CN113683834A - Melt-blown hydrophilic master batch and preparation method thereof - Google Patents
Melt-blown hydrophilic master batch and preparation method thereof Download PDFInfo
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- CN113683834A CN113683834A CN202010423677.1A CN202010423677A CN113683834A CN 113683834 A CN113683834 A CN 113683834A CN 202010423677 A CN202010423677 A CN 202010423677A CN 113683834 A CN113683834 A CN 113683834A
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- 239000004594 Masterbatch (MB) Substances 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims description 6
- -1 polypropylene Polymers 0.000 claims abstract description 10
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 5
- 229920001971 elastomer Polymers 0.000 claims abstract description 4
- 239000000806 elastomer Substances 0.000 claims abstract description 4
- 239000003999 initiator Substances 0.000 claims abstract description 4
- 239000000314 lubricant Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 6
- 239000000498 cooling water Substances 0.000 claims description 6
- 238000001125 extrusion Methods 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 3
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical group CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 7
- 229920001155 polypropylene Polymers 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000004745 nonwoven fabric Substances 0.000 abstract description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 239000004750 melt-blown nonwoven Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
- C08K5/526—Esters of phosphorous acids, e.g. of H3PO3 with hydroxyaryl compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention relates to a melt-blown hydrophilic master batch, which comprises the following components in percentage by mass: 20-40 parts of a hydrophilic agent; 1-3 parts of a lubricant; 0.1-0.5 part of antioxidant 1010; antioxidant 168 in 0.2-1 weight portion; 4-10 parts of elastomer; initiator 0.3-0.8 weight portions; 50-70 parts of polypropylene. The master batch produced by the invention is a high-concentration hydrophilic master batch, the hydrophilic effect can be achieved only in 3-7 days or even longer time under the condition that the addition amount of the general hydrophilic master batch is 2-4% in the production of non-woven fabric products, and the hydrophilic effect can be advanced to about 1-3 days by the same addition amount of the master batch produced by the formula process.
Description
Technical Field
The invention relates to a melt-blown hydrophilic master batch and a preparation method thereof.
Background
The polypropylene melt-blown non-woven fabric is a superfine short fiber non-woven fabric formed by directly forming a net by melt spinning polypropylene chips, and can be used as a sanitary material, a filter material and a battery separator, and the polypropylene melt-blown fabric is required to have certain moisture absorption capacity. However, polypropylene melt-blown fabric hardly absorbs moisture due to the nonpolar structure and extremely strong crystallinity of polypropylene, and the polypropylene product is mainly subjected to after-treatment modification in the market at present to achieve a hydrophilic effect. But this increases the equipment investment and also reduces the production speed. The other method is to add spun-bonded hydrophilic master batch for modification, but the formula is not suitable for melt-blown cloth and is easy to block a spinneret orifice.
Disclosure of Invention
In view of the above, the present invention provides a meltblown hydrophilic masterbatch to solve the above problems.
In order to achieve the purpose, the invention adopts the melt-blown hydrophilic master batch which is characterized in that: the composition comprises the following components in parts by mass:
the invention further provides that: the hydrophilic agent is a nonionic surfactant.
The invention further provides that: the lubricant is ethylene bis stearamide.
The invention further provides that: the antioxidant tetra 1010 is tetra (3, 5-di-tert-butyl-4-hydroxy) phenylpropionic acid pentaerythritol ester.
The invention further provides that: the antioxidant 168 is tris (2, 4-di-tert-butylphenyl) phosphite.
The invention further provides that: the elastomer is a polymer of 1-octene and ethylene.
The invention further provides that: the initiator A is di-tert-butyl peroxide.
The invention also provides a preparation method of the melt-blown hydrophilic master batch, which comprises the following steps:
adding the materials into a mixing pot according to the parts by weight, and then opening the mixing pot for mixing for 3 minutes; and 2, pouring the mixture into a feeding machine, wherein the feeding machine is a double-screw feeding machine, the feeding machine is provided with a cooling water channel, and the temperature of cooling water is controlled to be lower than the melting point temperature of the hydrophilic agent, so that the mixture is ensured to enter the screw in a powder state. 3-the material enters a screw of a double-screw feeder, and the temperature of the feed inlet part is set to be 0 ℃. 4-melt extrusion, namely extruding the material in the step 3 through a screw extruder; the screw extruder comprises twelve zones, wherein the temperature of the first zone is 0 ℃, the temperature of the second zone is 50 ℃, the temperature of the third zone is 80 ℃, the temperature of the fourth zone is 120 ℃, the temperature of the fifth zone is 160 ℃, the temperature of the sixth zone is 175 ℃, the temperature of the seventh zone is 175 ℃, the temperature of the eighth zone is 170 ℃, the temperature of the ninth zone is 160 ℃, the temperature of the tenth zone is 155 ℃, the temperature of the eleventh zone is 155 ℃ and the temperature of the twelfth zone is 150 ℃.
The invention has the beneficial effects that: the master batch produced by the invention is a high-concentration hydrophilic master batch, the hydrophilic effect can be achieved only in 3-7 days or even longer time under the condition that the addition amount of the general hydrophilic master batch is 2-4% in the production of non-woven fabric products, and the hydrophilic effect can be advanced to about 1-3 days by the same addition amount of the master batch produced by the formula process.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention more apparent, the technical solutions of the present invention are described clearly and completely below, and it is obvious that the described embodiments are a part of the embodiments of the present invention, not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention relates to a melt-blown hydrophilic master batch, which is characterized in that: the composition comprises the following components in parts by mass:
the invention further provides that: the hydrophilic agent is a nonionic surfactant.
The invention further provides that: the lubricant is ethylene bis stearamide.
The invention further provides that: the antioxidant tetra 1010 is tetra (3, 5-di-tert-butyl-4-hydroxy) phenylpropionic acid pentaerythritol ester.
The invention further provides that: the antioxidant 168 is tris (2, 4-di-tert-butylphenyl) phosphite.
The invention further provides that: the elastomer is a polymer of 1-octene and ethylene.
The invention further provides that: the initiator A is di-tert-butyl peroxide.
The invention also provides a preparation method of the melt-blown hydrophilic master batch, which comprises the following steps:
adding the materials into a mixing pot according to the parts by weight, and then opening the mixing pot for mixing for 3 minutes; and 2, pouring the mixture into a feeding machine, wherein the feeding machine is a double-screw feeding machine, the feeding machine is provided with a cooling water channel, and the temperature of cooling water is controlled to be lower than the melting point temperature of the hydrophilic agent, so that the mixture is ensured to enter the screw in a powder state. 3-the material enters a screw of a double-screw feeder, and the temperature of the feed inlet part is set to be 0 ℃. 4-melt extrusion, namely extruding the material in the step 3 through a screw extruder; wherein the screw extruder has twelve zones, the temperature of the first zone is 0 ℃, the temperature of the second zone is 50 ℃, the temperature of the third zone is 80 ℃, the temperature of the fourth zone is 120 ℃, the temperature of the fifth zone is 160 ℃, the temperature of the sixth zone is 175 ℃, the temperature of the seventh zone is 175 ℃, the temperature of the eighth zone is 170 ℃, the temperature of the ninth zone is 160 ℃, the temperature of the tenth zone is 155 ℃, the temperature of the eleventh zone is 155 ℃, the temperature of the twelfth zone is 150 ℃, wherein the extrusion temperature of the head is 150 ℃, and further the main machine speed is 480(r/min) and the feeding speed is 20 (r/min).
The invention has the beneficial effects that: the master batch produced by the invention is a high-concentration hydrophilic master batch, the hydrophilic effect can be achieved only in 3-7 days or even longer time under the condition that the addition amount of the general hydrophilic master batch is 2-4% in the production of non-woven fabric products, and the hydrophilic effect can be advanced to about 1-3 days by the same addition amount of the master batch produced by the formula process.
Finally, it should be noted that: the above-mentioned embodiments are only specific embodiments of the present invention, which are used for illustrating the technical solutions of the present invention and not for limiting the same, and the protection scope of the present invention is not limited thereto, although the present invention is described in detail with reference to the foregoing embodiments, those skilled in the art should understand that: any person skilled in the art can modify or easily conceive the technical solutions described in the foregoing embodiments or equivalent substitutes for some technical features within the technical scope of the present disclosure; such modifications, changes or substitutions do not depart from the spirit and scope of the embodiments of the present invention, and they should be construed as being included therein. Therefore, the protection scope of the present invention shall be subject to the protection scope of the claims.
Claims (8)
1. A melt-blown hydrophilic masterbatch is characterized in that: the composition comprises the following components in parts by mass:
2. the meltblown hydrophilic masterbatch of claim 1, wherein: the hydrophilic agent is a nonionic surfactant.
3. The meltblown hydrophilic masterbatch of claim 1, wherein: the lubricant is ethylene bis stearamide.
4. The meltblown hydrophilic masterbatch of claim 1, wherein: the antioxidant tetra 1010 is tetra (3, 5-di-tert-butyl-4-hydroxy) phenylpropionic acid pentaerythritol ester.
5. The meltblown hydrophilic masterbatch of claim 1, wherein: the antioxidant 168 is tris (2, 4-di-tert-butylphenyl) phosphite.
6. The meltblown hydrophilic masterbatch of claim 1, wherein: the elastomer is a polymer of 1-octene and ethylene.
7. The meltblown hydrophilic masterbatch of claim 1, wherein: the initiator A is di-tert-butyl peroxide.
8. A preparation method of melt-blown hydrophilic master batch is characterized by comprising the following steps: the method comprises the following steps:
adding the materials into a mixing pot according to the parts by weight, and then opening the mixing pot for mixing for 3 minutes; and 2, pouring the mixture into a feeding machine, wherein the feeding machine is a double-screw feeding machine, the feeding machine is provided with a cooling water channel, and the temperature of cooling water is controlled to be lower than the melting point temperature of the hydrophilic agent, so that the mixture is ensured to enter the screw in a powder state. 3-the material enters a screw of a double-screw feeder, and the temperature of the feed inlet part is set to be 0 ℃. 4-melt extrusion, namely extruding the material in the step 3 through a screw extruder; the screw extruder comprises twelve zones, wherein the temperature of the first zone is 0 ℃, the temperature of the second zone is 50 ℃, the temperature of the third zone is 80 ℃, the temperature of the fourth zone is 120 ℃, the temperature of the fifth zone is 160 ℃, the temperature of the sixth zone is 175 ℃, the temperature of the seventh zone is 175 ℃, the temperature of the eighth zone is 170 ℃, the temperature of the ninth zone is 160 ℃, the temperature of the tenth zone is 155 ℃, the temperature of the eleventh zone is 155 ℃ and the temperature of the twelfth zone is 150 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010423677.1A CN113683834A (en) | 2020-05-19 | 2020-05-19 | Melt-blown hydrophilic master batch and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202010423677.1A CN113683834A (en) | 2020-05-19 | 2020-05-19 | Melt-blown hydrophilic master batch and preparation method thereof |
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| CN113683834A true CN113683834A (en) | 2021-11-23 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114134645A (en) * | 2021-12-10 | 2022-03-04 | 东莞市利韬过滤材料有限公司 | Hydrophilic meltblown and process for making same |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111020870A (en) * | 2019-11-25 | 2020-04-17 | 联泓(江苏)新材料研究院有限公司 | Hydrophilic antistatic polypropylene composition and preparation method and application thereof |
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2020
- 2020-05-19 CN CN202010423677.1A patent/CN113683834A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111020870A (en) * | 2019-11-25 | 2020-04-17 | 联泓(江苏)新材料研究院有限公司 | Hydrophilic antistatic polypropylene composition and preparation method and application thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114134645A (en) * | 2021-12-10 | 2022-03-04 | 东莞市利韬过滤材料有限公司 | Hydrophilic meltblown and process for making same |
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Application publication date: 20211123 |