CN113621446A - Environment-friendly quick-modification alcohol detergent - Google Patents
Environment-friendly quick-modification alcohol detergent Download PDFInfo
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- CN113621446A CN113621446A CN202111067450.9A CN202111067450A CN113621446A CN 113621446 A CN113621446 A CN 113621446A CN 202111067450 A CN202111067450 A CN 202111067450A CN 113621446 A CN113621446 A CN 113621446A
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 239000003599 detergent Substances 0.000 title claims abstract description 21
- 238000012986 modification Methods 0.000 title abstract description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims abstract description 75
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 50
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 45
- 239000012459 cleaning agent Substances 0.000 claims abstract description 33
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 25
- -1 sodium alkyl benzene Chemical class 0.000 claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 18
- 239000003381 stabilizer Substances 0.000 claims abstract description 18
- 239000002562 thickening agent Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 claims abstract description 15
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000011734 sodium Substances 0.000 claims abstract description 15
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 15
- 229940048842 sodium xylenesulfonate Drugs 0.000 claims abstract description 15
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims abstract description 15
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims abstract description 15
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 claims abstract description 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229940077388 benzenesulfonate Drugs 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 150000001298 alcohols Chemical class 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 143
- 239000000203 mixture Substances 0.000 claims description 109
- 238000006243 chemical reaction Methods 0.000 claims description 50
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 10
- 239000000194 fatty acid Substances 0.000 claims description 10
- 229930195729 fatty acid Natural products 0.000 claims description 10
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 5
- 229960000892 attapulgite Drugs 0.000 claims description 5
- 239000000440 bentonite Substances 0.000 claims description 5
- 229910000278 bentonite Inorganic materials 0.000 claims description 5
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 5
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 5
- 235000013539 calcium stearate Nutrition 0.000 claims description 5
- 239000008116 calcium stearate Substances 0.000 claims description 5
- 239000004927 clay Substances 0.000 claims description 5
- 231100000252 nontoxic Toxicity 0.000 claims description 5
- 230000003000 nontoxic effect Effects 0.000 claims description 5
- 229910052625 palygorskite Inorganic materials 0.000 claims description 5
- 239000010702 perfluoropolyether Substances 0.000 claims description 5
- 150000008301 phosphite esters Chemical class 0.000 claims description 5
- 229920000223 polyglycerol Polymers 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 229920002379 silicone rubber Polymers 0.000 claims description 5
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 9
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 229940098424 potassium pyrophosphate Drugs 0.000 abstract description 2
- 229960004418 trolamine Drugs 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000003124 biologic agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention discloses an environment-friendly quick-modification alcohol cleaning agent, which relates to the technical field of cleaning agents and adopts the technical scheme that: the compound feed comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 40 g-50 g of water, 20 g-24 g of modified methanol, 8 g-10 g of ethanol, 4 g-6 g of dichloromethane, 2 g-6 g of trichloroethane, 2 g-8 g of trichloroethylene, 6 g-8 g of acetone, 4 g-6 g of sodium hydroxide, 2 g-4 g of sodium alkyl benzene sulfonate and 2 g-4 g of triethanolamine, wherein the auxiliary materials (by weight) comprise: 8-10 g of nonionic surfactant, 4-12 g of thickener, 8-10 g of stabilizer, 14-16 g of heat-resistant agent, 4-6 g of sodium xylene sulfonate and 2-6 g of potassium pyrophosphate, and the environment-friendly rapidly-modified alcohol detergent has the beneficial effects that: the washing effect of the cleaning agent is improved by dichloromethane, trichloroethane, trichloroethylene, acetone, sodium hydroxide, sodium alkyl benzene sulfonate, triethanolamine, sodium xylene sulfonate and potassium pyrophosphate.
Description
Technical Field
The invention relates to the technical field of cleaning agents, and particularly relates to an environment-friendly quickly-modified alcohol cleaning agent.
Background
The cleaning agent is a large category and various types, including inorganic cleaning and organic cleaning, and the difference between the organic cleaning agent and the inorganic cleaning agent is that the organic cleaning agent is a cleaning agent made of a carbon-containing compound, and the inorganic cleaning agent is a cleaning agent made of a carbon-free compound, so that the organic cleaning agent and the inorganic cleaning agent belong to inorganic matters, the classification methods of the cleaning agents are various and different from each country, and the cleaning agents are generally classified into three types, namely water-based cleaning agent, semi-water-based cleaning agent and non-water-based cleaning agent, and the industrial cleaning agents are chemical or biological agents used in industry for removing dirt and are collectively called industrial cleaning agents.
The prior art has the following defects: the existing industrial cleaning agent is not environment-friendly and has poor cleaning effect.
Therefore, the invention is necessary to develop an environment-friendly quick-modifying alcohol detergent.
Disclosure of Invention
Therefore, the invention provides an environment-friendly quick modified alcohol cleaning agent, which is prepared by selecting water, modified methanol, ethanol, dichloromethane, trichloroethane, trichloroethylene, acetone, sodium hydroxide, sodium alkyl benzene sulfonate and triethanolamine as raw materials, selecting a nonionic surfactant, a thickening agent, a stabilizer, a heat-resistant agent, sodium xylene sulfonate and potassium pyrophosphate as auxiliary materials and then proportioning according to a certain proportion, so as to solve the problems that the existing industrial cleaning agent is not environment-friendly and has poor cleaning effect.
In order to achieve the above purpose, the invention provides the following technical scheme: an environment-friendly fast-modified alcohol cleaning agent comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 40 g-50 g of water, 20 g-24 g of modified methanol, 8 g-10 g of ethanol, 4 g-6 g of dichloromethane, 2 g-6 g of trichloroethane, 2 g-8 g of trichloroethylene, 6 g-8 g of acetone, 4 g-6 g of sodium hydroxide, 2 g-4 g of sodium alkyl benzene sulfonate and 2 g-4 g of triethanolamine, wherein the auxiliary materials (by weight) comprise: 8-10 g of nonionic surfactant, 4-12 g of thickening agent, 8-10 g of stabilizer, 14-16 g of heat-resistant agent, 4-6 g of sodium xylene sulfonate and 2-6 g of potassium pyrophosphate.
Preferably, the nonionic surfactant is one or a mixture of fatty alcohol-polyoxyethylene ether, polyoxyethylene sorbitan fatty acid ester and polyglycerol fatty acid ester.
Preferably, the thickener is one or a mixture of more of organic bentonite, diatomite and attapulgite clay.
Preferably, the stabilizer is one or a mixture of more of calcium stearate, zinc stearate and nontoxic phosphite ester.
Preferably, the heat-resistant agent is one or a mixture of more of organosilicon, perfluoropolyether, diatomite and silicone rubber.
Preferably, the preparation method comprises the following specific steps:
s1, adding water, modified methanol and ethanol into a reaction kettle, stirring, and then adding dichloromethane into the reaction kettle, and stirring to obtain a mixture A;
s2, adding trichloroethane and trichloroethylene into the reaction kettle, stirring, and then adding acetone into the reaction kettle, stirring to obtain a mixture B;
s3, adding sodium hydroxide and sodium alkyl benzene sulfonate into a reaction kettle for stirring, and after stirring, adding triethanolamine into the reaction kettle for stirring to obtain a mixture C;
s4, adding sodium xylene sulfonate and potassium pyrophosphate into a reaction kettle, and stirring to obtain a mixture D;
s5, placing the mixture A, the mixture B, the mixture C and the mixture D into a reaction kettle, and stirring to obtain a mixture E;
s6, putting the mixture E and the heat-resistant agent into a reaction kettle, and stirring to obtain a mixture F;
s7, putting the mixture F, the nonionic surfactant, the thickening agent and the stabilizing agent into a reaction kettle, and stirring to obtain a mixture G;
s8, the mixture G is allowed to stand and is allowed to cool naturally, thereby obtaining a detergent.
Preferably, in the step S1, the stirring temperature without adding dichloromethane is 45-50 ℃, the stirring time is 60-66 min, the stirring temperature after adding dichloromethane is 50-60 ℃, and the stirring time is 70-80 min.
Preferably, in the step S2, the stirring temperature without adding acetone is 60-70 ℃, the stirring time is 55-60 min, the stirring temperature with adding acetone is 60-65 ℃, and the stirring time is 70-80 min.
Preferably, in the step S3, the stirring temperature without adding triethanolamine is 70-80 ℃, the stirring time is 62-66 min, the stirring temperature after adding triethanolamine is 75-80 ℃, and the stirring time is 50-70 min.
Preferably, in the step S4, the stirring time and temperature are 110-120 ℃, and the stirring time is 45-55 min;
in the step S5, the stirring time and temperature is 420-440 ℃, and the stirring time is 50-55 min;
in the step S6, the stirring time and temperature are 440-460 ℃, and the stirring time is 40-50 min;
in the step S7, the stirring time and temperature are 450-470 ℃, and the stirring time is 60-70 min.
The invention has the beneficial effects that:
1. the modified methanol has the effect of improving the environmental protection of the cleaning agent;
2. the washing effect of the cleaning agent is improved by dichloromethane, trichloroethane, trichloroethylene, acetone, sodium hydroxide, sodium alkyl benzene sulfonate, triethanolamine, sodium xylene sulfonate and potassium pyrophosphate;
3. the heat-resistant agent has the effect of improving the low-temperature resistance of the detergent, thereby improving the application range of the detergent.
Detailed Description
The following description of the preferred embodiments of the present invention is provided for the purpose of illustration and description, and is in no way intended to limit the invention.
Example 1:
the invention provides an environment-friendly fast-modified alcohol cleaning agent, which comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 40g of water, 20g of modified methanol, 8g of ethanol, 4g of dichloromethane, 2g of trichloroethane, 2g of trichloroethylene, 6g of acetone, 4g of sodium hydroxide, 2g of sodium alkyl benzene sulfonate and 2g of triethanolamine, wherein the auxiliary materials (by weight) comprise: 8g of nonionic surfactant, 4g of thickening agent, 8g of stabilizing agent, 14g of heat-resistant agent, 4g of sodium xylene sulfonate and 2g of potassium pyrophosphate.
Further, the nonionic surfactant is one or a mixture of fatty alcohol-polyoxyethylene ether, polyoxyethylene sorbitan fatty acid ester and polyglycerol fatty acid ester.
Further, the thickener is one or a mixture of more of organic bentonite, diatomite and attapulgite clay.
Further, the stabilizer is one or a mixture of more of calcium stearate, zinc stearate and nontoxic phosphite ester.
Further, the heat-resistant agent is one or a mixture of more of organic silicon, perfluoropolyether, diatomite and silicon rubber.
Further, the preparation method comprises the following specific steps:
s1, adding water, modified methanol and ethanol into a reaction kettle, stirring, adding dichloromethane into the reaction kettle, and stirring to obtain a mixture A, wherein the stirring temperature of the mixture A without dichloromethane is 45 ℃, the stirring time is 60min, the stirring temperature of the mixture A after dichloromethane is added is 50 ℃, and the stirring time is 70 min;
s2, adding trichloroethane and trichloroethylene into a reaction kettle, stirring, then adding acetone into the reaction kettle, and stirring to obtain a mixture B, wherein the stirring temperature without adding acetone is 60 ℃, the stirring time is 55min, and the stirring temperature with adding acetone is 60 ℃, and the stirring time is 70 min;
s3, adding sodium hydroxide and sodium alkyl benzene sulfonate into a reaction kettle, stirring, adding triethanolamine into the reaction kettle, and stirring to obtain a mixture C, wherein the stirring temperature of the mixture C without triethanolamine is 70 ℃, the stirring time is 62min, the stirring temperature of the mixture C after triethanolamine is added is 75 ℃, and the stirring time is 50 min;
s4, placing sodium xylene sulfonate and potassium pyrophosphate into a reaction kettle to be stirred, so as to obtain a mixture D, wherein the stirring time is 110 ℃, and the stirring time is 45 min;
s5, placing the mixture A, the mixture B, the mixture C and the mixture D into a reaction kettle, and stirring to obtain a mixture E, wherein the stirring time is 420 ℃ and 50 min;
s6, putting the mixture E and the heat-resistant agent into a reaction kettle, and stirring to obtain a mixture F, wherein the stirring time is 440 ℃, and the stirring time is 40 min;
s7, placing the mixture F, the nonionic surfactant, the thickening agent and the stabilizing agent into a reaction kettle, and stirring to obtain a mixture G, wherein the stirring time is 450 ℃ and 60 min;
s8, the mixture G is allowed to stand and is allowed to cool naturally, thereby obtaining a detergent.
Example 2:
the invention provides an environment-friendly fast-modified alcohol cleaning agent, which comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 45g of water, 22g of modified methanol, 9g of ethanol, 5g of dichloromethane, 4g of trichloroethane, 5g of trichloroethylene, 7g of acetone, 5g of sodium hydroxide, 3g of sodium alkyl benzene sulfonate and 3g of triethanolamine, wherein the auxiliary materials (by weight) comprise: 9g of nonionic surfactant, 8g of thickening agent, 9g of stabilizing agent, 15g of heat-resistant agent, 5g of sodium xylene sulfonate and 4g of potassium pyrophosphate.
Further, the nonionic surfactant is one or a mixture of fatty alcohol-polyoxyethylene ether, polyoxyethylene sorbitan fatty acid ester and polyglycerol fatty acid ester.
Further, the thickener is one or a mixture of more of organic bentonite, diatomite and attapulgite clay.
Further, the stabilizer is one or a mixture of more of calcium stearate, zinc stearate and nontoxic phosphite ester.
Further, the heat-resistant agent is one or a mixture of more of organic silicon, perfluoropolyether, diatomite and silicon rubber.
Further, the preparation method comprises the following specific steps:
s1, adding water, modified methanol and ethanol into a reaction kettle, stirring, adding dichloromethane into the reaction kettle, and stirring to obtain a mixture A, wherein the stirring temperature of the mixture A without dichloromethane is 47.5 ℃, the stirring time is 63min, the stirring temperature of the mixture A after dichloromethane is added is 55 ℃, and the stirring time is 75 min;
s2, adding trichloroethane and trichloroethylene into a reaction kettle, stirring, adding acetone into the reaction kettle, and stirring to obtain a mixture B, wherein the stirring temperature without adding acetone is 65 ℃, the stirring time is 57.5min, the stirring temperature with adding acetone is 62.5 ℃, and the stirring time is 75 min;
s3, adding sodium hydroxide and sodium alkyl benzene sulfonate into a reaction kettle, stirring, adding triethanolamine into the reaction kettle, and stirring to obtain a mixture C, wherein the stirring temperature of the mixture C without triethanolamine is 75 ℃, the stirring time is 64min, the stirring temperature of the mixture C after triethanolamine is added is 77.5 ℃, and the stirring time is 60 min;
s4, placing sodium xylene sulfonate and potassium pyrophosphate into a reaction kettle to be stirred, so as to obtain a mixture D, wherein the stirring time is 115 ℃, and the stirring time is 50 min;
s5, placing the mixture A, the mixture B, the mixture C and the mixture D into a reaction kettle, and stirring to obtain a mixture E, wherein the stirring time is 430 ℃ and 52.5 min;
s6, putting the mixture E and the heat-resistant agent into a reaction kettle, and stirring to obtain a mixture F, wherein the stirring time is 450 ℃ and 45 min;
s7, placing the mixture F, the nonionic surfactant, the thickening agent and the stabilizing agent into a reaction kettle, and stirring to obtain a mixture G, wherein the stirring time is 460 ℃ and 65 min;
s8, the mixture G is allowed to stand and is allowed to cool naturally, thereby obtaining a detergent.
Example 3:
the invention provides an environment-friendly fast-modified alcohol cleaning agent, which comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 50g of water, 24g of modified methanol, 10g of ethanol, 6g of dichloromethane, 6g of trichloroethane, 8g of trichloroethylene, 8g of acetone, 6g of sodium hydroxide, 4g of sodium alkyl benzene sulfonate and 4g of triethanolamine, wherein the auxiliary materials (by weight) comprise: 10g of nonionic surfactant, 12g of thickening agent, 10g of stabilizing agent, 16g of heat-resistant agent, 6g of sodium xylene sulfonate and 6g of potassium pyrophosphate.
Further, the nonionic surfactant is one or a mixture of fatty alcohol-polyoxyethylene ether, polyoxyethylene sorbitan fatty acid ester and polyglycerol fatty acid ester.
Further, the thickener is one or a mixture of more of organic bentonite, diatomite and attapulgite clay.
Further, the stabilizer is one or a mixture of more of calcium stearate, zinc stearate and nontoxic phosphite ester.
Further, the heat-resistant agent is one or a mixture of more of organic silicon, perfluoropolyether, diatomite and silicon rubber.
Further, the preparation method comprises the following specific steps:
s1, adding water, modified methanol and ethanol into a reaction kettle, stirring, adding dichloromethane into the reaction kettle, and stirring to obtain a mixture A, wherein the stirring temperature of the mixture A without dichloromethane is 50 ℃, the stirring time is 66min, the stirring temperature of the mixture A after dichloromethane is added is 60 ℃, and the stirring time is 80 min;
s2, adding trichloroethane and trichloroethylene into a reaction kettle, stirring, adding acetone into the reaction kettle, and stirring to obtain a mixture B, wherein the stirring temperature without adding acetone is 70 ℃, the stirring time is 60min, the stirring temperature with adding acetone is 65 ℃, and the stirring time is 80 min;
s3, adding sodium hydroxide and sodium alkyl benzene sulfonate into a reaction kettle, stirring, adding triethanolamine into the reaction kettle, and stirring to obtain a mixture C, wherein the stirring temperature of the mixture C without triethanolamine is 80 ℃, the stirring time is 66min, the stirring temperature of the mixture C after triethanolamine is added is 80 ℃, and the stirring time is 70 min;
s4, placing sodium xylene sulfonate and potassium pyrophosphate into a reaction kettle to be stirred, so as to obtain a mixture D, wherein the stirring time is 120 ℃, and the stirring time is 55 min;
s5, placing the mixture A, the mixture B, the mixture C and the mixture D into a reaction kettle, and stirring to obtain a mixture E, wherein the stirring time is 440 ℃, and the stirring time is 55 min;
s6, putting the mixture E and the heat-resistant agent into a reaction kettle, and stirring to obtain a mixture F, wherein the stirring time is 460 ℃ and the stirring time is 50 min;
s7, placing the mixture F, the nonionic surfactant, the thickening agent and the stabilizing agent into a reaction kettle, and stirring to obtain a mixture G, wherein the stirring time is 470 ℃ and 70 min;
s8, the mixture G is allowed to stand and is allowed to cool naturally, thereby obtaining a detergent.
The following data were obtained by comparing the detergents prepared in examples 1 to 3 above:
as can be seen from the above table, the cleaning agents prepared in examples 1 to 3 have better performances in terms of cleaning effect, heat resistance and environmental protection, but the cleaning agents have different effects in terms of cleaning effect, heat resistance and environmental protection due to different ratios of water, modified methanol, ethanol, dichloromethane, trichloroethane, trichloroethylene, acetone, sodium hydroxide, sodium alkylbenzenesulfonate, triethanolamine, nonionic surfactant, thickener, stabilizer, heat resistance, sodium xylene sulfonate and potassium pyrophosphate.
The above description is only a preferred embodiment of the present invention, and any person skilled in the art may modify the present invention or modify it into an equivalent technical solution by using the technical solution described above. Therefore, any simple modifications or equivalent substitutions made in accordance with the technical solution of the present invention are within the scope of the claims of the present invention.
Claims (10)
1. An environment-friendly fast-modified alcohol cleaning agent comprises raw materials and auxiliary materials, and is characterized in that: the raw materials (by weight) comprise: 40 g-50 g of water, 20 g-24 g of modified methanol, 8 g-10 g of ethanol, 4 g-6 g of dichloromethane, 2 g-6 g of trichloroethane, 2 g-8 g of trichloroethylene, 6 g-8 g of acetone, 4 g-6 g of sodium hydroxide, 2 g-4 g of sodium alkyl benzene sulfonate and 2 g-4 g of triethanolamine, wherein the auxiliary materials (by weight) comprise: 8-10 g of nonionic surfactant, 4-12 g of thickening agent, 8-10 g of stabilizer, 14-16 g of heat-resistant agent, 4-6 g of sodium xylene sulfonate and 2-6 g of potassium pyrophosphate.
2. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 1, wherein: the nonionic surfactant is one or more of fatty alcohol-polyoxyethylene ether, polyoxyethylene sorbitan fatty acid ester and polyglycerol fatty acid ester.
3. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 1, wherein: the thickener is one or more of organic bentonite, diatomite and attapulgite clay.
4. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 1, wherein: the stabilizer is one or a mixture of more of calcium stearate, zinc stearate and nontoxic phosphite ester.
5. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 1, wherein: the heat-resistant agent is one or a mixture of more of organic silicon, perfluoropolyether, diatomite and silicon rubber.
6. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 1, wherein: the preparation method comprises the following specific steps:
s1, adding water, modified methanol and ethanol into a reaction kettle, stirring, and then adding dichloromethane into the reaction kettle, and stirring to obtain a mixture A;
s2, adding trichloroethane and trichloroethylene into the reaction kettle, stirring, and then adding acetone into the reaction kettle, stirring to obtain a mixture B;
s3, adding sodium hydroxide and sodium alkyl benzene sulfonate into a reaction kettle for stirring, and after stirring, adding triethanolamine into the reaction kettle for stirring to obtain a mixture C;
s4, adding sodium xylene sulfonate and potassium pyrophosphate into a reaction kettle, and stirring to obtain a mixture D;
s5, placing the mixture A, the mixture B, the mixture C and the mixture D into a reaction kettle, and stirring to obtain a mixture E;
s6, putting the mixture E and the heat-resistant agent into a reaction kettle, and stirring to obtain a mixture F;
s7, putting the mixture F, the nonionic surfactant, the thickening agent and the stabilizing agent into a reaction kettle, and stirring to obtain a mixture G;
s8, the mixture G is allowed to stand and is allowed to cool naturally, thereby obtaining a detergent.
7. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 6, wherein: in the step S1, the stirring temperature without adding dichloromethane is 45-50 ℃, the stirring time is 60-66 min, the stirring temperature after adding dichloromethane is 50-60 ℃, and the stirring time is 70-80 min.
8. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 6, wherein: in the step S2, the stirring temperature without adding acetone is 60-70 ℃, the stirring time is 55-60 min, the stirring temperature with adding acetone is 60-65 ℃, and the stirring time is 70-80 min.
9. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 6, wherein: in the step S3, the stirring temperature without adding triethanolamine is 70-80 ℃, the stirring time is 62-66 min, the stirring temperature after adding triethanolamine is 75-80 ℃, and the stirring time is 50-70 min.
10. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 6, wherein: in the step S4, the stirring time and temperature are 110-120 ℃, and the stirring time is 45-55 min;
in the step S5, the stirring time and temperature is 420-440 ℃, and the stirring time is 50-55 min;
in the step S6, the stirring time and temperature are 440-460 ℃, and the stirring time is 40-50 min;
in the step S7, the stirring time and temperature are 450-470 ℃, and the stirring time is 60-70 min.
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| JP2000129287A (en) * | 1998-10-29 | 2000-05-09 | Lion Corp | Neutral liquid detergent composition |
| CN101538511A (en) * | 2009-03-11 | 2009-09-23 | 上海九盛实业有限公司 | Decarburization cleaner |
| CN103497853A (en) * | 2013-10-10 | 2014-01-08 | 青岛三立新源电器有限公司 | Special cleaning agent for electric equipment |
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| CN106906082A (en) * | 2017-03-08 | 2017-06-30 | 齐齐哈尔百思特科技有限责任公司 | One kind is except gluing cleaning agent and preparation method thereof |
| CN112680291A (en) * | 2020-12-29 | 2021-04-20 | 世华中科(北京)科技股份有限公司 | Electrified cleaning agent for machine room |
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2021
- 2021-09-13 CN CN202111067450.9A patent/CN113621446A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000129287A (en) * | 1998-10-29 | 2000-05-09 | Lion Corp | Neutral liquid detergent composition |
| CN101538511A (en) * | 2009-03-11 | 2009-09-23 | 上海九盛实业有限公司 | Decarburization cleaner |
| CN103497853A (en) * | 2013-10-10 | 2014-01-08 | 青岛三立新源电器有限公司 | Special cleaning agent for electric equipment |
| CN106350326A (en) * | 2016-08-24 | 2017-01-25 | 诺而曼环保科技（江苏）有限公司 | Surface tension increasing agent for hydrocarbon cleaning agent as well as preparation method and use method of surface tension increasing agent |
| CN106906082A (en) * | 2017-03-08 | 2017-06-30 | 齐齐哈尔百思特科技有限责任公司 | One kind is except gluing cleaning agent and preparation method thereof |
| CN112680291A (en) * | 2020-12-29 | 2021-04-20 | 世华中科(北京)科技股份有限公司 | Electrified cleaning agent for machine room |
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