CN113697906A - Eutrophic water body self-purification device and method - Google Patents
Eutrophic water body self-purification device and method Download PDFInfo
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- CN113697906A CN113697906A CN202111028905.6A CN202111028905A CN113697906A CN 113697906 A CN113697906 A CN 113697906A CN 202111028905 A CN202111028905 A CN 202111028905A CN 113697906 A CN113697906 A CN 113697906A
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- photovoltaic
- water body
- anode
- eutrophic water
- magnesium
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 65
- 238000000746 purification Methods 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 14
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 26
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011777 magnesium Substances 0.000 claims abstract description 11
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 10
- 238000010248 power generation Methods 0.000 claims abstract description 9
- 229910021421 monocrystalline silicon Inorganic materials 0.000 claims abstract description 7
- 229910052567 struvite Inorganic materials 0.000 claims description 21
- MXZRMHIULZDAKC-UHFFFAOYSA-L ammonium magnesium phosphate Chemical compound [NH4+].[Mg+2].[O-]P([O-])([O-])=O MXZRMHIULZDAKC-UHFFFAOYSA-L 0.000 claims description 18
- 239000013078 crystal Substances 0.000 claims description 15
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 12
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 11
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 claims description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 4
- 230000005611 electricity Effects 0.000 abstract description 4
- 239000001569 carbon dioxide Substances 0.000 abstract description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- CKMXBZGNNVIXHC-UHFFFAOYSA-L ammonium magnesium phosphate hexahydrate Chemical compound [NH4+].O.O.O.O.O.O.[Mg+2].[O-]P([O-])([O-])=O CKMXBZGNNVIXHC-UHFFFAOYSA-L 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 238000001420 photoelectron spectroscopy Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000000921 elemental analysis Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 230000009182 swimming Effects 0.000 description 2
- 241000195493 Cryptophyta Species 0.000 description 1
- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 235000003784 poor nutrition Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B35/00—Vessels or similar floating structures specially adapted for specific purposes and not otherwise provided for
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J7/00—Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries
- H02J7/34—Parallel operation in networks using both storage and other dc sources, e.g. providing buffering
- H02J7/35—Parallel operation in networks using both storage and other dc sources, e.g. providing buffering with light sensitive cells
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/105—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/007—Contaminated open waterways, rivers, lakes or ponds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/008—Mobile apparatus and plants, e.g. mounted on a vehicle
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/4612—Controlling or monitoring
- C02F2201/46125—Electrical variables
- C02F2201/46135—Voltage
Abstract
The invention discloses a eutrophic water body self-purification device and a eutrophic water body self-purification method, the device comprises a ship body, a photovoltaic power generation device, a constant speed cruise system and an electrolysis device are installed on the ship body, the photovoltaic power generation device comprises a solar photovoltaic panel, a photovoltaic controller and a photovoltaic storage battery, the electrolysis device comprises an anode and a cathode which are installed below the ship body and are in contact with a water body, the anode and the cathode are magnesium rods, the solar photovoltaic panel is connected with the photovoltaic storage battery through the photovoltaic controller, the photovoltaic storage battery is respectively connected with the constant speed cruise system and the anode and the cathode of the electrolysis device through leads, the solar photovoltaic panel is of a hemispherical dome-shaped structure formed by splicing a plurality of blocky monocrystalline silicon photovoltaic panels, and a support column is arranged inside the hemispherical dome-shaped structure. The invention is environment-friendly, has no carbon dioxide emission, does not need extra power supply, automatically generates and charges electricity, does not produce secondary pollution and can automatically tour and purify water.
Description
Technical Field
The invention relates to the field of water body purification, in particular to a eutrophic water body self-purification device and a self-purification method.
Background
Excessive nitrogen (N) and phosphorus (P) in the water body can cause eutrophication of the water body, and the pollution is caused by mass propagation of algae. Currently, ammonia Nitrogen (NH)4 -N) has become the leading water body pollutant in our country, compared with nitrogen of other forms, the harm brought by ammoniacal nitrogen is more extensive, complicated and lasting, how to remove nitrogen, phosphorus element in the water body is the hot spot of research all the time.
The traditional water body purification device has poor adaptability with water body equipment, cannot purify large-area water areas, and cannot meet the high-quality water purification requirement. And the cost is high, the efficiency is low, the time is consumed, the difficulty in detection, maintenance, reconstruction and upgrading is high, and secondary pollution is also brought to the water body environment. Therefore, it is necessary to provide a new simple technical solution to solve the above technical problems, and to realize a water self-purification device with simple control mode, low cost, high efficiency and outstanding purification effect.
Disclosure of Invention
In order to solve the technical problems, the invention provides a eutrophic water body self-purification device and a eutrophic water body self-purification method, so as to achieve the purposes of automatic cruising of a ship body, generation of electricity by utilizing solar photovoltaic, precipitation of electrolytic magnesium and automatic purification of a water body.
In order to achieve the purpose, the technical scheme of the invention is as follows:
the utility model provides an eutrophic water self-purification device, includes the hull, install photovoltaic power generation device, constant speed cruise system and electrolytic device on the hull, photovoltaic power generation device includes solar photovoltaic board, photovoltaic controller and photovoltaic battery, electrolytic device is including installing in the positive pole and the negative pole of hull below and water contact, positive pole and negative pole are the magnesium stick, photovoltaic battery is connected through photovoltaic controller to the solar photovoltaic board, photovoltaic battery passes through the wire and connects constant speed cruise system and electrolytic device's positive pole and negative pole respectively, the hemisphere dome type structure that the solar photovoltaic board formed for the concatenation of a plurality of cubic monocrystalline silicon photovoltaic boards, the inside support column that sets up of hemisphere dome type structure.
In the scheme, the solar photovoltaic panel is formed by splicing 21 pieces of 100ma monocrystalline silicon photovoltaic panels with phi 55 x 55 cm.
In the scheme, the specification of the magnesium rod is phi 15 x 135, and the purity is 99%.
In the scheme, the photovoltaic storage battery outputs 1.5-2V voltage to the anode and the cathode of the electrolysis device through the inverter.
A eutrophic water body self-purification method adopts the eutrophic water body self-purification device, a ship body walks in the eutrophic water body through a constant speed cruise system, a solar photovoltaic panel positioned on the ship body receives sunlight, the sunlight is converted into electric energy through a photovoltaic controller and stored in a photovoltaic storage battery, the photovoltaic storage battery provides 1.5-2V voltage for an anode and a cathode of an electrolysis device, a magnesium rod of the anode can generate magnesium ions, and the magnesium ions, ammonia nitrogen and phosphoric acid in the water body are combined to generate magnesium ammonium phosphate crystals which are deposited at the bottom of the water body, so that the water body purification is realized.
In the scheme, the depth of the magnesium rod inserted into the liquid level is 5.3 cm.
Through the technical scheme, the eutrophic water body self-purification device and the eutrophic water body self-purification method provided by the invention have the following beneficial effects:
1. the invention utilizes the hemispherical dome type solar photovoltaic panel to receive solar illumination 24 hours a day, automatically generate and store electricity, provide electric support for the electrolysis device and the constant-speed cruise system, and can continuously carry out electrolysis and cruise 24 hours a day.
2. According to the invention, the magnesium rods are used as the anode and the cathode of the electrolysis device, and under the action of current, the magnesium rods at the anode can generate magnesium ions, and the magnesium ions can be combined with ammonia nitrogen and phosphoric acid in the water body to generate magnesium ammonium phosphate crystals which are deposited at the bottom of the water body, so that the purification of the water body is realized, and the yield of the magnesium ammonium phosphate crystals can be controlled by controlling the controlled release amount of the magnesium ions by controlling the output voltage.
3. The invention is environment-friendly, has no carbon dioxide emission, does not need extra power supply, automatically generates and charges electricity, does not produce secondary pollution and can automatically tour and purify water. The water surface swimming ship model can be used as a water surface swimming ship model, can decorate and beautify lakes and reservoirs while performing a purification function, and can also prevent the pollution of water bodies of poor nutrition lakes and middle nutrition lakes and reservoirs in advance. The invention expands the efficient, convenient and self-purification method of the eutrophic lake reservoir water body, and provides a potential feasible means for 'carbon peak reaching', 'carbon neutralization' and diversified treatment of eutrophic pollution of the water body.
4. The invention can also be directly installed on a large-scale pleasure boat, and provides theoretical basis and experimental data for an extended purification device for reducing pollution by solid-borne solar power generation magnesium anode electrolysis.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below.
FIG. 1 is a schematic view of a eutrophic water body self-purification device disclosed in the embodiment of the invention;
FIG. 2 is a graph showing the effect of different electrolysis voltages on the pH of a water body;
FIG. 3 is a graph showing the influence of different electrolytic voltages on the escape rate of ammonia nitrogen;
FIG. 4 shows different electrolysis voltages vs. NH4+-graph of the effect of N removal rate;
FIG. 5 is an XRD pattern of high purity magnesium ammonium phosphate crystals and standard magnesium ammonium phosphate crystals produced by electrolysis in accordance with an embodiment of the present invention;
FIG. 6 is an XPS elemental analysis chart of magnesium ammonium phosphate crystals produced by the present invention;
FIG. 7 is a photoelectron spectroscopy analysis chart of Mg element in magnesium ammonium phosphate crystal prepared by the present invention;
FIG. 8 is a diagram of photoelectron spectroscopy analysis of the N element in the magnesium ammonium phosphate crystal prepared by the present invention;
FIG. 9 is a diagram of photoelectron spectroscopy analysis of the P element in the magnesium ammonium phosphate crystal prepared by the present invention.
In the figure, 1, a ship body; 2. a solar photovoltaic panel; 3. a photovoltaic controller; 4. a photovoltaic storage battery; 5. an anode; 6. a cathode; 7. a constant-speed cruise drive motor; 8. an inverter.
Detailed Description
The technical solution in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention.
The invention provides a eutrophic water body self-purification device, which comprises a ship body 1, wherein a photovoltaic power generation device, a constant-speed cruise system and an electrolysis device are arranged on the ship body 1, as shown in figure 1. The photovoltaic power generation device comprises a solar photovoltaic panel 2, a photovoltaic controller 3 and a photovoltaic storage battery 4, the electrolysis device comprises an anode 5 and a cathode 6 which are arranged below the ship body and are in contact with a water body, the anode 5 and the cathode 6 are magnesium rods, the specification of the magnesium rods is phi 15 x 135, the purity is 99%, and the depth of the magnesium rods inserted into the liquid level is 5.3 cm. The solar photovoltaic panel 2 is connected with a photovoltaic storage battery 4 through a photovoltaic controller 3, and the photovoltaic storage battery 4 is respectively connected with a constant-speed cruise driving motor 7 of a constant-speed cruise system and an anode 5 and a cathode 6 of an electrolysis device through leads.
The solar photovoltaic panel 2 is of a hemispherical dome-shaped structure formed by splicing a plurality of blocky monocrystalline silicon photovoltaic panels, and is beneficial to comprehensively receiving light irradiation at different times in one day. And a supporting column is arranged in the hemispherical dome-shaped structure. In this embodiment, the solar photovoltaic panel 2 is formed by splicing 21 pieces of 100ma monocrystalline silicon photovoltaic panels with phi 55 × 55cm, and has a hemispherical dome-shaped structure with a diameter of 20 cm. The photovoltaic storage battery 4 outputs a voltage of 1.5-2V to the anode 5 and the cathode 6 of the electrolysis device through the inverter 8.
A eutrophic water body self-purification method adopts the eutrophic water body self-purification device, a ship body 1 is driven by a constant speed cruise drive motor 7 of a constant speed cruise system to cruise in the eutrophic water body, sunlight is received by a solar photovoltaic plate 2 on the ship body 1 and is converted into electric energy through a photovoltaic controller 3 to be stored in a photovoltaic storage battery 4, the photovoltaic storage battery 4 provides 1.5-2V voltage for an anode 5 and a cathode 6 of an electrolysis device, a magnesium rod of the anode 5 can generate magnesium ions, ammonium magnesium phosphate crystals can be generated by combining with ammonia nitrogen and phosphoric acid in the water body and are deposited at the bottom of the water body, and therefore the water body purification is achieved.
The reactions that occur at the anode are:
Mg–2e-=Mg2+ (1)
the reactions that occur at the cathode are:
2H2O+2e-=H2↑+2OH- (2)
precipitation reaction equation (n ═ 0, 1 or 2) of magnesium ammonium phosphate (struvite) in the electrolytic cell:
HnPO4 3-n+Mg2++NH4 ++6H2O→MgNH4PO4·6H2O+nH+ (3)
the embodiment of the invention researches the electrolytic voltage output by the photovoltaic storage battery, tests the influence of different electrolytic voltages on the electrolytic process within the electrolytic voltage range of 0-12V, and the figure 2 shows the influence of different electrolytic voltages on the pH value of the water body. After the electrolytic voltage exceeds 2V, the pH value of the water body changes obviously, and the aquatic ecology can be influenced.
FIG. 3 shows the effect of different electrolysis voltages on the ammonia nitrogen escape rate, and FIG. 4 shows the effect of different electrolysis voltages on NH4+-effect of N removal rate. As can be seen from the figures 3 and 4, the escape rate of ammonia nitrogen (the part which can not be converted into struvite and escapes into the atmosphere to cause pollution) is the minimum under the voltage of 2V along with the increase of the electrolysis time, and the output voltage of the photovoltaic storage battery, which is set to be 2V, can meet the cruising of the driving motor at a constant speed and can effectively ensure the electrolysis effect.
According to faraday's law: the mass of the substance precipitated or dissolved at the electrode is proportional to the charge passed, and higher voltages can generate more magnesium ions while consuming more protons, resulting in a greater increase in solution pH. NH in solution4+Will gradually increase to NH with increasing pH3And (4) conversion, which leads to the increase of the escape rate of ammonia nitrogen. According to joule's law: with the same resistance, the amount of heat generated is proportional to the square of the voltage. The process of promoting ammonia volatilization at high temperature combines energy consumption and environmental protection factors, the 2V voltage has low energy consumption and objective recovery efficiency, and simultaneously, the generated ammonia gas is less, the influence on the environment is small, and the device is more suitable for being used as the selected voltage for electrolyzing and recovering struvite. Therefore, the voltage of no more than 2V, preferably 1.5V-2V, is adopted in the actual cruising electrolysis process.
In the embodiment of the invention, the magnesium ammonium phosphate precipitate generated by electrolysis is analyzed, an X-ray photoelectron spectrometer (Thermo Fischer, ESCALB 250Xi, USA) is used for adopting Al ka rays of 1486.6eV, and all binding energy of an XPS spectrum is used for carrying out charge correction by using C1 s-284.80 eV binding energy as an energy standard. Fitting atomic data for Mg, N and P using XPS peak software, XRD of the highly pure magnesium ammonium phosphate crystals as shown in figure 5 was obtained in good agreement with the XRD pattern of the standard magnesium ammonium phosphate samples, compared to the standard electron binding energy.
FIGS. 6 to 9 show XPS elemental analysis of struvite crystals prepared according to the present invention, and photoelectron spectroscopy analysis of respective Mg, N and P elements. As can be seen from the above figures, the magnesium ammonium phosphate crystals produced by electrolysis in accordance with the present invention are highly consistent with the magnesium ammonium phosphate crystals in the standard sample. The experimental product magnesium ammonium phosphate was demonstrated to be of high purity.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.
Claims (6)
1. The utility model provides an eutrophic water self-purification device, a serial communication port, includes the hull, install photovoltaic power generation device, constant speed system of cruising and electrolytic device on the hull, photovoltaic power generation device includes solar photovoltaic board, photovoltaic controller and photovoltaic battery, electrolytic device is including installing in the positive pole and the negative pole of hull below and water contact, positive pole and negative pole are the magnesium stick, the photovoltaic battery is connected through photovoltaic controller to the solar photovoltaic board, the photovoltaic battery passes through the wire and connects constant speed system of cruising and electrolytic device's positive pole and negative pole respectively, the hemisphere dome type structure that the solar photovoltaic board formed for the concatenation of a plurality of cubic monocrystalline silicon photovoltaic boards, the inside support column that sets up of hemisphere dome type structure.
2. The eutrophic water body self-purification device of claim 1, wherein the solar photovoltaic panel is formed by splicing 21 pieces of 100ma monocrystalline silicon photovoltaic panels with phi 55 x 55 cm.
3. The eutrophic water body self-purification device of claim 1, wherein the specification of the magnesium rod is phi 15 x 135, and the purity is 99%.
4. The eutrophic water body self-purification device of claim 1, wherein the photovoltaic storage battery outputs 1.5-2V to the anode and the cathode of the electrolysis device through an inverter.
5. The eutrophic water body self-purification method adopts the eutrophic water body self-purification device as claimed in claim 1, and is characterized in that the ship body patrols in the eutrophic water body through a constant speed cruising system, a solar photovoltaic panel positioned on the ship body receives sunlight, the sunlight is converted into electric energy through a photovoltaic controller and stored in a photovoltaic storage battery, the photovoltaic storage battery provides 1.5-2V voltage for an anode and a cathode of the electrolysis device, a magnesium rod of the anode can generate magnesium ions, and the magnesium ions are combined with ammonia nitrogen and phosphoric acid in the water body to generate magnesium ammonium phosphate crystals which are deposited on the water bottom, so that the water body is purified.
6. The eutrophic water body self-purification method of claim 5, wherein the magnesium rod is inserted into the water surface to a depth of 5.3 cm.
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102992454A (en) * | 2012-12-06 | 2013-03-27 | 刘通 | Method and device for treating water body pollution by solar energy |
CN110357219A (en) * | 2019-06-28 | 2019-10-22 | 湖北美辰环保股份有限公司 | A kind of efficient recovery of nitrogen and phosphorus electrochemical reaction system |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102992454A (en) * | 2012-12-06 | 2013-03-27 | 刘通 | Method and device for treating water body pollution by solar energy |
CN110357219A (en) * | 2019-06-28 | 2019-10-22 | 湖北美辰环保股份有限公司 | A kind of efficient recovery of nitrogen and phosphorus electrochemical reaction system |
Non-Patent Citations (1)
Title |
---|
刘长发等: "《中国建材产业发展研究论文集》", 31 May 2010, 北京:中国建材工业出版社 * |
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