CN113698889A - Novel anti-aging isooctyl ester insulating tape and production process thereof - Google Patents

Novel anti-aging isooctyl ester insulating tape and production process thereof Download PDF

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Publication number
CN113698889A
CN113698889A CN202110933772.0A CN202110933772A CN113698889A CN 113698889 A CN113698889 A CN 113698889A CN 202110933772 A CN202110933772 A CN 202110933772A CN 113698889 A CN113698889 A CN 113698889A
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China
Prior art keywords
glue
aging
base material
insulating tape
production process
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CN202110933772.0A
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Chinese (zh)
Inventor
廖平湘
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Xintian Derun New Material Industrial Park Co ltd
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Xintian Derun New Material Industrial Park Co ltd
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Priority to CN202110933772.0A priority Critical patent/CN113698889A/en
Publication of CN113698889A publication Critical patent/CN113698889A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/50Adhesives in the form of films or foils characterised by a primer layer between the carrier and the adhesive
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/302Applications of adhesives in processes or use of adhesives in the form of films or foils for bundling cables
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/40Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a novel anti-aging isooctyl ester insulating tape and a production process thereof, and the production process comprises the following steps: a raw material preparation stage, a coking stage, an asphalt coating stage, a glue preparation stage, a glue coating stage, a packaging and storing stage, through the steps, the back surface of the base material is coked to form a coking layer, so that the ageing resistance of the back surface of the base material is improved, the anti-aging performance of the inner side of the base material is improved through the arranged asphalt coating, the anti-oxidation performance of the glue is enhanced through the arranged glue, the possibility of oxidation of the glue in the air is reduced by adding the antioxidant into the glue, the flame retardant performance of the glue is enhanced through adding the silicon resin flame retardant, thereby improving the flame retardant property of the adhesive tape, and combining the steps to ensure that the anti-aging property of the insulating adhesive tape is more excellent, and the flame retardant property of the insulating tape is improved, so that the possibility of aging is reduced after the insulating tape is exposed to air for a long time in the use process, and the insulating tape is used for a longer time and is safer.

Description

Novel anti-aging isooctyl ester insulating tape and production process thereof
Technical Field
The invention relates to the field of isooctyl ester insulating tapes, in particular to a novel anti-aging isooctyl ester insulating tape and a production process thereof.
Background
The utility model provides an insulating tape is used for preventing the electric leakage that the special finger electric work of insulating tape used, the sticky tape of insulating effect, it is an electrician's class consumptive material, also known as insulating tape, the rubberized tape area, electrician's rubberized tape, constitute by baseband and pressure sensitive adhesive layer, be used for wrapping up naked end of a thread or metal and make it reach insulating effect, avoid unexpected electric shock or short circuit, traditional insulating tape is at the in-process of in-service use, insulating tape exposes externally, easy ageing, and pressure sensitive adhesive layer is along with exposing for a long time, the same easy oxidative aging, consequently, need a new insulating tape that ageing resistance is good.
Disclosure of Invention
The invention mainly aims to provide a novel anti-aging isooctyl ester insulating tape and a production process thereof, which can effectively solve the problems in the background art.
In order to achieve the purpose, the invention adopts the technical scheme that:
a novel anti-aging isooctyl ester insulating tape and a production process thereof comprise the following steps:
s1, a raw material preparation stage, wherein various raw materials including a base material, an asphalt coating, polyamide resin, isooctyl acrylate glue, an antioxidant, a silicone resin flame retardant, titanium dioxide and vinyl triamine are prepared;
s2, in the coking stage, uniformly paving the base material in a sealed bin, wherein an electric heating device is arranged above the sealed bin, and inert gas is filled into the sealed bin to realize coking treatment on one surface of the base material;
s3, asphalt coating, namely coating the other side of the uncoked base material obtained in the previous step with asphalt paint;
s4, in a glue preparation stage, preparing polyamide resin, isooctyl acrylate glue, an antioxidant, a silicone resin flame retardant, titanium dioxide and vinyl triamine according to a weight ratio, wherein the polyamide resin accounts for 4-6%, the isooctyl acrylate glue accounts for 65-70%, the antioxidant accounts for 2-5% and the silicone resin flame retardant accounts for 9-14%; 5-8% of titanium dioxide and 15-20% of vinyl triamine are uniformly mixed to prepare glue;
s5, in the glue smearing stage, smearing the glue prepared in the previous step on the base material and locating above the asphalt coating;
s6, packaging and storing, namely, after the manufactured adhesive tape is packaged, filling nitrogen into a packaging bag, and sealing and storing;
preferably, in the step S1, the antioxidant selected is antioxidant 168.
Preferably, in step S2, the heating temperature in the sealed bin should be between 100 and 150, the sealed bin is filled with water before use to detect the air tightness of the sealed bin, after the detection is completed, the water is discharged and dried, after the drying is completed, the base material is laid on the bottom surface of the sealed bin, and the coking time is 0.5-1 hour.
Preferably, in the step S3, during the asphalt coating process, the asphalt is heated so that the temperature of the asphalt liquid is maintained between 50 and 60 degrees celsius.
Preferably, in the step S4, a stirrer is used to mix the raw materials, the stirring time is 2-3 hours, and the temperature of the raw materials is maintained between 60-80 ℃ during mixing.
Preferably, in the step S5, the glue prepared in the previous step is applied to the substrate and located on the asphalt coating, and in the application process, the temperature of the adhesive tape is kept between 50 and 60 ℃, and the adhesive tape is rapidly applied, wherein the thickness of the coating is 1 to 2 mm.
Compared with the prior art, the novel anti-aging isooctyl ester insulating tape and the production process thereof have the advantages that the back surface of the base material is coked in the coking stage to form a coking layer, the anti-aging performance of the back surface of the base material is enhanced, the oxidation resistance of the inner side of the base material is enhanced through the arranged asphalt coating, the antioxidant is added into the configured glue, the oxidation resistance of the glue is enhanced, the possibility of oxidation aging of the glue coating is reduced, and the flame retardant performance of the adhesive tape is improved through the added silicone resin flame retardant, so that the flame retardant performance of the adhesive tape is better.
Drawings
FIG. 1 is a production step diagram of the novel anti-aging isooctyl ester insulating tape and the production process thereof.
Detailed Description
In order to make the technical means, the creation characteristics, the achievement purposes and the effects of the invention easy to understand, the invention is further described with the specific embodiments.
As shown in figure 1, the novel anti-aging isooctyl ester insulating tape and the production process thereof comprise the following steps:
s1, a raw material preparation stage, wherein various raw materials including a base material, an asphalt coating, polyamide resin, isooctyl acrylate glue, an antioxidant, a silicone resin flame retardant, titanium dioxide and vinyl triamine are prepared;
s2, in the coking stage, uniformly paving the base material in a sealed bin, wherein an electric heating device is arranged above the sealed bin, and inert gas is filled into the sealed bin to realize coking treatment on one surface of the base material;
s3, asphalt coating, namely coating the other side of the uncoked base material obtained in the previous step with asphalt paint;
s4, in a glue preparation stage, preparing polyamide resin, isooctyl acrylate glue, an antioxidant, a silicone resin flame retardant, titanium dioxide and vinyl triamine according to a weight ratio, wherein the polyamide resin accounts for 4-6%, the isooctyl acrylate glue accounts for 65-70%, the antioxidant accounts for 2-5% and the silicone resin flame retardant accounts for 9-14%; 5-8% of titanium dioxide and 15-20% of vinyl triamine are uniformly mixed to prepare glue;
s5, in the glue smearing stage, smearing the glue prepared in the previous step on the base material and locating above the asphalt coating;
and S6, packaging and storing, namely, after the manufactured adhesive tape is packaged, filling nitrogen into a packaging bag, and sealing and storing.
In the step S1, the antioxidant 168 is selected; in step S2, the heating temperature in the sealed cabin is between 100 and 150 ℃, water is filled in the sealed cabin before use to detect the air tightness of the sealed cabin, water is discharged after detection is finished, air drying is carried out, the base material is flatly laid on the bottom surface of the sealed cabin after air drying is finished, and the coking time is 0.5-1 hour; s3, heating the asphalt in the asphalt coating process to keep the temperature of the asphalt liquid between 50 and 60 ℃; in the S4 process, mixing various raw materials by a stirrer for 2-3 hours, and keeping the temperature of the raw materials between 60-80 ℃ during mixing; and S5, coating the glue prepared in the previous step on the base material and on the asphalt coating, wherein in the coating process, the temperature of the adhesive tape is kept between 50 and 60 ℃, and the adhesive tape is quickly coated, wherein the thickness of the coating is 1 to 2 mm.
The invention relates to a novel anti-aging isooctyl ester insulating tape and a production process thereof, which comprises the steps of preparing various raw materials, carrying out air tightness test on a sealed bin, flushing liquid water into the sealed bin, observing whether the liquid water leaks out of the sealed bin, if the liquid water leaks out, leading the sealed bin on the surface to be air-leaking, treating the air-leaking part, or replacing another sealed bin for carrying out air tightness test, if the sealed bin does not leak water, indicating that the sealed bin does not leak air, discharging the liquid water in the sealed bin, leading hot air into the sealed bin for drying or airing, drying the sealed bin after drying the sealed bin, cooling, installing a heating device, uniformly laying one surface of a base material on the bottom surface of the sealed bin, starting the heating device, keeping the heating temperature between 100 and 150 ℃, flushing inert gas into the sealed bin, the method comprises the steps of avoiding ignition of a base material, coking one side of the base material for 0.5-1 hour to coke one side of the base material to form a coking layer, enhancing the anti-aging capacity of one side of an adhesive tape, enhancing the partial insulating property of the base material by the coked base material, taking out the base material after coking, winding and accommodating, taking out asphalt liquid in the material, heating the asphalt liquid at 50-60 ℃, smearing the non-coked inner side of the base material, quickly performing atomization spraying on the inner side of the base material in an atomization spraying mode, drying the sprayed base material while spraying to quickly dry an asphalt thin layer on the inner side of the base material, preparing glue, and mixing polyamide resin, isooctyl acrylate glue, an antioxidant, and the like, The preparation method comprises the steps of preparing a silicone resin flame retardant, titanium dioxide and vinyl triamine according to weight percentage, sequentially adding the materials into a stirrer, wherein the stirrer adopts a dispersing stirrer, after the materials are placed into the dispersing stirrer, the stirring time is 2-3 hours, the temperature of the materials is kept between 60 ℃ and 80 ℃ in the mixing process, the materials are uniformly dispersed through the dispersing stirrer, so that the prepared glue has an emulsifying effect, wherein the antioxidant is antioxidant 168, the antioxidant capacity of the prepared glue is enhanced through the added antioxidant 168, the aging of the glue is mainly caused by exposure to air and oxidation with air, so that the aging resistance of the glue is improved, the added silicone resin flame retardant enhances the flame retardant performance of the glue, so that the flame retardant performance of the insulating tape is improved, and the flame retardant performance of the insulating tape is more excellent, after glue is configured, the base material is coated in an atomization spraying mode, in the coating process, the temperature of the adhesive tape is kept between 50 and 60 ℃, the adhesive tape is quickly sprayed, the thickness of the coating is 1 to 2mm, after the spraying is completed, the adhesive tape is wound and stored, the adhesive tape is placed into a packaging bag, nitrogen is filled into the packaging bag, the sealing is kept, and the oxidation and the aging are avoided.
The foregoing shows and describes the general principles and broad features of the present invention and advantages thereof. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.

Claims (6)

1. A novel anti-aging isooctyl ester insulating tape and a production process thereof are characterized in that: the method comprises the following steps:
s1, a raw material preparation stage, wherein various raw materials including a base material, an asphalt coating, polyamide resin, isooctyl acrylate glue, an antioxidant, a silicone resin flame retardant, titanium dioxide and vinyl triamine are prepared;
s2, in the coking stage, uniformly paving the base material in a sealed bin, wherein an electric heating device is arranged above the sealed bin, and inert gas is filled into the sealed bin to realize coking treatment on one surface of the base material;
s3, asphalt coating, namely coating the other side of the uncoked base material obtained in the previous step with asphalt paint;
s4, in a glue preparation stage, preparing polyamide resin, isooctyl acrylate glue, an antioxidant, a silicone resin flame retardant, titanium dioxide and vinyl triamine according to a weight ratio, wherein the polyamide resin accounts for 4-6%, the isooctyl acrylate glue accounts for 65-70%, the antioxidant accounts for 2-5% and the silicone resin flame retardant accounts for 9-14%; 5-8% of titanium dioxide and 15-20% of vinyl triamine are uniformly mixed to prepare glue;
s5, in the glue smearing stage, smearing the glue prepared in the previous step on the base material and locating above the asphalt coating;
and S6, packaging and storing, namely, after the manufactured adhesive tape is packaged, filling nitrogen into a packaging bag, and sealing and storing.
2. The novel anti-aging isooctyl ester insulating tape and the production process thereof as claimed in claim 1, wherein: in the step S1, the antioxidant 168 is selected.
3. The novel anti-aging isooctyl ester insulating tape and the production process thereof as claimed in claim 1, wherein: in the step S2, the heating temperature in the sealed cabin should be between 100 and 150, the sealed cabin is filled with water before use to detect the air tightness of the sealed cabin, after the detection is completed, the water is discharged and dried, after the drying is completed, the base material is laid on the bottom surface of the sealed cabin, and the coking time is 0.5-1 hour.
4. The novel anti-aging isooctyl ester insulating tape and the production process thereof as claimed in claim 1, wherein: in the step S3, in the process of smearing the asphalt, the asphalt is heated so that the temperature of the asphalt liquid is kept between 50 and 60 ℃.
5. The novel anti-aging isooctyl ester insulating tape and the production process thereof as claimed in claim 1, wherein: and in the S4 process, mixing various raw materials by using a stirrer, wherein the stirring time is 2-3 hours, and the temperature of the raw materials is kept between 60 ℃ and 80 ℃ during mixing.
6. The novel anti-aging isooctyl ester insulating tape and the production process thereof as claimed in claim 1, wherein: and in the step S5, the glue prepared in the previous step is smeared on the base material and is positioned on the asphalt coating, in the smearing process, the temperature of the adhesive tape is kept between 50 and 60 ℃, the adhesive tape is quickly smeared, and the thickness of the coating is 1 to 2 mm.
CN202110933772.0A 2021-08-15 2021-08-15 Novel anti-aging isooctyl ester insulating tape and production process thereof Pending CN113698889A (en)

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Application Number Priority Date Filing Date Title
CN202110933772.0A CN113698889A (en) 2021-08-15 2021-08-15 Novel anti-aging isooctyl ester insulating tape and production process thereof

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108948947A (en) * 2018-05-29 2018-12-07 安徽省通信产业服务有限公司 A method of slowing down insulating tape aging
CN110565310A (en) * 2019-08-30 2019-12-13 安徽省通信产业服务有限公司 Anti-aging method for insulating adhesive tape
CN110564313A (en) * 2019-08-30 2019-12-13 安徽省通信产业服务有限公司 Method for slowing down aging of insulating tape

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108948947A (en) * 2018-05-29 2018-12-07 安徽省通信产业服务有限公司 A method of slowing down insulating tape aging
CN110565310A (en) * 2019-08-30 2019-12-13 安徽省通信产业服务有限公司 Anti-aging method for insulating adhesive tape
CN110564313A (en) * 2019-08-30 2019-12-13 安徽省通信产业服务有限公司 Method for slowing down aging of insulating tape

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张开 主编: "《粘合与密封材料》", 30 June 1996, 化学工业出版社 *
李兰亭 主编: "《木材加工材料学》", 31 March 1992, 东北林业大学出版社 *

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Application publication date: 20211126