO-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000004302 potassium sorbate Chemical class 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000004405 propyl p-hydroxybenzoate Chemical class 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical class CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical class [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Chemical class 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 229960003885 sodium benzoate Drugs 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019259 sodium dehydroacetate Nutrition 0.000 description 1
- 229940079839 sodium dehydroacetate Drugs 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical class [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229940094908 stearyl myristate Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 1
- TYFQFVWCELRYAO-UHFFFAOYSA-L suberate(2-) Chemical compound [O-]C(=O)CCCCCCC([O-])=O TYFQFVWCELRYAO-UHFFFAOYSA-L 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- AVKVDDQTHIQFSC-UHFFFAOYSA-N tetradecyl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC AVKVDDQTHIQFSC-UHFFFAOYSA-N 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 1
- 229950006389 thiodiglycol Drugs 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
- ABVVEAHYODGCLZ-UHFFFAOYSA-N tridecan-1-amine Chemical compound CCCCCCCCCCCCCN ABVVEAHYODGCLZ-UHFFFAOYSA-N 0.000 description 1
- VBCBSDJKFLGBIX-UHFFFAOYSA-N tridecyl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCC VBCBSDJKFLGBIX-UHFFFAOYSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 229940113164 trimyristin Drugs 0.000 description 1
- PVNIQBQSYATKKL-UHFFFAOYSA-N tripalmitin Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCC PVNIQBQSYATKKL-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- QFKMMXYLAPZKIB-UHFFFAOYSA-N undecan-1-amine Chemical compound CCCCCCCCCCCN QFKMMXYLAPZKIB-UHFFFAOYSA-N 0.000 description 1
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 1
- UPIXQYOSHAJORT-UHFFFAOYSA-N undecyl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCC UPIXQYOSHAJORT-UHFFFAOYSA-N 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B11/00—Diaryl- or thriarylmethane dyes
- C09B11/04—Diaryl- or thriarylmethane dyes derived from triarylmethanes, i.e. central C-atom is substituted by amino, cyano, alkyl
- C09B11/10—Amino derivatives of triarylmethanes
- C09B11/12—Amino derivatives of triarylmethanes without any OH group bound to an aryl nucleus
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B11/00—Diaryl- or thriarylmethane dyes
- C09B11/04—Diaryl- or thriarylmethane dyes derived from triarylmethanes, i.e. central C-atom is substituted by amino, cyano, alkyl
- C09B11/26—Triarylmethane dyes in which at least one of the aromatic nuclei is heterocyclic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B11/00—Diaryl- or thriarylmethane dyes
- C09B11/28—Pyronines ; Xanthon, thioxanthon, selenoxanthan, telluroxanthon dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
- C09K9/02—Organic tenebrescent materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
Abstract
The invention provides a color-changing indicator which is easy to display the color change from the decolored state to the colored state by heating at the temperature near the temperature of daily life in the temperature range of living environmentAnd a reversible thermochromic microcapsule pigment which is in a state of returning to a decolored state and has a high color density at the time of coloring. The solution is a reversible thermal discoloration microcapsule pigment, which contains a reversible thermal discoloration composition, wherein the reversible thermal discoloration composition comprises: (a) an electron-donating color-developing organic compound; (b) an electron-accepting compound which is a hydroxyphenyl acetate compound represented by the following general formula (1); (c) a compound selected from the group consisting of chain hydrocarbons, alicyclic hydrocarbons, and halogenated hydrocarbons as a reaction medium for reversibly causing an electron transfer reaction between the component (a) and the component (b); and (d) a styrene compound having a softening point of 5 ℃ or higher and a weight-average molecular weight of 200 to 10 ten thousand. (wherein R represents a linear or branched alkyl group having 12 to 22 carbon atoms, X, Y and Z are each independently hydrogen or a hydroxyl group, and two or three of them are hydroxyl groups.)
Description
Technical Field
The present invention relates to reversible thermochromic microcapsular pigments. More specifically, the present invention relates to a reversible thermochromic microcapsule pigment which develops color from a decolorized state by heating.
Background
Conventionally, among reversible thermochromic compositions containing (a) an electron-donating color-developing organic compound, (b) an electron-accepting compound, and (c) a reaction medium which reversibly causes an electron transfer reaction between the components (a) and (b), there have been disclosed a reversible thermochromic composition which exhibits a color change behavior that changes from a decolorized state to a colored state by heating and returns to the decolorized state by lowering the temperature by using a hydroxybenzoate ester as the component (b), and a microcapsule pigment containing the reversible thermochromic composition (for example, see patent document 1).
These reversible thermal discoloration compositions exhibit a color development state by heating, but the temperature of color development is high, and it is difficult to develop color easily at a temperature at or near the temperature of daily life. Further, even if a reversible thermochromic composition that develops color at a temperature at or near a temperature in daily life is obtained, the color density in the color developed state is low, and the practicability is not satisfactory.
Documents of the prior art
Patent document
Patent document 1: japanese patent laid-open publication No. 2001-105732
Disclosure of Invention
Problems to be solved by the invention
The present inventors have conducted intensive studies on a reversible thermal discoloration composition which develops color from a decolorized state by heating, and as a result, have found that a reversible thermal discoloration microcapsule pigment which contains a reversible thermal discoloration composition exhibiting a discoloration behavior that is easily changed from a decolorized state to a colored state by heating at a temperature in the living environment temperature range or in the vicinity of the daily living temperature and is restored to the decolorized state again, and having a high color density at the time of color development is obtained by using a specific hydroxyphenyl acetate compound as component (b) and adding a specific compound as component (d), and have completed the present invention.
Means for solving the problems
The reversible thermal discoloration microcapsule pigment according to the present invention contains a reversible thermal discoloration composition, the reversible thermal discoloration composition comprising:
(a) an electron-donating color-developing organic compound;
(b) an electron-accepting compound which is a hydroxyphenyl acetate compound represented by the following general formula (1);
(c) a compound selected from the group consisting of chain hydrocarbons, alicyclic hydrocarbons and halogenated hydrocarbons as a reaction medium for reversibly causing an electron transfer reaction between the component (a) and the component (b); and
(d) a styrene compound having a softening point of 5 ℃ or higher and a weight average molecular weight of 200 to 10 ten thousand.
(in the formula, wherein,
r represents a linear or branched alkyl group having 12 to 22 carbon atoms,
x, Y, and Z are each independently hydrogen or hydroxy, two of which are hydroxy and the remainder are hydrogen, or three of which are hydroxy)
The present invention relates to a reversible thermal discoloration liquid composition comprising the above reversible thermal discoloration microcapsule pigment, and a carrier.
The laminate according to the present invention comprises: a support; and a reversible thermochromic layer comprising the microcapsule pigment.
The molded article of the present invention contains the above microcapsule pigment in a support.
ADVANTAGEOUS EFFECTS OF INVENTION
The present invention can provide a reversible thermochromic microcapsule pigment which exhibits a reversible discoloration behavior that is easily changed from a decolored state to a colored state by heating and then returns to the decolored state again at a temperature in the living environment temperature range or around the daily life temperature, has a high color density in color development, and can be used in various fields such as teaching elements, toys, and decorations.
Detailed Description
The following compounds are specifically exemplified for each component.
The component (a) of the present invention, that is, the electron-donating color former is a color-determining component, and is a compound that donates electrons to the component (b) as a developer to develop color.
Examples of the electron donating color developing organic compound include a phthalide compound, a fluoran compound, a styrylquinoline compound, a diazahydrorhodamine lactone compound, a pyridine compound, a quinazoline compound, and a bisquinazoline compound, and among them, a phthalide compound and a fluoran compound are preferable.
Examples of the phthalide compound include diphenylmethane phthalide compounds, phenylindolyl phthalide compounds, indolyl phthalide compounds, diphenylmethane azaphthalide compounds, phenylindolyl azaphthalide compounds, and derivatives thereof, and among them, phenylindolyl azaphthalide compounds and derivatives thereof are preferable.
Further, examples of the fluoran compound include an aminofluoran compound, an alkoxyfluoran compound, and derivatives thereof.
These compounds are exemplified below. There may be mentioned:
3, 3-bis (p-dimethylaminophenyl) -6-dimethylaminophthalide,
3- (4-diethylaminophenyl) -3- (1-ethyl-2-methylindol-3-yl) phthalide,
3, 3-bis (1-n-butyl-2-methylindol-3-yl) phthalide,
3, 3-bis (2-ethoxy-4-diethylaminophenyl) -4-azaphthalide,
3- (2-ethoxy-4-diethylaminophenyl) -3- (1-ethyl-2-methylindol-3-yl) -4-azaphthalide,
3- (2-hexyloxy-4-diethylaminophenyl) -3- (1-ethyl-2-methylindol-3-yl) -4-azaphthalide,
3- [ 2-ethoxy-4- (N-ethylanilino) phenyl ] -3- (1-ethyl-2-methylindol-3-yl) -4-azaphthalide,
3- (2-acetamide-4-diethylaminophenyl) -3- (1-propylindol-3-yl) -4-azaphthalide,
3, 6-bis (diphenylamino) fluorane,
3, 6-dimethoxy fluorane,
3, 6-di-n-butoxy fluorane,
2-methyl-6- (N-ethyl-N-p-tolylamino) fluorane,
3-chloro-6-cyclohexylaminofluoran,
2-methyl-6-cyclohexylaminofluoran,
2- (2-chloroamino) -6-dibutylaminofluoran,
2- (2-chloroanilino) -6-di-n-butylaminofluoran,
2- (3-trifluoromethylanilino) -6-diethylaminofluoran,
2- (3-trifluoromethylanilino) -6-dipentylaminofluoran,
2- (dibenzylamino) -6-diethylaminofluoran,
2- (N-methylanilino) -6- (N-ethyl-N-p-tolylamino) fluoran,
1, 3-dimethyl-6-diethylaminofluorane,
2-chloro-3-methyl-6-diethylaminofluorane,
2-anilino-3-methyl-6-diethylaminofluoran,
2-anilino-3-methoxy-6-diethylaminofluoran,
2-anilino-3-methyl-6-di-n-butylaminofluoran,
2-anilino-3-methoxy-6-di-n-butylaminofluoran,
2-dimethylamino-3-methyl-6-diethylaminofluoran,
2-anilino-3-methyl-6- (N-ethyl-N-p-tolylamino) fluoran,
1, 2-benzo-6-diethylaminofluorane,
1, 2-benzo-6- (N-ethyl-N-isobutylamino) fluoran,
1, 2-benzo-6- (N-ethyl-N-isopentylamino) fluoran,
2- (3-methoxy-4-dodecyloxystyrene) quinoline,
Spiro [5H- (1) benzopyrano (2,3-d) pyrimidine-5, 1 ' (3 ' H) isobenzofuran ] -3 ' -one, 2- (diethylamino) -8- (diethylamino) -4-methyl,
Spiro [5H- (1) benzopyrano (2,3-d) pyrimidine-5, 1 ' (3 ' H) isobenzofuran ] -3 ' -one, 2- (di-n-butylamino) -8- (di-n-butylamino) -4-methyl,
Spiro [5H- (1) benzopyrano (2,3-d) pyrimidine-5, 1 ' (3 ' H) isobenzofuran ] -3 ' -one, 2- (di-n-butylamino) -8- (diethylamino) -4-methyl,
Spiro [5H- (1) benzopyrano (2,3-d) pyrimidine-5, 1 ' (3 ' H) isobenzofuran ] -3 ' -one, 2- (di-N-butylamino) -8- (N-ethyl-N-isopentylamino) -4-methyl,
Spiro [5H- (1) benzopyrano (2,3-d) pyrimidine-5, 1 ' (3 ' H) isobenzofuran ] -3 ' -one, 2- (dibutylamino) -8- (dipentylamino) -4-methyl,
4,5,6, 7-tetrachloro-3- [4- (dimethylamino) -2-methoxyphenyl ] -3- (1-butyl-2-methyl-1H-indol-3-yl) -1(3H) -isobenzofuranone,
4,5,6, 7-tetrachloro-3- [4- (diethylamino) -2-ethoxyphenyl ] -3- (1-ethyl-2-methyl-1H-indol-3-yl) -1(3H) -isobenzofuranone,
4,5,6, 7-tetrachloro-3- [4- (diethylamino) -2-ethoxyphenyl ] -3- (1-pentyl-2-methyl-1H-indol-3-yl) -1(3H) -isobenzofuranone,
4,5,6, 7-tetrachloro-3- [4- (diethylamino) -2-methylphenyl ] -3- (1-ethyl-2-methyl-1H-indol-3-yl) -1(3H) -isobenzofuranone,
3 ', 6 ' -bis [ phenyl (2-methylphenyl) amino ] -spiro [ isobenzofuran-1 (3H),9 ' - [9H ] xanthen ] -3-one,
3 ', 6 ' -bis [ phenyl (3-methylphenyl) amino ] -spiro [ isobenzofuran-1 (3H),9 ' - [9H ] xanthen ] -3-one,
3 ', 6 ' -bis [ phenyl (3-ethylphenyl) amino ] -spiro [ isobenzofuran-1 (3H),9 ' - [9H ] xanthen ] -3-one,
2, 6-bis (2 '-ethyloxyphenyl) -4- (4' -dimethylaminophenyl) pyridine,
2, 6-bis (2 ', 4 ' -diethyloxyphenyl) -4- (4 ' -dimethylaminophenyl) pyridine,
2- (4' -dimethylaminophenyl) -4-methoxy-quinazoline,
4, 4' - (ethylenedioxy) -bis [2- (4-diethylaminophenyl) quinazoline ]
And so on.
In addition, the fluorans may be a compound having a substituent on the phenyl group forming the xanthene ring, and a substituent (for example, an alkyl group such as a methyl group, or a halogen atom such as a chlorine group) on the phenyl group forming the lactone ring, which is substituted on the phenyl group forming the xanthene ring, and which exhibits a blue or black color.
As the electron-accepting compound (b), a hydroxyphenyl acetate compound represented by the general formula (1) is used.
In the formula (I), the compound is shown in the specification,
r represents a linear or branched alkyl group having 12 to 22 carbon atoms,
x, Y and Z are each independently hydrogen or hydroxy, two or three of which are hydroxy,
preferably X, Y and Z are both hydroxy groups and one is hydrogen.
Further preferably, X and Y are hydroxyl groups and Z is hydrogen. Specifically, the 3, 4-dihydroxyphenyl acetate compound represented by the general formula (2) is preferable, and is suitable for use because it has a high color density when it develops color.
Wherein R is the same as R in the formula (1).
The alkyl group of the hydroxyphenyl acetate compound is a linear or branched alkyl group having 12 to 22 carbon atoms, and preferably a linear or branched alkyl group having 14 to 22 carbon atoms. The compound having an alkyl group having a carbon number of less than 12 or more than 22 is not practical because of low crystallinity. In addition, in consideration of practical performance such as discoloration characteristics and color development density, the linear alkyl group is preferably a linear alkyl group having 12 to 22 carbon atoms, more preferably a linear alkyl group having 16 to 22 carbon atoms, still more preferably a linear alkyl group having 16 to 20 carbon atoms, and still more preferably a linear alkyl group having 16 to 18 carbon atoms.
Examples of the hydroxyphenyl acetate compound include dodecyl 3, 4-dihydroxyphenyl acetate, tridecyl 3, 4-dihydroxyphenyl acetate, tetradecyl 3, 4-dihydroxyphenyl acetate, 2-methyltridecyl 3, 4-dihydroxyphenyl acetate, pentadecyl 3, 4-dihydroxyphenyl acetate, hexadecyl 3, 4-dihydroxyphenyl acetate, 2-ethyltetradecyl 3, 4-dihydroxyphenyl acetate, heptadecyl 3, 4-dihydroxyphenyl acetate, 2-methylhexadecyl 3, 4-dihydroxyphenyl acetate, octadecyl 3, 4-dihydroxyphenyl acetate, 2-methylheptadecyl 3, 4-dihydroxyphenyl acetate, 2-ethylhexadecyl 3, 4-dihydroxyphenyl acetate, and mixtures thereof, Nonadecyl 3, 4-dihydroxyphenylacetate, eicosyl 3, 4-dihydroxyphenylacetate, 2-methylnonadecyl 3, 4-dihydroxyphenylacetate, 2-ethyloctadecyl 3, 4-dihydroxyphenylacetate, heneicosyl 3, 4-dihydroxyphenylacetate, docosyl 3, 4-dihydroxyphenylacetate, dodecyl 3, 5-dihydroxyphenylacetate, tridecyl 3, 5-dihydroxyphenylacetate, tetradecyl 3, 5-dihydroxyphenylacetate, 2-methyltrodecyl 3, 5-dihydroxyphenylacetate, pentadecyl 3, 5-dihydroxyphenylacetate, hexadecyl 3, 5-dihydroxyphenylacetate, 2-ethyltetradecyl 3, 5-dihydroxyphenylacetate, eicosyl 3, 4-dihydroxyphenylacetate, eicosyl 3, 5-dihydroxyphenylacetate, and the like, Heptadecyl 3, 5-dihydroxyphenylacetate, 2-methylhexadecyl 3, 5-dihydroxyphenylacetate, octadecyl 3, 5-dihydroxyphenylacetate, 2-methylheptadecyl 3, 5-dihydroxyphenylacetate, 2-ethylhexadecyl 3, 5-dihydroxyphenylacetate, nonadecyl 3, 5-dihydroxyphenylacetate, eicosyl 3, 5-dihydroxyphenylacetate, 2-methylnonadecyl 3, 5-dihydroxyphenylacetate, 2-ethyloctadecyl 3, 5-dihydroxyphenylacetate, heneicosyl 3, 5-dihydroxyphenylacetate, docosyl 3, 5-dihydroxyphenylacetate. Further, X, Y examples of the substance in which all of Z and Z are hydroxyl groups include dodecyl 3,4, 5-trihydroxyphenyl acetate, tridecyl 3,4, 5-trihydroxyphenyl acetate, tetradecyl 3,4, 5-trihydroxyphenyl acetate, 2-methyltrodecyl 3,4, 5-trihydroxyphenyl acetate, pentadecyl 3,4, 5-trihydroxyphenyl acetate, hexadecyl 3,4, 5-trihydroxyphenyl acetate, 2-ethyltetradecyl 3,4, 5-trihydroxyphenyl acetate, heptadecyl 3,4, 5-trihydroxyphenyl acetate, 2-methylhexadecyl 3,4, 5-trihydroxyphenyl acetate, octadecyl 3,4, 5-trihydroxyphenyl acetate, and the like, 2-methylheptadecyl 3,4, 5-trihydroxyphenylacetate, 2-ethylhexadecyl 3,4, 5-trihydroxyphenylacetate, nonadecyl 3,4, 5-trihydroxyphenylacetate, eicosyl 3,4, 5-trihydroxyphenylacetate, 2-methylnonadecyl 3,4, 5-trihydroxyphenylacetate, 2-ethyloctadecyl 3,4, 5-trihydroxyphenylacetate, heneicosyl 3,4, 5-trihydroxyphenylacetate, etc. Generally, a compound having a high hydroxyl group tends to have a high color density when it develops color.
As a reaction medium for reversibly causing an electron transfer reaction between the component (a) and the component (b), a compound selected from the group consisting of chain hydrocarbons, alicyclic hydrocarbons and halogenated hydrocarbons is used.
By using the compound of component (c), the sensitivity to color development by the reaction of component (a) and component (b) is small, and the color development behavior and color density due to heating can be effectively improved.
The higher the number of carbon atoms of the alkyl group in the hydroxybenzoate ester as the component (b) is, the higher the crystallinity tends to be, and thus, a hydroxybenzoate ester having high crystallinity can be used at a discoloration temperature in a low temperature range by adding the component (c).
Examples of the catenated hydrocarbon include saturated catenated hydrocarbons such as pentadecane, hexadecane, heptadecane, octadecane, nonadecane, eicosane, heneicosane, docosane, tricosane, tetracosane, pentacosane, hexacosane, heptacosane, octacosane, nonacosane and triacontane, unsaturated catenated hydrocarbons such as 1-pentadecene, 1-hexadecene, 1-heptadecene, 1-octadecene, 1-nonadecene, 1-eicosene, 1-heneicosene, 1-docosene, 1-tricosene, 1-tetracosene, 1-pentacocene, 1-hexacocene, 1-heptacosene, 1-octacosene, 1-nonacosene and 1-triacontene.
Examples of the alicyclic hydrocarbon include cyclooctane, cyclododecane, n-pentadecylcyclohexane, n-octadecylcyclohexane, n-nonadecylcyclohexane and decahydronaphthalene.
Examples of the halogenated hydrocarbon include 1-bromodecane, 1-bromoundecane, 1-bromododecane, 1-bromotridecane, 1-bromotetradecane, 1-chlorotetradecane, 1-bromopentadecane, 1-bromohexadecane, 1-chlorohexadecane, 1-iodohexadecane, 1-bromoheptadecane, 1-bromooctadecane, 1-chlorooctadecane, 1-iodooctadecane, 1-bromoeicosane, 1-chloroeicosane, 1-bromodocosane, and 1-chlorodocosane.
The following are styrene compounds (d) having a softening point of 5 ℃ or higher and a weight average molecular weight of 200 to 10 ten thousand.
As the styrene compound, a compound having a weight average molecular weight of 200 to 6000 is suitably used.
The weight average molecular weight was measured by GPC (gel permeation chromatography).
Examples of the styrene-based compound include low-molecular-weight polystyrene, styrene- α -methylstyrene-based copolymers, α -methylstyrene polymers, and copolymers of α -methylstyrene and vinyltoluene.
As the low molecular weight polystyrene, those available under the trade name of sanyo chemical industries (ltd.): ハイマー SB-75 (weight average molecular weight 2000), ハイマー ST-95 (weight average molecular weight 4000) and the like.
As the styrene- α -methylstyrene-based copolymer, a product name manufactured by physico-chemical ハーキュレス (ltd.): ピコラスチック A5 (weight average molecular weight 317), ピコラスチック A75 (weight average molecular weight 917), trade name of physicochemical No. ハーキュレス (Strain): ピコラスチック D125 (weight average molecular weight 3000), etc.
The α -methylstyrene polymer may be used under the trade name of physiochemical ハーキュレス (co.): クリスタレックス 3085 (weight average molecular weight 664), クリスタレックス 3100 (weight average molecular weight 1020), クリスタレックス 1120 (weight average molecular weight 2420), and the like.
As the copolymer of α -methylstyrene and vinyltoluene, those having trade names of physiochemical ハーキュレス (strain): ピコテックス LC (weight average molecular weight 950), ピコテックス 100 (weight average molecular weight 1740), and the like.
The styrene-based compounds may be used alone or in combination of 2 or more.
The addition of the component (d) changes the polarity of the compound selected from the group consisting of chain hydrocarbons, alicyclic hydrocarbons, aromatic hydrocarbons and halogenated hydrocarbons as a reaction medium, so that the solubility of the component (b) in the reaction medium decreases and the crystallization of the component (b) proceeds slowly. Therefore, a reversible thermochromic microcapsule pigment (hereinafter, may be simply referred to as a microcapsule pigment) containing a reversible thermochromic composition, which is cooled from a color-developed state to a discoloration-inducing temperature in a temperature-lowering process, is decolorized by leaving it.
The microcapsule pigment of the present invention preferably further comprises (e) a compound having a melting point of 50 ℃ or higher and selected from the group consisting of alcohols, esters, ethers, ketones, acid amides and aromatic hydrocarbons (hereinafter, may be simply referred to as component (e)). The component (e) is exemplified below.
Examples of the alcohols include hexadecane 1-ol, heptadecane 1-ol, octadecane 1-ol, nonadecane 1-ol, eicosane 1-ol, heneicosane 1-ol, docosane 1-ol, tetracosane 1-ol, hexacosane 1-ol, octacosane 1-ol, and triacontane 1-ol.
Examples of the esters include eicosyl laurate, behenyl laurate, ditetradecyl laurate, hexacosanyl laurate, dioctadecyl laurate, cetyl myristate, stearyl myristate, eicosyl myristate, behenyl myristate, ditetradecyl myristate, hexacosanyl myristate, dioctadecyl myristate, myristyl palmitate, cetyl palmitate, stearyl palmitate, eicosyl palmitate, behenyl palmitate, ditetradecyl palmitate, hexacosanyl palmitate, dioctadecyl palmitate, cetyl stearate, stearyl stearate, eicosyl stearate, behenyl stearate, hexacosanyl stearate, distearyl stearate, stearyl stearate, behenyl stearate, docosanyl stearate, distearyl stearate, stearyl stearate, behenyl stearate, and the like, Decyl eicosanoate, undecyl eicosanoate, tridecyl eicosanoate, myristyl eicosanoate, cetyl eicosanoate, stearyl eicosanoate, behenyl eicosanoate, ditetradecyl eicosanoate, hexacosanoic eicosanoate, dioctadecyl eicosanoate, methyl behenate, hexyl behenate, octyl behenate, decyl behenate, undecyl behenate, lauryl behenate, tridecyl behenate, myristyl behenate, cetyl behenate, stearyl behenate, eicosanoyl behenate, behenyl behenate, ditetradecyl behenate, hexacosanoic behenyl behenate, dioctadecyl behenate, distearyl oxalate, behenyl succinate, eicosyl succinate, behenyl acetate, and behenyl acetate, Behenyl succinate, distearyl glutarate, dieicosyl glutarate, behenyl glutarate, dimyristyl adipate, dicetyl adipate, distearyl adipate, eicosyl adipate, behenyl adipate, dicetyl suberate, distearyl suberate, dieicosyl suberate, behenyl suberate, myristyl azelate, dicetyl azelate, distearyl azelate, eicosyl azelate, behenyl azelate, dimyristyl sebacate, dicetyl sebacate, distearyl sebacate, dieicosyl sebacate, behenyl sebacate, ditridecyl 1, 14-tetradecylidene dicarboxylate, dimyristyl 1, 14-tetradecylidene dicarboxylate, Dicetyl 1, 14-tetradecylidene dicarboxylate, dipalmityl 1, 14-tetradecylidene dicarboxylate, distearyl 1, 14-tetradecylidene dicarboxylate, dieicosyl 1, 14-tetradecylidene dicarboxylate, dibehenyl 1, 14-tetradecylidene dicarboxylate, dilauryl 1, 16-hexadecylidene dicarboxylate, ditridecyl 1, 16-hexadecylidene dicarboxylate, dimyristyl 1, 16-hexadecylidene dicarboxylate, dicetyl 1, 16-hexadecylidene dicarboxylate, dipalmityl 1, 16-hexadecylidene dicarboxylate, distearyl 1, 16-hexadecylidene dicarboxylate, dieicosyl 1, 16-hexadecylidene dicarboxylate, dibehenyl 1, 16-hexadecylidene dicarboxylate, Didecyl 1, 18-octadecylenedicarboxylate, dilauryl 1, 18-octadecylenedicarboxylate, ditridecyl 1, 18-octadecylenedicarboxylate, dimyristyl 1, 18-octadecylenedicarboxylate, dicetyl 1, 18-octadecylenedicarboxylate, dipalmityl 1, 18-octadecylenedicarboxylate, distearyl 1, 18-octadecylenedicarboxylate, dieicosyl 1, 18-octadecylenedicarboxylate, dibehenyl 1, 18-octadecylenedicarboxylate, didecyl 1, 20-eicosylenedicarboxylate, dilauryl 1, 20-eicosylenedicarboxylate, ditridecyl 1, 20-eicosylenedicarboxylate, dimyristyl 1, 20-eicosylenedicarboxylate, Dicetyl 1, 20-eicosanedicarboxylate, dipalmityl 1, 20-eicosanedicarboxylate, distearyl 1, 20-eicosanedicarboxylate, dieicosyl 1, 20-eicosanedicarboxylate, dibehenyl 1, 20-eicosanedicarboxylate, trimyristin glycerol, tripalmitate glycerol tristearate, triglyceride nonadecanoate, cholesterol caproate, cholesterol caprylate, cholesterol capriate, cholesterol undecanoate, cholesterol laurate, cholesterol myristate, cholesterol palmitate, cholesterol stearate, cholesterol eicosanoate, cholesterol behenate, and the like.
Examples of the ethers include pentadecyl ether, dihexadecyl ether, dioctadecyl ether, dieicosyl ether, and dieicosyl ether.
Examples of the ketones include dioctyl ketone, dinonyl ketone, diundecyl ketone, ditridecyl ketone, dipentadecyl ketone, diheptadecyl ketone, dinonadecyl ketone, phenyloctyl ketone, phenylundecyl ketone, phenyltridecyl ketone, phenylpentadecyl ketone, and phenylheptadecyl ketone.
Examples of the acid amide include hexyl amide, heptyl amide, octyl amide, nonyl amide, decyl amide, undecyl amide, lauryl amide, tridecyl amide, myristyl amide, palmityl amide, stearyl amide, eicosyl amide, behenyl amide, hexacosyl amide, and octacosyl amide.
Examples of the aromatic hydrocarbons include biphenyl, o-terphenyl, m-terphenyl, p-terphenyl, and trithiophene.
As the component (e), compounds shown in the following tables can be used.
TABLE 1
(e) The component (C) is preferably a compound selected from esters, ethers, and aromatic hydrocarbons, and more preferably an aromatic hydrocarbon.
In the case where the component (d) is crystallized during the temperature reduction from the color-developed state to the component (b) and the color is reduced, it may take a long time to completely reduce the color, and the addition of the component (e) can further promote the crystallization and improve the color reduction sensitivity.
(a) The proportions of the components (b), (c) and (d) are dependent on the color density, color change temperature, color change form and the type of each component, but generally the proportions of the components for obtaining desired characteristics are in the following ranges, with respect to 1 part of the component (a), 0.1 to 50 parts, preferably 0.5 to 20 parts of the component (b), 1 to 200 parts, preferably 5 to 100 parts of the component (c), 0.1 to 10.0 parts, preferably 0.5 to 5.0 parts of the component (d), and 0.1 to 5.0 parts, preferably 0.1 to 3.0 parts of the component (e) (the proportions are parts by mass).
The reversible thermal discoloration composition is used in the form of encapsulated microcapsules. This is because the reversible thermal discoloration composition can exhibit the same effect and maintain the same composition under various use conditions because the function thereof is not deteriorated and the heat resistance stability can be maintained even when the reversible thermal discoloration composition is brought into contact with a chemically active substance such as an acidic substance, a basic substance, or a peroxide or other solvent component.
The microcapsule pigment containing the reversible thermal discoloration composition has a particle size of 0.1 to 100 μm, preferably 0.5 to 30 μm, and more preferably 1 to 20 μm, which satisfies the practical use.
The particle size and the average particle size were measured by determining the particle area using an image analysis type particle size distribution measurement software "Mac-view" manufactured by Mountech, calculating the projected area equivalent circle diameter (Heywood diameter) from the area of the particle area, and measuring the particle size and the average particle size of the equivalent particles of the isosphere obtained therefrom. When the particle size of all or most of the particles exceeds 0.2. mu.m, the particle size and the average particle size as equivoluminous equivalent particles can be measured by the Coulter method using a particle size distribution measuring apparatus (product name: Multisizer 4e, manufactured by Beckmann Coulter).
Further, the volume-based particle diameter and the average particle diameter (median particle diameter) can be measured using a laser diffraction/scattering type particle diameter distribution measuring apparatus (apparatus name: LA-300, manufactured by horiba, Ltd.) calibrated based on the value measured using a measuring apparatus using the Coulter method.
Further, each component may be a mixture of 2 or more compounds, and a light stabilizer may be further added in a range not impairing the function.
Examples of the light stabilizer include compounds for inhibiting oxidation reaction, such as ultraviolet absorbers, visible light absorbers, infrared absorbers, antioxidants, carotenes, pigments, amines, phenols, nickel complexes, singlet oxygen quenchers such as thioethers, superoxide anion quenchers such as complexes of oxidative dismutase and cobalt and complexes of oxidative dismutase and nickel, and ozone quenchers, which prevent photodegradation by light due to the excited state caused by photoreaction of the component (a), and the like, and the mixing ratio is 0.3 to 24% by mass, preferably 0.8 to 16% by mass. Among these, a system using an ultraviolet absorber and an antioxidant and/or singlet oxygen quencher in combination is particularly effective for improving light resistance.
Further, an antioxidant, an antistatic agent, a polarity-imparting agent, a thixotropy-imparting agent, a defoaming agent, or the like may be added as necessary to improve the functions.
Further, a dye pigment (non-thermal discoloration) may be generally blended.
The color change characteristics of a microcapsule pigment comprising a reversible thermal discoloration composition comprising components (a), (b), (c), and (d) or components (a), (b), (c), (d), and (e) will be described.
Reversible thermochromic composition exhibiting a decolored state starts from a color development start temperature (T) during heating1) If the temperature of (A) reaches the complete color development temperature (T)2) The reversible thermochromic composition is brought into a complete color-developed state and cooled to a color-fading inducing temperature in the course of temperature reduction, and undergoes color fading upon standing.
T1Preferably 15 to 35 ℃, and more preferably 15 to 27 ℃. T is2Preferably 25 to 50 ℃, and more preferably 25 to 40 ℃.
The reversibly thermochromic microcapsular pigment material is dispersed in a carrier containing an additive as needed to prepare a liquid composition, and thus can be used for (i) a printing ink used for screen printing, offset printing, chromatography printing, gravure printing, coater, pad printing, etc., (ii) a coating material used for brush coating, spray coating, electrostatic coating, electrodeposition coating, flow coating, roll coating, dip coating, etc., (iii) an ink for a writing instrument such as a marker pen, a ball pen, a brush pen, etc., (iv) an ink for a writing instrument, (v) a drawing pigment, (vi) a cosmetic material, or (vii) a reversibly thermochromic liquid composition such as a coloring liquid for fibers.
Examples of the additives include resins, crosslinking agents, curing agents, drying agents, plasticizers, viscosity modifiers, dispersants, ultraviolet absorbers, infrared absorbers, antioxidants, light stabilizers, dissolution aids, anti-settling agents, smoothing agents, gelling agents, antifoaming agents, matting agents, penetrants, pH modifiers, foaming agents, coupling agents, humectants, antifungal agents, preservatives, and rust inhibitors.
Examples of the carrier of the liquid composition according to the present invention include an oily carrier containing an organic solvent, and an aqueous carrier containing water and, if necessary, an organic solvent.
Examples of the organic solvent that can be used in the present invention include ethanol, propanol, butanol, glycerol, sorbitol, triethanolamine, diethanolamine, monoethanolamine, ethylene glycol, diethylene glycol, thiodiglycol, polyethylene glycol, propylene glycol, butylene glycol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol monobutyl ether, ethylene glycol monomethyl ether acetate, sulfolane, 2-pyrrolidone, N-methyl-2-pyrrolidone, and the like.
Examples of the liquid composition include a shear thinning liquid composition containing a shear thinning viscosity-imparting agent in a carrier, and an aggregating liquid composition containing a water-soluble polymer aggregating agent in a carrier and suspending a pigment in a slowly aggregated state.
By including the shear thinning agent in the liquid composition, for example, when the ink composition is used, the aggregation and sedimentation of the pigment can be suppressed, and the bleeding of the handwriting can be suppressed, so that a good handwriting can be formed.
Further, when the ink composition containing the shear thinning agent is filled in a ballpoint pen, it is possible to prevent leakage of ink from a gap between the ballpoint and a pen tip when not in use, or to prevent backflow of the ink composition when the writing tip portion is placed upward (upright state).
Examples of the shear thinning viscosity-imparting agent include xanthan gum, welan gum, succinoglycan (average molecular weight of about 100 to 800 ten thousand) constituting an organic acid-modified heteropolysaccharide in which monosaccharide is glucose and galactose, guar gum, locust bean gum and a derivative thereof, hydroxyethyl cellulose, alkyl alginate, a polymer having a molecular weight of 10 to 15 ten thousand and containing an alkyl methacrylate as a main component, a thickening polysaccharide having gelling ability extracted from seaweed such as glucomannan, agar, and carrageenan, a benzylidene sorbitol, a benzylidene xylitol, or a derivative thereof, a crosslinkable acrylic polymer, inorganic microparticles, a polyglycerol fatty acid ester, a polyoxyethylene sorbitan fatty acid ester, a polyethylene glycol fatty acid ester, a polyoxyethylene alkyl ether, a polyoxypropylene alkyl ether, a polyoxyethylene alkylphenyl ether, a nonionic surfactant having an HLB value of 8 to 12 such as a fatty acid amide, a polyoxyethylene sorbitan fatty acid ester, a polyoxyethylene alkyl ether, a polyoxypropylene alkyl ether, a polyoxyethylene alkylphenyl ether, and the like, Salts of dialkyl or dialkenyl sulfosuccinic acid, a mixture of N-alkyl-2-pyrrolidone and an anionic surfactant, and a mixture of polyvinyl alcohol and an acrylic resin.
Examples of the water-soluble polymer coagulant which can be used in the present invention include polyvinylpyrrolidone, polyethylene oxide, and water-soluble polysaccharides.
Examples of the water-soluble polysaccharide include tragacanth gum, guar gum, pullulan, cyclodextrin, and a water-soluble cellulose derivative, and specific examples of the water-soluble cellulose derivative include methyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxyethyl methyl cellulose, and hydroxypropyl methyl cellulose.
When the liquid composition is used as an ink composition to be filled in a ball point pen, it is preferable to prevent abrasion of the ball holder by adding a lubricant such as a higher fatty acid such as oleic acid, a nonionic surfactant having a long-chain alkyl group, a polyether-modified silicone oil, a thiophosphoric triester such as tris (alkoxycarbonylmethyl) thiophosphoric acid, tris (alkoxycarbonylethyl) thiophosphoric acid, a phosphoric monoester of a polyoxyethylene alkyl ether or a polyoxyethylene alkylaryl ether, a phosphoric diester of a polyoxyethylene alkyl ether or a polyoxyethylene alkylaryl ether, or a metal salt, ammonium salt, amine salt, or alkanolamine salt thereof.
Further, by containing 2, 5-dimercapto-1, 3, 4-thiadiazole and/or a salt thereof, even when the pH of the ink is in an acidic or basic region, dispersion failure and aggregation of the microcapsule pigment which occur after the ink which has been frozen first is thawed can be suppressed, increase in the viscosity of the ink and blurring and lightening of handwriting accompanying the increase can be prevented, and corrosion of the ball can be prevented when the ink is used in a ball-point pen.
In addition, preservatives or fungicides such as (i) acrylic resins, styrene maleic acid copolymers, cellulose derivatives, polyvinylpyrrolidone, polyvinyl alcohol, dextrin, etc., resins for imparting tackiness and tackiness to paper surface, (ii) inorganic salts such as sodium carbonate, sodium phosphate, sodium acetate, etc., and pH adjusters such as organic basic compounds such as water-soluble amine compounds, (iii) rust inhibitors such as benzotriazole, methylbenzotriazole, dicyclohexylammonium nitrite, diisopropylammonium nitrite, saponin, etc., (iv) phenol, sodium salts of 1, 2-benzothiazolin 3-one, sodium benzoate, sodium dehydroacetate, potassium sorbate, propyl p-hydroxybenzoate, 2,3,5, 6-tetrachloro-4- (methylsulfonyl) pyridine, etc., (v) urea, nonionic surfactants, etc., can be added as necessary, Reduced or non-reduced starch hydrolysate, oligosaccharide such as trehalose, wetting agents such as sucrose, cyclodextrin, glucose, dextrin, sorbitol, mannitol, sodium pyrophosphate, etc., (vi) antifoaming agents, (vii) dispersing agents, (viii) fluorine-based surfactants and nonionic surfactants that improve the permeability of the ink composition.
The reversible thermal discoloration microcapsule pigment may be contained in an amount of preferably 5 to 40% by mass, more preferably 10 to 40% by mass, and still more preferably 10 to 30% by mass, based on the total mass of the liquid composition. When the content of the microcapsule pigment is in the above range, a desired color development intensity can be achieved, and further, when the microcapsule pigment is used as an ink composition, the running property can be prevented from being lowered.
A writing instrument capable of containing the liquid composition according to the present invention will be described. In one embodiment, the writing instrument includes a barrel containing the ink composition and a pen body for guiding out the ink in the barrel. Examples of the pen body include a marker pen body, a ball-point pen body, and a writing pen body. The marker pen body may be a fiber pen tip, a felt pen tip, a plastic pen tip, or the like. The ballpoint pen body may be a ballpoint pen tip.
The microcapsule pigment of the present invention can be combined with a support to form a laminate, and includes a reversible thermochromic layer containing the microcapsule pigment and a support. Further, a molded body containing a microcapsule pigment in a support may be used.
Specifically, the microcapsule pigment can be dispersed in a medium containing a binder as a film-forming material, applied as a reversible thermochromic material such as ink or paint, and formed into a laminate by forming a reversible thermochromic layer on a support such as paper, synthetic paper, cloth, flocked or napped cloth, nonwoven fabric, synthetic leather, plastic, glass, ceramics, wood, stone, or the like, or dispersed in a support to obtain a molded article, by a conventionally known method such as printing means such as screen printing, offset printing, gravure printing, coater, pad printing, transfer printing, etc., brush coating, spray coating, electrostatic coating, electrodeposition coating, flow coating, roll coating, dip coating, etc.
Further, the molded article may be obtained as a material that is kneaded and integrated with a thermoplastic in a molten state.
Specific examples of the product to which the microcapsule pigment is applied include the following.
(1) Toy type
Doll and animal-shaped toys, hair for doll and animal-shaped toys, accessories for doll such as doll, clothes, hat, handbag, shoes, etc., ornamental toys, cloth toys, drawing toys, picture book for toys, puzzle-like educational toys, building block toys, clay toys, flowing toys, spinning tops, kites, musical instrument toys, cooking toys, gun toys, catching toys, background toys, toys imitating vehicles, animals, plants, buildings, foods, etc.,
(2) clothing articles
T-shirt, training clothes, blouse, lady dress, swimsuit, raincoat, ski suit, shoes, shoelace, etc., handkerchief, towel, cloth bag, etc,
(3) indoor decoration
Carpets, curtains, window curtain ropes, tablecloths, bedding fabrics, back cushions, decorative frames, artificial flowers, photo frames and the like,
(4) furniture
Bedding such as bedding, pillow, mattress, etc., lighting equipment, air conditioning and heating equipment, etc.,
(5) ornament (CN)
Finger rings, bracelets, headwear, earrings, hairpins, false nails, ribbons, bowties and the like, clocks, glasses and the like,
(6) stationery
Writing tools, stamping tools, erasers, backing plates, rulers, adhesive tapes and the like,
(7) daily necessities
Cosmetics such as lipstick, eye shadow, nail beauty, hair dye, artificial nail, paint for artificial nail, toothbrush, etc.,
(8) kitchen article
Cups, plates, chopsticks, spoons, forks, pots, frying pans and the like,
(9) others
Calendars, labels, cards, recording materials, various printed matters for forgery prevention, books such as picture books, handbags, packaging containers, embroidery threads, sporting goods, fishing gear, cup mats, musical instruments, pocket warmers, bags such as coolant and purses, umbrellas, transportation means, buildings, temperature detection indicators, teaching tools, and the like.
Examples
Examples 1 to 14
The compositions used for the reversible thermal discoloration compositions of the present invention are shown in the following table.
In addition, the numbers in () in the table represent parts by mass, and the numbers below representing the amounts to be mixed are all parts by mass.
TABLE 2
As for component (D) in the table, ピコラスチック A75 is a low molecular weight polystyrene resin having a softening point of 75 ℃ and ピコラスチック D125 is a low molecular weight polystyrene resin having a softening point of 125 ℃ and ピコラスチック A5 is a low molecular weight polystyrene resin having a softening point of 5 ℃.
The compounds 1,2 and 6 described in the component (e) in the table are each compound described in the table exemplifying the component (e).
Each of the reversible thermal discoloration compositions was heated and melted to prepare a compatible body, and then an interfacial polymerization reaction was performed using an epoxy resin and an amine curing agent to obtain a microcapsule pigment in the form of a microcapsule encapsulated in an epoxy resin film.
With respect to the microcapsule pigment, the following measurement samples were prepared, and then the discoloration temperature was measured by the following measurement method.
Measurement sample
As for the discoloration characteristics of the microcapsule pigment, a reversible thermal discoloration ink in which 40 parts of the microcapsule pigment was dispersed in 60 parts of an ethylene-vinyl acetate emulsion was used, and the resulting mixture was printed on high-quality paper by screen printing to obtain a test sample.
Measurement method
The measurement samples of examples 1 to 14 were placed at predetermined positions of a colorimeter [ TC-3600 type colorimeter, Tokyo electrochromatography ], and heated at a rate of 10 ℃/min in a temperature range of 0 ℃ to 40 ℃.
After heating to 40 ℃, the mixture was cooled to the discoloration-inducing temperature and left to be decolorized.
The color change and color development onset temperature (T) of each example were measured1) Complete color development temperature (T)2) The following table shows the color erasing induction temperature and the color density (lightness value) at the time of color development.
TABLE 3
Comparative examples 1 and 2
The compositions used for the reversible thermal discoloration compositions are shown in the following table.
In addition, the numbers in () in the table represent parts by mass, and the numbers below representing the amounts to be mixed are all parts by mass.
TABLE 4
Each of the reversible thermal discoloration compositions was heated and melted to prepare a compatible body, and then an interfacial polymerization reaction was performed using an epoxy resin and an amine curing agent to obtain a microcapsule pigment in the form of a microcapsule encapsulated in an epoxy resin film.
With respect to the microcapsule pigment, after the following measurement samples were prepared, the discoloration temperature was measured by the following measurement method.
Measurement sample
As for the discoloration characteristics of the microcapsule pigment, a reversible thermal discoloration ink in which 40 parts of the microcapsule pigment was dispersed in 60 parts of an ethylene-vinyl acetate emulsion was used, and the resulting mixture was printed on high-quality paper by screen printing to obtain a test sample.
Measurement method
The measurement samples of comparative examples 1 and 2 were placed at predetermined positions of a colorimeter [ TC-3600 type colorimeter, Tokyo electrochromatography ], and heated at a rate of 10 ℃/min in a temperature range of 0 ℃ to 40 ℃.
After heating to 40 ℃, the resultant was cooled to a discoloration-inducing temperature and left to decolorize.
The color change and color development onset temperature (T) of each example were measured1) Complete color development temperature (T)2) The following table shows the color erasing induction temperature and the color density (lightness value) at the time of color development.
In the table, the smaller the lightness value, the higher the concentration, and the larger the concentration.
TABLE 5
Application example 1
A reversible thermal discoloration screen ink was prepared which consisted of 30.0 parts of the microcapsule pigment containing the reversible thermal discoloration composition prepared in example 1, 2.0 parts of a fluorescent pigment (pink color), 50.0 parts of an acrylic resin emulsion, 3.0 parts of an antifoaming agent, and 15.0 parts of a turpentine oil emulsion.
On polyester taffeta, printing was performed by screen printing using a reversible thermochromic screen ink to form a reversible thermochromic layer, and a reversible thermochromic sheet was obtained.
The reversible thermal discoloration sheet shows a purple color when heated to 26 ℃ or higher.
After the reversible thermal discoloration sheet was cooled to 18 ℃, the reversible thermal discoloration sheet appeared pink when it was left to stand.
Application example 2
50.0 parts of the microcapsule pigment containing the reversible thermal discoloration composition prepared in example 2 was uniformly dispersed and mixed in 50.0 parts of a linseed oil based offset ink carrier to prepare a reversible thermal discoloration offset ink.
A reversible thermochromic sheet is obtained by forming a reversible thermochromic layer on high-quality paper by offset printing using the above-mentioned offset ink.
The sheet appeared blue if warmed above 38 ℃.
After cooling the reversible thermal discoloration sheet up to 26 ℃, the reversible thermal discoloration sheet appeared colorless if left to stand.
Application example 3
33.3 parts of the microcapsule pigment containing the reversible thermal discoloration composition prepared in example 3, 66.4 parts of a hard liquid epoxy resin, and 0.3 part of a defoaming agent were uniformly dispersed and kneaded to obtain a reversible thermal discoloration epoxy ink, and 20.0 parts of an aliphatic polyamide curable at room temperature was added to the ink, followed by stirring and mixing to prepare a reversible thermal discoloration epoxy ink.
A reversible thermochromic cup was obtained by performing screen printing on the surface of a ceramic cup with a 100-mesh screen made of stainless steel using a reversible thermochromic epoxy ink on a curved surface, and heating and curing at 70 ℃ for 60 minutes to form a reversible thermochromic layer.
The reversible thermochromic cup shows a blue color when heated to 50 ℃ or higher.
After cooling the reversible thermal discoloration cup to 35 ℃, the reversible thermal discoloration cup appeared colorless upon standing.
Application example 4
A carrier composed of 10.0 parts of the microcapsule pigment containing the reversible thermal discoloration composition prepared in example 4, 1.0 part of a fluorescent pigment (pink color), 45.0 parts of a 50% acrylic resin/xylene solution, 15.0 parts of xylene, 23.0 parts of methyl isobutyl ketone, and 6.0 parts of a polyisocyanate-based curing agent was stirred and mixed to prepare a reversible thermal discoloration spray coating.
And spraying and coating a reversible thermal discoloration spraying coating on the whole electric car model to form a reversible thermal discoloration layer, thereby obtaining the reversible thermal discoloration electric car model.
The reversible thermochromic electric car model showed a purple color when heated to 32 ℃ or higher.
After the reversible thermal discoloration electric car model was cooled to 24 ℃, the reversible thermal discoloration electric car model appeared pink after being left to stand.
Application example 5
A carrier composed of 10.0 parts of the microcapsule pigment containing the reversible thermal discoloration composition prepared in example 7, 1.0 part of a blue pigment, 45.0 parts of a 50% acrylic resin/xylene solution, 15.0 parts of xylene, 23.0 parts of methyl isobutyl ketone, and 6.0 parts of a polyisocyanate-based curing agent was stirred and mixed to prepare a reversible thermal discoloration spray coating.
And spraying and coating a reversible thermal discoloration spraying coating on the whole electric car model to form a reversible thermal discoloration layer, thereby obtaining the reversible thermal discoloration car model.
The reversible thermal discoloration automobile model showed purple color when heated to 38 ℃ or higher.
After cooling the reversible thermal discoloration automobile model to 26 ℃, the reversible thermal discoloration automobile model appeared blue upon standing.
Application example 6
50.0 parts of the microcapsule pigment encapsulating the reversible thermal discoloration composition prepared in example 5, 0.04 parts of a yellow pigment, 1000.0 parts of a 12 nylon resin (melting point 178 ℃ C.), and 10.0 parts of an ultraviolet absorber were mixed and dispersed in a Henschel mixer, and then, a reversible thermal discoloration 12 nylon resin pellet (resin composition for reversible thermal discoloration molding) was obtained using an extrusion molding machine.
The reversible thermal discoloration-moldable resin composition was melt-spun to obtain a molded article, i.e., a reversible thermal discoloration-moldable filament.
Hair was planted on the doll head using filaments.
The filaments appear a blue-yellow mixed green color when heated to a temperature of 32 ℃ or higher.
After cooling the filaments to 10 ℃, the filaments appeared yellow upon standing.
Application example 7
30.0 parts of the microcapsule pigment containing the reversible thermal discoloration composition prepared in example 6 was mixed with a carrier composed of 45.0 parts of an acrylic resin emulsion, 1.0 part of an antifoaming agent, and 23.0 parts of dilution water, and the mixture was filtered through a 180-mesh screen to obtain a reversible thermal discoloration spray coating.
A spray gun (bore diameter 0.6mm) was filled with the spray paint to coat the entire surface of the white fabric (support), and then the resultant was dried to form a reversible thermochromic layer, thereby obtaining a reversible thermochromic fabric.
The swimsuit was produced by sewing a fabric.
Swimwear appears blue if warmed above 38 ℃.
After the swimsuit is cooled to 20 ℃, the swimsuit appears white upon standing.
Application example 8
50.0 parts of the microcapsule pigment containing the reversible thermal discoloration composition prepared in example 8 was uniformly dispersed and mixed in 50.0 parts of a linseed oil based offset ink carrier to prepare a reversible thermal discoloration offset ink.
A reversible thermochromic sheet is obtained by forming a reversible thermochromic layer on high-quality paper by offset printing using the above-mentioned offset ink.
The sheet was rubbed with a rubbing tool made of SEBS to generate heat, and the sheet was blue when heated to 32 ℃ or higher.
After the reversible thermal discoloration sheet was cooled to 5 ℃, the reversible thermal discoloration sheet appeared white after being left to stand.
Application example 9
50.0 parts of the microcapsule pigment containing the reversible thermal discoloration composition prepared in example 9 was uniformly dispersed and mixed in 50.0 parts of a linseed oil based offset ink carrier to prepare a reversible thermal discoloration offset ink.
On high-quality paper, offset printing was performed using an offset ink to form a reversible thermochromic layer, thereby obtaining a reversible thermochromic sheet.
Blue in color if warmed above 32 c from the sheet using an electrical heating tool.
After the reversible thermal discoloration sheet was cooled to 24 ℃ and left to stand for a while, the reversible thermal discoloration sheet appeared white.
Claims (11)
1. A reversible thermal discoloration microcapsule pigment having encapsulated therein a reversible thermal discoloration composition comprising:
(a) an electron-donating color-developing organic compound;
(b) an electron-accepting compound which is a hydroxyphenyl acetate compound represented by the following general formula (1);
(c) a compound selected from the group consisting of chain hydrocarbons, alicyclic hydrocarbons and halogenated hydrocarbons as a reaction medium in which an electron transfer reaction between the component (a) and the component (b) reversibly occurs; and
(d) a styrene compound having a softening point of 5 ℃ or higher and a weight average molecular weight of 200 to 10 ten thousand,
and the reversible thermal discoloration composition changes from a decolorized state to a colored state by heating and changes from the colored state to the decolorized state by lowering the temperature,
in the formula (I), the compound is shown in the specification,
r represents a linear or branched alkyl group having 12 to 22 carbon atoms,
x, Y and Z are each independently hydrogen or hydroxy, two of them are hydroxy and the remainder are hydrogen, or three of them are hydroxy.
2. The microcapsule pigment of claim 1, both of X, Y and Z being hydroxyl groups, one being hydrogen.
3. The microcapsule pigment of claim 1, X and Y are hydroxyl groups, and Z is hydrogen.
4. The microcapsule pigment according to any one of claims 1 to 3, wherein R is a linear alkyl group having 12 to 22 carbon atoms.
5. The microcapsule pigment according to any one of claims 1 to 4, wherein R is a linear alkyl group having 16 to 20 carbon atoms.
6. The microcapsule pigment according to any one of claims 1 to 5, further comprising (e) a compound having a melting point of 50 ℃ or higher selected from alcohols, esters, ketones, ethers, acid amides, and aromatic hydrocarbons.
7. The microcapsule pigment according to claim 6, wherein the component (e) is a compound selected from the group consisting of esters, ethers and aromatic hydrocarbons.
8. A reversible thermal discoloration liquid composition comprising the microcapsule pigment according to any one of claims 1 to 7, and a carrier.
9. The composition according to claim 8, wherein the microcapsule pigment is contained in an amount of 5 to 40% by mass based on the total mass of the liquid composition.
10. A laminate comprising: a support; a reversible thermochromic layer comprising the microcapsule pigment of any one of claims 1 to 7.
11. A molded article comprising the microcapsule pigment according to any one of claims 1 to 7 in a support.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2019-063576 | 2019-03-28 | ||
JP2019063576 | 2019-03-28 | ||
JP2020-013508 | 2020-01-30 | ||
JP2020013508 | 2020-01-30 | ||
PCT/JP2020/011594 WO2020196073A1 (en) | 2019-03-28 | 2020-03-17 | Reversible thermochromic microcapsule pigment |
Publications (1)
Publication Number | Publication Date |
---|---|
CN113767159A true CN113767159A (en) | 2021-12-07 |
Family
ID=72610161
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202080025196.3A Pending CN113767159A (en) | 2019-03-28 | 2020-03-17 | Reversible thermochromic microcapsule pigments |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP7443335B2 (en) |
CN (1) | CN113767159A (en) |
WO (1) | WO2020196073A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023100627A1 (en) * | 2021-11-30 | 2023-06-08 | 株式会社パイロットコーポレーション | Reversibly thermochromic microcapsule pigment |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW554027B (en) * | 2001-10-18 | 2003-09-21 | New Prismatic Entpr Co Ltd | Reversible thermochromic composition |
CN103080269A (en) * | 2010-08-06 | 2013-05-01 | 德山株式会社 | Photochromic composition |
JP2013159706A (en) * | 2012-02-06 | 2013-08-19 | Pilot Ink Co Ltd | Reversible thermochromic microencapsulated pigment |
JP2013231138A (en) * | 2012-04-30 | 2013-11-14 | Pilot Ink Co Ltd | Reversible thermochromic microcapsulated pigment |
JP2014094554A (en) * | 2012-10-11 | 2014-05-22 | Pilot Ink Co Ltd | Reversible thermochromism print |
JP2017014328A (en) * | 2015-06-29 | 2017-01-19 | パイロットインキ株式会社 | Reversible thermochromic microcapsule pigment |
FR3063082A1 (en) * | 2017-02-17 | 2018-08-24 | Societe Bic | NOVEL THERMOCHROME PIGMENT COMPOSITION COMPRISING A COMPOUND OF FORMULA (I) AS A REACTIONAL MEDIUM |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5919329B2 (en) * | 1979-12-27 | 1984-05-04 | 石原産業株式会社 | Electrophotographic materials |
JP2000263947A (en) | 1999-03-17 | 2000-09-26 | Nippon Paper Industries Co Ltd | Heat-sensitive recording body |
FR2953289B1 (en) | 2009-11-30 | 2012-04-27 | Snecma | METHOD AND DEVICE FOR MONITORING TORSION VIBRATIONS OF A ROTARY SHAFT OF A TURBOMACHINE. |
US9126451B2 (en) | 2013-12-18 | 2015-09-08 | Appvion, Inc. | Thermal recording materials |
-
2020
- 2020-03-17 CN CN202080025196.3A patent/CN113767159A/en active Pending
- 2020-03-17 WO PCT/JP2020/011594 patent/WO2020196073A1/en active Application Filing
- 2020-03-17 JP JP2021509112A patent/JP7443335B2/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW554027B (en) * | 2001-10-18 | 2003-09-21 | New Prismatic Entpr Co Ltd | Reversible thermochromic composition |
CN103080269A (en) * | 2010-08-06 | 2013-05-01 | 德山株式会社 | Photochromic composition |
JP2013159706A (en) * | 2012-02-06 | 2013-08-19 | Pilot Ink Co Ltd | Reversible thermochromic microencapsulated pigment |
JP2013231138A (en) * | 2012-04-30 | 2013-11-14 | Pilot Ink Co Ltd | Reversible thermochromic microcapsulated pigment |
JP2014094554A (en) * | 2012-10-11 | 2014-05-22 | Pilot Ink Co Ltd | Reversible thermochromism print |
JP2017014328A (en) * | 2015-06-29 | 2017-01-19 | パイロットインキ株式会社 | Reversible thermochromic microcapsule pigment |
FR3063082A1 (en) * | 2017-02-17 | 2018-08-24 | Societe Bic | NOVEL THERMOCHROME PIGMENT COMPOSITION COMPRISING A COMPOUND OF FORMULA (I) AS A REACTIONAL MEDIUM |
Non-Patent Citations (1)
Title |
---|
黄承亚,等: "热致变色橡胶及其应用", 橡胶科技市场, no. 06, 31 December 2003 (2003-12-31), pages 15 - 18 * |
Also Published As
Publication number | Publication date |
---|---|
WO2020196073A1 (en) | 2020-10-01 |
JPWO2020196073A1 (en) | 2020-10-01 |
JP7443335B2 (en) | 2024-03-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US9695329B2 (en) | Thermochromic color-memory composition and thermochromic color-memory microcapsule pigment encapsulating same | |
JP5875520B2 (en) | Temperature-sensitive color change color memory microcapsule pigment | |
EP3333240B1 (en) | Thermochromic color-memory composition and thermochromic color-memory microcapsule pigment encapsulating same | |
JP4782542B2 (en) | Temperature-sensitive color-change color memory composition and temperature-sensitive color-change color memory microcapsule pigment containing the same | |
JP6437465B2 (en) | Temperature-sensitive color-change color memory composition and temperature-sensitive color-change color memory microcapsule pigment containing the same | |
US11060018B2 (en) | Reversibly thermochromic composition and reversibly thermochromic microcapsule pigment encapsulating the same | |
EP3192845B1 (en) | Thermochromic color-memory composition and thermochromic color-memory microcapsule pigment including same | |
JP6851787B2 (en) | Reversible thermochromic microcapsule pigments, as well as liquid compositions and laminates containing them | |
JP7068267B2 (en) | Thermochromic color memorizing composition and its contained thermochromic color memorizing microcapsule pigment | |
CN113767159A (en) | Reversible thermochromic microcapsule pigments | |
JP6800032B2 (en) | Reversible thermochromic composition and reversible thermochromic microcapsule pigment containing it | |
US20230383175A1 (en) | Reversibly thermochromic composition and reversibly thermochromic microcapsule pigment encapsulating the same | |
JP2010001339A (en) | Reversible thermochromic composition and reversible thermochromic microcapsule pigment containing it | |
JP2012229294A (en) | Reversible thermochromic composition, and reversible thermochromic microcapsule pigment including the same | |
JP2015086233A (en) | Reversible thermochromic liquid composition and reversible thermochromic laminate using the same | |
JP2018123204A (en) | Reversible thermochromic composition and reversible thermochromic microcapsule pigment containing the same | |
JP4575789B2 (en) | Reversible thermochromic microcapsule pigment encapsulating a reversible thermochromic composition | |
JP2013010810A (en) | Reversible thermochromic composition and reversible thermochromic microcapsuled pigment including the same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |