CN113681708B - Manufacturing method of glass fiber reinforced concrete slab - Google Patents

Manufacturing method of glass fiber reinforced concrete slab Download PDF

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CN113681708B
CN113681708B CN202111064774.7A CN202111064774A CN113681708B CN 113681708 B CN113681708 B CN 113681708B CN 202111064774 A CN202111064774 A CN 202111064774A CN 113681708 B CN113681708 B CN 113681708B
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concrete
glass fiber
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net
hollow glass
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CN113681708A (en
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黄士刚
夏正忠
杨德华
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Shaanxi Huayuan Changmao Intelligent Assembly Technology Co.,Ltd.
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Shanghai Dihao Decoration Design Engineering Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B23/00Arrangements specially adapted for the production of shaped articles with elements wholly or partly embedded in the moulding material; Production of reinforced objects
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B13/00Feeding the unshaped material to moulds or apparatus for producing shaped articles; Discharging shaped articles from such moulds or apparatus
    • B28B13/02Feeding the unshaped material to moulds or apparatus for producing shaped articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B23/00Arrangements specially adapted for the production of shaped articles with elements wholly or partly embedded in the moulding material; Production of reinforced objects
    • B28B23/02Arrangements specially adapted for the production of shaped articles with elements wholly or partly embedded in the moulding material; Production of reinforced objects wherein the elements are reinforcing members
    • B28B23/022Means for inserting reinforcing members into the mould or for supporting them in the mould

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Abstract

本发明涉及一种玻璃纤维增强混凝土板的制作方法。使用将玻璃柱和细空心玻璃管按一定比例混合排列,之后将玻璃柱和细空心玻璃一起装入粗空心玻璃管中,并拉伸成型得到玻璃纤维的方法,并在拉拔后的玻璃中灌入橡胶后继续拉拔,从而大大提高了玻璃纤维的整体韧性,之后编制成网,大大提高了玻璃纤维的长程强度和韧性;使用多个层次的玻璃纤维和混凝土进行结合,可以大大提高混凝土的强度和韧性;同时各个层级使用不同的玻璃纤维密度,外层使用较高的玻璃纤维密度,可以提高抗冲击能力,内层使用较低密度的玻璃纤维网,可以防止由于混凝土内层被玻璃纤维占据而导致的分层断裂情况出现。

Figure 202111064774

The invention relates to a manufacturing method of a glass fiber reinforced concrete slab. The glass column and thin hollow glass tube are mixed and arranged in a certain proportion, and then the glass column and thin hollow glass are put into the thick hollow glass tube together, and the glass fiber is obtained by stretching and forming, and the drawn glass is placed in the glass fiber. After pouring into the rubber, it continues to draw, which greatly improves the overall toughness of the glass fiber, and then weaves it into a net, which greatly improves the long-range strength and toughness of the glass fiber; the use of multiple layers of glass fiber combined with concrete can greatly improve the concrete. At the same time, different glass fiber densities are used at each level, the outer layer uses a higher glass fiber density, which can improve the impact resistance, and the inner layer uses a lower density glass fiber mesh, which can prevent the inner layer of concrete from being damaged by glass. Delamination breaks due to fiber occupancy occur.

Figure 202111064774

Description

一种玻璃纤维增强混凝土板的制作方法A kind of manufacturing method of glass fiber reinforced concrete slab

技术领域technical field

本发明涉及工程新材料领域,尤其涉及一种玻璃纤维增强混凝土板的制作方法。The invention relates to the field of new engineering materials, in particular to a manufacturing method of a glass fiber reinforced concrete slab.

背景技术Background technique

玻璃纤维(Fiberglass),是一种性能优异的无机非金属材料,种类繁多,优点是绝缘性好、耐热性强、抗腐蚀性好、机械强度高,但缺点是性脆,耐磨性较差。它是以叶腊石、石英砂、石灰石、白云石、硼钙石、硼镁石六种矿石为原料经高温熔制、拉丝、络纱、织布等工艺制造成的,相当于一根头发丝的1/20-1/5,每束纤维原丝都由数百根甚至上千根单丝组成。玻璃纤维通常用作复合材料中的增强材料,电绝缘材料和绝热保温材料,电路基板等国民经济各个领域。Fiberglass (Fiberglass) is an inorganic non-metallic material with excellent performance. Difference. It is made of pyrophyllite, quartz sand, limestone, dolomite, boronite and boronite as raw materials through high temperature melting, wire drawing, winding, weaving and other processes, which is equivalent to a hair. 1/20-1/5, each bundle of fiber strands is composed of hundreds or even thousands of monofilaments. Glass fibers are usually used as reinforcing materials in composite materials, electrical insulating materials and thermal insulation materials, circuit substrates and other fields of the national economy.

公告号CN105971194B提供了一种具有拉丝效果的透光混凝土板及其制作方法,每相邻两光导纤维布层之间设有一玻璃纤维网格布层;所述光导纤维布层包括在同一平面上依次排列的多条光导纤维,每条光导纤维上均涂覆有偶联剂涂层。本发明增强了产品的美观性,且大大提高了产品的强度。公开号CN108468409A公开了一种织物增强混凝土与玻璃纤维增强塑料组合承重预制板,可以根据承载力要求配置沿C形型材长度方向的FRP受力筋,使混凝土和玻璃钢的强度得到充分利用,所以和钢筋混凝土板一样能作为墙体和楼板承重。然而玻璃纤维在实际使用时一般由于自身长度较短,所以长程强度不足;且由于玻璃纤维脆性大,当面对较大冲击时,韧性不足,容易断裂。Bulletin No. CN105971194B provides a light-transmitting concrete slab with a wire drawing effect and a manufacturing method thereof. A glass fiber mesh cloth layer is arranged between each adjacent two optical fiber cloth layers; the optical fiber cloth layers are included on the same plane. A plurality of optical fibers are arranged in sequence, and each optical fiber is coated with a coupling agent coating. The invention enhances the aesthetics of the product and greatly improves the strength of the product. Publication No. CN108468409A discloses a combined load-bearing prefabricated panel of fabric reinforced concrete and glass fiber reinforced plastic, which can be configured with FRP reinforcement bars along the length of the C-shaped profile according to the bearing capacity requirements, so that the strength of concrete and glass fiber reinforced plastic can be fully utilized. Reinforced concrete slabs can also be load-bearing as walls and floors. However, in actual use, glass fiber generally has insufficient long-range strength due to its short length; and due to the large brittleness of glass fiber, when faced with a large impact, the toughness is insufficient and it is easy to break.

发明内容SUMMARY OF THE INVENTION

针对上述内容,为解决上述问题,提供一种玻璃纤维增强混凝土板的制作方法,包括如下步骤:In view of the above content, in order to solve the above problems, a method for making a glass fiber reinforced concrete slab is provided, comprising the following steps:

步骤1:玻璃纤维拉伸成型,将玻璃柱和细空心玻璃管按一定比例混合排列,之后将玻璃柱和细空心玻璃一起装入粗空心玻璃管中,并拉伸成型得到玻璃纤维;Step 1: The glass fiber is stretched and formed, the glass column and the thin hollow glass tube are mixed and arranged in a certain proportion, and then the glass column and the thin hollow glass are put into the thick hollow glass tube together, and the glass fiber is obtained by stretching and forming;

步骤2:灌胶,将步骤1中的拉伸成型的玻璃纤维内灌入橡胶,灌入橡胶后进行二次拉拔;Step 2: pouring glue, pouring rubber into the stretched glass fiber in Step 1, and then pulling it for a second time after pouring into the rubber;

步骤3:将步骤2得到的二次拉拔后的玻璃纤维按照预定的形状编织成网;Step 3: Weaving the glass fiber obtained in step 2 after the secondary drawing into a net according to a predetermined shape;

步骤4:以编织成网的玻璃纤维作为骨架构建混凝土板,保温养护后得到玻璃纤维增强混凝土板。Step 4: Constructing a concrete slab with the woven glass fiber as a skeleton, and obtaining a glass fiber reinforced concrete slab after heat preservation and curing.

玻璃纤维拉伸成型和灌胶的步骤具体为:The steps of glass fiber drawing and gluing are as follows:

按照预定的比例混合玻璃柱和细空心玻璃管,其中玻璃柱和细空心玻璃管的比例为1:1至1:2;玻璃柱和细空心玻璃管的外径相同为5-8mm,细空心玻璃管的内径为3-5mm;Mix the glass column and the thin hollow glass tube according to a predetermined ratio, wherein the ratio of the glass column and the thin hollow glass tube is 1:1 to 1:2; the outer diameter of the glass column and the thin hollow glass tube are the same as 5-8mm, and the thin hollow glass tube The inner diameter of the glass tube is 3-5mm;

将玻璃柱和细空心玻璃管填入粗空心玻璃管中,每根粗空心玻璃管的外径为30-50mm,内径为25-45mm;粗空心玻璃管中可以并排填充多根玻璃柱和细空心玻璃管;Fill the glass column and thin hollow glass tube into the thick hollow glass tube, the outer diameter of each thick hollow glass tube is 30-50mm and the inner diameter is 25-45mm; the thick hollow glass tube can be filled side by side with multiple glass columns and thin hollow glass tubes. hollow glass tube;

将填充后的粗空心玻璃管在高温炉内加热至500-800℃使其软化,然后采用竖直拉拔的方式将粗空心玻璃管拉长,进行第一次拉拔,使得粗空心玻璃管的外径达到10-15mm;The filled rough hollow glass tube is heated to 500-800 ℃ in a high temperature furnace to soften it, and then the rough hollow glass tube is elongated by vertical drawing, and the first drawing is performed to make the rough hollow glass tube The outer diameter reaches 10-15mm;

将第一次拉拔后的粗空心玻璃管内灌入氟橡胶,使得粗空心玻璃管和细空心玻璃管内充满氟橡胶;Fill the thick hollow glass tube after the first drawing with fluorine rubber, so that the thick hollow glass tube and the thin hollow glass tube are filled with fluorine rubber;

将充满氟橡胶的粗空心玻璃管在500℃至550℃下进行二次拉拔,使得粗空心玻璃的管的外径达到0.2mm以下,得到玻璃纤维。The rough hollow glass tube filled with fluororubber is subjected to secondary drawing at 500° C. to 550° C. so that the outer diameter of the tube of the rough hollow glass becomes 0.2 mm or less to obtain glass fibers.

灌胶后二次拉拔的玻璃纤维的韧性大大提高,可以编制成网,具体为:The toughness of the glass fiber drawn for the second time after pouring glue is greatly improved, and it can be woven into a net, specifically:

以每束50-150根的数量将二次拉拔后的玻璃纤维扎成玻璃纤维束,然后将玻璃纤维束按照间距100-200mm的间距排列,纵横交错形成网格型,并在玻璃纤维束交叉的位置使用水性聚氨酯胶粘接牢固,得到玻璃纤维束网。The number of 50-150 glass fibers in each bundle is tied into glass fiber bundles, and then the glass fiber bundles are arranged at a distance of 100-200mm, crisscrossing to form a grid, and the glass fiber bundles are arranged in a grid pattern. The crossed position is firmly bonded with water-based polyurethane glue to obtain a glass fiber bundle mesh.

以编织成网的玻璃纤维作为骨架构建混凝土板的具体步骤为:The specific steps for constructing a concrete slab with woven glass fibers as a skeleton are:

选择一张间距100mm至150mm的玻璃纤维束网作为最下层网,固定到混凝土模具上方,并且保证最下层网距离混凝土模具的底板距离为5-8mm,喷水使得最下层网整体被浸湿;Select a glass fiber bundle mesh with a spacing of 100mm to 150mm as the lowermost mesh, and fix it on the top of the concrete mold, and ensure that the distance between the lowermost mesh and the bottom plate of the concrete mould is 5-8mm, and spray water to make the lowermost mesh as a whole soaked;

向混凝土模具中第一次填入混合好的混凝土浆料,使得混凝土高度为10-20mm;Fill the mixed concrete slurry into the concrete mold for the first time, so that the concrete height is 10-20mm;

选择一张间距150mm至200mm的玻璃纤维束网作为第二层网,喷水使得第二层网整体被浸湿,放置到混凝土上方,并振捣使得第二层网与混凝土浆料结合良好;Select a glass fiber bundle mesh with a spacing of 150mm to 200mm as the second layer mesh, spray water to make the second layer mesh wet, place it on top of the concrete, and vibrate to make the second layer mesh well combined with the concrete slurry;

向混凝土模具中第二次填入混合好的混凝土浆料,使得混凝土高度为30-40mm;Fill the concrete mold with the mixed concrete slurry for the second time, so that the concrete height is 30-40mm;

选择一张间距150mm至200mm的玻璃纤维束网作为第三层网,喷水使得第三层网整体被浸湿,放置到混凝土上方,并振捣使得第三层网与混凝土浆料结合良好;Select a glass fiber bundle mesh with a spacing of 150mm to 200mm as the third layer mesh, spray water to make the third layer mesh as a whole soaked, place it above the concrete, and vibrate to make the third layer mesh well combined with the concrete slurry;

向混凝土模具中第三次填入混合好的混凝土浆料,使得混凝土高度为50-60mm;Fill the concrete mold with the mixed concrete slurry for the third time, so that the concrete height is 50-60mm;

选择一张间距100mm至150mm的玻璃纤维束网作为第四层网,喷水使得第四层网整体被浸湿,放置到混凝土上方,并振捣使得第四层网与混凝土浆料结合良好,并整体没入混凝土。Select a glass fiber bundle mesh with a spacing of 100mm to 150mm as the fourth layer mesh, spray water to make the fourth layer mesh wet, place it above the concrete, and vibrate to make the fourth layer mesh well combined with the concrete slurry. And the whole is submerged into the concrete.

混凝土浆料中水泥、石英砂、轻集料、减水剂,消泡剂的重量比为1:1:0.14:0.02:0.1,水灰比控制在0.15以下。The weight ratio of cement, quartz sand, light aggregate, water reducing agent and defoamer in the concrete slurry is 1:1:0.14:0.02:0.1, and the water-cement ratio is controlled below 0.15.

振捣使得第四层网与混凝土浆料结合良好后可以不直接使第四层网整体没入混凝土,而选择向混凝土模具中第四次填入混合好的混凝土浆料,使第四层网整体没入混凝土。After vibrating to make the fourth-layer mesh well combined with the concrete slurry, it is not necessary to directly submerge the fourth-layer mesh into the concrete, but choose to fill the mixed concrete slurry into the concrete mold for the fourth time to make the fourth-layer mesh as a whole submerged in concrete.

第一次拉拔时的采用整体加热的方式,竖直放置粗空心玻璃管并整体加热粗空心玻璃管,拉拔速度要求在1m/min至1.5m/min之间;In the first drawing, the overall heating method is adopted, the thick hollow glass tube is placed vertically and the thick hollow glass tube is heated as a whole, and the drawing speed is required to be between 1m/min and 1.5m/min;

第二次拉拔时采用局部加热的方式,选取粗空心玻璃管的一端长度50cm的宽度进行加热,并在加热过程中拉拔粗空心玻璃管,拉拔速度在2m/min至2.5m/min之间。In the second drawing, the method of local heating is adopted, and the width of one end of the thick hollow glass tube is selected to be 50cm long, and the thick hollow glass tube is drawn during the heating process at a drawing speed of 2m/min to 2.5m/min. between.

混凝土保温养护的具体参数为:The specific parameters of concrete insulation and maintenance are:

阶段1:35-50℃下,湿度35-60%,养护时间不小于72小时;Stage 1: 35-50℃, humidity 35-60%, curing time not less than 72 hours;

阶段2:室温下,湿度35-60%,养护时间不小于10天,每天向混凝土表面喷水,要求单位面积喷水量达到200mL/m2Stage 2: At room temperature, the humidity is 35-60%, the curing time is not less than 10 days, and water is sprayed on the concrete surface every day, and the water spray volume per unit area is required to reach 200mL/m 2 .

玻璃纤维在拉拔过程中出现拉断的现象,只要玻璃纤维长度大于500mm,就能够使用;The glass fiber is broken during the drawing process, as long as the glass fiber length is greater than 500mm, it can be used;

组成玻璃纤维束的玻璃纤维如果长度不足,则直接搭接使用。If the glass fibers constituting the glass fiber bundles are insufficient in length, they are directly lapped and used.

本发明的有益效果为:The beneficial effects of the present invention are:

本发明使用将玻璃柱和细空心玻璃管按一定比例混合排列,之后将玻璃柱和细空心玻璃一起装入粗空心玻璃管中,并拉伸成型得到玻璃纤维的方法,并在拉拔后的玻璃中灌入橡胶后继续拉拔,从而大大提高了玻璃纤维的整体韧性,之后编制成网,大大提高了玻璃纤维的长程强度和韧性;The invention uses the method of mixing and arranging the glass column and the thin hollow glass tube according to a certain ratio, then putting the glass column and the thin hollow glass together into the thick hollow glass tube, and drawing and forming to obtain the glass fiber. After pouring rubber into the glass, it continues to be drawn, which greatly improves the overall toughness of the glass fiber, and then weaves it into a net, which greatly improves the long-range strength and toughness of the glass fiber;

使用多个层次的玻璃纤维和混凝土进行结合,可以大大提高混凝土的强度和韧性;同时各个层级使用不同的玻璃纤维密度,外层使用较高的玻璃纤维密度,可以提高抗冲击能力,内层使用较低密度的玻璃纤维网,可以防止由于混凝土内层被玻璃纤维占据而导致的分层断裂情况出现。The combination of multiple layers of glass fiber and concrete can greatly improve the strength and toughness of concrete; at the same time, different glass fiber densities are used for each level, and a higher glass fiber density is used for the outer layer, which can improve the impact resistance. The lower density fiberglass mesh prevents delamination fractures that can occur when the inner layer of concrete is occupied by fiberglass.

附图说明Description of drawings

被包括来提供对所公开主题的进一步认识的附图,将被并入此说明书并构成该说明书的一部分。附图也阐明了所公开主题的实现,以及连同详细描述一起用于解释所公开主题的实现原则。没有尝试对所公开主题的基本理解及其多种实践方式展示超过需要的结构细节。The accompanying drawings, which are included to provide a further understanding of the disclosed subject matter, are incorporated into and constitute a part of this specification. The drawings also illustrate implementations of the disclosed subject matter, and together with the detailed description serve to explain principles of implementation of the disclosed subject matter. No attempt has been made to show more structural detail than is required for a basic understanding of the disclosed subject matter and its various ways of practicing.

图1为本发明的玻璃纤维束网的形状结构示意图;Fig. 1 is the shape structure schematic diagram of the glass fiber bundle net of the present invention;

图2为本发明的粗玻璃管截面示意图;Fig. 2 is the rough glass tube cross-sectional schematic diagram of the present invention;

图3为本发明的混凝土层结构示意图。FIG. 3 is a schematic diagram of the concrete layer structure of the present invention.

具体实施方式Detailed ways

本发明的优点、特征以及达成所述目的的方法通过附图及后续的详细说明将会明确。The advantages and features of the present invention and the method for achieving the stated objects will be apparent from the accompanying drawings and the following detailed description.

实施例1:Example 1:

一种玻璃纤维增强混凝土板的制作方法,包括如下步骤:A manufacturing method of a glass fiber reinforced concrete slab, comprising the following steps:

步骤1:玻璃纤维拉伸成型,将玻璃柱和细空心玻璃管按一定比例混合排列,之后将玻璃柱和细空心玻璃一起装入粗空心玻璃管中,并拉伸成型得到玻璃纤维;Step 1: The glass fiber is stretched and formed, the glass column and the thin hollow glass tube are mixed and arranged in a certain proportion, and then the glass column and the thin hollow glass are put into the thick hollow glass tube together, and the glass fiber is obtained by stretching and forming;

步骤2:灌胶,将步骤1中的拉伸成型的玻璃纤维内灌入橡胶,灌入橡胶后进行二次拉拔;Step 2: pouring glue, pouring rubber into the stretched glass fiber in Step 1, and then pulling it for a second time after pouring into the rubber;

步骤3:将步骤2得到的二次拉拔后的玻璃纤维按照预定的形状编织成网;Step 3: Weaving the glass fiber obtained in step 2 after the secondary drawing into a net according to a predetermined shape;

步骤4:以编织成网的玻璃纤维作为骨架构建混凝土板,保温养护后得到玻璃纤维增强混凝土板。Step 4: Constructing a concrete slab with the woven glass fiber as a skeleton, and obtaining a glass fiber reinforced concrete slab after heat preservation and curing.

玻璃纤维拉伸成型和灌胶的步骤具体为:The steps of glass fiber drawing and gluing are as follows:

按照预定的比例混合玻璃柱和细空心玻璃管,其中玻璃柱和细空心玻璃管的比例为1:1至1:2;玻璃柱和细空心玻璃管的外径相同为5-8mm,细空心玻璃管的内径为3-5mm;Mix the glass column and the thin hollow glass tube according to a predetermined ratio, wherein the ratio of the glass column and the thin hollow glass tube is 1:1 to 1:2; the outer diameter of the glass column and the thin hollow glass tube are the same as 5-8mm, and the thin hollow glass tube The inner diameter of the glass tube is 3-5mm;

将玻璃柱和细空心玻璃管填入粗空心玻璃管中,每根粗空心玻璃管的外径为30-50mm,内径为25-45mm;粗空心玻璃管中可以并排填充多根玻璃柱和细空心玻璃管;Fill the glass column and thin hollow glass tube into the thick hollow glass tube, the outer diameter of each thick hollow glass tube is 30-50mm and the inner diameter is 25-45mm; the thick hollow glass tube can be filled side by side with multiple glass columns and thin hollow glass tubes. hollow glass tube;

将填充后的粗空心玻璃管在高温炉内加热至500-800℃使其软化,然后采用竖直拉拔的方式将粗空心玻璃管拉长,进行第一次拉拔,使得粗空心玻璃管的外径达到10-15mm;The filled rough hollow glass tube is heated to 500-800 ℃ in a high temperature furnace to soften it, and then the rough hollow glass tube is elongated by vertical drawing, and the first drawing is performed to make the rough hollow glass tube The outer diameter reaches 10-15mm;

将第一次拉拔后的粗空心玻璃管内灌入氟橡胶,使得粗空心玻璃管和细空心玻璃管内充满氟橡胶;Fill the thick hollow glass tube after the first drawing with fluorine rubber, so that the thick hollow glass tube and the thin hollow glass tube are filled with fluorine rubber;

将充满氟橡胶的粗空心玻璃管在500℃至550℃下进行二次拉拔,使得粗空心玻璃的管的外径达到0.2mm以下,得到玻璃纤维。The rough hollow glass tube filled with fluororubber is subjected to secondary drawing at 500° C. to 550° C. so that the outer diameter of the tube of the rough hollow glass becomes 0.2 mm or less to obtain glass fibers.

灌胶后二次拉拔的玻璃纤维的韧性大大提高,可以编制成网,具体为:The toughness of the glass fiber drawn for the second time after pouring glue is greatly improved, and it can be woven into a net, specifically:

以每束50根的数量将二次拉拔后的玻璃纤维扎成玻璃纤维束,然后将玻璃纤维束按照间距100-200mm的间距排列,纵横交错形成网格型,并在玻璃纤维束交叉的位置使用水性聚氨酯胶粘接牢固,得到玻璃纤维束网。The glass fibers after the secondary drawing are tied into glass fiber bundles in the number of 50 per bundle, and then the glass fiber bundles are arranged at a spacing of 100-200 mm, crisscrossed to form a grid, and the glass fiber bundles are crossed. The position is firmly bonded with water-based polyurethane glue to obtain a glass fiber bundle mesh.

以编织成网的玻璃纤维作为骨架构建混凝土板的具体步骤为:The specific steps for constructing a concrete slab with woven glass fibers as a skeleton are:

选择一张间距150mm的玻璃纤维束网作为最下层网,固定到混凝土模具上方,并且保证最下层网距离混凝土模具的底板距离为5-8mm,喷水使得最下层网整体被浸湿;Select a glass fiber bundle mesh with a spacing of 150mm as the lowermost mesh, and fix it on the top of the concrete mold, and ensure that the distance between the lowermost mesh and the bottom plate of the concrete mould is 5-8mm, and spray water to make the lowermost mesh as a whole soaked;

向混凝土模具中第一次填入混合好的混凝土浆料,使得混凝土高度为10-20mm;Fill the mixed concrete slurry into the concrete mold for the first time, so that the concrete height is 10-20mm;

选择一张间距200mm的玻璃纤维束网作为第二层网,喷水使得第二层网整体被浸湿,放置到混凝土上方,并振捣使得第二层网与混凝土浆料结合良好;Select a glass fiber bundle mesh with a spacing of 200mm as the second layer mesh, spray water to make the whole second layer mesh wet, place it on top of the concrete, and vibrate to make the second layer mesh and the concrete slurry well combined;

向混凝土模具中第二次填入混合好的混凝土浆料,使得混凝土高度为30-40mm;Fill the concrete mold with the mixed concrete slurry for the second time, so that the concrete height is 30-40mm;

选择一张间距200mm的玻璃纤维束网作为第三层网,喷水使得第三层网整体被浸湿,放置到混凝土上方,并振捣使得第三层网与混凝土浆料结合良好;Select a glass fiber bundle mesh with a spacing of 200mm as the third layer mesh, spray water to make the third layer mesh wet, place it on top of the concrete, and vibrate to make the third layer mesh and concrete slurry well combined;

向混凝土模具中第三次填入混合好的混凝土浆料,使得混凝土高度为50-60mm;Fill the concrete mold with the mixed concrete slurry for the third time, so that the concrete height is 50-60mm;

选择一张间距150mm的玻璃纤维束网作为第四层网,喷水使得第四层网整体被浸湿,放置到混凝土上方,并振捣使得第四层网与混凝土浆料结合良好,并整体没入混凝土。Select a glass fiber bundle mesh with a spacing of 150mm as the fourth layer mesh, spray water to make the fourth layer mesh wet, place it on top of the concrete, and vibrate it so that the fourth layer mesh is well combined with the concrete slurry, and the overall submerged in concrete.

混凝土浆料中水泥、石英砂、轻集料、减水剂,消泡剂的重量比为1:1:0.14:0.02:0.1,水灰比控制在0.15以下。The weight ratio of cement, quartz sand, light aggregate, water reducing agent and defoamer in the concrete slurry is 1:1:0.14:0.02:0.1, and the water-cement ratio is controlled below 0.15.

振捣使得第四层网与混凝土浆料结合良好后可以不直接使第四层网整体没入混凝土,而选择向混凝土模具中第四次填入混合好的混凝土浆料,使第四层网整体没入混凝土。After vibrating to make the fourth-layer mesh well combined with the concrete slurry, it is not necessary to directly submerge the fourth-layer mesh into the concrete, but choose to fill the mixed concrete slurry into the concrete mold for the fourth time to make the fourth-layer mesh as a whole submerged in concrete.

第一次拉拔时的采用整体加热的方式,竖直放置粗空心玻璃管并整体加热粗空心玻璃管,拉拔速度要求在1m/min至1.5m/min之间;In the first drawing, the overall heating method is adopted, the thick hollow glass tube is placed vertically and the thick hollow glass tube is heated as a whole, and the drawing speed is required to be between 1m/min and 1.5m/min;

第二次拉拔时采用局部加热的方式,选取粗空心玻璃管的一端长度50cm的宽度进行加热,并在加热过程中拉拔粗空心玻璃管,拉拔速度在2m/min至2.5m/min之间。In the second drawing, the method of local heating is adopted, and the width of one end of the thick hollow glass tube is selected to be 50cm long, and the thick hollow glass tube is drawn during the heating process at a drawing speed of 2m/min to 2.5m/min. between.

混凝土保温养护的具体参数为:The specific parameters of concrete insulation and maintenance are:

阶段1:35-50℃下,湿度35-60%,养护时间不小于72小时;Stage 1: 35-50℃, humidity 35-60%, curing time not less than 72 hours;

阶段2:室温下,湿度35-60%,养护时间不小于10天,每天向混凝土表面喷水,要求单位面积喷水量达到200mL/m2Stage 2: At room temperature, the humidity is 35-60%, the curing time is not less than 10 days, and water is sprayed on the concrete surface every day, and the water spray volume per unit area is required to reach 200mL/m 2 .

玻璃纤维在拉拔过程中出现拉断的现象,只要玻璃纤维长度大于500mm,就能够使用;The glass fiber is broken during the drawing process, as long as the glass fiber length is greater than 500mm, it can be used;

组成玻璃纤维束的玻璃纤维如果长度不足,则直接搭接使用。If the glass fibers constituting the glass fiber bundles are insufficient in length, they are directly lapped and used.

实施例2:Example 2:

一种玻璃纤维增强混凝土板的制作方法,包括如下步骤:A manufacturing method of a glass fiber reinforced concrete slab, comprising the following steps:

步骤1:玻璃纤维拉伸成型,将玻璃柱和细空心玻璃管按一定比例混合排列,之后将玻璃柱和细空心玻璃一起装入粗空心玻璃管中,并拉伸成型得到玻璃纤维;Step 1: The glass fiber is stretched and formed, the glass column and the thin hollow glass tube are mixed and arranged in a certain proportion, and then the glass column and the thin hollow glass are put into the thick hollow glass tube together, and the glass fiber is obtained by stretching and forming;

步骤2:灌胶,将步骤1中的拉伸成型的玻璃纤维内灌入橡胶,灌入橡胶后进行二次拉拔;Step 2: pouring glue, pouring rubber into the stretched glass fiber in Step 1, and then pulling it for a second time after pouring into the rubber;

步骤3:将步骤2得到的二次拉拔后的玻璃纤维按照预定的形状编织成网;Step 3: Weaving the glass fiber obtained in step 2 after the secondary drawing into a net according to a predetermined shape;

步骤4:以编织成网的玻璃纤维作为骨架构建混凝土板,保温养护后得到玻璃纤维增强混凝土板。Step 4: Constructing a concrete slab with the woven glass fiber as a skeleton, and obtaining a glass fiber reinforced concrete slab after heat preservation and curing.

玻璃纤维拉伸成型和灌胶的步骤具体为:The steps of glass fiber drawing and gluing are as follows:

按照预定的比例混合玻璃柱和细空心玻璃管,其中玻璃柱和细空心玻璃管的比例为1:1至1:2;玻璃柱和细空心玻璃管的外径相同为5-8mm,细空心玻璃管的内径为3-5mm;Mix the glass column and the thin hollow glass tube according to a predetermined ratio, wherein the ratio of the glass column and the thin hollow glass tube is 1:1 to 1:2; the outer diameter of the glass column and the thin hollow glass tube are the same as 5-8mm, and the thin hollow glass tube The inner diameter of the glass tube is 3-5mm;

将玻璃柱和细空心玻璃管填入粗空心玻璃管中,每根粗空心玻璃管的外径为30-50mm,内径为25-45mm;粗空心玻璃管中可以并排填充多根玻璃柱和细空心玻璃管;Fill the glass column and thin hollow glass tube into the thick hollow glass tube, the outer diameter of each thick hollow glass tube is 30-50mm and the inner diameter is 25-45mm; the thick hollow glass tube can be filled side by side with multiple glass columns and thin hollow glass tubes. hollow glass tube;

将填充后的粗空心玻璃管在高温炉内加热至500-800℃使其软化,然后采用竖直拉拔的方式将粗空心玻璃管拉长,进行第一次拉拔,使得粗空心玻璃管的外径达到10-15mm;The filled rough hollow glass tube is heated to 500-800 ℃ in a high temperature furnace to soften it, and then the rough hollow glass tube is elongated by vertical drawing, and the first drawing is performed to make the rough hollow glass tube The outer diameter reaches 10-15mm;

将第一次拉拔后的粗空心玻璃管内灌入氟橡胶,使得粗空心玻璃管和细空心玻璃管内充满氟橡胶;Fill the thick hollow glass tube after the first drawing with fluorine rubber, so that the thick hollow glass tube and the thin hollow glass tube are filled with fluorine rubber;

将充满氟橡胶的粗空心玻璃管在500℃至550℃下进行二次拉拔,使得粗空心玻璃的管的外径达到0.2mm以下,得到玻璃纤维。The rough hollow glass tube filled with fluororubber is subjected to secondary drawing at 500° C. to 550° C. so that the outer diameter of the tube of the rough hollow glass becomes 0.2 mm or less to obtain glass fibers.

灌胶后二次拉拔的玻璃纤维的韧性大大提高,可以编制成网,具体为:The toughness of the glass fiber drawn for the second time after pouring glue is greatly improved, and it can be woven into a net, specifically:

以每束150根的数量将二次拉拔后的玻璃纤维扎成玻璃纤维束,然后将玻璃纤维束按照间距100-200mm的间距排列,纵横交错形成网格型,并在玻璃纤维束交叉的位置使用水性聚氨酯胶粘接牢固,得到玻璃纤维束网。The glass fibers after the secondary drawing are tied into glass fiber bundles in the number of 150 per bundle, and then the glass fiber bundles are arranged at a distance of 100-200mm, criss-cross to form a grid, and the glass fiber bundles are crossed. The position is firmly bonded with water-based polyurethane glue to obtain a glass fiber bundle mesh.

以编织成网的玻璃纤维作为骨架构建混凝土板的具体步骤为:The specific steps for constructing a concrete slab with woven glass fibers as a skeleton are:

选择一张间距150mm的玻璃纤维束网作为最下层网,固定到混凝土模具上方,并且保证最下层网距离混凝土模具的底板距离为5-8mm,喷水使得最下层网整体被浸湿;Select a glass fiber bundle mesh with a spacing of 150mm as the lowermost mesh, and fix it on the top of the concrete mold, and ensure that the distance between the lowermost mesh and the bottom plate of the concrete mould is 5-8mm, and spray water to make the lowermost mesh as a whole soaked;

向混凝土模具中第一次填入混合好的混凝土浆料,使得混凝土高度为10-20mm;Fill the mixed concrete slurry into the concrete mold for the first time, so that the concrete height is 10-20mm;

选择一张间距200mm的玻璃纤维束网作为第二层网,喷水使得第二层网整体被浸湿,放置到混凝土上方,并振捣使得第二层网与混凝土浆料结合良好;Select a glass fiber bundle mesh with a spacing of 200mm as the second layer mesh, spray water to make the whole second layer mesh wet, place it on top of the concrete, and vibrate to make the second layer mesh and the concrete slurry well combined;

向混凝土模具中第二次填入混合好的混凝土浆料,使得混凝土高度为30-40mm;Fill the concrete mold with the mixed concrete slurry for the second time, so that the concrete height is 30-40mm;

选择一张间距200mm的玻璃纤维束网作为第三层网,喷水使得第三层网整体被浸湿,放置到混凝土上方,并振捣使得第三层网与混凝土浆料结合良好;Select a glass fiber bundle mesh with a spacing of 200mm as the third layer mesh, spray water to make the third layer mesh wet, place it on top of the concrete, and vibrate to make the third layer mesh and concrete slurry well combined;

向混凝土模具中第三次填入混合好的混凝土浆料,使得混凝土高度为50-60mm;Fill the concrete mold with the mixed concrete slurry for the third time, so that the concrete height is 50-60mm;

选择一张间距150mm的玻璃纤维束网作为第四层网,喷水使得第四层网整体被浸湿,放置到混凝土上方,并振捣使得第四层网与混凝土浆料结合良好,并整体没入混凝土。Select a glass fiber bundle mesh with a spacing of 150mm as the fourth layer mesh, spray water to make the fourth layer mesh wet, place it on top of the concrete, and vibrate it so that the fourth layer mesh is well combined with the concrete slurry, and the overall submerged in concrete.

混凝土浆料中水泥、石英砂、轻集料、减水剂,消泡剂的重量比为1:1:0.14:0.02:0.1,水灰比控制在0.15以下。The weight ratio of cement, quartz sand, light aggregate, water reducing agent and defoamer in the concrete slurry is 1:1:0.14:0.02:0.1, and the water-cement ratio is controlled below 0.15.

振捣使得第四层网与混凝土浆料结合良好后可以不直接使第四层网整体没入混凝土,而选择向混凝土模具中第四次填入混合好的混凝土浆料,使第四层网整体没入混凝土。After vibrating to make the fourth-layer mesh well combined with the concrete slurry, it is not necessary to directly submerge the fourth-layer mesh into the concrete, but choose to fill the mixed concrete slurry into the concrete mold for the fourth time to make the fourth-layer mesh as a whole submerged in concrete.

第一次拉拔时的采用整体加热的方式,竖直放置粗空心玻璃管并整体加热粗空心玻璃管,拉拔速度要求在1m/min至1.5m/min之间;In the first drawing, the overall heating method is adopted, the thick hollow glass tube is placed vertically and the thick hollow glass tube is heated as a whole, and the drawing speed is required to be between 1m/min and 1.5m/min;

第二次拉拔时采用局部加热的方式,选取粗空心玻璃管的一端长度50cm的宽度进行加热,并在加热过程中拉拔粗空心玻璃管,拉拔速度在2m/min至2.5m/min之间。In the second drawing, the method of local heating is adopted, and the width of one end of the thick hollow glass tube is selected to be 50cm long, and the thick hollow glass tube is drawn during the heating process at a drawing speed of 2m/min to 2.5m/min. between.

混凝土保温养护的具体参数为:The specific parameters of concrete insulation and maintenance are:

阶段1:35-50℃下,湿度35-60%,养护时间不小于72小时;Stage 1: 35-50℃, humidity 35-60%, curing time not less than 72 hours;

阶段2:室温下,湿度35-60%,养护时间不小于10天,每天向混凝土表面喷水,要求单位面积喷水量达到200mL/m2Stage 2: At room temperature, the humidity is 35-60%, the curing time is not less than 10 days, and water is sprayed on the concrete surface every day, and the water spray volume per unit area is required to reach 200mL/m 2 .

玻璃纤维在拉拔过程中出现拉断的现象,只要玻璃纤维长度大于500mm,就能够使用;The glass fiber is broken during the drawing process, as long as the glass fiber length is greater than 500mm, it can be used;

组成玻璃纤维束的玻璃纤维如果长度不足,则直接搭接使用。If the glass fibers constituting the glass fiber bundles are insufficient in length, they are directly lapped and used.

以上所述,仅为本发明的优选实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,可轻易想到变化或替换,都应涵盖在本发明的保护范围之内。因此,本发明的保护范围应以所述权利要求的保护范围为准。The above are only the preferred embodiments of the present invention, but the protection scope of the present invention is not limited thereto. Any person skilled in the art can easily think of changes or substitutions within the technical scope disclosed by the present invention. should be included within the protection scope of the present invention. Therefore, the protection scope of the present invention should be based on the protection scope of the claims.

Claims (8)

1. A manufacturing method of a glass fiber reinforced concrete slab is characterized by comprising the following steps:
step 1: the glass fiber is stretched and formed, the glass column and the thin hollow glass tube are mixed and arranged according to a predetermined proportion, then the glass column and the thin hollow glass are put into the thick hollow glass tube together, and the glass fiber is obtained through stretching and forming;
step 2: pouring rubber, namely pouring rubber into the glass fiber formed by stretching in the step 1, and performing secondary drawing after pouring the rubber;
and step 3: weaving the glass fiber obtained in the step 2 after the secondary drawing into a net according to a preset shape;
and 4, step 4: constructing a concrete slab by using the glass fiber woven into the net as a framework, and performing heat preservation and maintenance to obtain a glass fiber reinforced concrete slab;
the steps of the glass fiber stretch forming and glue pouring are as follows:
mixing the glass column and the thin hollow glass tube according to a preset ratio, wherein the ratio of the glass column to the thin hollow glass tube is 1:1 to 1: 2; the outer diameters of the glass column and the thin hollow glass tube are the same and are 5-8mm, and the inner diameter of the thin hollow glass tube is 3-5 mm;
filling the glass column and the thin hollow glass tube into the thick hollow glass tube, wherein the outer diameter of each thick hollow glass tube is 30-50mm, and the inner diameter is 25-45 mm; a plurality of glass columns and thin hollow glass tubes can be filled in the thick hollow glass tube side by side;
heating the filled thick hollow glass tube to 800 ℃ in a high-temperature furnace to soften the tube, then elongating the thick hollow glass tube in a vertical drawing mode, and carrying out primary drawing to ensure that the outer diameter of the thick hollow glass tube reaches 10-15 mm;
filling fluororubber into the thick hollow glass tube subjected to primary drawing, so that the thick hollow glass tube and the thin hollow glass tube are filled with the fluororubber;
and (3) carrying out secondary drawing on the rough hollow glass tube filled with the fluororubber at 500-550 ℃ to enable the outer diameter of the rough hollow glass tube to be less than 0.2mm, and obtaining the glass fiber.
2. The method of making a glass fiber reinforced concrete panel according to claim 1, characterized in that:
the toughness of the glass fiber drawn twice after glue pouring is greatly improved, and the glass fiber can be woven into a net, and the method specifically comprises the following steps:
and rolling the glass fibers subjected to secondary drawing into glass fiber bundles according to the number of 50-150 glass fibers per bundle, arranging the glass fiber bundles according to the distance of 100-200mm, criss-cross forming a grid shape, and firmly bonding the crossed positions of the glass fiber bundles by using aqueous polyurethane adhesive to obtain the glass fiber bundle net.
3. The method of making a glass fiber reinforced concrete panel according to claim 2, characterized in that:
the concrete steps of constructing the concrete slab by using the glass fiber woven into the net as the framework are as follows:
selecting a glass fiber bundle net with the distance of 100mm to 150mm as a lowest net, fixing the lowest net above the concrete mould, ensuring that the distance between the lowest net and a bottom plate of the concrete mould is 5-8mm, and spraying water to wet the whole lowest net;
filling the mixed concrete slurry into the concrete mould for the first time to ensure that the height of the concrete is 10-20 mm;
selecting a glass fiber bundle net with the distance of 150mm to 200mm as a second layer net, spraying water to wet the whole second layer net, placing the second layer net above concrete, and vibrating to enable the second layer net to be well combined with concrete slurry;
filling the mixed concrete slurry into the concrete mould for the second time to ensure that the height of the concrete is 30-40 mm;
selecting a glass fiber bundle net with the distance of 150mm to 200mm as a third layer net, spraying water to soak the whole third layer net, placing the third layer net above concrete, and vibrating to ensure that the third layer net is well combined with the concrete slurry;
filling the mixed concrete slurry into the concrete mould for the third time to ensure that the height of the concrete is 50-60 mm;
selecting a glass fiber bundle net with the distance of 100mm to 150mm as a fourth layer net, spraying water to enable the fourth layer net to be soaked in the whole body, placing the fourth layer net above concrete, vibrating to enable the fourth layer net to be well combined with concrete slurry, and enabling the fourth layer net to be immersed in the concrete in the whole body.
4. A method of making glass fibre reinforced concrete panels as claimed in claim 3 wherein:
the concrete slurry comprises cement, quartz sand, light aggregate and a water reducing agent, wherein the weight ratio of the defoaming agent is 1: 1: 0.14: 0.02: 0.1, and the water-cement ratio is controlled below 0.15.
5. A method of making glass fibre reinforced concrete panels as claimed in claim 3 wherein:
and after the fourth layer of net is well combined with the concrete slurry by vibration, the fourth layer of net is not directly immersed into the concrete, and the mixed concrete slurry is filled into the concrete mould for the fourth time, so that the fourth layer of net is entirely immersed into the concrete.
6. The method for manufacturing a glass fiber reinforced concrete panel according to claim 1, wherein:
when the thick hollow glass tube is drawn for the first time, an integral heating mode is adopted, the thick hollow glass tube is vertically placed and integrally heated, and the drawing speed is required to be between 1m/min and 1.5 m/min;
and during the second drawing, a local heating mode is adopted, the width of 50cm of the length of one end of the thick hollow glass tube is selected for heating, and the thick hollow glass tube is drawn in the heating process, wherein the drawing speed is between 2m/min and 2.5 m/min.
7. A method of making glass fibre reinforced concrete panels as claimed in any one of claims 3 to 5 wherein:
concrete heat preservation and maintenance parameters are as follows:
stage 1, humidity is 35-60% at 35-50 ℃, and curing time is not less than 72 hours;
and (2) stage: spraying water to the surface of the concrete every day at room temperature with the humidity of 35-60% and the curing time of not less than 10 days, wherein the water spraying amount per unit area is required to reach 200mL/m 2
8. The method of making a glass fiber reinforced concrete panel according to claim 2, characterized in that:
the glass fiber is broken in the drawing process, and can be used as long as the length of the glass fiber is more than 500 mm;
if the length of the glass fibers constituting the glass fiber bundle is insufficient, the glass fibers are directly used in an overlapping manner.
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CN100363285C (en) * 2002-05-09 2008-01-23 古河电气工业株式会社 Method for manufacturing optical fiber
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KR101911575B1 (en) * 2014-05-23 2018-10-25 (주)엘지하우시스 Continuous fiber reinforced composite material and method of manufacturing the same
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